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Journal articles on the topic 'Aqueous rechargeable mixed ion batteries'

Author: Grafiati

Published: 6 September 2023

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1

Minami, Hironari, Hiroaki Izumi, Takumi Hasegawa, Fan Bai, Daisuke Mori, Sou Taminato, Yasuo Takeda, Osamu Yamamoto, and Nobuyuki Imanishi. "Aqueous Lithium--Air Batteries with High Power Density at Room Temperature under Air Atmosphere." Journal of Energy and Power Technology 03, no. 03 (June 30, 2021): 1. http://dx.doi.org/10.21926/jept.2103041.

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Rechargeable batteries with higher energy and power density exceeding the performance of the currently available lithium-ion batteries are suitable for application as the power source in electric vehicles (EVs). Aqueous lithium-air batteries are candidates for various EV applications due to their high energy density of 1910 Wh kg-1. The present study reports a rechargeable aqueous lithium-air battery with high power density at room temperature. The battery cell comprised a lithium anode, a non-aqueous anode electrolyte, a water-stable lithium-ion-conducting NASICON type separator, an aqueous catholyte, and an air electrode. The non-aqueous electrolyte served as an interlayer between the lithium anode and the solid electrolyte because the solid electrolyte in contact with lithium was unstable. The mixed separator comprised a Kimwipe paper and a Celgard polypropylene membrane for the interlayer electrolyte, which was used for preventing the formation of lithium dendrites at a high current density. The proposed aqueous lithium-air battery was successfully cycled at 2 mA cm-2 for 6 h at room temperature under an air atmosphere.

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2

Yan, Huihui, Cheng Yang, Liping Zhao, Jing Liu, Peng Zhang, and Lian Gao. "Proton-assisted mixed-valence vanadium oxides cathode with long-term stability for rechargeable aqueous zinc ion batteries." Electrochimica Acta 429 (October 2022): 141003. http://dx.doi.org/10.1016/j.electacta.2022.141003.

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3

Gao, Yaning, Haoyi Yang, Xinran Wang, Ying Bai, Na Zhu, Shuainan Guo, Liumin Suo, Hong Li, Huajie Xu, and Chuan Wu. "The Compensation Effect Mechanism of Fe–Ni Mixed Prussian Blue Analogues in Aqueous Rechargeable Aluminum‐Ion Batteries." ChemSusChem 13, no. 4 (January 27, 2020): 732–40. http://dx.doi.org/10.1002/cssc.201903067.

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4

Kim, Seokhun, Vaiyapuri Soundharrajan, Sungjin Kim, Balaji Sambandam, Vinod Mathew, Jang-Yeon Hwang, and Jaekook Kim. "Microwave-Assisted Rapid Synthesis of NH4V4O10 Layered Oxide: A High Energy Cathode for Aqueous Rechargeable Zinc Ion Batteries." Nanomaterials 11, no. 8 (July 24, 2021): 1905. http://dx.doi.org/10.3390/nano11081905.

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Aqueous rechargeable zinc ion batteries (ARZIBs) have gained wide interest in recent years as prospective high power and high energy devices to meet the ever-rising commercial needs for large-scale eco-friendly energy storage applications. The advancement in the development of electrodes, especially cathodes for ARZIB, is faced with hurdles related to the shortage of host materials that support divalent zinc storage. Even the existing materials, mostly based on transition metal compounds, have limitations of poor electrochemical stability, low specific capacity, and hence apparently low specific energies. Herein, NH4V4O10 (NHVO), a layered oxide electrode material with a uniquely mixed morphology of plate and belt-like particles is synthesized by a microwave method utilizing a short reaction time (~0.5 h) for use as a high energy cathode for ARZIB applications. The remarkable electrochemical reversibility of Zn2+/H+ intercalation in this layered electrode contributes to impressive specific capacity (417 mAh g−1 at 0.25 A g−1) and high rate performance (170 mAh g−1 at 6.4 A g−1) with almost 100% Coulombic efficiencies. Further, a very high specific energy of 306 Wh Kg−1 at a specific power of 72 W Kg−1 was achieved by the ARZIB using the present NHVO cathode. The present study thus facilitates the opportunity for developing high energy ARZIB electrodes even under short reaction time to explore potential materials for safe and sustainable green energy storage devices.

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5

Yoshida, Luna, Yuki Orikasa, and Masashi Ishikawa. "Mechanism of Improved Lithium-Sulfur Battery Performance by Oxidation Treatment to Microporous Carbon as Sulfur Matrix." ECS Meeting Abstracts MA2022-02, no. 64 (October 9, 2022): 2299. http://dx.doi.org/10.1149/ma2022-02642299mtgabs.

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1. Introduction Lithium-sulfur (Li-S) batteries are rechargeable devices assembled with a sulfur cathode and a lithium metal anode. Li-S batteries have twice the volumetric energy density and 5 times the gravimetric energy density of lithium-ion batteries (LIB). Hence, Li-S batteries are expected to be applied to stationary power sources and EV vehicles [1]. However, Li-S batteries have the following issues: ・Sulfur and the final discharge product (Li2S) are insulators. ・In the discharge process, sulfur expands up to 1.8 times, so the structure of batteries is unstable. ・Intermediate products (Li2Sx (x = 4 – 8)) dissolve in an electrolyte; Li2Sx (x = 4 – 8) diffused to an anode to provide an insulating layer at the anode surface. ・In the charge process, Li2Sx (x = 4 – 8) causes redox shuttling. As a result, Li-S batteries cannot charge and discharge stably. In order to deal with this problem, Nazar et al. reported the method that sulfur is confined in porous carbon [2]. This approach provides a cathode realizing good electronic conductivity, restriction of sulfur expansion, and suppression of Li2Sx (x = 4 – 8) dissolution. Although these improved characteristics allow Li-S batteries to operate, The discharge capacity of Li-S batteries is still not high enough and this needs to be addressed. In our previous study, we reported that oxidation treatment to microporous carbon (MC) with HNO3 improves Li-S batteries' discharge capacity [3]. Moreover, we clarified that the discharge capacity of Li-S batteries has an approximate proportional relation with the amount of oxygen-containing functional groups on the MC surface [4]. This work attempts to elucidate the mechanism of improved Li-S battery performance by oxidation treatment to MC. Our report would lead to the proposal of a novel strategy to improve the performance of Li-S batteries. 2. Method 2.1 Preparation of Oxidized MC-Sulfur composite (Ox MC-S) MC was added into 69 wt.% HNO3 and refluxed at 120ºC for 2 h. By vacuum filtration and washing with deionized water, Ox MC was obtained. Ox MC dried in vacuum at 80ºC overnight was mixed with sulfur at a weight ratio of Ox MC: S = 48: 52. The mixture was thermally annealed at 155ºC for 5 h (Ox MC-S). Untreated MC was also composited with sulfur by the same method (MC-S). 2.2 Assembling of Cells Each MC-S cathode was prepared by mixing the MC-S, acetylene black, carboxymethyl cellulose, and styrene butadiene rubber at a respective weight ratio of 89: 5: 3: 3 and coating the resulting aqueous slurry on an Al foil current collector. The cells with the MC-S electrode and Li metal foil as an anode were assembled in a glove box filled with Ar. Lithium bis(trifluorosulfonyl)imide (LiTFSI): tetraglyme (G4): hydrofluoroether (HFE) = 10: 8: 40 (by mol) was used as the electrolyte. 2.3 Electrochemical Impedance Spectroscopy (EIS) To elucidate the effect of oxidation treatment on the internal resistance of Li-S batteries, EIS was carried out at various potentials (Discharge 2.0 – 1.0 V and Charge 1.0 – 3.0 V). The obtained Nyquist plots were used for the evaluation of solid electrolyte interphase (SEI) resistance (Rsei), charge-transfer resistance (Rct), and Warburg impedance (Rw). Rw was investigated with the calculation of Warburg coefficient (σ). 3. Major results and conclusion Since oxidation treatment to MC significantly increased the discharge capacity of Li-S batteries [3][4], it was expected that oxidation treatment would lower the internal resistance of Li-S batteries. EIS of MC-S and Ox MC-S at various potentials showed that oxidation treatment reduced Rsei by an average of 12.2 Ω. This indicates that the SEI thickness was reduced, or the SEI was composed of highly ion-conductive components by the oxidation treatment. Rct decreased only at lower potentials, and the Warburg coefficient decreased except at the end of charge and discharge potential. These results suggest that the oxidation treatment decreases overall resistance, but especially SEI resistance and Warburg impedance, which may improve the discharge capacity of Li-S batteries. We will also report the activation energy of Rsei and Rct and mechanism analysis of decreasing Rsei by oxidation to MC. This work was supported by “Advanced Low Carbon Technology Research and Development Program, Specially Promoted Research for Innovative Next Generation Batteries (ALCA-SPRING [JPMJAL1301])” from JST. [1] Y. Guo et al., Angew. Chem. Int. Ed., 52 (2013) 13186. [2] X. Ji et al., Nat. Mater., 8 (2009) 500. [3] S. Okabe et al., Electrochemistry, 85 (2017) 671. [4] L. Yoshida et al., ECS 238th PRiME Meeting Abstracts (2020).

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6

Kim, Haegyeom, Jihyun Hong, Kyu-Young Park, Hyungsub Kim, Sung-Wook Kim, and Kisuk Kang. "Aqueous Rechargeable Li and Na Ion Batteries." Chemical Reviews 114, no. 23 (September 11, 2014): 11788–827. http://dx.doi.org/10.1021/cr500232y.

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7

Bin, Duan, Fei Wang, Andebet Gedamu Tamirat, Liumin Suo, Yonggang Wang, Chunsheng Wang, and Yongyao Xia. "Progress in Aqueous Rechargeable Sodium-Ion Batteries." Advanced Energy Materials 8, no. 17 (March 12, 2018): 1703008. http://dx.doi.org/10.1002/aenm.201703008.

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8

Liu, Zhuoxin, Yan Huang, Yang Huang, Qi Yang, Xinliang Li, Zhaodong Huang, and Chunyi Zhi. "Voltage issue of aqueous rechargeable metal-ion batteries." Chemical Society Reviews 49, no. 1 (2020): 180–232. http://dx.doi.org/10.1039/c9cs00131j.

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9

Tang, Boya, Lutong Shan, Shuquan Liang, and Jiang Zhou. "Issues and opportunities facing aqueous zinc-ion batteries." Energy & Environmental Science 12, no. 11 (2019): 3288–304. http://dx.doi.org/10.1039/c9ee02526j.

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We retrospect recent advances in rechargeable aqueous zinc-ion batteries system and the facing challenges of aqueous zinc-ion batteries. Importantly, some concerns and feasible solutions for achieving practical aqueous zinc-ion batteries are discussed in detail.

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10

Verma, Vivek, Sonal Kumar, William Manalastas, and Madhavi Srinivasan. "Undesired Reactions in Aqueous Rechargeable Zinc Ion Batteries." ACS Energy Letters 6, no. 5 (April 13, 2021): 1773–85. http://dx.doi.org/10.1021/acsenergylett.1c00393.

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11

Wainwright, David, and Jeffery Dahn. "Safer Rechargeable Lithium Ion Batteries Use Aqueous ElectroIyte." Materials Technology 11, no. 1 (January 1996): 9–12. http://dx.doi.org/10.1080/10667857.1996.11752650.

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12

Qin, H., Z. P. Song, H. Zhan, and Y. H. Zhou. "Aqueous rechargeable alkali-ion batteries with polyimide anode." Journal of Power Sources 249 (March 2014): 367–72. http://dx.doi.org/10.1016/j.jpowsour.2013.10.091.

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13

Liu, M., H. Ao, Y. Jin, Z. Hou, X. Zhang, Y. Zhu, and Y. Qian. "Aqueous rechargeable sodium ion batteries: developments and prospects." Materials Today Energy 17 (September 2020): 100432. http://dx.doi.org/10.1016/j.mtener.2020.100432.

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14

Ao, Huaisheng, Yingyue Zhao, Jie Zhou, Wenlong Cai, Xiaotan Zhang, Yongchun Zhu, and Yitai Qian. "Rechargeable aqueous hybrid ion batteries: developments and prospects." Journal of Materials Chemistry A 7, no. 32 (2019): 18708–34. http://dx.doi.org/10.1039/c9ta06433h.

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15

Sharma, Lalit, and Arumugam Manthiram. "Polyanionic insertion hosts for aqueous rechargeable batteries." Journal of Materials Chemistry A 10, no. 12 (2022): 6376–96. http://dx.doi.org/10.1039/d1ta11080b.

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16

Demir-Cakan, Rezan, Mathieu Morcrette, Jean-Bernard Leriche, and Jean-Marie Tarascon. "An aqueous electrolyte rechargeable Li-ion/polysulfide battery." J. Mater. Chem. A 2, no. 24 (2014): 9025–29. http://dx.doi.org/10.1039/c4ta01308e.

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In spite of great research efforts on Li–S batteries in aprotic organic electrolytes, there have been very few studies showing the potential application of this system in aqueous electrolyte. Herein, we explore this option and report on a cheaper and safer new aqueous system coupling a well-known cathode material in Li-ion batteries (i.e. LiMn₂O₄) with a dissolved polysulfide anode.

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17

Miyazaki, Kohei, Toshiki Shimada, Satomi Ito, Yuko Yokoyama, Tomokazu Fukutsuka, and Takeshi Abe. "Enhanced resistance to oxidative decomposition of aqueous electrolytes for aqueous lithium-ion batteries." Chemical Communications 52, no. 28 (2016): 4979–82. http://dx.doi.org/10.1039/c6cc00873a.

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18

Liu, Zhuoxin, Yan Huang, Yang Huang, Qi Yang, Xinliang Li, Zhaodong Huang, and Chunyi Zhi. "Correction: Voltage issue of aqueous rechargeable metal-ion batteries." Chemical Society Reviews 49, no. 2 (2020): 643–44. http://dx.doi.org/10.1039/c9cs90105a.

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19

Park, Sodam, Imanuel Kristanto, Gwan Yeong Jung, David B. Ahn, Kihun Jeong, Sang Kyu Kwak, and Sang-Young Lee. "A single-ion conducting covalent organic framework for aqueous rechargeable Zn-ion batteries." Chemical Science 11, no. 43 (2020): 11692–98. http://dx.doi.org/10.1039/d0sc02785e.

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20

Gao, Yaning, Haoyi Yang, Ying Bai, and Chuan Wu. "Mn-based oxides for aqueous rechargeable metal ion batteries." Journal of Materials Chemistry A 9, no. 19 (2021): 11472–500. http://dx.doi.org/10.1039/d1ta01951a.

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21

Yue, Jinming, and Liumin Suo. "Progress in Rechargeable Aqueous Alkali-Ion Batteries in China." Energy & Fuels 35, no. 11 (May 24, 2021): 9228–39. http://dx.doi.org/10.1021/acs.energyfuels.1c00817.

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22

Yang, Mingrui, Jun Luo, Xiaoniu Guo, Jiacheng Chen, Yuliang Cao, and Weihua Chen. "Aqueous Rechargeable Sodium-Ion Batteries: From Liquid to Hydrogel." Batteries 8, no. 10 (October 12, 2022): 180. http://dx.doi.org/10.3390/batteries8100180.

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Sodium-ion batteries stand out as a promising technology for developing a new generation of energy storage devices because of their apparent advantages in terms of costs and resources. Aqueous electrolytes, which are flame-resistant, inexpensive, and environmentally acceptable, are receiving a lot of attention in light of the present environmental and electronic equipment safety concerns. In recent decades, numerous improvements have been made to the performance of aqueous sodium-ion batteries (ASIBs). One particular development has been the transition from liquid to hydrogel electrolytes, whose durability, flexibility, and leakproof properties are eagerly anticipated in the next generation of flexible wearable electronics. The current review examines the most recent developments in the investigation and development of the electrolytes and associated electrode materials of ASIBs. An overview of new discoveries based on cycle stability, electrochemical performance, and morphology is presented along with previously published data. Additionally, the main milestones, applications, and challenges of this field are briefly discussed.

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23

Pan, Zhenghui, Ximeng Liu, Jie Yang, Xin Li, Zhaolin Liu, Xian Jun Loh, and John Wang. "Aqueous Rechargeable Multivalent Metal‐Ion Batteries: Advances and Challenges." Advanced Energy Materials 11, no. 24 (May 12, 2021): 2100608. http://dx.doi.org/10.1002/aenm.202100608.

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24

Jeong, Seonghun, Byung Hoon Kim, Yeong Don Park, Chang Yeon Lee, Junyoung Mun, and Artur Tron. "Artificially coated NaFePO4 for aqueous rechargeable sodium-ion batteries." Journal of Alloys and Compounds 784 (May 2019): 720–26. http://dx.doi.org/10.1016/j.jallcom.2019.01.046.

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25

Fenta, Fekadu Wubatu, Bizualem Wakuma Olbasa, Meng-Che Tsai, Misganaw Adigo Weret, Tilahun Awoke Zegeye, Chen-Jui Huang, Wei-Hsiang Huang, et al. "Electrochemical transformation reaction of Cu–MnO in aqueous rechargeable zinc-ion batteries for high performance and long cycle life." Journal of Materials Chemistry A 8, no. 34 (2020): 17595–607. http://dx.doi.org/10.1039/d0ta04175k.

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26

Gong, Jiangfeng, Hao Li, Kaixiao Zhang, Zhupeng Zhang, Jie Cao, Zhibin Shao, Chunmei Tang, Shaojie Fu, Qianjin Wang, and Xiang Wu. "Zinc-Ion Storage Mechanism of Polyaniline for Rechargeable Aqueous Zinc-Ion Batteries." Nanomaterials 12, no. 9 (April 23, 2022): 1438. http://dx.doi.org/10.3390/nano12091438.

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Aqueous multivalent ion batteries, especially aqueous zinc-ion batteries (ZIBs), have promising energy storage application due to their unique merits of safety, high ionic conductivity, and high gravimetric energy density. To improve their electrochemical performance, polyaniline (PANI) is often chosen to suppress cathode dissolution. Herein, this work focuses on the zinc ion storage behavior of a PANI cathode. The energy storage mechanism of PANI is associated with four types of protonated/non-protonated amine or imine. The PANI cathode achieves a high capacity of 74 mAh g−1 at 0.3 A g−1 and maintains 48.4% of its initial discharge capacity after 1000 cycles. It also demonstrates an ultrahigh diffusion coefficient of 6.25 × 10−9~7.82 × 10−8 cm−2 s−1 during discharging and 7.69 × 10−10~1.81 × 10−7 cm−2 s−1 during charging processes, which is one or two orders of magnitude higher than other reported studies. This work sheds a light on developing PANI-composited cathodes in rechargeable aqueous ZIBs energy storage devices.

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27

Chaithra Munivenkatappa, Vijeth Rajshekar Shetty, and Suresh Gurukar Shivappa. "Chalcone as Anode Material for Aqueous Rechargeable Lithium-Ion Batteries." Russian Journal of Electrochemistry 57, no. 4 (April 2021): 419–33. http://dx.doi.org/10.1134/s1023193520120162.

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28

Kumankuma-Sarpong, James, Shuai Tang, Wei Guo, and Yongzhu Fu. "Naphthoquinone-Based Composite Cathodes for Aqueous Rechargeable Zinc-Ion Batteries." ACS Applied Materials & Interfaces 13, no. 3 (January 17, 2021): 4084–92. http://dx.doi.org/10.1021/acsami.0c21339.

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29

Wu, Buke, Wen Luo, Ming Li, Lin Zeng, and Liqiang Mai. "Achieving better aqueous rechargeable zinc ion batteries with heterostructure electrodes." Nano Research 14, no. 9 (April 7, 2021): 3174–87. http://dx.doi.org/10.1007/s12274-021-3392-1.

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30

Puttaswamy, Rangaswamy, Suresh Gurukar Shivappa, Mahadevan Kittappa Malavalli, and Yanjerappa Arthoba Nayaka. "Triclinic LiVPO4F/C Cathode For Aqueous Rechargeable Lithium-Ion Batteries." Advanced Materials Letters 10, no. 3 (December 31, 2018): 193–200. http://dx.doi.org/10.5185/amlett.2019.2141.

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31

Ru, Yue, Shasha Zheng, Huaiguo Xue, and Huan Pang. "Layered V-MOF nanorods for rechargeable aqueous zinc-ion batteries." Materials Today Chemistry 21 (August 2021): 100513. http://dx.doi.org/10.1016/j.mtchem.2021.100513.

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32

Choi, Dongkyu, Seonguk Lim, and Dongwook Han. "Advanced metal–organic frameworks for aqueous sodium-ion rechargeable batteries." Journal of Energy Chemistry 53 (February 2021): 396–406. http://dx.doi.org/10.1016/j.jechem.2020.07.024.

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33

Liu, Shude, Ling Kang, Jong Min Kim, Young Tea Chun, Jian Zhang, and Seong Chan Jun. "Recent Advances in Vanadium‐Based Aqueous Rechargeable Zinc‐Ion Batteries." Advanced Energy Materials 10, no. 25 (May 15, 2020): 2000477. http://dx.doi.org/10.1002/aenm.202000477.

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34

Li, Siqi, Yanan Wei, Qiong Wu, Yuan Han, Guixiang Qain, Jiaming Liu, and Chao Yang. "Spherical PDA@MnO2 cathode for rechargeable aqueous zinc ion batteries." Materials Letters 348 (October 2023): 134671. http://dx.doi.org/10.1016/j.matlet.2023.134671.

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35

Demir-Cakan, Rezan, M. Rosa Palacin, and Laurence Croguennec. "Rechargeable aqueous electrolyte batteries: from univalent to multivalent cation chemistry." Journal of Materials Chemistry A 7, no. 36 (2019): 20519–39. http://dx.doi.org/10.1039/c9ta04735b.

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36

González, J. R., F. Nacimiento, M. Cabello, R. Alcántara, P. Lavela, and J. L. Tirado. "Reversible intercalation of aluminium into vanadium pentoxide xerogel for aqueous rechargeable batteries." RSC Advances 6, no. 67 (2016): 62157–64. http://dx.doi.org/10.1039/c6ra11030d.

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37

Sakamoto, Ryo, Maho Yamashita, Kosuke Nakamoto, Yongquan Zhou, Nobuko Yoshimoto, Kenta Fujii, Toshio Yamaguchi, Ayuko Kitajou, and Shigeto Okada. "Local structure of a highly concentrated NaClO4 aqueous solution-type electrolyte for sodium ion batteries." Physical Chemistry Chemical Physics 22, no. 45 (2020): 26452–58. http://dx.doi.org/10.1039/d0cp04376a.

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38

Xu, L., Y. Zhang, J. Zheng, H. Jiang, T. Hu, and C. Meng. "Ammonium ion intercalated hydrated vanadium pentoxide for advanced aqueous rechargeable Zn-ion batteries." Materials Today Energy 18 (December 2020): 100509. http://dx.doi.org/10.1016/j.mtener.2020.100509.

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39

Chomkhuntod, Praeploy, Kanit Hantanasirisakul, Salatan Duangdangchote, Nutthaphon Phattharasupakun, and Montree Sawangphruk. "The charge density of intercalants inside layered birnessite manganese oxide nanosheets determining Zn-ion storage capability towards rechargeable Zn-ion batteries." Journal of Materials Chemistry A 10, no. 10 (2022): 5561–68. http://dx.doi.org/10.1039/d1ta09968j.

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Rechargeable aqueous Zn–MnO2 batteries have been considered as one of the promising alternative energy technologies due to their high abundance, environmental friendliness, and safety of both Zn–metal anodes and manganese oxide cathodes.

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40

Luo, Zhiqiang, Silin Zheng, Shuo Zhao, Xin Jiao, Zongshuai Gong, Fengshi Cai, Yueqin Duan, Fujun Li, and Zhihao Yuan. "High energy density aqueous zinc–benzoquinone batteries enabled by carbon cloth with multiple anchoring effects." Journal of Materials Chemistry A 9, no. 10 (2021): 6131–38. http://dx.doi.org/10.1039/d0ta12127d.

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Benzoquinone with high theoretical capacity is anchored on N-plasma engraved porous carbon as a desirable cathode for rechargeable aqueous Zn-ion batteries. Such batteries display tremendous potential in large-scale energy storage applications.

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41

You, Gongchuan, and Liang He. "High Performance Electrolyte for Iron-Ion batteries." Academic Journal of Science and Technology 5, no. 2 (April 2, 2023): 244–47. http://dx.doi.org/10.54097/ajst.v5i2.6995.

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Aqueous rechargeable batteries have received widespread attention due to their excellent power density, simple manufacturing process, and inexpensive electrolyte. Iron-ion batteries are expected to meet the goals of high safety, low cost, and non-toxicity pursued in the field of rechargeable batteries. However, passivation, parasitic hydrogen evolution reaction (HER), and low electroplating efficiency (50%-70%) limit the improvement of electrochemical performance, which greatly restricts their practical application. In this study, a high-performance electrolyte for iron-ion batteries was prepared, and the effect of zinc chloride (ZnCl2) additives on inhibiting HER and the improvement of coulomb efficiency in ferrous chloride (FeCl2) electrolyte was explored. Additionally, the effect of the addition of complexing agents in the electrolyte on the coulomb efficiency of the electrodes was studied. It’s demonstrated that the electrode can still obtain a coulomb efficiency of nearly 100% after 20 hours cycling in the electrolyte containing ZnCl2 additive and FeCl2, while in FeCl2 electrolyte, its coulomb efficiency after 20 hours of cycling is only 65%.

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42

Duan, Wenyuan, Mubashir Husain, Yanlin Li, Najeeb ur Rehman Lashari, Yuhuan Yang, Cheng Ma, Yuzhen Zhao, and Xiaorui Li. "Enhanced charge transport properties of an LFP/C/graphite composite as a cathode material for aqueous rechargeable lithium batteries." RSC Advances 13, no. 36 (2023): 25327–33. http://dx.doi.org/10.1039/d3ra04143c.

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43

Liu, Yiyang, Guanjie He, Hao Jiang, Ivan P. Parkin, Paul R. Shearing, and Dan J. L. Brett. "Cathode Design for Aqueous Rechargeable Multivalent Ion Batteries: Challenges and Opportunities." Advanced Functional Materials 31, no. 13 (January 20, 2021): 2010445. http://dx.doi.org/10.1002/adfm.202010445.

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44

Tang, Mengyao, Qiaonan Zhu, Pengfei Hu, Li Jiang, Rongyang Liu, Jiawei Wang, Liwei Cheng, Xiuhui Zhang, Wenxing Chen, and Hua Wang. "Ultrafast Rechargeable Aqueous Zinc‐Ion Batteries Based on Stable Radical Chemistry." Advanced Functional Materials 31, no. 33 (June 13, 2021): 2102011. http://dx.doi.org/10.1002/adfm.202102011.

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45

Kumar, Santosh, Hocheol Yoon, Hyeonghun Park, Geumyong Park, Seokho Suh, and Hyeong-Jin Kim. "A dendrite-free anode for stable aqueous rechargeable zinc-ion batteries." Journal of Industrial and Engineering Chemistry 108 (April 2022): 321–27. http://dx.doi.org/10.1016/j.jiec.2022.01.011.

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46

Wang, L., and J. Zheng. "Recent advances in cathode materials of rechargeable aqueous zinc-ion batteries." Materials Today Advances 7 (September 2020): 100078. http://dx.doi.org/10.1016/j.mtadv.2020.100078.

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47

Liu, Tingting, Xing Cheng, Haoxiang Yu, Haojie Zhu, Na Peng, Runtian Zheng, Jundong Zhang, Miao Shui, Yanhua Cui, and Jie Shu. "An overview and future perspectives of aqueous rechargeable polyvalent ion batteries." Energy Storage Materials 18 (March 2019): 68–91. http://dx.doi.org/10.1016/j.ensm.2018.09.027.

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48

Sada, Krishnakanth, Baskar Senthilkumar, and Prabeer Barpanda. "Cryptomelane K1.33Mn8O16 as a cathode for rechargeable aqueous zinc-ion batteries." Journal of Materials Chemistry A 7, no. 41 (2019): 23981–88. http://dx.doi.org/10.1039/c9ta05836b.

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Abstract:

Reversible intercalation of Zn ions in tetragonal K_1.33Mn₈O₁₆ delivers 312 mA h g⁻¹ capacity at a galvanostatic cycling rate of 0.1C with an average voltage of 1.5 V.

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Wu, Yutong, Yamin Zhang, Yao Ma, Joshua D. Howe, Haochen Yang, Peng Chen, Sireesha Aluri, and Nian Liu. "Ion-Sieving Carbon Nanoshells for Deeply Rechargeable Zn-Based Aqueous Batteries." Advanced Energy Materials 8, no. 36 (October 30, 2018): 1802470. http://dx.doi.org/10.1002/aenm.201802470.

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50

Cao, Ziyi, Peiyuan Zhuang, Xiang Zhang, Mingxin Ye, Jianfeng Shen, and Pulickel M. Ajayan. "Strategies for Dendrite‐Free Anode in Aqueous Rechargeable Zinc Ion Batteries." Advanced Energy Materials 10, no. 30 (June 30, 2020): 2001599. http://dx.doi.org/10.1002/aenm.202001599.

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