Relevant bibliographies by topics / Asymmetric dihydroxylation

Academic literature on the topic 'Asymmetric dihydroxylation'

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Published: 4 June 2021
Last updated: 20 February 2023

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Journal articles on the topic "Asymmetric dihydroxylation"

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Kolb, Hartmuth C., Michael S. VanNieuwenhze, and K. Barry Sharpless. "Catalytic Asymmetric Dihydroxylation." Chemical Reviews 94, no. 8 (December 1994): 2483–547. http://dx.doi.org/10.1021/cr00032a009.

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Crispino, Gerard A., and K. Barry Sharpless. "Asymmetric dihydroxylation of squalene." Tetrahedron Letters 33, no. 30 (July 1992): 4273–74. http://dx.doi.org/10.1016/s0040-4039(00)74236-5.

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Jeong, Kyu-Sung, Peter Sjö, and K. Barry Sharpless. "Asymmetric dihydroxylation of enynes." Tetrahedron Letters 33, no. 27 (June 1992): 3833–36. http://dx.doi.org/10.1016/s0040-4039(00)74797-6.

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Fleming, Steven A., Sean M. Carroll, Jennifer Hirschi, Renmao Liu, J. Lee Pace, and J. Ty Redd. "Asymmetric dihydroxylation of allenes." Tetrahedron Letters 45, no. 17 (April 2004): 3341–43. http://dx.doi.org/10.1016/j.tetlet.2004.03.037.

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Kolb, Hartmuth C., and K. Barry Sharpless. "ChemInform Abstract: Asymmetric Dihydroxylation." ChemInform 30, no. 12 (June 17, 2010): no. http://dx.doi.org/10.1002/chin.199912312.

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Devi, Runjun, and Sajal Kumar Das. "Studies directed toward the exploitation of vicinal diols in the synthesis of (+)-nebivolol intermediates." Beilstein Journal of Organic Chemistry 13 (March 21, 2017): 571–78. http://dx.doi.org/10.3762/bjoc.13.56.

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While the exploitation of the Sharpless asymmetric dihydroxylation as the source of chirality in the synthesis of acyclic molecules and saturated heterocycles has been tremendous, its synthetic utility toward chiral benzo-annulated heterocycles is relatively limited. Thus, in the search for wider applications of Sharpless asymmetric dihydroxylation-derived diols for the synthesis of benzo-annulated heterocycles, we report herein our studies in the asymmetric synthesis of (R)-1-((R)-6-fluorochroman-2-yl)ethane-1,2-diol, (R)-1-((S)-6-fluorochroman-2-yl)ethane-1,2-diol and (S)-6-fluoro-2-((R)-oxiran-2-yl)chroman, which have been used as late-stage intermediates for the asymmetric synthesis of the antihypertensive drug (S,R,R,R)-nebivolol. Noteworthy is that a large number of racemic and asymmetric syntheses of nebivolol and their intermediates have been described in the literature, however, the Sharpless asymmetric dihydroxylation has never been employed as the sole source of chirality for this purpose.
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Morikawa, Kouhei, and K. Barry Sharpless. "Double diastereoselection in asymmetric dihydroxylation." Tetrahedron Letters 34, no. 35 (August 1993): 5575–78. http://dx.doi.org/10.1016/s0040-4039(00)73885-8.

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Feng, Zhi-Xiang, and Wei-Shan Zhou. "Asymmetric dihydroxylation of heteroaromatic acrylates." Tetrahedron Letters 44, no. 3 (January 2003): 493–95. http://dx.doi.org/10.1016/s0040-4039(02)02605-9.

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STINSON, STEPHEN. "Asymmetric Dihydroxylation Of Olefins Achieved." Chemical & Engineering News 66, no. 12 (March 21, 1988): 19–20. http://dx.doi.org/10.1021/cen-v066n012.p019.

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Fleming, Steven A., Renmao Liu, and J. Ty Redd. "Asymmetric dihydroxylation of disubstituted allenes." Tetrahedron Letters 46, no. 47 (November 2005): 8095–98. http://dx.doi.org/10.1016/j.tetlet.2005.09.138.

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Dissertations / Theses on the topic "Asymmetric dihydroxylation"

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Nelson, Adam Stephen. "The asymmetric dihydroxylation of allylic phosphine oxides." Thesis, University of Cambridge, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627579.

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Liu, Renmao. "Asymmetric dihydroxylation and aziridination of allenes and related chemestry /." Diss., CLICK HERE for online access, 2007. http://contentdm.lib.byu.edu/ETD/image/etd1843.pdf.

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Liu, Renmao. "Asymmetric Dihydroxylation and Aziridination of Allenes and Related Chemistry." BYU ScholarsArchive, 2007. https://scholarsarchive.byu.edu/etd/899.

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A novel method for asymmetric synthesis of α-hydroxy ketone with excellent regio- and stereoselectivity has been established by the systematic investigation of asymmetric dihydroxylation of allenes. The efficiency of kinetic resolution of racemic allenes was also investigated by using the AD reaction on both 1,3-disubstituted and trisubstituted allenes. Steric effects, electronic effects and allene substitution are also discussed. Aziridines were formed by copper-catalyzed intramolecular nitrene addition to alkenes. The carbamate group was used as the tether between the alkene and the nitrene. Subsequent nucleophilic attack of the aziridine was accomplished using RSH, R2NH, N3-,or ROH as the nucleophile. This addition was found to be regio- and stereoselective. This methodology has provided a new strategy for the stereoselective construction of three adjacent functional groups, in particular the 1,2 diamino-3-hydroxy unit. The rhodium-catalyzed intramolecular aziridination of allenic N-sulfonyloxy carbamates has been established. Efficient ring opening of these bicyclic compounds may provide synthetic utility in organic chemistry. The intramolecular aziridination of allenic sulfamate esters was tested on a single example to afford in situ a ring opened product.
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Sunose, Mihiro. "Asymmetric methods for functionalisation of nitrogen heterocycles." Thesis, University of Bristol, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297768.

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Gally, Christine [Verfasser], and Bernhard [Akademischer Betreuer] Hauer. "Enzymatic asymmetric dihydroxylation of alkenes / Christine Gally ; Betreuer: Bernhard Hauer." Stuttgart : Universitätsbibliothek der Universität Stuttgart, 2016. http://d-nb.info/1118370341/34.

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Shanmugathasan, Sakthitharan. "Model studies directed towards the asymmetric synthesis of neocarzinostatin chromophore." Thesis, University of Sussex, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.360501.

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Griffen, Julia Anne. "Underexploited (ipso, ortho) microbial arene dihydroxylation : uses in synthesis & catalysis." Thesis, University of Bath, 2013. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.619147.

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This thesis sought to expand upon the synthetic application of the underexploited ipso, ortho diene cis-diol microbial arene oxidation product from benzoic acid. The microbial oxidation of benzoic acid by mutant strains of bacteria to give the ipso, otho diene cis-diol may be considered to be a green and clean method. This biocatalytic route yields large quantities of an enantiopure chiral building block, which is not assessable via traditional synthetic methods. The fermentation product has seen application towards the synthesis of aminocylitols, which have been tested for their biological activity. Attempts to synthesise the fully oxygenated counterparts, cyclitols, were investigated. Expansion of previous work using a bromine substituted derivative led to a range of cross-coupled and iron co-ordinated products. Finally, a range of novel chiral acids and ketones were synthesised and evaluated for their catalytic activity towards asymmetric epoxidation.
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Bhunnoo, Riaz A. "Permanganate promoted bi-directional oxidative cyclisation (Part 1) ; Permanganate-mediated asymmetric dihydroxylation (Part 2)." Thesis, University of Southampton, 2005. https://eprints.soton.ac.uk/426926/.

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DeClue, Michael Scott. "Functionalized polymers : synthesis of photorefractive polymers and solid phase asymmetric dihydroxylation ligands on polysiloxane /." Diss., Connect to a 24 p. preview or request complete full text in PDF formate. Access restricted to UC campuses, 2002. http://wwwlib.umi.com/cr/ucsd/fullcit?p3071006.

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Shuter, Emily Clare. "Studies toward the synthesis of the microsclerodermin natural products." Faculty of Science, School of Chemistry, University of Sydney, 2006. http://hdl.handle.net/2123/1970.

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Doctor of Philosophy (PhD), Science
A concise stereo-selective synthesis of a protected form of APTO 1, an unusual amino acid component of microsclerodermin C 2, was undertaken. Sequential Sharpless Asymmetric Aminohydroxylation (AA) and Asymmetric Dihydroxylation (AD) reactions were used to introduce the chiral amino and hydroxyl groups. Specific directing groups were chosen to ensure high regio- and enantio-selectivity in these reactions. The target compound was reached in a linear reaction sequence of fourteen steps. The strategy was designed to generate common intermediates which could be used to access analogous amino acid fragments in other microsclerodermins. A protected form of AETD 3, from microsclerodermin E, was synthesised via a late-stage common intermediate. Initial studies into the modification of the sequence to allow access to AMPTD 4 and 10-methyl AMPTD 5 were made.
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Book chapters on the topic "Asymmetric dihydroxylation"

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Li, Jie Jack. "Sharpless asymmetric dihydroxylation." In Name Reactions, 549–51. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_249.

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Jack Li, Jie. "Sharpless asymmetric dihydroxylation." In Name Reactions, 499–501. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_233.

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Li, Jie Jack. "Sharpless Asymmetric Dihydroxylation." In Name Reactions, 493–96. Cham: Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_137.

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Johnson, Roy A., and K. Barry Sharpless. "Asymmetric Oxidations and Related Reactions: Catalytic Asymmetric Dihydroxylation-Discovery and Development." In Catalytic Asymmetric Synthesis, 357–98. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/0471721506.ch11.

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Bolm, Carsten, Jens P. Hildebrand, and Kilian Muñiz. "Asymmetric Oxidations and Related Reactions: Recent Advances in Asymmetric Dihydroxylation and Aminohydroxylation." In Catalytic Asymmetric Synthesis, 399–428. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/0471721506.ch12.

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Pini, Dario, Antonella Petri, Alberto Mastantuono, and Piero Salvadori. "Heterogeneous Enantioselective Hydrogenation and Dihydroxylation of Carbon Carbon Double Bond Mediated by Transition Metal Asymmetric Catalysts." In Chiral Reactions in Heterogeneous Catalysis, 155–76. Boston, MA: Springer US, 1995. http://dx.doi.org/10.1007/978-1-4615-1909-6_18.

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Hodgson, D. M., and P. G. Humphreys. "Asymmetric Dihydroxylation." In Alcohols, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00492.

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Robina, I., and P. Vogel. "Sharpless Asymmetric Dihydroxylation." In Ethers, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-037-00518.

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Muñiz, K. "Sharpless Asymmetric Dihydroxylation of Alkenes." In Stereoselective Synthesis 1 Stereoselective Reactions of Carbon—Carbon Double Bonds, 1. Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-201-00005.

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Maier, M. E. "Asymmetric Dihydroxylation Followed by Lactonization." In Three Carbon-Heteroatom Bonds: Acid Halides; Carboxylic Acids and Acid Salts, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-020-01373.

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Conference papers on the topic "Asymmetric dihydroxylation"

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Xu, Yi, Aitao Li, Xin Jia, and Zhi Li. "Asymmetric Trans-dihydroxylation of Cyclic Olefins by Enzymatic or Chemo-enzymatic Sequential Epoxidation and Hydrolysis in One Pot." In 14th Asia Pacific Confederation of Chemical Engineering Congress. Singapore: Research Publishing Services, 2012. http://dx.doi.org/10.3850/978-981-07-1445-1_719.

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