Relevant bibliographies by topics / C-F functionalisation

Academic literature on the topic 'C-F functionalisation'

Author: Grafiati
Published: 10 December 2022
Last updated: 28 January 2023

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Consult the lists of relevant articles, books, theses, conference reports, and other scholarly sources on the topic 'C-F functionalisation.'

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Journal articles on the topic "C-F functionalisation"

1

Hope, Michael A., Alexander C. Forse, Kent J. Griffith, Maria R. Lukatskaya, Michael Ghidiu, Yury Gogotsi, and Clare P. Grey. "NMR reveals the surface functionalisation of Ti3C2MXene." Physical Chemistry Chemical Physics 18, no. 7 (2016): 5099–102. http://dx.doi.org/10.1039/c6cp00330c.

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2

Nicholls, Thomas P., Johnathon C. Robertson, Michael G. Gardiner, and Alex C. Bissember. "Identifying the potential of pulsed LED irradiation in synthesis: copper-photocatalysed C–F functionalisation." Chemical Communications 54, no. 36 (2018): 4589–92. http://dx.doi.org/10.1039/c8cc02244e.

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The results of a proof-of-concept study demonstrate for the first time that pulsed LED irradiation enhances the rate of product formation and the yield of a visible light-mediated photoredox-catalysed reaction.
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3

Maddock, Lewis C. H., Tracy Nixon, Alan R. Kennedy, Michael R. Probert, William Clegg, and Eva Hevia. "Utilising Sodium-Mediated Ferration for Regioselective Functionalisation of Fluoroarenes via C−H and C−F Bond Activations." Angewandte Chemie International Edition 57, no. 1 (November 30, 2017): 187–91. http://dx.doi.org/10.1002/anie.201709750.

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4

Maddock, Lewis C. H., Tracy Nixon, Alan R. Kennedy, Michael R. Probert, William Clegg, and Eva Hevia. "Utilising Sodium-Mediated Ferration for Regioselective Functionalisation of Fluoroarenes via C−H and C−F Bond Activations." Angewandte Chemie 130, no. 1 (November 30, 2017): 193–97. http://dx.doi.org/10.1002/ange.201709750.

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5

Jacobs, Emily, and Sinead T. Keaveney. "Experimental and Computational Studies towards Chemoselective C−F over C−Cl Functionalisation: Reversible Oxidative Addition is the Key." ChemCatChem, November 17, 2020. http://dx.doi.org/10.1002/cctc.202001462.

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6

Ronchi, Paolo, Sara Guariento, Daniele Pala, Daniela Pizzirani, Claudio Fiorelli, Paolo Bruno, Veronica Nigroni, and Matteo Biagetti. "F-Based Small Group Decoration of Heteroarenes via C-H Activation: Medicinal Chemistry Rationale and late-stage Synthetic Methods." Current Organic Chemistry 25 (July 6, 2021). http://dx.doi.org/10.2174/1385272825666210706130210.

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: The use of F-based decorations in drug discovery started from the development of fluorocorticoids and fluorochinolones (1950s and 1980s, respectively), and has resulted in about 20% of approved drugs on the Market containing fluorine. From a medicinal chemistry perspective, the installation of F-based small groups (e.g., CF3, -CF2H, -OCF3, -OCF2H, -SCF3, -SCF2H) necessarily impacts on physicochemical, pharmacokinetics, pharmacodynamics and toxicological properties of small molecules. Accordingly, a huge interest in this topic is constantly arising in the medicinal chemistry community. Focusing on heteroarenes, the synthetic access to these substitutions is guaranteed by a number of effective reactions such as Minisci-type reaction, photochemistry or electrochemistry C-H activation. The aim of this work is to analyze the rationale in using these groups in medicinal chemistry and highlight the currently available synthetic toolbox of C-H activation for their introduction on heteroarenes of pharmaceutical interest. A particular focus has been given to those procedures amenable to the late-stage functionalisation process.
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