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Journal articles on the topic 'Borocarbonitrides'

Author: Grafiati
Published: 6 September 2023

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1

kumar, Nitesh, Kota Moses, K. Pramoda, Sharmila N. Shirodkar, Abhishek Kumar Mishra, Umesh V. Waghmare, A. Sundaresan, and C. N. R. Rao. "Borocarbonitrides, BxCyNz." Journal of Materials Chemistry A 1, no. 19 (2013): 5806. http://dx.doi.org/10.1039/c3ta01345f.

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2

Chakraborty, Himanshu, Santosh Mogurampelly, Vivek K. Yadav, Umesh V. Waghmare, and Michael L. Klein. "Phonons and thermal conducting properties of borocarbonitride (BCN) nanosheets." Nanoscale 10, no. 47 (2018): 22148–54. http://dx.doi.org/10.1039/c8nr07373b.

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3

Banerjee, Swastika, and Swapan K. Pati. "Criticality of surface topology for charge-carrier transport characteristics in two-dimensional borocarbonitrides: design principles for an efficient electronic material." Nanoscale 6, no. 22 (2014): 13430–34. http://dx.doi.org/10.1039/c4nr04198d.

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A computational investigation based on ab initio DFT combined with the Boltzmann transport equation enlightens the principle for maximizing mobility and the possibility of obtaining a particular (electron/hole) conduction polarity of borocarbonitrides.
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4

Rao, C. N. R., and K. Pramoda. "Borocarbonitrides, BxCyNz, 2D Nanocomposites with Novel Properties." Bulletin of the Chemical Society of Japan 92, no. 2 (February 15, 2019): 441–68. http://dx.doi.org/10.1246/bcsj.20180335.

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5

Kumar, Nitesh, Kalyan Raidongia, Abhishek K. Mishra, Umesh V. Waghmare, A. Sundaresan, and C. N. R. Rao. "Synthetic approaches to borocarbonitrides, BCxN (x=1–2)." Journal of Solid State Chemistry 184, no. 11 (November 2011): 2902–8. http://dx.doi.org/10.1016/j.jssc.2011.08.034.

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6

Rao, C. N. R., and K. Gopalakrishnan. "Borocarbonitrides, BxCyNz: Synthesis, Characterization, and Properties with Potential Applications." ACS Applied Materials & Interfaces 9, no. 23 (November 10, 2016): 19478–94. http://dx.doi.org/10.1021/acsami.6b08401.

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7

Chhetri, Manjeet, Somak Maitra, Himanshu Chakraborty, Umesh V. Waghmare, and C. N. R. Rao. "Superior performance of borocarbonitrides, BxCyNz, as stable, low-cost metal-free electrocatalysts for the hydrogen evolution reaction." Energy Environ. Sci. 9, no. 1 (2016): 95–101. http://dx.doi.org/10.1039/c5ee02521d.

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8

Gopalakrishnan, K., Kota Moses, A. Govindaraj, and C. N. R. Rao. "Supercapacitors based on nitrogen-doped reduced graphene oxide and borocarbonitrides." Solid State Communications 175-176 (December 2013): 43–50. http://dx.doi.org/10.1016/j.ssc.2013.02.005.

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9

Kumar, Nitesh, Kalyan Raidongia, Abhishek K. Mishra, Umesh V. Waghmare, A. Sundaresan, and C. N. R. Rao. "ChemInform Abstract: Synthetic Approaches to Borocarbonitrides, BCxN (x = 1-2)." ChemInform 43, no. 5 (January 5, 2012): no. http://dx.doi.org/10.1002/chin.201205013.

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10

Rao, Chintamani Nagesa Ramachandra, and Manjeet Chhetri. "Borocarbonitrides as Metal‐Free Catalysts for the Hydrogen Evolution Reaction." Advanced Materials 31, no. 13 (October 30, 2018): 1803668. http://dx.doi.org/10.1002/adma.201803668.

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11

Mighri, Rimeh, Umit B. Demirci, and Johan G. Alauzun. "Microporous Borocarbonitrides BxCyNz: Synthesis, Characterization, and Promises for CO2 Capture." Nanomaterials 13, no. 4 (February 15, 2023): 734. http://dx.doi.org/10.3390/nano13040734.

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Porous borocarbonitrides (denoted BCN) were prepared through pyrolysis of the polymer stemmed from dehydrocoupled ethane 1,2-diamineborane (BH3NH2CH2CH2NH2BH3, EDAB) in the presence of F-127. These materials contain interconnected pores in the nanometer range with a high specific surface area up to 511 m2 · g−1. Gas adsorption of CO2 demonstrated an interesting uptake (3.23 mmol · g−1 at 0 °C), a high CO2/N2 selectivity as well as a significant recyclability after several adsorption–desorption cycles. For comparison’s sake, a synthesized non-porous BCN as well as a commercial BN sample were studied to investigate the role of porosity and carbon doping factors in CO2 capture. The present work thus tends to demonstrate that the two-step synthesis of microporous BCN adsorbent materials from EDAB using a bottom-up approach (dehydrocoupling followed by pyrolysis at 1100 °C) is relatively simple and interesting.
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12

Kumar, Nitesh, K. S. Subrahmanyam, Piyush Chaturbedy, Kalyan Raidongia, Achutharao Govindaraj, Kailash P. S. S. Hembram, Abhishek K. Mishra, Umesh V. Waghmare, and C. N. R. Rao. "Remarkable Uptake of CO2 and CH4 by Graphene-Like Borocarbonitrides, BxCyNz." ChemSusChem 4, no. 11 (August 25, 2011): 1662–70. http://dx.doi.org/10.1002/cssc.201100197.

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13

Leardini, Fabrice, Lorenzo Massimi, Eduardo Flores-Cuevas, Jose Fernández, Jose Ares, Maria Betti, and Carlo Mariani. "Synthesis of Ternary Borocarbonitrides by High Temperature Pyrolysis of Ethane 1,2-Diamineborane." Materials 8, no. 9 (September 9, 2015): 5974–85. http://dx.doi.org/10.3390/ma8095285.

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14

Massimi, Lorenzo, Maria Grazia Betti, Simone Caramazza, Paolo Postorino, Carlo Mariani, Alessandro Latini, and Fabrice Leardini. "In-vacuum thermolysis of ethane 1,2-diamineborane for the synthesis of ternary borocarbonitrides." Nanotechnology 27, no. 43 (September 22, 2016): 435601. http://dx.doi.org/10.1088/0957-4484/27/43/435601.

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15

Zhang, Lei, and Gang Zhou. "Coordination engineering of single-atom copper embedded graphene-like borocarbonitrides for hydrogen production." Applied Surface Science 610 (February 2023): 155506. http://dx.doi.org/10.1016/j.apsusc.2022.155506.

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16

Barua, Manaswee, M. B. Sreedhara, K. Pramoda, and C. N. R. Rao. "Quantification of surface functionalities on graphene, boron nitride and borocarbonitrides by fluorescence labeling." Chemical Physics Letters 683 (September 2017): 459–66. http://dx.doi.org/10.1016/j.cplett.2017.02.028.

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17

Sen, Sudeshna, Kota Moses, Aninda J. Bhattacharyya, and C. N. R. Rao. "Excellent Performance of Few-Layer Borocarbonitrides as Anode Materials in Lithium-Ion Batteries." Chemistry - An Asian Journal 9, no. 1 (October 21, 2013): 100–103. http://dx.doi.org/10.1002/asia.201301037.

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18

Moses, Kota, Sharmila N. Shirodkar, U. V. Waghmare, and C. N. R. Rao. "Composition-dependent photoluminescence and electronic structure of 2-dimensional borocarbonitrides, BCXN (x= 1, 5)." Materials Research Express 1, no. 2 (May 29, 2014): 025603. http://dx.doi.org/10.1088/2053-1591/1/2/025603.

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19

Sreedhara, M. B., K. Gopalakrishnan, B. Bharath, Ram Kumar, G. U. Kulkarni, and C. N. R. Rao. "Properties of nanosheets of 2D-borocarbonitrides related to energy devices, transistors and other areas." Chemical Physics Letters 657 (July 2016): 124–30. http://dx.doi.org/10.1016/j.cplett.2016.05.064.

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20

Berthebaud, David, Toshiyuki Nishimura, and Takao Mori. "Thermoelectric properties and spark plasma sintering of doped YB22C2N." Journal of Materials Research 25, no. 4 (April 2010): 665–69. http://dx.doi.org/10.1557/jmr.2010.0100.

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YB22C2N is one of a series of rare earth borocarbonitrides and is potentially the long awaited n-type counterpart to boron carbide. We conducted studies on YB22C2N spark plasma sintered with additions of YB4 and YB25C, including the investigations of the densification process and the thermoelectric properties of the material. We discovered that a small amount of dopants can lower the starting temperature of densification during spark plasma sintering (SPS). Variations of pressure and temperature during the sintering process are also found to have an effect. Electrical conductivity of the dense samples has increased due to insertion of metal borides and also because of the improvement of the relative density. At the same time, only a slight reduction was observed for the Seebeck coefficient leading to an important improvement of power factor. The highest density of more than 95% was achieved with 5 wt% of YB25(C) dopant.
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21

Zhang, Xuefei, Pengqiang Yan, Junkang Xu, Fan Li, Felix Herold, Bastian J. M. Etzold, Peng Wang, et al. "Methanol conversion on borocarbonitride catalysts: Identification and quantification of active sites." Science Advances 6, no. 26 (June 2020): eaba5778. http://dx.doi.org/10.1126/sciadv.aba5778.

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Borocarbonitrides (BCNs) have emerged as highly selective catalysts for the oxidative dehydrogenation (ODH) reaction. However, there is a lack of in-depth understanding of the catalytic mechanism over BCN catalysts due to the complexity of the surface oxygen functional groups. Here, BCN nanotubes with multiple active sites are synthesized for oxygen-assisted methanol conversion reaction. The catalyst shows a notable activity improvement for methanol conversion (29%) with excellent selectivity to formaldehyde (54%). Kinetic measurements indicate that carboxylic acid groups on BCN are responsible for the formation of dimethyl ether, while the redox catalysis to formaldehyde occurs on both ketonic carbonyl and boron hydroxyl (B─OH) sites. The ODH reaction pathway on the B─OH site is further revealed by in situ infrared, x-ray absorption spectra, and density functional theory. The present work provides physical-chemical insights into the functional mechanism of BCN catalysts, paving the way for further development of the underexplored nonmetallic catalytic systems.
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22

Mishra, Abhishek Kumar, and Soni Mishra. "Tuning of adsorption energies of CO2 and CH4 in borocarbonitrides BxCyNz: A first-principles study." Journal of Molecular Graphics and Modelling 93 (December 2019): 107446. http://dx.doi.org/10.1016/j.jmgm.2019.107446.

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23

Jiang, Ding, Xiaojiao Du, Lei Zhou, Henan Li, and Kun Wang. "TiO2 nanoparticles embedded in borocarbonitrides nanosheets for sensitive and selective photoelectrochemical aptasensing of bisphenol A." Journal of Electroanalytical Chemistry 818 (June 2018): 191–97. http://dx.doi.org/10.1016/j.jelechem.2018.04.042.

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24

Zhao, Cancan, Anfeng Shen, Liangzhu Zhang, Kaili Lin, and Xudong Wang. "Borocarbonitrides nanosheets engineered 3D-printed scaffolds for integrated strategy of osteosarcoma therapy and bone regeneration." Chemical Engineering Journal 401 (December 2020): 125989. http://dx.doi.org/10.1016/j.cej.2020.125989.

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25

Weng, Ruiyu, Liangzhu Zhang, Yuanhang Cao, Zhihua Wang, Cancan Zhao, Jiemin Wang, and Changsheng Zhao. "Two-dimensional borocarbonitrides nanosheets engineered sulfonated polyether sulfone microspheres as highly efficient and photothermally recyclable adsorbents for hemoperfusion." Chemical Engineering Journal 463 (May 2023): 142365. http://dx.doi.org/10.1016/j.cej.2023.142365.

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26

Pramoda, K., Devesh Chandra Binwal, and C. N. R. Rao. "Nanocomposites of MoS2 nanoparticles with carboxyl-functionalized carbon nanotubes and borocarbonitrides nanosheets, and their electrocatalytic hydrogen evolution reaction activity." Materials Research Bulletin 149 (May 2022): 111697. http://dx.doi.org/10.1016/j.materresbull.2021.111697.

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27

Attri, Rohit, M. B. Sreedhara, and C. N. R. Rao. "Compositional Tuning of Electrical and Optical Properties of PLD-Generated Thin Films of 2D Borocarbonitrides (BN)1–x(C)x." ACS Applied Electronic Materials 1, no. 4 (April 2, 2019): 569–76. http://dx.doi.org/10.1021/acsaelm.9b00025.

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28

Attri, Rohit, M. B. Sreedhara, and C. N. R. Rao. "Correction to Compositional Tuning of Electrical and Optical Properties of PLD-Generated Thin Films of 2D Borocarbonitrides (BN)1–x(C)x." ACS Applied Electronic Materials 1, no. 7 (June 21, 2019): 1336. http://dx.doi.org/10.1021/acsaelm.9b00335.

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29

Singh, Navin Kumar, K. Pramoda, K. Gopalakrishnan, and C. N. R. Rao. "Synthesis, characterization, surface properties and energy device characterstics of 2D borocarbonitrides, (BN)xC1−x, covalently cross-linked with sheets of other 2D materials." RSC Advances 8, no. 31 (2018): 17237–53. http://dx.doi.org/10.1039/c8ra01885e.

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Covalent cross-linking of 2D structures such as graphene, MoS2 and C3N4 using coupling reactions affords the generation of novel materials with new or improved properties.
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30

Yang, Mingzhi, Dong Shi, Xiucai Sun, Yanlu Li, Zhenyan Liang, Lei Zhang, Yongliang Shao, Yongzhong Wu, and Xiaopeng Hao. "Shuttle confinement of lithium polysulfides in borocarbonitride nanotubes with enhanced performance for lithium–sulfur batteries." Journal of Materials Chemistry A 8, no. 1 (2020): 296–304. http://dx.doi.org/10.1039/c9ta11500e.

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31

Huang, Yan, Tongtong Yang, Li Yang, Ran Liu, Guozhen Zhang, Jun Jiang, Yi Luo, Ping Lian, and Shaobin Tang. "Graphene–boron nitride hybrid-supported single Mo atom electrocatalysts for efficient nitrogen reduction reaction." Journal of Materials Chemistry A 7, no. 25 (2019): 15173–80. http://dx.doi.org/10.1039/c9ta02947h.

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32

Jiang, Heyan, Cuicui Zang, Hongmei Cheng, Bin Sun, and Xue Gao. "Photocatalytic green synthesis of benzazoles from alcohol oxidation/toluene sp3 C–H activation over metal-free BCN: effect of crystallinity and N–B pair exposure." Catalysis Science & Technology 11, no. 24 (2021): 7955–62. http://dx.doi.org/10.1039/d1cy01623g.

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Porous borocarbonitride, with characteristics of enhanced crystallinity and improved N–B pairs exposure, was employed for the heterogeneous photocatalytic tandem synthesis of benzazoles from alcohol oxidation/toluene sp3 C–H activation.
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33

Wen, Tian, Er-Xia Chen, De-Xiang Zhang, and Jian Zhang. "Synthesis of borocarbonitride from a multifunctional Cu(i) boron imidazolate framework." Dalton Transactions 45, no. 12 (2016): 5223–28. http://dx.doi.org/10.1039/c5dt04805b.

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A multifunctional Cu(i) boron imidazole framework (BIF-36) not only directly reduced noble trimetal Au–Ag–Pd nanoparticles and turned into borocarbonitride material after carbonisation, but also showed redox-triggered reversible crystal structural transformation.
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34

Hussain, Kashif, Umer Younis, Imran Muhammad, Yu Qie, Yaguang Guo, Tingwei Li, Huanhuan Xie, and Qiang Sun. "Three-dimensional porous borocarbonitride BC2N with negative Poisson's ratio." Journal of Materials Chemistry C 8, no. 44 (2020): 15771–77. http://dx.doi.org/10.1039/d0tc03832f.

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Motivated by the recent synthesis of three-dimensional (3D) porous borocarbonitride (Angew. Chem., Int. Ed., 2019, 58, 6033–6037), we propose a porous 3D-BC2N structure composed of BC2N nanoribbons.
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35

Liu, Xiaobiao, Xikui Ma, Han Gao, Xiaoming Zhang, Haoqiang Ai, Weifeng Li, and Mingwen Zhao. "Valley-selective circular dichroism and high carrier mobility of graphene-like BC6N." Nanoscale 10, no. 27 (2018): 13179–86. http://dx.doi.org/10.1039/c8nr03080d.

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Graphene-like borocarbonitride (g-BC6N) has a direct-band gap of 1.833 eV, high carrier mobility comparable to that of black phosphorene and a pair of inequivalent valleys with opposite Berry curvatures in K and K′ points.
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36

Attri, Rohit, Subhajit Roychowdhury, Kanishka Biswas, and C. N. R. Rao. "Low thermal conductivity of 2D borocarbonitride nanosheets." Journal of Solid State Chemistry 282 (February 2020): 121105. http://dx.doi.org/10.1016/j.jssc.2019.121105.

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37

Luo, Zhishan, Yuanxing Fang, Min Zhou, and Xinchen Wang. "A Borocarbonitride Ceramic Aerogel for Photoredox Catalysis." Angewandte Chemie International Edition 58, no. 18 (April 23, 2019): 6033–37. http://dx.doi.org/10.1002/anie.201901888.

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38

Luo, Zhishan, Yuanxing Fang, Min Zhou, and Xinchen Wang. "A Borocarbonitride Ceramic Aerogel for Photoredox Catalysis." Angewandte Chemie 131, no. 18 (April 23, 2019): 6094–98. http://dx.doi.org/10.1002/ange.201901888.

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39

Chithaiah, Pallellappa, Kuppe Pramoda, Giridhar U. Kulkarni, and C. N. R. Rao. "A Simple Chemical Route to Borocarbonitride Nanotubes." European Journal of Inorganic Chemistry 2020, no. 13 (March 12, 2020): 1230–32. http://dx.doi.org/10.1002/ejic.201901362.

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40

Mori, Takao, Toshiyuki Nishimura, Walter Schnelle, Ulrich Burkhardt, and Yuri Grin. "The origin of the n-type behavior in rare earth borocarbide Y1−xB28.5C4." Dalton Trans. 43, no. 40 (2014): 15048–54. http://dx.doi.org/10.1039/c4dt01303d.

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It was revealed that boron carbide inclusions were the origin of the p-type behavior in the Seebeck coefficient α previously observed for Y1−xB28.5C4 in contrast to Y1−xB15.5CN and Y1−xB22C2N, the long awaited n-type counterparts to boron carbide. Calculations show a pseudo gap-like structure in density of states and importance of the borocarbonitride network.
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41

Bahadur, Rohan, Gurwinder Singh, Yoshio Bando, and Ajayan Vinu. "Advanced porous borocarbonitride nanoarchitectonics: Their structural designs and applications." Carbon 190 (April 2022): 142–69. http://dx.doi.org/10.1016/j.carbon.2022.01.013.

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42

Moses, K., K. Pramoda, and C. N. R. Rao. "Use of a borocarbonitride–iron pthalocyanine composite in ORR." Nanomaterials and Energy 4, no. 1 (June 2015): 3–8. http://dx.doi.org/10.1680/nme.14.00021.

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43

Jiménez-Arévalo, Nuria, Eduardo Flores, Alessio Giampietri, Marco Sbroscia, Maria Grazia Betti, Carlo Mariani, José R. Ares, Isabel J. Ferrer, and Fabrice Leardini. "Borocarbonitride Layers on Titanium Dioxide Nanoribbons for Efficient Photoelectrocatalytic Water Splitting." Materials 14, no. 19 (September 23, 2021): 5490. http://dx.doi.org/10.3390/ma14195490.

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Heterostructures formed by ultrathin borocarbonitride (BCN) layers grown on TiO2 nanoribbons were investigated as photoanodes for photoelectrochemical water splitting. TiO2 nanoribbons were obtained by thermal oxidation of TiS3 samples. Then, BCN layers were successfully grown by plasma enhanced chemical vapour deposition. The structure and the chemical composition of the starting TiS3, the TiO2 nanoribbons and the TiO2-BCN heterostructures were investigated by Raman spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy. Diffuse reflectance measurements showed a change in the gap from 0.94 eV (TiS3) to 3.3 eV (TiO2) after the thermal annealing of the starting material. Morphological characterizations, such as scanning electron microscopy and optical microscopy, show that the morphology of the samples was not affected by the change in the structure and composition. The obtained TiO2-BCN heterostructures were measured in a photoelectrochemical cell, showing an enhanced density of current under dark conditions and higher photocurrents when compared with TiO2. Finally, using electrochemical impedance spectroscopy, the flat band potential was determined to be equal in both TiO2 and TiO2-BCN samples, whereas the product of the dielectric constant and the density of donors was higher for TiO2-BCN.
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44

Wang, Shouzhi, Fukun Ma, Hehe Jiang, Yongliang Shao, Yongzhong Wu, and Xiaopeng Hao. "Band gap-Tunable Porous Borocarbonitride Nanosheets for High Energy-Density Supercapacitors." ACS Applied Materials & Interfaces 10, no. 23 (May 18, 2018): 19588–97. http://dx.doi.org/10.1021/acsami.8b02317.

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45

Wang, Guangming, Xuefei Zhang, Yao Yan, Xing Huang, and Zailai Xie. "New insight into structural transformations of borocarbonitride in oxidative dehydrogenation of propane." Applied Catalysis A: General 628 (November 2021): 118402. http://dx.doi.org/10.1016/j.apcata.2021.118402.

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46

Moses, Kota, Vankayala Kiran, S. Sampath, and C. N. R. Rao. "Few-Layer Borocarbonitride Nanosheets: Platinum-Free Catalyst for the Oxygen Reduction Reaction." Chemistry - An Asian Journal 9, no. 3 (January 27, 2014): 838–43. http://dx.doi.org/10.1002/asia.201301471.

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47

Liang, Ce, Zi-Ang Lu, Ming Zheng, Mengxin Chen, Yuanyuan Zhang, Bin Zhang, Jiaxu Zhang, and Ping Xu. "Band Structure Engineering within Two-Dimensional Borocarbonitride Nanosheets for Surface-Enhanced Raman Scattering." Nano Letters 22, no. 16 (August 15, 2022): 6590–98. http://dx.doi.org/10.1021/acs.nanolett.2c01825.

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48

Shi, Lei, Shengnan Bi, Ye Qi, Guiling Ning, and Junwei Ye. "Highly efficient metal-free borocarbonitride catalysts for electrochemical reduction of N2 to NH3." Journal of Colloid and Interface Science 641 (July 2023): 577–84. http://dx.doi.org/10.1016/j.jcis.2023.03.099.

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49

Zhang, Liangzhu, Kai Huang, Pengchao Wen, Jiemin Wang, Guoliang Yang, Dan Liu, Zifeng Lin, et al. "Tailoring the defects of two-dimensional borocarbonitride nanomesh for high energy density micro-supercapacitor." Energy Storage Materials 42 (November 2021): 430–37. http://dx.doi.org/10.1016/j.ensm.2021.07.041.

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50

Sreedhara, M. B., Manaswee Barua, Abhishek Chaturvedi, C. N. R. Rao, and Upadrasta Ramamurty. "Borocarbonitride, (BN)X(C)1-X, nanosheet-reinforced polymer nanocomposites for high mechanical performance." Carbon 140 (December 2018): 688–95. http://dx.doi.org/10.1016/j.carbon.2018.09.028.

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