Academic literature on the topic 'Aqueous rechargeable mixed ion batteries'

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Journal articles on the topic "Aqueous rechargeable mixed ion batteries"

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Minami, Hironari, Hiroaki Izumi, Takumi Hasegawa, Fan Bai, Daisuke Mori, Sou Taminato, Yasuo Takeda, Osamu Yamamoto, and Nobuyuki Imanishi. "Aqueous Lithium--Air Batteries with High Power Density at Room Temperature under Air Atmosphere." Journal of Energy and Power Technology 03, no. 03 (June 30, 2021): 1. http://dx.doi.org/10.21926/jept.2103041.

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Rechargeable batteries with higher energy and power density exceeding the performance of the currently available lithium-ion batteries are suitable for application as the power source in electric vehicles (EVs). Aqueous lithium-air batteries are candidates for various EV applications due to their high energy density of 1910 Wh kg-1. The present study reports a rechargeable aqueous lithium-air battery with high power density at room temperature. The battery cell comprised a lithium anode, a non-aqueous anode electrolyte, a water-stable lithium-ion-conducting NASICON type separator, an aqueous catholyte, and an air electrode. The non-aqueous electrolyte served as an interlayer between the lithium anode and the solid electrolyte because the solid electrolyte in contact with lithium was unstable. The mixed separator comprised a Kimwipe paper and a Celgard polypropylene membrane for the interlayer electrolyte, which was used for preventing the formation of lithium dendrites at a high current density. The proposed aqueous lithium-air battery was successfully cycled at 2 mA cm-2 for 6 h at room temperature under an air atmosphere.
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Yan, Huihui, Cheng Yang, Liping Zhao, Jing Liu, Peng Zhang, and Lian Gao. "Proton-assisted mixed-valence vanadium oxides cathode with long-term stability for rechargeable aqueous zinc ion batteries." Electrochimica Acta 429 (October 2022): 141003. http://dx.doi.org/10.1016/j.electacta.2022.141003.

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Gao, Yaning, Haoyi Yang, Xinran Wang, Ying Bai, Na Zhu, Shuainan Guo, Liumin Suo, Hong Li, Huajie Xu, and Chuan Wu. "The Compensation Effect Mechanism of Fe–Ni Mixed Prussian Blue Analogues in Aqueous Rechargeable Aluminum‐Ion Batteries." ChemSusChem 13, no. 4 (January 27, 2020): 732–40. http://dx.doi.org/10.1002/cssc.201903067.

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Kim, Seokhun, Vaiyapuri Soundharrajan, Sungjin Kim, Balaji Sambandam, Vinod Mathew, Jang-Yeon Hwang, and Jaekook Kim. "Microwave-Assisted Rapid Synthesis of NH4V4O10 Layered Oxide: A High Energy Cathode for Aqueous Rechargeable Zinc Ion Batteries." Nanomaterials 11, no. 8 (July 24, 2021): 1905. http://dx.doi.org/10.3390/nano11081905.

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Aqueous rechargeable zinc ion batteries (ARZIBs) have gained wide interest in recent years as prospective high power and high energy devices to meet the ever-rising commercial needs for large-scale eco-friendly energy storage applications. The advancement in the development of electrodes, especially cathodes for ARZIB, is faced with hurdles related to the shortage of host materials that support divalent zinc storage. Even the existing materials, mostly based on transition metal compounds, have limitations of poor electrochemical stability, low specific capacity, and hence apparently low specific energies. Herein, NH4V4O10 (NHVO), a layered oxide electrode material with a uniquely mixed morphology of plate and belt-like particles is synthesized by a microwave method utilizing a short reaction time (~0.5 h) for use as a high energy cathode for ARZIB applications. The remarkable electrochemical reversibility of Zn2+/H+ intercalation in this layered electrode contributes to impressive specific capacity (417 mAh g−1 at 0.25 A g−1) and high rate performance (170 mAh g−1 at 6.4 A g−1) with almost 100% Coulombic efficiencies. Further, a very high specific energy of 306 Wh Kg−1 at a specific power of 72 W Kg−1 was achieved by the ARZIB using the present NHVO cathode. The present study thus facilitates the opportunity for developing high energy ARZIB electrodes even under short reaction time to explore potential materials for safe and sustainable green energy storage devices.
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Yoshida, Luna, Yuki Orikasa, and Masashi Ishikawa. "Mechanism of Improved Lithium-Sulfur Battery Performance by Oxidation Treatment to Microporous Carbon as Sulfur Matrix." ECS Meeting Abstracts MA2022-02, no. 64 (October 9, 2022): 2299. http://dx.doi.org/10.1149/ma2022-02642299mtgabs.

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1. Introduction Lithium-sulfur (Li-S) batteries are rechargeable devices assembled with a sulfur cathode and a lithium metal anode. Li-S batteries have twice the volumetric energy density and 5 times the gravimetric energy density of lithium-ion batteries (LIB). Hence, Li-S batteries are expected to be applied to stationary power sources and EV vehicles [1]. However, Li-S batteries have the following issues: ・Sulfur and the final discharge product (Li2S) are insulators. ・In the discharge process, sulfur expands up to 1.8 times, so the structure of batteries is unstable. ・Intermediate products (Li2Sx (x = 4 – 8)) dissolve in an electrolyte; Li2Sx (x = 4 – 8) diffused to an anode to provide an insulating layer at the anode surface. ・In the charge process, Li2Sx (x = 4 – 8) causes redox shuttling. As a result, Li-S batteries cannot charge and discharge stably. In order to deal with this problem, Nazar et al. reported the method that sulfur is confined in porous carbon [2]. This approach provides a cathode realizing good electronic conductivity, restriction of sulfur expansion, and suppression of Li2Sx (x = 4 – 8) dissolution. Although these improved characteristics allow Li-S batteries to operate, The discharge capacity of Li-S batteries is still not high enough and this needs to be addressed. In our previous study, we reported that oxidation treatment to microporous carbon (MC) with HNO3 improves Li-S batteries' discharge capacity [3]. Moreover, we clarified that the discharge capacity of Li-S batteries has an approximate proportional relation with the amount of oxygen-containing functional groups on the MC surface [4]. This work attempts to elucidate the mechanism of improved Li-S battery performance by oxidation treatment to MC. Our report would lead to the proposal of a novel strategy to improve the performance of Li-S batteries. 2. Method 2.1 Preparation of Oxidized MC-Sulfur composite (Ox MC-S) MC was added into 69 wt.% HNO3 and refluxed at 120ºC for 2 h. By vacuum filtration and washing with deionized water, Ox MC was obtained. Ox MC dried in vacuum at 80ºC overnight was mixed with sulfur at a weight ratio of Ox MC: S = 48: 52. The mixture was thermally annealed at 155ºC for 5 h (Ox MC-S). Untreated MC was also composited with sulfur by the same method (MC-S). 2.2 Assembling of Cells Each MC-S cathode was prepared by mixing the MC-S, acetylene black, carboxymethyl cellulose, and styrene butadiene rubber at a respective weight ratio of 89: 5: 3: 3 and coating the resulting aqueous slurry on an Al foil current collector. The cells with the MC-S electrode and Li metal foil as an anode were assembled in a glove box filled with Ar. Lithium bis(trifluorosulfonyl)imide (LiTFSI): tetraglyme (G4): hydrofluoroether (HFE) = 10: 8: 40 (by mol) was used as the electrolyte. 2.3 Electrochemical Impedance Spectroscopy (EIS) To elucidate the effect of oxidation treatment on the internal resistance of Li-S batteries, EIS was carried out at various potentials (Discharge 2.0 – 1.0 V and Charge 1.0 – 3.0 V). The obtained Nyquist plots were used for the evaluation of solid electrolyte interphase (SEI) resistance (Rsei), charge-transfer resistance (Rct), and Warburg impedance (Rw). Rw was investigated with the calculation of Warburg coefficient (σ). 3. Major results and conclusion Since oxidation treatment to MC significantly increased the discharge capacity of Li-S batteries [3][4], it was expected that oxidation treatment would lower the internal resistance of Li-S batteries. EIS of MC-S and Ox MC-S at various potentials showed that oxidation treatment reduced Rsei by an average of 12.2 Ω. This indicates that the SEI thickness was reduced, or the SEI was composed of highly ion-conductive components by the oxidation treatment. Rct decreased only at lower potentials, and the Warburg coefficient decreased except at the end of charge and discharge potential. These results suggest that the oxidation treatment decreases overall resistance, but especially SEI resistance and Warburg impedance, which may improve the discharge capacity of Li-S batteries. We will also report the activation energy of Rsei and Rct and mechanism analysis of decreasing Rsei by oxidation to MC. This work was supported by “Advanced Low Carbon Technology Research and Development Program, Specially Promoted Research for Innovative Next Generation Batteries (ALCA-SPRING [JPMJAL1301])” from JST. [1] Y. Guo et al., Angew. Chem. Int. Ed., 52 (2013) 13186. [2] X. Ji et al., Nat. Mater., 8 (2009) 500. [3] S. Okabe et al., Electrochemistry, 85 (2017) 671. [4] L. Yoshida et al., ECS 238th PRiME Meeting Abstracts (2020).
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Kim, Haegyeom, Jihyun Hong, Kyu-Young Park, Hyungsub Kim, Sung-Wook Kim, and Kisuk Kang. "Aqueous Rechargeable Li and Na Ion Batteries." Chemical Reviews 114, no. 23 (September 11, 2014): 11788–827. http://dx.doi.org/10.1021/cr500232y.

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Bin, Duan, Fei Wang, Andebet Gedamu Tamirat, Liumin Suo, Yonggang Wang, Chunsheng Wang, and Yongyao Xia. "Progress in Aqueous Rechargeable Sodium-Ion Batteries." Advanced Energy Materials 8, no. 17 (March 12, 2018): 1703008. http://dx.doi.org/10.1002/aenm.201703008.

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Liu, Zhuoxin, Yan Huang, Yang Huang, Qi Yang, Xinliang Li, Zhaodong Huang, and Chunyi Zhi. "Voltage issue of aqueous rechargeable metal-ion batteries." Chemical Society Reviews 49, no. 1 (2020): 180–232. http://dx.doi.org/10.1039/c9cs00131j.

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Tang, Boya, Lutong Shan, Shuquan Liang, and Jiang Zhou. "Issues and opportunities facing aqueous zinc-ion batteries." Energy & Environmental Science 12, no. 11 (2019): 3288–304. http://dx.doi.org/10.1039/c9ee02526j.

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We retrospect recent advances in rechargeable aqueous zinc-ion batteries system and the facing challenges of aqueous zinc-ion batteries. Importantly, some concerns and feasible solutions for achieving practical aqueous zinc-ion batteries are discussed in detail.
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Verma, Vivek, Sonal Kumar, William Manalastas, and Madhavi Srinivasan. "Undesired Reactions in Aqueous Rechargeable Zinc Ion Batteries." ACS Energy Letters 6, no. 5 (April 13, 2021): 1773–85. http://dx.doi.org/10.1021/acsenergylett.1c00393.

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Dissertations / Theses on the topic "Aqueous rechargeable mixed ion batteries"

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Yokoyama, Yuko. "Studies on Electrolytes for High-Voltage Aqueous Rechargeable Lithium-ion Batteries." Kyoto University, 2019. http://hdl.handle.net/2433/242525.

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Joseph, Jickson. "Investigation of organic-inorganic nano hybrid materials for aluminum ion batteries." Thesis, Queensland University of Technology, 2020. https://eprints.qut.edu.au/198086/1/Jickson_Joseph_Thesis.pdf.

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The objective of this project was to develop efficient electrode materials for use in an aqueous aluminum-ion battery. This study of electrodes mainly focuses on the development of earth-abundant materials fabricated by a simple hydrothermal process. This project describes the development of highly stable and efficient battery electrodes from different metal oxides from manganese and molybdenum. A cation exchange mechanism is proposed and validated in this thesis where the cations trapped in the electrodes and exchanged during aluminum-ion intercalation and extraction. In short, this thesis focuses on the development of a sustainable aqueous aluminum ion battery.
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Venkatesha, Akshatha. "Structural and Electrochemical Investigations of Monovalent and Divalent Aqueous Rechargeable Batteries." Thesis, 2023. https://etd.iisc.ac.in/handle/2005/6205.

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Several stringent laws and regulations have been enforced by various National/International agencies for the adoption of sustainable methods for energy production and usage. In recent times, electric grids based on alternative renewable sources such as solar, tidal, geothermal, and biomass have witnessed an upsurge. However, the intermittent nature of renewable resources and the sub-optimal electricity distribution/transmission calls for corrective measures leading to enhancement in the efficiency of electricity utilization. It is now widely recognized that energy storage via rechargeable batteries can be an efficient strategy in making the process(es) of electricity production and utilization from the grid to the end-user. Lithium-ion batteries are considered one of the most promising candidates with their outreach in various sectors, such as portable electronics, electric mobility, and grid storage applications. While advanced LiBs may offer good power and energy density, these are unlikely to meet the stiff scale-up targets concerning performance, cost, and safety in large-scale applications such as electric vehicles and the grid. Lithium reserves are limited and distributed heterogeneously. Additionally, conventional Li-ion uses expensive and flammable organic liquid electrolytes Aqueous rechargeable batteries (both monovalent and multivalent) are considered safer alternatives to state-of-the-art LIB technology and other non-aqueous battery chemistries owing to several advantages based on higher safety, cost-effectiveness, and higher ionic conductivity. As water is the solvent, aqueous rechargeable batteries do not require a sophisticated cell assembly line. One of the significant challenges that hinder their wide-scale application is the choice of suitable electrode materials that can work in the aqueous environment. In this thesis, various electrode materials with optimized electrolyte compositions for both aqueous monovalent and multivalent metal-ion rechargeable batteries have been explored. Chapter 3 explores the aqueous rechargeable mixed ion batteries we have developed using a NASICON anode and an olivine cathode in mixed ion electrolytes. The interesting phenomenon of selective ion insertion by the host structure in the presence of more than one cation in the electrolyte is probed in detail. In Chapters 4 to 7, we have explored various host materials (redox-active 2-D covalent organic frameworks, transition metal oxides, Prussian blue analogs) for the aqueous rechargeable divalent metal ion batteries (Zn, Ca, and Mg). The electrochemical characterizations of the materials are performed in detail to account for their redox behavior. The effect of electrolyte composition on the electrochemical performance of the cell is studied in detail. The thesis also probes the underlying mechanism of the battery operation associated with the structural/phase evolution of the electrode structure (with successive cycling) in detail with the help of various post-cycling ex-situ measurements.
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Konarov, Aishuak. "Self-discharge of Rechargeable Hybrid Aqueous Battery." Thesis, 2014. http://hdl.handle.net/10012/8437.

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This thesis studies the self-discharge performance of recently developed rechargeable hybrid aqueous batteries, using LiMn2O4 as a cathode and Zinc as an anode. It is shown through a variety of electrochemical and ex-situ analytical techniques that many parts of the composite cathode play important roles on the self-discharge of the battery. It was determined that the current collector must be passive towards corrosion, and polyethylene was identified as the best option for this application. The effect of amount and type of conductive agent was also investigated, with low surface area carbonaceous material giving best performances. It was also shown that the state of charge has strong effects on the extension of self-discharge. More importantly, this study shows that the self-discharge mechanism in the ReHAB system involves the cathode active material and contains a reversible and an irreversible part. The reversible portion is predominant and is due to lithium re-intercalation into the LiMn2O4 spinel framework, and results from Zn dissolution into the electrolyte, which drives the Li+ ions out of the solution. The irreversible portion of the self-discharge occurs as a result of the decomposition of the LiMn2O4 material in the presence of the acidic electrolyte, and is much less extensive than the reversible process.
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Book chapters on the topic "Aqueous rechargeable mixed ion batteries"

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Makimura, Y., and T. Ohzuku. "SECONDARY BATTERIES – LITHIUM RECHARGEABLE SYSTEMS – LITHIUM-ION | Positive Electrode: Layered Mixed Metal Oxides." In Encyclopedia of Electrochemical Power Sources, 249–57. Elsevier, 2009. http://dx.doi.org/10.1016/b978-044452745-5.00196-9.

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Conference papers on the topic "Aqueous rechargeable mixed ion batteries"

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Alshareef, Husam. "Electrode & Electrolyte Engineering in Rechargeable Aqueous Zinc-ion Batteries." In MATSUS23 & Sustainable Technology Forum València (STECH23). València: FUNDACIO DE LA COMUNITAT VALENCIANA SCITO, 2022. http://dx.doi.org/10.29363/nanoge.matsus.2023.195.

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Raja, Arsalan Ahmad, Rana Abdul Shakoor, and Ramazan Kahraman. "Electrochemical Analyses of Sodium based Mixed Pyrophosphate Cathodes for Rechargeable Sodium Ion Batteries." In Qatar Foundation Annual Research Conference Proceedings. Hamad bin Khalifa University Press (HBKU Press), 2016. http://dx.doi.org/10.5339/qfarc.2016.eepp3291.

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Stamps, Michael A., and Hsiao-Ying Shadow Huang. "Mixed Modes Fracture and Fatigue Evaluation for Lithium-Ion Batteries." In ASME 2012 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2012. http://dx.doi.org/10.1115/imece2012-88037.

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Lithium ion batteries have become a widely known commodity for satisfying the world’s mobile energy storage needs. But these needs are becoming increasingly important, especially in the transportation industry, as concern for rising oil prices and environmental impact from fossil fuels are pushing for deployment of more electric vehicles (EV) or plug in hybrid-electric vehicles (PHEV) and renewable energy sources. The objective of this research is to obtain a fundamental understanding of degradation mechanisms and rate-capacity loss in lithium-ion batteries through fracture mechanics and fatigue analysis approaches. In this study we follow empirical observations that mechanical stresses accumulate on electrode materials during the cycling process. Crack induced fracturing will then follow in the material which electrical contact surface area is degraded and over capacitance of the battery reduces. A fatigue analysis simulation is applied using ANSYS finite element software coupled with analytical models to alleviate these parameters that play the most pivotal roles in affecting the rate-capacity and cycle life of the lithium-ion battery. Our results have potential to provide new models and simulation tools for clarifying the interplay of structure mechanics and electrochemistry while offering an increased understanding of fatigue degradation mechanisms in rechargeable battery materials. These models can aid manufacturers in the optimization of battery materials to ensure longer electrochemical cycling life with high-rate capacity for improved consumer electronics, electric vehicles, and many other military or space applications.
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Al-Shammari, Hammad, Roja Esmaeeli, Haniph Aliniagerdroudbari, Muapper Alhadri, Seyed Reza Hashemi, Hadis Zarrin, and Siamak Farhad. "Recycling Lithium-Ion Battery: Mechanical Separation of Mixed Cathode Active Materials." In ASME 2019 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/imece2019-10755.

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Abstract Lithium-ion batteries (LIBs) have driven the industry of rechargeable batteries in recent years due to their advantages such as high energy and power density and relatively long lifespan. Nevertheless, the dispose of spent LIBs has harmful impacts on the environment which needs to be addressed by recycling LIBs. However, none of the currently developed recycling processes is economical. The physical recycling process of LIBs may be economical if the cathode active materials can be separated, regenerated, and reused to make new LIBs. However, the first barrier for regeneration and reusing is the separation of different types of spent cathode active materials in the filter cake that are mixed with each other and come in the form of very fine powders with various sizes (< 30 μm) from the physical recycling process. The aim of this study is to separate the mixture of cathode active materials by adopting Stokes’ law. The focus will be only on mechanical separation with no thermal or chemical separation methods. For the validation, an experiment was designed and successfully performed where different types of spent cathode materials (e.g., LiCoO2, LiFePO4, and LiMn2O4) were separated from the spent anode materials (e.g., graphite) with high efficiency and reasonable time.
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