Academic literature on the topic 'Basalt'

The Paraná-Etendeka Continental Flood Basalt province hosts world-class agate and amethyst geode deposits in Rio Grande do Sul (Brazil; Serra Geral Fm.). Salto do Jacuí Mining District (Rio Grande do Sul, Brasil) has different types of agate geode hosted in vesicular basalt. A series of structural features has recently been investigated in the Salto do Jacuí Mining District, and indicates at least two volcanic episodes: i) normal tholeiitic basalt and dacite eruption, and ii) vesicular basalt and dacite intrusions as sills and dikes. These structural features include: basalt and aeolian sandstone xenoliths in vesicular basalts, vesicular basalt apophyses in massive basalts, sandstone and basalt breccias, sandstone dikes cutting across vesicular lavas and connected to mixed sandstone-agate geodes, sandstone assimilation by vesicular lava, and mixed sandstone and agate geodes. These features show that agate geodes were formed by melting of Botucatu sandstone xenoliths. High density contrast between vesicular basalt and Botucatu sandstone melts makes them immiscible during flow. Botucatu sandstone xenoliths melting is favored by degasing of intrusive volatile-rich basalts. The high-silica globs crystallize dynamically in a closed-system environment, giving rise to agate banding and fibrosity.

AbstractThe origin of large I-type batholiths remains a disputed topic. One model states that I-type granites form by partial melting of older crustal lithologies (amphibolites or intermediate igneous rocks). In another view, granites are trapped rhyolitic liquids occurring at the end of fractionation trends defining a basalt–andesite–dacite–rhyolite series. This paper explores the thermal implications of both scenarios, using a heat balance model that abstracts the heat production and consumption during crustal melting. Heat is consumed by melting and by losses through the surface (conductive or advective, as a result of eruption). It is supplied as a basal conductive heat flux, as internal heat production or as advective heat carried by an influx of hot basalt into the crust. Using this abstract approach, it is possible to explore the role different parameters play in the balance of granites formed by differentiation of basalts or by crustal melting. Two end-member situations appear equally favourable to generating large volumes of granites: (1) short-lived environments dominated by high basaltic flux, where granites result mostly from basalt differentiation; and (2) long-lived systems with no or minimal basalt flux, with granites resulting chiefly from crustal melting.

Biostratigraphic evidence of the presence of Early Jurassic flood basalts on the Franz Josef Land archipelago is presented. The flood basalts form layered section with two units, which is not discovered for Early Cretaceous basalts. The lower unit is composed by large-columnar basalts (colonnade), and the upper unit by small-columnar (entablature) chaotic-fan basalts. On the Hooker Island, the basalt flow is exposed on the Sedov Plateau, on the Lunacharsky Rock Cape and, possibly, on Al’banov Cape. On the southern slope of the Sedov Plateau, the basalt flow overlaps sands and sandstones, which contain palynoassemblage of the lower Toarcian. In the Lunacharsky Rock Cape outcrop, the underlying basalt sands are of the Pliensbachian to Early Toarcian chronostratigraphic interval. Apart from the Hooker Island, we observed basalts with the “colonnade/entablature” on three other islands: Scott Keltie, May and Leigh-Smith. The most complete section was found in the western part of the Leigh-Smith Island, where basalts are underlain and overlapped by sand units. The underlying sands in contact with basalts have a quenching zone. There is no quenching zone at the contact with the overlapping sands. A palynocomplex from the lower sand unit is early Toarcian in age. The palynocomplex found in the upper sand unit indicates its accumulation in the interval from the lower part of the late Toarcian to the early Aalenian. A palynological study of the underlying and overlying deposits of the basalt flow has shown that the flow is underlain by continental and coastal-marine sediments of the Pliensbachian to the upper part of the early Toarcian age interval. Basalt flow is overlain by the earliest late Toarcian–early Aalenian marine sediments. According to the modern chronostratigraphic scale, the age of the basalt flow can be estimated as approximately 180 million years, which is quite consistent with the earlier obtained 40Ar/39Ar data of 189.1 ± 11.4 million years. These data indicate that the basalt flow was formed during a narrow stratigraphic interval of the uppermost lower–earliest upper Toarcian.

We use the wide‐angle wavefield to constrain estimates of the seismic velocity and thickness of basalt flows overlying sediments. Wide angle means the seismic wavefield recorded at offsets beyond the emergence of the direct wave. This wide‐angle wavefield contains arrivals that are returned from within and below the basalt flows, including the diving wave through the basalts as the first arrival and P‐wave reflections from the base of the basalts and from subbasalt structures. The velocity structure of basalt flows can be determined to first order from traveltime information by ray tracing the basalt turning rays and the wide‐angle base‐basalt reflection. This can be refined by using the amplitude variation with offset (AVO) of the basalt diving wave. Synthetic seismogram models with varying flow thicknesses and velocity gradients demonstrate the sensitivity to the velocity structure of the basalt diving wave and of reflections from the base of the basalt layer and below. The diving‐wave amplitudes of the models containing velocity gradients show a local amplitude minimum followed by a maximum at a greater range if the basalt thickness exceeds one wavelength and beyond that an exponential amplitude decay. The offset at which the maximum occurs can be used to determine the basalt thickness. The velocity gradient within the basalt can be determined from the slope of the exponential amplitude decay. The amplitudes of subbasalt reflections can be used to determine seismic velocities of the overburden and the impedance contrast at the reflector. Combining wide‐angle traveltimes and amplitudes of the basalt diving wave and subbasalt reflections enables us to obtain a more detailed velocity profile than is possible with the NMO velocities of small‐offset reflections. This paper concentrates on the subbasalt problem, but the results are more generally applicable to situations where high‐velocity bodies overlie a low‐velocity target, such as subsalt structures.

Paleogene basalts are present over much of the northeastern Atlantic European margin. In regions containing significant thicknesses of layered basalt flows, conducting seismic imaging within and beneath the volcanic section has proven difficult, largely because the basalts severely attenuate and scatter seismic energy. We use data from a vertical seismic profile (VSP) from well 164/07-1 that penetrated [Formula: see text] of basalt in the northern Rockall Trough west of Britain to measure the seismic attenuation caused by the in-situ basalts. The effective quality factor [Formula: see text] of the basalt layer is found from the VSP to be 15–35, which is considerably lower (more attenuative) than the intrinsic attenuation measured on basalt samples in the laboratory. We then run synthetic seismogram models to investigate the likely cause of the attenuation. Full waveform 1D modeling of stacked sequences of lava flows based on rock properties from the same well indicates that much of the seismic attenuation observed from the VSP can be accounted for by the scattering effects of multiple thin layers with high impedance contrasts. Phase-screen seismic modeling of the rugose basalt surface at the top-of-basalt sediment interface, with the magnitude and wavelength of the relief constrained by a 3D seismic survey around the well, suggests that surface scattering from this interface plays a much smaller role than internal scattering in attenuating the seismic signal as it passes through the basalt sequence.

Basalts totalling 236 m in thickness were intersected in the wildcat oil well Mobil Gulf Chinampas N-37 in the Bay of Fundy. A 5.5 m section of conventional core retrieved from the middle of the basalt section sampled two fine-grained, phenocryst-poor, amygdaloidal basalt flows. The basalts, though somewhat altered, show concentrations of ferromagnesian elements (e.g., Fe, Mg, Cr, Ni) and immobile elements (e.g., Zr, Nb, Ta, Hf) as well as chondrite-normalized REE patterns typical of high-Ti quartz-normative tholeiites and are identical to more evolved samples of the North Mountain basalts at Digby. These petrographic and geochemical characteristics allow correlation with middle unit flows of the North Mountain basalts. The lower unit of North Mountain basalt may be as thick in the well as in the Digby area (~200 m), but the upper unit is either missing or very thin (< 68 m). A 25 m thick sedimentary section just above the conventional core but within the basalt sequence has not been reported on land and hints at the existence of a basalt unit not present on North Mountain. The conclusion that North Mountain basalts occur in the Chinampas well suggests that the flows underlie most of the Bay of Fundy, originally covered 9400 km2, and had a total volume of 2350 km3.

This paper presents the results of the analysis of the quality of basalts, their heat treatment and studies of changes in the chemical composition of basalts, which leads to a change in the external color of partially processed basalt raw materials (hereinafter referred to as semi-finished product). The results of a study of purified basalt from slime, impurities and hydroxides, changes in the chemical composition of basalt rock are presented. The prospects of heat treatment of a semi-finished product and obtaining multi-colored products from mineral raw materials is shown. It was found that the optimal firing temperature of the semi-finished product, the possible options for changing the external color and the criterion points of the thermal effect at which the basalt semi-finished product changes the external shade. These statements are of great scientific and practical interest in the fact that during the heat treatment of a semifinished product, basalt easily overheats and gradually acquires a different color, which occurs to a liquids temperature and allows the future to plan to obtain high-quality multi-colored products from basalts, for example, products for design.

Susceptibility measurements from cores (representing basalt, lapilli-tuffs and tuffs) and magnetic logs from the Lopra-1/1A well are presented. The basalts fall into high- and low-susceptibility groups with no overlap. The high-susceptibility basalts (seven cores) have susceptibilities between 4 and 88 ×10–3 SI and consist of basalt with < 1% vesicles from thick massive units. The low-susceptibility basalts are intergranular, intersertal or hypocrystalline and contain no or very little (< 1%) visible magnetite, are generally more altered than the high-susceptibility basalts and have susceptibilities in the range from 0.6 to 1.4 × 10–3 SI (seven cores). The susceptibility of ten volcaniclastites of lapilli-tuff or tuff varies from 0.4 to 3.8 × 10–3 SI. The cores from the Lopra-1/1A well reveal a bimodal distribution of magnetic susceptibility. Low susceptibilities ranging from 0.4 to 4 are characteristic of altered basalts poor in magnetite, lapilli-tuffs and tuffs. Thus single measurements of susceptibility are of little use in discriminating between these three types of rock. Susceptibility logs from the Lopra-1/1A well show that the variation below 3315 m distinguishes clearly between volcaniclastics (hyaloclastites) with low and fairly constant susceptibility and basalt beds of between 5 and 10 m thickness (with high susceptibility). The volcaniclastics comprise some 60–70% of the sequence between 3315 and 3515 m with the maximum continuous sediment layer being 80 m thick. A 1½ m core of solid basalt at 2381 m and sidewall cores of basalt from the Lopra1/1A well have a mean susceptibility of 22.1 ± 3.5 × 10–3 SI (standard deviation (σ) = 23.6, number of samples (N) = 46), while samples of hyaloclastite (lapilli-tuff and tuff) have a mean susceptibility of 0.85 × 10–3 SI (σ = 0.39, N = 17). The mean values of the rock magnetic parameters for 303 basalt plugs from the Vestmanna-1 well are: Qave = 13.3 ± 0.6 (σ = 11), Save = 11.8 ± 0.6 × 10–3 SI (σ = 11) and Jave = 4.64 ± 0.25 A/m (σ = 4.4). The reversely polarised, lowermost (hidden) part of the c. 4½ km thick lower basalt formation correlates with Chron C26r. The upper (exposed) part of the lower basalt formation correlates with Chrons C26n, C25r and C25n and the more than 2.3 km thick middle and upper basalt formations correlate with Chron C24n.3r.

Columbia River province magmatism is now known to include abundant and widespread rhyolite centers even though the view that the earliest rhyolites erupted from the McDermitt Caldera and other nearby volcanic fields along the Oregon–Nevada state border has persisted. Our study covers little-studied or unknown rhyolite occurrences in eastern Oregon that show a much wider distribution of older centers. With our new data on distribution of rhyolite centers and ages along with literature data, we consider rhyolites spanning from 17.5 to 14.5 Ma of eastern Oregon, northern Nevada, and western Idaho to be a direct response to flood basalts of the Columbia River Basalt Group (CRBG) and collectively categorize them as Columbia River rhyolites. The age distribution patterns of Columbia River rhyolites have implications for the arrival, location, and dispersion of flood basalt magmas in the crust. We consider the period from 17.5 to 16.4 Ma to be the waxing phase of rhyolite activity and the period from 15.3 to 14.5 Ma to be the waning phase. The largest number of centers was active between 16.3–15.4 Ma. The existence of crustal CRBG magma reservoirs beneath rhyolites seems inevitable, and hence, rhyolites suggest the following. The locations of centers of the waxing phase imply the arrival of CRBG magmas across the distribution area of rhyolites and are thought to correspond to the thermal pulses of arriving Picture Gorge Basalt and Picture-Gorge-Basalt-like magmas of the Imnaha Basalt in the north and to those of Steens Basalt magmas in the south. The earlier main rhyolite activity phase corresponds with Grande Ronde Basalt and evolved Picture Gorge Basalt and Steens Basalt. The later main phase rhyolite activity slightly postdated these basalts but is contemporaneous with icelanditic magmas that evolved from flood basalts. Similarly, centers of the waning phase span the area distribution of earlier phases and are similarly contemporaneous with icelanditic magmas and with other local basalts. These data have a number of implications for long-held notions about flood basalt migration through time and the age-progressive Snake River Plain Yellowstone rhyolite trend. There is no age progression in rhyolite activity from south-to-north, and this places doubt on the postulated south-to-north progression in basalt activity, at least for main-phase CRBG lavas. Furthermore, we suggest that age-progressive rhyolite activity of the Snake River Plain–Yellowstone trend starts at ~12 Ma with activity at the Bruneau Jarbidge center, and early centers along the Oregon–Nevada border, such as McDermitt, belong to the early to main phase rhyolite identified here.

A erupção histórica de 1580 A.D. ocorreu ao sudoeste da Ilha de São Jorge, Açores recobrindo uma área total de 4 km². Este trabalho teve como objetivo caracterizar as diferentes morfologias de lava de 1580 A.D, juntamente com a definição de padrões petrográficos e geoquímicos. A erupção gerou quatro flow fields: Ribeira do Almeida, Queimada, Ribeira do Nabo I e Ribeira do Nabo II. A descrição detalhada das lavas permitiu identificar spiny, sheet, e slabby pahoehoe e derrames do tipo ‘a´ā. Próximo aos cones, derrames do tipo ‘a´ā são descritos. Com a constante erupção, estas lavas fluem em direção a costa formando deltas de lava ao entrar em contato com a água. Estes deltas geram um relevo sub-horizontal favorecendo a colocação de derrames do tipo sheet pahoehoe. A contínua alimentação interna favorece o espessamento dos derrames, podendo gerar o rompimento da superfície formando derrames slabby pahoehoe. Os estágios finais da erupção são marcados por derrames do tipo ‘a´ā canalizados lateralmente e sobre os derrames do tipo sheet pahoehoe. A variação na superfície dos derrames é controlada pelas taxas de efusão e pela topografia. Petrograficamente, todas as lavas da erupção de 1580 A.D. são olivina basaltos. Os dados geoquímicos indicam uma afinidade magmática alcalina com os termos menos diferenciados localizados na região de Ponta Queimada. Isto pode ser explicado por uma constante recarga de magma mais primitivo na câmara magmática. Os padrões de ETR normalizados sugerem que os basaltos estudados foram gerados a partir de um baixo grau de fusão de uma fonte profunda e enriquecida do tipo OIB. O estudo dos aspectos físicos dos derrames de 1580 juntamente com a petrografia e geoquímica permitiram compreender a história geológica deste evento.
The historic eruption of 1580 A.D. occurred in the southwestern of São Jorge Island, in the central Azores covering a total area of 4 km². This work provides a characterization of the distribution and morphology of the 1580 A.D. lava flows, integrated to petrography and geochemistry. The eruption formed four distinct flows fields: Ribeira do Almeida, Queimada, Ribeira do Nabo I and Ribeira do Nabo II. Detailed geological analysis allowed the identification of spiny, sheet and sllaby pahoehoe and ‘a´ā lava morphotypes. Near the vent, the flow fields are characterized by channelized ‘a´ā flows. With continuous eruption, these lavas flowed downwards forming fan-shaped lava deltas when entering the sea. Sheet pahoehoe flows overlay the ‘a´ā lavas and with continuous inflation the surface of the flows breaks generating slabby pahoehoe surface. The gradual increase in surface fragmentation form rubbly surfaces. In the late stages of the eruption channelized ‘a´ā flows were emplaced, depositing laterally and over the sheet pahoehoe flows. The variations in the lava surface are controlled by the effusion rates and the topography. Petrographically, all lava flows are olivine basalts. The chemistry of the basalts indicate an alkaline nature for the 1580 volcanism. The less-evolved compositions are found in Ribeira do Almeida and this fact can be related to continuous recharge of the magma chamber with more primitive melts. Normalized REE profiles show that the basalts were generated by low volumes of melt of an enriched OIB source. The study of the physical aspects of 1580 lava flows with petrography and geochemistry allowed understand the geologic history of this event.

Cette étude évalue expérimentalement et analytiquement le comportement au cisaillement des poutres en béton renforcé de fibres de basalte (BRFB) renforcées longitudinalement avec des barres en polymère renforcé de fibres de basalte (PRFB). Un nouveau type de macro-fibres de basalte a été ajouté au mélange de béton pour produire le mélange de BRFB. Quatorze poutres (152 x 254 x 2000 mm) sans armature transversale ajouté ont été testées sous une configuration de chargement à quatre points jusqu'à la défaillance. Les poutres ont été regroupés en deux groupes A et B en fonction de leurs rapports portée de cisaillement/profondeur, a/d. Les poutres du groupe A avaient un rapport a/d de 3,3 tandis que celles du groupe B avaient un rapport a/d de 2,5. Outre les rapports a/d, les paramètres étudiés comprenaient la fraction volumique des fibres ajoutées (0,75 et 1,5%) et le taux de renforcement longitudinal des barres en PRFB (0,31, 0,48, 0,69, 1,05 et 1,52). Les résultats des tests ont montré que l’ajout de macro-fibres de basalte au mélange de béton améliorait sa résistance à la compression. Une relation directe entre la fraction volumique de fibres, Vf, et la résistance à la compression a été observée. Les cylindres de béton coulés avec une Vf de 0,75 et 1,5% ont entraîné une augmentation de 11 et 30% de leur résistance à la compression par rapport à ceux moulés en béton standard (sans fibres), respectivement. L'ajout de fibres a également amélioré le mode de défaillance des poutres BRFB-PRFB que les poutres de contrôle coulées avec du béton standard. L’augmentation de la fraction volumique des fibres a réduit l’espacement entre les fissures et gêné sa propagation. Une amélioration significative des capacités de cisaillement des poutres testées a également été observée lorsque les macro-fibres de basalte ont été ajoutées à une fraction volumique Vf de 0,75. L'augmentation moyenne des capacités de cisaillement des poutres des groupes A et B, ayant les mêmes taux de renforcement, était respectivement de 45 et 44%, par rapport à celles des poutres de contrôle. Il a été noté que le gain en capacité de cisaillement des poutres testées était plus prononcé dans les poutres avec a/d= 3,3 que dans les poutres avec a/d = 2,5 lorsque le taux de renforcement augmentait. Au cours de la phase analytique, plusieurs modèles ont été utilisés pour prédire les capacités de cisaillement des poutres. Tous les modèles disponibles surestimaient les capacités de cisaillement des poutres testées avec un rapport moyen Vpre/Vexp compris entre 1,29 et 2,64. Cette observation a montré que ces modèles ne permettaient pas de prédire les capacités de cisaillement des poutres BRFB-PRFB. Un nouveau modèle modifié intégrant le type de renforcement longitudinal, le type de béton fibré et la densité du béton est proposé. Le modèle d’Ashour et al. -A (1992) a été modifié en utilisant un facteur égal au rapport entre le module des barres en PRF, Ef, et celui des barres en acier Es. Ce rapport prend en compte la différence de propriétés entre les barres en PRF et celles en acier, négligée par les modèles précédents. Le modèle proposé prédit bien les capacités de cisaillement des poutres BRFB-PRFB testées dans la présente étude avec des rapports moyens Vpre/Vexp = 0,82 ± 0,12 et 0,80 ± 0,01 pour les poutres des groupes A et B, respectivement. Les capacités de cisaillement des poutres en béton léger testées par Abbadi (2018) ont été prédites avec un rapport moyen Vpre/Vexp = 0,77 ± 0,05. De plus, le modèle prédit bien les capacités de cisaillement des poutres coulées avec du béton qui contient des fibres en acier testées par Awadallah et al. (2014) avec un rapport moyen Vpre/Vexp = 0,89 ± 0,07. Cela indique la large gamme d'applicabilité du modèle proposé. Cependant, il est recommandé d’évaluer le modèle proposé sur un ensemble de données plus large que celui présenté dans cette étude.
This study evaluates both experimentally and analytically the shear behavior of basalt fiber-reinforced concrete (BFRC) beams reinforced longitudinally with basalt fiber-reinforced polymer (BFRP) bars. A new type of basalt macro-fibers was added to the concrete mix to produce the BFRC mix. Fourteen beams (152 x 254 x 2000 mm) with no transverse reinforcement provided were tested under four-point loading configuration until failure occurred. The beams were grouped in two groups A and B depending on their span-to-depth ratios, a/d. Beams of group A had a ratio a/d of 3.3 while those of group B had a ratio a/d of 2.5. Besides the span-to-depth ratios, the parameters investigated included the volume fraction of the fibers added (0.75 and 1.5%) and the longitudinal reinforcement ratio of the BFRP reinforcing bars (0.31, 0.48, 0.69, 1.05, and 1.52). The test results showed that the addition of basalt macro-fibers to the concrete mix enhanced its compressive strength. A direct relationship between the fiber volume fraction, Vf, and the compressive strength was observed. Concrete cylinders cast with Vf of 0.75 and 1.5% yielded 11 and 30% increase in their compressive strengths over those cast with plain concrete, respectively. The addition of fibers greatly enhanced the shear capacity of BFRC-BFRP beams compared to their control beams cast with plain concrete. The increase of the fiber volume fraction decreased the spacing between cracks and hindered its propagation. A significant enhancement in the shear capacities of the tested beams was also observed when the basalt macro-fibers were added at a volume fraction Vf of 0.75%. The average increase in the shear capacities of beams of group A and B, having the same reinforcement ratios, were 45 and 44%, respectively, in comparison with those of the control beams. It was noticed that the gain in shear capacities of the tested beams was more pronounced in beams with a/d = 3.3 than in beams with a/d = 2.5 when the reinforcement ratio increased. In the analytical phase, several models were used to predict the shear capacities of the beams. All of the available models overestimated the shear capacities of the tested beams with average ratio Vpre/Vexp ranging between 1.29 to 2.64. This finding indicated that these models were not suitable to predict the shear capacities of the BFRC-BFRP beams. A new modified model incorporating the type of the longitudinal reinforcement, the type of FRC used, and the density of concrete is proposed. The model of Ashour et al. –A (1992) was calibrated using a calibration factor equal to the ratio of modulus of FRP bars used, Ef, and that of steel bars, Es. This ratio takes into consideration the difference in properties between the FRP and steel bars, which was overlooked by previous models. The proposed model predicted well the shear capacities of the BFRC-BFRP beams tested in the current study with average ratios Vpre/Vexp = 0.82 ± 0.12 and 0.80 ± 0.01 for beams of groups A and B, respectively. The shear capacities of the lightweight concrete beams tested by Abbadi (2018) were predicted with an average ratio Vpre/Vexp = 0.77 ± 0.05. Moreover, the model predicted well the shear capacities of the SFRC beams reinforced with BFRP bars tested by Awadallah et al. (2014) with an average ratio Vpre/Vexp = 0.89 ± 0.07. This indicates the wide range of applicability of the proposed model. However, it is recommended that the proposed model be assessed on larger set of data than that presented in this study

La concentration croissante de CO2 dans l'atmosphère et les dangers potentiels qu'elle représente pour la terre au travers des changements climatiques, l'acidification des océans et l'élévation du niveau de la mer a conduit à un certain nombre de projets qui tentent de trouver un moyen sûr et inoffensifs pour capturer et stocker le CO2 dans des formations géologiques. Une de ces tentatives se déroule actuellement en Islande à la centrale géothermique Hellisheiði, située à proximité de la capitale, Reykjavik (le projet CarbFix). Le dioxyde de carbone et d'autres gaz comme H2S, N2, H2, CH4, et Ar sont des sous-produits de l'exploitation de l'énergie géothermique et l'objectif est de stocker tout ce CO2 dans les formations basaltiques qui se situent sous Hellisheiði. Le CO2 est dissous dans un courant d'eau injecté par pompage dans puits jusqu'à à 350 mètres de profondeur et qui s'écoule ensuite au sein d'horizons mixtes de verre basaltique et de basalte cristallin. Les roches basaltiques sont caractérisées par des teneurs élevées en cations divalents comme Mg2+, Fe2+ et Ca2+ et des vitesses de dissolution relativement rapides. L'eau acide chargée en CO2 dissout le basalte, libérant ainsi des cations qui peuvent réagir avec les ions carbonates pour former des minéraux carbonatés (magnésite, sidérite, calcite, ankérite ainsi que des solutions solides (Ca-Mg-Fe)CO3)). Si on admet que c'est la dissolution des roches basaltiques qui contrôle ce processus de séquestration du carbone, on peut en déduire que tout ce qui pourra limiter cette dissolution sera préjudiciable à l'ensemble du processus de confinement du CO2. Mon rôle dans le projet CarbFix a été d'examiner les effets de la formation de revêtements de carbonate de calcium sur la dissolution des phases primaires de basalte. Je me suis concentrée sur le verre basaltique et le clinopyroxène, diopside, afin de comparer des phases cristallines et non cristallines. En outre, une série d'expériences ont été menées pour étudier l'effet de la structure du minéral primaire sur la nucléation de calcite. Ces expériences ont été faites pour vérifier si les différentes structures de silicate conduiraient à une différente étendue de la nucléation et croissance de la calcite à la surface des silicates. Enfin, de nombreuses expériences de dissolution de verre basaltique ont été menées en présence de bactéries hétérotrophes mortes et vivantes, Pseudomonas reactans, afin de déterminer l'effet des bactéries sur la dissolution des roches dans le système des eaux souterraines du site Hellisheiði. Les expériences de dissolution de verre basaltique et de diopside ont été réalisés à 25 et 70 °C pour un pH de 7-8 dans des réacteurs à circulation alimentés en solutions de forces ioniques > 0,03 mol / kg contenant CaCl2 ± NaHCO3. Deux séries d'essais ont été menés simultanément, une série appelée essais de 'précipitations' au cours de laquelle la solution dans le réacteur était sursaturée par rapport à la calcite, et l'autre série appelée essais de 'contrôle', pour laquelle la modélisation PHREEQC ne prévoyait pas formation de minéraux secondaires. Ainsi, il a été possible de comparer les vitesses de dissolution du verre basaltique et du diopside à 25 °C avec et sans la formation de carbonate de calcium et d'autres minéraux secondaires afin d'en déduire leur effet sur les vitesses de dissolution. Les images de microscopie électronique à balayage ont montré que des quantités importantes de carbonate de calcium ont précipité au cours des expériences de 'précipitations' mais, dans le cas du verre basaltique la croissance primaire se présente sous forme gros amas discrets de calcite et d'aragonite qui ne se forment pas sur le verre lui-même. Par contre, plusieurs des cristaux de diopside ont été largement envahis par des revêtements de calcite sans aragonite décelable. Dans les deux cas, la présence de calcite / aragonite n'a pas eu d'incidence sur les vitesses de dissolution du verre basaltique et de diopside qui sont les mêmes que celles mesurées dans la série 'contrôle'. Il semblerait que la couverture discontinue et poreuse de carbonates permet aux ions des phases primaires de continuer à diffuser sans entrave à travers la couche secondaire. Pour mieux évaluer l'effet de la surface des silicates sur la nucléation de la calcite, les vitesses de dissolution de six minéraux et roches silicatés ont été mesurées à 25 °C dans des réacteurs à circulation en présence de solutions de pH ~ 9,1 sursaturées par rapport à la calcite. Les phases silicatées étaient les suivantes: olivine, enstatite, augite, labradorite, verre basaltique et péridotite. Les résultats montrent que le temps d'induction pour la nucléation de calcite et l'étendue de la couverture de carbonatée avec le temps varient selon la phase silicatée. Dans un même laps de temps l'olivine, l'enstatite et la péridotite (principalement composé d'olivine riche en Mg) étaient les plus couvertes par les précipitations de calcite, suivis par l'augite, la labradorite et enfin le verre basaltique. Toute la croissance de calcite a eu lieu sur la surface du silicate, y compris sur le verre basaltique. La cinétique favorise la croissance de calcite par nucléation sur les minéraux orthorhombiques (enstatite et olivine) par rapport aux minéraux monocliniques et tricliniques. Les plus faibles quantités de calcite ont été trouvées sur le verre qui n'a pas de structure silicatée ordonnée. Des bactéries hétérotrophes, Pseudomonas reactans ont été extraites de l'un des puits de contrôle à Hellisheiði et ont ensuite été séparées, purifiées et cultivées en laboratoire. Avec le bouillon de culture utilisé, les conditions de croissance optimales de cette bactérie sont 5-37 °C et un pH de 7,0 à 8. Cette bactérie, très commune dans l'eau et le sol, est une bonne candidate pour tester l'impact des bactéries hétérotrophes en général lors de la séquestration du CO2 dans un aquifère naturel comme en Islande. Les vitesses de dissolution du verre basaltique ont été mesurés à 25 °C dans des nouveaux réacteurs à circulation permettant d'opérer en présence de bactéries (BMFR) dans des solutions tamponnées transportant 0,1 à 0,4 g/L de bactéries mortes et 0,9 à 19 g/L de bactéries vivantes à 4 = pH = 10. Les résultats ont montré que la présence de ces bactéries n'avait quasiment pas d'effet effet sur la vitesse de dissolution. La conclusion générale de cette étude est que ni les revêtements de carbonate, ni les bactéries n'ont d'impact majeur sur les vitesses de dissolution des phases primaires silicatées. Ainsi, leur effet devrait être négligeable sur le processus de séquestration du CO2 sur le site Hellisheiði en Islande. Le basalte cristallin pourrait être recouvert plus rapidement en carbonate de calcium, mais le verre basaltique pourrait aussi servir de support pour la nucléation de calcite
The increasing levels of CO2 in the atmosphere and the potential dangers this pose to the Earth through climate change, ocean acidification and sea-level rise has lead to a substantial number of projects attempting to find a safe and benign way to capture and store CO2 in geological formations, also referred to as the CCS (Carbon Capture Storage) technology. One of these CCS attempts is currently taking place in Iceland at the geothermal power plant Hellisheiði, located close to the capital Reykjavik (the CarbFix project). CO2 and other gasses (H2S, N2, H2, CH4) are waste products of the geothermal energy exploitation and the aim is with time to store all of this anthropogenic-made CO2 in the basaltic formations underlying Hellisheiði. The CO2 is dissolved in groundwater as it is pumped down to 350 meters depth and then injected into mixed horizons of basaltic glass and crystalline basalt. The basaltic rocks are characterized by high contents of divalent cations like Mg2+, Fe2+ and Ca2+ and relatively fast dissolution rates. The acidic CO2-loaded water will dissolve the basalt thereby releasing cations, which can react with the aqueous carbonate ions to form carbonate minerals (magnesite, siderite, calcite, ankerite and Ca-Mg-Fe solid solutions). The rate-limiting step of this carbon sequestration process is thought to be the dissolution of basaltic rocks, thus any effect that could potentially limit basalt dissolution would be detrimental to the overall CO2 sequestration process. My part of the CarbFix project has been to look at the effects the formation of calcium carbonate coatings would have on the dissolution of the primary phase, in this case basaltic glass and the clinopyroxene diopside, so there would be a glass phase to compare with the results of a mineral phase. Furthermore, a series of experiments were conducted where we tested the primary mineral structure's affect on calcite nucleation. This was done in order to test if different silicate structures would lead to different extent of calcite nucleation and growth. Finally, extensive series were conducted on the dissolution of basaltic glass in the presence of dead and live heterotrophic bacteria, Pseudomonas reactans in order to determine the potential effect of bacteria on the carbon storage effort at the Hellisheiði site. The basaltic glass and diopside dissolution experiments were run at 25 and 70 ºC and pH 7-8 in mixed-flow reactors connected to solutions containing CaCl2±NaHCO3 with ionic strengths > 0. 03 mol/kg. Two sets of experimental series were run simultaneously, one series called the "precipitation" experiments in which the solution inside the reactor was supersaturated with respect to calcite, and the other series called the "control" experiments, where PHREEQC modeling foretold no major secondary mineral formation. By this, it was possible to compare dissolution rates of basaltic glass and diopside at 25 ºC with and without calcium carbonate and other secondary mineral formation in order to deduce the effect on their dissolution rates. Scanning electron microscope images showed substantial amounts of calcium carbonate had precipitated in the "precipitation" experiments, but in the case of basaltic glass the primary growth appeared as big, discrete cluster of calcite and aragonite with no growth on the glass itself. Opposed to this, several of the diopside crystals were extensively overgrown by calcite coatings and no aragonite was found. In neither cases did the presence of calcite/aragonite have an effect on the dissolution rates of basaltic glass and diopside when compared to the "control' dissolution rates. It appears the discontinuous cover of the carbonate allows the ions of the primary phases to continue to diffuse through the secondary layer unhindered. To further assess the effect of silicate surface on the nucleation of calcite, the dissolution rates of six selected silicate minerals and rocks were measured in mixed-flow reactors in solutions supersaturated with respect to calcite at 25 ºC and pH ~9. 1. The silicate phases were: Mg-rich olivine, enstatite, augite, labradorite, basaltic glass and peridotite. The results show different onset time of calcite nucleation and thus different extent of carbonate coverage with elapsed time depending on silicate phase. Within the same timeframe olivine, enstatite and peridotite (mainly composed of Mg-rich olivine) were the most covered by calcite precipitations, followed by augite, labradorite and finally basaltic glass. All calcite growth took place on the silicate surface including on the basaltic glass. Kinetics favor calcite nucleation growth on the orthorhombic minerals (enstatite and olivine) over the monoclinic and triclinic minerals. Least calcite was found on the glass, which has no ordered silicate structure. Heterotrophic bacteria, Pseudomonas reactans was extracted from one of the monitoring wells at Hellisheiði, and then separated, purified and cultured in the laboratory. Its optimal growth conditions were found to be 5-37 ºC and pH 7. 0-8. 2 on Brain Heart Broth nutrient. Being a common water- and soil bacteria it offered a good candidacy to test what could be expected of heterotrophic bacteria in general when storing CO2 in a natural aquifers like the one at the Hellisheiði site, in Iceland. Basaltic glass dissolution rates were measured at 25 ºC in newly developed Bacterial Mixed-Flow reactors (BMFR) in buffer solutions carrying 0. 1-0. 4 g/L of dead bacteria and 0. 9-19 g/L of live bacteria at 4 = pH =10. The results show that the presence had either no or a slightly rate-limiting effect. The overall conclusion is that neither the carbonate coatings nor the bacteria had major impact on the measured dissolution rates of the primary silicate phases, thus their effect are expected to be negligible on the CO2 sequestration process in basalt. Crystalline basalt might be faster covered by calcium carbonate, but also basaltic glass can act as a nucleation platform for calcite nucleation

Laboratory experiments were conducted on vesicular basalt cores to estimate hydraulic properties. Properties included dry bulk density, effective porosity, skeletal density, saturated hydraulic conductivity and determination of moisture characteristic curves. Unsaturated hydraulic properties estimated included hydraulic conductivity and diffusivity as a function of matrix suction. Infiltration tests were run on a larger block of the same basalt. Infiltration curves were developed and saturated hydraulic conductivity estimated.

Seismic imaging of sub-basalt sedimentary layers is difficult due to high impedance of the basalt layer, the roughness of the top and bottom of the basalt layer and sometimes the heterogeneities within the basalt layer. In this thesis we identify specific problems within the modern imaging technology which limit sub-basalt imaging. The basic framework for the identification of this limitation is that we are able to group most basalt layers into the following four categories: A basalt layer having smooth top and bottom surfaces. A basalt layer having rough top and bottom surfaces. Small-scale heterogeneities within the basalt layer. Intra-basalt velocity variation due to different basalt flows. All the above models of basalt layers obviously have high impedance with respect to the surrounding sedimentary layers. These four models encapsulate all the possible heterogeneities of basalt layers seen in areas like the Voring and More basins off mid- Norway, basins in the Faroes, W. Greenland, Angola and Brazil margins, and the Deccan Traps of India. In this work, problems in seismic processing and imaging specific to these models have been presented. For instance, we have found that the application of the multiple attenuation technique, which first predicts the multiples and then subtracts them from the data, using least-squares criteria, can be effective for all the models except for the model, which has intra-bedded layers within the basalt. The failure in the second case is due to the destructive interference of multiple scattering from the intra-bedded layers within the basalt and the multiples located below the primary associated with the top of the basalt layer. This interference degrades the signal-to-noise (S/N) ratio of the multiples contained in the data, whereas the predicted multiples, which are constructed from the reflectors above the basalt, have a much higher signal-to-noise ratio. Our recommendation is to subtract the predicted multiples from the data using either leastabsolute- value criteria or any other higher-order-statistics-based criteria.

The Sabie River Basalt Formation is a group of tholeiitic basaltic rocks erupted ca 190 Ma ago in the eastern zone of the Karoo Igneous Province of southern Africa. It is traceable over a distance of 700 km from Zululand, northwards along the Lebombo monocline into the Transvaal and south-east Zimbabwe. An abrupt compositional change in this formation occurs about halfway down its length in the vicinity of the Sabie and Komati Rivers: basalts to the north are known to be enriched in certain incompatible elements relative to basalts in the south, which are comparable in geochemistry to most basaltic rocks in the southern part of the Karoo Igneous Province. New data obtained in this work include 134 major and trace element whole-rock analyses, some 400 analyses of constituent minerals, 38 ⁸⁷Sr/⁸⁶Sr ratio determinations, 19 ¹⁴³Nd/¹⁴⁴Nd ratio determinations, 16 common Pb determinations and 12 oxygen isotope analyses. The "normal" (N) and "enriched" basaltic rocks are distinguished by differences in the concentrations of Ti, P, Zr, Nb, Y, La, Ce and Nd (high field strength elements). Broadly these differences are substantiated by K, Rb, Ba and Sr, but with much more overlap. The "enriched" group of basaltic rocks has been further subdivided into a low-Fe "enriched" (LFE) group and a high-Fe "enriched" group (HFE). The LFE-group basalts, which predominate at the base of the stratigraphic sections, are considered to be equivalent to basalts occurring in the N. Lebombo. In the central Lebombo N-group basalts predominate in the mid- and upper portions of the sections and HFE-group basalt occurs near the top of each section. Interbedding of all basalt groups occurs in the Sabie River section at the northern end of the study area, while the N- and HFE-group basalts are interbedded in the Crocodile and Komati River sections further to the south. The decrease in LFE-group basalt abundance southwards is accompanied by an increase in N-group basalt abundance. HFE-group basalts appear to be unique to the central Lebombo area of the Karoo Igneous Province and are volumetrically less significant than N- or LFE-group basalts. Petrogenetic models involving closed-system fractional crystallization; coupled assimilation (of granitic crust) fractional crystallization; replenished, tapped and fractionated magma chambers and partial melting are examined. Granitic crustal contamination appears to have been significant only in some samples of the N group where assimilation of granitic material has proceeded in a bulk fashion described by an AFC model. RTF models are dynamically more realistic than closed-system fractional crystallization models and explain increases in incompatible elements with decreasing MgO in the LFE and HFE groups. Variations in the N group, however, require varying degrees of partial melting of a N-type source to be explained fully. RTF models may explain the absence of any stratigraphic correlations of element abundances in the three groups. The HFE group may be related to an uncontaminated N-type parent composition by a combination of continued fractional crystallization from an N-group parent composition and varying degrees of partial melting of an N-type source. The only petrogenetic process by which the N and LFE groups may be related is different degrees of partial melting. However, this demands a source composition which has no resemblance on trace element and isotopic grounds, to observed mantle xenolith compositions. The preferred model is one in which the LFE group is derived from old sub-cratonic mantle similar to garnet-bearing "cold" peridotite xenoliths and the N group from a source similar in composition to estimates of primitive mantle. The existence of two types of mantle derived continental flood basalt magmas occurs in other Mesozoic basalt provinces in "southern" Gondwanaland (e.g. Kirwanveggan of Antarctica, Etendeka of Namibia and the Parana Basin of South America). It is suggested that there is a geographical association of LFE-type basalts with Archaean crust (or Archaean crust re-worked in low temperature - high pressure events) and N-type basalts with post-Archaean crust (or Archaean crust re-worked in high temperature - low pressure events). This model suggests the derivation of the LFE group, from old sub-cratonic lithospheric mantle relatively enriched in incompatible elements and the N group being derived from more recently accreted and less enriched lithospheric mantle underlying younger crustal terraines.

ABSTRACT The Miocene Columbia River Basalt Group (CRBG) is world famous and the best studied continental flood basalt province on Earth. Decades of field and laboratory study have resulted in a detailed stratigraphy, consisting of seven formations containing more than 350 flows, a well-constrained chronology, and a large geochemical database. Petrogenesis of the flood basalts is constrained by many thousands of major element, trace element, and isotopic analyses of whole rocks and their constituent minerals. There is broad consensus that the province is the product of a deep mantle plume, although the details of plume interaction with North American lithosphere, and the generation, storage, transport, and eruption of flood basalt magma, are the subjects of continuing research. This field trip focuses on basalt flow sequences, dikes, vents, evolution of basaltic magmas through the lifetime of flood lava activity, and their relation to the larger Yellowstone Hotspot Province. The formations to be examined include the Imnaha, Grande Ronde, Wanapum, and Saddle Mountain Basalts. Trip stops are primarily along the Snake and Grande Ronde Rivers located in and adjacent to the canyon country of southeast Washington, western Idaho, and northeast Oregon.

The Deccan Volcanic Province of India is considered as one of the largest basalts-covered regions in the world, formed due to extensive outpouring of basaltic lavas during Deccan volcanism (∼65 Ma). The sedimentary sequence below the flood basalt is mainly characterized by Mesozoic strata with a varying thickness of 1000 m to 2500 m. It is considered that requisite heat generation due to Deccan Trap volcanism soon after the Cretaceous sedimentation may have acted as a catalyst in hydrocarbon potential in this area (Vardhan et al. 2008). However, it is essentially unexplored because of the limitations of conventional marine streamer P-wave seismic acquisition in imaging the structures both intra-basalt and sub-basalt. The major challenges can be considered as follows: Strong reflections due to high impedance contrasts at the top (and bottom) of the basalts leading to significant loss of transmitted seismic energy; Scattering of energy due to large acoustic impedance contrast at top and bottom of the basalt; Generation of multiples, both surface-related and interbed, from the top and bottom of the basalt, and intra-basalt boundaries, masking genuine primary reflections at the pre-basasediments; Significant attenuation of seismic energy in the basaltic sequences due to its complex internal structure generally causing weak sub-basasignal; Low signal-to-noise ratio creating ambiguity in estimating accurate velocity model of subsurface. This case study demonstrates that, even with legacy marine streamer surveys, an appropriate workflow of combining suitable advanced technologies can help to overcome the long-standing challenges of sub-basalt imaging. The reprocessed data show clear uplift in the sub-basalt imaging and the inversion results validate the quality of the new data in relation to the well logs.

ABSTRACT CO2 wettability and the reservoir rock-fluid interfacial interactions are crucial parameters that regulates the successful CO2 geological sequestration. This study implemented the feed-forward neural network to model the wettability behavior of Saudi Arabian (SA) basaltic rocks in a ternary system of basaltic rocks, CO2, and brine under different operating conditions. To gain higher accuracy of the machine learning models, a sufficient dataset was utilized that was recorded by conducting a large number of laboratory experiments under a realistic pressure range, 0 – 25 MPa and the temperatures range, 298 – 343 K. Different graphical exploratory data analysis techniques, such as heatmaps, violin plots, and pair plots were used to analyze the experimental dataset. The machine learning models were trained to predict the receding and advancing contact angles of SA basalt/CO2/brine systems. Both statistical evaluation and graphical analyses were performed to show the reliability and performance of the developed models. The results showed that the implemented ML model accurately predicted the wettability behavior under various operating conditions. INTRODUCTION Geological formations offer a promising solution to reduce global warming and achieve a low-CO2 economy by injecting carbon dioxide (CO2) into them (Alam et al., 2014; Bethke, 2007; Egermann et al., 2005, 2005; Iglauer et al., 2015; Wang et al., 1998). Saudi Arabia, a significant hydrocarbon-producing country, possesses numerous existing infrastructures and transportation pipelines suitable for natural gas storage, which could be utilized for large-scale CO2 storage in depleted hydrocarbon reservoirs, saline aquifers, and salt caverns. Moreover, sedimentary formations like shales, tight sandstone or carbonates, and igneous rocks such as basalts have recently emerged as potential formations to investigate for CO2 storage (Yan et al., 2022c). Dark-colored, fine-grained igneous rocks called basalts consist mainly of pyroxene, plagioclase, and olivine. They are more abundant and accessible than shales, and the Cenozoic volcanic rocks in Saudi Arabia are one of the largest areas of alkali olivine basalt worldwide, covering nearly 90,000 km2. Carbon mineralization is the primary method of CO2 storage in reactive rocks like basalt, and research has shown that basalt can be suitable for CO2 storage through this method, or residual trapping if the basalt formation is capped. Basalt is distributed worldwide with a favorable mineral composition, significant thickness, and good vesicular texture. In contrast to silica minerals in sedimentary formations, CO2 injection into volcanic rocks like basalt can swiftly initiate carbon mineralization and mineral trapping, as evidenced by successful pilot project trials conducted in Washington State (USA) and Iceland, which showed that most of the injected CO2 was mineralized in less than two years.