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Journal articles on the topic 'Aurophilicity'

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Published: 4 June 2021
Last updated: 6 February 2022

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1

Schmidbaur, Hubert, and Annette Schier. "A briefing on aurophilicity." Chemical Society Reviews 37, no. 9 (2008): 1931. http://dx.doi.org/10.1039/b708845k.

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2

Lin, Ivan JB, and Chandra Sekhar Vasam. "Review of gold(I) N-heterocyclic carbenes." Canadian Journal of Chemistry 83, no. 6-7 (June 1, 2005): 812–25. http://dx.doi.org/10.1139/v05-087.

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This review presents an overview of the work on Au(I)–NHC chemistry. The efficiency of different synthetic strategies of Au(I)–NHCs is discussed. Transmetallation of Ag(I)–NHCs appears to be an easy method as compared with the others. The influence of aurophilicity "a traditional property of a Au(I) center" in making the supramolecular assemblies is also covered. The combination of the Au(I) center with NHCs has great potential in the fields of medicine, catalysis, liquid crystal, and optoelectronic.Key words: gold–carbenes, silver–carbenes, carbene transfer, aurophilicity.
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3

OUYANG, Yi-Fu, Chang LIU, Hang YU, and Le-Fei YU. "Aurophilicity in Gold (Ⅰ) Species." University Chemistry 32, no. 2 (2017): 79–88. http://dx.doi.org/10.3866/pku.dxhx201603011.

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4

Castiñeiras, Alfonso, and Rosa Pedrido. "Aurophilicity in gold(i) thiosemicarbazone clusters." Dalton Trans. 41, no. 4 (2012): 1363–72. http://dx.doi.org/10.1039/c1dt11680k.

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5

Liu, Qi, Mo Xie, Xiaoyong Chang, Qin Gao, Yong Chen, and Wei Lu. "Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(i) double salt with infinite aurophilicity." Chemical Communications 54, no. 91 (2018): 12844–47. http://dx.doi.org/10.1039/c8cc05210g.

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Something learnt from a golden trio: polymorphs of a [Au(NHC)2][Au(CN)2] double salt allow an understanding of the thermochromic and mechanochromic phosphorescence of the gold(i) complexes with extended aurophilicity.
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6

Roberts, Ryan J., Debbie Le, and Daniel B. Leznoff. "Controlling intermolecular aurophilicity in emissive dinuclear Au(i) materials and their luminescent response to ammonia vapour." Chemical Communications 51, no. 76 (2015): 14299–302. http://dx.doi.org/10.1039/c5cc05277g.

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Intermolecular aurophilicity can be turned on in dinuclear gold(i) dithiolate anions by simply incorporating hydrogen-bonding cations; a drastic red-shift in photoluminescence results. NH3 vapour reversibly lengthens the aurophilic network and induces further emission and colour changes.
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7

Seifert, Tim P., Vanitha R. Naina, Thomas J. Feuerstein, Nicolai D. Knöfel, and Peter W. Roesky. "Molecular gold strings: aurophilicity, luminescence and structure–property correlations." Nanoscale 12, no. 39 (2020): 20065–88. http://dx.doi.org/10.1039/d0nr04748a.

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8

Croix, C., A. Balland-Longeau, H. Allouchi, M. Giorgi, A. Duchêne, and J. Thibonnet. "Organogold(I) complexes: Synthesis, X-ray crystal structures and aurophilicity." Journal of Organometallic Chemistry 690, no. 21-22 (November 2005): 4835–43. http://dx.doi.org/10.1016/j.jorganchem.2005.07.080.

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9

Do, Truong Giang, Emanuel Hupf, Enno Lork, Julius F. Kögel, Fabian Mohr, Alex Brown, Ryojun Toyoda, et al. "Aurophilicity and Photoluminescence of (6-Diphenylpnicogenoacenaphth-5-yl)gold Compounds." European Journal of Inorganic Chemistry 2019, no. 5 (January 17, 2019): 647–59. http://dx.doi.org/10.1002/ejic.201801190.

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10

Zank, Johann, Annette Schier, and Hubert Schmidbaur. "Aurophilicity-impaired internal molecular motion of trinuclear gold(I) complexes †." Journal of the Chemical Society, Dalton Transactions, no. 3 (1998): 323–24. http://dx.doi.org/10.1039/a708704g.

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11

Mirzadeh, Nedaossadat, Steven H. Privér, Alexander J. Blake, Hubert Schmidbaur, and Suresh K. Bhargava. "Innovative Molecular Design Strategies in Materials Science Following the Aurophilicity Concept." Chemical Reviews 120, no. 15 (July 14, 2020): 7551–91. http://dx.doi.org/10.1021/acs.chemrev.9b00816.

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12

O'Connor, Alice E., Nedaossadat Mirzadeh, Suresh K. Bhargava, Timothy L. Easun, Martin Schröder, and Alexander J. Blake. "Aurophilicity under pressure: a combined crystallographic and in situ spectroscopic study." Chemical Communications 52, no. 41 (2016): 6769–72. http://dx.doi.org/10.1039/c6cc00923a.

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High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(i) complex and further analysis confirms the presence of several types of intermolecular interactions.
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13

Li, Wan-Lu, Hong-Tao Liu, Tian Jian, Gary V. Lopez, Zachary A. Piazza, Dao-Ling Huang, Teng-Teng Chen, et al. "Bond-bending isomerism of Au2I3−: competition between covalent bonding and aurophilicity." Chemical Science 7, no. 1 (2016): 475–81. http://dx.doi.org/10.1039/c5sc03568f.

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14

Gründlinger, Petra, Michael Györök, Sebastian Wolfmayr, Tobias Breuer, Daniel Primetzhofer, Barbara Bruckner, Uwe Monkowius, and Thorsten Wagner. "Aggregation of Au(i)-complexes on amorphous substrates governed by aurophilicity." Dalton Transactions 48, no. 39 (2019): 14712–23. http://dx.doi.org/10.1039/c9dt03049b.

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15

Moreno-Alcántar, Guillermo, Guillermo Romo-Islas, Marcos Flores-Álamo, and Hugo Torrens. "Aurophilicity vs. thiophilicity: directing the crystalline supramolecular arrangement in luminescent gold compounds." New Journal of Chemistry 42, no. 10 (2018): 7845–52. http://dx.doi.org/10.1039/c7nj04354f.

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16

Rösch, Notker, Andreas Görling, Donald E. Ellis, and Hubert Schmidbaur. "Aurophilicity as Concerted Effect: Relativistic MO Calculations on Carbon-Centered Gold Clusters." Angewandte Chemie International Edition in English 28, no. 10 (October 1989): 1357–59. http://dx.doi.org/10.1002/anie.198913571.

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17

Muñiz, Jesús, Cong Wang, and Pekka Pyykkö. "Aurophilicity: The Effect of the Neutral Ligand L on [{ClAuL}2] Systems." Chemistry - A European Journal 17, no. 1 (January 3, 2011): 368–77. http://dx.doi.org/10.1002/chem.201001765.

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18

Pintado-Alba, Aranzazu, Héctor de la Riva, Mark Nieuwhuyzen, Delia Bautista, Paul R. Raithby, Hazel A. Sparkes, Simon J. Teat, José M. López-de-Luzuriaga, and M. Cristina Lagunas. "Effects of diphosphine structure on aurophilicity and luminescence in Au(i) complexes." Dalton Trans., no. 21 (2004): 3459–67. http://dx.doi.org/10.1039/b410619a.

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19

Han, Zhen, Xueli Zhao, Peng Peng, Si Li, Chong Zhang, Man Cao, Kai Li, Zhao-Yang Wang, and Shuang-Quan Zang. "Intercluster aurophilicity-driven aggregation lighting circularly polarized luminescence of chiral gold clusters." Nano Research 13, no. 12 (August 25, 2020): 3248–52. http://dx.doi.org/10.1007/s12274-020-2997-0.

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20

Bechtoldt, Alexander, Hans-Wolfram Lerner, and Michael Bolte. "The first example of a two-coordinated AuIatom bonded to an FeIIatom and an N-heterocyclic carbene (NHC) ligand." Acta Crystallographica Section C Structural Chemistry 71, no. 6 (May 13, 2015): 448–51. http://dx.doi.org/10.1107/s205322961500892x.

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The aurophilicity exhibited by AuIcomplexes depends strongly on the nature of the supporting ligands present and the length of the Au–element (Au—E) bond may be used as a measure of the donor–acceptor properties of the coordinated ligands. A binuclear iron–gold complex, [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene-2κC2]dicarbonyl-1κ2C-(1η5-cyclopentadienyl)gold(I)iron(II)(Au—Fe) benzene trisolvate, [AuFe(C5H5)(C27H36N2)(CO)2]·3C6H6, was prepared by reaction of K[CpFe(CO)2] (Cp is cyclopentadienyl) with (NHC)AuCl [NHC = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]. In addition to the binuclear complex, the asymmetric unit contains three benzene solvent molecules. This is the first example of a two-coordinated Au atom bonded to an Fe and a C atom of an N-heterocyclic carbene.
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21

Ehlich, Hendrik, Annette Schier, and Hubert Schmidbaur. "Aurophilicity-Based One-Dimensional Arrays of Gold(I) Phenylene-1,3- and -1,4-dithiolates." Inorganic Chemistry 41, no. 14 (July 2002): 3721–27. http://dx.doi.org/10.1021/ic020107i.

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22

Jobbágy, Csaba, Péter Baranyai, Gábor Marsi, Barbara Rácz, Liang Li, Panče Naumov, and Andrea Deák. "Novel gold(i) diphosphine-based dimers with aurophilicity triggered multistimuli light-emitting properties." Journal of Materials Chemistry C 4, no. 43 (2016): 10253–64. http://dx.doi.org/10.1039/c6tc01427e.

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We report a design strategy for the preparation of stimuli-responsive materials with multicolour emission that is based on a single type of luminophore molecule comprising gold(i) and a flexible diphosphine ligand.
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23

Schmidbaur, Hubert. "The aurophilicity phenomenon: A decade of experimental findings, theoretical concepts and emerging applications." Gold Bulletin 33, no. 1 (March 2000): 3–10. http://dx.doi.org/10.1007/bf03215477.

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24

Ghimire, Mukunda M., Vladimir N. Nesterov, and Mohammad A. Omary. "Remarkable Aurophilicity and Photoluminescence Thermochromism in a Homoleptic Cyclic Trinuclear Gold(I) Imidazolate Complex." Inorganic Chemistry 56, no. 20 (September 28, 2017): 12086–89. http://dx.doi.org/10.1021/acs.inorgchem.7b01679.

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25

Engesser, Tobias A., Christian Friedmann, Arthur Martens, Daniel Kratzert, Przemysław J. Malinowski, and Ingo Krossing. "Homoleptic Gold Acetonitrile Complexes with Medium to Very Weakly Coordinating Counterions: Effect on Aurophilicity?" Chemistry - A European Journal 22, no. 42 (September 4, 2016): 15085–94. http://dx.doi.org/10.1002/chem.201602797.

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26

Niermeier, Philipp, Lucas Wickemeyer, Beate Neumann, Hans-Georg Stammler, Lukas Goett-Zink, Tilman Kottke, and Norbert W. Mitzel. "Aurophilicity in action: stepwise formation of dinuclear Au(i) macrocycles with rigid 1,8-dialkynylanthracenes." Dalton Transactions 48, no. 13 (2019): 4109–13. http://dx.doi.org/10.1039/c8dt04783a.

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27

Scherbaum, Franz, Andreas Grohmann, Brigitte Huber, Carl Krüger, and Hubert Schmidbaur. "“Aurophilicity” as a Consequence of Relativistic Effects: The Hexakis(triphenylphosphaneaurio)methane Dication[(Ph3PAu)6C]2⊕." Angewandte Chemie International Edition in English 27, no. 11 (November 1988): 1544–46. http://dx.doi.org/10.1002/anie.198815441.

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28

Lagunas, M. Cristina, Claudio Mendicute Fierro, Aranzazu Pintado-Alba, Héctor de la Riva, and Soledad Betanzos-Lara. "Factors affecting luminescence and aurophilicity on digold(I) complexes and their potential as cation probes." Gold Bulletin 40, no. 2 (June 2007): 135–41. http://dx.doi.org/10.1007/bf03215570.

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29

Schmidbaur, Hubert. "ChemInform Abstract: The Aurophilicity Phenomenon: A Decade of Experimental Findings, Theoretical Concepts and Emerging Applications." ChemInform 32, no. 27 (May 25, 2010): no. http://dx.doi.org/10.1002/chin.200127231.

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30

Hunks, William J., Michael C. Jennings, and Richard J. Puddephatt. "Supramolecular Gold(I) Thiobarbiturate Chemistry: Combining Aurophilicity and Hydrogen Bonding to Make Polymers, Sheets, and Networks." Inorganic Chemistry 41, no. 17 (August 2002): 4590–98. http://dx.doi.org/10.1021/ic020178h.

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31

Elbjeirami, Oussama, and Mohammad A. Omary. "Photochemistry of Neutral Isonitrile Gold(I) Complexes: Modulation of Photoreactivity by Aurophilicity and π-Acceptance Ability." Journal of the American Chemical Society 129, no. 37 (September 2007): 11384–93. http://dx.doi.org/10.1021/ja0703933.

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32

Seki, Tomohiro, Kentaro Ida, Hiroyasu Sato, Shinji Aono, Shigeyoshi Sakaki, and Hajime Ito. "Aurophilicity‐Mediated Construction of Emissive Porous Molecular Crystals as Versatile Hosts for Liquid and Solid Guests." Chemistry – A European Journal 26, no. 3 (December 16, 2019): 735–44. http://dx.doi.org/10.1002/chem.201904597.

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33

Guo, Yuan-Ru, Qing-Jiang Pan, Gui-Zhen Fang, and Zhi-Ming Liu. "Theoretical studies on aurophilicity and excited-state properties in binuclear gold (I) trithiocarbonate and related complexes." Chemical Physics Letters 413, no. 1-3 (September 2005): 59–64. http://dx.doi.org/10.1016/j.cplett.2005.06.086.

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34

Chou, Chang-Chuan, Chia-Chi Yang, Hao-Ching Chang, Way-Zen Lee, and Ting-Shen Kuo. "Weaving an infinite 3-D supramolecular network via AuI⋯AuIII aurophilicity and C–H⋯Cl hydrogen bonding." New Journal of Chemistry 40, no. 3 (2016): 1944–47. http://dx.doi.org/10.1039/c5nj02860d.

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35

Fernández, Eduardo J., Antonio Laguna, José M. López-de-Luzuriaga, Miguel Monge, Manuel Montiel, M. Elena Olmos, and María Rodríguez-Castillo. "Unsupported Au(i)⋯Cu(i) interactions: influence of nitrile ligands and aurophilicity on the structure and luminescence." Dalton Transactions, no. 36 (2009): 7509. http://dx.doi.org/10.1039/b900768g.

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36

Canales, Fernando, M. Concepción Gimeno, Peter G. Jones, and Antonio Laguna. "Aurophilicity at Sulfur Centers: Synthesis and Structure of the Tetragold(I) Species[(Ph3PAu)4S](CF3SO3)2· 2CH2Cl2." Angewandte Chemie International Edition in English 33, no. 7 (April 18, 1994): 769–70. http://dx.doi.org/10.1002/anie.199407691.

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37

Vreshch, Volodimir, Wenting Shen, Brigitte Nohra, Sung-Kong Yip, Vivian Wing-Wah Yam, Christophe Lescop, and Régis Réau. "Aurophilicity versus Mercurophilicity: Impact of d10-d10 Metallophilic Interactions on the Structure of Metal-Rich Supramolecular Assemblies." Chemistry - A European Journal 18, no. 2 (December 6, 2011): 466–77. http://dx.doi.org/10.1002/chem.201102389.

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38

Canales, Fernando, Concepción Gimeno, Antonio Laguna, and M. Dolores Villacampa. "Aurophilicity at sulfur centers. Synthesis of the polyaurated species [S(AuPR3)n](n−2)+ (n = 2–6)." Inorganica Chimica Acta 244, no. 1 (March 1996): 95–103. http://dx.doi.org/10.1016/0020-1693(95)04759-x.

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39

Ai, Pengfei, Andreas A. Danopoulos, and Pierre Braunstein. "Aurophilicity-Triggered Assembly of Novel Cyclic Penta- and Hexanuclear Gold(I) Complexes with Rigid Anionic NHC-Type Ligands." Inorganic Chemistry 54, no. 8 (March 9, 2015): 3722–24. http://dx.doi.org/10.1021/acs.inorgchem.5b00276.

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40

Pan, Qing-Jiang, and Hong-Xing Zhang. "Ab initio Study on Luminescence and Aurophilicity of a Dinuclear [(AuPH3)2(i-mnt)] Complex (i-mnt = isomer-Malononitriledithiolate)." European Journal of Inorganic Chemistry 2003, no. 23 (December 2003): 4202–10. http://dx.doi.org/10.1002/ejic.200300389.

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41

Effendy, Peter C. Healy, Cassandra L. Noack, Brian W. Skelton, Allan H. White, and David J. Young. "Aurophilicity in Tetraphenylphosphonium 7,8-Bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-dibromo-digold(I) [PPh4][{(PPh2)2-C2B9H10}(AuBr)2]." Zeitschrift für anorganische und allgemeine Chemie 633, no. 15 (November 2007): 2689–91. http://dx.doi.org/10.1002/zaac.200700339.

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42

Foley, Janet B., Stanley E. Gay, Christopher Turmel, Gang Wei, Tong Jiang, Ratnavathany Narayanaswamy, Bruce M. Foxman, Michael J. Vela, Alice E. Bruce, and Mitchell R. M. Bruce. "Electronic Structure of Dinuclear Gold(I) Complexes." Metal-Based Drugs 6, no. 4-5 (January 1, 1999): 255–60. http://dx.doi.org/10.1155/mbd.1999.255.

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Cyclic voltammetry (CV) experiments on LL(AuSR∗)2 complexes [LL = diphenylphosphinomethane (dppm), diphenylphosphinopentane (dpppn); R* = p-SC6H4CH3] show anodic sweeps that broaden by about 25 mV on going from the longer (dpppn) to the shorter (dppm) bidentate phosphine ligand. Changing concentrations had no effect on the shape of the waveform. The result suggests a weak intramolecular metal-metal interaction in dppm(AuSR∗)2 that correlates well with rate acceleration occurring in the reaction of dppm(AuSR∗)2 with organic disulfides. Quantum yields for cis-dppee(AuX)2 [dppee = 1,2-bis(diphenylphosphino)ethylene; X = Cl, Br, I] complexes, (disappearance)Φ, are significantly higher in complexes with a softer X ligand, a trend that correlates well with aurophilicity. This result also suggests that electronic perturbation caused by Au(I)-Au(I) interactions is important in explaining the reactivity of some dinuclear gold(I) complexes. The crystal structure for cis-dppee(Aul)2 shows short intramolecular Au(I)-Au(I) interactions of 2.9526 (6) A°, while the structure of trans-dppee(AuI)2 , shows intermolecular Au(I)-Au(I) interactions of 3.2292 (9) A°. The substitution of .As for P results in a ligand, cis-diphenylarsinoethylene (cis-dpaee), that is photochemically active, in contrast to the cis-dppee ligand. The complexes, cis-dpaee(AuX)2, are also photochemically active but with lower quantum yields than the cis-dppee(AuX)2 complexes.
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43

Foley, Janet B., Stanley E. Gay, Michael J. Vela, Bruce M. Foxman, Alice E. Bruce, and Mitchell R. M. Bruce. "Structure and Photochemical Isomerization of the Dinuclear Gold(I) Halide Bis(diphenylphosphanyl)ethylene Complexes: Correlation Between Quantum Yield and Aurophilicity." European Journal of Inorganic Chemistry 2007, no. 31 (November 2007): 4946–51. http://dx.doi.org/10.1002/ejic.200700575.

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44

Zeman, Charles J., Yu-Hsuan Shen, Jessica K. Heller, Khalil A. Abboud, Kirk S. Schanze, and Adam S. Veige. "Excited-State Turn-On of Aurophilicity and Tunability of Relativistic Effects in a Series of Digold Triazolates Synthesized via iClick." Journal of the American Chemical Society 142, no. 18 (April 8, 2020): 8331–41. http://dx.doi.org/10.1021/jacs.0c01624.

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45

Dong, Wen, Yan Ouyang, Li-Na Zhu, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, and Peng Cheng. "Two Mn(II)–Au(I) supramolecular assemblies bonded by coordination, aurophilicity and hydrogen-bonding, π–π interactions and their magnetic properties." Inorganic Chemistry Communications 10, no. 7 (July 2007): 779–83. http://dx.doi.org/10.1016/j.inoche.2007.03.022.

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46

Zeman, Charles J., Yu-Hsuan Shen, Jessica K. Heller, Khalil A. Abboud, Kirk S. Schanze, and Adam S. Veige. "Correction to “Excited-State Turn-On of Aurophilicity and Tunability of Relativistic Effects in a Series of Digold Triazolates Synthesized via iClick”." Journal of the American Chemical Society 142, no. 33 (August 4, 2020): 14391. http://dx.doi.org/10.1021/jacs.0c07691.

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47

Colacio, Enrique, Francesc Lloret, Raikko Kivekäs, José Ruiz, José Suárez-Varela, and Markku R. Sundberg. "Aurophilicity as a cofactor in crystal engineering. Dicyanoaurate(i) anion as a building block in a novel Co(ii)–Au(i) bimetallic assembly." Chemical Communications, no. 6 (February 20, 2002): 592–93. http://dx.doi.org/10.1039/b110020c.

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48

Colacio, Enrique, Francesc Lloret, Raikko Kivekaes, Jose Ruiz, Jose Suarez-Varela, and Markku R. Sundberg. "ChemInform Abstract: Aurophilicity as a Cofactor in Crystal Engineering. Dicyanoaurate(I) Anion as a Building Block in a Novel Co(II)-Au(I) Bimetallic Assembly." ChemInform 33, no. 23 (May 21, 2010): no. http://dx.doi.org/10.1002/chin.200223023.

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49

Colacio, Enrique, Francesc Lloret, Raikko Kivekäs, José Suárez-Varela, Markku R. Sundberg, and Rolf Uggla. "Aurophilicity−Coordination Interplay in the Design of Cyano-Bridged Nickel(II)−Gold(I) Bimetallic Assemblies: Structural and Computational Studies of the Gold(I)−Gold(I) Interactions." Inorganic Chemistry 42, no. 2 (January 2003): 560–65. http://dx.doi.org/10.1021/ic025949w.

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50

Leznoff, Daniel B., Bao-Yu Xue, Brian O. Patrick, Victor Sanchez, and Robert C. Thompson. "An aurophilicity-determined 3-D bimetallic coordination polymer: using [Au(CN)2]− to increase structural dimensionality through gold‥gold bonds in (tmeda)Cu[Au(CN)2]2." Chemical Communications, no. 3 (2001): 259–60. http://dx.doi.org/10.1039/b007342n.

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