Academic literature on the topic 'Borate Glass Matrices'

Theoretical calculations of mass attenuation coefficients, partial interactions, atomic cross-section, and effective atomic numbers of PbO-based silicate, borate, and phosphate glass systems have been investigated at 662 keV. PbO-based silicate glass has been found with the highest total mass attenuation coefficient and then phosphate and borate glasses, respectively. Compton scattering has been the dominate interaction contributed to the different total attenuation coefficients in each of the glass matrices. The silicate and phosphate glass systems are more appropriate choices as lead-based radiation shielding glass than the borate glass system. Moreover, comparison of results has shown that the glasses possess better shielding properties than standard shielding concretes, suggesting a smaller size requirement in addition to transparency in the visible region.

Glass samples with 3 B 2 O 3· Bi 2 O 3 and B 2 O 3· Bi 2 O 3 matrices containing up to 30 mol% Y 2 O 3 were prepared by melt fast quenching method. The effect of yttrium addition on the local order in glasses was investigated by infrared spectroscopic analysis. The results indicate that the local structure is more ordered in the glass system with higher bismuth content and the progressive addition of yttrium increases the local disorder in both bismuth-borate glass matrices.

The results presented in this communication concern visible and near-IR emission of Pr3+ ions in selected inorganic glasses, i.e., borate-based glass with Ga2O3 and BaO, lead-phosphate glass with Ga2O3, gallo-germanate glass modified by BaO/BaF2, and multicomponent fluoride glass based on InF3. Glasses present several emission bands at blue, reddish orange, and near-infrared spectral ranges, which correspond to 4f–4f electronic transitions of Pr3+. The profiles of emission bands and their relative intensity ratios depend strongly on glass-host. Visible emission of Pr3+ ions is tuned from red/orange for borate-based glass to nearly white light for multicomponent fluoride glass based on InF3. The positions and spectral linewidths for near-infrared luminescence bands at the optical telecommunication window corresponding to the 1G4 → 3H5, 1D2 → 1G4, and 3H4 → 3F3,3F4 transitions of Pr3+ are dependent on glass-host matrices and excitation wavelengths. Low-phonon fluoride glasses based on InF3 and gallo-germanate glasses with BaO/BaF2 are excellent candidates for broadband near-infrared optical amplifiers. Spectroscopic properties of Pr3+-doped glasses are compared and discussed in relation to potential optical applications.

Some bismuth-borate oxide glass' samples were prepared by the fast quenching method, where B2O3 was replaced with equal concentrations of ZnO and CaO. X-ray diffraction (XRD) was used to examine the internal structure and Fourier transform infrared (FTIR) to identify building units and bonds throughout the studied structural matrices. XRD showed that all samples have short range order structural nature, while FTIR demonstrated some of Zn2+ acted as glass network formers and all Bi3+ acted as glass. UV-visible measurements and calculations showed a decreasing in the energy band gap from 3.83 eV to 1.73 eV with decreasing B2O3 content. Also with decreasing B2O3 content, both real refractive index and metallization factor decreased from 3.1 to 1.9 and from 0.56 to 0.71, respectively. For the studied glass' samples, density and molar volume showed inverted behaviors, where the density decreased while the molar volume increases with decreasing B2O3.

Two completely different glass-host matrices containing lead, i.e. borate and germanate glasses doped with erbium were studied. Replacement of glass-former B2O3 by GeO2 in amorphous host was evidenced by optical methods. The luminescence decay from the 4I13/2 upper laser state of Er3+ ions is relatively short, whereas up-converted emission signal is reduced definitely in borate glass containing lead due to its high B-O stretching vibrations. The results indicate that germanate glasses containing lead are promising for near-infrared luminescence and up-conversion applications. Full Text: PDF ReferencesR. Balda, A. Oleaga, J. Fernandez, J.M. Fdez-Navarro, "Spectroscopy and frequency upconversion of Er3+ ions in lead niobium germanate glasses", Opt. Mater. 24, 83 (2003). CrossRef H. Yamauchi, Y. Ohishi, "Spectroscopic properties of Er3+-doped PbO?Ga2O3?GeO2 glass for optical amplifiers", Opt. Mater. 27, 679 (2005). CrossRef W.A. Pisarski, Ł. Grobelny, J. Pisarska, R. Lisiecki, W. Ryba-Romanowski, "Spectroscopic properties of Yb3+ and Er3+ ions in heavy metal glasses", J. Alloys Compd. 509, 8088 (2011). CrossRef M.B. Saisudha, J. Ramakrishna, "Effect of host glass on the optical absorption properties of Nd3+, Sm3+, and Dy3+ in lead borate glasses", Phys. Rev. B 53, 6186 (1996). CrossRef C.K. Jayasankar, V. Venkatramu, S. Surendra Babu, P. Babu, "Luminescence properties of Dy3+ ions in a variety of borate and fluoroborate glasses containing lithium, zinc, and lead", J. Alloys Compd. 374, 22 (2004). CrossRef W.A. Pisarski et al. "Luminescence spectroscopy of rare earth-doped oxychloride lead borate glasses", J. Lumin. 131, 649 (2011). CrossRef M. Kochanowicz, W. Mazerski, J. Żmojda, K. Czajkowski, D. Dorosz, "Green upconversion emission in tellurite optical fibre codoped with Yb3+/Er3+", Phot. Lett. Poland 5, 35 (2013). CrossRef J. Dorosz, "Novel constructions of optical fibers doped with rare ? earth ions", Ceramics 86 (2005). CrossRef J. Żmojda, D. Dorosz, M. Kochanowicz, J. Dorosz, "Spectroscopic properties of Yb3+/Er3+ - doped antimony-phosphate glasses for fiber amplifiers", Phot. Lett. Poland 2, 76 (2010). CrossRef J. Dorosz, R. S. Romaniuk, "Development of Optical Fiber Technology in Poland", INTL J. Electron. Telecom. 57, 191 (2011). CrossRef Q.Y. Zhang et al. "Effects of PbF2 doping on structure and spectroscopic properties of Ga2O3?GeO2?Bi2O3?PbO glasses doped with rare earths", J. Appl. Phys. 99, 033510 (2006) CrossRef W.A. Pisarski, G. Dominiak-Dzik, W. Ryba-Romanowski, J. Pisarska, "Role of PbO substitution by PbF2 on structural behavior and luminescence of rare earth-doped lead borate glass", J. Alloys Compd. 451, 220 (2008). CrossRef M. Sołtys, J. Pisarska, L. Żur, T. Goryczka, W.A. Pisarski, "Influence of M2O3 (M = Al, Ga) glass modifiers on structure, thermal and spectroscopic properties of rare earth ions in lead phosphate based systems", Proc. SPIE 9228, 92280A (2014). CrossRef J. Janek, J. Pisarska, W.A. Pisarski, "Rare earth doped lead-free germanate glasses for modern photonics", Phot. Lett. Poland 6, 71 (2014). CrossRef W.A. Pisarski et al. "Infrared-to-visible conversion luminescence of Er3+ ions in lead borate transparent glass-ceramics", Opt. Mater. 31, 1781 (2009). CrossRef J. Pisarska, L. Żur, W.A. Pisarski, "Optical spectroscopy of Dy3+ ions in heavy metal lead-based glasses and glass?ceramics", J. Mol. Struct. 993, 160 (2011). CrossRef L. Żur, M. Sołtys, J. Pisarska, W.A. Pisarski, "Absorption and luminescence properties of terbium ions in heavy metal glasses", J. Alloys Compd. 578, 512 (2013). CrossRef W.A. Pisarski, L. Żur, M. Kowal, J. Pisarska, "Enhancement and quenching photoluminescence effects for rare earth ? Doped lead bismuth gallate glasses", J. Alloys Compd. 651, 565 (2015). CrossRef M. Shojiya, Y. Kawamoto, K. Kadono, "Judd?Ofelt parameters and multiphonon relaxation of Ho3+ ions in ZnCl2-based glass", J. Appl. Phys. 89, 4944 (2001). CrossRef

Experimental EPR results of 99.5%[x B2O3 (1-x) Bi2O3]0.5%MO glass samples (MO = MnO, Fe2O3 and 0.07 ≤ x ≤ 0.8) systems are presented. The resonance absorptions are centered at g ≈ 4.3 and g ≈ 2.0. For manganese-doped samples both lines show hyperfine structure for certain values of Bi/B ratio. In addition to these lines a well defined shoulder at g ≈ 9.8 is recorded from the samples doped with iron. The changes in matrix composition, corresponding to different values of x, induce changes in the surroundings of the resonance centers. Structural data obtained from the EPR measurements indicate various sites for Mn2+ and Fe3+ ions in environments characterized by different crystalline field intensities. The EPR data also provides evidence that the redox effect of bismuth–borate matrices on the doped paramagnetic ions is a function of Bi/B ratio.

This paper presents the results of research on the luminescent properties of antimony-borate glass rods doped with europium and silver ions. The reduction of silver ions to the form of nanoparticles was carried out and the occurrence of localized plasmon resonance was demonstrated, which caused changes in the Eu3+ luminescence signal at a wavelength of 613 nm. The effect of the concentration of silver ions dopant at a constant content of europium ions on the luminescence and absorption characteristics of the produced samples was investigated. In the examined doping range, no large dependencies of spectral changes as a function of the concentration of silver ions were found. A clear quenching of the luminescence was observed due to the heating time of the doped glass matrices for the energy transition (5D0 → 7F2). Full Text: PDF ReferencesS. Kuzman, J. Perisa, V. Dordevic, I. Zekovic, I. Vukoje, Z. Antic and M. D. Dramicanin, "Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles", Materials 13, 3071 (2020). CrossRef V.P. Prakashan, M.S. Sajna, G. Gejo, M.S. Sanu, A.C. Saritha, P.R. Biju, J. Cyriac and N.V. Unnikrishan, "Surface Plasmon Assisted Luminescence Enhancement of Ag NP/NWs-Doped SiO2-TiO2-ZrO2:Eu3+ Ternary System", Plasmonics 14, 673 (2019). CrossRef O. Malta, P. Santa-Cruz, G. Sa and F. Auzel, "Fluorescence enhancement induced by the presence of small silver particles in Eu3+ doped materials", J. Lumin., 33, 261 (1985). CrossRef O. Malta, P. Santa-Cruz, G. Sa and F. Auzel, "Time evolution of the decay of the 5Do level of Eu3+ in glass materials doped with small silver particles", Chem. Phys. Lett, 116, 396 (1985). CrossRef J. Zmojda, M. Kochanowicz, P. Miluski et al., "The influence of Ag content and annealing time on structural and optical properties of SGS antimony-germanate glass doped with Er3+ ions", Journal of Molecular Structure 1160, 428 (2018). CrossRef Ki Young Kim, Plasmonics: Principles and Applications (Croatia, InTechOpen 2012) CrossRef M.R. Dousti, M.R. Sahar, S.K. Ghoshal et al., "Up-conversion enhancement in Er3 +-Ag co-doped zinc tellurite glass: Effect of heat treatment", Journal of Non-Crystalline Solids 358, 2939 (2012). CrossRef I. Soltani, S. Hraiech, K. Horchani-Naifer et al., "Effect of silver nanoparticles on spectroscopic properties of Er3+ doped phosphate glass", Optical Materials 46, 454 (2015). CrossRef R. Schneider, E.A. de Campos, J.B.S. Mendes, J.F. Felix, P.A. Santa-Cruz, "Lead–germanate glasses: an easy growth process for silver nanoparticles and their promising applications in photonics and catalysis", RSC Advances 7 (66), 41479 (2017). CrossRef

The samarium-doped lithium-gadolinium borate [60Li2O:10Gd2O3:(30-x) B2O3:xSm2O3] (LGBO:Sm3+) glasses have been melted and quenched in stainless plate under an air atmosphere. Some physical and optical properties within wavelength concerned and photoluminescence of the LGBO:Sm3+glasses were measured and discussed. The density of glasses dropped until 0.10 mol% and tends to increase after that point, while molar volume of the glasses tends to increase with concentration of Sm2O3.. In absorption spectra, there are 2 obvious peaks in UV-VIS range and 6 peaks in NIR range indicating the Sm3+in glass matrices. The sharpness of a peak, in the absorption spectra, also increases with concentration of the dopant. The 7 obvious peaks in excitation spectra represent the transitions from the ground state6H5/2to various excited states. Furthermore, The emission spectra were observed under 404 nm light from the Xenon compact arc lamps, and showed the concentration quenching effect (CQE) at 1.00 mol% of Sm3+. Additional, The lifetimes showed decreasing trend with concentration of Sm2O3.. As the result, The LGBO:Sm3+glass doped with 1.00 mol% of Sm3+gives the highest result for luminescence properties.

The design, fabrication and application of materials that are of dimension(s) in the nanoscale form the basis of nanotechnology. Nanotechnology thrives owing to the anomalous, unique or even at times, extraordinary physical properties exhibited by nanomaterials as compared to their bulk counterparts. Also, modern technological advancements in the form of miniaturized instruments and sensors facilitate the use of several forms of nanomaterials. Nanostructures are of different types – nanoparticles/crystals, nanorods and nanowires, thin films, and bulk materials comprising nanoscale structures, etc. Various techniques are employed to synthesize nanomaterials. They are categorized into two types – top-down and bottom-up approach. Top-down approach includes methods, such as milling and etching, where nanoscale dimensions are achieved by the disintegration of bulk matter. On the other hand, bottom-up approach consists of integration in the atomic scale forming clusters, followed by nucleation and growth processes to obtain nanocrystals. In this thesis a unique method, i.e., glass ceramics is used for obtaining nanostructures embedded in glass matrices. The fabrication process includes two steps – obtaining an amorphous system and inducing controlled crystallization of the desired phase(s), resulting in a composite structure of nanocrystals embedded in a continuous glass matrix. Apart from the ease and flexibility of synthesis, glass-nanocrystal composites possess uniformity and reproducibility in microstructure, with little or no porosity. The other method used to synthesize nanostructures was molten salt synthesis, which is categorized as one of the liquid phase syntheses, where a molten flux in the form of salts with a low melting point is used as a medium for the formation of the desired phase. The importance of molten-salt synthesis can be understood from the ease of synthesis and low time consumption; the technique is economical too. The thesis focusses on obtaining nanostructures of lithium tantalite (LiTaO3) and lithium niobite (LiNbO3) in glass matrices. The versatility of these two compounds in the fields of electronics and optics is multi-fold. The intriguing properties exhibited by these compounds arise from their non-centrosymmetric rhombohedral crystal structure. Ferroelectricity, pyroelectricity, piezoelectricity, non-linear optic effect and electro-optic effect are some of the many incredible properties exhibited by these materials. More emphasis will be laid on the synthesis and characterization of LiTaO3 in this thesis. Fabrication of nanostructures of lithium tantalite embedded in a glass matrix is scarce in the literature owing to the tediousness involved in the glass preparation and requires high melting temperature (1600 oC). Therefore, it was worth attempting to find an appropriate glass matrix to crystallize LiTaO3 and analyse their physical properties as a function of crystallite size and volume fraction of crystallization in order to be used in devices. Furthermore, the solid solutions of LiTaO3 and LiNbO3 crystallized in a glass matrix will be interesting from the perspective of tunability of microstructure and other properties. Whereas for nanoparticle synthesis using wet chemical methods, not many tantalum precursors are available. The commonly used tantalum precursor is tantalum ethoxide. Moreover, the synthesis of LiTaO3 nanoparticles from this precursor involves rigorous methodology. This made it even more difficult to synthesize 1-D structures of LiTaO3. Hence, employing molten-salt technique to yield LiTaO3 nanorods proved very important that can be used in several miniaturized devices. The results obtained in the research work are categorized into five chapters apart from the chapters on introduction and experimental methods. Chapter 1 constitutes a brief introduction to the phenomena associated with the piezoelectric, pyroelectric, ferroelectric and non-linear optical properties of materials with an added emphasis on the structures of lithium tantalite and lithium niobite. Principles behind the fabrication of glasses and glass–nanocrystal composites, and their structures and dielectric properties are also discussed. Chapter 2 describes in detail the various experimental techniques employed to synthesize and characterize the materials under investigation. Chapter 3 deals with the analysis of evolution of LiTaO3 nanocrystals in a borate-based glass matrix and, analyse their microstructural characteristics and pyro/ferroelectric properties as a function of heat treatment temperatures. The amorphous composites were obtained using conventional melt-quenching technique, which when heat-treated at temperatures in the range of 530–560 oC/3h yielded nanocrystals of LiTaO3 (of 18–32 nm size). In order to analyse the microstructural evolution during heat treatment, it is imperative to understand the crystallization process involved in the glass system. For that, isothermal crystallization kinetics were performed on the as-quenched glasses by invoking the Johnson–Mehul–Avrami–Kolmogorov equation. A three-dimensional growth with an Avrami exponent of 3.5 and effective activation energy for crystallization of 735 ± 65 kJ/mol was determined from the crystallization kinetics studies. The structural characteristics of the as quenched and heat-treated glasses were realized by employing ray diffraction and Raman spectra analyses. Coalesced nanocrystals forming dendritic spherulites on heat treatment of as-quenched glasses were observed using electron microscopy techniques. Byer and Roundy method was employed to determine the pyroelectric coefficient from the glass-nanocrystal composites and interestingly, the 550 oC/3h heat-treated glasses comprising ~30 nm-sized crystallites exhibit a pyroelectric coefficient as high as 15 nC/cm2K and a remnant polarization, Pr, in the order of 0.42 μC/cm2. Chapter 4 presents the lithium ion conduction in LiTaO3-based glass–nanocrystal composites. Lithium tantalite in single-crystalline and coarse-grained configurations is a poor ionic conductor and does not qualify as a solid electrolyte for lithium-based batteries. In this chapter, ionic conductivity was sought to be enhanced by use of nanocrystals of LiTaO3 embedded in a borate-based glass matrix. Heat treatment of the as-quenched glasses of composition 3Li2O–4B2O3–Ta2O5 yielded coalesced LiTaO3 nanocrystals of 18–32 nm size, forming dendritic structures in the glass matrix. Impedance analyses of the as quenched and heat-treated glasses show a dramatic improvement in dc conductivity (σdc), with a maximum around 3×10–3 S/m at 200 Oc (σdcT = 1.5 S m–1 K) and activation energy of 0.54 eV for 530 oC/3h heat-treated glasses. The values of σdc of the as-quenched glasses and of the 530 and 540 oC/3h heat-treated glasses are about seven orders of magnitude higher than that of single crystalline LiTaO3. Furthermore, the effect of heat treatment on lithium ion dynamics in the 40–200 oC temperature range was investigated by modulus formalism, invoking the stretched exponential Kohlrausch–Williams–Watts function. The stretched exponential function was found to be temperature dependent for all the samples under investigation. The activation energies determined from the modulus formalism matched that of impedance analysis.7Li magic angle spinning NMR was used to investigate lithium self-diffusion in the nanostructured glass-nanocrystal composites as a function of temperature between – 10 and 60 oC. Chapter 5 comprises the synthesis of nanocrystals of LiNbxTa1–xO3 (where x = 0.0, 0.25, 0.5, 0.75 and 1.0) embedded in a borate glass matrix, and their microstructure and nonlinear optical properties. The solid solution of LiTaO3 and LiNbO3 presents an opportunity to tune various physical properties. The glasses of 1.5Li2O–2B2O3–xNb2O5– (1–x) Ta2O5 system were fabricated by conventional melt-quenching technique where the precursors were melted in the 1200–1300 oC temperature region. Heat treatment of the as quenched glasses was performed in the 530–560 oC (with a dwelling period of 3h) temperature range to induce Nano crystallization. Rietveld refinement of XRD patterns and Raman spectral analysis of the glass–nanocrystal composites confirm the formation of solid solutions of LiTaO3 and LiNbO3. The sizes of the crystallites evolved during heat treatment were determined using Williamson-Hall plot and are in the range 19–37 nm (for x = 0–0.75) and 23–45 nm (for x = 1.00). Electron microscopic studies confirm a transformation of the morphology of the Nano-crystallites from dendritic star-shaped spherulites for x = 0 to rod-shaped structures for x = 1.00, brought about by a coalescence of crystallites. Broad Maker-fringe patterns (recorded at 532 nm) were obtained by subjecting heat-treated glass plates to 1064 nm fundamental radiation. An effective second order non-linear optical coefficient (deff) of 0.45 pm/V, which is nearly 1.2 times the d36 of KDP single crystal, is obtained from the heat-treated glasses of the composition x = 0.50 comprising 37 nm sized crystallites. The improved efficiency in x = 0.50 is correlated with the spherulitic microstructure obtained from the heat treatment. Chapter 6 depicts the non-linear optical properties and photoluminescence exhibited by Pr-doped LiNb0.5Ta0.5O3 nanocrystals embedded in a borate-based glass. Glasses of composition 1.5Li2O–2B2O3–0.5Nb2O5–0. 5Ta2O5:xPr6O11 (x = 0.0025, 0.005 and 0.010) were synthesized by the conventional melt-quenching technique. Nanocrystal growth was induced by subjecting the as-quenched glasses to heat treatment between 530 and 560oC. Coalesced nanocrystals of sizes in the 20–38 nm range were obtained, which resulted in the formation of dendritic spherulites. Raman studies indicate that Pr3+ ions occupy Li+ vacancies or Nb/Ta andesites. A strong red emission at 620 nm, due to 1D2 → 3H4 electronic transition of Pr3+ ions, was observed upon excitation by a 450 nm radiation. The maximum intensity of red emission was exhibited by the composition with a Pr doping level of 0.005. The second harmonic generation emanating from the glass nanocrystal composites were recorded as a function of crystallite size and composition. The non-linear optical coefficient as high as 0.77 pm/V (twice that of d36 of KDP single crystal) was obtained from the bulk glass–nanocrystal composites with x = 0.0025 comprising 33 nm sized crystallites. Chapter 7 illustrates the synthesis of single-crystalline LiTaO3 nanorods (of average length 3 μm and width 300 nm) by a facile, yet rapid, molten-salt reaction. In addition to synthesis, the piezoelectric response and second harmonic generation from the nanorods are presented. Potassium chloride (KCl) was used as the flux and heat treatment of the mixture of precursors was performed at 850 oC over a period of 15 minutes. The X-ray diffraction and Raman spectral studies confirm the formation of LiTaO3 phase along with a minor impurity phase (K0.73Li0.27TaO3). The effect of heating rate and concentration of KCl on the yield of nanorods was also investigated. The piezoelectric coefficient of an individual nanorod was determined to be around 8 pm/V, using piezo-force microscopy. The second harmonic emission at 532 nm was recorded as a function of incident intensity (at 1064 nm) in a reflection mode. There was a significant enhancement in second harmonic intensity emanating from the nanorods as compared to the cubic-shaped crystallites of LiTaO3.