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1

Liu, Yi, and Rudolf Holze. "Metal-Ion Batteries." Encyclopedia 2, no. 3 (September 15, 2022): 1611–23. http://dx.doi.org/10.3390/encyclopedia2030110.

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Metal-ion batteries are systems for electrochemical energy conversion and storage with only one kind of ion shuttling between the negative and the positive electrode during discharge and charge. This concept also known as rocking-chair battery has been made highly popular with the lithium-ion battery as its most popular example. The principle can also be applied with other cations both mono- and multivalent. This might have implications and advantages in terms of increased safety, lower expenses, and utilizing materials, in particular metals, not being subject to resource limitations.
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2

Kiai, Maryam Sadat, Omer Eroglu, and Navid Aslfattahi. "Metal-Ion Batteries: Achievements, Challenges, and Prospects." Crystals 13, no. 7 (June 23, 2023): 1002. http://dx.doi.org/10.3390/cryst13071002.

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A new type of battery known as metal-ion batteries promises better performance than existing batteries. In terms of energy storage, they could prove useful and eliminate some of the problems existing batteries face. This review aims to help academics and industry work together better. It will propose ways to measure the performance of metal-ion batteries using important factors such as capacity, convertibility, Coulombic efficiency, and electrolyte consumption. With the development of technology, a series of metal ion-based batteries are expected to hit the market. This review presents the latest innovative research findings on the fabrication of metal-ion batteries with new techniques.
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3

Yang, Qingyun, Yanjin Liu, Hong Ou, Xueyi Li, Xiaoming Lin, Akif Zeb, and Lei Hu. "Fe-Based metal–organic frameworks as functional materials for battery applications." Inorganic Chemistry Frontiers 9, no. 5 (2022): 827–44. http://dx.doi.org/10.1039/d1qi01396c.

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This review presents a comprehensive discussion on the development and application of pristine Fe-MOFs in lithium-ion batteries, sodium-ion batteries, potassium-ion batteries, metal–air batteries and lithium–sulfur batteries.
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4

M Nishtha Singh, M. "An Investigation into Sodium-Metal Battery as an Alternative to Lithium-Ion Batteries." International Journal of Science and Research (IJSR) 10, no. 1 (January 27, 2021): 110–15. https://doi.org/10.21275/sr21102173054.

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5

Chen, Qiang. "Investigation of High-Performance Electrode Materials: Processing and Storage Mechanism." Materials 15, no. 24 (December 16, 2022): 8987. http://dx.doi.org/10.3390/ma15248987.

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The scope of the Special Issue entitled “Investigation of High-Performance Electrode Materials: Processing and Storage Mechanism” includes the research on electrodes of high-performance electrochemical energy storage and conversion devices (metal ion batteries, non-metallic ion batteries, metal–air batteries, supercapacitors, photocatalysis, electrocatalysis, etc [...]
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6

Hu, Shukai. "Mxenes applications in different metal ion batteries." Applied and Computational Engineering 3, no. 1 (May 25, 2023): 336–40. http://dx.doi.org/10.54254/2755-2721/3/20230537.

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Mxenes, with unique two-dimensional structures, possess excellent electrical conductivity and low diffusion barriers, which are potential materials used in different metal ion batteries. Herein this paper focuses on synthesising MXenes applications through a literature review method. In relevant analysis, Mxenes can be Constructed in Ultrathin Layered with TiN in Heterostructure to Facilitate the Favorable Catalytic Capability of LithiumSulfur Batteries. For Potassium-Ion Batteries, MXene coated in Carbon to form a Three-Dimensional MXene/Iron Selenide Ball with CoreShell Structure shows a high reversible capacity with significant cycle stability. Ti3C2Tx MXene Electrolyte Additive prevents zinc ion batteries from Zinc Dendrite Deposition. Lastly, customizing the MXene nitrogen terminals for Na-Ion Batteries facilitates fast charging and stable cycling even when the temperature is low.
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7

Somo, Thabang Ronny, Tumiso Eminence Mabokela, Daniel Malesela Teffu, Tshepo Kgokane Sekgobela, Brian Ramogayana, Mpitloane Joseph Hato, and Kwena Desmond Modibane. "A Comparative Review of Metal Oxide Surface Coatings on Three Families of Cathode Materials for Lithium Ion Batteries." Coatings 11, no. 7 (June 22, 2021): 744. http://dx.doi.org/10.3390/coatings11070744.

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In the recent years, lithium-ion batteries have prevailed and dominated as the primary power sources for mobile electronic applications. Equally, their use in electric resources of transportation and other high-level applications is hindered to some certain extent. As a result, innovative fabrication of lithium-ion batteries based on best performing cathode materials should be developed as electrochemical performances of batteries depends largely on the electrode materials. Elemental doping and coating of cathode materials as a way of upgrading Li-ion batteries have gained interest and have modified most of the commonly used cathode materials. This has resulted in enhanced penetration of Li-ions, ionic mobility, electric conductivity and cyclability, with lesser capacity fading compared to traditional parent materials. The current paper reviews the role and effect of metal oxides as coatings for improvement of cathode materials in Li-ion batteries. For layered cathode materials, a clear evaluation of how metal oxide coatings sweep of metal ion dissolution, phase transitions and hydrofluoric acid attacks is detailed. Whereas the effective ways in which metal oxides suppress metal ion dissolution and capacity fading related to spinel cathode materials are explained. Lastly, challenges faced by olivine-type cathode materials, namely; low electronic conductivity and diffusion coefficient of Li+ ion, are discussed and recent findings on how metal oxide coatings could curb such limitations are outlined.
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8

Zhang, Xin, Yongan Yang, and Zhen Zhou. "Towards practical lithium-metal anodes." Chemical Society Reviews 49, no. 10 (2020): 3040–71. http://dx.doi.org/10.1039/c9cs00838a.

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Lithium ion batteries cannot meet the ever increasing demands of human society. Thus batteries with Li-metal anodes are eyed to revive. Here we summarize the recent progress in developing practical Li-metal anodes for various Li-based batteries.
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9

Wu, Yuchen. "Application of Theoretical Computational Simulations in Lithium Metal Batteries." Applied and Computational Engineering 23, no. 1 (November 7, 2023): 287–92. http://dx.doi.org/10.54254/2755-2721/23/20230668.

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In the area of high energy density batteries, lithium metal has attracted a lot of interest as an electrode material. But since lithium is so reactive, lithium metal batteries frequently have safety problems like thermal runaway, particularly under conditions such as overcharging, over-discharging, high temperatures, and mechanical impact. These safety issues can lead to dangerous situations such as battery explosion and fire. Furthermore, lithium-metal batteries are prone to dendrite development during the cycling process, which can pierce the separator and result in internal short-circuits, shortening the battery's cycle life. Lithium-metal battery use is strongly constrained by these important problems. To overcome these challenges, researchers are exploring various strategies, such as developing new electrolytes and additives, designing new battery structures, and exploring new anode materials. Computational simulations have emerged as a powerful tool to aid in this research. This review summarizes the recent applications of computational simulations in lithium metal batteries. Specifically, molecular dynamics (MD) and first-principles calculations have been widely employed to study key issues such as interface reactions, ion transport, and dendrite formation in lithium batteries. Additionally, this review discusses recent research directions in new types of ion electrolytes that can effectively address the safety concerns of lithium batteries and increase energy density, while still facing challenges in interface resistance and conductivity. The discussion of potential avenues for future research that will be pursued finishes this paper. These possibilities include multiscale simulations, the creation and manufacturing of new electrolyte materials, and the functional modification of lithium-metal anode surfaces.
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10

Landmann, Daniel, Enea Svaluto-Ferro, Meike Heinz, Patrik Schmutz, and Corsin Battaglia. "(Digital Presentation) Elucidating the Rate-Limiting Processes in High-Temperature Sodium-Metal Chloride Batteries." ECS Meeting Abstracts MA2022-02, no. 5 (October 9, 2022): 578. http://dx.doi.org/10.1149/ma2022-025578mtgabs.

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Sodium-metal chloride batteries are considered a sustainable and safe alternative to lithium-ion batteries for large-scale stationary electricity storage, but exhibit disadvantages in rate capability. Several studies identified metal-ion migration through the metal chloride conversion layer on the positive electrode as the rate-limiting step, limiting charge and discharge rates in sodium-metal chloride batteries. Here we present electrochemical nickel and iron chlorination with planar model electrodes in molten sodium tetrachloroaluminate electrolyte at 300 °C. We discovered that, instead of metal-ion migration through the metal chloride conversion layer, it is metal-ion diffusion in sodium tetrachloraluminate. which limits chlorination of both the nickel and iron electrodes. Upon charge, chlorination of the nickel electrode proceeds via uniform oxidation of nickel and the formation of NiCl2 platelets on the surface of the electrode. In contrast, the oxidation of the iron electrodes proceeds via localized intergranular dissolution, resulting in non-uniform iron oxidation and pulverization of the iron electrode. We further discuss the transition from planar model electrodes to porous high-capacity electrodes, where sodium-ion migration along the tortuous path in the porous electrode can become rate limiting. These mechanistic insights are important for the design of competitive next-generation sodium-metal chloride batteries with improved rate performance.
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11

Tatrari, Gaurav, Rong An, and Faiz Ullah Shah. "Designed metal-organic framework composites for metal-ion batteries and metal-ion capacitors." Coordination Chemistry Reviews 512 (August 2024): 215876. http://dx.doi.org/10.1016/j.ccr.2024.215876.

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12

Voropaeva, D. Yu, S. A. Novikova, and A. B. Yaroslavtsev. "Polymer electrolytes for metal-ion batteries." Russian Chemical Reviews 89, no. 10 (September 18, 2020): 1132–55. http://dx.doi.org/10.1070/rcr4956.

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13

Oumellal, Y., A. Rougier, G. A. Nazri, J.-M. Tarascon, and L. Aymard. "Metal hydrides for lithium-ion batteries." Nature Materials 7, no. 11 (October 12, 2008): 916–21. http://dx.doi.org/10.1038/nmat2288.

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14

Dong, Xu, Dominik Steinle, and Dominic Bresser. "Single-Ion Conducting Polymer Electrolytes for Sodium Batteries." ECS Meeting Abstracts MA2023-01, no. 5 (August 28, 2023): 954. http://dx.doi.org/10.1149/ma2023-015954mtgabs.

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Sodium-ion batteries have attracted extensive attention recently owing to the announcements of several companies to commercialize this technology in the (very) near future. Just like commercial lithium-ion batteries, though, these batteries are comprising and/or will comprise a liquid electrolyte – with all its advantages and challenges. Thinking one step ahead (as also done by a few companies already), the next step might be the transition to (“zero-excess”) sodium-metal batteries, which will require fundamentally new electrolyte solutions, and just like for lithium-metal batteries, these might be based, e.g., on polymers. Herein, we present our latest results on single-ion conducting polymer electrolytes for sodium-metal batteries. These polymer electrolytes do not only show higher ionic conductivity than its lithium analogues (>2.5 mS cm-1 at 40 °C), but moreover the same beneficial properties in terms of high electrochemical stability towards oxidation, highly reversible sodium plating and stripping, and excellent cycling stability of Na‖Na3V2(PO4)3 cells for more than 500 cycles. The results thus show that single-ion conducting polymer electrolytes are very promising candidates for high-performance sodium batteries.
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15

Liu, Zhuoxin, Yan Huang, Yang Huang, Qi Yang, Xinliang Li, Zhaodong Huang, and Chunyi Zhi. "Voltage issue of aqueous rechargeable metal-ion batteries." Chemical Society Reviews 49, no. 1 (2020): 180–232. http://dx.doi.org/10.1039/c9cs00131j.

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16

AKSU, Hasan, Cengiz Ayhan ZIBA, and Mehmet Hakan MORCALI. "DETERMINING THE CONTENT AND COST ANALYSIS OF RECYCLING REGIONALLY COLLECTED WASTE LI-ION BATTERIES." Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi 25, no. 3 (September 3, 2022): 408–17. http://dx.doi.org/10.17780/ksujes.1125586.

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Our need for portable energy is increased day by day. Batteries, which are indispensable for modern life, gain more importance in the communication time. Therefore, batteries with the ability to storage a lot of energy in a short time are need. This need is met by Lithium-ion batteries. Of course, the increasing use of batteries with the formation of a fast consumer society poses a potential danger to the environment and human health.Indiscriminate release end of life batteriesto the environment causes serious metal pollution, but there are also serious economic losses due to the materials that have economic value. In this study, 12 waste battery collection points were determined within the boundaries of Namik Kemal neighborhood of Umraniye district in Istanbul, and the "end-of-life batteries" collected at these points within a three-month period were classified and their components were examined. The average composition of 110 Li-ion batteries collected during this period was determined as 20% Cu (Copper), 8% Al (Aluminum), 10% plastic, 55% battery paste (LiCoO2) and 7% others. The reusability of the metal and plastic parts obtained in the study was observed, and some spectroscopic analyzes were carried out for the reusability of the battery paste. As can be seen from the SEM-EDX analyzes supported by XRD and XRF analyzes, the morphological structure of the compound is disrupt during the application of charging and discharging many times to the Li-metal oxide compounds used as cathode material. It does not appear possible to reuse the battery paste of used (depleted) Li-ion batteries directly and/or by applying some simple operations. Multi-step chemical processes are needed to ensure the reusability of the battery paste. An economic value study was carried out for the collected Li-ion batteries and the importance of collecting the waste batteries and bringing them into the economy was emphasized.
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17

Zhao, Chunsong, Shuwei Li, Xi Luo, Bo Li, Wei Pan, and Hui Wu. "Integration of Si in a metal foam current collector for stable electrochemical cycling in Li-ion batteries." Journal of Materials Chemistry A 3, no. 18 (2015): 10114–18. http://dx.doi.org/10.1039/c5ta00786k.

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18

Wang, Wang. "Advanced carbon nanomaterials and nanotechnology applied in anode for lithium metal/ion batteries." Applied and Computational Engineering 60, no. 1 (May 7, 2024): 241–46. http://dx.doi.org/10.54254/2755-2721/60/20240892.

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Lithium batteries have a significant impact on the automotive industry and play an indispensable role in modern life. The demand for lithium batteries has increased with the advent of carbon nanomaterials. These materials provide higher energy storage and have the potential to replace graphite as the negative battery material. Although graphite is the most frequently used material on the market, it has an amorphous structure and limited capacity. To enhance the capacity of lithium batteries and increase their ability to store more lithium ions within a smaller volume, researchers have developed many advanced carbon nanomaterials with great specific properties. These materials not only increase the battery's capacity but also offer viable solutions to the challenges encountered by lithium batteries. The focus of this article is on how these advanced carbon nanomaterials from 3 dimensions to 1 dimension can realize material performance improvements and changes in battery lifespan, energy density, resistance in dendritic lithium-deposition, and other aspects.
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19

Fan, Huilin, Pengcheng Mao, Hongyu Sun, Yuan Wang, Sajjad S. Mofarah, Pramod Koshy, Hamidreza Arandiyan, Zhiyuan Wang, Yanguo Liu, and Zongping Shao. "Recent advances of metal telluride anodes for high-performance lithium/sodium–ion batteries." Materials Horizons 9, no. 2 (2022): 524–46. http://dx.doi.org/10.1039/d1mh01587g.

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Recent advances of metal telluride anodes for high-performance lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs), which is important electrochemical energy storage technologies with high energy density and environmental benignity.
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20

Wang, Chia-Nan, Nhat-Luong Nhieu, and Yen-Hui Wang. "The Future of Energy Storage in Vietnam: A Fuzzy Multi-Criteria Decision-Making Approach to Metal-Ion Battery Assessments." Batteries 10, no. 4 (April 14, 2024): 130. http://dx.doi.org/10.3390/batteries10040130.

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Lithium-ion (Li-ion) batteries, despite their prevalence, face issues of resource scarcity and environmental concerns, prompting the search for alternative technologies. This study addresses the need to assess and identify viable metal-ion battery alternatives to Li-ion batteries, focusing on the rapidly industrializing context of Vietnam. It acknowledges the criticality of developing a sustainable, cost-effective, and resource-efficient energy storage solution that aligns with the country’s growth trajectory. The primary objective is to evaluate the suitability of emerging metal-ion batteries—specifically sodium-ion (SIB), sodium-ion saltwater (SIB-S), magnesium-ion (MIB), and zinc-ion (ZIB)—for Vietnam’s energy storage needs, guiding future investment and policy decisions. A Fuzzy Multiple-Criteria Decision-Making (MCDM) approach is employed, incorporating both quantitative and qualitative criteria. This study utilizes the Fuzzy Best-Worst Method (BWM) to determine the relative importance of various performance indicators and then applies the Bonferroni Fuzzy Combined Compromise Solution (Bonferroni FCoCoSo) method to rank the battery alternatives. The SIBs emerged as the most promising alternative, scoring the highest in the overall evaluation. The MIBs and SIB-saltwater batteries displayed competitive potential, while the ZIBs ranked the lowest among the considered options. This research provides a strategic framework for energy policy formulation and investment prioritization. It contributes to the field by applying a fuzzy-based MCDM approach in a novel context and offers a structured comparative analysis of metal-ion batteries, enhancing the body of knowledge on sustainable energy storage technologies.
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Al‐Abbasi, Malek, Yanrui Zhao, Honggang He, Hui Liu, Huarong Xia, Tianxue Zhu, Kexuan Wang, et al. "Challenges and protective strategies on zinc anode toward practical aqueous zinc‐ion batteries." Carbon Neutralization 3, no. 1 (January 2024): 108–41. http://dx.doi.org/10.1002/cnl2.109.

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AbstractOver the past decades, there has been a growing interest in rechargeable aqueous Zn‐ion batteries (AZIBs) as a viable substitute for lithium‐ion batteries. This is primarily due to their low cost, lower redox potential, and high safety. Nevertheless, the progress of Zn metal anodes has been impeded by various challenges, including the growth of dendrites, corrosion, and hydrogen evolution reaction during repeated cycles that result in low Coulombic efficiency and a short lifetime. Therefore, we represent recent advances in Zn metal anode protection for constructing high‐performance AZIBs. Besides, we show in‐depth analyses and supposed hypotheses on the working mechanism of these issues associated with mildly acidic aqueous electrolytes. Meanwhile, design principles and feasible strategies are proposed to suppress dendrites' formation of Zn batteries, including electrode design, electrolyte modification, and interface regulation, which are suitable for restraining corrosion and hydrogen evolution reaction. Finally, the current challenges and future trends are raised to pave the way for the commercialization of AZIBs. These design principles and potential strategies are applicable in other metal‐ion batteries, such as Li and K metal batteries.
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22

Karatrantos, Argyrios V., Md Sharif Khan, Chuanyu Yan, Reiner Dieden, Koki Urita, Tomonori Ohba, and Qiong Cai. "Ion Transport in Organic Electrolyte Solutions for Lithium-ion Batteries and Beyond." Journal of Energy and Power Technology 03, no. 03 (May 24, 2021): 1. http://dx.doi.org/10.21926/jept.2103043.

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The performance of metal-ion batteries at low temperatures and their fast charge/discharge rates are determined mainly by the electrolyte (ion) transport. Accurate transport properties must be evaluated for designing and/or optimization of lithium-ion and other metal-ion batteries. In this review, we report and discuss experimental and atomistic computational studies on ion transport, in particular, ion diffusion/dynamics, transference number, and ionic conductivity. Although a large number of studies focusing on lithium-ion transport in organic liquids have been performed, only a few experimental studies have been conducted in the organic liquid electrolyte phase for other alkali metals that are used in batteries (such as sodium, potassium, magnesium, etc.). Atomistic computer simulations can play a primary role and predict ion transport in organic liquids. However, to date, atomistic force fields and models have not been explored and developed exhaustively to simulate such organic liquids in quantitative agreement to experimental measurements.
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23

Tyagi, Ashwani, Nagmani, and Sreeraj Puravankara. "Opportunities in Na/K [hexacyanoferrate] frameworks for sustainable non-aqueous Na+/K+ batteries." Sustainable Energy & Fuels 6, no. 3 (2022): 550–95. http://dx.doi.org/10.1039/d1se01653a.

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The review focuses on the alkali metal hexacyanoferrates (AMHCFs) as cathodes for sodium-ion batteries (SIBs) and potassium-ion batteries (KIBs) for sustainable and economic Li-free future energy storage solutions.
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24

Bachinin, Semyon, Venera Gilemkhanova, Maria Timofeeva, Yuliya Kenzhebayeva, Andrei Yankin, and Valentin A. Milichko. "Metal-Organic Frameworks for Metal-Ion Batteries: Towards Scalability." Chimica Techno Acta 8, no. 3 (August 27, 2021): 20210304. http://dx.doi.org/10.15826/chimtech.2021.8.3.04.

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Metal-organic frameworks (MOFs), being a family of highly crystalline and porous materials, have attracted particular attention in material science due to their unprecedented chemical and structural tunability. Next to their application in gas adsorption, separation, and storage, MOFs also can be utilized for energy transfer and storage in batteries and supercapacitors. Based on recent studies, this review describes the latest developments about MOFs as structural elements of metal-ion battery with a focus on their industry-oriented and large-scale production.
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25

Yang, Wenlong, Jun Wang, and Jikang Jian. "Metal organic framework-based materials for metal-ion batteries." Energy Storage Materials 66 (February 2024): 103249. http://dx.doi.org/10.1016/j.ensm.2024.103249.

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26

Klein, Antoine, Matthew Sadd, Nataliia Mozhzhukhina, Martina Olsson, Shizhao Xiong, and Aleksandar Matic. "Visualization of Lithium Plating Morphologies on Graphite Electrode By O perando X-Ray Tomography." ECS Meeting Abstracts MA2023-02, no. 2 (December 22, 2023): 211. http://dx.doi.org/10.1149/ma2023-022211mtgabs.

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The plating of lithium metal on graphite electrodes in Li-ion batteries is a major factor limiting the fast charging of electric vehicles. Lithium metal plating leads to the growth of dendritic structures that can pierce through the battery’s separator resulting in an internal short circuit and catastrophic failure of the battery. Moreover, the plating of lithium metal on graphite is not reversible, manifesting in poor Coulombic efficiency, severe reduction of the battery’s life expectancy, and safety issues. Understanding how and when plating occurs in Li-ion batteries is crucial in the development of strategies to prevent plating under fast charging conditions. Thus, we have conducted an operando X-ray tomographic microscopy experiment to directly monitor the plating of lithium metal in a Li/Graphite cell when applying electrolytes with the additives vinylene carbonate (VC) and Lithium bis(fluorosulfonyl)imide (LiFSI). The experiment was performed at the ID19 beamline (ESRF, France) where tomographic scans, linked with the lithiation state of graphite, made it possible to gain a strong understanding of the mechanisms behind Li-deposition and stripping at high current rates in addition to understand the effect of the VC and LiFSI additives.
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Puttaswamy, Rangaswamy, Ranjith Krishna Pai, and Debasis Ghosh. "Recent progress in quantum dots based nanocomposite electrodes for rechargeable monovalent metal-ion and lithium metal batteries." Journal of Materials Chemistry A 10, no. 2 (2022): 508–53. http://dx.doi.org/10.1039/d1ta06747h.

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This review summarizes the recent progress in quantum dot based nanocomposites as electrode materials in Li/Na/K-ion batteries, as cathodes in Li–S and Li–O2 batteries and in improving the electrochemical performance of Li metal anode batteries.
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Yao, Hu-Rong, Ya You, Ya-Xia Yin, Li-Jun Wan, and Yu-Guo Guo. "Rechargeable dual-metal-ion batteries for advanced energy storage." Physical Chemistry Chemical Physics 18, no. 14 (2016): 9326–33. http://dx.doi.org/10.1039/c6cp00586a.

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Possible configurations of hybrid-ion batteries based on dual-metal-ions are summarized: these could be promising rechargeable battery systems as they combine the respective advantages of each single-metal-ion.
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Ni, Qiao, Yuejiao Yang, Haoshen Du, Hao Deng, Jianbo Lin, Liu Lin, Mengwei Yuan, Zemin Sun, and Genban Sun. "Anode-Free Rechargeable Sodium-Metal Batteries." Batteries 8, no. 12 (December 5, 2022): 272. http://dx.doi.org/10.3390/batteries8120272.

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Due to the advantages of rich resources, low cost, high energy conversion efficiency, long cycle life, and low maintenance fee, sodium–ion batteries have been regarded as a promising energy storage technology. However, their relatively low energy density compared with the commercialized lithium–ion batteries still impedes their application for power systems. Anode–free rechargeable sodium–metal batteries (AFSMBs) pose a solution to boost energy density and tackle the safety problems of metal batteries. At present, researchers still lack a comprehensive understanding of the anode-free cells in terms of electrolytes, solid–electrolyte interphase (SEI), and current collectors. This review is devoted to the field of AFSMBs, and outlines the breakthroughs that have been accomplished along with our perspective on the direction of future development for AFSMBs and the areas that warrant further investigation.
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30

Shi, Wenhui, Xilian Xu, Lin Zhang, Wenxian Liu, and Xiehong Cao. "Metal-organic framework-derived structures for next-generation rechargeable batteries." Functional Materials Letters 11, no. 06 (December 2018): 1830006. http://dx.doi.org/10.1142/s1793604718300062.

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Metal-organic frameworks (MOFs) have attracted great attention as versatile precursors or sacrificial templates for the preparation of novel porous structures. Due to their tunable compositions, structures and porosities as well as high surface area, MOF-derived materials have revealed promising performance for energy storage devices. In this mini review, the recent progress of MOF-derived materials as electrodes of next-generation rechargeable batteries was summarized. We briefly introduce the preparation methods, various design strategies and the structure-dependent performance of recently reported MOF-derived materials as electrodes of post-lithium-ion batteries, focusing on lithium-sulfur (Li-S) batteries, sodium-ion batteries (SIBs) and metal–air batteries. Finally, we give the conclusion with some insights into future development of MOF-derived materials for next-generation rechargeable batteries.
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Zhang, Qi, Dixiong Li, Jia Wang, Sijia Guo, Wei Zhang, Dong Chen, Qi Li, Xianhong Rui, Liyong Gan, and Shaoming Huang. "Multiscale optimization of Li-ion diffusion in solid lithium metal batteries via ion conductive metal–organic frameworks." Nanoscale 12, no. 13 (2020): 6976–82. http://dx.doi.org/10.1039/c9nr10338d.

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32

He, Jinya. "Classification and Application Research of Lithium Electronic Batteries." MATEC Web of Conferences 386 (2023): 03008. http://dx.doi.org/10.1051/matecconf/202338603008.

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In recent years, the damaging effects of burning fossil fuels on the environment and petrol has started to decline, the demand for sustainable energy has risen sharply, and lithium electronic batteries have become a hot spot today due to their high specific capacity, high self-discharge rate, long life and high safety performance. Since lithium metal is an active metal, its preparation and preservation have high requirements on the environment. This paper discusses the development history, working principle, classification and practical application of lithium electronic batteries in real life. The two types of lithium batteries are called lithium metal batteries and lithium ion batteries, respectively. The battery of lithium electronic battery is composed of positive electrode, diaphragm, organic electrolyte, battery shell and negative electrode. Rechargeable battery is also called “lithium ion". Its working principle is to cycle lithium ion back and forth between positive and negative electrodes, and to add and reuse lithium ion alternately and continuously between positive and negative electrodes during charge and discharge. There are basically three categories of lithium-ion battery electrolyte: liquid, solid and molten salt. At present, lithium iron phosphate or frequently used nickel-manganese-cobalt ternary materials are employed as the cathode of standard goods., and negative electrode is mainly graphite and other carbon materials. A better study could result from a deeper understanding of lithium-ion batteries, providing a wealth of theoretical knowledge for in-depth research.
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33

Mäntymäki, Miia, Mikko Ritala, and Markku Leskelä. "Metal Fluorides as Lithium-Ion Battery Materials: An Atomic Layer Deposition Perspective." Coatings 8, no. 8 (August 8, 2018): 277. http://dx.doi.org/10.3390/coatings8080277.

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Lithium-ion batteries are the enabling technology for a variety of modern day devices, including cell phones, laptops and electric vehicles. To answer the energy and voltage demands of future applications, further materials engineering of the battery components is necessary. To that end, metal fluorides could provide interesting new conversion cathode and solid electrolyte materials for future batteries. To be applicable in thin film batteries, metal fluorides should be deposited with a method providing a high level of control over uniformity and conformality on various substrate materials and geometries. Atomic layer deposition (ALD), a method widely used in microelectronics, offers unrivalled film uniformity and conformality, in conjunction with strict control of film composition. In this review, the basics of lithium-ion batteries are shortly introduced, followed by a discussion of metal fluorides as potential lithium-ion battery materials. The basics of ALD are then covered, followed by a review of some conventional lithium-ion battery materials that have been deposited by ALD. Finally, metal fluoride ALD processes reported in the literature are comprehensively reviewed. It is clear that more research on the ALD of fluorides is needed, especially transition metal fluorides, to expand the number of potential battery materials available.
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34

Zhang, Huimin, Siwei Zhao, and Fuqiang Huang. "A comparative overview of carbon anodes for nonaqueous alkali metal-ion batteries." Journal of Materials Chemistry A 9, no. 48 (2021): 27140–69. http://dx.doi.org/10.1039/d1ta07962j.

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35

Chen, Zheng. "(Invited) Electrolyte Design for Wide-Temperature Li-Ion and Li-Metal Batteries." ECS Meeting Abstracts MA2022-02, no. 5 (October 9, 2022): 581. http://dx.doi.org/10.1149/ma2022-025581mtgabs.

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Improving the wide temperature operation of rechargeable batteries is vital to the operation of electronics in extreme environments, where systems capable of higher energy, high-rate discharge and long cycling are in short supply. In this talk, we will show electrolyte designs to achieve high-energy density and stable cycling performance in wide temperature range for both lithium-ion and lithium metal batteries. We will show how to circumvent the sluggish ion desolvation process found in typical lithium-ion batteries during discharge. These batteries are enabled by a novel ester electrolyte, which simultaneously provided high electrochemical stability and ionic conductivity at low temperature. Then we will extend the fundamental understanding developed from these system to other high-capacity, high-rate electrodes, leading to further improved energy density and stability for both high and extremely low temperatures, demonstrated by rechargeable Li metal batteries using both high-Ni oxide and sulfur cathodes.
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36

Chen, Yue-Sheng, and Yu-Sheng Su. "Lithium Silicates as an Artificial SEI for Rechargeable Lithium Metal Batteries." ECS Meeting Abstracts MA2023-02, no. 4 (December 22, 2023): 680. http://dx.doi.org/10.1149/ma2023-024680mtgabs.

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The major motivation of replacing lithium-ion batteries with lithium metal batteries is to obtain higher energy density by adopting the metallic lithium anode (3860 mAh g-1, theoretically), which means they can store more energy in the same volume or weight. One of the main challenges of rechargeable lithium metal batteries is the formation of lithium dendrites during the charging process.1 Lithium dendrites are tiny needle-like structures that can grow from the surface of the lithium metal electrode and penetrate the separator, causing battery short-circuiting. This can lead to safety issues, including the potential for fire or explosion. Another challenge is the formation of solid-electrolyte interface (SEI) on the surface of the lithium metal electrode, which can reduce the battery's efficiency and cycle life.2 The SEI layer can also lead to the formation of inactive lithium and increase the risk of dendrite growth. In the present work, various lithium silicates have been synthesized to be implemented as the artificial SEI layer via a facile dry coating method.3,4 The lithium silicate coating acts as a protective barrier that prevents direct contact between the lithium metal and the electrolyte, which may cause undesirable side reactions and reduce the efficiency and lifespan of the battery.4 The lithium silicate-based artificial SEI layer improves the stability and efficiency of lithium metal batteries by reducing unwanted surface reactions, improving ion transport kinetics, and protecting the lithium metal anode from mechanical deformation and unstable SEI formation during extended cycling. This laminated lithium anode structure could be an effective design for the future development of long-cycle-life lithium metal batteries. F. Wu et al., Energy Storage Materials, 15, 148–170 (2018). X.-B. Cheng et al., Adv. Sci., 3, 1500213 (2016). A. Bhat, P. Sireesha, Y. Chen, and Y. Su, ChemElectroChem, 9 (2022) https://onlinelibrary.wiley.com/doi/10.1002/celc.202200772. Y.-S. Su, K.-C. Hsiao, P. Sireesha, and J.-Y. Huang, Batteries, 8, 2 (2022). Figure 1
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37

Krishnamoorthy, Umapathi, Parimala Gandhi Ayyavu, Hitesh Panchal, Dayana Shanmugam, Sukanya Balasubramani, Ali Jawad Al-rubaie, Ameer Al-khaykan, et al. "Efficient Battery Models for Performance Studies-Lithium Ion and Nickel Metal Hydride Battery." Batteries 9, no. 1 (January 12, 2023): 52. http://dx.doi.org/10.3390/batteries9010052.

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Apart from being emission-free, electric vehicles enjoy benefits such as low maintenance and operating costs, noise-free, easy to drive, and the convenience of charging at home. All these benefits are directly dependent on the performance of the battery used in the vehicle. In this paper, one-dimensional modeling of Li-ion and NiMH batteries was developed, and their performances were studied. The performance characteristics of the batteries, such as the charging and discharging characteristics, the constituent losses of over-potential voltage, and the electrolyte concentration profile at various stages of charge and discharge cycles, were also studied. It is found that the electrolyte concentration profiles of Li-ion batteries show a drooping behavior at the start of the discharge cycle and a rising behavior at the end of discharge because of the concentration polarization due to the low diffusion coefficient. The electrolyte concentration profiles of NiMH batteries show rising behavior throughout the discharge cycle without any deviations. The reason behind this even behavior throughout the discharge cycle is attributed to the reduced concentration polarization due to electrolyte transport limitations. It is found that the losses associated with the NiMH battery are larger and almost constant throughout the battery’s operation. Whereas for the Li-ion batteries, the losses are less variable. The electrolyte concentration directly affects the overpotential losses incurred during the charging and discharging phases.
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38

Jihad, Ahmad, Affiano Akbar Nur Pratama, Salsabila Ainun Nisa, Shofirul Sholikhatun Nisa, Cornelius Satria Yudha, and Agus Purwanto. "Resynthesis of NMC Type Cathode from Spent Lithium-Ion Batteries: A Review." Materials Science Forum 1044 (August 27, 2021): 3–14. http://dx.doi.org/10.4028/www.scientific.net/msf.1044.3.

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Li-ion batteries are one of the most popular energy storage devices widely applied to various kinds of equipment, such as mobile phones, medical and military equipment, etc. Therefore, due to its numerous advantages, especially on the NMC type, there is a predictable yearly increase in Li-ion batteries' demand. However, even though it is rechargeable, Li-ion batteries also have a usage time limit, thereby increasing the amount of waste disposed of in the environment. Therefore, this study aims to determine the optimum conditions and the potential and challenges from the waste Li-ion battery recycling process, which consists of pretreatment, metal extraction, and product preparation. Data were obtained by studying the literature related to Li-ion battery waste's recycling process, which was then compiled into a review. The results showed that the most optimum recycling process of Li-ion batteries consists of metal extraction by a leaching process that utilizes H2SO4 and H2O2 as leaching and reducing agents, respectively. Furthermore, it was proceeding with the manufacturing of a new Li-ion battery.
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39

Lu, Wen-Hsuan, and Han-Yi Chen. "Suppressing Ti Reduction Via Multiple Doping in Nasicon-Type Solid Electrolyte." ECS Meeting Abstracts MA2024-01, no. 2 (August 9, 2024): 255. http://dx.doi.org/10.1149/ma2024-012255mtgabs.

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The NASICON-type solid electrolyte emerges as a promising candidate for lithium-ion batteries due to its notable ionic conductivity and stability in ambient conditions. However, the LiTi2(PO4)3 and LiGe2(PO4)3 series encounter a reduction of Ti and Ge upon contact with lithium metal, limiting their use in all-solid-state lithium-ion batteries. To address this challenge, we propose a solution by introducing multi-doped NASICON-type oxides. Following the doping process, the material demonstrates electrochemical stability when in contact with lithium metal, as evidenced by cyclic voltammetry measurements. Moreover, the material achieves a noteworthy ionic conductivity of ca. 1.3 × 10-4 S/cm, rendering it suitable for integration into lithium-ion batteries. By resolving the reduction issue of Ti in the material, it becomes feasible to employ it in all-solid-state lithium-ion batteries without the need for a protective layer between lithium metal and the solid electrolyte. This absence of an additional layer reduces interfacial resistance within the device, thereby anticipating improved battery performance.
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40

Geng, Lishan, Xuanpeng Wang, Kang Han, Ping Hu, Liang Zhou, Yunlong Zhao, Wen Luo, and Liqiang Mai. "Eutectic Electrolytes in Advanced Metal-Ion Batteries." ACS Energy Letters 7, no. 1 (December 15, 2021): 247–60. http://dx.doi.org/10.1021/acsenergylett.1c02088.

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41

Shea, John J., and Chao Luo. "Organic Electrode Materials for Metal Ion Batteries." ACS Applied Materials & Interfaces 12, no. 5 (January 9, 2020): 5361–80. http://dx.doi.org/10.1021/acsami.9b20384.

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42

Su, Heng, Saddique Jaffer, and Haijun Yu. "Transition metal oxides for sodium-ion batteries." Energy Storage Materials 5 (October 2016): 116–31. http://dx.doi.org/10.1016/j.ensm.2016.06.005.

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43

Chen, Xiang, Xueqiang Zhang, Xin Shen, and Qiang Zhang. "Ion–Solvent Chemistry in Alkali Metal Batteries." ECS Meeting Abstracts MA2020-01, no. 4 (May 1, 2020): 571. http://dx.doi.org/10.1149/ma2020-014571mtgabs.

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44

Brousse, T., D. Defives, L. Pasquereau, S. M. Lee, U. Herterich, and D. M. Schleich. "Metal oxide anodes for Li-ion batteries." Ionics 3, no. 5-6 (September 1997): 332–37. http://dx.doi.org/10.1007/bf02375707.

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45

Chen, Yuan, Shuming Zhuo, Zengyu Li, and Chengliang Wang. "Redox polymers for rechargeable metal-ion batteries." EnergyChem 2, no. 2 (May 2020): 100030. http://dx.doi.org/10.1016/j.enchem.2020.100030.

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46

Greaves, Michael, Suelen Barg, and Mark A. Bissett. "MXene‐Based Anodes for Metal‐Ion Batteries." Batteries & Supercaps 3, no. 3 (February 26, 2020): 211. http://dx.doi.org/10.1002/batt.202000029.

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47

Greaves, Michael, Suelen Barg, and Mark A. Bissett. "MXene‐Based Anodes for Metal‐Ion Batteries." Batteries & Supercaps 3, no. 3 (January 16, 2020): 214–35. http://dx.doi.org/10.1002/batt.201900165.

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48

Perera, W. A. N. L., and W. W. P. De Silva. "Borophene as an anode material for metal-ion batteries." Sri Lankan Journal of Physics 24, no. 2 (December 31, 2023): 118–34. http://dx.doi.org/10.4038/sljp.v24i2.8133.

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Borophene is a novel 2D material whose history goes back only as far as the year 2015. Borophene is one atom thick 2D boron sheet which depict excellent optical, electronic, metallic, semiconducting, high mechanical anisotropic, and photothermal properties. Also, due to borophene’s high mechanical strength, high specific capacity, and low diffusion barrier it poses as an ideal candidate as an anode material for metal metal-ion batteries. This is the avenue of interest of this review paper, where we intend to discuss the existing theoretical and experimental basis of various polymorphic structures of Borophene, as anode materials for metal-ion batteries.
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49

Guo, Dongfang, Siyu Chu, Bin Zhang, and Zijiong Li. "The Development and Prospect of Stable Polyanion Compound Cathodes in LIBs and Promising Complementers." Small Methods, October 26, 2024. http://dx.doi.org/10.1002/smtd.202400587.

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AbstractCathode materials are usually the key to determining battery capacity, suitable cathode materials are an important prerequisite to meet the needs of large‐scale energy storage systems in the future. Polyanionic compounds have significant advantages in metal ion storage, such as high operating voltage, excellent structural stability, safety, low cost, and environmental friendliness, and can be excellent cathode options for rechargeable metal‐ion batteries. Although some polyanionic compounds have been commercialized, there are still some shortcomings in electronic conductivity, reversible specific capacity, and rate performance, which obviously limits the development of polyanionic compound cathodes in large‐scale energy storage systems. Up to now, many strategies including structural design, ion doping, surface coating, and electrolyte optimization have been explored to improve the above defects. Based on the above contents, this paper briefly reviews the research progress and optimization strategies of typical polyanionic compound cathodes in the fields of lithium‐ion batteries (LIBs) and other promising metal ion batteries (sodium ion batteries (SIBs), potassium ion batteries (PIBs), magnesium ion batteries (MIBs), calcium ion batteries (CIBs), zinc ion batteries (ZIBs), aluminum ion batteries (AIBs), etc.), aiming to provide a valuable reference for accelerating the commercial application of polyanionic compound cathodes in rechargeable battery systems.
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Wang, Gang, Quan Kuang, Pan Jiang, Qinghua Fan, Youzhong Dong, and Yanming Zhao. "Integrating molybdenum into zinc vanadate enable Zn3V2MoO8 as a high-capacity Zn-supplied cathode for Zn-metal free aqueous batteries." Nanoscale, 2023. http://dx.doi.org/10.1039/d3nr00136a.

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The commercialization of aqueous zinc-ion batteries (AZIBs) has been hindered by the obsession of Zn-metal anode, just like the early days of lithium-ion batteries. Developing Zn-metal free aqueous batteries (ZFABs)...
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