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Journal articles on the topic 'Binary Nitride'

Author: Grafiati

Published: 1 April 2023

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1

FREEMANTLE, MICHAEL. "ELUSIVE BINARY NITRIDE PREPARED." Chemical & Engineering News Archive 80, no. 20 (2002): 9. http://dx.doi.org/10.1021/cen-v080n020.p009a.

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2

Mondal, S., and A. K. Banthia. "Triethanolamine Molybdate, a New Polymeric Precursor for Molybdenum Nitride." Advanced Materials Research 29-30 (November 2007): 195–98. http://dx.doi.org/10.4028/www.scientific.net/amr.29-30.195.

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Nitrides remain a relatively unexplored class of materials primarily due to the difficulties associated with their synthesis and characterization. Several synthetic routes, including high temperature reactions, microwave assisted synthesis, and the use of plasmas, to prepare binary and ternary nitrides have been explored. Transition metal nitrides form a class of materials with unique physical properties, which give them varied applications, as high temperature ceramics, magnetic materials, superconductors or catalysts. They are commonly prepared by high temperature conventional processes, but

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Schnick, Wolfgang. "The First Nitride Spinels—New Synthetic Approaches to Binary Group 14 Nitrides." Angewandte Chemie International Edition 38, no. 22 (1999): 3309–10. http://dx.doi.org/10.1002/(sici)1521-3773(19991115)38:22<3309::aid-anie3309>3.0.co;2-u.

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4

Schwarz, Benjamin, Regina E. Hörth, Ewald Bischoff, Ralf E. Schacherl, and Eric J. Mittemeijer. "The Process of Tungsten-Nitride Precipitation upon Nitriding Ferritic Fe-0.5 at.% W Alloy." Defect and Diffusion Forum 334-335 (February 2013): 284–89. http://dx.doi.org/10.4028/www.scientific.net/ddf.334-335.284.

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The precipitation of tungsten nitride upon internal nitriding of ferritic Fe-0.5 at.% W alloy was investigated at 610°C in a flowing NH3/H2 gas mixture. Different tungsten nitrides developed successively; the thermodynamically stable hexagonal δ-WN could not be detected. The state of deformation of the surface plays an important role for the development of tungsten nitride at the surface. The morphologies of the tungsten nitrides developed at the surface and those precipitated at some depth in the specimen are different. The nitride particles at the surface exhibit mostly an equiaxed morpholog

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5

Kerdoud, Djahida, Faouzia Benkafada, Nora Boussouf, and Chahrazed Benhamideche. "Nitride Materials: Synthesis, Crystal Structures, and Optical Properties." Annales de Chimie - Science des Matériaux 46, no. 2 (2022): 103–8. http://dx.doi.org/10.18280/acsm.460206.

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Our research involves the preparation of transition metal nitrides of the composition Mn4N, NbN, Mo2N, TaN and ZrN. The synthesis of Li3N binary alkali metal nitride was also part of this work. Simple and cost-effective methods with relatively low impact on the environment have been privileged in the selection. The experimental work has focused on determining the optimum conditions of synthesis and the convenient high yield route to the desired nitrides, and ultimately improvement of the properties of the final materials. All samples were characterised by X-ray powder diffraction. Their struct

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6

Bauers, Sage R., Aaron Holder, Wenhao Sun, et al. "Ternary nitride semiconductors in the rocksalt crystal structure." Proceedings of the National Academy of Sciences 116, no. 30 (2019): 14829–34. http://dx.doi.org/10.1073/pnas.1904926116.

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Inorganic nitrides with wurtzite crystal structures are well-known semiconductors used in optical and electronic devices. In contrast, rocksalt-structured nitrides are known for their superconducting and refractory properties. Breaking this dichotomy, here we report ternary nitride semiconductors with rocksalt crystal structures, remarkable electronic properties, and the general chemical formula MgxTM1−xN (TM = Ti, Zr, Hf, Nb). Our experiments show that these materials form over a broad metal composition range, and that Mg-rich compositions are nondegenerate semiconductors with visible-range o

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7

Wang, Xinwu, Haobin Sun, Hua Zhang, et al. "Advances in binary nitride coatings for cemented carbides." Journal of Physics: Conference Series 2256, no. 1 (2022): 012020. http://dx.doi.org/10.1088/1742-6596/2256/1/012020.

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Abstract With the development of science and technology, cemented carbide tool coatings for machining are updating constantly. Different chemical elements in tool coatings have different performance. This paper introduces the current status of the use of various chemical elements in carbide tool coatings, common chemical elements include metallic elements (transition metal elements, rare-earth elements and aluminium elements) and non-metallic elements (silicon and boron). In addition, this paper presents the current status of research on related basic coatings which includes CrN, TiN, TiCN and

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8

Dziubek, K., M. Ceppatelli, D. Scelta, et al. "Binary arsenic nitride synthesized from elements under pressure." Acta Crystallographica Section A Foundations and Advances 78, a2 (2022): a180. http://dx.doi.org/10.1107/s2053273322095201.

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9

Ghufran, Muhammad, Ghulam Moeen Uddin, Syed Muhammad Arafat, Muhammad Jawad, and Abdul Rehman. "Development and tribo-mechanical properties of functional ternary nitride coatings: Applications-based comprehensive review." Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology 235, no. 1 (2020): 196–232. http://dx.doi.org/10.1177/1350650120933412.

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Friction and wear are very crucial aspects of the performance, service life, and the operational costs for a mechanical component or equipment. To reduce the friction and wear at the interface of the sliding or mating parts, different conventional binary coatings like TiN, CrN, TiC, etc., have been used in the last two decades. But ternary nitride coatings have replaced the binary coatings due to better tribo-mechanical properties. Now, ternary nitride coatings are being extensively used in several fields such as cutting tools, machinery parts, orthopedic implants, microelectronics, marine equ

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10

Schwarz, Ulrich, Kai Guo, William P. Clark та ін. "Ferromagnetic ε-Fe2MnN: High-Pressure Synthesis, Hardness and Magnetic Properties". Materials 12, № 12 (2019): 1993. http://dx.doi.org/10.3390/ma12121993.

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The iron manganese nitride Fe2MnN was obtained by high-pressure–high-temperature synthesis from ζ-Fe2N and elemental Mn at 15(2) GPa and 1573(200) K. The phase crystallizes isostructural to binary ε-Fe3N. In comparison to the corresponding binary iron nitride, the microhardness of ε-Fe2MnN is reduced to 6.2(2) GPa. Above about 800 K the ternary compound decomposes exothermally under loss of nitrogen. ε-Fe2MnN is ferromagnetic with a Curie temperature of roughly 402 K.

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11

Leigh, G. J., and P. J. Stotereau. "Investigation of the oxidative pyrolysis of binary metal nitrides, and particularly of boron nitride." Journal of Analytical and Applied Pyrolysis 35, no. 1 (1995): 61–76. http://dx.doi.org/10.1016/0165-2370(95)00902-q.

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12

Schnick, Wolfgang. "ChemInform Abstract: The First Nitride Spinels - New Synthetic Approaches to Binary Group 14 Nitrides." ChemInform 31, no. 7 (2010): no. http://dx.doi.org/10.1002/chin.200007247.

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13

Akıncı, Özden, H. Hakan Gürel, and Hilmi Ünlü. "Tight Binding Modelling of Energy Band Structure in Nitride Heterostructures." Journal of Nanoscience and Nanotechnology 8, no. 2 (2008): 540–48. http://dx.doi.org/10.1166/jnn.2008.a223.

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We studied the electronic structure of group III–V nitride ternary/binary heterostructures by using a semi-empirical sp3s* tight binding theory, parametrized to provide accurate description of both valence and conductions bands. It is shown that the sp3s* basis, along with the second nearest neighbor (2NN) interactions, spin-orbit splitting of cation and anion atoms, and nonlinear composition variations of atomic energy levels and bond length of ternary, is sufficient to describe the electronic structure of III–V ternary/binary nitride heterostructures. Comparison with experiment shows that ti

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14

Gregoryanz, Eugene, Chrystele Sanloup, M. Somayazulu, et al. "Synthesis and characterization of a binary noble metal nitride." Nature Materials 3, no. 5 (2004): 294–97. http://dx.doi.org/10.1038/nmat1115.

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15

Kroke, Edwin. "gt-C3N4-The First Stable Binary Carbon(IV) Nitride." Angewandte Chemie International Edition 53, no. 42 (2014): 11134–36. http://dx.doi.org/10.1002/anie.201406427.

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16

Şenel, Mahmut Can, Mevlüt Gürbüz, and Erdem Koç. "Fabrication and characterization of aluminum hybrid composites reinforced with silicon nitride/graphene nanoplatelet binary particles." Journal of Composite Materials 53, no. 28-30 (2019): 4043–54. http://dx.doi.org/10.1177/0021998319853329.

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In this study, pure aluminum was reinforced with pure silicon nitride (varying from 1 to 12 wt%), pure graphene nanoplatelets (changing from 0.1 to 0.5 wt%), and their hybrid form (silicon nitride/graphene nanoplatelets) by using powder metallurgy method. The results show that Vickers hardness increased to 57.5 ± 3 HV (Al-9Si3N4) and 57 ± 2.5 HV (Al-0.1GNPs) from 28 ± 2 HV (pure aluminum). Similarly, ultimate compressive strength of the pure silicon nitride and pure graphene nanoplatelet-reinforced aluminum composite was improved to 268 ± 6 MPa (Al-9Si3N4) and 138 ± 4 MPa (Al-0.5GNPs) from 106

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17

Du, Jin, Zheng Huan Wu, and Quan Wang. "Exploration of Thermal Degradation Kinetics of Epoxy Resin Composites." Key Engineering Materials 904 (November 22, 2021): 202–6. http://dx.doi.org/10.4028/www.scientific.net/kem.904.202.

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The thermal degradation process of epoxy resin/intumescent flame retardant/flake graphite/hexagonal boron nitride (EP/IFR/FGP/h-BN) was analyzed by thermogravimetry. The effects of binary nano flake graphite/hexagonal boron nitride as synergistic flame retardant on the thermal stability. Flynn wall Ozawa method was used to calculate the activation energy of thermal degradation kinetics of EP/IFR/FGP/h-BN. The mechanism functions of the EP/IFR/FGP/h-BN in different reaction stages were determined according to Malek method, and the thermal degradation mechanism of EP/IFR/FGP/h-BN was obtained. T

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18

Dong, Yuanyuan, Yijie Deng, Jianhuang Zeng, Huiyu Song, and Shijun Liao. "A high-performance composite ORR catalyst based on the synergy between binary transition metal nitride and nitrogen-doped reduced graphene oxide." Journal of Materials Chemistry A 5, no. 12 (2017): 5829–37. http://dx.doi.org/10.1039/c6ta10496g.

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19

Suda, Jun, and Masahiro Horita. "Polytype Replication in Heteroepitaxial Growth of Nonpolar AlN on SiC." MRS Bulletin 34, no. 5 (2009): 348–52. http://dx.doi.org/10.1557/mrs2009.98.

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AbstractZinc-blende and wurtzite are the most common structures for binary compound semiconductors. Aluminum nitrides (AIN), one of the most promising materials for deep ultraviolet light-emitting diodes, have a wurtzite structure as an equilibrium phase due to its strong ionicity. Silicon carbide (SiC) is widely used as a substrate for heteroepitaxial growth of AlN, since SiC has a hexagonal structure whose lattice constant is close to that of AIN. Different from other compound semiconductors, SiC can have many different crystalline structures, called polytypism. Among various polytypes of Si

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20

AHMED, RASHID, FAZAL-E-ALEEM, HARIS RASHID, H. AKBARZADEH, and S. JAVAD HASHEMIFAR. "STRUCTURAL PROPERTIES OF III-NITRIDE BINARY COMPOUNDS: A COMPREHENSIVE STUDY." Modern Physics Letters B 23, no. 08 (2009): 1111–27. http://dx.doi.org/10.1142/s0217984909019247.

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Very little information is available about the structural properties of III-nitride binary compounds in the rock-salt phase. We report/review a comprehensive theoretical study of structural properties of these compounds in rock-salt, zinc-blende and wurtzite phases. Calculations have been made using full-potential linearized augmented plane wave plus local orbitals (FP-L(APW+lo)) method as embodied in WIEN2k code framed within density functional theory (DFT). In this approach of calculations, local density approximation (LDA) [J. P. Perdew and Y. Wang, Phys. Rev. B45 (1992) 13244] and generali

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21

Lu, Jun, Zhigang Zak Fang, Young Joon Choi, and Hong Yong Sohn. "Potential of Binary Lithium Magnesium Nitride for Hydrogen Storage Applications." Journal of Physical Chemistry C 111, no. 32 (2007): 12129–34. http://dx.doi.org/10.1021/jp0733724.

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22

Steinbrenner, U., and A. Simon. "Ba3N - a New Binary Nitride of an Alkaline Earth Metal." Zeitschrift für anorganische und allgemeine Chemie 624, no. 2 (1998): 228–32. http://dx.doi.org/10.1002/(sici)1521-3749(199802)624:2<228::aid-zaac228>3.0.co;2-8.

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23

Xiao, Wen-Zhi, Gang Xiao, Qing-Yan Rong, and Ling-Ling Wang. "Theoretical discovery of novel two-dimensional VA-N binary compounds with auxiticity." Physical Chemistry Chemical Physics 20, no. 34 (2018): 22027–37. http://dx.doi.org/10.1039/c8cp04158j.

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24

Chen, Yan, Huasong Qin, Juzheng Song, Zeming Liu, Yilun Liu, and Qing-Xiang Pei. "Exploring the structure–property relationship of three-dimensional hexagonal boron nitride aerogels with gyroid surfaces." Nanoscale 12, no. 18 (2020): 10180–88. http://dx.doi.org/10.1039/d0nr01055c.

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25

Sultan, Adil, Sharique Ahmad, Tarique Anwer, and Faiz Mohammad. "Binary doped polypyrrole and polypyrrole/boron nitride nanocomposites: preparation, characterization and application in detection of liquefied petroleum gas leaks." RSC Advances 5, no. 128 (2015): 105980–91. http://dx.doi.org/10.1039/c5ra21173e.

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We report an electrical conductivity based rapid response liquefied petroleum gas (LPG) sensor using binary doped polypyrrole and polypyrrole/boron nitride (PPy/BN) nanocomposites as the conductive material.

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26

Lao, Xun, Xiao Yan, Jiao Xie, and Ya Li Li. "Fabrication of Iron Carbide and Nitride Ceramics with Controlled Magnetic Properties by the Non-Oxide Sol-Gel Process." Key Engineering Materials 512-515 (June 2012): 1429–33. http://dx.doi.org/10.4028/www.scientific.net/kem.512-515.1429.

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The carbodiimide-based non-oxide sol-gel process is a novel route to non-oxide nitride and carbide ceramics. This process has been applied to fabricate ternary or binary silicon based nitride and carbide ceramics. Based on this non-oxide sol-gel process, iron carbide and nitride have been fabricated by reaction of iron trichloride with bis(trimethylsilyl)carbodiimide to form FeCN gel followed by pyrolysis in argon flow at different temperatures. The iron carbide material obtained at 700 °C exhibits hard ferromagnetic properties whereas α-iron along with iron nitride formed at 1300 °C shows sof

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27

Schön, Johann, Alexander Hannemann, Guneet Sethi, Vladimirovich Pentin, and Martin Jansen. "Modelling structure and properties of amorphous silicon boron nitride ceramics." Processing and Application of Ceramics 5, no. 2 (2011): 49–61. http://dx.doi.org/10.2298/pac1102049s.

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Silicon boron nitride is the parent compound of a new class of high-temperature stable amorphous ceramics constituted of silicon, boron, nitrogen, and carbon, featuring a set of properties that is without precedent, and represents a prototypical random network based on chemical bonds of predominantly covalent character. In contrast to many other amorphous materials of technological interest, a-Si3B3N7 is not produced via glass formation, i.e. by quenching from a melt, the reason being that the binary components, BN and Si3N4, melt incongruently under standard conditions. Neither has it been po

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28

Leitner, Jindřich. "Binary AIII nitride solid solutions: Estimation of the excess Gibbs energy." Journal of Physics and Chemistry of Solids 58, no. 9 (1997): 1329–34. http://dx.doi.org/10.1016/s0022-3697(97)00035-8.

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29

Probst, J., U. Gbureck, and R. Thull. "Binary nitride and oxynitride PVD coatings on titanium for biomedical applications." Surface and Coatings Technology 148, no. 2-3 (2001): 226–33. http://dx.doi.org/10.1016/s0257-8972(01)01357-3.

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30

Roul, Basanta, Mahesh Kumar, Mohana K. Rajpalke, Thirumaleshwara N. Bhat, and S. B. Krupanidhi. "Binary group III-nitride based heterostructures: band offsets and transport properties." Journal of Physics D: Applied Physics 48, no. 42 (2015): 423001. http://dx.doi.org/10.1088/0022-3727/48/42/423001.

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31

Ashritha, M. G., and K. Hareesh. "A review on Graphitic Carbon Nitride based binary nanocomposites as supercapacitors." Journal of Energy Storage 32 (December 2020): 101840. http://dx.doi.org/10.1016/j.est.2020.101840.

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32

He, Jianyun, Shijun Liu, Yunqi Li, et al. "Fabrication of boron nitride nanosheet/polymer composites with tunable thermal insulating properties." New Journal of Chemistry 43, no. 12 (2019): 4878–85. http://dx.doi.org/10.1039/c8nj06236f.

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33

Schultz-Coulon, Verena, and Wolfgang Schnick. "CaMg2N2 – ein gemischtes Erdalkalimetallnitrid mit anti-La2O3-Struktur / CaMg2N2 – a Mixed Alkaline-Earth Metal Nitride with anti-La2O3 Structure." Zeitschrift für Naturforschung B 50, no. 4 (1995): 619–22. http://dx.doi.org/10.1515/znb-1995-0425.

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CaMg2N2 (trigonal, P3̄ m 1 (Nr. 164); a = 354.046(1), c = 609.079(2) pm; Z = 1) is isotypic to the anti-La2O3 structure with octahedral and tetrahedral coordination for Ca2+ and Mg2+ ions, respectively. The compound has been prepared by the reaction o f the binary nitrides Ca3N2 and Mg3N2 (molar ratio 1:2) in a tungsten crucible under a pure nitrogen atmosphere at 1050 °C. The formation of the solid CaMg2N2 may be interpreted in analogy to reactions o f related oxides as an acid-base reaction between the binary nitrides with different coordination tendencies of Ca2+ and Mg2+ ions. An analysis

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34

Justice, J., A. Kadiyala, J. Dawson, and D. Korakakis. "Group III-Nitride Based Electronic and Optoelectronic Integrated Circuits for Smart Lighting Applications." MRS Proceedings 1492 (2013): 123–28. http://dx.doi.org/10.1557/opl.2013.369.

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ABSTRACTWith general lighting applications being responsible for over 20% of the energy consumption in the United States, advances in solid-state lighting have the potential for considerable energy and cost savings. The United States Department of Energy predicts that the increased use of solid state lighting will result in a 46% lighting consumption energy savings by the year 2030. Smart lighting systems have the potential for reducing energy costs while also providing a means for short distance data transmission via free space optics. The group III-nitride (III-N) family of materials, includ

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35

Lo Nigro, Raffaella, Patrick Fiorenza, Giuseppe Greco, Emanuela Schilirò, and Fabrizio Roccaforte. "Structural and Insulating Behaviour of High-Permittivity Binary Oxide Thin Films for Silicon Carbide and Gallium Nitride Electronic Devices." Materials 15, no. 3 (2022): 830. http://dx.doi.org/10.3390/ma15030830.

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High-κ dielectrics are insulating materials with higher permittivity than silicon dioxide. These materials have already found application in microelectronics, mainly as gate insulators or passivating layers for silicon (Si) technology. However, since the last decade, the post-Si era began with the pervasive introduction of wide band gap (WBG) semiconductors, such as silicon carbide (SiC) and gallium nitride (GaN), which opened new perspectives for high-κ materials in these emerging technologies. In this context, aluminium and hafnium oxides (i.e., Al2O3, HfO2) and some rare earth oxides (e.g.,

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36

Ahmad, Ashfaq, Pawel Strak, Kamil Koronski, et al. "Critical Evaluation of Various Spontaneous Polarization Models and Induced Electric Fields in III-Nitride Multi-Quantum Wells." Materials 14, no. 17 (2021): 4935. http://dx.doi.org/10.3390/ma14174935.

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In this paper, ab initio calculations are used to determine polarization difference in zinc blende (ZB), hexagonal (H) and wurtzite (WZ) AlN-GaN and GaN-InN superlattices. It is shown that a polarization difference exists between WZ nitride compounds, while for H and ZB lattices the results are consistent with zero polarization difference. It is therefore proven that the difference in Berry phase spontaneous polarization for bulk nitrides (AlN, GaN and InN) obtained by Bernardini et al. and Dreyer et al. was not caused by the different reference phase. These models provided absolute values of

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37

Jiang, Ming, Yingjie Li, Zhiyi Lu, Xiaoming Sun, and Xue Duan. "Binary nickel–iron nitride nanoarrays as bifunctional electrocatalysts for overall water splitting." Inorganic Chemistry Frontiers 3, no. 5 (2016): 630–34. http://dx.doi.org/10.1039/c5qi00232j.

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Electrochemical water splitting provides a facile method for high-purity hydrogen production, but electro-catalysts with a stable bifunctional activity towards both oxygen and hydrogen evolution have been rarely developed.

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38

Wang, Wei, Xucai Kan, Xiansong Liu та ін. "Analysis of the Griffiths–like phase observed in binary ε-Fe2N nitride". Applied Physics Letters 117, № 12 (2020): 122408. http://dx.doi.org/10.1063/5.0021190.

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39

Rupp, T., G. Henn, and H. Schröder. "Laser-induced reactive epitaxy of binary and ternary group III nitride heterostructures." Applied Surface Science 186, no. 1-4 (2002): 429–34. http://dx.doi.org/10.1016/s0169-4332(01)00778-4.

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40

Fan, Changzeng. "Valence electronic structure and cohesive property of a binary noble metal nitride." Chinese Science Bulletin 50, no. 11 (2005): 1079. http://dx.doi.org/10.1360/982004-622.

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41

Niewa, Rainer. "Na3N—An Original Synthetic Route for a Long Sought After Binary Nitride." Angewandte Chemie International Edition 41, no. 10 (2002): 1701–2. http://dx.doi.org/10.1002/1521-3773(20020517)41:10<1701::aid-anie1701>3.0.co;2-9.

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42

STEINBRENNER, U., and A. SIMON. "ChemInform Abstract: Ba3N - A New Binary Nitride of an Alkaline Earth Metal." ChemInform 29, no. 17 (2010): no. http://dx.doi.org/10.1002/chin.199817004.

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43

Wallenberger, Frederick T., and Paul C. Nordine. "Amorphous silicon nitride fibers grown from the vapor phase." Journal of Materials Research 9, no. 3 (1994): 527–30. http://dx.doi.org/10.1557/jmr.1994.0527.

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Using high reactor pressures (>1 bar) and a unique rate control mechanism, three fibers were recently obtained by laser assisted chemical vapor deposition (LCVD) having elemental (i.e., boron, carbon, and silicon) compositions, small diameters (>9 μm), and surprisingly high growth rates (0.3–1.1 mm/s). By reacting silane and ammonia at high pressures (>1 bar) near the focus of a Nd-YAG laser beam, we have now obtained the first LCVD fibers with binary (i.e., silicon-nitrogen and silicon nitride) compositions having small diameters and high growth rates (0.34–0.74 mm/s). These fibers w

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44

Lyashkov, Kirill, Valery Shabashov, Andrey Zamatovskii, et al. "Structure-Phase Transformations in the Course of Solid-State Mechanical Alloying of High-Nitrogen Chromium-Manganese Steels." Metals 11, no. 2 (2021): 301. http://dx.doi.org/10.3390/met11020301.

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The solid-state mechanical alloying (MA) of high-nitrogen chromium-manganese austenite steel—MA in a planetary ball mill, —was studied by methods of Mössbauer spectroscopy and transmission electron microscopy (TEM). In the capacity of a material for the alloying we used mixtures of the binary Fe–Mn and Fe–Cr alloys with the nitrides CrN (Cr2N) and Mn2N. It is shown that ball milling of the mixtures has led to the occurrence of the α → γ transitions being accompanied by the (i) formation of the solid solutions supersaturated with nitrogen and by (ii) their decomposition with the formation of se

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45

Torchane, L., P. Bilger, J. Dulcy, and M. Gantois. "Control of iron nitride layers growth kinetics in the binary Fe-N system." Metallurgical and Materials Transactions A 27, no. 7 (1996): 1823–35. http://dx.doi.org/10.1007/bf02651932.

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46

Huang, Xinfan, Zhifeng Li, Wenqi Gao, Jin Zhou, Xiaofeng Gu, and Kunji Chen. "Silicon Nitride Binary-Phase Optical Elements with Both Functions of Splitting and Foscussing." Physica Status Solidi (a) 147, no. 2 (1995): K111—K114. http://dx.doi.org/10.1002/pssa.2211470247.

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47

Low, It Meng, and Wei Kong Pang. "Thermal Stability of MAX Phases." Key Engineering Materials 617 (June 2014): 153–58. http://dx.doi.org/10.4028/www.scientific.net/kem.617.153.

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The susceptibility of MAX phases to thermal dissociation at 1300-1550 °C in high vacuum has been studied using in-situ neutron diffraction. Above 1400 °C, MAX phases decomposed to binary carbide (e.g. TiCx) or binary nitride (e.g. TiNx), primarily through the sublimation of A-elements such as Al or Si, which results in a porous surface layer of MXx being formed. Positive activation energies were determined for decomposed MAX phases with coarse pores but a negative activation energy when the pore size was less than 1.0 μm. The insights for tailor-design of MAX phases with controlled thermal sta

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48

Weitzer, F., K. Remschnig, J. C. Schuster, and P. Rogl. "Phase equilibria and structural chemistry in the ternary systems M–Si–N and M–B–N (M = Al, Cu, Zn, Ag, Cd, In, Sn, Sb, Au, Tl, Pb, Bi)." Journal of Materials Research 5, no. 10 (1990): 2152–59. http://dx.doi.org/10.1557/jmr.1990.2152.

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Phase equilibria in the ternary systems M–Si–N and M–B–N (M = Cu, Ag, Au, Zn, Cd, Al, In, Tl, Sn, Pb, Sb, and Bi) at temperatures 50–100 °C below the melting point of the metal components were investigated by means of x-ray powder analysis and are represented in the form of isothermal sections. No ternary compound formation was observed in any of the combinations M–Si–N and M–B–N. Silicon nitride and boron nitride, respectively, coexist with all metals investigated and with all binary compounds stable at the chosen temperatures. From unit cell dimensions negligible mutual solid solubilities ar

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Bastin, G. F., and H. J. M. Heijligers. "Quantitative EPMA of nitrogen : A tricky element in the electron-probe microanalyzer." Proceedings, annual meeting, Electron Microscopy Society of America 50, no. 2 (1992): 1622–23. http://dx.doi.org/10.1017/s0424820100132741.

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Among the ultra-light elements B, C, N, and O nitrogen is the most difficult element to deal with in the electron probe microanalyzer. This is mainly caused by the severe absorption that N-Kα radiation suffers in carbon which is abundantly present in the detection system (lead-stearate crystal, carbonaceous counter window). As a result the peak-to-background ratios for N-Kα measured with a conventional lead-stearate crystal can attain values well below unity in many binary nitrides . An additional complication can be caused by the presence of interfering higher-order reflections from the metal

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Pogrebnjak, Alexander, Kateryna Smyrnova, and Oleksandr Bondar. "Nanocomposite Multilayer Binary Nitride Coatings Based on Transition and Refractory Metals: Structure and Properties." Coatings 9, no. 3 (2019): 155. http://dx.doi.org/10.3390/coatings9030155.

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One area of constant interest in many fields of industry is development of functional multilayer coatings that possess excellent performance characteristics. That is why in our brief review the results of studies of structure and properties of multilayer structures based on binary nitrides of transition or refractory metals obtained by various physical-vapor deposition (PVD) techniques are presented. The influence of substrate temperature, substrate bias voltage, bilayer thickness and interface boundaries on the structure of coatings and their properties, such as hardness, plasticity, wear and

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