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1

Kluczewski, S. M., K. A. Brown, and J. N. B. Bel. "Deposition of carbonyl sulphide to soils." Atmospheric Environment (1967) 19, no. 8 (January 1985): 1295–99. http://dx.doi.org/10.1016/0004-6981(85)90260-4.

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2

Palumbo, M. E., A. G. G. M. Tielens, and A. T. Tokunaga. "Solid Carbonyl Sulphide (OCS) in W33A." Astrophysical Journal 449 (August 1995): 674. http://dx.doi.org/10.1086/176088.

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3

Peter Williams, B., Nicola C. Young, John West, Colin Rhodes, and Graham J. Hutchings. "Carbonyl sulphide hydrolysis using alumina catalysts." Catalysis Today 49, no. 1-3 (February 1999): 99–104. http://dx.doi.org/10.1016/s0920-5861(98)00413-1.

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4

JACKSON, S. "Carbonyl sulphide adsorption on supported rhodium." Journal of Catalysis 121, no. 2 (February 1990): 312–17. http://dx.doi.org/10.1016/0021-9517(90)90239-g.

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5

Heesink, A. B. M., and W. P. M. Van Swaaij. "The sulphidation of calcined limestone with hydrogen sulphide and carbonyl sulphide." Chemical Engineering Science 50, no. 18 (September 1995): 2983–96. http://dx.doi.org/10.1016/0009-2509(95)91133-j.

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6

Barnes, I., K. H. Becker, and I. Patroescu. "FTIR product study of the OH initiated oxidation of dimethyl sulphide: Observation of carbonyl sulphide and dimethyl sulphoxide." Atmospheric Environment 30, no. 10-11 (May 1996): 1805–14. http://dx.doi.org/10.1016/1352-2310(95)00389-4.

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7

Deakin, A. A., and S. H. Walmsley. "Potential energy functions and the carbonyl sulphide dimer." Journal of Molecular Structure 247 (July 1991): 89–92. http://dx.doi.org/10.1016/0022-2860(91)87065-p.

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8

Morgan, Ross A., Andrew J. Orr‐Ewing, Daniela Ascenzi, Michael N. R. Ashfold, Wybren Jan Buma, Connie R. Scheper, and Cornelis A. de Lange. "Resonance enhanced multiphoton ionization spectroscopy of carbonyl sulphide." Journal of Chemical Physics 105, no. 6 (August 8, 1996): 2141–52. http://dx.doi.org/10.1063/1.472088.

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9

Kluczewski, S. M., K. A. Brown, and J. N. B. Bell. "Deposition of [35S]-Carbonyl Sulphide to Vegetable Crops." Radiation Protection Dosimetry 11, no. 3 (May 1, 1985): 173–77. http://dx.doi.org/10.1093/oxfordjournals.rpd.a079463.

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10

Oakes, B. W., and M. Hale. "Dispersion patterns of carbonyl sulphide above mineral deposits." Journal of Geochemical Exploration 28, no. 1-3 (June 1987): 235–49. http://dx.doi.org/10.1016/0375-6742(87)90050-1.

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11

Liss, Peter S., Angela D. Hatton, Gill Malin, Philip D. Nightingale, and Suzanne M. Turner. "Marine sulphur emissions." Philosophical Transactions of the Royal Society of London. Series B: Biological Sciences 352, no. 1350 (February 28, 1997): 159–69. http://dx.doi.org/10.1098/rstb.1997.0011.

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The principal volatile sulphur species found in seawater are dimethyl sulphide (DMS), carbonyl sulphide (COS) and carbon disulphide (CS 2 . Of these, DMS is the most abundant and widespread in its distribution. The predominant oceanic source of DMS is dimethylsulphonioproprionate (DMSP), a compatible solute synthesized by phytoplankton for osmoregulation and/or cryoprotection. Not all species have the same ability to form DMSP; for example, diatoms generally produce little, whereas prymnesiophytes and some dinoflagellates make significantly larger amounts. Much of the release of DMSP and DMS to the water occurs on death or through predation of the plankton. Our recent field data strongly suggest that oxidation of DMS to dimethyl sulphoxide (DMSO) is an important process in the water column, and it is clear that considerable internal cycling in the DMSP/DMS/DMSO system occurs in the euphotic zone. A fraction of the DMS crosses the sea surface and enters the atmosphere where it is oxidized by radicals such OH and NO 3 to form products such as methanesulphonate (MSA), DMSO and non-sea salt sulphate (NSSS) particles. These particles are the main source of cloud condensation nuclei (CCN) over oceanic areas remote from land.
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12

Singh, Rajendra K., Rooma Mago Mehta, and R. G. Bass. "Synthesis and characterization of extended poly(phenylquinoxalines) containing carbonyl, ether and sulphide linking groups." High Performance Polymers 7, no. 4 (August 1995): 481–92. http://dx.doi.org/10.1088/0954-0083/7/4/010.

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A series of eight novel extended poly(phenylquinoxalines) (PPQs) containing carbonyl, ether and sulphide linking groups were prepared by polycondensation of 4,4'-bis(phenylglyoxalyl-4-phenoxy-4'-benzoyl)diphenyl sulphide, I-D, and 4,4'-bis(phenyl glyoxalyl-4-phenylthio-4'-benzoyl)diphenyl sulphide, 2-D, with four aromatic bis(o-diamines) in m-cresol. The primary objective of this study was to correlate the effect of these linkages on the various properties such as solubility, thermal stability and glass transition temperature of the PPQs. Polymerization of 1-D was carried out in an oil bath maintained at 195-200C whereas polymerization of 2-D was performed at ambient temperature. The polymers prepared were soluble in m-cresol. dimethylsulphoxide, N,N-dimethylacetamide, I-methyl-2-pyrrolidinone and chlorinated hydrocarbon solvents, and formed tough transparent, yellow fingernail-creasable films from chloroform solutions. The inherent viscosities ranged between 0.44 and 0.96 dl g' '. The glass transition temperatures were nearly identical for both systems and ranged from 217-231 'C for polymers prepared from l-D and from 215-233"C for polymers prepared from 2-D. The PPQs having carbonyl and stJlphide linking groups had higher thermal stability in comparison to PPQs having carbonyl, ether and sulphide linkages. The temperature of 10% weight loss for I-D ranged from 484-496 'C in air and 485-516"C in helium whereas those for 2-D ranged from 538-579 XC in air and 522-549 in helium.
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13

Camy-Peyret, C., G. Liuzzi, G. Masiello, C. Serio, S. Venafra, and S. A. Montzka. "Assessment of IASI capability for retrieving carbonyl sulphide (OCS)." Journal of Quantitative Spectroscopy and Radiative Transfer 201 (November 2017): 197–208. http://dx.doi.org/10.1016/j.jqsrt.2017.07.006.

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14

Krysztofiak, Gisèle, Yao Veng Té, Valéry Catoire, Gwenaël Berthet, Geoffrey C. Toon, Fabrice Jégou, Pascal Jeseck, and Claude Robert. "Carbonyl Sulphide (OCS) Variability with Latitude in the Atmosphere." Atmosphere-Ocean 53, no. 1 (January 17, 2014): 89–101. http://dx.doi.org/10.1080/07055900.2013.876609.

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15

Asaf, David, Eyal Rotenberg, Fyodor Tatarinov, Uri Dicken, Stephen A. Montzka, and Dan Yakir. "Ecosystem photosynthesis inferred from measurements of carbonyl sulphide flux." Nature Geoscience 6, no. 3 (February 17, 2013): 186–90. http://dx.doi.org/10.1038/ngeo1730.

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16

Deakin, A. A., and S. H. Walmsley. "Potential functions and the lattice dynamics of carbonyl sulphide." Chemical Physics 136, no. 1 (September 1989): 105–13. http://dx.doi.org/10.1016/0301-0104(89)80132-6.

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17

Abraham Joseph, K., and M. Srinivasan. "Synthesis and characterization of polyesters containing sulphide, sulphone or carbonyl groups in their backbones." European Polymer Journal 29, no. 12 (December 1993): 1641–45. http://dx.doi.org/10.1016/0014-3057(93)90259-i.

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18

Pandey, Krishna Kumar, and Sharad Kumar Tewari. "Reactions of carbonyl sulphide and carbon disulphide with ruthenium complexes." Polyhedron 8, no. 9 (January 1989): 1149–55. http://dx.doi.org/10.1016/s0277-5387(00)81136-5.

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19

Vijayasekhar, J., M. Rao, and G. Rao. "Vibrational Spectra of Carbonyl Sulphide by U(2) Lie Algebraic Method." Journal of Advances in Mathematics and Computer Science 25, no. 3 (January 10, 2017): 1–5. http://dx.doi.org/10.9734/jamcs/2017/37595.

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20

Adriaens, D. A., T. P. M. Goumans, C. R. A. Catlow, and W. A. Brown. "Computational Study of Carbonyl Sulphide Formation on Model Interstellar Dust Grains." Journal of Physical Chemistry C 114, no. 4 (January 8, 2010): 1892–900. http://dx.doi.org/10.1021/jp9083212.

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21

Stassen, H., Th Dorfmüller, and J. Samios. "Molecular dynamics investigations of the electrostatic interactions in liquid carbonyl sulphide." Molecular Physics 77, no. 2 (October 10, 1992): 339–50. http://dx.doi.org/10.1080/00268979200102481.

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22

Bilalbegović, G. "Carbonyl sulphide under strong laser field: Time-dependent density functional theory." European Physical Journal D 49, no. 1 (July 16, 2008): 43–49. http://dx.doi.org/10.1140/epjd/e2008-00137-8.

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23

Alper, Erdogan. "Comments on kinetics of reaction of carbonyl sulphide with aqueous MDEA." Chemical Engineering Science 48, no. 6 (1993): 1179–80. http://dx.doi.org/10.1016/0009-2509(93)81047-y.

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24

Dawodu, Olukayode Fatai, and Axel Meisen. "Identification of products resulting from carbonyl sulphide-induced degradation of diethanolamine." Journal of Chromatography A 587, no. 2 (December 1991): 237–46. http://dx.doi.org/10.1016/0021-9673(91)85160-h.

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25

Protoschill-Krebs, G., C. Wilhelm, and J. Kesselmeier. "Consumption of carbonyl sulphide (COS) by higher plant carbonic anhydrase (CA)." Atmospheric Environment 30, no. 18 (September 1996): 3151–56. http://dx.doi.org/10.1016/1352-2310(96)00026-x.

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26

Brühl, C., J. Lelieveld, P. J. Crutzen, and H. Tost. "The role of carbonyl sulphide as a source of stratospheric sulphate aerosol and its impact on climate." Atmospheric Chemistry and Physics Discussions 11, no. 7 (July 22, 2011): 20823–54. http://dx.doi.org/10.5194/acpd-11-20823-2011.

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Abstract. Globally, carbonyl sulphide (COS) is the most abundant sulphur gas in the atmosphere. Our chemistry-climate model of the lower and middle atmosphere with aerosol module realistically simulates the background stratospheric sulphur cycle, as observed by satellites in volcanically quiescent periods. The model results indicate that upward transport of COS from the troposphere largely controls the sulphur budget and the aerosol loading of the background stratosphere. This differs from most previous studies which indicated that short-lived sulphur gases are also important. The model realistically simulates the modulation of the particulate and gaseous sulphur abundance in the stratosphere by the quasi-biennial oscillation (QBO). In the lowermost stratosphere organic carbon aerosol contributes significantly to extinction. Further, we compute that the radiative forcing efficiency by 1 kg of COS is 724 times that of 1 kg CO2, which translates into an overall radiative forcing by anthropogenic COS of 0.003 W m−2. The global warming potentials of COS over time horizons of 20 and 100 yr are GWP(20 yr) = 97 and GWP(100 yr) = 27, respectively (by mass). Furthermore, stratospheric aerosol particles produced by the photolysis of COS contribute to a negative radiative forcing, which amounts to −0.007 W m−2 at the top of the atmosphere for the anthropogenic fraction, more than two times the warming forcing of COS. Considering that the lifetime of COS is twice that of stratospheric aerosols the warming and cooling tendencies approximately cancel. If the forcing of the troposphere near the tropopause is considered, the cooling dominates.
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27

Brühl, C., J. Lelieveld, P. J. Crutzen, and H. Tost. "The role of carbonyl sulphide as a source of stratospheric sulphate aerosol and its impact on climate." Atmospheric Chemistry and Physics 12, no. 3 (February 1, 2012): 1239–53. http://dx.doi.org/10.5194/acp-12-1239-2012.

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Abstract. Globally, carbonyl sulphide (COS) is the most abundant sulphur gas in the atmosphere. Our chemistry-climate model (CCM) of the lower and middle atmosphere with aerosol module realistically simulates the background stratospheric sulphur cycle, as observed by satellites in volcanically quiescent periods. The model results indicate that upward transport of COS from the troposphere largely controls the sulphur budget and the aerosol loading of the background stratosphere. This differs from most previous studies which indicated that short-lived sulphur gases are also important. The model realistically simulates the modulation of the particulate and gaseous sulphur abundance in the stratosphere by the quasi-biennial oscillation (QBO). In the lowermost stratosphere organic carbon aerosol contributes significantly to extinction. Further, using a chemical radiative convective model and recent spectra, we compute that the direct radiative forcing efficiency by 1 kg of COS is 724 times that of 1 kg CO2. Considering an anthropogenic fraction of 30% (derived from ice core data), this translates into an overall direct radiative forcing by COS of 0.003 W m−2. The direct global warming potentials of COS over time horizons of 20 and 100 yr are GWP(20 yr) = 97 and GWP(100 yr) = 27, respectively (by mass). Furthermore, stratospheric aerosol particles produced by the photolysis of COS (chemical feedback) contribute to a negative direct solar radiative forcing, which in the CCM amounts to −0.007 W m−2 at the top of the atmosphere for the anthropogenic fraction, more than two times the direct warming forcing of COS. Considering that the lifetime of COS is twice that of stratospheric aerosols the warming and cooling tendencies approximately cancel.
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28

Brown, K. A., and J. N. B. Bell. "Vegetation—The missing sink in the global cycle of carbonyl sulphide (COS)." Atmospheric Environment (1967) 20, no. 3 (January 1986): 537–40. http://dx.doi.org/10.1016/0004-6981(86)90094-6.

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29

Burke, Daren J., Tomas Vondrak, and Stephen R. Meech. "Photodesorption and photochemical dynamics on roughened silver: Sulphur dioxide and carbonyl sulphide." Surface Science 585, no. 1-2 (July 2005): 123–33. http://dx.doi.org/10.1016/j.susc.2005.04.020.

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30

Protoschill-Krebs, G., and J. Kesselmeier. "Enzymatic Pathways for the Consumption of Carbonyl Sulphide (COS) by Higher Plants*." Botanica Acta 105, no. 3 (June 1992): 206–12. http://dx.doi.org/10.1111/j.1438-8677.1992.tb00288.x.

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31

Singh, Mander, and Jerry A. Bullin. "Determination of rate constants for the reaction between diglycolamine and carbonyl sulphide." Gas Separation & Purification 2, no. 3 (September 1988): 131–37. http://dx.doi.org/10.1016/0950-4214(88)80029-x.

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32

Piazzetta, P., T. Marino, and N. Russo. "The working mechanism of the β-carbonic anhydrase degrading carbonyl sulphide (COSase): a theoretical study." Physical Chemistry Chemical Physics 17, no. 22 (2015): 14843–48. http://dx.doi.org/10.1039/c4cp05975a.

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The working mechanism of the novel characterized enzyme carbonyl sulfide hydrolase (COSase), which efficiently converts COS to H2S and CO2, has been investigated at a density functional theory level.
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33

Tameesh, Adnan H. H., Ali O. Bender, and Takoohi M. Sarkissian. "Gas chromatographic study of the analysis and elution mechanism of hydrogen sulphide, carbonyl sulphide and light mercaptans in petroleum gases." Journal of Chromatography A 321 (January 1985): 59–67. http://dx.doi.org/10.1016/s0021-9673(01)90423-6.

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34

Kaisermann, Aurore, Sam Jones, Steven Wohl, Jérôme Ogée, and Lisa Wingate. "Nitrogen Fertilization Reduces the Capacity of Soils to Take up Atmospheric Carbonyl Sulphide." Soil Systems 2, no. 4 (November 15, 2018): 62. http://dx.doi.org/10.3390/soilsystems2040062.

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Soils are an important carbonyl sulphide (COS) sink. However, they can also act as sources of COS to the atmosphere. Here we demonstrate that variability in the soil COS sink and source strength is strongly linked to the available soil inorganic nitrogen (N) content across a diverse range of biomes in Europe. We revealed in controlled laboratory experiments that a one-off addition of ammonium nitrate systematically decreased the COS uptake rate whilst simultaneously increasing the COS production rate of soils from boreal and temperate sites in Europe. Furthermore, we found strong links between variations in the two gross COS fluxes, microbial biomass, and nitrate and ammonium contents, providing new insights into the mechanisms involved. Our findings provide evidence for how the soil–atmosphere exchange of COS is likely to vary spatially and temporally, a necessary step for constraining the role of soils and land use in the COS mass budget.
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35

von Hobe, M., A. J. Kettle, and M. O. Andreae. "Carbonyl sulphide in and over seawater: summer data from the northeast Atlantic Ocean." Atmospheric Environment 33, no. 21 (September 1999): 3503–14. http://dx.doi.org/10.1016/s1352-2310(98)00236-2.

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36

Goodwin, Elizabeth J., and A. C. Legon. "Rotational spectrum of a weakly bound dimer of carbonyl sulphide and hydrogen chloride." Journal of the Chemical Society, Faraday Transactions 2 81, no. 11 (1985): 1709. http://dx.doi.org/10.1039/f29858101709.

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37

Chiodini, G., R. Cioni, B. Raco, and G. Scandiffio. "Carbonyl sulphide (cos) in geothermal fluids: an example from the Larderello field (Italy)." Geothermics 20, no. 5-6 (January 1991): 319–27. http://dx.doi.org/10.1016/0375-6505(91)90023-o.

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38

Sunanda, K., B. N. Rajasekhar, P. Saraswathy, and B. N. Jagatap. "Photo-absorption studies on carbonyl sulphide in 30,000–91,000cm−1 region using synchrotron radiation." Journal of Quantitative Spectroscopy and Radiative Transfer 113, no. 1 (January 2012): 58–66. http://dx.doi.org/10.1016/j.jqsrt.2011.09.009.

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39

Bigourd, D., G. Mouret, A. Cuisset, F. Hindle, E. Fertein, and R. Bocquet. "Rotational spectroscopy and dynamics of carbonyl sulphide studied by terahertz free induction decays signals." Optics Communications 281, no. 11 (June 2008): 3111–19. http://dx.doi.org/10.1016/j.optcom.2008.01.054.

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40

Taylor, Mary, Hugh Evans, Peter Smith, Rengen Ding, Yu Lung Chiu, Subash Rai, Brian Connolly, Neal Smith, Lesley Pearson, and Clive Mowforth. "The Effect of Temperature and Carbonyl Sulphide on Carbon Deposition on 20Cr25Ni Stainless Steel." Oxidation of Metals 87, no. 5-6 (February 7, 2017): 667–78. http://dx.doi.org/10.1007/s11085-017-9723-7.

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41

Pinillos, S. Cabredo, I. Sanz Vicente, J. Galbán Bernal, and J. Sanz Asensio. "Determination of thiocyanate by carbonyl sulphide (OCS) generation and gas-phase molecular absorption spectrometry." Analytica Chimica Acta 318, no. 3 (January 1996): 377–83. http://dx.doi.org/10.1016/0003-2670(95)00463-7.

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42

McConnell, T. D. L., and S. H. Walmsley. "Potential functions and the lattice dynamics of carbonyl sulphide. II. Repulsive terms and compressibility." Chemical Physics 168, no. 2-3 (December 1992): 195–201. http://dx.doi.org/10.1016/0301-0104(92)87154-2.

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43

Lennartz, Sinikka T., Michael Gauss, Marc von Hobe, and Christa A. Marandino. "Monthly resolved modelled oceanic emissions of carbonyl sulphide and carbon disulphide for the period 2000–2019." Earth System Science Data 13, no. 5 (May 18, 2021): 2095–110. http://dx.doi.org/10.5194/essd-13-2095-2021.

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Abstract. Carbonyl sulphide (OCS) is the most abundant, long-lived sulphur gas in the atmosphere and a major supplier of sulphur to the stratospheric sulphate aerosol layer. The short-lived gas carbon disulphide (CS2) is oxidized to OCS and constitutes a major indirect source to the atmospheric OCS budget. The atmospheric budget of OCS is not well constrained due to a large missing source needed to compensate for substantial evidence that was provided for significantly higher sinks. Oceanic emissions are associated with major uncertainties. Here we provide a first, monthly resolved ocean emission inventory of both gases for the period 2000–2019 (available at https://doi.org/10.5281/zenodo.4297010) (Lennartz et al., 2020a). Emissions are calculated with a numerical box model (2.8∘×2.8∘ resolution at the Equator, T42 grid) for the oceanic surface mixed layer, driven by ERA5 data from ECMWF and chromophoric dissolved organic matter (CDOM) from Aqua MODIS. We find that interannual variability in OCS emissions is smaller than seasonal variability and is mainly driven by variations in CDOM, which influences both photochemical and light-independent production. A comparison with a global database of more than 2500 measurements reveals overall good agreement. Emissions of CS2 constitute a larger sulphur source to the atmosphere than OCS and equally show interannual variability connected to variability in CDOM. The emission estimate of CS2 is associated with higher uncertainties as process understanding of the marine cycling of CS2 is incomplete. We encourage the use of the data provided here as input for atmospheric modelling studies to further assess the atmospheric OCS budget and the role of OCS in climate.
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44

Morgan, Ross A., Michael A. Baldwin, Daniela Ascenz, Andrew J. Orr-Ewing, Michael N. R. Ashfold, Wybren Jan Buma, Jolanda B. Milan, Conny R. Scheper, and Cornelis A. de Langeb. "Resonance enhanced multiphoton ionisation (REMPI) and REMPI-photoelectron spectroscopy of carbonyl sulphide and carbon disulphide." International Journal of Mass Spectrometry and Ion Processes 159, no. 1-3 (December 1996): 1–11. http://dx.doi.org/10.1016/s0168-1176(96)04437-0.

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45

Millward, G. R., H. E. Evans, I. P. Jones, C. D. Eley, and C. W. Mowforth. "The influence of carbonyl sulphide on the inhibition of filamentary carbon deposition on stainless steel." Materials and Corrosion 54, no. 11 (November 2003): 864–69. http://dx.doi.org/10.1002/maco.200303733.

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46

Ren, Yong-Lin, Ian G. O'Brien, and James Desmarchelier. "Effect of Hydrogen Cyanide and Carbonyl Sulphide on the Germination and Plumule Vigour of Wheat." Pesticide Science 47, no. 1 (May 1996): 1–5. http://dx.doi.org/10.1002/(sici)1096-9063(199605)47:1<1::aid-ps323>3.0.co;2-l.

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47

Dellis, D., and J. Samios. "Dynamical properties of carbonyl sulphide diluted in argon at different densities. A molecular dynamics investigation." Chemical Physics 192, no. 3 (March 1995): 281–94. http://dx.doi.org/10.1016/0301-0104(94)00385-n.

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48

Nemeth, L., G. Gati, A. Gervasini, A. Auroux, G. Mink, I. S. Pap, and T. Szekely. "Kinetic study of the carbonyl sulphide synthesis from carbon dioxide and carbon disulphide on alumina catalysts." Applied Catalysis 64 (September 1990): 143–59. http://dx.doi.org/10.1016/s0166-9834(00)81558-4.

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49

Ren, YongLin, Daphne Mahon, Jan van Someren Graver, and Matthew Head. "Fumigation trial on direct application of liquid carbonyl sulphide to wheat in a 2500t concrete silo." Journal of Stored Products Research 44, no. 2 (January 2008): 115–25. http://dx.doi.org/10.1016/j.jspr.2007.08.001.

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50

Barnett, S. M., N. J. Mason, and W. R. Newell. "Dissociative excitation of metastable fragments by electron impact on carbonyl sulphide, carbon dioxide and carbon monoxide." Journal of Physics B: Atomic, Molecular and Optical Physics 25, no. 6 (March 28, 1992): 1307–20. http://dx.doi.org/10.1088/0953-4075/25/6/021.

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