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Journal articles on the topic 'C-H bonds functionalisation'

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Author: Grafiati
Published: 10 December 2022
Last updated: 29 January 2023

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1

Banerjee, Arghya, Satavisha Sarkar, and Bhisma K. Patel. "C–H functionalisation of cycloalkanes." Organic & Biomolecular Chemistry 15, no. 3 (2017): 505–30. http://dx.doi.org/10.1039/c6ob01975g.

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2

Prakash, Gaurav, Nilanjan Paul, Gwyndaf A. Oliver, Daniel B. Werz, and Debabrata Maiti. "C–H deuteration of organic compounds and potential drug candidates." Chemical Society Reviews 51, no. 8 (2022): 3123–63. http://dx.doi.org/10.1039/d0cs01496f.

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This review summarises deuteration methods of various organic motifs containing C(sp2)−H and C(sp3)−H bonds utilizing C−H bond functionalisation as a key step along with a variety of catalysts, and exemplifies their biological relevance.
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3

Patrick, Scott R., Ine I. F. Boogaerts, Sylvain Gaillard, Alexandra M. Z. Slawin, and Steven P. Nolan. "The role of silver additives in gold-mediated C–H functionalisation." Beilstein Journal of Organic Chemistry 7 (July 1, 2011): 892–96. http://dx.doi.org/10.3762/bjoc.7.102.

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The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C–H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.
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4

Che, Chi-Ming, Vanessa Kar-Yan Lo, Cong-Ying Zhou, and Jie-Sheng Huang. "Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts." Chemical Society Reviews 40, no. 4 (2011): 1950. http://dx.doi.org/10.1039/c0cs00142b.

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5

Crowe, Charlotte, Samuel Molyneux, Sunil V. Sharma, Ying Zhang, Danai S. Gkotsi, Helen Connaris, and Rebecca J. M. Goss. "Halogenases: a palette of emerging opportunities for synthetic biology–synthetic chemistry and C–H functionalisation." Chemical Society Reviews 50, no. 17 (2021): 9443–81. http://dx.doi.org/10.1039/d0cs01551b.

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6

Vellakkaran, Mari, Jagadish Das, Sourajit Bera, and Debasis Banerjee. "Nickel-catalysed alkylation of C(sp3)–H bonds with alcohols: direct access to functionalised N-heteroaromatics." Chemical Communications 54, no. 87 (2018): 12369–72. http://dx.doi.org/10.1039/c8cc06370b.

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7

Gulzar, Naeem, Bertrand Schweitzer-Chaput, and Martin Klussmann. "Oxidative coupling reactions for the functionalisation of C–H bonds using oxygen." Catalysis Science & Technology 4, no. 9 (June 16, 2014): 2778. http://dx.doi.org/10.1039/c4cy00544a.

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8

Shaikh, Mohammed Umar M., Sulochana S. Mudaliar, and Kishor H. Chikhalia. "An efficient alkynylation of 4-thiazolidinone with terminal alkyne under C–H functionalisation." RSC Advances 6, no. 56 (2016): 50780–85. http://dx.doi.org/10.1039/c6ra05015h.

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9

St John-Campbell, Sahra, and James A. Bull. "Transient imines as ‘next generation’ directing groups for the catalytic functionalisation of C–H bonds in a single operation." Organic & Biomolecular Chemistry 16, no. 25 (2018): 4582–95. http://dx.doi.org/10.1039/c8ob00926k.

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This review describes recent developments in the use of catalytic transient directing groups, through imine linkages, which in combination with transition metal catalysts provide streamlined C–H functionalisation processes.
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10

Gulzar, Naeem, Bertrand Schweitzer-Chaput, and Martin Klussmann. "ChemInform Abstract: Oxidative Coupling Reactions for the Functionalisation of C-H Bonds Using Oxygen." ChemInform 45, no. 41 (September 25, 2014): no. http://dx.doi.org/10.1002/chin.201441235.

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11

Majji, Ganesh, Srimanta Guin, Saroj K. Rout, Ahalya Behera, and Bhisma K. Patel. "Cyclic ethers to esters and monoesters to bis-esters with unconventional coupling partners under metal free conditions via sp3 C–H functionalisation." Chem. Commun. 50, no. 81 (2014): 12193–96. http://dx.doi.org/10.1039/c4cc05050a.

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12

Seyyedi, Behnam, Mohammad Edrisi, Maryam Seyyedi, and Gholamreza Mahdavinia. "A new single step synthesis of copper phthalocyanine green using microwave irradiation effects in functionalisation of C−H bonds in aromatic rings." Pigment & Resin Technology 43, no. 3 (April 29, 2014): 113–17. http://dx.doi.org/10.1108/prt-04-2013-0029.

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Purpose – The paper introduces a new method for single step synthesis of copper phthalocyanine green pigment using microwave irradiation to activate C−H bonds on the aromatic rings that are possible by creation of chlorine radicals. The aims of this study are to investigate the possibility of high-efficiency product reaction, removing acidic wastewater, time optimization, and maximizing number of chlorine on aromatic rings. Design/methodology/approach – The paper presents a new synthesis technique, which does not have the problems of the conventional methods. Microwave irradiation is used as a chemical reaction initiator by creation of chlorine radicals in saturated aqueous solution of sodium chloride and C−H bond activation on aromatic rings. The approach yields to a high quality of product, uniform particle size distribution, high efficiency and an environmental friendly procedure. Findings – The paper introduces the use of suitable materials and water solvents in chemical reactions under microwave radiation at low temperatures. This shows that the microwave irradiation activates C−H bonds on aromatic rings and creates chlorine radicals at the same time, which results in relatively fast reaction of synthesis copper phthalocyanine green. Research limitations/implications – The ammonium molybdate catalyst, which is used in this method, should be weighed carefully. The effects of transition metals on chemical reactions in the presence of microwave irradiation can also be chlorinated other unsaturated bonds. Practical implications – The method develops a simple and practical solution to improve the synthesis of phthalocyanine green pigment. Originality/value – The synthesis method of copper phthalocyanine green pigment is novel. CuPhcCl16 has numerous applications in industrial.
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13

Li, Bin, Christophe Darcel, and Pierre H. Dixneuf. "Ruthenium(II)-catalysed Functionalisation of CH Bonds via a Six-membered Cyclometallate: Monoarylation of Aryl 2-pyridyl Ketones." ChemCatChem 6, no. 1 (November 6, 2013): 127–30. http://dx.doi.org/10.1002/cctc.201300752.

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14

Vidal, Véronique, Albert Théolier, Jean Thivolle-Cazat, and Jean-Marie Basset. "Activation and functionalisation of the C–H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex." J. Chem. Soc., Chem. Commun., no. 10 (1995): 991–92. http://dx.doi.org/10.1039/c39950000991.

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15

Požgan, Franc, and Pierre H Dixneuf. "Ruthenium(II) Acetate Catalyst for Direct Functionalisation of sp2-CH Bonds with Aryl Chlorides and Access to Tris- Heterocyclic Molecules." Advanced Synthesis & Catalysis 351, no. 11-12 (August 14, 2009): 1737–43. http://dx.doi.org/10.1002/adsc.200900350.

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16

Felkin, Hugh, Tauqir Fillebeen-khan, Rupert Holmes-Smith, and Lin Yingrui. "Activation of C-H bonds in saturated hydrocarbons. The selective, catalytic functionalisation of methyl groups by means of a soluble iridium polyhydride system." Tetrahedron Letters 26, no. 16 (January 1985): 1999–2000. http://dx.doi.org/10.1016/s0040-4039(00)98363-1.

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17

Arockiam, Percia B., Cédric Fischmeister, Christian Bruneau, and Pierre H. Dixneuf. "Ruthenium(ii)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds." Green Chem. 15, no. 1 (2013): 67–71. http://dx.doi.org/10.1039/c2gc36222h.

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18

Das, Shoubhik, Robin Cauwenbergh, Sivaraman Gandhi, Philippe Nimmegeers, Yuman Qin, Prakash Kumar Sahoo, Peng Ren, Steven Van Passel, Yu Zhang, and Andrea Guidetti. "Transition Metal-Free Approach for the Late-Stage Benzylic C(sp3)–H Etherifications and Esterifications." Chemical Communications, 2022. http://dx.doi.org/10.1039/d2cc02661a.

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Herein, we report a transition metal-free approach for the regioselective functionalisation of benzylic C(sp3)-H bonds using alcohols and carboxylic acids as the nucleophiles. This approach provides a straightforward route for...
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19

Ahmed, Nehaal, Richard J. Spears, Tom Sheppard, and Vijay Chudasama. "Functionalisation of ethereal-based saturated heterocycles with concomitant aerobic C–H activation and C–C bond formation." Chemical Science, 2022. http://dx.doi.org/10.1039/d2sc01626e.

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