Journal articles on the topic 'Biopolymers'

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1

Arrieta, Alvaro A., Yamid Nuñez de la Rosa, and Manuel Palencia. "Electrochemistry Study of Bio-Based Composite Biopolymer Electrolyte—Starch/Cardol." Polymers 15, no. 9 (April 23, 2023): 1994. http://dx.doi.org/10.3390/polym15091994.

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The environmental problems generated by pollution due to polymers of petrochemical origin have led to the search for eco-friendly alternatives such as the development of biopolymers or bio-based polymers. The aim of this work was to evaluate the electrochemical behavior of a biopolymer composite made from cassava starch and cardol extracted from cashew nut shell liquid. The biopolymers were prepared using the thermochemical method, varying the synthesis pH and the cardol amounts. The biopolymers were synthesized in the form of films and characterized by cyclic voltamperometry and electrochemical impedance spectroscopy. The biopolymers showed a rich electroactivity, with three oxidation–reduction processes evidenced in the voltamperograms. On the other hand, the equivalent circuit corresponding to the impedance behavior of biopolymers integrated the processes of electron transfer resistance, electric double layer, redox reaction process, and resistance of the biopolymeric matrix. The results allowed us to conclude that the cardol content and the synthesis pH were factors that affect the electrochemical behavior of biopolymer composite films. Electrochemical processes in biopolymers were reversible and involved two-electron transfer and were diffusion-controlled processes.
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2

Shamshina, Julia L., and Paula Berton. "Ionic Liquids as Designed, Multi-Functional Plasticizers for Biodegradable Polymeric Materials: A Mini-Review." International Journal of Molecular Sciences 25, no. 3 (January 31, 2024): 1720. http://dx.doi.org/10.3390/ijms25031720.

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Measures to endorse the adoption of eco-friendly biodegradable plastics as a response to the scale of plastic pollution has created a demand for innovative products from materials from Nature. Ionic liquids (ILs) have the ability to disrupt the hydrogen bonding network of biopolymers, increase the mobility of biopolymer chains, reduce friction, and produce materials with various morphologies and mechanical properties. Due to these qualities, ILs are considered ideal for plasticizing biopolymers, enabling them to meet a wide range of specifications for biopolymeric materials. This mini-review discusses the effect of different IL-plasticizers on the processing, tensile strength, and elasticity of materials made from various biopolymers (e.g., starch, chitosan, alginate, cellulose), and specifically covers IL-plasticized packaging materials and materials for biomedical and electrochemical applications. Furthermore, challenges (cost, scale, and eco-friendliness) and future research directions in IL-based plasticizers for biopolymers are discussed.
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Băbuțan, Mihai, and Ioan Botiz. "Morphological Characteristics of Biopolymer Thin Films Swollen-Rich in Solvent Vapors." Biomimetics 9, no. 7 (June 30, 2024): 396. http://dx.doi.org/10.3390/biomimetics9070396.

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Biopolymers exhibit a large variety of attractive properties including biocompatibility, flexibility, gelation ability, and low cost. Therefore, especially in more recent years, they have become highly suitable for a wider and wider range of applications stretching across several key sectors such as those related to food packaging, pharmaceutic, and medical industries, just to name a few. Moreover, biopolymers’ properties are known to be strongly dependent on the molecular arrangements adopted by such chains at the nanoscale and microscale. Fortunately, these arrangements can be altered and eventually optimized through a plethora of more or less efficient polymer processing methods. Here, we used a space-confined solvent vapor annealing (C-SVA) method to subject various biopolymers to rich swelling in solvent vapors in order to favor their further crystallization or self-assembly, with the final aim of obtaining thin biopolymer films exhibiting more ordered chain conformations. The results obtained by atomic force microscopy revealed that while the gelatin biopolymer nucleated and then crystallized into granular compact structures, other biopolymers preferred to self-assemble into (curved) lamellar rows composed of spherical nanoparticles (glycogen and chitosan) or into more complex helix-resembling morphologies (phytagel). The capability of the C-SVA processing method to favor crystallization and to induce self-assembly in various biopolymeric species or even monomeric units further emphasizes its great potential in the future structuring of a variety of biological (macro)molecules.
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4

Fatehi, Hadi, Dominic E. L. Ong, Jimmy Yu, and Ilhan Chang. "Biopolymers as Green Binders for Soil Improvement in Geotechnical Applications: A Review." Geosciences 11, no. 7 (July 15, 2021): 291. http://dx.doi.org/10.3390/geosciences11070291.

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Soil improvement using biopolymers has attracted considerable attention in recent years, with the aim to reduce the harmful environmental effects of traditional materials, such as cement. This paper aims to provide a review on the environmental assessment of using biopolymers as binders in soil improvement, biopolymer-treated soil characteristics, as well as the most important factors affecting the behavior of the treated soil. In more detail, environmental benefits and concerns about the use of biopolymers in soil improvement as well as biopolymer–soil interaction are discussed. Various geotechnical properties are evaluated and compared, including the unconfined compressive strength, shear strength, erosion resistance, physical properties, and durability of biopolymer-treated soils. The influential factors and soil and environmental conditions affecting various geotechnical characteristics of biopolymer-treated soils are also discussed. These factors include biopolymer concentration in the biopolymer–soil mixture, moisture condition, temperature, and dehydration time. Potential opportunities for biopolymers in geotechnical engineering and the challenges are also presented.
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5

Unger, Scott R., Troy A. Hottle, Shakira R. Hobbs, Cassandra L. Thiel, Nicole Campion, Melissa M. Bilec, and Amy E. Landis. "Do single-use medical devices containing biopolymers reduce the environmental impacts of surgical procedures compared with their plastic equivalents?" Journal of Health Services Research & Policy 22, no. 4 (May 22, 2017): 218–25. http://dx.doi.org/10.1177/1355819617705683.

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Background While petroleum-based plastics are extensively used in health care, recent developments in biopolymer manufacturing have created new opportunities for increased integration of biopolymers into medical products, devices and services. This study compared the environmental impacts of single-use disposable devices with increased biopolymer content versus typically manufactured devices in hysterectomy. Methods A comparative life cycle assessment of single-use disposable medical products containing plastic(s) versus the same single-use medical devices with biopolymers substituted for plastic(s) at Magee-Women’s Hospital (Magee) in Pittsburgh, PA and the products used in four types of hysterectomies that contained plastics potentially suitable for biopolymer substitution. Magee is a 360-bed teaching hospital, which performs approximately 1400 hysterectomies annually. Results There are life cycle environmental impact tradeoffs when substituting biopolymers for petroplastics in procedures such as hysterectomies. The substitution of biopolymers for petroleum-based plastics increased smog-related impacts by approximately 900% for laparoscopic and robotic hysterectomies, and increased ozone depletion-related impacts by approximately 125% for laparoscopic and robotic hysterectomies. Conversely, biopolymers reduced life cycle human health impacts, acidification and cumulative energy demand for the four hysterectomy procedures. The integration of biopolymers into medical products is correlated with reductions in carcinogenic impacts, non-carcinogenic impacts and respiratory effects. However, the significant agricultural inputs associated with manufacturing biopolymers exacerbate environmental impacts of products and devices made using biopolymers. Conclusions The integration of biopolymers into medical products is correlated with reductions in carcinogenic impacts, non-carcinogenic impacts and respiratory effects; however, the significant agricultural inputs associated with manufacturing biopolymers exacerbate environmental impacts.
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6

Frølund, B., K. Keiding, and P. H. Nielsen. "A Comparative Study of Biopolymers from a Conventional and an Advanced Activated Sludge Treatment Plant." Water Science and Technology 29, no. 7 (April 1, 1994): 137–41. http://dx.doi.org/10.2166/wst.1994.0326.

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Biopolymer characteristics from a traditional and an advanced activated sludge treatment plant performing biological N and P removal were compared. The biopolymers were extracted using an ion exchange resin (DOWEX in Na-form). Differences between chemical compositions of the total sludges were observed by measuring protein, polysaccharide and uronic acids whereas differences in the same compounds were not found in the extracted biopolymers. High Pressure Size Exclusion Chromatography was performed on the two biopolymer matrixes and differences were found in the biopolymer matrixes. Biopolymers from the advanced treatment plant contained two fractions of large and hydrophobic compounds which contributed to a major fraction of the chromatogram area. These peaks could only to a minor extent be found in the extracted biopolymers from the traditional treatment plant.
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7

Preiss, Laura C., Katharina Landfester, and Rafael Muñoz-Espí. "Biopolymer colloids for controlling and templating inorganic synthesis." Beilstein Journal of Nanotechnology 5 (November 17, 2014): 2129–38. http://dx.doi.org/10.3762/bjnano.5.222.

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Biopolymers and biopolymer colloids can act as controlling agents and templates not only in many processes in nature, but also in a wide range of synthetic approaches. Inorganic materials can be either synthesized ex situ and later incorporated into a biopolymer structuring matrix or grown in situ in the presence of biopolymers. In this review, we focus mainly on the latter case and distinguish between the following possibilities: (i) biopolymers as controlling agents of nucleation and growth of inorganic materials; (ii) biopolymers as supports, either as molecular supports or as carrier particles acting as cores of core–shell structures; and (iii) so-called “soft templates”, which include on one hand stabilized droplets, micelles, and vesicles, and on the other hand continuous scaffolds generated by gelling biopolymers.
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8

Lemboye, Kehinde, and Abdullah Almajed. "Effect of Varying Curing Conditions on the Strength of Biopolymer Modified Sand." Polymers 15, no. 7 (March 28, 2023): 1678. http://dx.doi.org/10.3390/polym15071678.

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Recently, the improvement of the engineering properties of soil has been centered on using sustainable and eco-friendly materials. This study investigates the efficacy of three biopolymers: Acacia, sodium alginate, and pectin, on the unconfined compressive strength (UCS) of dune sand. The UCS test measured the effects of the biopolymer type and concentration, curing intervals and temperature, and moisture loss. The changes in the morphology caused by the biopolymer addition were examined via scanning electron microscopy (SEM). Results indicate that the UCS of the biopolymer-modified sand increased with biopolymer concentration and curing intervals. Varying the curing temperature from 25–110 °C, slightly affected the strength of the acacia-modified sand specimen, increased that of the sodium alginate-modified sand specimen up to a temperature of 85 °C, and continued to decrease that of the pectin-modified sand specimen as the temperature was increased from 25 to 110 °C. The SEM images indicated that the biopolymer’s presence within the sand pores significantly contributed to the strength. Bond decomposition occurs at temperatures greater than 110 °C for sodium alginate and pectin-modified sands, whereas bonds remain stable at higher temperatures for the acacia-modified sand. In conclusion, all three biopolymers show potential as robust and economic dune stabilisers.
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9

Arrieta, Alvaro Angel, Jorge Alberto Ducuara, and Enrique Miguel Combatt. "Valorization of cashew nut processing by-product: development of a cardol/starch biopolymer composite with electrochemical properties and technological potential." Eastern-European Journal of Enterprise Technologies 3, no. 6 (123) (June 30, 2023): 32–41. http://dx.doi.org/10.15587/1729-4061.2023.282208.

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The problem of food agro-industry residues represents a growing concern in our society, therefore its use as a raw material to obtain biopolymers of technological interest is an attractive alternative. The objective of this work was to assess the viability of utilizing cardol, derived from cashew nut shell liquid, in the production of a biopolymer composite by combining it with cassava starch. The biopolymer composite was prepared by thermochemical method using different cardol concentrations and varying the synthesis pH. The results allowed us to demonstrate the formation of cardol/starch biopolymeric films. The infrared spectra showed possible interactions by hydrogen bonds between the cardol and the glucose units of the starch. The impedance behavior showed a similar conduction mechanism in all cases, allowing the establishment of a single equivalent circuit. The electrochemical parameters showed that the presence of cardol and the lower pH increased the values of the electrical resistance and the double layer capacitance in the biopolymers. In addition, the values of the CPE/Rre system, related to the electractivity, were not affected by the pH, but by the presence of cardol. The biodegradability tests showed a complete decomposition of the biopolymer composite films in three stages in a period of 17 to 19 days. It could be concluded that it is possible to use the cardol extracted from the cashew nut shell liquid to elaborate a biopolymer composite with electrochemical properties when combined with cassava starch. The electrical properties of the biopolymer can be modulated by varying the synthesis pH and the amount of cardol used. The composite cardol/starch biopolymer could be used as a biopolymeric solid electrolyte in the manufacture of batteries, capacitors, etc
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10

Kumar, M. Ashok, Arif Ali Baig Moghal, Kopparthi Venkata Vydehi, and Abdullah Almajed. "Embodied Energy in the Production of Guar and Xanthan Biopolymers and Their Cross-Linking Effect in Enhancing the Geotechnical Properties of Cohesive Soil." Buildings 13, no. 9 (September 10, 2023): 2304. http://dx.doi.org/10.3390/buildings13092304.

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Traditional soil stabilization techniques, such as cement and lime, are known for their menacing effect on the environment through heavy carbon emissions. Sustainable soil stabilization methods are grabbing attention, and the utilization of biopolymers is surely one among them. Recent studies proved the efficiency of biopolymers in enhancing the geotechnical properties to meet the requirements of the construction industry. The suitability of biopolymer application in different soils is still unexplored, and the carbon footprint analysis (CFA) of biopolymers is crucial in promoting the biopolymers as a promising sustainable soil stabilization method. This study attempts to investigate the out-turn of cross-linked biopolymer on soils exhibiting different plasticity characteristics (Medium & High compressibility) and to determine the Embodied carbon factor (ECF) for the selected biopolymers. Guar (G) and Xanthan (X) biopolymers were cross-linked at different proportions to enhance the geotechnical properties of soils. Atterberg’s limits, Compaction characteristics, and Unconfined Compressive Strength were chosen as performance indicators, and their values were analyzed at different combinations of biopolymers before and after cross-linking. The test results have shown that Atterberg’s limits of the soils increased with the addition of biopolymers, and it is attributed to the formation of hydrogels in the soil matrix. Compaction test results reveal that the Optimum Moisture Content (OMC) of biopolymer-modified soil increased, and Maximum Dry Density (MDD) reduced due to the resistance offered by hydrogel against compaction effort. Soils amended with biopolymers and cured for 14, 28, and 60 days have shown an appreciable improvement in Unconfined Compressive Strength (UCS) results. Microlevel analysis was carried out using SEM (Scanning Electron Microscopy) and FTIR (Fourier-transform infrared spectroscopy) to formulate the mechanism responsible for the alteration in targeted performance indicators due to the cross-linking of biopolymers in the soil. The embodied energy in the production of both Guar and Xanthan biopolymers was calculated, and the obtained ECF values were 0.087 and 1.67, respectively.
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11

Cigala, Rosalia Maria, Giovanna De Luca, Ileana Ielo, and Francesco Crea. "Biopolymeric Nanocomposites for CO2 Capture." Polymers 16, no. 8 (April 11, 2024): 1063. http://dx.doi.org/10.3390/polym16081063.

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Carbon dioxide (CO2) impacts the greenhouse effect significantly and results in global warming, prompting urgent attention to climate change concerns. In response, CO2 capture has emerged as a crucial process to capture carbon produced in industrial and power processes before its release into the atmosphere. The main aim of CO2 capture is to mitigate the emissions of greenhouse gas and reduce the anthropogenic impact on climate change. Biopolymer nanocomposites offer a promising avenue for CO2 capture due to their renewable nature. These composites consist of biopolymers derived from biological sources and nanofillers like nanoparticles and nanotubes, enhancing the properties of the composite. Various biopolymers like chitosan, cellulose, carrageenan, and others, possessing unique functional groups, can interact with CO2 molecules. Nanofillers are incorporated to improve mechanical, thermal, and sorption properties, with materials such as graphene, carbon nanotubes, and metallic nanoparticles enhancing surface area and porosity. The CO2 capture mechanism within biopolymer nanocomposites involves physical absorption, chemisorption, and physisorption, driven by functional groups like amino and hydroxyl groups in the biopolymer matrix. The integration of nanofillers further boosts CO2 adsorption capacity by increasing surface area and porosity. Numerous advanced materials, including biopolymeric derivatives like cellulose, alginate, and chitosan, are developed for CO2 capture technology, offering accessibility and cost-effectiveness. This semi-systematic literature review focuses on recent studies involving biopolymer-based materials for CO2 capture, providing an overview of composite materials enriched with nanomaterials, specifically based on cellulose, alginate, chitosan, and carrageenan; the choice of these biopolymers is dictated by the lack of a literature perspective focused on a currently relevant topic such as these biorenewable resources in the framework of carbon capture. The production and efficacy of biopolymer-based adsorbents and membranes are examined, shedding light on potential trends in global CO2 capture technology enhancement.
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12

Aslam Khan, Muhammad Umar, Saiful Izwan Abd Razak, Wafa Shamsan Al Arjan, Samina Nazir, T. Joseph Sahaya Anand, Hassan Mehboob, and Rashid Amin. "Recent Advances in Biopolymeric Composite Materials for Tissue Engineering and Regenerative Medicines: A Review." Molecules 26, no. 3 (January 25, 2021): 619. http://dx.doi.org/10.3390/molecules26030619.

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The polymeric composite material with desirable features can be gained by selecting suitable biopolymers with selected additives to get polymer-filler interaction. Several parameters can be modified according to the design requirements, such as chemical structure, degradation kinetics, and biopolymer composites’ mechanical properties. The interfacial interactions between the biopolymer and the nanofiller have substantial control over biopolymer composites’ mechanical characteristics. This review focuses on different applications of biopolymeric composites in controlled drug release, tissue engineering, and wound healing with considerable properties. The biopolymeric composite materials are required with advanced and multifunctional properties in the biomedical field and regenerative medicines with a complete analysis of routine biomaterials with enhanced biomedical engineering characteristics. Several studies in the literature on tissue engineering, drug delivery, and wound dressing have been mentioned. These results need to be reviewed for possible development and analysis, which makes an essential study.
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MAAN, SHEETAL, ANUSHREE JATRANA, VINAY KUMAR, MEENA SINDHU, and SANCHIT MONDAL. "Chlorpyrifos Release Kinetics from Citric Acid Crosslinked Biopolymeric Nanoparticles: A Sustainable Approach." Asian Journal of Chemistry 35, no. 11 (October 31, 2023): 2822–28. http://dx.doi.org/10.14233/ajchem.2023.30755.

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Biopolymer based nanoformulation was synthesized by using microwave assisted nano-precipitaion method. The biopolymers consist of chitosan and guar gum were crosslinked using citric acid in order to encapsulate chlorpyrifos pesticide. The successful synthesis of chlorpyrifos containing nano-formulations was thoroughly examined, where the surface morphology examined by using field emission scanning electron microscopy (FE-SEM) has established the loading of chlorpyrifos in the biopolymeric matrix, transmission electron microscopy (TEM) examination revealed the spherical shaped particles of about 234 nm and Fourier-transform infrared spectroscopy (FTIR) analysis has confirmed the crosslinking between two biopolymers through citric acid due to the presence of peaks corresponding to ester linkages at 1730 cm-1. The encapsulation efficiency of chlorpyrifos at pH 7 and 30 ºC was around 50%. The successfully synthesized chlorpyrifos loaded biopolymeric nano-formulation were further utilized to study the release behaviour of chlorpyrifos in water and biocompatibility towards soil microbiota. The release of chlorpyrifos was almost 15% slower than conventional chlorpyrifos and the formulation was found biocompatible towards microbiota.
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14

Ramadhan, Romal, Muslim Abdurahman, and Falan Srisuriyachai. "Sensitivity Analysis Comparisson of Synthetic Polymer and Biopolymer using Reservoir Simulation." Scientific Contributions Oil and Gas 43, no. 3 (December 31, 2020): 143–52. http://dx.doi.org/10.29017/scog.43.3.516.

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With a simultaneous increasing demand for oil and large decreases worldwide in newly discovered oil reserves in the past few decades, much attention has been paid to more effi cient production approaches such as enhanced-oil-recovery (EOR) methods for developing oil and gas from existing reservoirs (Li et al., 2014). Basically, there are two types of polymers; biopolymers and synthetic polymers (Cenk et al., 2017). Method used for this study is reservoir simulation by Computer Modeling Group (CMG) STARS simulator. The study concerns to investigate and analyze the polymer sensitivity on two diff erent types of polymer: synthetic polymer and biopolymer. The simulation is done on 15x15x4 grid for 3653 days (10 years). The simulation indicates that the biopolymer injection shows more stable result in compare to synthetic polymer. The biopolymer’s adsorption occurs on smaller area and takes longer time. Conversely, the adsorption of synthetic polymer goes on bigger area of the reservoir and transpire on shorter time. Considering these facts, the use of biopolymers is more eff ective in order to increase the sweep effi ciency by reducing viscous fi ngering of chemical injection in reservoir.
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Avila, Luisa Bataglin, Carlos Schnorr, Luis F. O. Silva, Marcilio Machado Morais, Caroline Costa Moraes, Gabriela Silveira da Rosa, Guilherme L. Dotto, Éder C. Lima, and Mu Naushad. "Trends in Bioactive Multilayer Films: Perspectives in the Use of Polysaccharides, Proteins, and Carbohydrates with Natural Additives for Application in Food Packaging." Foods 12, no. 8 (April 19, 2023): 1692. http://dx.doi.org/10.3390/foods12081692.

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The harmful effects on the environment caused by the indiscriminate use of synthetic plastics and the inadequate management of post-consumer waste have given rise to efforts to redirect this consumption to bio-based economic models. In this sense, using biopolymers to produce materials is a reality for food packaging companies searching for technologies that allow these materials to compete with those from synthetic sources. This review paper focused on the recent trends in multilayer films with the perspective of using biopolymers and natural additives for application in food packaging. Firstly, the recent developments in the area were presented concisely. Then, the main biopolymers used (gelatin, chitosan, zein, polylactic acid) and main methods for multilayer film preparation were discussed, including the layer-by-layer, casting, compression, extrusion, and electrospinning methods. Furthermore, we highlighted the bioactive compounds and how they are inserted in the multilayer systems to form active biopolymeric food packaging. Furthermore, the advantages and drawbacks of multilayer packaging development are also discussed. Finally, the main trends and challenges in using multilayer systems are presented. Therefore, this review aims to bring updated information in an innovative approach to current research on food packaging materials, focusing on sustainable resources such as biopolymers and natural additives. In addition, it proposes viable production routes for improving the market competitiveness of biopolymer materials against synthetic materials.
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Perera, Kalpani Y., Amit K. Jaiswal, and Swarna Jaiswal. "Biopolymer-Based Sustainable Food Packaging Materials: Challenges, Solutions, and Applications." Foods 12, no. 12 (June 20, 2023): 2422. http://dx.doi.org/10.3390/foods12122422.

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Biopolymer-based packaging materials have become of greater interest to the world due to their biodegradability, renewability, and biocompatibility. In recent years, numerous biopolymers—such as starch, chitosan, carrageenan, polylactic acid, etc.—have been investigated for their potential application in food packaging. Reinforcement agents such as nanofillers and active agents improve the properties of the biopolymers, making them suitable for active and intelligent packaging. Some of the packaging materials, e.g., cellulose, starch, polylactic acid, and polybutylene adipate terephthalate, are currently used in the packaging industry. The trend of using biopolymers in the packaging industry has increased immensely; therefore, many legislations have been approved by various organizations. This review article describes various challenges and possible solutions associated with food packaging materials. It covers a wide range of biopolymers used in food packaging and the limitations of using them in their pure form. Finally, a SWOT analysis is presented for biopolymers, and the future trends are discussed. Biopolymers are eco-friendly, biodegradable, nontoxic, renewable, and biocompatible alternatives to synthetic packaging materials. Research shows that biopolymer-based packaging materials are of great essence in combined form, and further studies are needed for them to be used as an alternative packaging material.
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Soldo, Antonio, and Marta Miletic. "Durability against Wetting-Drying Cycles of Sustainable Biopolymer-Treated Soil." Polymers 14, no. 19 (October 10, 2022): 4247. http://dx.doi.org/10.3390/polym14194247.

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The world today is more oriented towards sustainable and environmental-friendly solutions in every field of science, technology, and engineering. Therefore, novel sustainable and eco-friendly approaches for soil improvement have also emerged. One of the effective, promising, and green solutions is the utilization of biopolymers. However, even though the biopolymers proved to be effective in enhancing the soil-mechanical properties, it is still unknown how they behave under real environmental conditions, such as fluctuating temperatures, moisture, plants, microorganisms, to name a few. The main research aim is to investigate the durability of biopolymer-improved soil on the cyclic processes of wetting and drying. Two types of biopolymers (Xanthan Gum and Guar Gum), and two types of soils (clean sand and silty sand) were investigated in this study. The results indicated that some biopolymer-amended specimens kept more than 70% of their original mass during wetting-drying cycles. During the compressive strength analysis, some biopolymer-treated specimens kept up to 45% of their initial strength during seven wetting-drying cycles. Furthermore, this study showed that certain damaged soil-biopolymer bonds could be restored with proper treatment. Repeating the process of wetting and drying can reactivate the bonding properties of biopolymers, which amends the broken bonds in soil. The regenerative property of biopolymers is an important feature that should not be neglected. It gives a clearer picture of the biopolymer utilization and makes it a good option for rapid temporary construction or long-standing construction in the areas with an arid climate.
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Coelho, Natacha, Alexandra Filipe, Bruno Medronho, Solange Magalhães, Carla Vitorino, Luís Alves, Sandra Gonçalves, and Anabela Romano. "Rheological and Microstructural Features of Plant Culture Media Doped with Biopolymers: Influence on the Growth and Physiological Responses of In Vitro-Grown Shoots of Thymus lotocephalus." Polysaccharides 2, no. 2 (June 17, 2021): 538–53. http://dx.doi.org/10.3390/polysaccharides2020032.

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In vitro culture is an important biotechnological tool in plant research and an appropriate culture media is a key for a successful plant development under in vitro conditions. The use of natural compounds to improve culture media has been growing and biopolymers are interesting alternatives to synthetic compounds due to their low toxicity, biodegradability, renewability, and availability. In the present study, different culture media containing one biopolymer (chitosan, gum arabic) or a biopolymer derivative [hydroxyethyl cellulose (HEC), carboxymethyl cellulose (CMC)], at 100 or 1000 mg L−1, were tested regarding their influence on the growth and physiological responses of Thymus lotocephalus in vitro culture. Cellulose-based biopolymers (HEC and CMC) and gum arabic were used for the first time in plant culture media. The results showed that CMC at 100 mg L−1 significantly improved shoot elongation while chitosan, at the highest concentration, was detrimental to T. lotocephalus. Concerning only the evaluated physiological parameters, all tested biopolymers and biopolymer derivatives are safe to plants as there was no evidence of stress-induced changes on T. lotocephalus. The rheological and microstructural features of the culture media were assessed to understand how the biopolymers and biopolymer derivatives added to the culture medium could influence shoot growth. As expected, all media presented a gel-like behaviour with minor differences in the complex viscosity at the beginning of the culture period. Most media showed increased viscosity overtime. The surface area increased with the addition of biopolymers and biopolymer derivatives to the culture media and the average pore size was considerably lower for CMC at 100 mg L−1. The smaller pores of this medium might be related to a more efficient nutrients and water uptake by T. lotocephalus shoots, leading to a significant improvement in shoot elongation. In short, this study demonstrated that the different types of biopolymers and biopolymer derivatives added to culture medium can modify their microstructure and at the right concentrations, are harmless to T. lotocephalus shoots growing in vitro, and that CMC improves shoot length.
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Ikumapayi, Omolayo M., Opeyeolu T. Laseinde, Adedayo S. Adebayo, Jesutoni R. Oluwafemi, Temitayo S. Ogedengbe, Stephen A. Akinlabi, and Esther T. Akinlabi. "An Overview on recent trends in Biopolymer Base Composites for Tissue Regeneration." E3S Web of Conferences 391 (2023): 01085. http://dx.doi.org/10.1051/e3sconf/202339101085.

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This paper focused on the short review of biopolymer based composite for tissue regeneration. Biopolymers have been slowly introduced into medical applications as a result of their ability to be bio-degradable and to be easily made. By selecting the appropriate biopolymer containing the selected additives to facilitate the polymer-filler interaction, composites with the desired properties can be obtained. Interfacial interactions between biopolymers, and thus Nano-fillers, significantly control the mechanical properties of biopolymer composites and these biopolymer composites such as bone, cartilage, vascular implants, and others.
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Zhang, Junran, and Jiahao Liu. "A Review on Soils Treated with Biopolymers Based on Unsaturated Soil Theory." Polymers 15, no. 22 (November 16, 2023): 4431. http://dx.doi.org/10.3390/polym15224431.

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Adding different materials to soil can improve its engineering properties, but traditional materials such as cement, lime, fly ash, etc., have caused pollution to the environment. Recently, biopolymers have shown many advantages, such as economy and environmental protection, which make them applicable to geotechnical engineering. This study summarizes the effects of biopolymers on soil’s engineering properties and the main directions of current research. Firstly, the advantages and disadvantages of a variety of widely used biopolymer materials and their effects on the specific engineering characteristics of soil (i.e., water retention characteristics, strength characteristics, permeability characteristics, microstructure) are introduced, as well as the source, viscosity, pH, and cost of these biopolymers. Then, based on the theory of unsaturated soil, the current research progress on the water retention characteristics of improved soil is summarized. The key factors affecting the strength of biopolymer-treated soil are introduced. Due to the actual environmental conditions, such as rainfall, the permeability and durability of biopolymer-treated soil are also worthy of attention. In summary, it is necessary to study the variation laws of the engineering properties of biopolymer-treated soil in the full suction range, and to predict such laws reasonably. The relevant results are conducive to the safer and more scientific application of biopolymers in geotechnical engineering practice.
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Soni, Prof Dharini Kunal. "Biopolymers." Indian Journal of Applied Research 1, no. 12 (October 1, 2011): 72–73. http://dx.doi.org/10.15373/2249555x/sep2012/25.

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Berton, Paula, and Julia L. Shamshina. "Ionic Liquids as Tools to Incorporate Pharmaceutical Ingredients into Biopolymer-Based Drug Delivery Systems." Pharmaceuticals 16, no. 2 (February 11, 2023): 272. http://dx.doi.org/10.3390/ph16020272.

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This mini-review focuses on the various roles that ionic liquids play in the development and applications of biopolymer-based drug delivery systems (DDSs). Biopolymers are particularly attractive as drug delivery matrices due to their biocompatibility, low immunogenicity, biodegradability, and strength, whereas ILs can assist the formation of drug delivery carriers as 1. dopants to control drug release rate; 2. anchoring agents to incorporate APIs into biopolymeric materials; 3. actives (in the form of API-ILs) for controlled release; or 4. a matrix preparation media.
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Nazrun, Touha, Md Kamrul Hassan, Md Delwar Hossain, Bulbul Ahmed, Md Rayhan Hasnat, and Swapan Saha. "Application of Biopolymers as Sustainable Cladding Materials: A Review." Sustainability 16, no. 1 (December 19, 2023): 27. http://dx.doi.org/10.3390/su16010027.

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The application of biopolymer materials in cladding presents a promising avenue for enhancing building sustainability, while addressing the limitations of conventional synthetic polymers. Cladding serves a dual purpose of protection and aesthetics for buildings, but increasing global energy consumption and environmental concerns necessitate the adoption of sustainable practices. The construction sector’s substantial energy usage and greenhouse gas emissions highlight the urgent need for sustainable building materials. Conventional cladding materials often lack sustainability and environmental compatibility. Biopolymers, derived from living organisms or by-products, offer a potential solution with their biodegradability, renewability, and low embodied energy. These materials can revolutionise cladding practices by providing eco-friendly alternatives aligned with sustainable construction demands. Integrating biopolymers with synthetic polymers can enhance material biodegradability, contributing to overall degradation. Prominent biopolymers like PLA, PHAs, starch-based polymers, cellulose, PHB, and PBS exhibit biodegradability and sustainability, positioning them in the front rank for cladding applications. Despite significant research in biopolymer applications in different fields, there is limited research to identify the application and limitations of biopolymers as building cladding materials. This review paper aims to bridge the research gaps by comprehensively analysing diverse biopolymer cladding materials based on their properties and exploring their cross-domain utility, thereby highlighting their transformative role in sustainable construction practices. The expanding biopolymer market in building cladding materials underscores their potential to drive innovation, with projected growth emphasising their importance.
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Tan, Wei, and Tejal A. Desai. "Microfluidic Patterning of Cellular Biopolymer Matrices." JALA: Journal of the Association for Laboratory Automation 8, no. 3 (June 2003): 40–43. http://dx.doi.org/10.1016/s1535-5535-04-00269-2.

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Due to the complex structures of living systems, the use of microtechnology to recreate in vivo architecture has exciting potential applications. Living tissues maintain a well-organized three-dimensional (3-D) architecture, with “micro” and “nano” scale features. Microtechnologies offer the new possibility of designing and building sensors and devices in dimensional scales close to that of living tissues.1–2 However, most available microscale systems are two-dimensional, and few 3-D systems are being explored. Therefore, we have developed a versatile technique to create a 3-D microscale hierarchical system for cells and biopolymers. By taking advantage of the contraction of hydrogel matrix biopolymers, one can achieve multiple layers of cells within biopolymers using microchannels, and eventually form a hierarchical layered microstructure of cells and biopolymer. Pressure-driven microfluidics using a syringe pump (Harvard Apparatus, Model 11‘) was applied to transport cells within matrix biopolymers through the channels with controlled flow rates. Flow imaging was used to estimate the shear stress and examine the useful range of flow rates for biopolymer fluids to form the layered structure. The 3-aminopropyltriethoxysilane (APTES) — glutaraldehyde activated glass chips were found to effectively immobilize cell-matrix assemblies. Collagen or collagen-chitosan matrix biopolymers were used as constructs throughout the layers. The final structure was characterized using scanning electron microscopy (SEM). Using this approach, the “neotissue” is formed with cellular and biopolymer components engineered to model the in vivo system.
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Jo, Yun Kee. "Natural biopolymer-based hydrogels as designer matrices for organoid cultures." Organoid 3 (September 25, 2023): e13. http://dx.doi.org/10.51335/organoid.2023.3.e13.

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Matrigel, a mouse sarcoma-derived extract, is considered the gold standard for organoid cultures. However, it has several drawbacks, including inconsistent and ill-defined composition, varying quality between batches, and potential cancer-related health risks. These factors highlight the need to develop chemically defined alternatives to Matrigel. Natural biopolymers derived from living organisms have emerged as promising substitutes capable of creating chemically defined extracellular matrix (ECM)-mimicking materials to support organoids in a 3-dimensional (3D) environment. This article provides an overview of natural biopolymeric hydrogel-based bioengineering approaches for constructing 3D matrices resembling artificial ECM for organoid cultures. It discusses the latest developments in utilizing natural biopolymers to direct the growth, differentiation, and maturation of organoids, along with their translational applications in the fields of bioengineering and biomedicine. Additionally, the article offers perspectives on multidisciplinary research on natural biopolymer-based hydrogels for more practical applications as next-generation matrices for organoid cultures.
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Bose, Ipsheta, Nousheen, Swarup Roy, Pallvi Yaduvanshi, Somesh Sharma, Vinay Chandel, and Deblina Biswas. "Unveiling the Potential of Marine Biopolymers: Sources, Classification, and Diverse Food Applications." Materials 16, no. 13 (July 5, 2023): 4840. http://dx.doi.org/10.3390/ma16134840.

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Environmental concerns regarding the usage of nonrenewable materials are driving up the demand for biodegradable marine biopolymers. Marine biopolymers are gaining increasing attention as sustainable alternatives in various industries, including the food sector. This review article aims to provide a comprehensive overview of marine biopolymers and their applications in the food industry. Marine sources are given attention as innovative resources for the production of sea-originated biopolymers, such as agar, alginate, chitin/chitosan, and carrageenan, which are safe, biodegradable, and are widely employed in a broad spectrum of industrial uses. This article begins by discussing the diverse source materials of marine biopolymers, which encompass biopolymers derived from seaweed and marine animals. It explores the unique characteristics and properties of these biopolymers, highlighting their potential for food applications. Furthermore, this review presents a classification of marine biopolymers, categorizing them based on their chemical composition and structural properties. This classification provides a framework for understanding the versatility and functionality of different marine biopolymers in food systems. This article also delves into the various food applications of marine biopolymers across different sectors, including meat, milk products, fruits, and vegetables. Thus, the motive of this review article is to offer a brief outline of (a) the source materials of marine biopolymers, which incorporates marine biopolymers derived from seaweed and marine animals, (b) a marine biopolymer classification, and (c) the various food applications in different food systems such as meat, milk products, fruits, and vegetables.
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Xia, Shunxiang, Laibao Zhang, Artur Davletshin, Zhuoran Li, Jiahui You, and Siyuan Tan. "Application of Polysaccharide Biopolymer in Petroleum Recovery." Polymers 12, no. 9 (August 19, 2020): 1860. http://dx.doi.org/10.3390/polym12091860.

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Polysaccharide biopolymers are biomacromolecules derived from renewable resources with versatile functions including thickening, crosslinking, adsorption, etc. Possessing high efficiency and low cost, they have brought wide applications in all phases of petroleum recovery, from well drilling to wastewater treatment. The biopolymers are generally utilized as additives of fluids or plugging agents, to correct the fluid properties that affect the performance and cost of petroleum recovery. This review focuses on both the characteristics of biopolymers and their utilization in the petroleum recovery process. Research on the synthesis and characterization of polymers, as well as controlling their structures through modification, aims to develop novel recipes of biopolymer treatment with new application realms. The influences of biopolymer in many petroleum recovery cases were also evaluated to permit establishing the correlations between their physicochemical properties and performances. As their performance is heavily affected by the local environment, screening and testing polymers under controlled conditions is the necessary step to guarantee the efficiency and safety of biopolymer treatments.
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Garduño-Juárez, Ramón, David O. Tovar-Anaya, Jose Manuel Perez-Aguilar, Luis Fernando Lozano-Aguirre Beltran, Rafael A. Zubillaga, Marco Antonio Alvarez-Perez, and Eduardo Villarreal-Ramirez. "Molecular Dynamic Simulations for Biopolymers with Biomedical Applications." Polymers 16, no. 13 (June 29, 2024): 1864. http://dx.doi.org/10.3390/polym16131864.

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Computational modeling (CM) is a versatile scientific methodology used to examine the properties and behavior of complex systems, such as polymeric materials for biomedical bioengineering. CM has emerged as a primary tool for predicting, setting up, and interpreting experimental results. Integrating in silico and in vitro experiments accelerates scientific advancements, yielding quicker results at a reduced cost. While CM is a mature discipline, its use in biomedical engineering for biopolymer materials has only recently gained prominence. In biopolymer biomedical engineering, CM focuses on three key research areas: (A) Computer-aided design (CAD/CAM) utilizes specialized software to design and model biopolymers for various biomedical applications. This technology allows researchers to create precise three-dimensional models of biopolymers, taking into account their chemical, structural, and functional properties. These models can be used to enhance the structure of biopolymers and improve their effectiveness in specific medical applications. (B) Finite element analysis, a computational technique used to analyze and solve problems in engineering and physics. This approach divides the physical domain into small finite elements with simple geometric shapes. This computational technique enables the study and understanding of the mechanical and structural behavior of biopolymers in biomedical environments. (C) Molecular dynamics (MD) simulations involve using advanced computational techniques to study the behavior of biopolymers at the molecular and atomic levels. These simulations are fundamental for better understanding biological processes at the molecular level. Studying the wide-ranging uses of MD simulations in biopolymers involves examining the structural, functional, and evolutionary aspects of biomolecular systems over time. MD simulations solve Newton’s equations of motion for all-atom systems, producing spatial trajectories for each atom. This provides valuable insights into properties such as water absorption on biopolymer surfaces and interactions with solid surfaces, which are crucial for assessing biomaterials. This review provides a comprehensive overview of the various applications of MD simulations in biopolymers. Additionally, it highlights the flexibility, robustness, and synergistic relationship between in silico and experimental techniques.
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Soldo, Antonio, Victor Aguilar, and Marta Miletić. "Macroscopic Stress-Strain Response and Strain-Localization Behavior of Biopolymer-Treated Soil." Polymers 14, no. 5 (February 28, 2022): 997. http://dx.doi.org/10.3390/polym14050997.

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The enhancement of soil engineering properties with biopolymers has been shown recently as a viable and environmentally benign alternative to cement and chemical stabilization. Interest in biopolymer-treated soil is evident from the upsurge of related research activities in the last five years, most of which have been experimental in nature. However, biopolymers have not yet found their way into engineering practice. One of the reasons for this may be the absence of computational models that would allow engineers to incorporate biopolymer-treated soil into their designs. Therefore, the main goal of this study is to numerically capture a macroscopic stress-strain response and investigate the effect of biopolymers on the onset of strain localization. Several diagnostic strain-localization analyses were conducted, thus providing strain and stress levels at the onset of strain localization, along with the orientations of the deformation band. Several unconfined compression and triaxial tests on the plain and biopolymer-treated soils were modeled. Results showed that biopolymers significantly improved the mechanical behavior of the soil and affected the onset of strain localization. The numerical results were confirmed by the digital image analysis of the unconfined compression tests. Digital image processing successfully captured high strain concentrations, which tended to occur close to the peak stress.
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Diyana, Z. N., R. Jumaidin, Mohd Zulkefli Selamat, Ihwan Ghazali, Norliza Julmohammad, Nurul Huda, and R. A. Ilyas. "Physical Properties of Thermoplastic Starch Derived from Natural Resources and Its Blends: A Review." Polymers 13, no. 9 (April 26, 2021): 1396. http://dx.doi.org/10.3390/polym13091396.

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Thermoplastic starch composites have attracted significant attention due to the rise of environmental pollutions induced by the use of synthetic petroleum-based polymer materials. The degradation of traditional plastics requires an unusually long time, which may lead to high cost and secondary pollution. To solve these difficulties, more petroleum-based plastics should be substituted with sustainable bio-based plastics. Renewable and natural materials that are abundant in nature are potential candidates for a wide range of polymers, which can be used to replace their synthetic counterparts. This paper focuses on some aspects of biopolymers and their classes, providing a description of starch as a main component of biopolymers, composites, and potential applications of thermoplastics starch-based in packaging application. Currently, biopolymer composites blended with other components have exhibited several enhanced qualities. The same behavior is also observed when natural fibre is incorporated with biopolymers. However, it should be noted that the degree of compatibility between starch and other biopolymers extensively varies depending on the specific biopolymer. Although their efficacy is yet to reach the level of their fossil fuel counterparts, biopolymers have made a distinguishing mark, which will continue to inspire the creation of novel substances for many years to come.
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Appiah, Eugene Sefa, Perseverance Dzikunu, Nashiru Mahadeen, Daniel Nframah Ampong, Kwadwo Mensah-Darkwa, Anuj Kumar, Ram K. Gupta, and Mark Adom-Asamoah. "Biopolymers-Derived Materials for Supercapacitors: Recent Trends, Challenges, and Future Prospects." Molecules 27, no. 19 (October 3, 2022): 6556. http://dx.doi.org/10.3390/molecules27196556.

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Supercapacitors may be able to store more energy while maintaining fast charging times; however, they need low-cost and sophisticated electrode materials. Developing innovative and effective carbon-based electrode materials from naturally occurring chemical components is thus critical for supercapacitor development. In this context, biopolymer-derived porous carbon electrode materials for energy storage applications have gained considerable momentum due to their wide accessibility, high porosity, cost-effectiveness, low weight, biodegradability, and environmental friendliness. Moreover, the carbon structures derived from biopolymeric materials possess unique compositional, morphological, and electrochemical properties. This review aims to emphasize (i) the comprehensive concepts of biopolymers and supercapacitors to approach smart carbon-based materials for supercapacitors, (ii) synthesis strategies for biopolymer derived nanostructured carbons, (iii) recent advancements in biopolymer derived nanostructured carbons for supercapacitors, and (iv) challenges and future prospects from the viewpoint of green chemistry-based energy storage. This study is likely to be useful to the scientific community interested in the design of low-cost, efficient, and green electrode materials for supercapacitors as well as various types of electrocatalysis for energy production.
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Atanase, Leonard-Ionut. "Biopolymers for Enhanced Health Benefits." International Journal of Molecular Sciences 24, no. 22 (November 13, 2023): 16251. http://dx.doi.org/10.3390/ijms242216251.

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Li, Xiaoming, Rongrong Cui, Lianwen Sun, Katerina E. Aifantis, Yubo Fan, Qingling Feng, Fuzhai Cui, and Fumio Watari. "3D-Printed Biopolymers for Tissue Engineering Application." International Journal of Polymer Science 2014 (2014): 1–13. http://dx.doi.org/10.1155/2014/829145.

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3D printing technology has recently gained substantial interest for potential applications in tissue engineering due to the ability of making a three-dimensional object of virtually any shape from a digital model. 3D-printed biopolymers, which combine the 3D printing technology and biopolymers, have shown great potential in tissue engineering applications and are receiving significant attention, which has resulted in the development of numerous research programs regarding the material systems which are available for 3D printing. This review focuses on recent advances in the development of biopolymer materials, including natural biopolymer-based materials and synthetic biopolymer-based materials prepared using 3D printing technology, and some future challenges and applications of this technology are discussed.
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da Luz, Tayla Gabriela, Valber Sales, and Raquel Dalla Costa da Rocha. "Evaluation of technology potential of Aloe arborescens biopolymer in galvanic effluent treatment." Water Science and Technology 2017, no. 1 (February 23, 2018): 48–57. http://dx.doi.org/10.2166/wst.2018.082.

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Abstract Biopolymers have the ability to form gels that can be used in coagulation/flocculation processes. For this reason, the present work evaluated the application of the Aloe arborescens gel as a biopolymer in the treatment of the effluent generated in galvanic processes. The centesimal, thermogravimetric and texture profiles, as well as the functional groups and the biopolymer's performance in the treatment was analyzed. The performance results were evaluated by central composite rotational design 23. The variables biopolymer concentration, aluminum sulphate and initial pH of the effluent were significant at the confidence level of 95%. The Cr(VI) removal efficiency ranged from 6.37% to 37.74%; significant reductions in dissolved solids (89.80% to 94.13%) and suspended solids (71.06% to 90.00%) were also observed. The treated effluent still presents parameters above the regulatory limits stated by the legislation, therefore, the biopolymer could be used as initial treatment for solids removal.
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Baranwal, Jaya, Brajesh Barse, Antonella Fais, Giovanna Lucia Delogu, and Amit Kumar. "Biopolymer: A Sustainable Material for Food and Medical Applications." Polymers 14, no. 5 (February 28, 2022): 983. http://dx.doi.org/10.3390/polym14050983.

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Biopolymers are a leading class of functional material suitable for high-value applications and are of great interest to researchers and professionals across various disciplines. Interdisciplinary research is important to understand the basic and applied aspects of biopolymers to address several complex problems associated with good health and well-being. To reduce the environmental impact and dependence on fossil fuels, a lot of effort has gone into replacing synthetic polymers with biodegradable materials, especially those derived from natural resources. In this regard, many types of natural or biopolymers have been developed to meet the needs of ever-expanding applications. These biopolymers are currently used in food applications and are expanding their use in the pharmaceutical and medical industries due to their unique properties. This review focuses on the various uses of biopolymers in the food and medical industry and provides a future outlook for the biopolymer industry.
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Zupančič, Gregor Drago, Anamarija Lončar, Sandra Budžaki, and Mario Panjičko. "Biopolymers Produced by Treating Waste Brewer’s Yeast with Active Sludge Bacteria: The Qualitative Analysis and Evaluation of the Potential for 3D Printing." Sustainability 14, no. 15 (July 30, 2022): 9365. http://dx.doi.org/10.3390/su14159365.

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Biopolymers are a suitable alternative for the ongoing problem of plastic accumulation, even though commercialization is difficult, which is reflected in the price of the product. However, costs can be reduced if active sludge bacteria and cheap, accessible substrates such as waste brewer’s yeast are used. Waste brewer’s yeast is a rich source of carbon and nitrogen and is widespread as a substrate in various industries. Thus, the cultivation of active sludge bacteria was performed on waste brewers’ yeast to obtain biopolymers that can be used in 3D printing. FT-IR, TG, and DSC analyses of produced polymers were conducted after extraction, as well as biogas and biomethane potential tests. Results of cultivation under various conditions show that biopolymer content is extremely heterogeneous. However, during cultivation in SBR, signals at 1741.3, 1709.6, 1634.3, and 1238 cm−1 were detected. Further analyses are needed, but when said results are compared to those of consulted scientific articles, there is an indication that at least a small amount of PHA is present in biomass produced in SBR. Biopolymers produced in SBR were used as a material for the 3D printing of a cube. Moreover, testing of the physical properties (Young’s modulus) of a 3D-printed cube was performed. After conducting experiments, it can be concluded that said process, although time-consuming, achieved the goal of printing a stable and rigid 3D-printed cube made from biopolymers. Further optimization of said process should focus on more detailed microbial selection as well as biopolymer extraction. In that way, isolation, purification, and identification techniques will be improved, which could achieve higher biopolymer yield and, thus, make biopolymers more accessible in various industries.
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Sieger, Johannes Lukas, Bernd Georg Lottermoser, and Justus Freer. "Effectiveness of Protein and Polysaccharide Biopolymers as Dust Suppressants on Mine Soils: Large-Scale Field Trials." Mining 3, no. 3 (July 18, 2023): 428–62. http://dx.doi.org/10.3390/mining3030026.

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Recent laboratory studies have shown that biopolymers have the potential to act as dust suppressants on barren mine soils. However, there is a lack of field trials investigating the effectiveness of biopolymer treatments under real field conditions on a large scale. This study performed field trials to examine the potential of three biopolymers—corn starch (CS), xanthan gum (XG), and fava bean protein concentrate (FBPC)—as dust suppressants. The field trials started in August 2022 with spraying of low doses of the selected biopolymers on trial areas of an overburden dump at the Inden open-cast lignite mine, Germany. The field trials were conducted over 45 days. They included repeated measurements of dust emissions from soil plots exposed to different airflows generated by an electric blower, visual inspections, and penetrometer tests. The results showed that all biopolymer treatments effectively suppressed dust emissions in the short term up to 8 days after application. Total suspended particle emissions measured on the biopolymer-treated trial plots were significantly reduced and ranged from 0.05 to 0.27 mg/m3 compared to the untreated control (4.5 to 39.2 mg/m3). The visual inspections and penetrometer tests supported these results. After day 8, rainfall-induced leaching of the biopolymers resulted in the rapid degradation of the treatments’ effectiveness. The results suggest that the treatments would have lasted longer under dry conditions. Thus, the field trials provide practical evidence that biopolymers can effectively mitigate dust emissions on exposed, undisturbed mine soils in the short term, making them a bio-based alternative to traditional dust suppressants, such as chloride salts or petroleum-based products.
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Chen, I.-Hao, Tzer-Min Lee, and Chih-Ling Huang. "Biopolymers Hybrid Particles Used in Dentistry." Gels 7, no. 1 (March 22, 2021): 31. http://dx.doi.org/10.3390/gels7010031.

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This literature review provides an overview of the fabrication and application of biopolymer hybrid particles in dentistry. A total of 95 articles have been included in this review. In the review paper, the common inorganic particles and biopolymers used in dentistry are discussed in general, and detailed examples of inorganic particles (i.e., hydroxyapatite, calcium phosphate, and bioactive glass) and biopolymers such as collagen, gelatin, and chitosan have been drawn from the scientific literature and practical work. Among the included studies, calcium phosphate including hydroxyapatite is the most widely applied for inorganic particles used in dentistry, but bioactive glass is more applicable and multifunctional than hydroxyapatite and is currently used in clinical practice. Today, biopolymer hybrid particles are receiving more attention as novel materials for several applications in dentistry, such as drug delivery systems, bone repair, and periodontal regeneration surgery. The literature published on the biopolymer gel-assisted synthesis of inorganic particles for dentistry is somewhat limited, and therefore, this article focuses on reviewing and discussing the biopolymer hybrid particles used in dentistry.
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Patel, Nidhiben, and Dagnija Blumberga. "Insights of Bioeconomy: Biopolymer Evaluation Based on Sustainability Criteria." Environmental and Climate Technologies 27, no. 1 (January 1, 2023): 323–38. http://dx.doi.org/10.2478/rtuect-2023-0025.

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Abstract Sustainable development in the agriculture sector can be boosted by integrating a sustainable bioeconomy and transforming renewable resources into added-value products. There are various methods to determine, measure, and compare the extent of sustainability. We promote the bioeconomy concept by utilizing agricultural waste in biopolymers considering the sustainable development in the agriculture sector. This research aims to evaluate biopolymer alternatives based on sustainability criteria and indicators using the integrated multi-criteria decision analysis approach under the sustainability umbrella. We evaluated the PLA, PHA/PHB, starch, protein, and cellulose-based biopolymers. As a result, the cellulose-based biopolymer shows the best performance. The research findings provide valuable information to establish a sustainable pathway for biopolymer production for industries.
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Shi, Jiayuan, and Bin Shi. "Environment-Friendly Design of Lithium Batteries Starting from Biopolymer-Based Electrolyte." Nano 16, no. 05 (April 7, 2021): 2130006. http://dx.doi.org/10.1142/s1793292021300061.

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The nondegradable nature and toxicity of organic liquid electrolytes reveal the design deficiency of lithium batteries in environmental protection. Biopolymers can be extracted from biomass under mild conditions, thus they are usually low cost and renewable. The unique characteristics of biopolymers such as water solubility, film-forming capability and adhesive property are of importance for lithium battery. The studies on the biopolymer materials for lithium batteries have been reviewed in this work. Although a lot of work on the biopolymer-based battery materials has been reported, it is still a challenge in the design of lithium battery with zero pollution and zero waste.
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Eckstein, Fritz, Daniel Kahne, and William F. Degrado. "Biopolymers: Multifaceted biopolymers." Current Opinion in Chemical Biology 6, no. 6 (December 2002): 805–8. http://dx.doi.org/10.1016/s1367-5931(02)00404-0.

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Kumar, Nitin, Preetinder Kaur, and Surekha Bhatia. "Advances in bio-nanocomposite materials for food packaging: a review." Nutrition & Food Science 47, no. 4 (July 10, 2017): 591–606. http://dx.doi.org/10.1108/nfs-11-2016-0176.

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Purpose The purpose of this paper is to acquaint the readers with recent developments in biopolymer-based food packaging materials like natural biopolymers (such as starches and proteins), synthetic biopolymers (such as poly lactic acid), biopolymer blending and nanocomposites grounded on natural and synthetic biopolymers. This paper is an attempt to draw the readers towards the advantages and attributes of new era polymers to diminish the usage of traditional non-biodegradable polymers. Design/methodology/approach Plastic packaging for food and associated applications is non-biodegradable and uses up valuable and treasured non-renewable petroleum products. With the current focus on researching alternatives to petroleum, research is progressively being channelized towards the development of biodegradable food packaging, thereby reducing adverse impact on the environment. Findings Natural biopolymer-based nanocomposite packaging materials seem to have a scintillating future for a broad range of applications in the food industry, including advanced active food packaging with biofunctional attributes. The present review summarizes the scientific information of various packaging materials along with their attributes, applications and the methods for production. Originality/value This is an apropos review as there has been a recent renewed concern in research studies, both in the industry and academe, for development of new generation biopolymer-based food packaging materials, with possible applications in many areas.
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Irfan, Sayed Ameenuddin, Babar Azeem, Kashif Irshad, Salem Algarni, KuZilati KuShaari, Saiful Islam, and Mostafa A. H. Abdelmohimen. "Machine Learning Model for Nutrient Release from Biopolymers Coated Controlled-Release Fertilizer." Agriculture 10, no. 11 (November 9, 2020): 538. http://dx.doi.org/10.3390/agriculture10110538.

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Recent developments in the controlled-release fertilizer (CRF) have led to the new modern agriculture industry, also known as precision farming. Biopolymers as encapsulating agents for the production of controlled-release fertilizers have helped to overcome many challenging problems such as nutrients’ leaching, soil degradation, soil debris, and hefty production cost. Mechanistic modeling of biopolymers coated CRF makes it challenging due to the complicated phenomenon of biodegradation. In this study, a machine learning model is developed utilizing Gaussian process regression to predict the nutrient release time from biopolymer coated CRF with the input parameters consisting of diffusion coefficient, coefficient of-variance of coating thickness, coating mass thickness, coefficient of variance of size distribution and surface hardness from biopolymer coated controlled-release fertilizer. The developed model has shown greater prediction capabilities measured with R2 equalling 1 and a Root Mean Square Error (RMSE) equalling 0.003. The developed model can be utilized to study the nutrient release profile of different biopolymers’-coated controlled-release fertilizers.
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De Luca, Stefano, Daniel Milanese, Duccio Gallichi-Nottiani, Antonella Cavazza, and Corrado Sciancalepore. "Poly(lactic acid) and Its Blends for Packaging Application: A Review." Clean Technologies 5, no. 4 (November 10, 2023): 1304–43. http://dx.doi.org/10.3390/cleantechnol5040066.

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Biopolymers obtained from renewable resources are an interesting alternative to conventional polymers obtained from fossil resources, as they are sustainable and environmentally friendly. Poly(lactic acid) (PLA) is a biodegradable aliphatic polyester produced from 100% renewable plant resources and plays a key role in the biopolymer market, and is experiencing ever-increasing use worldwide. Unfortunately, this biopolymer has some usage limitations when compared with traditional polymers; therefore, blending it with other biopolymers, such as poly(butylene succinate) (PBS), poly(butylene succinate-co-butylene adipate) (PBSA), poly(butylene adipate-co-butylene terephthalate) (PBAT) and different poly(hydroxyalkanoates) (PHA), is considered an interesting method to improve it significantly, customize its properties and extend the range of its applications. The following review highlights, in its first part, the physico-chemical and mechanical properties of PLA in comparison to the other biopolymers listed above, highlighting the various drawbacks of PLA. The second part of the review deals with recent developments, results, and perspectives in the field of PLA-based blends.
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45

Mackie, Alan. "Biopolymers 2013: Biopolymer assemblies for material design." Biopolymers 101, no. 9 (June 23, 2014): 913–14. http://dx.doi.org/10.1002/bip.22511.

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46

Camacho-Chab, Juan Carlos, Pedro Alberto Camacho-Chab, Juan Enrique Pereañez-Sacarías, Jorge Luis Montero-Muñoz, Augusto Ignacio Almeyda-Cen, Luis Alonso Dzul-López, María Manuela Reyes-Estebanez, and Benjamín Otto Ortega-Morales. "Short-Term Effect of Biopolymer-Based Coatings on Surface Hardness and Color of Limestone Exposed to Tropical Outdoor Conditions." Coatings 14, no. 2 (January 23, 2024): 154. http://dx.doi.org/10.3390/coatings14020154.

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It has previously been shown that epilithic bacterial biopolymers used as coatings influenced the physical properties (surface hardness and color change) at different levels and decreased the surface disaggregation of experimental limestone when evaluated at the laboratory level. A short-term study (30 days) was conducted to evaluate the performance under natural conditions of limestone blocks exposed to tropical conditions of a selected bacterial biopolymer (TM1B-488, after the producing bacterium) and a previously unreported Mayan plant biopolymer known as “Escobilla”, Sida rhombifolia (Malvaceae) used in conservation procedures. Surface hardness (Leeb units) and color (L*a*b* coordinates) were measured and statistically tested for two types of limestone blocks (sound and deteriorated limestone). Both biopolymers increased surface hardness, decreased surface disaggregation, and did not alter color. Escobilla polymer is a carbohydrate-rich biopolymer characterized by tangential filtration, global chemical composition, and monosaccharide composition of hydrolyzed polymer. These results indicate that biopolymers of a heteropolysaccharide nature are constituted by some anionic charge residues that could contribute to surface stabilization and consolidation, but compatibility with traditional building materials (mortars) and longer time of exposure (a year) are necessary to fully assess their applicability in the restoration of architectural heritage.
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47

Sharma, Mohit, Nihed Tellili, Imen Kacem, and Tarek Rouissi. "Microbial Biopolymers: From Production to Environmental Applications—A Review." Applied Sciences 14, no. 12 (June 11, 2024): 5081. http://dx.doi.org/10.3390/app14125081.

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Industrial evolution and agricultural expansion, explained by continuing population growth, have rendered enormous problems for the world throughout the past few decades, primarily because of waste generation. To reduce environmental impact and dependence on fossil fuels, scientists have explored replacing synthetic polymers with environmentally friendly and sustainable alternatives in many emergent applications. In this regard, microbial biopolymers have gained special attention. Many biopolymers originating from various strains of bacteria, fungi, and algae have been reported and their possible applications have increased rapidly. This review focuses on the wide range of microbial biopolymers, their characteristics, and factors influencing their production. The present study also describes the environmental applications of microbial biopolymers. The use of these biopolymers is very attractive as a value-added and sustainable approach to wastewater treatment. By acting as adsorbents, coagulants, and flocculants as well as filters in membrane processes, microbial biopolymers shine as promising solutions beyond conventional methods. They can be integrated into various stages of the treatment process, further enhancing the efficiency of wastewater treatment methods. Microbial biopolymer applications in bioremediation and soil stabilization are also reviewed. Several studies have demonstrated the strong potential of biopolymers in soil improvement due to their ability to minimize permeability, eliminate heavy metals, stabilize soil, and limit erosion. Challenges related to scaling up and the downstream processing of microbial biopolymers, as well as its future perspectives in environmental applications, are also discussed.
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48

Lisitsyn, Andrey, Anastasia Semenova, Viktoria Nasonova, Ekaterina Polishchuk, Natalia Revutskaya, Ivan Kozyrev, and Elena Kotenkova. "Approaches in Animal Proteins and Natural Polysaccharides Application for Food Packaging: Edible Film Production and Quality Estimation." Polymers 13, no. 10 (May 15, 2021): 1592. http://dx.doi.org/10.3390/polym13101592.

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Natural biopolymers are an interesting resource for edible films production, as they are environmentally friendly packaging materials. The possibilities of the application of main animal proteins and natural polysaccharides are considered in the review, including the sources, structure, and limitations of usage. The main ways for overcoming the limitations caused by the physico-chemical properties of biopolymers are also discussed, including composites approaches, plasticizers, and the addition of crosslinking agents. Approaches for the production of biopolymer-based films and coatings are classified according to wet and dried processes and considered depending on biopolymer types. The methods for mechanical, physico-chemical, hydration, and uniformity estimation of edible films are reviewed.
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49

Friuli, Marco, Rebecca Pellegrino, Leonardo Lamanna, Paola Nitti, Marta Madaghiele, and Christian Demitri. "Materials Engineering to Help Pest Control: A Narrative Overview of Biopolymer-Based Entomopathogenic Fungi Formulations." Journal of Fungi 9, no. 9 (September 12, 2023): 918. http://dx.doi.org/10.3390/jof9090918.

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Biopolymer-based formulations show great promise in enhancing the effectiveness of entomopathogenic fungi as bioinsecticides. Chitosan and starch, among other biopolymers, have been utilized to improve spore delivery, persistence, and adherence to target insects. These formulations offer advantages such as target specificity, eco-friendliness, and sustainability. However, challenges related to production costs, stability, and shelf life need to be addressed. Recently, biomimetic lure and kill approaches based on biopolymers offer cost-effective solutions by leveraging natural attractants. Further research is needed to optimize these formulations and overcome challenges. Biopolymer-based formulations have the potential to revolutionize pest control practices, providing environmentally friendly and sustainable solutions for agriculture.
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Shamsuri, Ahmad Adlie, Khalina Abdan, and Tatsuo Kaneko. "A Concise Review on the Physicochemical Properties of Biopolymer Blends Prepared in Ionic Liquids." Molecules 26, no. 1 (January 4, 2021): 216. http://dx.doi.org/10.3390/molecules26010216.

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An enhancement of environmental concern lately has improved the awareness of researchers in employing eco-friendly solvents for processing biopolymers. Recently, ionic liquids have been utilized to prepare biopolymer blends as they are non-volatile and recyclable. Biopolymers such as cellulose, chitin, chitosan, keratin, lignin, silk, starch, and zein are widely used for the preparation of biopolymer blends via dissolution in ionic liquids, followed by coagulation procedure. In this concise review, three types of ionic liquids based on imidazolium cations combined with different counter anions that are frequently utilized to prepare biopolymer blends are described. Moreover, three types of biopolymer blends that are prepared in ionic liquids were classified, specifically polysaccharide/polysaccharide blends, polysaccharide/polypeptide blends, and polysaccharide/bioplastic blends. The physicochemical properties of biopolymer blends prepared in different imidazolium-based ionic liquids are also concisely reviewed. This paper may assist the researchers in the polymer blend area and generate fresh ideas for future research.
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