Academic literature on the topic 'Carbon deposition resistance'

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Journal articles on the topic "Carbon deposition resistance"

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Shi, Yu, Shiwei Wang, Yiming Li, Fan Yang, Hongbo Yu, Yuting Chu, Tong Li, and Hongfeng Yin. "Improving Anti-Coking Properties of Ni/Al2O3 Catalysts via Synergistic Effect of Metallic Nickel and Nickel Phosphides in Dry Methane Reforming." Materials 15, no. 9 (April 22, 2022): 3044. http://dx.doi.org/10.3390/ma15093044.

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A series of NiP-x/Al2O3 catalysts containing different ratio of metallic nickel to nickel phosphides, prepared by varying Ni/P molar ratio of 4, 3, 2 through a co-impregnation method, were employed to investigate the synergistic effect of metallic nickel-nickel phosphides in dry methane reforming reaction. The Ni/Al2O3 catalyst indicates good activity along with severe carbon deposition. The presence of phosphorus increases nickel dispersion as well as the interaction between nickel and alumina support, which results in smaller nickel particles. The co-existence of metallic nickel and nickel phosphides species is confirmed at all the P contained catalysts. Due to the relative stronger CO2 dissociation ability, the NiP-x/Al2O3 catalysts indicate obvious higher resistance of carbon deposition. Furthermore, because of good balance between CH4 dissociation and CO2 dissociation, NiP-2/Al2O3 catalyst exhibits best resistance of carbon deposition, few carbon depositions were formed after 50 h of dry methane reforming.
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Qingliang, Shen, Li Hejun, Zhao Fengling, Song Qiang, and Fu Qiangang. "Electrophoretic deposition of carbon nanotubes for improved ablation resistance of carbon/carbon composites." Corrosion Science 132 (March 2018): 204–13. http://dx.doi.org/10.1016/j.corsci.2018.01.001.

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Tanaka, Kazuto, Takanobu Nishikawa, Kazuhiro Aoto, and Tsutao Katayama. "Effect of Carbon Nanotube Deposition Time to the Surface of Carbon Fibres on Flexural Strength of Resistance Welded Carbon Fibre Reinforced Thermoplastics Using Carbon Nanotube Grafted Carbon Fibre as Heating Element." Journal of Composites Science 3, no. 1 (January 12, 2019): 9. http://dx.doi.org/10.3390/jcs3010009.

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In recent years, carbon fibre reinforced thermoplastics (CFRTP) are expected to be used as lightweight structural materials for mass-produced vehicles. CFRTP with thermoplastics as matrix allows us to weld them using melting of matrix by heating. We have been developing a direct resistance heating method, which uses carbon fibres as the resistance heating element. Carbon nanotube (CNT) is expected to be used as additive to FRP and we reported that the fibre/matrix interfacial shear strength was improved by grafting CNT on the surface of carbon fibres and tensile lap-shear strength was improved by using CNT grafted carbon fibre as the heating element for welding. For the practical use of CFRTP for structural parts, flexural strength is also necessary to be evaluated. In this study, flexural test was carried out to clarify the effect of CNT deposition time to the surface of carbon fibres on flexural strength of resistance welded CFRTP using CNT grafted carbon fibre as the heating element. The highest flexural strength was obtained when CNT10, for which CNT is grafted on the carbon fibres for deposition time of 10 min, was used for the heating element of resistance welding. In the case of CNT deposition time of 60 min, the lowest flexural strength was obtained because of the poor impregnation of the resin into the carbon fibre due to the excess CNT on the carbon fibres.
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Xu, Xian Feng, Ling Sheng Zeng, Tian Ouyang, and Ling Zhi Chai. "Carbon Felt Properties of Pyrolytic Carbon Felt Direct Thermal CVD." Materials Science Forum 852 (April 2016): 1371–75. http://dx.doi.org/10.4028/www.scientific.net/msf.852.1371.

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Taking acetylene as the carbon source gas diluted with nitrogen gas in this paper, carbon felt was heated under the nitrogen atmosphere, the temperature of carbon felt increased using heat generated by itself, which so as to cleave the carbon source gas and densify carbon felt by pyrolytic carbon deposition. The electrothermal property of carbon felt at elevated temperature and pyrolytic carbon was fabricated by direct thermal chemical vapor deposition (CVD) were investigated. Deposition rate and microstructure morphology of pyrolytic carbon in the carbon felt under different processes were also researched by scanning electron microscopy (SEM). The results show that: the resistivity of carbon felt decreases with increasing temperature at 100°C~1000°C, temperature coefficient of resistance is-4.067×10-4. Deposition and Growth of Pyrolytic carbon are by small microcrystalline and layer mode, respectively, with the extension of the deposition time, tree-ring shape is formed. When other conditions are the same, the higher of gas carbon concentration, the faster of pyrolytic carbon deposition rate.
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Bannov, Alexander G., Ondřej Jašek, Jan Prášek, Jiří Buršík, and Lenka Zajíčková. "Enhanced Ammonia Adsorption on Directly Deposited Nanofibrous Carbon Films." Journal of Sensors 2018 (September 17, 2018): 1–14. http://dx.doi.org/10.1155/2018/7497619.

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The ammonia adsorption on the nanostructured carbon thin film was significantly influenced by the choice of deposition temperature and deposition time of thin film synthesis. The thin films were prepared on Si/SiO2 substrates by chemical vapour deposition in Ar/C2H2 gas mixture using iron catalytic nanoparticles. The analysis of the grown layer by the scanning and transmission electron microscopy showed the transition from long multiwalled nanotubes (MWCNTs) to bamboo-like hollow carbon nanofiber structure with the decrease of the deposition temperature from 700 to 600°C. Further, the material was analyzed by energy-dispersive X-ray spectroscopy and Raman spectroscopy confirmed the transition from graphitic sp2 structure to highly defective structure at lower deposition temperature. The resistance of the prepared layer strongly depends on deposition temperature (Td) and deposition time (td). High resistance layer, 38.6 kΩ, was formed at Td 600°C and td 10 min, while at Td 700°C and td 60 min, the resistance decreased to 860 ohms. Such behaviour is consistent with MWCNTs being responsible for the formation of the conductive network. Such system was studied using chemiresistor ammonia gas sensor configuration. The sensor resistance increased when exposed to ammonia in all the cases, but their response varied considerably. A decrease in deposition time, from 60 to 10 min, and the deposition temperature, from 700 to 600°C, led to the 10-fold increase in the sensor response. The measurements carried out at room temperature showed the higher sensor response than the measurements carried out at 200°C. This behaviour can be explained by the change in adsorption-desorption equilibrium at different temperatures. Analysis of dependence of the sensor response on the ammonia concentration proved that the underlying resistance change mechanism is chemisorption of ammonia molecules on the carbon network corresponding to the Langmuir isotherm.
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Chae, Hyang Hoon, Bo-Hye Kim, Kap Seung Yang, and Hee-Gweon Woo. "Boric Oxide Deposition on Carbon Nanofibers for Oxidation Resistance." Journal of Nanoscience and Nanotechnology 13, no. 8 (August 1, 2013): 5645–48. http://dx.doi.org/10.1166/jnn.2013.7065.

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Kalenik, Jerzy, Konrad Kielbasinski, Piotr Firek, Elżbieta Czerwosz, and Jan Szmidt. "Thermal properties of modified carbon films." Circuit World 42, no. 1 (February 1, 2016): 37–41. http://dx.doi.org/10.1108/cw-10-2015-0055.

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Purpose – The purpose of this paper is to present thermal properties of palladium-carbon films prepared by physical vapour deposition (PVD)/chemical vapour deposition (CVD) methods. Design/methodology/approach – Thin palladium-carbon films were prepared at Tele- and Radioresearch Institute. Test structures containing palladium-carbon films and titanium electrodes were made. Temperature-resistance characteristics were measured. Findings – The results show strong temperature dependence of modified carbon film resistance. The dependence is stable, and so modified carbon films can be applied for various electronic applications. Originality/value – The paper presents thermal properties of thin palladium-carbon prepared by original PVD/CVD method at Tele- and Radioresearch Institute.
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Zeng, Yan, Ayano Kimura, Peipei Zhang, Jiaming Liang, Jiaqi Fan, Liwei Xiao, Chengwei Wang, Guohui Yang, Xiaobo Peng, and Noritatsu Tsubaki. "Resistance against Carbon Deposition via Controlling Spatial Distance of Catalytic Components in Methane Dehydroaromatization." Catalysts 11, no. 2 (January 21, 2021): 148. http://dx.doi.org/10.3390/catal11020148.

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Molybdenum-zeolite catalysts always suffer from severe carbon deposition and rapid deactivation in the methane dehydroaromatization (MDA) process. Herein, we present a strategy that controls spatial distance between Mo species and HMCM-22 zeolite over Mo/HMCM-22 catalysts, to inhibit the severe carbon deposition. Our characterization analyses demonstrate that the Mo/HMCM-22 catalysts possess the same active components, but the spatial distance plays a key role in determining product selectivity in the MDA process. The MDA performance reveals that Mo/HMCM-22-MM (mechanical milling) catalyst, with a medium spatial distance between Mo species and HMCM-22 zeolite, significantly inhibits carbon deposition and produces high selectivity to benzene. This work shows that spatial distance between molybdenum and zeolite is an important property for suppressing carbon deposition and improving benzene selectivity in MDA process.
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LU, J. W., W. L. WANG, K. J. LIAO, and B. Y. WAN. "STRAIN-INDUCED RESISTANCE CHANGES OF CARBON NANOTUBE FILMS." International Journal of Modern Physics B 19, no. 01n03 (January 30, 2005): 627–29. http://dx.doi.org/10.1142/s0217979205029183.

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The strain-induced resistance changes of both SWNT and MWNT films have been studied. Carbon nanotubes in this study were synthesized by hot filament chemical vapor deposition. Experimental results showed that there is a striking piezoresistive effect in carbon nanotube films. The relative change in resistance of carbon nanotube films was increased with the increasing strain. In the same strain, the resistance changes of SWNT films exceed that of MWNT films. The origin of the resistance change in the films may be caused by strain-induced change in the bandgap and intertube contact resistance.
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Hannula, Pyry-Mikko, Minttu Junnila, Dawid Janas, Jari Aromaa, Olof Forsén, and Mari Lundström. "Carbon Nanotube Fiber Pretreatments for Electrodeposition of Copper." Advances in Materials Science and Engineering 2018 (2018): 1–8. http://dx.doi.org/10.1155/2018/3071913.

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There is increasing interest towards developing carbon nanotube-copper (CNT-Cu) composites due to potentially improved properties. Carbon nanotube macroscopic materials typically exhibit high resistivity, low electrochemical reactivity, and the presence of impurities, which impede its use as a substrate for electrochemical deposition of metals. In this research, different CNT fiber pretreatment methods, such as heat treatment, immersion in Watts bath, anodization, and exposure to boric acid (H3BO3), were investigated to improve the electrochemical response for copper deposition. It was shown that these treatments affect the surface activity of CNTs, including electrical resistivity, polarization resistance, and active surface area, which influence the electrodeposition process of copper. Properties of CNT structures and CNT-Cu composites were researched by electrochemical impedance spectroscopy (EIS), galvanostatic copper deposition, scanning electron microscope (SEM), and four-point electrical resistance measurements. Heat treatment, Watts bath, anodization, and boric acid treatments were shown to be effective for modifying the CNT surface reactivity for subsequent electrochemical deposition of copper.
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Dissertations / Theses on the topic "Carbon deposition resistance"

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Rykaczewski, Konrad. "Electron beam induced deposition (EBID) of carbon interface between carbon nanotube interconnect and metal electrode." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/31773.

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Thesis (Ph.D)--Mechanical Engineering, Georgia Institute of Technology, 2010.
Committee Chair: Dr. Andrei G. Fedorov; Committee Member: Dr. Azad Naeemi; Committee Member: Dr. Suresh Sitaraman; Committee Member: Dr. Vladimir V. Tsukruk; Committee Member: Dr. Yogendra Joshi. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Oliphant, Clive Justin. "Filament carburization during the hot-wire chemical vapour deposition of carbon nanotubes." Thesis, University of the Western Cape, 2008. http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=gen8Srv25Nme4_7060_1263948958.

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Fiedler, Holger. "Preparation and characterization of Carbon Nanotube based vertical interconnections for integrated circuits: Preparation and characterization of Carbon Nanotube based verticalinterconnections for integrated circuits." Doctoral thesis, Universitätsverlag der Technischen Universität Chemnitz, 2013. https://monarch.qucosa.de/id/qucosa%3A20091.

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(ULSI) causes an increase of the resistance of the wiring system by increased scattering of electrons at side walls and grain boundaries in the state of the art Cu technology, which increases the RC delay of the interconnect system and thus degrades the performance of the device. The outstanding properties of carbon nanotubes (CNT) such as a large mean free path, a high thermal conductance and a large resistance against electromigration make them an ideal candidate to replace Cu in future feature nodes. The present thesis contributes to the preparation and properties of CNT based vertical interconnections (vias). In addition, all processes applied during the fabrication are compatible to ULSI and an interface between CNT based vias and a Cu metallization is studied. The methodology for the evaluation of CNT based vias is improved; it is highlighted that by measuring the resistance of one multiwall CNT and taking into account the CNT density, the performance of the CNT based vias can be predicted accurately. This provides the means for a systematic evaluation of different integration procedures and materials. The lowest contact resistance is obtained for carbide forming metals, as long as oxidation during the integration is avoided. Even though metal-nitrides exhibit an enhanced contact resistance, they are recommended to be used at the bottom metallization in order to minimize the oxidation of the metal-CNT contact during subsequent processing steps. Overall a ranking for the materials from the lowest to the highest contact resistance is obtained: Ta < Ti < TaN < TiN « TiO2 « Ta2O5 Furthermore the impact of post CNT growth procedures as chemical mechanical planarization, HF treatment and annealing procedures after the CNT based via fabrication are evaluated. The conductance of the incorporated CNTs and the applicable electrical transport regime relative to the CNT quality and the CNT length is discussed. In addition, a strong correlation between the temperature coefficient of resistance and the initial resistance of the CNT based vias at room temperature has been observed.
Die kontinuierliche Miniaturisierung der charakteristischen Abmessungen in hochintegrierten Schaltungen (ULSI) verursacht einen Anstieg des Widerstandes im Zuleitungssystem aufgrund der erhöhten Streuung von Elektronen an Seitenwänden und Korngrenzen in der Cu-Technologie, wodurch die Verzögerungszeit des Zuleitungssystems ansteigt. Die herausragenden Eigenschaften von Kohlenstoffnanoröhren (CNT), wie eine große mittlere freie Weglänge, hohe thermische Leitfähigkeit und eine starke Resistenz gegenüber Elektromigration machen diese zu einem idealen Kandidaten, um Cu in zukünftigen Technologiegenerationen zu ersetzen. Die vorliegende Arbeit beschreibt die Herstellung und daraus resultierenden Eigenschaften von Zwischenebenenkontakten (Vias) basierend auf CNTs. Alle verwendeten Prozessierungsschritte sind kompatibel mit der Herstellung von hochintegrierten Schaltkreisen und eine Schnittstelle zwischen den CNT Vias und einer Cu-Metallisierung ist vorhanden. Insbesondere das Verfahren zur Evaluierung von CNT Vias wurde durch den Einsatz verschiedener Methoden verbessert. Insbesondere soll hervorgehoben werden, dass durch die Messung des Widerstandes eines einzelnen CNTs, bei bekannter CNT Dichte, der Via Widerstand sehr genau vorausgesagt werden kann. Dies ermöglicht eine systematische Untersuchung des Einflusses der verschiedenen Prozessschritte und der darin verwendeten Materialien auf den Via Widerstand. Der niedrigste Kontaktwiderstand wird für Karbidformierende Metalle erreicht, solange Oxidationsprozesse ausgeschlossen werden können. Obwohl Metallnitride einen höheren Kontaktwiderstand aufweisen, sind diese für die Unterseitenmetallisierung zu empfehlen, da dadurch die Oxidation der leitfähigen Schicht minimiert wird. Insgesamt kann eine Reihenfolge beginnend mit dem niedrigsten zum höchsten Kontaktwiderstand aufgestellt werden: Ta < Ti < TaN < TiN « TiO2 « Ta2O5 Desweiteren wurde der Einfluss von Verfahren nach dem CNTWachstum wie die chemischmechanische Planarisierung, eine HF Behandlung und einer Temperaturbehandlung evaluiert, sowie deren Einfluss auf die elektrischen Parameter des Vias untersucht. Die Leitfähigkeit der integrierten CNTs und die daraus resultierenden elektrischen Transporteigenschaften in Abhängigkeit der CNT Qualität und Länge werden besprochen. Ebenso wird die starke Korrelation zwischen dem Temperaturkoeffizienten des elektrischen Widerstandes und des Ausgangswiderstandes der CNT basierten Vias bei Raumtemperatur diskutiert.
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ANTUNES, RENATO A. "Caracterização do comportamento frente à corrosão de um aço inoxidável austenítico para aplicações biomédicas com revestimentos PVD de TiN, TiCN e DLC." reponame:Repositório Institucional do IPEN, 2006. http://repositorio.ipen.br:8080/xmlui/handle/123456789/11493.

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Made available in DSpace on 2014-10-09T12:52:30Z (GMT). No. of bitstreams: 0
Made available in DSpace on 2014-10-09T14:02:35Z (GMT). No. of bitstreams: 0
Tese (Doutoramento)
IPEN/T
Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP
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Fiedler, Holger. "Preparation and characterization of Carbon Nanotube based vertical interconnections for integrated circuits." Doctoral thesis, Universitätsbibliothek Chemnitz, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-149474.

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(ULSI) causes an increase of the resistance of the wiring system by increased scattering of electrons at side walls and grain boundaries in the state of the art Cu technology, which increases the RC delay of the interconnect system and thus degrades the performance of the device. The outstanding properties of carbon nanotubes (CNT) such as a large mean free path, a high thermal conductance and a large resistance against electromigration make them an ideal candidate to replace Cu in future feature nodes. The present thesis contributes to the preparation and properties of CNT based vertical interconnections (vias). In addition, all processes applied during the fabrication are compatible to ULSI and an interface between CNT based vias and a Cu metallization is studied. The methodology for the evaluation of CNT based vias is improved; it is highlighted that by measuring the resistance of one multiwall CNT and taking into account the CNT density, the performance of the CNT based vias can be predicted accurately. This provides the means for a systematic evaluation of different integration procedures and materials. The lowest contact resistance is obtained for carbide forming metals, as long as oxidation during the integration is avoided. Even though metal-nitrides exhibit an enhanced contact resistance, they are recommended to be used at the bottom metallization in order to minimize the oxidation of the metal-CNT contact during subsequent processing steps. Overall a ranking for the materials from the lowest to the highest contact resistance is obtained: Ta < Ti < TaN < TiN « TiO2 « Ta2O5 Furthermore the impact of post CNT growth procedures as chemical mechanical planarization, HF treatment and annealing procedures after the CNT based via fabrication are evaluated. The conductance of the incorporated CNTs and the applicable electrical transport regime relative to the CNT quality and the CNT length is discussed. In addition, a strong correlation between the temperature coefficient of resistance and the initial resistance of the CNT based vias at room temperature has been observed
Die kontinuierliche Miniaturisierung der charakteristischen Abmessungen in hochintegrierten Schaltungen (ULSI) verursacht einen Anstieg des Widerstandes im Zuleitungssystem aufgrund der erhöhten Streuung von Elektronen an Seitenwänden und Korngrenzen in der Cu-Technologie, wodurch die Verzögerungszeit des Zuleitungssystems ansteigt. Die herausragenden Eigenschaften von Kohlenstoffnanoröhren (CNT), wie eine große mittlere freie Weglänge, hohe thermische Leitfähigkeit und eine starke Resistenz gegenüber Elektromigration machen diese zu einem idealen Kandidaten, um Cu in zukünftigen Technologiegenerationen zu ersetzen. Die vorliegende Arbeit beschreibt die Herstellung und daraus resultierenden Eigenschaften von Zwischenebenenkontakten (Vias) basierend auf CNTs. Alle verwendeten Prozessierungsschritte sind kompatibel mit der Herstellung von hochintegrierten Schaltkreisen und eine Schnittstelle zwischen den CNT Vias und einer Cu-Metallisierung ist vorhanden. Insbesondere das Verfahren zur Evaluierung von CNT Vias wurde durch den Einsatz verschiedener Methoden verbessert. Insbesondere soll hervorgehoben werden, dass durch die Messung des Widerstandes eines einzelnen CNTs, bei bekannter CNT Dichte, der Via Widerstand sehr genau vorausgesagt werden kann. Dies ermöglicht eine systematische Untersuchung des Einflusses der verschiedenen Prozessschritte und der darin verwendeten Materialien auf den Via Widerstand. Der niedrigste Kontaktwiderstand wird für Karbidformierende Metalle erreicht, solange Oxidationsprozesse ausgeschlossen werden können. Obwohl Metallnitride einen höheren Kontaktwiderstand aufweisen, sind diese für die Unterseitenmetallisierung zu empfehlen, da dadurch die Oxidation der leitfähigen Schicht minimiert wird. Insgesamt kann eine Reihenfolge beginnend mit dem niedrigsten zum höchsten Kontaktwiderstand aufgestellt werden: Ta < Ti < TaN < TiN « TiO2 « Ta2O5 Desweiteren wurde der Einfluss von Verfahren nach dem CNTWachstum wie die chemischmechanische Planarisierung, eine HF Behandlung und einer Temperaturbehandlung evaluiert, sowie deren Einfluss auf die elektrischen Parameter des Vias untersucht. Die Leitfähigkeit der integrierten CNTs und die daraus resultierenden elektrischen Transporteigenschaften in Abhängigkeit der CNT Qualität und Länge werden besprochen. Ebenso wird die starke Korrelation zwischen dem Temperaturkoeffizienten des elektrischen Widerstandes und des Ausgangswiderstandes der CNT basierten Vias bei Raumtemperatur diskutiert
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Löffler, Markus. "Nanomanipulation and In-situ Transport Measurements on Carbon Nanotubes." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-33242.

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With the advent of microelectronics and micromechanical systems, the benefits of miniaturized technology became evident. With the discovery of carbon nanotubes by Iijima in 1991, a material has been found that offers superior porperties such as high tensile strength, excellent electrical and heat conductivity while being lightweight, flexible and tunable by the specific atomic arrangement in its structure. The first part of this thesis deals with a new synthesis approach, which combines the known routes of chemical vapour deposition and laser ablation. The results concerning diameter and yield fit well within an established model for the nucleation and growth of carbon nanotubes and extend it by considering a larger parameter space. Furthermore, conventional laser ablation has been used to synthesize C-13 augmented carbon nanotubes, whose diameters depend among the usual synthesis parameters also on the C-13 content, an influence which is in line with the changed thermal conductivities of isotope mixtures. Manipulation of carbon nanotubes inside a transmission electron microscope forms the second part of this thesis. With the help of an in-situ nanomanipulator, several experiments involving the mechanical and electrical properties of carbon nanotubes have been performed. Two-probe resistances of individual nanotubes have been measured and the observation of individual shell failures allowed for the determination of current limits per carbon shell. With the help of electrical current, a nanotube was modified in its electrical characteristics by reshaping its structure. By application of DC-currents or square current pulses, the filling of iron- or cementite-filled multi-wall carbon nanotubes has been found to move in a polarity-defined direction guided by the nanotube walls. Depending on the current, nanotube shape, and composition of the filling different regimes of material transport have been identified, including the reworking of the inner nanotube shells. The application of a high driving current leads to a complete reworking of the host nanotube and the current-induced growth of carbonaceous nanostructures of changed morphology. Utilizing the obtained results, a transport mechanism involving momentum transfer from the electron wind to the filling atoms and a solid filling core during transport is developed and discussed. Finally, measurements of mechanical properties using electrically induced resonant or non-resonant vibrations inside the transmission electron microscope have been observed and important mechanical parameters have been determined with the help of a modified Euler-Bernoulli-beam approach
Mit dem Aufkommen von Mikroelektronik und mikromechanischen Systemen wurden die Vorteile miniaturisierter Geräte augenscheinlich. Mit der Entdeckung von Kohlenstoff-Nanoröhren durch Iijima 1991 wurde ein Material gefunden, welches überlegene Eigenschaften wie hohe Festigkeit, exzellente elektrische und Wärmeleitfähigkeit zeigt, während es zeitgleich leicht und flexibel ist. Diese Eigentschaften können durch eine Änderung der spezifischen atomaren Anordnung in der Nanoröhrenhülle beeinflusst werden. Der erste Teil dieser Dissertationsschrift behandelt einen neuartigen Syntheseansatz, welche die bekannten Syntheserouten der chemischen Gasphasenabscheidung und Laserablation kombiniert. Die Ergebnisse bezüglich des Durchmessers und der Ausbeute lassen sich gut mit einem etablierten Modell der Nukleation und des Wachstums von Kohlenstoff-Nanoröhren beschreiben - sie erweitern es, indem sie einen größeren Parameterraum berücksichtigen. Des Weiteren wurde konventionelle Laserablation benutzt, um C-13 angereicherte Kohlenstoff-Nanoröhren herzustellen, deren Durchmesser nicht nur von den üblichen Parametern, sondern auch vom C-13 Anteil abhängt. Diese Abhängigkeit geht mit der veränderten thermischen Leitfähigkeit von Isotopenmischungen einher. Die Manipulation von Kohlenstoff-Nanoröhren in einem Transmission-Elektronenmikroskop formt den zweiten Teil der Dissertationschrift. Mit Hilfe eines in-situ Manipulators wurden vielfältige Experimente durchgeführt, um die mechanischen und elektrischen Eigenschaften der Kohlenstoff-Nanoröhren zu bestimmen. Zweipunktmessungen des Widerstands einzelner Nanoröhren und die Beobachtung des Versagens einzelner Kohlenstoffschichten erlaubte die Bestimmung der Stromtragfähigkeit einzelner Hüllen. Mit Hilfe eines elektrischen Stromes konnte eine Nanoröhre durch die veränderung der Struktur in ihren elektrischen Eigenschaften verändert werden. Unter Verwendung dauerhaften oder gepulsten Gleichstroms konnte die Eisen- oder Zementit-Füllung der Kohlenstoff-Nanoröhren in eine polaritätsabhängige Richtung bewegt werden. Die Füllung wurde dabei durch die Wände der Nanoröhre geführt. Abhängig von Strom, Form der Nanoröhre und Zusammensetzung der Füllung ließen sich verschiedene Bereiche des Materialtransports identifizieren, u.a. das Umarbeiten einiger innerer Kohlenstoffschichten. Ein hoher Strom hingegen bewirkt eine Umarbeitung der kompletten Nanoröhre und strominduziertes Wachstum von Kohlenstoff-Nanostrukturen mit veränderter Morphologie. Mit Hilfe der gewonnenen Resultate wurde ein Transportmodell entwickelt, welches den Impulstransfer von Elektronen an Füllungsatome sowie einen festen Füllungskern während des Transports diskutiert. Messungen der mechanischen Eigenschaften, welche mit Hilfe von resonanter oder nicht-resonanter elektrischer Anregung von Schwingungen im Transmissions-Elektronenmikroskop durchgeführt wurden bilden den Abschluss der Arbeit. Durch die Beobachtungen konnten mit einem modifizierten Euler-Bernoulli-Balkenmodell wichtige mechanische Eigenschaften bestimmt werden
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Choi, Song Ho. "Development of SOFC anodes resistant to sulfur poisoning and carbon deposition." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/26601.

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Thesis (Ph.D)--Materials Science and Engineering, Georgia Institute of Technology, 2008.
Committee Chair: Meilin Liu; Committee Member: Arun Gokhale; Committee Member: Christoper Summers; Committee Member: Preet Singh; Committee Member: Tom Fuller. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Steinhorst, Maximilian, Maurizio Giorgio, Slavcho Topalski, and Teja Roch. "Investigation of carbon-based coatings on austenitic stainless steel for bipolar plates in proton exchange membrane fuel cells, produced by cathodic arc deposition." 2019. https://monarch.qucosa.de/id/qucosa%3A36197.

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Stainless steel bipolar plates are a possible replacement for graphite and composite bipolar plates in fuel cells. However, due to a native oxide layer they exhibit a high interfacial contact resistance (ICR) which lowers the performance. Conductive coatings like gold are a possible solution because they can reduce the contact resistance of metallic bipolar plates. We investigate the pulsed cathodic arc technique for deposition of carbon-based thin films on austenitic stainless steel 316L as cost-efficient alternative. Different types of coatings were prepared by varying the layer structure and processing parameters. Potentiodynamic polarization tests and ICR measurements were conducted to evaluate the performance of the films as conductive and corrosion resistant coatings. It was found that the corrosion resistance of coated austenitic steel samples is improved by both coatings and that measured ICR-values are well below the DOE 2020 target of 10 mΩ/cm2.
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Löffler, Markus. "Nanomanipulation and In-situ Transport Measurements on Carbon Nanotubes." Doctoral thesis, 2009. https://tud.qucosa.de/id/qucosa%3A25282.

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With the advent of microelectronics and micromechanical systems, the benefits of miniaturized technology became evident. With the discovery of carbon nanotubes by Iijima in 1991, a material has been found that offers superior porperties such as high tensile strength, excellent electrical and heat conductivity while being lightweight, flexible and tunable by the specific atomic arrangement in its structure. The first part of this thesis deals with a new synthesis approach, which combines the known routes of chemical vapour deposition and laser ablation. The results concerning diameter and yield fit well within an established model for the nucleation and growth of carbon nanotubes and extend it by considering a larger parameter space. Furthermore, conventional laser ablation has been used to synthesize C-13 augmented carbon nanotubes, whose diameters depend among the usual synthesis parameters also on the C-13 content, an influence which is in line with the changed thermal conductivities of isotope mixtures. Manipulation of carbon nanotubes inside a transmission electron microscope forms the second part of this thesis. With the help of an in-situ nanomanipulator, several experiments involving the mechanical and electrical properties of carbon nanotubes have been performed. Two-probe resistances of individual nanotubes have been measured and the observation of individual shell failures allowed for the determination of current limits per carbon shell. With the help of electrical current, a nanotube was modified in its electrical characteristics by reshaping its structure. By application of DC-currents or square current pulses, the filling of iron- or cementite-filled multi-wall carbon nanotubes has been found to move in a polarity-defined direction guided by the nanotube walls. Depending on the current, nanotube shape, and composition of the filling different regimes of material transport have been identified, including the reworking of the inner nanotube shells. The application of a high driving current leads to a complete reworking of the host nanotube and the current-induced growth of carbonaceous nanostructures of changed morphology. Utilizing the obtained results, a transport mechanism involving momentum transfer from the electron wind to the filling atoms and a solid filling core during transport is developed and discussed. Finally, measurements of mechanical properties using electrically induced resonant or non-resonant vibrations inside the transmission electron microscope have been observed and important mechanical parameters have been determined with the help of a modified Euler-Bernoulli-beam approach.
Mit dem Aufkommen von Mikroelektronik und mikromechanischen Systemen wurden die Vorteile miniaturisierter Geräte augenscheinlich. Mit der Entdeckung von Kohlenstoff-Nanoröhren durch Iijima 1991 wurde ein Material gefunden, welches überlegene Eigenschaften wie hohe Festigkeit, exzellente elektrische und Wärmeleitfähigkeit zeigt, während es zeitgleich leicht und flexibel ist. Diese Eigentschaften können durch eine Änderung der spezifischen atomaren Anordnung in der Nanoröhrenhülle beeinflusst werden. Der erste Teil dieser Dissertationsschrift behandelt einen neuartigen Syntheseansatz, welche die bekannten Syntheserouten der chemischen Gasphasenabscheidung und Laserablation kombiniert. Die Ergebnisse bezüglich des Durchmessers und der Ausbeute lassen sich gut mit einem etablierten Modell der Nukleation und des Wachstums von Kohlenstoff-Nanoröhren beschreiben - sie erweitern es, indem sie einen größeren Parameterraum berücksichtigen. Des Weiteren wurde konventionelle Laserablation benutzt, um C-13 angereicherte Kohlenstoff-Nanoröhren herzustellen, deren Durchmesser nicht nur von den üblichen Parametern, sondern auch vom C-13 Anteil abhängt. Diese Abhängigkeit geht mit der veränderten thermischen Leitfähigkeit von Isotopenmischungen einher. Die Manipulation von Kohlenstoff-Nanoröhren in einem Transmission-Elektronenmikroskop formt den zweiten Teil der Dissertationschrift. Mit Hilfe eines in-situ Manipulators wurden vielfältige Experimente durchgeführt, um die mechanischen und elektrischen Eigenschaften der Kohlenstoff-Nanoröhren zu bestimmen. Zweipunktmessungen des Widerstands einzelner Nanoröhren und die Beobachtung des Versagens einzelner Kohlenstoffschichten erlaubte die Bestimmung der Stromtragfähigkeit einzelner Hüllen. Mit Hilfe eines elektrischen Stromes konnte eine Nanoröhre durch die veränderung der Struktur in ihren elektrischen Eigenschaften verändert werden. Unter Verwendung dauerhaften oder gepulsten Gleichstroms konnte die Eisen- oder Zementit-Füllung der Kohlenstoff-Nanoröhren in eine polaritätsabhängige Richtung bewegt werden. Die Füllung wurde dabei durch die Wände der Nanoröhre geführt. Abhängig von Strom, Form der Nanoröhre und Zusammensetzung der Füllung ließen sich verschiedene Bereiche des Materialtransports identifizieren, u.a. das Umarbeiten einiger innerer Kohlenstoffschichten. Ein hoher Strom hingegen bewirkt eine Umarbeitung der kompletten Nanoröhre und strominduziertes Wachstum von Kohlenstoff-Nanostrukturen mit veränderter Morphologie. Mit Hilfe der gewonnenen Resultate wurde ein Transportmodell entwickelt, welches den Impulstransfer von Elektronen an Füllungsatome sowie einen festen Füllungskern während des Transports diskutiert. Messungen der mechanischen Eigenschaften, welche mit Hilfe von resonanter oder nicht-resonanter elektrischer Anregung von Schwingungen im Transmissions-Elektronenmikroskop durchgeführt wurden bilden den Abschluss der Arbeit. Durch die Beobachtungen konnten mit einem modifizierten Euler-Bernoulli-Balkenmodell wichtige mechanische Eigenschaften bestimmt werden.
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Books on the topic "Carbon deposition resistance"

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Miyoshi, Kazuhisa. Diamond and diamondlike carbon as wear-resistant, self-lubricating coatings for silicon nitride. [Washington, D.C.]: National Aeronautics and Space Administration, 1995.

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Miyoshi, Kazuhisa. Friction and wear properties of as-deposited and carbon ion-implanted diamond films. Cleveland, Ohio: Lewis Research Center, 1994.

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Miyoshi, Kazuhisa. Friction and wear properties of as-deposited and carbon ion-implanted diamond films. [Washington, D.C: National Aeronautics and Space Administration, 1996.

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Miyoshi, Kazuhisa. Friction and wear of ion-beam-deposited diamondlike carbon on chemical-vapor-deposited, fine-grain diamond. [Washington, D.C: National Aeronautics and Space Administration, 1996.

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Miyoshi, Kazuhisa. Friction and wear of ion-beam-deposited diamondlike carbon on chemical-vapor-deposited, fine-grain diamond. [Washington, D.C: National Aeronautics and Space Administration, 1996.

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Miyoshi, Kazuhisa. Friction and wear of ion-beam-deposited diamondlike carbon on chemical-vapor-deposited, fine-grain diamond. [Washington, D.C: National Aeronautics and Space Administration, 1996.

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Miyoshi, Kazuhisa. Friction and wear of ion-beam-deposited diamondlike carbon on chemical-vapor-deposited, fine-grain diamond. [Washington, D.C: National Aeronautics and Space Administration, 1996.

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Miyoshi, Kazuhisa. Surface design and engineering toward wear-resistant, self-lubricant diamond films and coatings. [Cleveland, Ohio]: National Aeronautics and Space Administration, Glenn Research Center, 1999.

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Miyoshi, Kazuhisa. Surface design and engineering toward wear-resistant, self-lubricant diamond films and coatings. [Cleveland, Ohio]: National Aeronautics and Space Administration, Glenn Research Center, 1999.

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United States. National Aeronautics and Space Administration., ed. Diamond and diamondlike carbon as wear-resistant, self-lubricating coatings for silicon nitride. [Washington, D.C.]: National Aeronautics and Space Administration, 1995.

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Book chapters on the topic "Carbon deposition resistance"

1

Chang, Shih-Hsien, Chih-Chung Chang, and Cheng Liang. "Improving the Surface Hardness and Wear Resistance of S45C Carbon Steel Via Various Heat Treatments and pH Values of Electroless Ni-P Deposition." In Recent Trends in Nanotechnology and Materials Science, 1–13. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-04516-0_1.

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Domingues, Beatriz, Joana M. Silva, Ivo M. Aroso, Estêvão Lima, Alexandre A. Barros, and Rui L. Reis. "Coatings for Urinary Stents: Current State and Future Directions." In Urinary Stents, 209–23. Cham: Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-031-04484-7_18.

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AbstractUrinary stent coatings are a strategy to tackle certain complications associated with the use of biomaterials. The latest innovations in surface coatings focused on the prevention of those problems, thus reducing further costs with treatments. Urinary stents associated symptoms, infections and encrustation are considered the major challenges, and, in an attempt to prevent such morbidity, several strategies were developed. Hence, coatings have been designed to improve quality of life for patients, reducing the friction, inhibiting uropathogens survival or attachment on stents, and avoiding the deposition of urinary crystals that triggers encrustation. Currently for ureteral stents, hydrophilic and diamond-like carbon coatings are commercial options associated with an enhanced performance of devices, comparing with uncoated ones. These commercially available approaches are all anti-adhesive coatings, and, in the general overview, this type of strategy appears to be a superior alternative than bactericidal coatings. Designs that trigger uropathogen death are usually associated with higher toxicity, and, in some cases, it can even favor the development of microbial resistance, which can hamper the infection treatment. With the present knowledge about antimicrobial mechanisms and inspired by nature, more cutting-edge alternatives, able to confer antimicrobial properties to the inner and outer parts of stents, will surely appear.
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Azadi, Mahboobeh. "Deposition of TiN, TiC, and DLC Coatings by PACVD." In Production, Properties, and Applications of High Temperature Coatings, 381–402. IGI Global, 2018. http://dx.doi.org/10.4018/978-1-5225-4194-3.ch014.

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In this chapter, the author studied about titanium nitride (TiN), titanium carbide (TiC), diamond like carbon (DLC) single and multilayer coatings that utilize in harsh environments. These hard coatings were usually produced by the plasma assisted chemical vapor deposition (PACVD) method as a modern technique. PACVD is used to deposit thin coatings for different usages such as computer disc drives, automobile and aerospace parts, surgical/medical instruments and the food industry. The author tried to delineate the state of the performance of different coating systems and layer characteristics that suitable either for laboratory -scales or industrial applications. Mechanical features of these coatings contain the hardness, the toughness, the wear resistance and structural properties that were perused. Consequently, this chapter offers a source of information for those who want to familiarize with the knowledge in the area of materials science of functional coatings that was produced by new plasma-based technologies.
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Singh, Aniket, Aman Shukla, Aryan Singh, Aman Deep Singh, and Pawan Kumar Arora. "Review on Process Parameters of FDM and Their Impact on Tensile Strength and Wear Resistance of Additive Manufacturing Specimen." In Advances in Transdisciplinary Engineering. IOS Press, 2022. http://dx.doi.org/10.3233/atde220753.

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Additive Manufacturing (AM) is an advanced manufacturing process which reduces the physical involvement of human beings for producing products. All we required is to make a three-dimensional CAD module and feed it to a three-dimensional printer. During its beginning it was just used to make a prototype, as more research has been taking place to improve its ability to make a good product due to which now it is able to produce the final product. Whenever we think about producing a product using additive manufacturing it is necessary to wisely choose the right material, right AM technique and their process parameters which fulfill the requirements. In this paper we are reviewing the process parameters of the most popularly used AM technique that is Fused Deposition Modeling (FDM) and their effect on tensile and wear strength of the printed specimen. For our study we are majorly focused on PLA and Carbon PLA as PLA is mostly use and environment friendly.
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Scheiffarth, Jakob H., Brian J. Wagner, Karl Brennfleck, and Wolf Huettner. "Increasing high temperature oxidation and corrosion resistance of graphite and carbon-fiber-reinforced carbon by deposition of a low pressure chemically vapor-deposited silicon carbide coating." In Metallurgical Coatings and Thin Films 1992, 13–18. Elsevier, 1992. http://dx.doi.org/10.1016/b978-0-444-89900-2.50009-9.

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Milone, Margherita, and Teerin Liewluck. "Progressive Weakness and Rash." In Mayo Clinic Cases in Neuroimmunology, edited by Andrew McKeon, B. Mark Keegan, and W. Oliver Tobin, 154–56. Oxford University Press, 2021. http://dx.doi.org/10.1093/med/9780197583425.003.0050.

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A 47-year-old man with hypercholesterolemia sought care for a 4-month history of progressive, proximal upper limb weakness and myalgia, followed by dysphagia, difficulty climbing stairs, and facial rash. Discontinuation of atorvastatin was of no benefit. Neurologic examination showed moderate weakness of the neck flexor muscles, shoulder girdle muscles, and finger extensors, and mild weakness of hip flexor and ankle dorsiflexor muscles. He had a heliotrope rash and Gottron sign. Serum testing showed an increased creatine kinase level. Needle electromyography showed myopathic changes with fibrillation potentials in proximal and axial muscles. Biopsy of the deltoid demonstrated a perifascicular pathologic process, including muscle fiber atrophy, and perivascular inflammatory exudate in the perimysium. Immunocytochemical studies showed patchy loss of intramuscular capillaries, some of which had complement (C5b9) deposition, and sarcoplasmic expression of myxovirus resistance protein A, mainly in the perifascicular regions. Immunologic testing was positive for autoantibodies to nuclear matrix protein 2 and negative for 3-hydroxy-3-methylglutaryl–coenzyme A reductase antibodies. Video swallow studies showed oropharyngeal dysphagia. Pulmonary function tests indicated mildly decreased maximal respiratory pressures but normal diffusing lung capacity for carbon monoxide. The findings were consistent with a diagnosis of dermatomyositis. The patient was started on oral prednisone and azathioprine, after checking for adequate thiopurine methyltransferase activity. Liver function tests and complete blood cell count with differential were assessed to monitor for potential azathioprine toxicity. Intravenous immunoglobulin was given. Follow-up examination revealed mild weakness of the shoulder girdle muscles after immunotherapy, and normal strength and creatine kinase value while on azathioprine monotherapy. Dermatomyositis is an idiopathic inflammatory myopathy. Idiopathic inflammatory myopathy is a group of autoimmune muscle diseases that includes dermatomyositis, polymyositis, inclusion body myositis, immune-mediated necrotizing myopathy, and overlap myositis, including antisynthetase syndrome.
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Amirtharaj Mosas, Kamalan Kirubaharan, Dinesh Kumar Devarajan, Subhenjit Hazra, and Gobi Saravanan Kaliaraj. "Recent Advancements in Wear-Resistant Coatings Prepared by PVD Methods." In Handbook of Research on Tribology in Coatings and Surface Treatment, 174–95. IGI Global, 2022. http://dx.doi.org/10.4018/978-1-7998-9683-8.ch008.

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Physical vapor deposition (PVD) technologies are widely used to produce wear and corrosion resistant coatings for a variety of industrial applications. In recent years, there has been remarkable interest in the development of novel wear resistant coatings prepared through PVD methods, which helps to reduce friction and wear, as a result of recovering energy losses up to 30% due to friction and economy loss due to wear. This chapter provides comprehensive data of recent progress in wear resistant coatings prepared using PVD methods, starting with the introduction of it needs, significance, physiochemical properties, and the selection criteria of wear resistant coatings. The applications, physical, and chemical properties of superhard materials such as diamond like carbon (DLC), titanium nitride (TiN), chromium nitride (CrN), and tantalum nitride (TaN) are also presented.
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Tinker, Peter B., and Peter Nye. "Microbiological Modification of the Rhizosphere." In Solute Movement in the Rhizosphere. Oxford University Press, 2000. http://dx.doi.org/10.1093/oso/9780195124927.003.0012.

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The general questions of root/shoot ratio, allocation of carbon to the root system, and root system dynamics are discussed in chapter 9, and the detailed root structure in chapter 5. Root-derived carbon forms the substrate for rhizosphere and symbiotic organisms, and hence leads to the increase in their population densities close to or in the root. Some of the carbon compounds from the root have specific chemical effects also (see chapter 7). Both quantity and composition of these materials need to be known if their effects are to be understood, and we discuss this subject here. The terminology of these materials is rather confused. The collective name for the injection of plant-derived carbon into the soil around living roots is ‘rhizodeposition’, but this has been used in different ways; for example, it may include root-respired carbon dioxide (Whipps 1990), but Darrah (1996) excludes carbon dioxide. The various forms include (Rovira et al. 1979; Lambers 1987; Whipps 1990) solid tissues lost from the root during growth; mucigel and debris from root surfaces and root cap; low-molecular-weight organic compounds in solution; carbon dioxide produced by root respiration for maintenance and for growth; faunal grazing of root tissues; and carbon transferred into symbionts, such as mycorrhizas and rhizobia. Some authors subdivide certain of these classes further. ‘Rhizodeposition’ is loss from a functioning root, but over a longer period the death and decomposition of whole roots deposits large quantities of carbon into the soil, which continues to act as a more resistant microbial substrate (see chapter 9). All of these materials ultimately are converted to carbon dioxide (except for material formed into stable soil organic matter) and this is difficult to separate from carbon dioxide produced directly by root respiration. The main issue here is how the various forms of deposition alter the ability of the living root system to absorb nutrients. We use the following terms for clarity, and because they relate to the practical means whereby these materials are quantified. As the rhizosphere situation is very dynamic, the results obtained will depend upon the timescale considered. (a) Exudates: soluble low-molecular-weight material that comes directly from the living root (microbial metabolites may be similar, but are excluded).
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Conference papers on the topic "Carbon deposition resistance"

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Yu, Choongho, Li Shi, Alan M. Cassell, Brett A. Cruden, Quoc Ngo, and Jun Li. "Thermal Contact Resistance and Thermal Conductivity of a Carbon Nanofiber." In ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems. ASMEDC, 2005. http://dx.doi.org/10.1115/ht2005-72320.

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We have used a microfabricated device to measure the thermal contact resistance between a 152-nm-diameter carbon nanofiber and the measurement device, and found that heat conduction models based on Fourier’s law can underestimate the thermal contact resistance at the nanoscale constriction if a large reduction in the effective thermal conductivity of the constriction is not taken into account. With the thermal contact resistance reduced by the deposition of a platinum layer on the contact, we observed that the thermal conductivity of the carbon nanofiber grown by using a plasma enhanced chemical vapor deposition method is comparable to that of graphite fibers grown by pyrolysis of natural gas prior to high-temperature heat treatment.
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TANAKA, KAZUTO, KAZUHIRO AOTO, and TSUTAO KATAYAMA. "EFFECTS OF CARBON NANOTUBE DEPOSITION TIME TO CARBON FIBER ON TENSILE LAP-SHEAR STRENGTH OF RESISTANCE WELDED CFRTP." In MATERIALS CHARACTERISATION 2017. Southampton UK: WIT Press, 2017. http://dx.doi.org/10.2495/mc170321.

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Özmen, Yılmaz. "Tribological Behavior of Carbon Based Materials." In ASME 2015 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/imece2015-50233.

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Diamond-like carbon (DLC) films have excellent tribological properties. These include low friction, high wear resistance, high corrosion resistance, and a high anti-seizure resistance. DLC film with and without Si doping (due to its promising effect on friction coefficient), at approximately 1–2 μm thickness, was synthesized by a reactive ion plating method using C6H6 source on WC-Co substrate. Si addition on tribological properties of DLC was evaluated. The effects of relative humidity and contact load are also investigated. When the Si content was increased above 5.9 at. %, tribological properties of the coating were deteriorated. These properties are, however, affected by film deposition parameters and sliding conditions such as normal load, sliding speed, mating materials, and atmospheric conditions. The effect of environment is particularly significant.
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Dallaire, S. "Erosion and Abrasion Resistance of Fe2B-Based Arc-Sprayed Coatings and Weld Overlays Containing Chromium and Carbon." In ITSC 2012, edited by R. S. Lima, A. Agarwal, M. M. Hyland, Y. C. Lau, C. J. Li, A. McDonald, and F. L. Toma. ASM International, 2012. http://dx.doi.org/10.31399/asm.cp.itsc2012p0788.

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Abstract Earlier works have demonstrated that Fe2B-based arc-sprayed coatings and weld overlays present outstanding dry erosion resistance when compared to other carbide-based coatings and overlays. The present work was undertaken to examine their wear resistance, particularly their slurry erosion resistance. Cored wires containing chromium (2-20 wt%) and carbon (0.2-1.2 wt%) additives were deposited by arc spraying and gas metal arc welding (GMAW). The abrasion, particle erosion and slurry erosion resistances of these (Fe-B-Cr-C) coatings and overlays were evaluated in laboratory. The results demonstrate that both differences in cored wire composition and variations in the deposition process must be considered in order to obtain the best wear properties.
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Tong, Tao, Yang Zhao, Lance Delzeit, Ali Kashani, and Arun Majumdar. "Multiwalled Carbon Nanotube/Nanofiber Arrays as Conductive and Dry Adhesive Interface Materials." In ASME 2004 3rd Integrated Nanosystems Conference. ASMEDC, 2004. http://dx.doi.org/10.1115/nano2004-46013.

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We demonstrate the possibility of making conductive and dry adhesive interfaces between multiwalled carbon nano-tube (MWNT) and nanofiber (MWNF) arrays grown by chemical vapor deposition with transition-metal as catalyst on silicon substrates. The maximum observed adhesion force between MWNT and MWNF surfaces is 3.5 mN for an apparent contact area of 2 mm by 4 mm. The minimum contact resistance measured at the same time is ∼20 Ω. Contact resistances of MWNT-MWNT and MWNT-gold interfaces were also measured as pressure forces around several milli-Newton were applied at the interface. The resulting minimum contact resistances are on the same order but with considerable variation from sample to sample. For MWNT-MWNT contacts, a minimum contact resistance of ∼ 1 Ω is observed for a contact area of 2 mm by 1 mm. The relatively high contact resistances, considering the area density of the nanotubes, might be explained by the high cross-tube resistances at the contact interfaces and limited inter-penetration of the nanotube arrays.
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White, Richard L., Bing K. Yen, Jan-Ulrich Thiele, Hans-Herman Schneider, James H. Rogers, and Bernd Jacoby. "Comparison of Energetic Carbon Deposition Processes for Use As Ultra-Thin Disk Overcoats." In STLE/ASME 2001 International Joint Tribology Conference. American Society of Mechanical Engineers, 2001. http://dx.doi.org/10.1115/trib-nano2001-109.

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Abstract Three different processes, Plasma Enhanced CVD (PECVD), Ion Beam (IB), and Cathodic Arc (CA) have been used to deposit highly energetic carbon films in the 2–10 nm thickness range in commercial, high throughput disk manufacturing tools. The deposition conditions used are typical of those required for disk manufacturing. Raman spectroscopy, I-V measurements, nanoindentation, and AFM based scratch testing have been used to characterize the structural, electrical, and mechanical properties of the films. The measured maximum hardness for the PECVD and IBD films are 28 and 25 GPa, respectively, and found to be influenced by the hardness of the softer substrates for the 70–120nm films available for measurement. The scratch resistance of the CAC films is ∼2× the scratch resistance of the IBD films and 25% greater than the PECVD films. Addition of nitrogen to the films produced by both the PECVD and IB techniques reduces the hardness of the films. Both the Raman and I-V data suggest increasing concentrations of sp2 bonding result from these nitrogen additions.
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Voss, Sterling, Bret Mecham, Lucy Bowden, Jacquelyn Monroe, Anton E. Bowden, and Brian D. Jensen. "316L Stainless Steel Sensitization in Carbon Nanotube CVD Growth for Bacterial Resistance." In ASME 2020 International Design Engineering Technical Conferences and Computers and Information in Engineering Conference. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/detc2020-22391.

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Abstract Physically altering the micro-topography of a surface can dramatically affect its capacity to support or prevent biofilm growth. Growing carbon-infiltrated carbon nanotubes on biomedical materials is one such approach which has proven effective. Unfortunately, the high temperature and carbon-rich gas exposure required for this procedure has proven to have deleterious effects. This paper proposes a kinetic model to explain the rusting phenomenon observed on 316L stainless steel substrates which have undergone the chemical vapor deposition process to grow carbon-infiltrated carbon nanotubes. The model is derived from Fick’s Second Law, and predicts the growth of chromium carbide as a function of temperature and time. Chromium carbide formation is shown to be the mechanism of corrosion, as chromium atoms are leeched from the the matrix, preventing the formation of a passivating chromium oxide layer in place of problematic iron oxide (rust) formation. The model is validated using experimental methods, which involve immersion in bacteria culture, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX).
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Sojoudi, Hossein, Fernando Reiter, and Samuel Graham. "Transparent Electrodes From Graphene/Single Wall Carbon Nanotube Composites." In ASME 2013 International Technical Conference and Exhibition on Packaging and Integration of Electronic and Photonic Microsystems. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/ipack2013-73158.

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A transparent conductive electrode comprised of alternating layers of graphene grown by chemical vapor deposition (CVD) and metallic single wall nanotubes (M-SWNTs) is presented. It was found that the addition of two single-layer graphene sheets enhances the conduction pathways in the M-SWNT film, yielding up to a 75% decrease in the sheet resistance with little sacrifice in the optical transmittance. Enhancements in the electrical properties of the films were made through a heat treatment process followed by nitric acid and thionyl chloride doping, yielding a sheet resistance of 70 Ω/sq with a transmittance of 78% at 550 nm. Composite films having undergone an annealing step were found to have stable electrical properties upon exposure to atmospheric conditions while doped films demonstrated limited stability.
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Kawakami, Hiroshi, Masato Ohnishi, Ken Suzuki, and Hideo Miura. "Highly Sensitive 2D Strain Sensor Using Carbon Nanotube." In ASME 2013 International Technical Conference and Exhibition on Packaging and Integration of Electronic and Photonic Microsystems. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/ipack2013-73156.

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A new highly sensitive strain measurement method has been developed by applying the strain-induced change of the electronic conductivity of CNTs. It is reported that most multi-walled carbon nanotubes (MWCNTs) show metallic conductivity and they are rather cheap comparing with single-walled carbon nanotubes (SWCNTs). However, it was found that the electric conductivity of MWCNTs changes drastically under uniaxial strain because of the drastic change of their band gap. Therefore, the authors have developed a highly sensitive strain sensor which can detect the local strain distribution by using MWCNTs. In order to design a new sensor using MWCNT, it is very important to control the shape of the MWCNTs under strain. Thus, a method for controlling the shape of the MWCNTs was developed by applying a chemical vapor deposition (CVD) technique. It was found that the shape of the grown MWCNT could be controlled by changing the average thickness of the catalyst and the deposition temperature of the MWCNT. The electrical resistance of the grown MWCNT changed almost linearly with the applied strain, and the maximum strain sensitivity obtained under the application of uniaxial strain was about 10%/1000-μstrain (gauge factor: 100). A two-dimensional strain sensor, which consists of area-arrayed fine bundles of MWCNTs, has been developed by applying MEMS technology. Under the application of compressive strain, the electric resistance was confirmed to increase almost linearly with the applied strain.
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Rothman, M. F. "Oxidation Resistance of Gas Turbine Combustion Materials." In ASME 1985 International Gas Turbine Conference and Exhibit. American Society of Mechanical Engineers, 1985. http://dx.doi.org/10.1115/85-gt-10.

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The oxidation behavior of five different gas turbine combustor alloy materials has been characterized in both combustion burner rig environments and in flowing air. The alloys are compared in terms of resistance to weight loss, or thinning, and also in terms of resistance to subsurface internal attack. Burner rig exposures were performed at 1095°C (2000°F) for 100, 200 and 300 hours under combustion conditions involving an air to fuel ratio of about 50:1. Results are also presented for similar exposures where the burner rig air lines were unintentionally plugged-up, yielding a low air:fuel ratio and severe carbon deposition on the samples. In addition to the burner rig studies, results are presented for 1008 hour flowing-air oxidation exposures over the temperature range from 980°C (1800°F) to 1205°C (2200°F).
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