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Journal articles on the topic 'Alkoxylation'

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Author: Grafiati

Published: 10 December 2022

Last updated: 9 March 2023

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1

Liu, Zhuqing, Fei Huang, Jiang Lou, Quannan Wang, and Zhengkun Yu. "Copper-promoted direct C–H alkoxylation of S,S-functionalized internal olefins with alcohols." Organic & Biomolecular Chemistry 15, no. 26 (2017): 5535–40. http://dx.doi.org/10.1039/c7ob01234a.

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2

Shen, Jiabin, Jun Xu, Heng Cai, Chao Shen, and Pengfei Zhang. "Platinum(ii)-catalyzed selective para C–H alkoxylation of arylamines through a coordinating activation strategy." Organic & Biomolecular Chemistry 17, no. 3 (2019): 490–97. http://dx.doi.org/10.1039/c8ob02942c.

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3

Lin, John, Upali Weerasooriya, E. Leach Bruce, Steve V. Orsak, and Park T. X. Cedar. "5627121 Process for preparing alkoxylation catalysts and alkoxylation process." Journal of Molecular Catalysis A: Chemical 125, no. 2-3 (November 1997): 182. http://dx.doi.org/10.1016/s1381-1169(98)80116-7.

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4

Liu, Lunzu, Guowei Li, and Mingzhi Huang. "ALKOXYLATION OF HYDRIDOPHOSPHORANES." Phosphorus, Sulfur, and Silicon and the Related Elements 69, no. 1-2 (June 1992): 1–6. http://dx.doi.org/10.1080/10426509208036849.

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5

Weerasooriya, Upali. "Ester alkoxylation technology." Journal of Surfactants and Detergents 2, no. 3 (July 1999): 373–81. http://dx.doi.org/10.1007/s11743-999-0092-5.

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6

Lakhtin, V. G., V. L. Ryabkov, M. V. Polyakova, V. M. Nosova, A. F. Kisin, and E. A. Chernyshev. "Alkoxylation ofC-chlorovinylsilanes." Russian Chemical Bulletin 44, no. 4 (April 1995): 718–23. http://dx.doi.org/10.1007/bf00698510.

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7

Rogers, R. L., and K. Hermann. "Upgrading an Alkoxylation Facility." Process Safety and Environmental Protection 82, no. 1 (January 2004): 12–17. http://dx.doi.org/10.1205/095758204322777624.

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8

Romanova, S. M., A. M. Madyakina, L. A. Fatykhova, and S. V. Fridland. "Alkoxylation of cellulose nitrates." Russian Journal of General Chemistry 83, no. 1 (January 2013): 58–62. http://dx.doi.org/10.1134/s1070363213010106.

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9

Zhang, Yu-Feng, and Mohamed Mellah. "Samarium(ii)-electrocatalyzed chemoselective reductive alkoxylation of phthalimides." Organic Chemistry Frontiers 9, no. 5 (2022): 1308–14. http://dx.doi.org/10.1039/d1qo01760h.

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10

Takemura, Noriaki, Yoichiro Kuninobu, and Motomu Kanai. "Copper-catalyzed benzylic C(sp3)–H alkoxylation of heterocyclic compounds." Org. Biomol. Chem. 12, no. 16 (2014): 2528–32. http://dx.doi.org/10.1039/c4ob00215f.

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11

Yamaguchi, Eiji, Nao Taguchi, and Akichika Itoh. "Ruthenium polypyridyl complex-catalysed aryl alkoxylation of styrenes: improving reactivity using a continuous flow photo-microreactor." Reaction Chemistry & Engineering 4, no. 6 (2019): 995–99. http://dx.doi.org/10.1039/c9re00061e.

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12

Li, Long, Xin-Qi Zhu, Ying-Qi Zhang, Hao-Zhen Bu, Peng Yuan, Jinyu Chen, Jingyi Su, Xianming Deng, and Long-Wu Ye. "Metal-free alkene carbooxygenation following tandem intramolecular alkoxylation/Claisen rearrangement: stereocontrolled access to bridged [4.2.1] lactones." Chemical Science 10, no. 10 (2019): 3123–29. http://dx.doi.org/10.1039/c9sc00079h.

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13

Fan, Huaqiang, Yi Wan, Peng Pan, Wenbin Cai, Shihui Liu, Chuanxu Liu, and Yongqiang Zhang. "A cascade approach to 3D cyclic carbamates via an ionic decarboxylative functionalization of olefinic oxamic acids." Chemical Communications 56, no. 1 (2020): 86–89. http://dx.doi.org/10.1039/c9cc07709j.

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14

Lu, Wenkui, Hui Xu, and Zengming Shen. "Copper-catalyzed aromatic C–H alkoxylation with alcohols under aerobic conditions." Organic & Biomolecular Chemistry 15, no. 5 (2017): 1261–67. http://dx.doi.org/10.1039/c6ob02582j.

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15

Liu, Yongxiang, Jia Guo, Yang Liu, Xiaoyu Wang, Yanshi Wang, Xinyu Jia, Gaofei Wei, Lizhu Chen, Jianyong Xiao, and Maosheng Cheng. "Au(i)-catalyzed triple bond alkoxylation/dienolether aromaticity-driven cascade cyclization to naphthalenes." Chem. Commun. 50, no. 47 (2014): 6243–45. http://dx.doi.org/10.1039/c4cc00464g.

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16

Gatto, Mattia, Walter Baratta, Paola Belanzoni, Leonardo Belpassi, Alessandro Del Zotto, Francesco Tarantelli, and Daniele Zuccaccia. "Hydration and alkoxylation of alkynes catalyzed by NHC–Au–OTf." Green Chemistry 20, no. 9 (2018): 2125–34. http://dx.doi.org/10.1039/c8gc00508g.

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17

Enthaler, Stephan, and Anna Company. "Palladium-catalysed hydroxylation and alkoxylation." Chemical Society Reviews 40, no. 10 (2011): 4912. http://dx.doi.org/10.1039/c1cs15085e.

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18

Hlavatý, Jaromír. "Anodic alkoxylation of N-phenylsulfonylpyrrole." Electrochimica Acta 40, no. 5 (April 1995): 625–28. http://dx.doi.org/10.1016/0013-4686(94)00336-y.

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19

Khutorianskyi, Viktor V., Norbert Baris, and Petr Beier. "Oxidative nucleophilic alkoxylation of nitrobenzenes." Organic Chemistry Frontiers 8, no. 1 (2021): 77–81. http://dx.doi.org/10.1039/d0qo01291b.

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20

LIU, L., G. LI, and M. HUANG. "ChemInform Abstract: Alkoxylation of Hydridophosphoranes." ChemInform 23, no. 42 (August 21, 2010): no. http://dx.doi.org/10.1002/chin.199242209.

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21

Zhang, Shuaizhong, Jinquan Zhang, and Hongbin Zou. "C(sp³)–H oxygenation via alkoxypalladium(ii) species: an update for the mechanism." Chemical Science 13, no. 5 (2022): 1298–306. http://dx.doi.org/10.1039/d1sc06907a.

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22

Zeng, Wanting, Moldir Nukeyeva, Qiumei Wang, and Chao Jiang. "Synthesis of unnatural α-amino acid derivatives via selective o-C–H functionalization." Organic & Biomolecular Chemistry 16, no. 4 (2018): 598–608. http://dx.doi.org/10.1039/c7ob02921g.

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23

Xu, Zhaoliang, Yu Hu, Lei Wang, Mingli Sun, and Pinhua Li. "Merging cobalt and photoredox catalysis for the C8–H alkoxylation of 1-naphthylamine derivatives with alcohols." Organic & Biomolecular Chemistry 19, no. 46 (2021): 10112–19. http://dx.doi.org/10.1039/d1ob01721g.

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24

Wang, Wei, Jun-Rong Song, Zhi-Yao Li, Ting Zhong, Qin Chi, Hai Ren, and Wei-Dong Pan. "Copper-catalyzed aerobic oxidative radical alkoxycyclization of tryptamines to access 3-alkoxypyrroloindolines." RSC Advances 11, no. 29 (2021): 18080–83. http://dx.doi.org/10.1039/d1ra02679h.

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25

Tran, Chau B., Xuan N. T. Duong, Huy D. Lu, Thu T. V. Cao, and Thanh Truong. "Auxiliary-directed etherification of sp2 C–H bonds under heterogeneous metal–organic framework catalysis: synthesis of ethenzamide." RSC Advances 8, no. 5 (2018): 2829–36. http://dx.doi.org/10.1039/c7ra12010a.

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26

Beng, Timothy K., Victoria Shearer, Rachel Davey, and Ivianne Redman. "Site-selective, catalytic, and diastereoselective sp3 C–H hydroxylation and alkoxylation of vicinally functionalized lactams." RSC Advances 10, no. 34 (2020): 20264–71. http://dx.doi.org/10.1039/d0ra03726e.

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27

Villuendas, Pedro, Elena Serrano, and Esteban P. Urriolabeitia. "Pd-catalysed ortho-alkoxylation of benzamides N-protected with an iminophosphorane functionality." New Journal of Chemistry 39, no. 4 (2015): 3077–83. http://dx.doi.org/10.1039/c5nj00189g.

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28

Beng, Timothy K., Megan Bauder, Morgan J. Rodriguez, and Antonio Moreno. "Copper-catalyzed regioselective dehydrogenative alkoxylation of morpholinonyl alkenols: application to the synthesis of spirotricyclic dihydropyrans and of trans-fused bicyclic morpholines." New Journal of Chemistry 42, no. 20 (2018): 16451–55. http://dx.doi.org/10.1039/c8nj03890b.

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29

Dong, Min, Yuqi Jia, Wei Zhou, Jinlai Gao, Xiaoqing Lv, Fan Luo, Yongqiang Zhang, and Shihui Liu. "A photoredox/nickel dual-catalytic strategy for benzylic C–H alkoxylation." Organic Chemistry Frontiers 8, no. 24 (2021): 6881–87. http://dx.doi.org/10.1039/d1qo01421h.

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30

Ivandini, Tribidasari A., and Yasuaki Einaga. "Polycrystalline boron-doped diamond electrodes for electrocatalytic and electrosynthetic applications." Chemical Communications 53, no. 8 (2017): 1338–47. http://dx.doi.org/10.1039/c6cc08681k.

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31

Zhang, Ying-Qi, Xin-Qi Zhu, Yin Xu, Hao-Zhen Bu, Jia-Le Wang, Tong-Yi Zhai, Jin-Mei Zhou, and Long-Wu Ye. "Synthesis of functionalized 3-isochromanones via metal-free intramolecular alkoxylation-initiated cascade cyclization." Green Chemistry 21, no. 11 (2019): 3023–28. http://dx.doi.org/10.1039/c9gc01030k.

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32

Li, Heng, Fan Lv, Xing Guo, Qinghua Wu, Hao Wu, Bing Tang, Changjiang Yu, Hua Wang, Lijuan Jiao, and Erhong Hao. "Direct C–H alkoxylation of BODIPY dyes via cation radical accelerated oxidative nucleophilic hydrogen substitution: a new route to building blocks for functionalized BODIPYs." Chemical Communications 57, no. 13 (2021): 1647–50. http://dx.doi.org/10.1039/d0cc07961h.

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33

Shao, Zhong, Fang Wang, Jingqi Shi, Lifang Ma, and Ziyuan Li. "Synergetic copper/TEMPO-catalysed benzylic C–H imidation with N-fluorobenzenesulfonimide at room temperature and tandem conversions with alcohols or arenes." Organic Chemistry Frontiers 8, no. 13 (2021): 3298–307. http://dx.doi.org/10.1039/d1qo00340b.

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34

Hao, Feiyue, Haruyasu Asahara, and Nagatoshi Nishiwaki. "A direct and vicinal functionalization of the 1-methyl-2-quinolone framework: 4-alkoxylation and 3-chlorination." Organic & Biomolecular Chemistry 14, no. 22 (2016): 5128–35. http://dx.doi.org/10.1039/c6ob00868b.

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35

Sarkar, Souvik, Tapan Sahoo, Chiranjit Sen, and Subhash Chandra Ghosh. "Copper(ii) mediated ortho C–H alkoxylation of aromatic amines using organic peroxides: efficient synthesis of hindered ethers." Chemical Communications 57, no. 71 (2021): 8949–52. http://dx.doi.org/10.1039/d1cc01803e.

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A unique approach to synthesize hindered alkyl aryl ether derivatives (R–O–Ar) via copper catalyzed aromatic C–H alkoxylation with bulky alkoxy groups using very simple peroxide tBuOOtBu is described here.

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36

Petrov, Vladimir F. "Alkoxylation in achiral calamitic liquid crystals." Liquid Crystals 29, no. 6 (June 1, 2002): 805–35. http://dx.doi.org/10.1080/02678290210133114.

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37

Hou, Hong, Hengxue Li, Yue Xu, Daliang Tang, Ying Han, Chaoguo Yan, Xiaoyun Chen, and Shaoqun Zhu. "Catalyst-free fluorinative alkoxylation of alkenes." Tetrahedron 74, no. 45 (November 2018): 6577–83. http://dx.doi.org/10.1016/j.tet.2018.09.038.

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38

Rose-Munch, Françsoise, Jean Pierre Djukic, and Eric Rose. "Hydro-de-alkoxylation of alkoxybenzenetricarbonylchromium complexes." Tetrahedron Letters 31, no. 18 (January 1990): 2589–90. http://dx.doi.org/10.1016/0040-4039(90)80132-6.

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39

Ishida, Akito, Tatsumi Uesugi, and Setsuo Takamuku. "Photoinduced Alkoxylation of 2-Vinylpyridinium Ion." Bulletin of the Chemical Society of Japan 66, no. 5 (May 1993): 1580–82. http://dx.doi.org/10.1246/bcsj.66.1580.

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40

Guo, Ya-Fei, Bao-Hua Xu, Ting Li, Lei Wang, and Suo-Jiang Zhang. "Cobalt(ii)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions." Organic Chemistry Frontiers 3, no. 1 (2016): 47–52. http://dx.doi.org/10.1039/c5qo00293a.

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Efficient cobalt(ii) catalyzed oxidative alkoxylation of aldehydes leading to the corresponding esters is presented. Mechanism studies provide fresh insights into the cobalt mediated decomposition of TBHP in the presence of the iodide ion.

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41

Yang, Xinglin, Gang Shan, Zimo Yang, Guiyi Huang, Guoqiang Dong, Chunquan Sheng, and Yu Rao. "One-pot synthesis of quaternary carbon centered cyclobutanes via Pd(ii)-catalyzed cascade C(sp3)–H activations." Chemical Communications 53, no. 9 (2017): 1534–37. http://dx.doi.org/10.1039/c6cc06897a.

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A novel approach toward quaternary carbon centered cyclobutanes through Pd(ii)-catalyzed sequential intramolecular methylene C–H alkylation and intermolecular methine C–H bond arylation, alkenylation, alkylation, alkynylation, allylation, benzylation or alkoxylation is described.

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42

Amri, Nasser, Ryan A. Skilton, Duncan Guthrie, and Thomas Wirth. "Efficient Flow Electrochemical Alkoxylation of Pyrrolidine-1-carbaldehyde." Synlett 30, no. 10 (March 26, 2019): 1183–86. http://dx.doi.org/10.1055/s-0037-1611774.

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We report on the optimization of the alkoxylation of pyrrolidine-1-carbaldehyde by using a new electrochemical microreactor. Precise control of the reaction conditions permits the synthesis of either mono- or dialkoxylated reaction products in high yields.

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43

Yang, Can, Zhipeng Liu, Xinwei Hu, Haisheng Xie, Huanfeng Jiang, and Wei Zeng. "Rh(iii)-Catalyzed Csp2–Csp3 bond alkoxylation of α-indolyl alcohols via C–C σ bond cleavage." Organic Chemistry Frontiers 8, no. 12 (2021): 2949–54. http://dx.doi.org/10.1039/d1qo00194a.

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44

Estruch-Blasco, Manel, Irene Bosque, David Guijarro, and Jose C. Gonzalez-Gomez. "Electrochemically site-selective alkoxylation of twisted 2-arylbenzoic acids via spirolactonization." Organic Chemistry Frontiers 8, no. 18 (2021): 5130–38. http://dx.doi.org/10.1039/d1qo00834j.

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Twisted σ-biphenyl-2-carboxyl radicals show a significant spin density in the adjacent aryl ring, facilitating the spirocyclization. Electro-cross coupling with alcohols and isomerization provide a site-selective alkoxylation of 2-arylbenzoic acids.

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45

Zhang, Jingran, Ayesha Jalil, Jiaxin He, Zhenyang Yu, Yifu Cheng, Guangchen Li, Yunfei Du, and Kang Zhao. "Lactonization with concomitant 1,2-aryl migration and alkoxylation mediated by dialkoxyphenyl iodides generated in situ." Chemical Communications 57, no. 60 (2021): 7426–29. http://dx.doi.org/10.1039/d1cc03110d.

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Alkoxylated isobenzofuranones were synthesized mediated by PhI(OR)₂, generated in situ from the reaction of PhIO with alkyl alcohols. This one-pot transformation was postulated to involve lactonization, 1,2-aryl migration and alkoxylation processes.

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46

Abdolalian, Payam, Samaneh K. Tizhoush, Kaveh Farshadfar, and Alireza Ariafard. "The role of hypervalent iodine(iii) reagents in promoting alkoxylation of unactivated C(sp3)–H bonds catalyzed by palladium(ii) complexes." Chemical Science 12, no. 20 (2021): 7185–95. http://dx.doi.org/10.1039/d1sc01230d.

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This work uses DFT calculations to explore Pd(ii)-catalysed iodine(iii)-mediated alkoxylation of unactivated C(sp³)–H bonds and reveals how important the isomerization is in triggering the oxidative addition of ArIX₂ to Pd(ii).

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47

Musik, Marlena, Marcin Bartkowiak, and Eugeniusz Milchert. "Advanced Methods for Hydroxylation of Vegetable Oils, Unsaturated Fatty Acids and Their Alkyl Esters." Coatings 12, no. 1 (December 23, 2021): 13. http://dx.doi.org/10.3390/coatings12010013.

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Vegetable oils and their derivatives have great potential as renewable and sustainable raw materials for the production of polyurethanes and bio-based polyols. For industry an important process is their modification. Chemical reactions that are carried out on vegetable oils and their derivatives are: transesterification, auto-oxidation, hydrogenation, epoxidation, hydroxylation, acrylation, isocyanation and others. One of the modifications are reactions performed on double bonds and/or carbonyl moieties of plants oils and their derivatives. These reactions result in products that are actively used as binders in coating materials due to their unique structural properties. In this manuscript, we describe important technological methods for the introduction of hydroxyl groups: opening of oxirane rings by nucleophilic reagents such as: water, alcohols, glycols, amino alcohols, carboxylic acids; direct hydroxylation of unsaturated bonds with carboxylic peracids in combination with hydrolysis of carboxyl groups and hydration; hydroformylation of unsaturated bonds with subsequent hydrogenation and alkoxylation; and ozonolysis of unsaturated bonds in combination with subsequent hydrogenation and alkoxylation.

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48

Zhu, Jingshuai, Yiqun Xiao, Changxi Zhang, Boyu Jia, Heng Lu, Jiayu Wang, Xinhui Lu, Zhen Li, and Xiaowei Zhan. "Effects of alkoxylation position on fused-ring electron acceptors." Journal of Materials Chemistry C 8, no. 43 (2020): 15128–34. http://dx.doi.org/10.1039/d0tc02158j.

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Four fused-ring electron acceptors composed of the same core and end groups without or with hexyloxyl groups on the core and/or phenyl side chains are compared to systematically study the effects of alkoxylation position on the molecular packing, optical, electronic, and photovoltaic properties of the nonfullerene acceptors.

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49

Hamana, Masatomo, Mitsuo Hayashida, and Haruyoshi Honda. "Deoxygenative 2-Alkoxylation of Quinoline 1-Oxide." HETEROCYCLES 31, no. 7 (1990): 1325. http://dx.doi.org/10.3987/com-90-5413.

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50

Kidwai, Mazaahir, Parven Kumar, and Seema Kohli. "Microwave-induced Selective Alkoxylation of 1,4-Naphthoquinones†." Journal of Chemical Research, no. 1 (1997): 24–25. http://dx.doi.org/10.1039/a601810f.

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