Academic literature on the topic 'Carboaminaion'

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Journal articles on the topic "Carboaminaion"

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Chen, Xiang, Fang Xiao, and Wei-Min He. "Recent developments in the difunctionalization of alkenes with C–N bond formation." Organic Chemistry Frontiers 8, no. 18 (2021): 5206–28. http://dx.doi.org/10.1039/d1qo00375e.

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You, Cai, and Armido Studer. "Three-component 1,2-carboamination of vinyl boronic esters via amidyl radical induced 1,2-migration." Chemical Science 12, no. 47 (2021): 15765–69. http://dx.doi.org/10.1039/d1sc05811h.

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Jiang, Heng, and Armido Studer. "Intermolecular radical carboamination of alkenes." Chemical Society Reviews 49, no. 6 (2020): 1790–811. http://dx.doi.org/10.1039/c9cs00692c.

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Liu, Zhenhua, Huimin Ji, Wen Gao, Guangyu Zhu, Lili Tong, Fengcai Lei, and Bo Tang. "Copper(i)-mediated carboamination of vinyl azides by aryldiazonium salts: synthesis of N2-substituted 1,2,3-triazoles." Chemical Communications 53, no. 46 (2017): 6259–62. http://dx.doi.org/10.1039/c7cc02391j.

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Wang, Wei, Jun-Rong Song, Zhi-Yao Li, Ting Zhong, Qin Chi, Hai Ren, and Wei-Dong Pan. "Copper-catalyzed aerobic oxidative radical alkoxycyclization of tryptamines to access 3-alkoxypyrroloindolines." RSC Advances 11, no. 29 (2021): 18080–83. http://dx.doi.org/10.1039/d1ra02679h.

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Hopkins, B. A., and J. P. Wolfe. "Enantioselective synthesis of tetrahydroquinolines, tetrahydroquinoxalines, and tetrahydroisoquinolines via Pd-Catalyzed alkene carboamination reactions." Chem. Sci. 5, no. 12 (2014): 4840–44. http://dx.doi.org/10.1039/c4sc01327a.

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Asymmetric palladium-catalyzed carboamination reactions of aminoalkene substrates provide substituted six-membered heterocycles bearing quaternary stereocenters in good yield and high enantioselectivity.
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Gan, Zixu, Ke Zhang, Peng Shi, Yingsheng Zhao, and Runsheng Zeng. "Copper(i)-catalyzed radical carboamination reaction of 8-aminoquinoline-oriented buteneamides with chloroform: synthesis of-β-lactams." RSC Advances 11, no. 45 (2021): 28081–84. http://dx.doi.org/10.1039/d1ra05233k.

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Dai, Chenshu, Siqi Deng, Qiuhua Zhu, and Xiaodong Tang. "Synthesis of pyrrolo[1,2-a]quinoxalines via copper or iron-catalyzed aerobic oxidative carboamination of sp3C–H bonds." RSC Advances 7, no. 70 (2017): 44132–35. http://dx.doi.org/10.1039/c7ra09214h.

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Gazzotti, Stefano, Marco Manenti, Leonardo Lo Presti, and Alessandra Silvani. "Allylation of isatin-derived N-Boc-hydrazones followed by Pd-catalyzed carboamination reaction: an entry to 3-spiro-pyrazolidyl-oxindoles." RSC Advances 9, no. 65 (2019): 37788–800. http://dx.doi.org/10.1039/c9ra07712j.

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The indium-mediated allylation of novel 3-(2-Boc-hydrazono)indolin-2-one derivatives, followed by a palladium-catalysed carboamination reaction, is described to afford unprecedented spirocyclic oxindoles in good yields.
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Wolfe, John, and Zachary Garlets. "Asymmetric Synthesis of Six-Membered Cyclic Sulfamides via Palladium-Catalyzed Alkene Carboamination Reactions." Synthesis 50, no. 22 (May 3, 2018): 4444–52. http://dx.doi.org/10.1055/s-0036-1591574.

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The asymmetric synthesis of six-membered cyclic sulfamides via palladium-catalyzed alkene carboamination reactions of N-homo­allylsulfamides with aryl halides is described. High levels of enantio­selectivity were obtained with a catalyst composed of Pd2dba3 and (S)-Siphos-PE.
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Dissertations / Theses on the topic "Carboaminaion"

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MAZZA, ALBERTO. "SUSTAINABLE CHEMISTRY FOR THE PREPARATION OF NITROGENATED POLYHETEROCYCLIC SYSTEMS OF BIOLOGICAL INTEREST." Doctoral thesis, Università degli Studi di Milano, 2017. http://hdl.handle.net/2434/480115.

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The palladium and platinum catalyzed intramolecular reactions of unsaturated systems (alkynes, alkenes and allenes) arising from commercially available o-aminophenols and o-nitroaniline have been studied. Both carbo- and hydroamination processes resulted in the formation of nitrogen- benzofused rings. The carboamination domino process led to the C–C and C–N bond formation using a wide variety of aryl- and heteroaryl halides. The regioselectivity of the cyclization step was strongly dependent on the unsaturated system and on the protecting group tethered to the nitrogen atoms, allowing the formation of five- six- and seven-membered rings. In the second part, applications of two specific processes the Buchwald-Hartwig and Ullmann-type reactions were reported. The first process allowed the synthesis of a particular class of heteropolycyclic systems endowed with pharmacological properties as anticancer. The synthesis of the new hexacyclic system was realized starting from tryptamines and exploiting as a key step a sequential Pd-catalyzed N-arylation/acylation reaction. Having topoisomerases as biological target and the campthotecins class as benchmark, the new scaffold was decorated with substituents having different polarity and tested as Topoisomerase I inhibitors. The copper catalyzed Ullmann-type reaction was exploited to afford oxazino-indole scaffold through the intramolecular C-O bond formation, starting from N-hydroxyethyl-isatin derivatives.
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Bernasconi, A. "TRANSITION METALS CATALYZED REACTIONS FOR THE SYNTHESIS OF HETEROCYCLIC SYSTEMS." Doctoral thesis, Università degli Studi di Milano, 2013. http://hdl.handle.net/2434/217537.

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Pd-catalyzed reactions involving C-N bond formation on easily available substrates containing C-C multiple bonds represent useful methodology to achieve nitrogenated cyclic structures. To this aim unsaturated bonds such as alkenes, alkynes and allenes, tethered to a nucleophilic atom are suitable substrates to obtain products arising from exo- or endo-cyclization depending on the length and rigidity of the linking alkyl chain through amination reactions. In this work, we describe palladium catalyzed carboamination and hydroamination reactions of different substrates containing alkynyl and allenyl moieties resulting in the formation of new two-heteroatom-containing cyclic systems such as imidazoindoles, oxazoles, imidazoles, benzoxazines, oxazepines and isoxazolidines.
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Manzoni, Maria Rita. "Vicinal difunctionalization of olefins Aminohalogenation and carboamination for the rapid assembly of nitrogen /." 2006. http://proquest.umi.com/pqdweb?did=1192186371&sid=14&Fmt=2&clientId=39334&RQT=309&VName=PQD.

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Thesis (Ph.D.)--State University of New York at Buffalo, 2006.
Title from PDF title page (viewed on Mar. 02, 2007) Available through UMI ProQuest Digital Dissertations. Thesis adviser: Chemler, Sherry R. Includes bibliographical references.
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Book chapters on the topic "Carboaminaion"

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Wolfe, John P. "Synthesis of Saturated Heterocycles via Metal-Catalyzed Alkene Carboamination or Carboalkoxylation Reactions." In Topics in Heterocyclic Chemistry, 1–37. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/7081_2012_98.

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Chemler, S. R., and J. J. Kennedy-Ellis. "1.3 Copper-Catalyzed Alkene Difunctionalization." In Base-Metal Catalysis 1. Stuttgart: Georg Thieme Verlag KG, 2023. http://dx.doi.org/10.1055/sos-sd-238-00052.

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AbstractAlkene difunctionalization is a classic molecular transformation in organic synthesis, enabling the production of more-complex molecules from simple hydrocarbon-derived feedstocks. Alkene difunctionalizations catalyzed by copper complexes offer potentially more-sustainable protocols compared to those catalyzed by more-precious or -toxic metals. This chapter summarizes important recent advancements in the field, especially in the area of asymmetric catalysis. A number of copper-catalyzed intramolecular and intermolecular alkene difunctionalizations for the synthesis of cyclic and acyclic chiral amines and ethers, and related compounds, are presented. The reactions include alkene and/or diene hydroamination, hydroetherification, carboamination, carboetherification, diamination, oxyamination, and dicarbofunctionalization. Many of the reaction mechanisms involve a radical component either in the first or second bond-forming event. The ability of copper to engage with radicals in bond-forming events, including enantioselective ones, is a valuable aspect of many of these reactions.
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