Dissertations / Theses on the topic 'Archaean'
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Brown, Isobel Julia. "Geology and geochemistry of Archaean gold mineralization, Arcturus District, Zimbabwe." Thesis, Oxford Brookes University, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.290402.
Full textDougherty-Page, Jon Stanley. "The evolution of the Archaean continental crust of Northern Zimbabwe." Thesis, Open University, 1994. http://oro.open.ac.uk/54877/.
Full textRobertson, S. "Late Archaean crustal evolution in the Ivisartoq region, southern west Greenland." Thesis, University of Exeter, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.353048.
Full textOpiyo-Akech, Norbert. "Geology and geochemistry of the late Archaean greenstone associations, Maseno area, Kenya." Thesis, University of Leicester, 1988. http://hdl.handle.net/2381/35080.
Full textCarles, Patricia 1975. "Constraints on the genesis of the Archaean Troilus gold-copper deposit, Quebec." Thesis, McGill University, 2000. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=31204.
Full textRocks of the Troilus domain include a coarse- to medium-grained metadiorite, a finer-grained amphibolite, a rock with a brecciated texture and felsic dykes, which crosscut the metadioritic pluton, the amphibolite and the breccia. The amphibolite, breccia, and felsic dykes all locally host ore.
Previous researchers have proposed a porphyry-type model for the genesis of the Troilus deposit. However, evidence that the breccia unit is not hydrothermal but a product of magma mixing, that the felsic dykes predate mineralization, and that mineralization and associated alteration occurred as two discrete events separated by a major episode of regional metamorphism (amphibolite facies), requires that alternative genetic models for the deposit be considered, such as orogenic gold model. (Abstract shortened by UMI.)
Horstwood, Matthew Simon Anthony. "Stratigraphy, geochemistry and zircon geochronology of the Midlands Greenstone Belt, Zimbabwe." Thesis, University of Southampton, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246222.
Full textLane, Monica Leonie. "Nickel sulphide mineralization associated with Archean komatiites." Thesis, Rhodes University, 1992. http://hdl.handle.net/10962/d1005594.
Full textStubbs, Heather M. "The geochemistry and petrogenesis of Archaean and paleoproterozoic dykes and sills of Zimbabwe." Thesis, University of Portsmouth, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.440491.
Full textWightman, R. T. "Constraints on crustal development and tectonics in the Archaean rocks of south India." Thesis, Open University, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374494.
Full textTaylor, Jeanne. "The anatectic history of Archaean metasedimentary granulites from the Ancient Gneiss Complex, Swaziland." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/20311.
Full textENGLISH ABSTRACT: This study is an investigation of the anatectic history of high-grade paragneisses from the Ancient Gneiss Complex (AGC) in Swaziland. The work involved an integrated field, metamorphic, geochemical, geochronological and structural study of metasedimentary granulites from three separate, but spatially related areas of outcrop in south-central Swaziland, which were subjected to multiple high-grade partial melting events throughout the Meso- to Neoarchaean. The project has aimed to constrain the age(s) and conditions of metamorphism, so as to contribute to the understanding of geodynamic processes in the Barberton and AGC granite-greenstone terranes, as well as to investigate certain physical and chemical aspects of anatexis in the migmatites. The metamorphic record retained in these rocks, constrained by phase equilibria modelling as well as zircon and monazite SHRIMP and LA-ICP-MS geochronology, informs on the state of the mid- to lower-crust of the southeastern Kaapvaal Craton during key events associated with early lithosphere assembly and crustal differentiation. It also suggests that the region is comprised of more than one high-grade terrane. Two of the areas investigated experienced high-temperature metamorphism at ca. 3.23-3.21 Ga, in addition to a major 830-875º C, 6.5-7.6 kbar anatectic event at ca. 3.11-3.07 Ga. Intermediate and younger high-temperature events are recorded at ca. 3.18 Ga, ca. 3.16 Ga and 2.99 Ga. The timing of these metamorphic events coincided with the amalgamation of the eastern domain of the proto-Craton via subduction and accretion of micro-continental fragments at ca. 3.23 Ga, including the Barberton Greenstone Belt (BGB) and AGC terranes, as well as discrete episodes of crustal differentiation and potassic granitic magmatism between ca. 3.23 and 3.10 Ga. The third area investigated holds no record of Mesoarchaean metamorphism, but instead experienced a 830- 855 ºC, 4.4-6.4 kbar partial melting episode at ca. 2.73 Ga. This broadly coincided with the formation of a large continental flood basalt province, the ca. 2.71 Ga Ventersdorp LIP, and widespread intracratonic granitic magmatism on the Craton towards the end of the Neoarchaean. An explanation for the contrast in metamorphic record in the two terranes may be that the 2.71 Ga granulites represent a much younger sedimentary succession, and that granulites from the older terrane were left too restitic, after substantial partial melting during the Mesoarchaean, to record subsequent high-grade events. Finally, this study documents the details of S-type granitic magma production and extraction from a typical metapelitic source. Using the 2.73 Ga granulites from the AGC as a natural field laboratory, a case is made for the selective entrainment of peritectic garnet to the magma as a mechanism for generating relatively mafic, peraluminous S-type granite compositions. The work demonstrates the evolution of entrained peritectic garnet in such magmas, and is in strong support of a ‘peritectic phase entrainment’ process by which relatively mafic granite magmas are produced from melts which, in theory, should be highly leucocratic.
AFRIKAANSE OPSOMMING: Hierdie studie ondersoek die anatektiese geskiedenis van hoëgraadse metasedimentêre gneise uit die Ancient Gneiss Complex (AGC) in Swaziland. Die werk behels 'n geïntegreerde veld, metamorfiese, geochemiese, geochronologiese en strukturele studie van metasedimentêre granuliete van drie afsonderlike, maar ruimtelik verwante gebiede in suid-sentraal Swaziland, wat aan verskeie hoëgraadse anatektiese gebeure onderworpe was gedurende die Meso-tot Neoargeïese tydsperiode. Die studie is daarop gemik om die ouderdomme en die kondisies van metamorfose vas te stel, om sodoende by te dra tot die begrip van die geodinamiese prosesse in die Barberton en AGC granietgroensteen terrein, asook om sekere fisiese en chemiese aspekte van die anatektiese proses te ondersoek. Die metamorfe rekord, bepaal deur mineraal ewewigsmodellering sowel as sirkoon en monasiet SHRIMP en LA-ICP-MS geochronologie, belig die toestand van die middel-tot laer-kors van die suidoostelike Kaapvaal Kraton tydens vroeë litosfeer samesmelting en differensiasie. Dit stel ook voor dat die streek uit meer as een hoëgraadse terrein bestaan. Twee van die gebiede het hoë-temperatuur metamorfose by 3.23-3.21 Ga ervaar, asook 'n hoof 830-875 ° C, 6.5-7.6 kbar anatektiese gebeurtenis by 3.11-3.07 Ga. Intermediêre en jonger hoë-temperatuur gebeure was ook by 3.18 Ga, 3.16 Ga en 2.99 Ga geregistreer. Die metamorfose van die gebied stem ooreen met die samesmelting van die oos Kaapvaal Kraton domein deur subduksie en aanwas van mikro-kontinente by 3.23 Ga, insluitend die Barberton en AGC terreine, asook diskrete episodes van kors differensiasie en kalium-ryke graniet magmatisme tussen 3.23 en 3.10 Ga. Die derde gebied hou geen rekord van Mesoargeïkum metamorfose nie. In plaas daarvan het dit 'n 830-855 ° C, 4.4-6.4 kbar anatektiese episode by 2.73 Ga ervaar, wat ooreenstem met die vorming van 'n groot kontinentale vloedbasalt provinsie, die 2.71 Ga Ventersdorp Supergroep, en wydverspreide intrakratoniese graniet magmatisme teen die einde van die Neoargeïkum. 'n Moontlike verduideliking vir die kontras in metamorfe rekord in die twee terreine mag wees dat die 2.71 Ga granuliete 'n jonger sedimentêre afsetting verteenwoordig, en dat granuliete van die ouer terrein te restieties gelaat was na aansienlike anateksis in die Mesoargeïkum, om daaropvolgende hoëgraadse gebeure te registreer. Ten slotte, hierdie studie dokumenteer die besonderhede van S-tipe graniet magma produksie en ontginning van 'n tipiese metasedimentêre bron. Die 2.73 Ga granuliete word gebruik as 'n natuurlike veld laboratorium om die selektiewe optel-en-meevoering van peritektiese granaat tot die magma te ondersoek. Die werk toon die evolusie van peritektiese granate in sulke magmas aan, en ondersteun lewering van relatiewe mafiese graniet magmas deur 'n ‘peritektiese fase optel-en-meevoerings’ proses.
Oak, Keith Alan. "The geology and geochemistry of Closepet granite, Karnataka, South India." Thesis, Oxford Brookes University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.278897.
Full textPark, J. F. W. "Fault systems in the inner Godthabsfjord region of the Archaean Block, southern west Greenland." Thesis, University of Exeter, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377322.
Full textMellqvist, Claes. "Proterozoic crustal growth along the Archaean continental margin in the Luleå area, northern Sweden." Licentiate thesis, Luleå tekniska universitet, 1997. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-18235.
Full textHapugoda, Hapugoda Udage Sarath. "Late Archaean and Early Proterozoic crustal evolution of the Georgetown Block, Northeast Queensland, Australia /." St. Lucia, Qld, 2002. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe16503.pdf.
Full textWalsh, Carl. "Deep ultra-hot Archaean mantle dynamics; highly depleted residues as cradles for mantle diamond." Thesis, Queensland University of Technology, 2022. https://eprints.qut.edu.au/235717/1/Carl%2BWalsh%2BThesis.pdf.
Full textSilva, Katherine E. "Komatiites from the Belingwe Greenstone Belt, Zimbabwe : constraints on the development of Archaean Greenstone Belts." Thesis, Royal Holloway, University of London, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263522.
Full textBrewer, M. A. "The petrology of the Late Archaean gneisses and granites, Nunatarssuaq, Ivisartoq region, southern West Greenland." Thesis, University of Exeter, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.370924.
Full textYearron, Lorraine M. "Archaean granite petrogenesis and implications for the evolution of the Barberton mountain land, South Africa." Thesis, Kingston University, 2003. http://eprints.kingston.ac.uk/20723/.
Full textWiemer, Daniel. "Tectonic evolution of the Early Archaean Doolena Gap Greenstone Belt, East Pilbara Terrane, Western Australia." Thesis, Queensland University of Technology, 2017. https://eprints.qut.edu.au/102985/1/Daniel_Wiemer_Thesis.pdf.
Full textRivard, Benoit. "Petrochemistry of a layered Archean magma chamber and its relation to models of basalt evolution." Thesis, McGill University, 1985. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=66046.
Full textMellqvist, Claes. "Proterozoic crustal growth along the archaean continental margin in the Luleå and Jokkmokk areas, northern Sweden /." Luleå, 1999. http://epubl.luth.se/1402-1544/1999/24/index.html.
Full textCrewe, M. A. "The petrogenesis of Archaean basic and ultrabasic rocks from Ujaragssuit nunat, Ivisartoq region, southern West Greenland." Thesis, University of Exeter, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.372574.
Full textGilligan, Jonathan Mark. "The geology, geochemistry and genesis of gold mineralization associated with Archaean iron-formation, Lennox mine, Zimbabwe." Thesis, University of Southampton, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.292080.
Full textSnape, Ian. "Geological and geochemical anatomy of Archaean gneisses from the Vestfold Hills and Rauer Group, East Antarctica." Thesis, University of Edinburgh, 1997. http://hdl.handle.net/1842/14437.
Full textMaxlow, James. "Quantification of an Archaean to Recent Earth Expansion Process Using Global Geological and Geophysical Data Sets." Thesis, Curtin University, 2001. http://hdl.handle.net/20.500.11937/2423.
Full textMaxlow, James. "Quantification of an archaean to recent earth expansion process using global geological and geophysical data sets /." Full text available, 2001. http://adt.curtin.edu.au/theses/available/adt-WCU20020117.145715.
Full textHofmann, Axel. "Sedimentology and tectonic history of late Archaean sedimentary successions in Zimbabwe a study in greenstone belt geology /." [S.l.] : [s.n.], 2001. http://ArchiMeD.uni-mainz.de/pub/2002/0026/diss.pdf.
Full textWoodhouse, Ailsa Jane. "Provenance of late archaean metasedimentary rocks on the southern Gawler craton : implications for its early crustal development /." Title page, table of contents and abstract only, 2002. http://web4.library.adelaide.edu.au/theses/09SB/09sbw889.pdf.
Full textZulbati, Petrillo Fabio. "P-T-fluid conditions of an end-Archaean granulite-facies metamorphism in the Vestfold Hills, East Antartica." Thesis, University of Edinburgh, 2002. http://hdl.handle.net/1842/13259.
Full textBurke, Shyne Duncan Caleb Padraig. "On carbonate alteration zones in a greenstone keel of the East Pilbara Terrane (Doolena Gap Greenstone Belt)." Thesis, Queensland University of Technology, 2017. https://eprints.qut.edu.au/107570/1/Duncan_Burke%20-%20Shyne_Thesis.pdf.
Full textRich, Benjamin H. "An investigation of the Archaean Wangary Gneiss and its relevance to the evolution of the southern Gawler Craton /." Title page, abstract and contents only, 2000. http://web4.library.adelaide.edu.au/theses/09SB/09sbr498.pdf.
Full textWinter, Caroline Jane. "Geology and base-metal mineralization associated with Archaean iron-formation in the Pojuca Corpo Quatro deposit, Carajas, Brazil." Thesis, University of Southampton, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241182.
Full textNicoli, Gautier. "The metamorphic and anatectic history of Archaean metapelitic granulites from the South Marginal Zone, Limpopo Belt, South Africa." Thesis, Stellenbosch : Stellenbosch University, 2015. http://hdl.handle.net/10019.1/97041.
Full textENGLISH ABSTRACT: Anatexis is the first step in granite genesis. Partial melting in the lower crust may produce leucoratic features of unusual chemical compositions, very different from the final products of crustal differentiation. Therefore, the links that exists between some migmatites and crustal-derived granites can be ambiguous. This study is an investigation of the anatectic history of a high-grade terrain: the Southern Marginal Zone of the Limpopo Belt (SMZ), north to the Kaapvaal Craton in South Africa. The work involved an integrated field, metamorphic, geochemical and geochronogical study of the metasedimentary granulites from two separate quarries in the northern zone of the Southern Marginal Zone, the Bandelierkop quarry and the Brakspruit quarry, where Neoarchean high-grade partial melting features can be observed. The project has aimed to address two main issues: (1) to accurately constrain the pressuretemperature conditions and the age of the metamorphic episode in the SMZ, with implication for the geodynamic processes near the end of the Archean, (2) to investigate the fluid-absent partial melting reactions that control formation of K2O-poor leucosomes and to understand the chemical relationships in the system source-leucosome-melt–S-type granite. The P-T-t record retained in the Bandelierkop Formation metapelites, constrained by phase equilibria modelling as well as zircon LA-ICP-MS geochronology, gives an insight into crustal differentiation processes in the lower crust. Rocks in both quarries indicate high-temperature metamorphism episodes with peak conditions of 840-860 oC and 9-11 kbar at c. 2.71 Ga with formation of leucosomes (L1) during the prograde path. Minor leucocratic features (L2) were produced during decompression to 6-7 kbar. The end of the metamorphic event is marked by the granulites/amphibolites facies transition (< 640 oC) at c. 2.68 Ga. The maximum deposit age for the detrital zircons in the metapelites (c. 2.73 Ga) indicates a rapid burial process ( 0.17 cm.y1). Those evidences strongly support that the Southern Marginal Zone contains sediments deposited in an active margin during convergence, and that the metapelites were metamorphosed and partially melted as a consequence of continental collision along the northern margin of the Kaapvaal Craton at c. 2.7 Ga. The leucocratic features generated along this P-T-t path display an unusual chemistry with low K2O and FeO+MgO content and high CaO content. The combination of field observations, chemical mapping and geochemical analyses leads to the conclusion the major part of the leucosomes (L1) crystallized prior to syn-peak of metamorphism concurrent with melt extraction from the source. This study documents the details of leucosomes formation using field observations in the Southern Marginal Zone and numerical modelling. This work demonstrates that the formation of K2O-poor leucosome in the metasedimentary lower crust is controlled by the difference in volume of equilibration and heterogeneities within the migmatites. The partial melting of the source coupled with melt loss and water diffusivity within the melt transfer site is a potential mechanism to explain the chemical link in the sytem residuum– melt–S-type granite.
AFRIKAANSE OPSOMMING: Anateksis is die eerste stap in granietgenese. Meganismes wat in die onderste kors aan die werk is, is verantwoordelik vir korsdifferensiasie en bepaal die chemiese samestelling van die graniet. Hierdie studie het’n ondersoek behels van die anatektiese geskiedenis van ’n ho egraadse terrein: die suidelike randstreek van die Limpopo-gordel, noord van die Kaapvaal-kraton in Suid-Afrika. Die werk het ’n ge integreerde veld- , metamorfiese, geochemiese en geochronologiese studie van die metasedimentêre granuliete van twee afsonderlike groewe in die noordelike sone van die suidelike randstreek (SRS), die Bandelierkop-groef en die Brakspruit-groef, waar Neoarge iese ho egraadse gedeeltelike smeltkenmerke waargeneem kan word, ingesluit. Die projek was gerig op die ondersoek van twee belangrike kwessies: (1) om die drukâtemperatuurtoestande en die ouderdom van die metamorfiese episode in die SRS akkuraat te beheer, met implikasie vir die geodinamiese prosesse naby die einde van die Arge ikum, en (2) om die reaksies onder gedeeltelik gesmelte toestande wat die vorming van migmatiete beheer, te ondersoek en die chemiese verwantskappe in die stelsel bron - leukosoom - smelt - S-tipe graniet te begryp. Die P-T-t-rekord wat in die Bandelierkop-formasie metapeliete behoue is, ingeperk deur modellering van fase-ekwilibria asook sirkoon LA-ICP-MS-geochronologie, gee insig in korsdifferensiasieprosesse in die onderste kors. Rotse in albei groewe dui op metamorfismeepisodes teen hoë temperature met piektoestande van 840â860 oC en 9â11 kbar teen ongeveer 2.71 Ga met vorming van leukosome (L1) gedurende die progradeerpad. Geringe leukokratiese eienskappe (L2) het tydens dekompressie tot 6â7 kbar ontstaan. Die einde van die metamorfiese voorval word gekenmerk deur die fasiesoorgang van granuliete / amfiboliete (<640 oC) by ongeveer 2.68 Ga. Die maksimum afsettingsouderdom vir die detitrale sirkone in die metapeliete (ongeveer 2.73 Ga) dui op Å snelle begrawingsproses ( 0.17 cm.y1). Daardie bewyse bied sterk ondersteuning daarvoor dat die SRS sedimente bevat wat gedurende konvergensie in Å aktiewe rand afgeset is, en dat die metapeliete gemetamorfoseer en gedeeltelik gesmelt het as gevolg van kontinentbotsing langs die noordelike rand van die Kaapvaal-kraton teen ongeveer 2.7 Ga. Die leukokratiese eienskappe wat langs hierdie P-T-t-pad opgewek word, toon Å ongewone chemiese samestelling met lae K2O en FeO+MgO-inhoud en ho e CaO-inhoud. Die kombinasie van veldwaarnemings, chemiese kartering en geochemiese ontledings lei tot die gevolgtrekking dat die grootste deel van die leukosome (L1) gekristalliseer het voor die syn-piek van metamorfisme tesame met smeltekstraksie van die bron. Hierdie studie het die besonderhede van leukosoomformasie met behulp van veldwaarnemings in die SRS en numeriese modellering opgeteken. Hierdie werk toon aan dat korsdifferensiasie in die metasedimentêre onderste kors deur Å ander volume van ekwilibrasie en heterogeniteite in die migmatiete beheer word. Die gedeeltelike smelting van die bron gepaard met smeltverlies en waterdiffusiwiteit tot in die smeltoordragterrein is ’n potensiele meganisme om die chemiese skakel in die stelsel residuum-smelt-S-tipe graniet te verklaar.
Bullen, Warwick David. "Gold mineralization in an archaean granite-greenstone remnant west of Melmoth, Natal ore genesis and implications for exploration." Thesis, Rhodes University, 1991. http://hdl.handle.net/10962/d1005579.
Full textGreen, Michael Godfrey. "Early Archaean crustal evolution: evidence from ~3.5million year old greenstone successions in the Pilgangoora Belt, Pilbara Craton, Australia." Thesis, The University of Sydney, 2001. http://hdl.handle.net/2123/505.
Full textGreen, Michael Godfrey. "Early Archaean crustal evolution: evidence from ~3.5million year old greenstone successions in the Pilgangoora Belt, Pilbara Craton, Australia." University of Sydney. Geosciences, 2001. http://hdl.handle.net/2123/505.
Full textDelvigne, Camille. "The Archaean silicon cycle insights from silicon isotopes and Ge/Si ratios in banded iron formations, palaeosols and shales." Doctoral thesis, Universite Libre de Bruxelles, 2012. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/209652.
Full textFirst, this study focuses on Si inputs and outputs to ocean over a limited time period (~2.95 Ga Pongola Supergroup, South Africa) through the study of a palaeosol sequence and a contemporaneous banded iron formation. The palaeosol study offers precious clues in the comprehension of Archaean weathering processes and Si transfer from continent to ocean. Desilication and iron leaching were shown to be the major Archaean weathering processes. The occurrence of weathering residues issued of these processes as major component in fine-grained detrital sedimentary mass (shales) attests that identified weathering processes are widely developed and suggest an important dissolved Si flux from continent to the ocean. In parallel, banded iron formations (BIFs), typically characterised by alternation of iron-rich and silica-rich layers, represent an extraordinary record of the ocean-derived silica precipitation throughout the Precambrian. A detailed study of a 2.95 Ga BIF with excellent stratigraphic constraints identifies a seawater reservoir mixed with significant freshwater and very limited amount of high temperature hydrothermal fluids as the parental water mass from which BIFs precipitated. In addition, the export of silicon promoted by the silicon adsorption onto Fe-oxyhydroxides is evidenced. Then, both Si- and Fe-rich layers of BIFs have a common source water mass and a common siliceous ferric oxyhydroxides precursor. Thus, both palaeosols and BIFs highlight the significance of continental inputs to ocean, generally under- estimated or neglected, as well as the close link between Fe and Si cycles.
In a second time, this study explores secular changes in the Si cycle along the Precambrian. During this timespan, the world ocean underwent a progressive decrease in hydrothermal inputs and a long-term cooling. Effects of declining temperature over the oceanic Si cycle are highlighted by increasing δ30Si signatures of both chemically precipitated chert and BIF through time within the 3.8-2.5 Ga time interval. Interestingly, Si isotope compositions of BIF are shown to be kept systematically lighter of about 1.5‰ than contemporaneous cherts suggesting that both depositions occurred through different mechanisms. Along with the progressive increase of δ30Si signature, a decrease in Ge/Si ratios is attributed to a decrease in hydrothermal inputs along with the development of large and widespread desilication during continental weathering.
Le cycle externe du silicium au précambrien (4.5-0.5 Ga) reste mal compris malgré sa position clé dans la compréhension des processus opérant à la surface de la Terre primitive. En l’absence d’organismes sécrétant un squelette externe en silice, le cycle précambrien du silicium était vraisemblablement très différent de celui que nous connaissons à l’heure actuelle. Notre conception de l’océan archéen est limitée à l’hypothèse d’une concentration en silicium proche de la saturation en silice amorphe. Cette thèse vise à une meilleure compréhension des processus qui contrôlaient le cycle géochimique externe du silicium à l’archéen (3.8-2.5 Ga). Dans cette optique, le rapport germanium/silicium (Ge/Si) et les isotopes stables du silicium (δ30Si) représentent des traceurs idéaux pour démêler les différents processus contrôlant le cycle du Si.
Dans un premier temps, cette étude se focalise sur les apports et les exports de silicium à l’océan sur une période de temps restreinte (~2.95 Ga Pongola Supergroup, Afrique du Sud) via l’étude d’un paléosol et d’un dépôt sédimentaire de précipitation chimique quasi-contemporain. L’étude du paléosol apporte de précieux indices quant aux processus d’altération archéens et aux transferts de silicium des continents vers l’océan. Ainsi, la désilicification et le lessivage du fer apparaissent comme des processus majeurs de l’altération archéenne. La présence de résidus issus de ces processus d’altération en tant que composants majeurs de dépôts détritiques (shales) atteste de la globalité de ces processus et suggère des flux significatifs en silicium dissout des continents vers l’océan. En parallèle, les « banded iron formations » (BIFs), caractérisés par une alternance de niveaux riches en fer et en silice, représentent un enregistrement extraordinaire et caractéristique du précambrien de précipitation de silice à partir de l’océan. Une étude détaillée d’un dépôt de BIFs permet d’identifier une contribution importante des eaux douces dans la masse d’eau à partir de laquelle ces roches sont précipitées. Par ailleurs, un mécanisme d’export de silicium via absorption sur des oxyhydroxydes de fer est mis en évidence. Ainsi, les niveaux riches en fer et riche en silice constituant les BIFs auraient une même origine, un réservoir d’eau de mer mélangée avec des eaux douces et une contribution minime de fluides hydrothermaux de haute température, et un même précurseur commun. Dès lors, tant les paléosols que les BIFs mettent en évidence l’importance des apports continentaux à l’océan, souvent négligés ou sous estimés, ainsi que le lien étroit entre les cycles du fer et du silicium.
Dans un second temps, cette étude explore l’évolution du cycle du silicium au cours du précambrien. Durant cette période, l’océan voit les apports hydrothermaux ainsi que sa température diminuer. Dans l’intervalle de temps 3.8-2.5 Ga, les effets de tels changements sur le cycle du silicium sont marqués par un alourdissement progressif des signatures isotopiques des cherts et des BIFs. Le fort parallélisme entre l’évolution temporelle des compositions isotopiques des deux précipités met en évidence leur origine commune, l’océan. Cependant, les compositions isotopiques des BIFs sont systématiquement plus légères d’environ 1.5‰ que les signatures enregistrées pas les cherts. Cette différence est interprétée comme le reflet de mécanismes de dépôts différents. L’alourdissement progressif des compositions isotopiques concomitant à une diminution des rapports Ge/Si reflètent une diminution des apports hydrothermaux ainsi que la mise en place d’une désilicification de plus en plus importante et/ou généralisée lors de l’altération des continents.
Doctorat en Sciences
info:eu-repo/semantics/nonPublished
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