Academic literature on the topic 'BENZIPORPHODIMETHENES'

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Journal articles on the topic "BENZIPORPHODIMETHENES"

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Chang, Gao-Fong, Anil Kumar, Wei-Min Ching, Han-Wei Chu, and Chen-Hsiung Hung. "Tetramethyl-m-benziporphodimethene and Isomeric α,β-Unsaturated γ-Lactam Embedded N-Confused Tetramethyl-m-benziporphodimethenes." Chemistry - An Asian Journal 4, no. 1 (January 5, 2009): 164–73. http://dx.doi.org/10.1002/asia.200800279.

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Sharma, Ravi Kumar, Anurag Maurya, Paulraj Rajamani, Mohan Singh Mehata, and Anil Kumar. "meta-Benziporphodimethenes: New Cell-Imaging Porphyrin Analogue Molecules." ChemistrySelect 1, no. 13 (August 16, 2016): 3502–9. http://dx.doi.org/10.1002/slct.201600812.

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Sharma, Ravi Kumar, Lale Kiran Gajanan, Mohan Singh Mehata, Firasat Hussain, and Anil Kumar. "Synthesis, characterization and fluorescence turn-on behavior of new porphyrin analogue: meta -benziporphodimethenes." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 169 (December 2016): 58–65. http://dx.doi.org/10.1016/j.saa.2016.06.020.

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Ahluwalia, Deepali, Anil Kumar, Sudhir G. Warkar, Milind M. Deshmukh, and Arijit Bag. "Uncovering the geometrical aspects of intramolecular hydrogen bond in meta-benziporphodimethenes through molecular tailoring approach." Computational and Theoretical Chemistry 1209 (March 2022): 113631. http://dx.doi.org/10.1016/j.comptc.2022.113631.

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Ahluwalia, Deepali, Anil Kumar, Sudhir G. Warkar, and Milind M. Deshmukh. "Effect of substitutions on the geometry and intramolecular hydrogen bond strength in meta-benziporphodimethenes: A new porphyrin analogue." Journal of Molecular Structure 1220 (November 2020): 128773. http://dx.doi.org/10.1016/j.molstruc.2020.128773.

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Ahluwalia, Deepali, Anil Kumar, and Sudhir Gopalrao Warkar. "Recent developments in meta-benziporphodimethene: A new porphyrin analogue." Journal of Molecular Structure 1228 (March 2021): 129672. http://dx.doi.org/10.1016/j.molstruc.2020.129672.

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Hung, Chen-Hsiung, Gao-Fong Chang, Anil Kumar, Geng-Fong Lin, Li-Yang Luo, Wei-Min Ching, and Eric Wei-Guang Diau. "m-Benziporphodimethene: a new porphyrin analogue fluorescence zinc(ii) sensor." Chem. Commun., no. 8 (2008): 978–80. http://dx.doi.org/10.1039/b714412a.

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Kumar, Anil, Chen-Hsiung Hung, Shikha Rana, and Milind M. Deshmukh. "Study on the structure, stability and tautomerisms of meta-benziporphodimethene and N-Confused isomers containing γ–lactam ring." Journal of Molecular Structure 1187 (July 2019): 138–50. http://dx.doi.org/10.1016/j.molstruc.2019.03.064.

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9

Chang, Gao-Fong, Chun-Hung Wang, Hung-Chieh Lu, Lou-Sing Kan, Ito Chao, Wei Hao Chen, Anil Kumar, Liyang Lo, Mira Anne C. dela Rosa, and Chen-Hsiung Hung. "Factors That Regulate the Conformation of m-Benziporphodimethene Complexes: Agostic Metal-Arene Interaction, Hydrogen Bonding, and η2,π Coordination." Chemistry - A European Journal 17, no. 40 (August 23, 2011): 11332–43. http://dx.doi.org/10.1002/chem.201100780.

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Rana, Shikha, Ravi Kumar Sharma, Natalia Fridman, and Anil Kumar. "Structural characterization and bioimaging of Zn 2+ using meta ‐benziporphodimethene analogue." Luminescence, September 6, 2022. http://dx.doi.org/10.1002/bio.4382.

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Dissertations / Theses on the topic "BENZIPORPHODIMETHENES"

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AHLUWALIA, DEEPALI. "SYNTHESIS AND COMPUTATIONAL STUDIES OF FREE-BASE meta-BENZIPORPHODIMETHENES AND THEIR METAL COMPLEXES." Thesis, 2022. http://dspace.dtu.ac.in:8080/jspui/handle/repository/19714.

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This thesis begins with presenting a thorough review of m-BPDM analogues and their metal complexes. The literature review led us to the foundation of research gap. The studies were then diverted towards finding out the factors that could enhance the stability of the free base analogues of m-BPDM systems. Hence, in the next two chapters (4 and 5) the effect of substitutions at meso and C3-positions, studied computationally, has been presented. Molecular tailoring approach has been incorporated in order to find out the intramolecular hydrogen bond energies. The energies so obtained have been correlated with other factors obtained from the optimized geometry’s results, like the study of non-covalent interactions (NCI), frontier molecular orbital (FMO) visualization, molecular electrostatic surface potential (MESP) etc. We then moved to the synthesis of a new sterically hindered analogue of m-BPDM and its zinc and cadmium chloride complexes, viz. Chapter 6 of this thesis. The synthesis was confirmed by UV-Vis, 1H-NMR and mass spectrometry. The X-ray solid state structures stated the presence of two conformers of m-BPDM viz. syn and anti. It was found that crystal structures constituted varied conformers depending upon the group present at sp 3 meso carbon atoms. Thus, through chapter 7, we intend to understand the effect of substitution at meso-carbon atoms on the metalated (Zn(II) and Cd(II)) m-BPDM conformer stability.
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2

Lin, Geng-Fong, and 林庚鋒. "Design and Synthesis of m-Benziporphodimethene and Tripyrrinone Derivatives as Zn2+ Fluorescent Sensor." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/91476653485602130910.

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3

Chiang, Pei-Chun, and 江佩純. "Study of Porphyrin Analogue: Application of m-Benziporphodimethene Toward In-Vitro Zinc Sensing and Structural Diversity of [38]-N4S4-Octaphyrin." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/36264534307663851699.

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Abstract:
碩士
國立中央大學
化學研究所
97
Zinc is an essential metal ion in biology system. Over two hundred enzymes contain zinc in their active site in human body. They play important roles in bio-relate catalytic reactions. In this thesis, we demonstrate a new porphyrin analogue, m-benziporphodimethene (BPDM), as a highly selective fluorescence sensor for zinc ion. When zinc(2+) coordinated with BPDM to form a stable metal complex, the excitation by long wavelength light emits long wavelength fluorescence through chelation-enchanced fluorescence effect. To confirm the penetration of compounds into cells, we treat BPDM-Zn into medium of HeLa cell before incubation and detect the fluorescence by a high performance confocal microscope. In addition, we study the 24 hours cell toxicity of DMSO and BPDM-COOH in HeLa cell measured by MTT assay and ELISA reader. Finally, we also utilized BPDM-COOH as a sensor to trace the apoptotic process in HeLa cell. In the second chapter, we successfully synthesize a heteroatom substituted expanded porphyrin, [38]octaphyrin(1,1,1,1,1,1,1,1), embeding four nitrogen atoms and four sulfur atoms in the central core, which confirmed by one dimension 1H NMR, two dimensions 1H−1H COSY, 1H−13C HSQC, 1H−13C HMBC NMR spectra and single crystal structure. Interestingly, variable temperature 1H NMR experiment demonstrated a temperature dependent molecular structure ring current changes. Additionally, protonation by HClO4 also affects the structure and aromaticity of [38]N4S4-octaphyrin according to UV-vis and 1H−NMR spectroscopic data.
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