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Journal articles on the topic 'Biomimetic synthesis'

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Author: Grafiati

Published: 4 June 2021

Last updated: 6 September 2023

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1

Liu, Qiang, Bing Jian Zhang, and Hui Zhu. "Bio-Inspired Engineering: A Promising Technology for the Conservation of Historic Stone Buildings and Sculptures." Key Engineering Materials 460-461 (January 2011): 502–5. http://dx.doi.org/10.4028/www.scientific.net/kem.460-461.502.

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The conservation of historic stone buildings and sculptures is receiving growing attention from many fields because of increasing bad weathering. At present, special attentions are paid to development of new protective materials. In this paper, we review that some findings of crude protective film of biomimetic materials on the historic stone buildings and sculptures, discuss their biological origin, and propose an approach to prepare the protective agents through the biomimetic method. Moreover, an overview of the Principle of biomineraliztion and biomimetics syntheses is provided. Thus, it is dedicated that the biomimetic synthesis should have great potentialities in applied protective methods and should represent a new prospective in stone conservation.

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2

Wang, Zhang, and Donghui Ma. "Biomimetic Approaches: Synthesis of (±)-Homodimericin A." Synlett 29, no. 07 (February 19, 2018): 856–62. http://dx.doi.org/10.1055/s-0036-1591938.

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A brief history of biomimetic total synthesis is reviewed. The molecules covered in this SynPact account include tropinone (Robinson, 1917), usnic acid (Barton, 1956), progesterone (Johnson, 1971), endiandric acids (Nicolaou, 1982), methyl homosecodaphniphyllate (Heathcock, 1988), glabrescol (Corey, 2000), FR182877 (Sorensen, 2002 and Evans, 2002), and intricarene (Pattenden, 2006 and Trauner, 2006). Key biomimetic transformations of the syntheses are highlighted. Our recent biomimetic synthesis of homodimericin A is also discussed. Our study validates the key steps of the biosynthesis proposed by Clardy et al.

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3

Gebeshuber, Ille C. "Biomimetic Nanotechnology Vol. 3." Biomimetics 8, no. 1 (March 3, 2023): 102. http://dx.doi.org/10.3390/biomimetics8010102.

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Biomimetic nanotechnology pertains to the fundamental elements of living systems and the translation of their properties into human applications. The underlying functionalities of biological materials, structures and processes are primarily rooted in the nanoscale domain, serving as a source of inspiration for materials science, medicine, physics, sensor technologies, smart materials science and other interdisciplinary fields. The Biomimetics Special Issues Biomimetic Nanotechnology Vols. 1–3 feature a collection of research and review articles contributed by experts in the field, delving into significant realms of biomimetic nanotechnology. This publication, Vol. 3, comprises four research articles and one review article, which offer valuable insights and inspiration for innovative approaches inspired by Nature’s living systems. The spectrum of the articles is wide and deep and ranges from genetics, traditional medicine, origami, fungi and quartz to green synthesis of nanoparticles.

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4

Kamptmann, Sonja B., and Steven V. Ley. "Facilitating Biomimetic Syntheses of Borrerine Derived Alkaloids by Means of Flow-Chemical Methods." Australian Journal of Chemistry 68, no. 4 (2015): 693. http://dx.doi.org/10.1071/ch14530.

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Flow chemistry is widely used nowadays in synthetic chemistry and has increasingly been applied to complex natural product synthesis. However, to date flow chemistry has not found a place in the area of biomimetic synthesis. Here we show the syntheses of borrerine derived alkaloids, indicating that we can use biomimetic principles in flow to prepare complex architectures in a single step.

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5

McDonald, Frank E., Rongbiao Tong, Jason C. Valentine, and Fernando Bravo. "Biomimetic synthesis via polyepoxide cyclizations." Pure and Applied Chemistry 79, no. 2 (January 1, 2007): 281–91. http://dx.doi.org/10.1351/pac200779020281.

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The biomimetic synthesis of trans,syn,trans-fused polycyclic ether natural products involving a cascade of stereospecific and regioselective oxacyclizations of polyepoxide substrates is described as applied to the synthesis of polyoxepane and polypyran structures. In addition, an extension of biomimetic polyene cyclizations to terpenoid natural products is outlined.

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6

Hu, Xiangdong, Tao Yu, Xin Shu, and Kewu Yang. "Biomimetic Total Synthesis of Scabellone B." Synlett 29, no. 12 (June 18, 2018): 1617–21. http://dx.doi.org/10.1055/s-0037-1610178.

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A biomimetic total synthesis of scabellone B is described. Through sequential regioselective introduction of a geranyl group by means of silyl protection, oxidative dimerization, and biomimetic oxo-6π electrocyclization with good cyclization selectivity, a biomimetic approach to scabellone B was achieved in five steps and 32% overall yield.

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7

Okuda, Takuo, Takashi Yoshida, Tsutomu Hatano, and Yoshitaka Ikeda. "Biomimetic Synthesis of Elaeocarpusin." HETEROCYCLES 24, no. 7 (1986): 1841. http://dx.doi.org/10.3987/r-1986-07-1841.

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8

Annenkov, Vadim V., Stanislav N. Zelinskiy, Elena N. Danilovtseva, and Carole C. Perry. "Synthesis of biomimetic polyamines." Arkivoc 2009, no. 13 (December 6, 2009): 116–30. http://dx.doi.org/10.3998/ark.5550190.0010.d10.

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9

Wu, Yingying, Chao Du, Congcong Hu, Ying Li, and Zhixiang Xie. "Biomimetic Synthesis of Hyperolactones." Journal of Organic Chemistry 76, no. 10 (May 20, 2011): 4075–81. http://dx.doi.org/10.1021/jo102511x.

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10

Wanner, Martin J., and Gerrit-Jan Koomen. "Biomimetic Synthesis of Nitraramine." Journal of Organic Chemistry 60, no. 17 (September 1995): 5634–37. http://dx.doi.org/10.1021/jo00122a052.

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11

Sass, Daiane Cristina, Vladimir Constantino Gomes Heleno, Jader da Silva Barbosa, Gustavo Oliveira Morais, Fernando Batista Da Costa, and Mauricio Gomes Constantino. "Biomimetic synthesis of diversifolin." Tetrahedron Letters 54, no. 7 (February 2013): 625–27. http://dx.doi.org/10.1016/j.tetlet.2012.11.134.

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12

Cheng, Kin-Fai, Yun-Cheung Kong, and Tin-Yau Chan. "Biomimetic synthesis of yeuhchukene." Journal of the Chemical Society, Chemical Communications, no. 2 (1985): 48. http://dx.doi.org/10.1039/c39850000048.

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13

Baldwin, Jack E., R. M. Adlington, and Rolf Bohlmann. "Biomimetic synthesis of penicillin." Journal of the Chemical Society, Chemical Communications, no. 6 (1985): 357. http://dx.doi.org/10.1039/c39850000357.

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14

Lecerf-Schmidt, Florine, Romain Haudecoeur, Basile Peres, Marcos Marçal Ferreira Queiroz, Laurence Marcourt, Soura Challal, Emerson Ferreira Queiroz, et al. "Biomimetic synthesis of Tramadol." Chemical Communications 51, no. 77 (2015): 14451–53. http://dx.doi.org/10.1039/c5cc05948h.

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15

Huo, Xing, Xinfu Pan, Guosheng Huang, and Xuegong She. "Biomimetic Synthesis of (+)-Neroplofurol." Synlett 2011, no. 08 (April 7, 2011): 1149–50. http://dx.doi.org/10.1055/s-0030-1259943.

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16

Burrage, Sarah, Tony Raynham, Glyn Williams, Jonathan W. Essex, Carl Allen, Marianne Cardno, Vinay Swali, and Mark Bradley. "Biomimetic Synthesis of Lantibiotics." Chemistry - A European Journal 6, no. 8 (April 17, 2000): 1455–66. http://dx.doi.org/10.1002/(sici)1521-3765(20000417)6:8<1455::aid-chem1455>3.0.co;2-m.

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17

Yokoshima, Satoshi. "Synthesis of Polycyclic Natural Products through Skeletal Rearrangement." Synlett 31, no. 20 (July 23, 2020): 1967–75. http://dx.doi.org/10.1055/s-0040-1707904.

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Construction of rings through reliable reactions followed by changes in the ring size or the connectivity through skeletal rearrangement provides molecules with a wide range of skeletons. In this account, our syntheses of polycyclic natural products through skeletal rearrangement are discussed.1 Introduction2 Synthesis through Changes in the Ring Size3 Synthesis by Biomimetic Strategies4 Synthesis through Metathesis5 Synthesis through Temporary Formation of a Ring6 Conclusion

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18

Wei, Gang, Coucong Gong, Keke Hu, Yabin Wang, and Yantu Zhang. "Biomimetic Hydroxyapatite on Graphene Supports for Biomedical Applications: A Review." Nanomaterials 9, no. 10 (October 10, 2019): 1435. http://dx.doi.org/10.3390/nano9101435.

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Hydroxyapatite (HA) has been widely used in fields of materials science, tissue engineering, biomedicine, energy and environmental science, and analytical science due to its simple preparation, low-cost, and high biocompatibility. To overcome the weak mechanical properties of pure HA, various reinforcing materials were incorporated with HA to form high-performance composite materials. Due to the unique structural, biological, electrical, mechanical, thermal, and optical properties, graphene has exhibited great potentials for supporting the biomimetic synthesis of HA. In this review, we present recent advance in the biomimetic synthesis of HA on graphene supports for biomedical applications. More focuses on the biomimetic synthesis methods of HA and HA on graphene supports, as well as the biomedical applications of biomimetic graphene-HA nanohybrids in drug delivery, cell growth, bone regeneration, biosensors, and antibacterial test are performed. We believe that this review is state-of-the-art, and it will be valuable for readers to understand the biomimetic synthesis mechanisms of HA and other bioactive minerals, at the same time it can inspire the design and synthesis of graphene-based novel nanomaterials for advanced applications.

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19

Kulcitki, V. "Biomimetic Strategies in Organic Synthesis. Terpenes." Chemistry Journal of Moldova 7, no. 2 (December 2012): 46–56. http://dx.doi.org/10.19261/cjm.2012.07(2).14.

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The current paper represents an outline of the selected contributions to the biomimetic procedures and approaches for the synthesis of terpenes with complex structure and diverse functionalisation pattern. These include homologation strategies, cyclisations, rearrangements, as well as biomimetic remote functionalisations.

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20

Ma, Zaiqiang, Benke Li, and Ruikang Tang. "Biomineralization: Biomimetic Synthesis of Materials and Biomimetic Regulation of Organisms." Chinese Journal of Chemistry 39, no. 8 (June 23, 2021): 2071–82. http://dx.doi.org/10.1002/cjoc.202100119.

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21

Koser, Lilla, Vivian Miles Lechner, and Thorsten Bach. "Biomimetic Total Synthesis of Enterocin." Angewandte Chemie International Edition 60, no. 37 (August 11, 2021): 20269–73. http://dx.doi.org/10.1002/anie.202108157.

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22

Koser, Lilla, Vivian Miles Lechner, and Thorsten Bach. "Biomimetic Total Synthesis of Enterocin." Angewandte Chemie 133, no. 37 (August 11, 2021): 20431–35. http://dx.doi.org/10.1002/ange.202108157.

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23

Wang, Hong You, Kang Ning Sun, Ting Shan, Xiu Qing Yang, Yan Zhao, and Yan Jie Liang. "Biomimetic Synthesis of Fluorapatite Coating." Advanced Materials Research 306-307 (August 2011): 63–71. http://dx.doi.org/10.4028/www.scientific.net/amr.306-307.63.

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In the present study, a simple method of regenerating microstructure of human tooth under near-physiological conditions (pH 7.0, 37 °C, 1 atm) was developed. Commercial gelatin was used as matrix materials in this method, which nucleated the formation of fluorapatite (FA) nanocrystals and regulated the growth of nanocrystals. As a result, the resulting thin FA coatings had been prepared on human tooth slices and sintered hydroxyapatite disks, which were in tight contact with the substrates. Besides, the morphologies of FA nanocrystals changed from acicular to hexagonal with the exchange cycle of gel increased. Electron dispersive spectrometer analysis indicated that some sodium and carbonate ions were incorporated into the FA crystal lattices and the calcium to phosphorus ratio was approximate 1.58. The mechanical properties of the resulting FA coating were investigated through nanoindentation system, which showed the similar hardness with dentin. In conclusion, this method demonstrated a potential application to repair tooth damage in dental clinics.

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24

Malerich, Jeremiah P., Thomas J. Maimone, Gregory I. Elliott, and Dirk Trauner. "Biomimetic Synthesis of Antimalarial Naphthoquinones." Journal of the American Chemical Society 129, no. 6 (February 2007): 1836. http://dx.doi.org/10.1021/ja069018l.

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25

Ichikawa, Yoshiyasu, Tikako Kashiwagi, and Noriko Urano. "Biomimetic synthesis of agelasidine A." Journal of the Chemical Society, Perkin Transactions 1, no. 12 (1992): 1497. http://dx.doi.org/10.1039/p19920001497.

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26

Ichikawa, Yoshiyasu. "Biomimetic synthesis of theonellin isocyanide." Journal of the Chemical Society, Perkin Transactions 1, no. 16 (1992): 2135. http://dx.doi.org/10.1039/p19920002135.

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27

Adlington, Robert M., Jack E. Baldwin, Gareth J. Pritchard, Andrew J. Williams, and David J. Watkin. "A Biomimetic Synthesis of Lucidene." Organic Letters 1, no. 12 (December 1999): 1937–39. http://dx.doi.org/10.1021/ol991068q.

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28

Bell, Natalie V., W. Russell Bowman, Paul F. Coe, Andrew T. Turner, and Del Whybrow. "Synthesis of thyroxine: biomimetic studies." Canadian Journal of Chemistry 75, no. 6 (June 1, 1997): 873–83. http://dx.doi.org/10.1139/v97-105.

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The biomimetic oxidative coupling of the ethyl ester of N-acetyl-3,5-diiodotyrosine (1) to yield the ethyl ester of N-acetylthyroxine (2) has been investigated. A putative mechanism involving phenolic coupling to yield an intermediate aryloxydienone (7) followed by an E2 elimination for loss of the side chain has been proposed. Oxidative couplings with analogous 4-substituted 3,5-diiodophenols indicate that a number of mechanisms are possible; these include quinone methide intermediates and SN2 substitutions in the intermediate aryloxydienones. Rearomatization of the intermediate aryloxydienones is a strong driving force for the loss of the side chains. The results indicate that 3,5-diiodo-4-aryloxydienones are good leaving groups in E2 and SN2 mechanisms. The synthetic method provides a facile synthesis of thyroxine analogues from readily available 4-substituted 3,5-diiodophenols. Keywords: diiodotyrosine, phenolic coupling, phenoxyl radicals, thyroxine.

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29

Meier, Robin, Sebastian Strych, and Dirk Trauner. "Biomimetic Synthesis of (±)-Merochlorin B." Organic Letters 16, no. 10 (May 7, 2014): 2634–37. http://dx.doi.org/10.1021/ol500800z.

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30

Zheng, Kuan, Defeng Shen, and Ran Hong. "Biomimetic Synthesis of Lankacidin Antibiotics." Journal of the American Chemical Society 139, no. 37 (September 6, 2017): 12939–42. http://dx.doi.org/10.1021/jacs.7b08500.

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31

Wang, Xiaolei, Jie Zheng, Qiang Chen, Huaiji Zheng, Yongping He, Juan Yang, and Xuegong She. "Biomimetic Total Synthesis of (+)-Chabranol." Journal of Organic Chemistry 75, no. 15 (August 6, 2010): 5392–94. http://dx.doi.org/10.1021/jo101016g.

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32

Sofiyev, Vladimir, Gabriel Navarro, and Dirk Trauner. "Biomimetic Synthesis of the Shimalactones." Organic Letters 10, no. 1 (January 2008): 149–52. http://dx.doi.org/10.1021/ol702806v.

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33

Wanner, Martin J., and Gerrit-Jan Koomen. "Biomimetic synthesis of quinolizidine alkaloids." Tetrahedron 47, no. 39 (September 1991): 8431–42. http://dx.doi.org/10.1016/s0040-4020(01)96184-8.

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34

Jan, Jeng-Shiung, Seungju Lee, C. Shane Carr, and Daniel F. Shantz. "Biomimetic Synthesis of Inorganic Nanospheres." Chemistry of Materials 17, no. 17 (August 2005): 4310–17. http://dx.doi.org/10.1021/cm0504440.

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35

Baldwin, Jack E., Robert M. Adlington, Victoria W. W. Sham, Rodolfo Marquez, and Paul G. Bulger. "Biomimetic synthesis of (±)-aculeatin D." Tetrahedron 61, no. 9 (February 2005): 2353–63. http://dx.doi.org/10.1016/j.tet.2005.01.021.

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36

Moghimian, Pouya, Vesna Srot, Sandra J. Facey, and Peter A. van Aken. "Biomimetic Synthesis of Ceramic Composites." Microscopy and Microanalysis 23, S1 (July 2017): 1390–91. http://dx.doi.org/10.1017/s1431927617007619.

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37

Rose, Eric, Alexandra Lecas, Mélanie Quelquejeu, Alain Kossanyi, and Bernard Boitrel. "Synthesis of biomimetic heme precursors." Coordination Chemistry Reviews 178-180 (December 1998): 1407–31. http://dx.doi.org/10.1016/s0010-8545(98)00148-9.

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38

Zaremba, Charlotte M., and Galen D. Stucky. "Biosilicates and biomimetic silicate synthesis." Current Opinion in Solid State and Materials Science 1, no. 3 (June 1996): 425–29. http://dx.doi.org/10.1016/s1359-0286(96)80035-0.

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39

Zhang, Yuhan, Yonghong Guo, Zhongle Li, and Zhixiang Xie. "Biomimetic Total Synthesis of Paeoveitol." Organic Letters 18, no. 18 (August 29, 2016): 4578–81. http://dx.doi.org/10.1021/acs.orglett.6b02228.

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40

Boyd, Emily M., and Jonathan Sperry. "Biomimetic Synthesis of Dendridine A." Organic Letters 17, no. 5 (February 20, 2015): 1344–46. http://dx.doi.org/10.1021/acs.orglett.5b00300.

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41

Moses, John E., Robert M. Adlington, Raphaël Rodriguez, Serena J. Eade, and Jack E. Baldwin. "Biomimetic synthesis of (±)-9,10-deoxytridachione." Chem. Commun., no. 13 (2005): 1687–89. http://dx.doi.org/10.1039/b418988d.

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42

Tchabanenko, Kirill, Robert M. Adlington, Andrew R. Cowley, and Jack E. Baldwin. "Biomimetic Total Synthesis of (+)-Himbacine." Organic Letters 7, no. 4 (February 2005): 585–88. http://dx.doi.org/10.1021/ol047676+.

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43

Malerich, Jeremiah P., Thomas J. Maimone, Gregory I. Elliott, and Dirk Trauner. "Biomimetic Synthesis of Antimalarial Naphthoquinones." Journal of the American Chemical Society 127, no. 17 (May 2005): 6276–83. http://dx.doi.org/10.1021/ja050092y.

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44

Pepper, Henry P., Hiu C. Lam, Witold M. Bloch, and Jonathan H. George. "Biomimetic Total Synthesis of (±)-Garcibracteatone." Organic Letters 14, no. 19 (September 26, 2012): 5162–64. http://dx.doi.org/10.1021/ol302524q.

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45

Livage, Jacques. "Chemical synthesis of biomimetic forms." Comptes Rendus Palevol 8, no. 7 (October 2009): 629–36. http://dx.doi.org/10.1016/j.crpv.2008.11.009.

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46

Zhou, Xuan, Tao Xiao, Yusuke Iwama, and Yong Qin. "Biomimetic Total Synthesis of (+)-Gelsemine." Angewandte Chemie 124, no. 20 (April 4, 2012): 4993–96. http://dx.doi.org/10.1002/ange.201201736.

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47

Lam, Hiu C., Henry P. Pepper, Christopher J. Sumby, and Jonathan H. George. "Biomimetic Total Synthesis of (±)-Verrubenzospirolactone." Angewandte Chemie 129, no. 29 (February 22, 2017): 8652–55. http://dx.doi.org/10.1002/ange.201700114.

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48

Lam, Hiu C., Henry P. Pepper, Christopher J. Sumby, and Jonathan H. George. "Biomimetic Total Synthesis of (±)-Verrubenzospirolactone." Angewandte Chemie International Edition 56, no. 29 (February 22, 2017): 8532–35. http://dx.doi.org/10.1002/anie.201700114.

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49

Zhou, Xuan, Tao Xiao, Yusuke Iwama, and Yong Qin. "Biomimetic Total Synthesis of (+)-Gelsemine." Angewandte Chemie International Edition 51, no. 20 (April 4, 2012): 4909–12. http://dx.doi.org/10.1002/anie.201201736.

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50

Miyake, Fumiko Y., Kenichi Yakushijin, and David A. Horne. "Biomimetic Synthesis of Grossularines-1." Angewandte Chemie International Edition 44, no. 21 (May 20, 2005): 3280–82. http://dx.doi.org/10.1002/anie.200500055.

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