Dissertations / Theses on the topic 'Carbothermal reduction'
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Du, Xiaoyang 1960. "Carbothermal reduction of ilmenite and fayalite." Diss., The University of Arizona, 1996. http://hdl.handle.net/10150/290600.
Full textDewan, Mohammad Ashikur Rahman Materials Science & Engineering Faculty of Science UNSW. "Carbothermal synthesis of titanium oxycarbide." Awarded By:University of New South Wales. Materials Science & Engineering, 2009. http://handle.unsw.edu.au/1959.4/44511.
Full textDurham, Simon J. P. "Carbothermal reduction of silica to silicon nitride powder." Thesis, McGill University, 1989. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=74221.
Full textSol-gel processing was found to provide superior mixing conditions over dry mixing, which allowed for complete conversion to silicon nitride at optimum carbon:silica ratios of 7:1. The ideal reaction temperature was found to be in the range of 1500$ sp circ$C to 1550$ sp circ$C. Suppression of silicon oxynitride and silicon carbide was achieved by ensuring that: (a) the nitrogen gas was gettered of oxygen, and (b) that the gas passed through the reactants. Thermodynamic modelling of the Si-O-N-C system showed that ordinarily the equilibrium conditions for the formation of silicon nitride are very delicate. Slight deviations away from equilibrium leads to the formation of non-equilibrium species such as silicon carbide caused by the build-up of carbon monoxide. Reaction conditions such as allowing nitrogen gas to pass through the reactants beneficially moves the reaction equilibrium well away from the silicon carbide and silicon oxynitride stability regions.
The particle size of silicon nitride produced from carbon and silica precursors was of the order of 2-3 $ mu$m and could only be reduced to sub-micron range by seeding with ultra-fine silicon nitride. It was shown that the mechanism of nucleation and growth of unseeded reactants was first nucleation on the carbon by the reaction between carbon, SiO gas and nitrogen (gas-solid reaction), and then growth of the particles by the gas phase reaction (CO, SiO, N$ sb2$).
Mariappan, L. "In-Situ Synthesis Of A12O3_ZrO2_SiCw Ceramic Matrix Composites By Carbothermal Reduction Of Natural Silicates." Thesis, Indian Institute of Science, 2000. http://hdl.handle.net/2005/215.
Full textBejarano, Cesar. "Carbothermal reduction of sulfur dioxide using oil-sands fluid coke." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0016/MQ53340.pdf.
Full textCho, Young Whan. "Synthesis of nitrogen ceramic powders by carbothermal reduction and nitridation." Thesis, University of Cambridge, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.277802.
Full textJain, Anubhav. "Synthesis and Processing of Nanocrystalline Zirconium Carbide Formed by Carbothermal Reduction." Thesis, Georgia Institute of Technology, 2004. http://hdl.handle.net/1853/4797.
Full textTaneka, S. "Carbothermal reduction of friable chromite in a small-scale transferred-arc furnace." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37873.
Full textDuddukuri, Ramesh. "SYNTHESIZING AND CHARACTERIZATION OF TITANIUM DIBORIDE FOR COMPOSITE BIPOLAR PLATES IN PEM FUEL CELL." OpenSIUC, 2012. https://opensiuc.lib.siu.edu/theses/862.
Full textKononov, Ring Materials Science & Engineering Faculty of Science UNSW. "Carbothermal solid state reduction of manganese oxide and ores in different gas atmospheres." Publisher:University of New South Wales. Materials Science & Engineering, 2008. http://handle.unsw.edu.au/1959.4/41459.
Full textCheng, Zhe. "Reaction Kinetics and Structural Evolution for the Formation of Nanocrystalline Silicon Carbide via Carbothermal Reduction." Thesis, Georgia Institute of Technology, 2004. http://hdl.handle.net/1853/5896.
Full textTerner, Mark Robert. "The production of low-cost α-sialons via carbothermal reduction-nitridation of slag-based mixtures." Monash University, School of Physics and Materials Engineering, 2003. http://arrow.monash.edu.au/hdl/1959.1/9577.
Full textSondhi, Anchal. "Investigations in the Mechanism of Carbothermal Reduction of Yttria Stabilized Zirconia for Ultra-high Temperature Ceramics Application and Its Influence on Yttria Contained in It." Thesis, University of North Texas, 2014. https://digital.library.unt.edu/ark:/67531/metadc500159/.
Full textFiefhaus, Silas R. "The Optimization of The Synthesis and Characterization of Vapor-Liquid-Solid Grown ZnO Nanowires." UKnowledge, 2016. http://uknowledge.uky.edu/chemistry_etds/62.
Full textAdipuri, Andrew Materials Science & Engineering Faculty of Science UNSW. "Chlorination of Titanium Oxycarbide and Oxycarbonitride." Publisher:University of New South Wales. Materials Science & Engineering, 2009. http://handle.unsw.edu.au/1959.4/44405.
Full textIgiehon, Uwagboe Osamede. "Carbothermic reduction of complex sulphides." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/46358.
Full textCarvalho, Raquel Guilherme de. "Redu??o carbot?rmica de TiO2 por descarga em c?todo oco." Universidade Federal do Rio Grande do Norte, 2011. http://repositorio.ufrn.br:8080/jspui/handle/123456789/15673.
Full textConselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico
In this study we used the plasma as a source of energy in the process of carbothermic reduction of rutile ore (TiO2). The rutile and graphite powders were milled for 15 h and placed in a hollow cathode discharge produced by in order to obtain titanium carbonitride directly from the reaction, was verified the influence of processing parameters of plasma temperature and time in the synthesis of TiCN. The reaction was carried out at 600, 700 and 800˚C for 3 to 4 hours in an atmosphere of nitrogen and argon. During all reactions was monitored by plasma technique of optical emission spectroscopy (EEO) to check the active species present in the process of carbothermal reduction of TiO2. The powder obtained after the reactions were characterized by the techniques of X-ray diffraction (XRD) and scanning electron microscopy (SEM). The technique of EEO were detected in all reactions the spectra CO and NO, and these gas-phase resulting from the reduction of TiO2. The results of X-ray diffraction confirmed the reduction, where for all conditions studied there was evidence of early reduction of TiO2 through the emergence of intermediate oxides. In the samples reduced at 600 and 700˚C, there was only the phase Ti6O11, those reduced to 800˚C appeared Ti5O9 phases, and Ti6O11 Ti7O13, confirming that the carbothermal reduction in plasma, a reduction of the ore rutile (TiO2) in a series of intermediate titanium oxide (TinO2n-1) where n varies between 5 and 10
Neste trabalho foi utilizado o plasma como fonte energ?tica no processo de redu??o carbot?rmica do min?rio rutilo (TiO2). Os p?s de rutilo e grafite foram mo?dos durante 15 h e introduzidos numa descarga produzida por c?todo oco a fim de obter carbonitreto de tit?nio diretamente da rea??o, sendo verificado a influ?ncia dos par?metros de processamento de plasma, temperatura e tempo na s?ntese de TiCN. As rea??o foram efetuadas a 600, 700 e 800˚C por 3 e 4 horas numa atmosfera de nitrog?nio e arg?nio. Durante todas as rea??es o plasma foi monitorado pela t?cnica de espectroscopia de emiss?o ?ptica (EEO) para verificar as esp?cies ativas presente no processo de redu??o carbot?rmica de TiO2. Os p?s obtidos ap?s as rea??es foram caracterizados pelas t?cnicas de difra??o de raios X (DRX) e microscopia eletr?nica de varredura (MEV). Pela t?cnica de EEO foram detectados em todas as rea??es os espectros CO e NO, sendo essas fases gasosas resultante da redu??o do TiO2. Os resultados de difra??o de raios X confirmou essa redu??o, onde para todas as condi??es estudadas houve evid?ncia de in?cio da redu??o do TiO2 atrav?s do aparecimento de ?xidos intermedi?rios. Nas amostras reduzidas a 600 e 700˚C observou-se apenas a fase Ti6O11, naquelas reduzidas a 800 ˚C apareceram as fases Ti5O9, Ti6O11 e Ti7O13, comprovando que com a redu??o carbot?rmica em plasma, houve redu??o do min?rio rutilo (TiO2) em uma s?rie de ?xido intermedi?rios de tit?nio (TinO2n-1) onde n varia entre 5 e 10
Frank, Robert A. "Physical chemistry of carbothermic reduction of alumina." Thesis, Massachusetts Institute of Technology, 1985. http://hdl.handle.net/1721.1/15150.
Full textMICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE
Vita.
Bibliography: leaves 177-180.
by Robert A. Frank.
M.S.
VEIGA, SONIA M. B. da. "Obtencao e caracterizacao do composito Alsub2Osub3-SiC-ZrOsub2." reponame:Repositório Institucional do IPEN, 1996. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10469.
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Tese (Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Chuayboon, Srirat. "Solar fuels production from thermochemical gasification and reforming of carbonaceous feedstocks." Thesis, Perpignan, 2019. http://www.theses.fr/2019PERP0019.
Full textThe investigated solar thermochemical processes consist of the thermochemical conversion of solid and gaseous carbonaceous feedstocks into syngas as well as metal oxides reduction into metal commodities utilizing concentrated solar energy to drive endothermic chemical reactions, thereby enabling intermittent solar energy storage into solar fuels and avoiding CO2 emissions. This work aims to experimentally investigate three key solar thermochemical conversion approaches regarding biomass gasification, chemical looping reforming of methane, and carbothermal reduction of ZnO and MgO. Solar gasification and solar chemical looping reforming allowed valorizing wood biomass and methane into syngas, while solar carbothermal reduction was applied to produce Zn and Mg from ZnO and MgO. Such solar thermochemical processes were performed in 1.5 kWth prototype solar chemical reactors, utilizing highly concentrated sunlight provided by a solar concentrator at PROMES laboratory, Odeillo, France. The impact of controlling parameters of each process on the reaction mechanism, conversion, yields, and process performance, during on-sun testing was investigated and evaluated thoroughly. Such processes were proved to significantly improve the chemical conversion, syngas yields, energy efficiency, with solar energy storage into transportable fuels, thereby outperforming the conventional processes. Moreover, their feasibility, reliability, and robustness in converting both methane and biomass feedstocks to syngas as well as producing Mg and Zn metals in batch and continuous operation under vacuum and atmospheric conditions during on-sun operation were successfully demonstrated
Lundgren, Emil. "Preparation of uranium carbide through carbothermic reduction of uranium dioxide." Thesis, KTH, Fysik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-149675.
Full textBENIQUE, FERRY SABEL BELISARIO. "CONTRIBUTION AT CARBOTHERMIC SELF-REDUCTION OF AGGLOMERATES OF MANGANESE OXIDES." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2007. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=11024@1.
Full textNeste trabalho, foram feitas experiências de redução em temperaturas na faixa de 900°C a 1300°C, usando briquetes auto-redutores contendo óxidos de manganês e carvão vegetal, visando investigar o processo de redução de MnO2 para MnO. É apresentado um panorama geral do manganês, indicando os principais produtos, entre eles, o MnO para uso agropecuário e a liga FeMn, insumo siderúrgico e evidenciando os aspectos termodinâmicos e cinéticos no processamento para a obtenção destes produtos. Cabe assinalar que o MnO é um produto intermediário no processo de fabricação da liga ferro-manganês. Mostram-se também detalhes do procedimento experimental, caracterização dos materiais utilizados e as discussões sobre os resultados obtidos. Na determinação das conversões de MnO foi utilizado o método de análise química de titulação por complexometría com EDTA. A partir dos resultados experimentais foi proposto um modelo para determinação dos parâmetros cinéticos. Pelos resultados da redução de Mn+4 para Mn+2, foi possível distinguir dois estágios nas temperaturas ensaiadas. O primeiro estágio foi marcado por altas velocidades de reação, a até aproximadamente 10 minutos de experimentação, alcançando conversões elevadas de MnO; como foi o caso dos ensaios nas temperaturas de 1000°C e 1200°C, que já indicavam em 10 minutos valores de conversões iguais a 0.94. Já para o segundo estágio, após os 10 minutos iniciais de experimentação, as velocidades e os valores da conversão apresentaram uma queda, sugerindo que o produto do primeiro estágio, o MnO, poderia estar começando a se transformar em outra substancia ( provavelmente o Mn3C ). Por não ser objetivo desta dissertação determinar a natureza da citada transformação, apenas a evidência de sua ocorrência foi aqui explicitada, ficando os estudos mais detalhados para outro trabalho. O modelo cinético concluiu que o processo se passava essencialmente em duas etapas : uma para tempos curtos e outra para tempos longos, sendo o tempo de experimentação em torno de 10 minutos a fronteira destas etapas . O valor da energia de ativação para a etapa em tempos menores, ou seja, inferiores a 10 minutos, foi, nas temperaturas estudadas, 1000, 1100, 1150 e 1200°C, de 11,50 KJ/mol e o fator de freqüência pré-exponencial 0,057 mHz, sugerindo um controle difusional.. Já para os tempos maiores que 10 minutos, os experimentos nas temperaturas de 900, 1000, 1100, 1150, 1200 e 1300°C, muito embora não se tenha pesquisado a natureza do novo composto ( possivelmente o carboneto de manganês ), forneceu para a energia de ativação o valor de 46,10 KJ/mol e para o fator de freqüência pré-exponencial 48,045 Hz, sugerindo, em conseqüência, um mecanismo predominantemente misto, ou seja, equilibradamente difusional e químico.
In this work, aiming at the investigation on the reduction process of manganese dioxide to manganese oxide, experiments were made using selfreducing briquettes containing manganese oxides and charcoal, at temperatures ranging from 900 to 1300oC. A general overview of the manganese is presented, indicating its principal products such as, the farming usage of MnO and the steelmaking application of the FeMn alloys, also emphasizing the thermodynamical and kinectical aspects of their productions. It is worthwhile to emphasize that MnO is an intermediary product in the production of the FeMn alloy. Experimental details concerning materials characterization and discussion on the obtained results, are also presented. In the determination of the MnO conversion the complexometric titration with EDTA chemical procedure was applied. From these determinations a model was proposed for the calculation of the kinectic parameters. The experimental results of reduction, from Mn+4 towards Mn+2 , it was possible to identify two stages for the reactions in the temperature range from 900 to 1300 C. An onset stage was marked by high reaction rates, lasting for the first 10 minutes, achieving high MnO conversions. In the experiments carried out in the range of 1000 to 1200oC, for instance, a 0,94 conversion was attained within just 10 minutes. As for the second stage, beginning after 10 minutes, the conversion showed a decrease, suggesting that the product of the first stage, the MnO, could be suffering a transformation, generating an other substance - probably Mn3C. Being this a new process, out of the scope of this work, its elucidation is left here as a suggestion for later works. Wrapping up the kinetic model, a time frontier between the two processes, around 10 minutes, was considered . Below this limit, i.e., in the temperatures - 1000, 1100, 1150 and 1200oC -, the process exhibited an apparent activation energy of 11.50 kJ x mol -1 and a pre-exponential frequency factor of 57 µHz, inferring a diffusion control. As for times beyond 10 minutes, in experiments at 900, 1000, 1100, 1150, 1200 e 1300°C, though the nature of a new compound was not probed - possibly a manganese carbide - it was possible to measure a new apparent activation energy, 46.10 kJ x mol -1 , with a pre- exponential frequency factor of 48 Hz, values coherent with a mixed control, i.e., between the diffusional and the chemical mechanisms.
Réjasse, Florian. "Etude de la réactivité des dioxydes métalliques du groupe IVb en présence de carbone par une approche (micro)-structurale : Application à la modélisation des diagrammes de phases ternaires Me-C-O (où Me = Ti, Zr, Hf)." Thesis, Limoges, 2015. http://www.theses.fr/2015LIMO0099/document.
Full textDuring this work, the reactivity of group IVb dioxides (TiO2, ZrO2, HfO2) in contact with turbostractic carbon has been investigated in order to understand the reactional mechanisms of the carbothermal reduction. This way of synthesis has also allowed us to obtain oxycarbides phases in powder form to study the different stability domains of solids solutions with respect to the temperature of heat treatment. The addition of oxygen within the crystalline structure modifies the sintering behaviour of these materials and also their macroscopic properties. Consequently, the determination of solid solution boundaries requires an accurate methodology. A broad panoply of characterization techniques are coupled (Elemental analysis, XRD, Quantification of phases, TEM) to determine the compositions of oxycarbide phases. In order to complete this study, the reactivity of titanium carbide monoliths in contact with titanium dioxide has been studied during heat treatments of annealing under pressure in confined atmosphere. The identification of phases in equilibrium constitutes diagrammatic data which are necessary for the preliminary attempts of thermodynamic modeling of ternary phases diagrams Me-C-O (where Me = Ti, Zr, Hf) using the semi-empirical CALPHAD method
Hu, Xianfeng. "Studies on Carbothermic Reduction of Chromite in the Presence of FeOx." Doctoral thesis, Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-60100.
Full textBorchardt, Lars, Claudia Hoffmann, Martin Oschatz, Lars Mammitzsch, Uwe Petasch, Mathias Herrmann, and Stefan Kaskel. "Preparation and application of cellular and nanoporous carbides." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138910.
Full textDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich
Yoon, Su-Jong. "Synthesis and characterization of ceramics in the Ti-B-N-C system." Thesis, Brunel University, 1994. http://bura.brunel.ac.uk/handle/2438/5352.
Full textKahramansoy, Eylem. "Production Of Hexagonal Boron Nitride By Carbothermic Reduction Of Colemanite-boric Oxide Mixtures." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12613595/index.pdf.
Full textRegion in Turkey was investigated by subjecting pellets prepared from B2O3, activated carbon and colemanite mixtures to nitrogen gas at 1500°
C. Similar to CaCO3 addition, colemanite addition to the B2O3-C mixtures resulted in higher amounts of h-BN in the final products. As a result of the experiments conducted with colemanite and CaCO3 additions providing the same quantity of CaO to the initial mixtures, similar amounts of hexagonal BN in the reaction products were observed. As a result of the experiments conducted with different compositions of colemanite- B2O3- C mixtures, 5 wt % colemanite addition was determined to be the optimum composition giving the highest amount of hexagonal BN in the reaction products. Increasing duration of the experiments increased the amount and particle size of h-BN formed in the products. Optimum amount of colemanite addition resulted in higher amounts and coarser particles of h-BN in the products than the optimum amounts of CaCO3 addition.
Agarwal, Ashish 1975. "Mechanism of silicon transfer in tuyere injected reactors by carbothermic reduction of silica." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/39631.
Full textVita.
Includes bibliographical references (leaf 63).
The melting zone in a cupola has temperatures greater than 1773 K and a reducing atmosphere. This condition is suitable for the carbothermic reduction of silica. The key to the applicability of carbothermic reduction of silica for Ferro-alloy production is rapid in-situ production of SiC and its subsequent dissolution in the hot metal. The main objective of this investigation was to study the kinetics of the carbothermic reduction process and determine the optimum parameters for rapid and complete in-situ conversion of silica to SiC. At temperatures above 1773 K the key reactions in the carbothermic reduction process are (1) SiO2(s) + CO(g) = SiO(g) + C0 2(g), (2) SiO(g) + 2C(s) = SiC(s) + CO(g), (3) C(s) + C0 2(g) = 2CO(g). To meet the objective of this study, conditions must be such that the surface reactions occurring at the carbon and silica surfaces are rate limiting and the entire silica is converted to SiC. Pellet composition and structure in terms of carbon to silica ratio, their particle sizes and compaction pressure that ensure surface reaction is rate controlling, were determined. The gassolid reaction kinetics was mathematically modeled in terms of the process parameters. It was observed that the reaction kinetics improved by reducing both carbon and silica particle sizes. However, below a certain critical particle size there was no significant improvement in the reaction kinetics. For complete conversion of SiO2 to SiC, excess carbon and critical porosity are necessary to ensure that the entire SiO(g) generated by reaction (1) is consumed via reaction (2) within the pellet.
by Ashish Agarwal.
S.M.
Borchardt, Lars, Claudia Hoffmann, Martin Oschatz, Lars Mammitzsch, Uwe Petasch, Mathias Herrmann, and Stefan Kaskel. "Preparation and application of cellular and nanoporous carbides." Royal Society of Chemistry, 2012. https://tud.qucosa.de/id/qucosa%3A27792.
Full textDieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
Chin, Earle J. "Carbothermic reduction of pyrochlore and niobium pentoxide in a transferred arc plasma : a thesis." Thesis, McGill University, 1989. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=75989.
Full textThe carbothermic reduction of pyrochlore and niobium pentoxide were studied in the temperature range 1530-2440 and 1625-2855 K, respectively. The rate was independent of particle size but was influenced by the separation between the oxide and carbon particles. The rate was lower than the model predictions above a certain conversion, the level of which increased with temperature and carbon concentration.
The carbothermic reduction of pyrochlore and niobium pentoxide with iron addition were studied in the temperature range 1430-2125 and 1575-2440 K, respectively. The rates were independent of particle size but was enhanced by the presence of iron. Deviation from the model was observed to be less at high conversion levels.
Preliminary investigation of the conversion rate for the carbothermic reduction of a pyrochlore and ferric oxide mixture was done to simulate the type of reactants that would be used in a commercial process. The rate was improved by the addition of iron oxide.
Frank, Robert A. (Robert Antony). "Physical chemistry of the carbothermic reduction of alumina in the presence of a metallic solvent." Thesis, Massachusetts Institute of Technology, 1989. http://hdl.handle.net/1721.1/14216.
Full textVita.
Includes bibliographical references (leaves 354-372).
by Robert A. Frank.
Sc.D.
Harrison, Robert. "Processing and characterisation of ZrCxNy ceramics as a function of stoichiometry via carbothermic reduction-nitridation." Thesis, Imperial College London, 2015. http://hdl.handle.net/10044/1/24810.
Full textJunior, Ivan Parreiras de Carvalho. "Estudo da utilização de energia de microondas na redução de minério de ferro por carbono na forma de pelotas auto-redutoras." Universidade de São Paulo, 2001. http://www.teses.usp.br/teses/disponiveis/3/3133/tde-18122001-143418/.
Full textThe carbothermic reduction of iron ores is the most important reaction in ironmaking, and has been performed mainly in the Blast Furnace. In the last years, several new processes have been proposed as alternatives, and many types of reactors have been tested. The most promising processes are those in which a mixture of iron ore and carbonaceous material is heated at high temperatures, promoting the reaction with formation of metallic iron. It became clear that one of the main obstacles to a fast reaction is heat transfer from the surroundings to the core of the mixture. On the other hand, several studies have shown that microwave heating is very effective in some industrial processes, like drying and sintering of ceramics. In the microwave heating, the material is heated from the inside, thus avoiding the constraints of heat transfer from the surroundings to the inner part of the material. In this work, microwave heating has been applied to the carbothermic reduction of hematite. The obtained results have show that it is possible to heat iron-carbon mixture above the reduction temperature, and the reaction rates have been compared to those obtained employing conventional heating with the same mixtures .
CASTRO, ANGELA R. M. de. "Estudo e otimizacao do processo de obtencao de carbeto de boro por reducao carbotermca." reponame:Repositório Institucional do IPEN, 1989. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10216.
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Dissertacao (Mestrado)
IPEN/D
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Castro, Edmilson Renato de. "Contribuição ao desenvolvimento da redução carbotérmica de óxidos metálicos empregando energia de microondas." Universidade de São Paulo, 2009. http://www.teses.usp.br/teses/disponiveis/3/3133/tde-18112009-083224/.
Full textThis work presents of a device for microwave enhanced carbothermic reductions which permits the full control of microwave power irradiated, the measurement of effectively applied microwave power to the charge in process thus performing a high confidence determination of rate of reaction and energy balance. In particular, the simultaneous records of its temperature and mass loss, and good reproducibility of operation parameters, are obtainable. This prototype works with a 2.45 GHz microwave generator with variable power up to 3000 W. Samples are processes under argon gas atmosphere. Operational tests for Carajás iron ore reduction with petroleum coke were performed using spherical pellets with weight of 3,5 g and diameter of 15 mm. Kinetic curves of iron ore reduction and effective consumption of microwave power curves were determined. These results made possible to perform an analysis of actual energy consumption for enhanced microwave iron ore carbothermic reduction.
Mourão, Marcelo Breda. "Análise do processo de redução de minério de ferro por carbono na forma de pelotas auto-redutoras." Universidade de São Paulo, 1988. http://www.teses.usp.br/teses/disponiveis/3/3133/tde-25072017-152106/.
Full textThe factors that affect the rate of reaction between iron oxides and carbon were analysed by means of literature review and experimental investigation. The iron ore and the carbon were agglomerated in the form of self-reducing pellets. The investigated variables were: temperature, type and amount of redactor, presence of additives, gas composition and flow in the reactor vessel, and pellet\'s size. The experimental technique employed was thermogravimetric analysis, complemented by gas analysis and X-ray diffraction. It was shown that the rate control may change in the course of the reaction, and it depends on a number of interrelated varibles. The slowest reaction of the chemical step is the carbon gaseification by CO2. Heat transfer and gaseous diffusion through pellets pores play an important role in the rate; the factors that favours the heat transfer influence are: temperature increase, reducto\'s reactivity increase, the use of catalyst, pellet\'s size decrease, start up the reaction; reduction under CO/CO2 atmosphere near wustite-iron equilibrium. When the reaction is performed under inert gas atmosphere, gaseous diffusion through pellet\'s pores can dilute the CO/CO2 atmosphere prevailing in the pallet\'s core. Under these conditions, this effect is more pronounced for lower temperature, lower carbon reactivity, smaller pellets and at the end of the reaction. It was also found that variables related to pellet composition as well as process temperature greatly affect the pellet\'s dimensional behavior. In fact, pellets containing basic guangue (e.g.wood charcoal and/or basic additives) show catastrophic swelling; in contrast, pellets containing acid gangue (e.g. coke or coal) have good dimensional stability. Iron whiskers were observed with scanning electron microscope on pellets that swell catastrophically. The influence of reductor\'s volatile matter upon kinetics and dimensional behavior of pellets was also analysed as well as the catalysis of the reaction by the iron formed in the course of the reduction.
ROCHA, JOSE C. da. "Estudo da influencia das caracteristicas do po de nitreto de silicio sobre a sinterabilidade e propriedades mecanicas do sinterizado." reponame:Repositório Institucional do IPEN, 1995. http://repositorio.ipen.br:8080/xmlui/handle/123456789/10439.
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Tese (Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
Zambrano, Adolfo Pillihuaman. "Estudo da redução de pelotas auto-redutoras de cromita." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/3/3133/tde-04092006-165035/.
Full textThe reduction behaviors, at high temperature, of the self-reducing pellets of chromites for production of high carbon ferro-chromium are studied in this work. The influences of the temperature, of the excess of reductant and the small addition of the Fe-Si were analyzed. The materials used (chromites, petroleum coke, Portland cement, hydrated lime and silica) were characterized chemically and by size distribution. The composite pellets (self-reducing) were produced aiming a quaternary basicity of 0.91. The reductant was calculated considering a stoichiometry of reduction and dissolution of 4wt%C in the final metallic phase. The reduction experiments were made in a special system, in argon atmosphere, heated by induction and at temperatures of 1773, 1823 and 1873K. The dried pellets were placed into a pre-heated graphite crucible and left there along up to no gas evolution was observed. The results of the reacted fraction with time were plotted and the obtained product (metallic and slag phases) after experiments were analyzed by optical and by electron micrograph. The chemical estimations were made by micro-analysis (EDS) The effect of increasing the temperature of reduction was sensitive, such that, the reduction rate increased 4 to 6 times with increase of temperature from 1773 to 1873. The small additions, up to 2% of Fe-Si, for substituting the equivalent fixed carbon of the petroleum coke showed to improve substantially the reduction rate, almost doubling it in comparison with pellets without any addition. The use of excess of 26%, over the stoichiometry, of the petroleum coke decreased around 50% of the chromium content in the slag, with relation to pellet without excess. The chromium recovery yield reached 98%. This result coupled with very high reduction rate of self-reducing pellets show the potential for self-reducing processes for ferro-chromium production.
Castro, Edmilson Renato de. "Contribuição ao estudo da redução carbotérmica de minério de ferro empregando energia de micro-ondas." Universidade de São Paulo, 2016. http://www.teses.usp.br/teses/disponiveis/3/3133/tde-18012017-145505/.
Full textThis work deals with two different types of microwave cavities to be used in carbothermic reduction that were designed and built in order to select a better furnace conformation. Parallepipedic and hexagonal shapes were used for this purpose. Both of them share some common characteristics: full control of the power supplied to the furnace, and measurement of the effective microwave power applied to the load under reduction process. These characteristics help to achieve energy balance and reaction rate with high confidence levels. Simultaneous measurements of mass and temperature versus time are also easily done and helps reproduction of each test condition. The parallelepiped and hexagonal ovens are excited by 2.45 GHz microwave generators with adjustable power up to 6 kW. Argon gas atmosphere was used when processing the samples. Operational tests of the carbothermic reduction of iron ore from Carajás were done by the use of self-reducing pellets of Chipanga coal. Temperature and other data collected during the processes allowed calculation of their kinetic curves and energy consumption. The efficiency of each kind of furnace was obtained from statistical analysis of the data using reaction rate as well as the microwave energy consumption. Finally, going further from the hexagonal shape, a cylindrical furnace was built in order to verify the behavior of the pellets/cavity groups in heavier conditions with applied power up to 15 kW.
Nogueira, Alberto Eloy Anduze. "Estudo da redução carbotérmica de minérios de ferro na forma de pelotas ou misturas autorredutoras em forno rotativo." Universidade de São Paulo, 2010. http://www.teses.usp.br/teses/disponiveis/3/3133/tde-06122010-135201/.
Full textThe purpose of this work is to study the carbothermal reduction of hematite ore as self-reducing mixtures or pellets in an experimental rotary kiln. Two different temperatures were employed, 1673 and 1773 K (1400-1500 ° C) in an experimental rotary kiln heated by resistors, with a fixed rotation of 5 rpm and under an argon flow of 1Nl/min. Several experiments were performed by changing variables such as temperature, composition and quantity of slag, type of carbonaceous material, and type of conformation. The residence time inside the furnace and its interrelation with the slope of the kiln containing self-reducing pellets or mixtures was studied. It was measured the compressive strength of pellets of different compositions. It has been analyzed the fractional reduction achieved in the experiments with the help of an indirect method proposed in this work, reaching fractional reduction above 98%. Special attention was given to some cases, the first one with a self-reducing mixture of 81% low grade ore, 19% petroleum coke, ARI +10%, processed to 1773 K (1500 ° C) with 33% final slag, which despite the large amount of slag reached a fractional reduction of 98.7%, and the second for a self-reducing mixture of 43.5% low-grade ore, 56.5% of sawdust processed to 1773 K (1500 ° C) which reached a fractional reduction of 99.2%, proving, with reasonable exceptions, the feasibility of reducing directly with sawdust. Based on experimental observations, process models of both the reduction-melting of self-reducing mixtures and pellets in the rotary kiln were proposed. The composition of slag and composition of the metallic phase obtained were analyzed. To compare the degree of coalescence between the samples, particle size analysis of each one was performed, comparing the percentages by weight of iron-carbon nuggets with a diameter greater than 7.93 mm. Regarding the method of disintegration of the product, due to the lack of technical standards for specific self-reducing processes, the drum method (ASTM E279-95) was adapted and validated by manual grinding. It was studied the effect of the following parameters: processing temperature, slag liquidus temperature, the amount of high liquidus temperature slag, amount of volatile matter of the reducing agent, the amount of reducing agent, and the absence of conformation. These experiments have shown that the higher the processing temperature, the greater the degree of coalescence, and also that as long as the slag does not melt, the coalescence process is impaired. As the amount of slag with high liquidus temperature increases, the degree of coalescence decreases. Increasing the amount of carbonaceous material above to that necessary to reduction and carburization undermines the process of formation of iron-carbon nuggets. When comparing the degree of coalescence obtained between the self-reducing mixtures and pellets, it has been shown that the performance of self-reducing mixtures is superior. To clarify the effect of the slag liquidus temperature in the carburization and coarsening process, experiments were conducted to study how the liquidus temperature of the slag and the absence of FeO affected the coarsening. By studying the transport of carbon in slags with and without the presence of a reducible oxide, it has been shown that the transport of iron oxide in the slag without agitation is a diffusive phenomenon.
Chen, Jia-hong, and 陳嘉鴻. "Carbothermal reduction sintering of silicon carbide." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/89974486629123552901.
Full text國立聯合大學
材料科學工程學系碩士班
96
The objective of this study is to investigate the structure and electrical resistivity of SiC ceramics that added different amount of boron carbides, sintered at air and CO/CO2 in 1350 ~ 1400℃. This research shows that optimal mixed ratio of partical size of 1 ~ 10 μm and 40 ~ 60 μm by slip-casting in plaster of Paris and comparison of properties of bulk density, microstructure and electrical resistivity of sintered body was produced by adding amount of 0%、1%、2%、5% of boron carbide and sintering at various temperature in difference atmospheres. According to experiment result, we obtained the optimal condition without plasticizer that particle size of 1 ~ 10μm, 40 ~ 60μm and water of mixed ratio 3:3:4. We obtained the result that the highest density of sintered SiC by adding 1% boron carbide using Archimedes’ principle. Comparison of the result that the bulk density of sintering in air higher than sintering at CO/CO2 atmosphere due to formation of silica by SiC of oxidation infiltrated between particles. According the analysis result by XRD, generation of β-SiC by sintering at CO/CO2 atmosphere leads to electrical resistivity of sintering body decrease. In addition, we obtained that relative content of β–SiC significantly increased with higher reaction temperature by analysis of XRD and NMR.
LEE, JYH-JEN, and 李志仁. "Kinetics of Carbothermal Reduction of Zinc Ferrite." Thesis, 2000. http://ndltd.ncl.edu.tw/handle/41745166098073330366.
Full text國立臺灣科技大學
化學工程系
88
Kinetics of carbothermal reduction of zinc ferrite was studied in this study. A box furnace was used to synthesize zinc ferrite. X-ray diffractometer, wetting-chemical analysis method, surface area meter and scanning electron microscope were employed to monitor the changes of composition and physical properties during reaction. On the other hand, thermogravimetic analyzer was used to study the effects of processing parameters on the conversion rate of zinc ferrite. It was found that zinc ferrite of 96.84% pure could be synthesized under following conditions : molar ratio of ZnO/Fe2O3 of 1 ; air flown over sample through suction of hood ; temperature of 1,123 K and time of 18,000 s. Zinc ferrite was found to decompose to ZnO and Fe2O3 initially. ZnO was then rapidly reduced to zinc vapor and carbon monoxide which were escaped from solid sample. Fe2O3 was also reduced FeO. However, the rate was slower. It was transformed to Fe through FeO. Pore surface area of solid sample increased with reaction time while pore volume and pore diameter were increased and then decreased with time. They are due to the escaping of zinc vapor and the expansion of FeO. A model was proposed to explain the reaction. As to the effects of processing parameters on the rate of carbothermal reduction of zinc ferrite, following results were found : conversion rate of zinc ferrite could be increased by increasing the flow rate of agron stream or reaction temperature. The rate was also found to be increased by decreasing the height of solid sample, molar ratio of ZnFe2O4/C, the grain size of carbon agglomerate or the initial bulk density of solid sample.
Yang, Yi-lin, and 楊憶琳. "Preparation of Bio-Carbide by Carbothermal Reduction." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/10511679917928245206.
Full text國立聯合大學
化學工程學系碩士班
94
The research of the ceramic material mineralized from the biomaterial has become a popular trend and has been widely used in many applications. This work intends to combine bionics and materials science by carbothermal reduction to prepare bio-carbides. The discarded timber was selected as the raw material due to the rise in environmental consciousness and the consideration of the cost of R&D. The timber was carbonized at high temperature for 2 hours in the inert gas. The carbonized wood was then selected as the porous template. Porous bio-carbides with woodlike microstructures were prepared by carbothermal reduction reaction at high temperature. This kind of woodlike microstructures was fabricated either by infiltrating one of the following species, TEOS/TTIP/Si/Ti, into woodceramics under vacuum condition or in the inert gas. This research focuses on the preparations of porous bio-template, bio-SiC, bio-TiC, and porous bio-Ti3SiC2. The results provide some useful guidelines in biomimetic processes.
Lin, Thung-Hsien, and 林宗憲. "Synthesis of Electronic Grade Silicon Carbide Powders by Carbothermal Reduction." Thesis, 2015. http://ndltd.ncl.edu.tw/cgi-bin/gs32/gsweb.cgi/login?o=dnclcdr&s=id=%22103TIT05397033%22.&searchmode=basic.
Full text國立臺北科技大學
資源工程研究所
103
Recently, SiC has been widely used in many fields owing to its high hardness, heat resistance, corrosion resistance, oxidation resistance and high thermal conductivity. In this study, high purity SiO2 powders (> 99.99%) were used as the source of silicon and the graphite powders were employed as the reducing agent. The objective of this study is to synthesize high purity SiC powders (> 99.99%) by carbonthermal reduction under argon atmosphere. Due to the high crystallinity of graphite, the chemical bond can&;#39;t be broken easily without adding catalyst, optimizing reaction temperature and time have been conducted. All experiments were operated at 1400 ~ 1600℃ for certain hours. The purified products were characterized by XRD and SEM. The purity of SiC was acquired through ICP-AES. The results indicated that β-SiC with the purity of 99.99895% was synthesized. A series of experimients with parameters including various molar ratio of graphite to silica, reaction temperature, reaction time and after-treatment were carried out to investigate the optimal condition for the synthesis of SiC.
Meng-PangChang and 張孟邦. "Growth of ZnGa2O4 nanowires on a ZnO film by carbothermal reduction." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/85253309652029437334.
Full text國立成功大學
材料科學及工程學系碩博士班
98
The growth of ZnGa2O4 nanowires (NWs) on ZnO-coated Si substrates by carbothermal reduction of Ga2O3 powder as a function of the thickness of ZnO film and the weight of Ga2O3 powder was studied. With the weight of Ga2O3 powder held at 0.3-0.4 g, abundant and pure ZnGa2O4 NWs could grow at 550-650℃ on the 0.9 μm-thick ZnO film. Thinner ZnO film, more Ga2O3 powder, and higher substrate temperature favored the growth of Ga2O3 nanobelts. The growth of ZnGa2O4 NWs followed the vapor-solid process. The photolumescence spectra of ZnGa2O4 NWs showed the emission peaks around 460-480 nm.
Zeng, Wen Hong, and 曾文宏. "Synthesize aluminium nitride from carbothermal reduction & nitridation of aluminium hydroxide." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/47783247357525260525.
Full textChuang, Chih-Ming, and 莊誌銘. "The effects of transition metals on carbothermal reduction synthesis ofβ-SiC." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/59958600947990128356.
Full text大同大學
材料工程學系(所)
92
This research is divided into two parts. In the first part, I will use phenolic-resin and Ludox were as the starting materials and add transition metals and use carbothermal reduction to synthsize β-SiC powder. I will discuss the effect of the kinds and the amount of additive on reaction temperature of β-SiC and powder properties. The other part of this research is that I will use activated carbon fabric and TEOS to prepare SiC fabric by shape memory synthesis. I hope that the morphology of SiC preserved the morphology of carbon. Adding Fe, Co, Ni, Cu enhance β-SiC formation at lower temperature. Adding Fe and Cu caused product to sinter. The product remained as powder when reactants contained Co and Ni. Although reactant with Cu can form β-SiC at 1300℃, the melting point of Cu is lower than reaction temperature, which leads reactants stick together as a cake the reaction surface decreases. Consequently, the reactant can not effectively convert into β-SiC. Adding Mn into reactants can not produce β-SiC at lower temperature. The reason is similar to that of adding Cu. The existence of Mn promoted SiO(g) formation but can not enhance reactants to convert to β-SiC. The yields of adding 1wt% Fe, Co, Ni after reaction at 1400℃ are higher than that of reactants without additives after reaction at 1400℃. The yields of adding 1wt% Fe, Co are even higher than reactants without additives after reaction at 1500℃. It can be seen that adding 1wt% Fe, Co, Ni can promote β-SiC formation at low temperature. The highest yield is by adding 1wt% Fe which is 76.87%. Adding Co has the second highest yield (73.14%) and adding Ni has 30.40% of yield, but it near to reactants without additives after reaction at 1500℃ (32.07%). The product of adding 1wt% Fe was sintered so that it needed to crush and mill. The yield of samples adding 1wt% Co was near to that of sample adding 1wt% Fe. The powder contained few whisker. Its particle size is about 100~200nm. The product of samples adding 1wt% Ni contains a lot of whisker. After reaction at 1500℃ for 8hr, activated carbon fabric can convert to β-SiC fabric. The product remains the shape of carbon and is flexible. Activated carbon fabric has many micro-pore on surface after activated process. The micro-pore provides many reaction area and promote reaction.
Chen, Chih-yung, and 陳智勇. "Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide." Thesis, 1997. http://ndltd.ncl.edu.tw/handle/94220456840643778964.
Full text國立台灣工業技術學院
化學工程技術研究所
85
The kinetics of synthesis of silicon carbide through carbothermal reduction of silicon dioxide has been studied in our experiment. X-ray diffraction analysis were employed to determine the content of products. The effects of several parameters on the reaction rate were obtained. Experimental results indicated that the reaction rate could be increased by decreasing the flow rate of He, the SiO2/C ratio, the grain size of silicon oxide or carbon and the initial density of solid sample. The rate could also be increased by increasing the height of solid sample and the reaction temperature. It was also found implicitly that SiO was an intermediate product. The activation energy of the production of β-SiC was found to be 436kJ/mole. Following are the empirical rate expressions of conversions of carbon, silicon oxide and production of silicon carbide obtained by regression of the experimental data: dCc-rc = - -------- = 7.6E4 *exp(-412,132/RT) *dsio2^(-0.742)* dc^(-0.549) dt *Csio2^(0.308)* Cc^(0.316)*Csic^(-0.046)*D^(-0.218) *f^(-0.311)*h^(0.460) dCc-rsio2 = - ------ = 1.2E4 *exp(-401,513/RT) *dsio2^(-0.801)*dc^(-0.392) dt *Csio2^(0.476)*Cc^(0.283)*Csic^(-0.077)*D^(-0.241) *f^(-0.304)*h^(0.412) dCsicrsic = -------- = 2.5E4 *exp(-436,012/RT) *dsio2^(-0.474)*dc^(-0.315) dt *Csio2^(0.407)*Cc^(0.328)*Csic^(0.013)*D^(-0.234) *f^(-0.352)*h^(0.414) The applicable range of the empirical rate expressions are flow rate of He 1x10-5 - 5x10-5 m3/s, sample height 0.007 - 0.020m, reaction temperature 1,573 - 1,773K, SiO2/C molar ratio 1/5 - 1/1, grain size of silicon oxide 0.000042 - 0.000113m, grain size of carbon 0.000051 - 0.000134m and initial bulk density 339.5 - 577.2kg/m3.
Liao, Kuo-Hong, and 廖國宏. "The Influence of silicon on the Carbothermal Reduction and Nitriding of Silica." Thesis, 2000. http://ndltd.ncl.edu.tw/handle/03150444976075271505.
Full text國立中央大學
化學工程研究所
88
The carbothermal reduction and nitridation of silicon dioxide with silicon powder addition was investigated by weight gain measurement. The reaction were carried out in a vertical reaction tube heated by a tubular furnace. In this study, the operating variables have been discussed included: nitrogen flow rate, amount of silicon powder added in the reactant, silicon dioxide/carbon molar ratio, sample weight, and reaction temperature. The analysis of this experiment is conducted by X-ray diffraction (XRD), scanning electron microscope (SEM), BET surface area, and inductively coupled plasma-mass spectrometer (ICP-MS). The experimental results indicated that the conversion of silicon dioxide is increased with an increasing nitrogen flow rate and the effect is not appreciable when the flow rate exceeds 500ml/min. The conversion of silicon dioxide is increased with an increasing amount of silicon powder added in the reactant. An excess of carbon powder and decrease of the sample weight are required to promote the conversion, however, the effect is not appreciable when the molar ratio is above 5 and sample weight is below 0.3g. Moreover, the reaction rate and the conversion of silicon dioxide is significantly increased with higher reaction temperature. The reaction product is fibrous shape β-SiC with silicon powder addition. We conjectured that the large formation of gaseous SiO is an important way for β-SiC growth.
Hsu, Pei-Ju, and 徐沛儒. "The carbothermal reduction and nitridation of rice husk ash with iron powder addition." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/35154394454770268886.
Full text國立中央大學
化學工程與材料工程研究所
90
The carbothermal reduction and nitridation of rice husk ash with iron powder addition was investigated by weight change measurement. In this study, the operating variables have been discussed include: nitrogen flow rate, amount of iron powder addition in the reactant, pellet-forming pressure, sample weight, and reaction temperature. The analysis of this experiment is conducted by inductively coupled plasma-mass spectrometer (ICP-MS), element analysis (EA), BET surface area, X-ray diffraction (XRD) and scanning electron microscope (SEM). The experimental results indicated that the conversion of rice husk ash is increased with an increasing nitrogen flow rate and the effect is not appreciable when the flow rate exceeds 500ml/min. The conversion of rice husk ash is increased with an increasing amount of iron powder addition in the reactant. Increasing the pellet-forming pressure could increase the conversion, the effect is not appreciable when the pellet-forming pressure is above 9.65x105 kPa. Moreover, the reaction rate and the conversion of the rice husk ash are significantly increased with higher reaction temperature. The reaction product is fibrous shape β- SiC with iron addition. We conjectured that the formation of liquid Fe-Si alloy is an important way for β- SiC growth. In the chemical reaction controlled region, the activation energy of the reaction is 566.69 kJ /mol when iron powder addition is 1wt% .