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Journal articles on the topic 'Asymmetric synthesis'

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Published: 4 June 2021

Last updated: 28 July 2024

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1

Chen, Fen-Er, and Lei Chen. "Total Synthesis of Camptothecins: An Update." Synlett 28, no. 10 (March 15, 2017): 1134–50. http://dx.doi.org/10.1055/s-0036-1588738.

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Over the last few decades, considerable research efforts have been directed toward the development of effective chemical syntheses of camptothecin and its analogs. The last comprehensive review of this area was published in 2003 and many effective new methods have since been reported for the stereoselective synthesis of the camptothecin alkaloids. In this account, we have summarized most of the novel synthetic approaches developed for the synthesis of camptothecins during the last decade. We have focused on strategies for the construction of the pentacyclic ring system and the different methods used to install the chiral quaternary center on the E ring of camptothecin.1 Introduction2 Synthesis of Racemic Camptothecins3 Enantioselective Synthesis of Camptothecins3.1 Sharpless Asymmetric Dihydroxylation3.2 Catalytic Asymmetric Cyanosilylation3.3 Auxiliary-Induced Asymmetric Carbonyl Addition3.4 Catalytic Asymmetric Ethylation3.5 Asymmetric Hydroxylation4 Conclusion

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2

Arseniyadis, S., P. Q. Huang, D. Piveteau, and H. P. Husson. "Asymmetric synthesis." Tetrahedron 44, no. 9 (January 1988): 2457–70. http://dx.doi.org/10.1016/s0040-4020(01)81697-5.

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3

Jurczak, Janusz, and Tomasz Bauer. "Glyoxylic acid derivatives in asymmetric synthesis." Pure and Applied Chemistry 72, no. 9 (January 1, 2000): 1589–96. http://dx.doi.org/10.1351/pac200072091589.

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Synthesis of chiral derivatives of glyoxylic acid with special emphasis on N-glyoxyloyl-(2R)-bornane-10,2-sultam is presented. Investigation of glyoxylic acid chiral derivatives in various stereocontrolled organic syntheses showed their excellent ability to provide products of high optical purity. Application of our methodology to the synthesis of natural products and their analogs is presented.

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4

Deng, Yongming, Qing-Qing Cheng, and Michael Doyle. "Asymmetric [3+3] Cycloaddition for Heterocycle Synthesis." Synlett 28, no. 14 (July 5, 2017): 1695–706. http://dx.doi.org/10.1055/s-0036-1588453.

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Asymmetric syntheses of six-membered ring heterocycles are important research targets not only in synthetic organic chemistry but also in pharmaceuticals. The [3+3]-cycloaddition methodology is a complementary strategy to [4+2] cycloaddition for the synthesis of heterocyclic compounds. Recent progress in [3+3]-cycloaddition processes provide powerful asymmetric methodologies for the construction of six-membered ring heterocycles with one to three heteroatoms in the ring. In this account, synthetic efforts during the past five years toward the synthesis of enantioenriched six-membered ring heterocycles through asymmetric [3+3] cycloaddition are reported. Asymmetric organocatalysis uses chiral amines, thioureas, phosphoric acids, or NHC catalysis to achieve high enantiocontrol. Transition-metal catalysts used as chiral Lewis acids to activate a dipolar species is an alternative approach. The most recent advance, chiral transition-metal-catalyzed reactions of enoldiazo compounds, has contributed toward the versatile and highly selective synthesis of six-membered heterocyclic compounds.1 Introduction2 Asymmetric Formal [3+3]-Cycloaddition Reactions by Organocatalysis2.1 By Amino-Catalysis2.2 By N-Heterocyclic Carbenes2.3 By Bifunctional Tertiary Amine-thioureas2.4 By Chiral Phosphoric Acids3 Asymmetric Formal [3+3]-Cycloaddition Reactions by Transition-Metal Catalysis3.1 Copper Catalysis3.2 Other Transition-Metal Catalysis4 Asymmetric [3+3]-Cycloaddition Reactions of Enoldiazo Compounds4.1 Asymmetric [3+3]-Cycloaddition Reactions of Nitrones with Electrophilic Metallo-enolcarbene Intermediates4.2 Dearomatization in Asymmetric [3+3]-Cycloaddition Reactions of Enoldiazoacetates4.3 Asymmetric Stepwise [3+3]-Cycloaddition Reaction of Enoldiazoacetates with Hydrazones5 Summary and Outlook

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5

Devi, Runjun, and Sajal Kumar Das. "Studies directed toward the exploitation of vicinal diols in the synthesis of (+)-nebivolol intermediates." Beilstein Journal of Organic Chemistry 13 (March 21, 2017): 571–78. http://dx.doi.org/10.3762/bjoc.13.56.

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While the exploitation of the Sharpless asymmetric dihydroxylation as the source of chirality in the synthesis of acyclic molecules and saturated heterocycles has been tremendous, its synthetic utility toward chiral benzo-annulated heterocycles is relatively limited. Thus, in the search for wider applications of Sharpless asymmetric dihydroxylation-derived diols for the synthesis of benzo-annulated heterocycles, we report herein our studies in the asymmetric synthesis of (R)-1-((R)-6-fluorochroman-2-yl)ethane-1,2-diol, (R)-1-((S)-6-fluorochroman-2-yl)ethane-1,2-diol and (S)-6-fluoro-2-((R)-oxiran-2-yl)chroman, which have been used as late-stage intermediates for the asymmetric synthesis of the antihypertensive drug (S,R,R,R)-nebivolol. Noteworthy is that a large number of racemic and asymmetric syntheses of nebivolol and their intermediates have been described in the literature, however, the Sharpless asymmetric dihydroxylation has never been employed as the sole source of chirality for this purpose.

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6

PFANDER, H. "ChemInform Abstract: Carotenoid Synthesis. Asymmetric Syntheses." ChemInform 28, no. 6 (August 4, 2010): no. http://dx.doi.org/10.1002/chin.199706303.

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7

Khangarot, Rama Kanwar, Manisha Khandelwal, and Sumit Kumar Ray. "Syntheses and Applications of Singh’s Catalyst." Synthesis 52, no. 23 (August 19, 2020): 3577–82. http://dx.doi.org/10.1055/s-0040-1707235.

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Singh’s catalyst has emerged as one of the most promising and valuable catalysts in the field of asymmetric synthesis. Since its discovery, it has proven to be one of the best organocatalysts for asymmetric direct aldol reactions, and is equally efficient in aqueous and organic media. In this Short Review, we summarize reactions utilizing Singh’s catalyst under various conditions.1 Introduction2 Synthesis of Singh’s Catalyst3 Applications in Asymmetric Synthesis4 Conclusion

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8

Huang, Deng-Ming, Hui-Jing Li, Jun-Hu Wang, and Yan-Chao Wu. "Asymmetric total synthesis of talienbisflavan A." Organic & Biomolecular Chemistry 16, no. 4 (2018): 585–92. http://dx.doi.org/10.1039/c7ob02837g.

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The first asymmetric total syntheses of talienbisflavan A and bis-8,8′-epicatechinylmethane as well as a facile synthesis of bis-8,8′-catechinylmethane has been accomplished from readily available starting materials by using a newly developed direct regioselective methylenation of catechin derivatives as one of the key steps.

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9

Dhayalan, Vasudevan, Rambabu Dandela, K. Bavya Devi, and Ragupathy Dhanusuraman. "Synthesis and Applications of Asymmetric Catalysis Using Chiral Ligands Containing Quinoline Motifs." SynOpen 06, no. 01 (January 18, 2022): 31–57. http://dx.doi.org/10.1055/a-1743-4534.

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AbstractIn the past decade, asymmetric synthesis of chiral ligands containing quinoline motifs, a family of natural products displaying a broad range of structural diversity and their metal complexes, have become the most significant methodology for the generation of enantiomerically pure compounds of biological and pharmaceutical interest. This review provides comprehensive insight on the plethora of nitrogen-based chiral ligands containing quinoline motifs and organocatalysts used in asymmetric synthesis. However, it is confined to the synthesis of quinoline-based chiral ligands and metal complexes, and their applications in asymmetric synthesis as homogeneous and heterogeneous catalysts.1 Introduction2 Synthesis of Chiral Ligands Containing Quinoline Motifs2.1 Synthesis of Schiff Base Type Chiral Ligands2.2 Synthesis of Oxazolinyl-Type Chiral Ligands2.3 Synthesis of Chiral N,N-Type Ligands2.4 Synthesis of Amine-Based Chiral Ligands2.5 Synthesis of P,N-Type Chiral Ligands2.6 Synthesis of Chiral N-Oxide and Nitrogen Ligands3 Homogeneous Catalytic Asymmetric Reactions3.1 Asymmetric Carbon–Carbon Bond Formation Reactions3.2 Asymmetric Allylic Reactions3.3 Asymmetric Cycloadditions3.4 Asymmetric Carbene Insertions3.5 Asymmetric Pinacol Couplings3.6 Asymmetric Pudovik Reactions3.7 Asymmetric Strecker Reactions4 Heterogeneous Catalytic Asymmetric Reactions4.1 Asymmetric Cyclopropanation of Olefins4.2 Asymmetric Heck Reactions4.3 Asymmetric Hydrogenations4.4 Asymmetric Hydroformylation of Styrene4.5 Asymmetric Dialkoxylation of 2-Propenylphenols4.6 Asymmetric Cascade Cyclizations4.7 Asymmetric Allylic Alkylations4.8 Asymmetric Alkylation of β-Keto Esters4.9 Asymmetric C–H Bond Arylation Reactions4.10 Intramolecular Aerobic Oxidative Amination of Alkenes4.11 Asymmetric Oxidative Hydroboration of Alkenes5 Conclusions

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10

NOYORI, Ryoji. "Catalytic Asymmetric Synthesis." Journal of Synthetic Organic Chemistry, Japan 50, no. 12 (1992): 1131–39. http://dx.doi.org/10.5059/yukigoseikyokaishi.50.1131.

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11

Zhu, Jieping, Jean-Charles Quirion, and Henri-Philippe Husson. "Asymmetric synthesis XVIII." Tetrahedron Letters 30, no. 38 (1989): 5137–40. http://dx.doi.org/10.1016/s0040-4039(01)93468-9.

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12

Brown, John M. "Catalytic Asymmetric Synthesis." Synthesis 1994, no. 03 (1994): 335. http://dx.doi.org/10.1055/s-1994-25470.

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13

Brown, John M., and Stephen G. Davies. "Chemical asymmetric synthesis." Nature 342, no. 6250 (December 1989): 631–36. http://dx.doi.org/10.1038/342631a0.

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14

Denmark, Scott E., and Eric N. Jacobsen. "Catalytic Asymmetric Synthesis." Accounts of Chemical Research 33, no. 6 (June 2000): 324. http://dx.doi.org/10.1021/ar000046x.

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15

Kim, Yong Hae, Sam Min Kim, Doo Han Park, and So Won Youn. "Stereocontrolled asymmetric synthesis." Pure and Applied Chemistry 72, no. 9 (January 1, 2000): 1691–97. http://dx.doi.org/10.1351/pac200072091691.

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Stereo differentiated asymmetric syntheses have been achieved by S-indoline derivations. Diels-Alder cycloadditions of S-indoline chiral acrylamides with cyclopentadiene proceed with high diastereofacial selectivity, giving either endo-R or endo-S products depending on Lewis acid and the structures of chiral dienophiles. Diastereo- and enantio-selective pinacol coupling reactions of chiral α-ketoamides mediated by samarium diiodide afforded extremely high diastereoselectivities. Enantiopure (S,S)- or (R,R)-2,3-dialkyltar-taric acid and derivatives can be synthesized for the first time depending on the structure of α-ketoamides.

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16

Oehme, G. "Catalytic Asymmetric Synthesis." Zeitschrift für Physikalische Chemie 191, Part_1 (January 1995): 141–42. http://dx.doi.org/10.1524/zpch.1995.191.part_1.141.

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17

Caddick, S. "Catalytic asymmetric synthesis." Journal of Organometallic Chemistry 490, no. 1-2 (March 1995): C38—C39. http://dx.doi.org/10.1016/0022-328x(95)90303-v.

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18

Hashmi, Stephen. "Catalytic Asymmetric Synthesis." Advanced Synthesis & Catalysis 343, no. 8 (December 31, 2001): 827. http://dx.doi.org/10.1002/1615-4169(20011231)343:8<827::aid-adsc827>3.0.co;2-1.

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19

Pereira, Ana Margarida, Honorina Cidade, and Maria Elizabeth Tiritan. "Stereoselective Synthesis of Flavonoids: A Brief Overview." Molecules 28, no. 1 (January 3, 2023): 426. http://dx.doi.org/10.3390/molecules28010426.

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Stereoselective synthesis has been emerging as a resourceful tool because it enables the obtaining of compounds with biological interest and high enantiomeric purity. Flavonoids are natural products with several biological activities. Owing to their biological potential and aiming to achieve enantiomerically pure forms, several methodologies of stereoselective synthesis have been implemented. Those approaches encompass stereoselective chalcone epoxidation, Sharpless asymmetric dihydroxylation, Mitsunobu reaction, and the cycloaddition of 1,4-benzoquinone. Chiral auxiliaries, organo-, organometallic, and biocatalysis, as well as the chiral pool approach were also employed with the goal of obtaining chiral bioactive flavonoids with a high enantiomeric ratio. Additionally, the employment of the Diels–Alder reaction based on the stereodivergent reaction on a racemic mixture strategy or using catalyst complexes to synthesise pure enantiomers of flavonoids was reported. Furthermore, biomimetic pathways displayed another approach as illustrated by the asymmetric coupling of 2-hydroxychalcones driven by visible light. Recently, an asymmetric transfer hydrogen-dynamic kinetic resolution was also applied to synthesise (R,R)-cis-alcohols which, in turn, would be used as building blocks for the stereoselective synthesis of flavonoids.

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20

Rouh, Hossein, Yao Tang, Ting Xu, Qingkai Yuan, Sai Zhang, Jia-Yin Wang, Shengzhou Jin, et al. "Aggregation-Induced Synthesis (AIS): Asymmetric Synthesis via Chiral Aggregates." Research 2022 (August 12, 2022): 1–9. http://dx.doi.org/10.34133/2022/9865108.

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A new chiral aggregate-based tool for asymmetric synthesis has been developed by taking advantage of chiral aggregates of GAP (Group-Assisted Purification) reagents, N-phosphonyl imines. This tool was proven to be successful in the asymmetric GAP synthesis of functionalized 2,3-dihydrobenzofurans by reacting salicyl N-phosphonyl imines with dialkyl bromomalonates in various cosolvent systems. The chiral induction can be controlled by differentiating between two asymmetric directions simply by changing the ratios of cosolvents which are commonly adopted in AIE (aggregation-induced emission) systems. The formation of chiral aggregates was witnessed by a new analytical tool—aggregation-induced polarization (AIP). The present synthetic method will be broadly extended for general organic synthesis, particularly, for asymmetric synthesis and asymmetric catalysis in the future.

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21

Choi, Hosam, Hanho Jang, Joohee Choi, and Kiyoun Lee. "Stereoselective Synthesis of Oxazolidin-2-ones via an Asymmetric Aldol/Curtius Reaction: Concise Total Synthesis of (−)-Cytoxazone." Molecules 26, no. 3 (January 23, 2021): 597. http://dx.doi.org/10.3390/molecules26030597.

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Herein, we are reporting an efficient approach toward the synthesis of 4,5-disubstituted oxazolidin-2-one scaffolds. The developed approach is based on a combination of an asymmetric aldol and a modified Curtius protocol, which uses an effective intramolecular ring closure to rapidly access a range of oxazolidin-2-one building blocks. This strategy also permits a straightforward and concise asymmetric total synthesis of (−)-cytoxazone. Consisting of three steps, this is one of the shortest syntheses reported to date. Ultimately, this convenient platform would provide a promising method for the early phases of drug discovery.

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22

Mackenzie, Peter B., John Whelan, and B. Bosnich. "Asymmetric synthesis. Mechanism of asymmetric catalytic allylation." Journal of the American Chemical Society 107, no. 7 (April 1985): 2046–54. http://dx.doi.org/10.1021/ja00293a039.

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23

Kumagai, Naoya, Masakatsu Shibasaki, Yuya Ota, and Zhao Li. "Catalytic Asymmetric Synthesis of syn Aldols with Methyl Ketone Functionality and anti Aldols with a Thioamide Group." Synlett 30, no. 05 (February 13, 2019): 620–24. http://dx.doi.org/10.1055/s-0037-1610690.

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Catalytic asymmetric syntheses of syn aldols with a methyl ketone functionality were studied to confirm the generality of the methodology. In addition, catalytic asymmetric synthesis of anti aldols with a thioamide group was carefully examined, giving the desired products, albeit with moderate diastereoselectivity.

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24

Durmaz, Mustafa, Erkan Halay, and Selahattin Bozkurt. "Recent applications of chiral calixarenes in asymmetric catalysis." Beilstein Journal of Organic Chemistry 14 (June 8, 2018): 1389–412. http://dx.doi.org/10.3762/bjoc.14.117.

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The use of calixarenes in asymmetric catalysis is receiving increasing attention due to their tunable three-dimensional molecular platforms along with their easy syntheses and versatile modification at the upper and lower rims. This review summarizes the recent progress of synthesis and use of chiral calixarenes in asymmetric syntheses which emerged later than 2010.

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25

Qingle, Zeng, Qiaoling Zhang, Jufang Xi, and He Ze. "Syntheses and Transformations of Sulfinamides." Synthesis 53, no. 15 (March 11, 2021): 2570–82. http://dx.doi.org/10.1055/a-1426-4744.

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AbstractSulfinamides, especially enantiopure sulfinamides, are widely used in organic and medicinal synthesis. Syntheses and transformations of racemic and enantioenriched sulfinamides have achieved great progress. Especially sulfinamides demonstrate interesting and valuable reactivity, which deserves to be pertinent. This review summarizes the latest development in the synthesis and transformation of sulfinamides and will be helpful for future related research.1 Introduction2 Synthesis of Sulfinamides2.1 Synthesis of Racemic Sulfinamides2.2 Synthesis of Enantiomerically Pure Sulfinamides2.3 Synthesis of Other Sulfinamides3 Transformations of Sulfinamides3.1 Condensation with Aldehydes and Ketones3.2 Reaction with Alkynes3.3 Reaction with Alkenes3.4 Reaction with Aryl and Alkyl Halides3.5 Reaction with Alcohols, Dibenzyl Ether, and Benzyl Mercaptan3.6 Synthesis of tert-Butyldisulfanyl-Substituted Hetarenes3.7 Synthesis of Asymmetric Sulfides3.8 Synthesis of N-Phosphino-sulfinamide Ligands3.9 Asymmetric Synthesis of γ-Amino Acids3.10 Sulfonylation of Heterocyclic Compounds4 Summary and Outlook

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26

Monasterolo, Claudio, Helge Müller-Bunz, and Declan G. Gilheany. "Very short highly enantioselective Grignard synthesis of 2,2-disubstituted tetrahydrofurans and tetrahydropyrans." Chemical Science 10, no. 26 (2019): 6531–38. http://dx.doi.org/10.1039/c9sc00978g.

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27

Xie, Yangchun, Tao Yang, Junjun Ma, and Xiaohua He. "Synthesis, surface activities and aggregation properties of asymmetric Gemini surfactants." Physical Chemistry Chemical Physics 23, no. 48 (2021): 27460–67. http://dx.doi.org/10.1039/d1cp04216e.

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Gemini surfactants with an asymmetric structure (PKO 15-3(OH)-n) synthesized through a ring-opening reaction followed by a quaternization reaction exhibited higher surface activity and could assemble into vesicles or micelles with changing the asymmetry.

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28

Du, Yonglei, Jian Li, Kerong Chen, Chenglin Wu, Yu Zhou, and Hong Liu. "Construction of highly enantioenriched spirocyclopentaneoxindoles containing four consecutive stereocenters via thiourea-catalyzed asymmetric Michael–Henry cascade reactions." Beilstein Journal of Organic Chemistry 13 (July 7, 2017): 1342–49. http://dx.doi.org/10.3762/bjoc.13.131.

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The thiourea-catalyzed asymmetric synthesis of highly enantioenriched spirocyclopentaneoxindoles containing chiral amide functional groups using simple 3-substituted oxindoles and nitrovinylacetamide as starting materials was achieved successfully. This protocol features operational simplicity, high atom economy, and high catalytic asymmetry, thus representing a versatile approach to the synthesis of highly enantioenriched spirocyclopentaneoxindoles.

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29

Yus, Miguel. "Copper-Catalyzed Asymmetric Synthesis." Current Organic Chemistry 18, no. 15 (September 16, 2014): 2047. http://dx.doi.org/10.2174/138527281815140916093030.

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30

Uenishi, Jun'ichi, Mitsuhiro Motoyama, Yumi Kimura, and Osamu Yonemitsu. "Asymmetric Synthesis of Thietanose." HETEROCYCLES 47, no. 1 (1998): 439. http://dx.doi.org/10.3987/com-97-s(n)67.

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31

Blakemore, Paul R., Volker K. Schulze, and James D. White. "Asymmetric synthesis of (+)-loline." Chemical Communications, no. 14 (2000): 1263–64. http://dx.doi.org/10.1039/b003121f.

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32

Hua, Duy H., S. Venkataraman, Robert A. Ostrander, Gurudas Z. Sinai, Peggy J. McCann, M. Jo Coulter, and Min Ren Xu. "Asymmetric synthesis of (+)-hirsutene." Journal of Organic Chemistry 53, no. 3 (February 1988): 507–15. http://dx.doi.org/10.1021/jo00238a007.

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33

Sen, Subhabrata, Ganesh Prabhu, Chandramohan Bathula, and Santanu Hati. "Diversity-Oriented Asymmetric Synthesis." Synthesis 46, no. 16 (July 30, 2014): 2099–121. http://dx.doi.org/10.1055/s-0033-1341247.

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34

Mineeva, I. V. "Asymmetric synthesis of valilactone." Russian Journal of Organic Chemistry 50, no. 1 (January 2014): 100–104. http://dx.doi.org/10.1134/s1070428014010199.

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35

Jain, Rajendra P., Brian K. Albrecht, Duane E. DeMong, and Robert M. Williams. "Asymmetric Synthesis of (+)-Hypusine." Organic Letters 3, no. 26 (December 2001): 4287–89. http://dx.doi.org/10.1021/ol016959o.

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36

Itoh, Toshimasa, Naoki Yamazaki, and Chihiro Kibayashi. "Asymmetric Synthesis of (−)-Adaline." Organic Letters 4, no. 15 (July 2002): 2469–72. http://dx.doi.org/10.1021/ol0200807.

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37

Baird, C. P., A. J. Clark, S. M. Rooke, T. J. Sparey, and P. C. Taylor. "Sulfimide-mediated Asymmetric Synthesis." Phosphorus, Sulfur, and Silicon and the Related Elements 120, no. 1 (January 1, 1997): 365–66. http://dx.doi.org/10.1080/10426509708545551.

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38

Kesler, Brenda. "Asymmetric Synthesis (Procter, Garry)." Journal of Chemical Education 75, no. 5 (May 1998): 546. http://dx.doi.org/10.1021/ed075p546.

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39

Dai-Fei, Huang, and Huang Liang. "Asymmetric synthesis of (-)-dehydroclausenamide." Tetrahedron 46, no. 9 (January 1990): 3135–42. http://dx.doi.org/10.1016/s0040-4020(01)85453-3.

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40

Raghavan, Sadagopan, and Kailash Rathore. "Asymmetric synthesis of (−)-tetrahydrolipstatin." Tetrahedron 65, no. 48 (November 2009): 10083–92. http://dx.doi.org/10.1016/j.tet.2009.09.062.

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41

Zuberi, Sheena, Angela Glen, Robert C. Hider, and Sukhvinder S. Bansal. "Synthesis of asymmetric systines." Tetrahedron Letters 39, no. 41 (October 1998): 7567–70. http://dx.doi.org/10.1016/s0040-4039(98)01614-1.

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42

Chandrasekhar, S., S. Shameem Sultana, N. Kiranmai, and Ch Narsihmulu. "Asymmetric synthesis of (+)-tetrahydropseudodistomin." Tetrahedron Letters 48, no. 13 (March 2007): 2373–75. http://dx.doi.org/10.1016/j.tetlet.2007.01.143.

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43

Garg, Ashish, Ravi P. Singh, and Vinod K. Singh. "Asymmetric synthesis of (+)-cardiobutanolide." Tetrahedron 62, no. 48 (November 2006): 11240–44. http://dx.doi.org/10.1016/j.tet.2006.09.005.

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44

Case-Green, Stephen C., Stephen G. Davies, and Charles J. R. Hedgecock. "Asymmetric Synthesis of (-)-Tetrahydrolipstatin." Synlett 1991, no. 11 (1991): 781–82. http://dx.doi.org/10.1055/s-1991-20872.

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45

Bunnage, Mark E., Stephen G. Davies, and Christopher J. Goodwin. "Asymmetric Synthesis of Allophenylnorstatine." Synlett 1993, no. 10 (1993): 731–32. http://dx.doi.org/10.1055/s-1993-22587.

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46

North, Michael. "Catalytic Asymmetric Cyanohydrin Synthesis." Synlett 1993, no. 11 (1993): 807–20. http://dx.doi.org/10.1055/s-1993-22618.

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47

Williams, Robert M., and James A. Hendrix. "Asymmetric synthesis of arylglycines." Journal of Organic Chemistry 55, no. 12 (June 1990): 3723–28. http://dx.doi.org/10.1021/jo00299a009.

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48

Pohmakotr, Manat, Chutima Kuhakarn, Vichai Reutrakul, and Darunee Soorukram. "Asymmetric synthesis of furofurans." Tetrahedron Letters 58, no. 51 (December 2017): 4740–46. http://dx.doi.org/10.1016/j.tetlet.2017.11.011.

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49

Comins, Daniel L., and Hao Hong. "Asymmetric synthesis of (-)-porantheridine." Journal of the American Chemical Society 115, no. 19 (September 1993): 8851–52. http://dx.doi.org/10.1021/ja00072a053.

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50

Garner, Philip, Wen Bin Ho, and Hunwoo Shin. "Asymmetric synthesis of (-)-quinocarcin." Journal of the American Chemical Society 114, no. 7 (March 1992): 2767–68. http://dx.doi.org/10.1021/ja00033a089.

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