Relevant bibliographies by topics / Alkemy

Academic literature on the topic 'Alkemy'

Author: Grafiati
Published: 4 June 2021
Last updated: 10 February 2022

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Journal articles on the topic "Alkemy"

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Politi, Katerina, and Scott Gettinger. "Perfect ALKemy: Optimizing the Use of ALK-Directed Therapies in Lung Cancer." Clinical Cancer Research 20, no. 22 (September 16, 2014): 5576–78. http://dx.doi.org/10.1158/1078-0432.ccr-14-2306.

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Yamamoto, Eiji, Satoshi Ukigai, and Hajime Ito. "Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies." Chemical Science 6, no. 5 (2015): 2943–51. http://dx.doi.org/10.1039/c5sc00384a.

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A transition-metal-free method has been developed for the boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides using a silylborane/alkoxy-base reagent. Borylation of (Z)-alkenyl halides proceeded in a stereoretentive manner.
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Phipps, Erik J. T., Tiffany Piou, and Tomislav Rovis. "Rhodium(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C–H Activation." Synlett 30, no. 15 (July 22, 2019): 1787–90. http://dx.doi.org/10.1055/s-0039-1690130.

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We have developed a rhodium(III)-catalyzed cyclopropanation of unactivated olefins initiated by an alkenyl C–H activation. A variety of 1,1-disubstituted olefins undergo efficient cyclopropanation with a slight excess of alkene stoichiometry. A series of mechanistic interrogations implicate a metal carbene as an intermediate.
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Glover, SA, GP Hammond, DG Harman, JG Mills, and CA Rowbottom. "Cyclization of Alkoxyiminyl Radicals Onto Olefins: Formation of 2-Alkoxy-Delta(1)-Pyrrolines, 4,5-Dihydrooxazoles and 5,6-Dihydrol-4h-1,3-Oxazines." Australian Journal of Chemistry 46, no. 8 (1993): 1213. http://dx.doi.org/10.1071/ch9931213.

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Alkoxyiminyl radicals, generated by photolysis of N-bromo imidates, undergo exo-1,5 and exo-1,6 cyclization onto olefins on the O-alkyl side chains giving good yields of 4,5-dihydrooxazoles and 5,6-dihydro-4H-1,3-oxazines, respectively. exo-1,5 Cyclization onto an olefin on the iminyl side chain gives 2-alkoxy-Δ1-pyrrolines. 4,5-Dihydrooxazole formation is more favourable than cyclization to 2-alkoxy-Δ1-pyrrolines and both reactions are irreversible. These preferences are supported by MNDO molecular orbital calculations which predict that both processes are exothermic but cyclization onto the O- alkenyl side chain has a lower ΔH‡.
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Maraswami, Manikantha, and Teck-Peng Loh. "Transition-Metal-Catalyzed Alkenyl sp2 C–H Activation: A Short Account." Synthesis 51, no. 05 (January 23, 2019): 1049–62. http://dx.doi.org/10.1055/s-0037-1611649.

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Alkenes are ubiquitous in Nature and their functionalization continues to attract attention from the scientific community. On the other hand, activation of alkenyl sp2 C–H bonds is challenging due to their chemical properties. In this short account, we elucidate, discuss and describe the utilization of transition-metal catalysts in alkene activation and provide useful strategies to synthesize organic building blocks in an efficient and sustainable manner.1 Introduction2 Breakthrough3 Controlling E/Z, Z/E Selectivity3.1 Esters and Amides as Directing Groups3.2 The Chelation versus Non-Chelation Concept4 Other Alkene Derivatives5 Intramolecular C–H Activation6 Conclusion and Future Projects
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Listunov, Dymytrii, Valérie Maraval, Nathalie Saffon-Merceron, Sonia Mallet-Ladeira, Zoia Voitenko, Yulian Volovenko, Yves Génisson, and Remi Chauvin. "On terminal alkynylcarbinols and derivatization thereof." French-Ukrainian Journal of Chemistry 3, no. 1 (2015): 21–28. http://dx.doi.org/10.17721/fujcv3i1p21-28.

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The chemistry of three prototypes of secondary alkynylcarbinols (ACs), recently highlighted as challenging targets in anti-tumoral medicinal chemistry, is further documented by results on n-alkyl, alkynyl and alkenyl representatives. The N-naphthyl carbamate of an n-butyl-AC is thus characterized by X-ray crystallography. A novel dialkynylcarbinol (DAC) with synthetic potential is described, namely the highly dissymmetrical triisopropylsilyl-protected version of diethynylmethanol. The latter is shown to act as a dipolarophile in a selective Huisgen reaction with benzyl azide under CuAAC click conditions, giving an alkenyl-AC, where the alkene unsaturation is embedded in a 1,4-disubstituted 1,2,3-triazole ring, as confirmed by X-ray crystallography.
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Music, Arif, and Dorian Didier. "Organocerium: A New Contender for Halogen–Metal Exchanges." Synlett 30, no. 16 (June 3, 2019): 1843–49. http://dx.doi.org/10.1055/s-0037-1611843.

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In the context of our current research on dependable and sustainable methods for C–C bond-forming reactions, we have recently developed new strategies to generate organocerium reagents through simple bromide–cerium exchanges. n-Bu3Ce enabled a fast and general access to functionalized triaryl- and alkenyl cerium species from the corresponding aryl- and alkenyl bromides. A broad range of these new organocerium species was engaged in Zweifel’s olefination, allowing for the synthesis of widely substituted alkene derivatives in a stereospecific way. Herein, we place the formation of organocerium species in the context of known organometallic reagents (Li, Mg, Zn, Cu, Ca, La, and Sm) generated through halogen–metal exchange reactions and their application in further transformations.
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Tang, Xinjun, and Armido Studer. "Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration." Angewandte Chemie International Edition 57, no. 3 (January 15, 2018): 814–17. http://dx.doi.org/10.1002/anie.201710397.

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Tang, Xinjun, and Armido Studer. "Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration." Angewandte Chemie 130, no. 3 (December 14, 2017): 822–25. http://dx.doi.org/10.1002/ange.201710397.

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Gu, Zheng-Yang, Yang Wu, Xiaoguang Bao, Ji-Bao Xia, and Feng Jin. "Intermolecular C–H Amidation of Alkenes with Carbon Monoxide and Azides via Tandem Palladium Catalysis." Synthesis 53, no. 18 (February 26, 2021): 3361–71. http://dx.doi.org/10.1055/a-1401-4486.

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AbstractAn atom- and step-economic intermolecular multi-component palladium-catalyzed C–H amidation of alkenes with carbon monoxide and organic azides has been developed for the synthesis of alkenyl amides. The reaction proceeds efficiently without an ortho-directing group on the alkene substrates. Nontoxic dinitrogen is generated as the sole by-product. Computational studies and control experiments have revealed that the reaction takes place via an unexpected mechanism by tandem palladium catalysis.
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Dissertations / Theses on the topic "Alkemy"

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Phung, Toan, and Toan Phung@gmail com. "An Historical Based Adaptation Mechanism For BDI Agents." RMIT University. Computer Science and Information Technology, 2008. http://adt.lib.rmit.edu.au/adt/public/adt-VIT20080515.124049.

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One of the limitations of the BDI (Belief-Desire-Intention) model is the lack of any explicit mechanisms within the architecture to be able to learn. In particular, BDI agents do not possess the ability to adapt based on past experience. This is important in dynamic environments as they can change, causing previously successful methods for achieving goals to become inefficient or ineffective. We present a model in which learning, analogous reasoning, data pruning and learner accuracy evaluation can be utilised by a BDI agent and verify this model experimentally using Inductive and Statistical learning. Intelligent Agents are a new way of developing software applications. They are an amalgam of Artificial Intelligence (AI) and Software Engineering concepts that are highly suited to domains that are inherently complex and dynamic. Agents are software entities that are autonomous, reactive, proactive, situated and social. They are autonomous in that they are able to make decisions on their own volition. They are situated in some environment and are reactive to this environment yet are also capable of proactive behaviour where they actively pursue goals. They are capable of social behaviour where communication can occur between agents. BDI (Belief Desire Intention) agents are one popular type of agent that support complex behaviour in dynamic environments. Agent adaptation can be viewed as the process of changing the way in which an agent achieves its goals. We distinguish between 'reactive' or short-term adaptation, 'long-term' or historical adaptation and 'very long term' or evolutionary adaptation. Short-term adaptation, an ability that current BDI agents already possess, involves reacting to changes in the environment and choosing alternative plans of action which may involve choosing new plans if the current plan fails. 'Long-term' or historical adaptation entails the use of past cases during the reasoning process which enables agents to avoid repeating past mistak es. 'Evolutionary adaptation' could involve the use of genetic programming or similar techniques to mutate plans to lead to altered behaviour. Our work aims to improve BDI agents by introducing a framework that allows BDI agents to alter their behaviour based on past experience, i.e. to learn.
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Régent, Damien [Verfasser], and Bernhard [Akademischer Betreuer] Breit. "Rhodium-catalyzed intra- and intermolecular alkene hydroacylation = Rhodium-katalisierte Intra- und Intermolecular Alken Hydroacylation." Freiburg : Universität, 2014. http://d-nb.info/1115813811/34.

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Bräuner, Maja. "Alkemi och jungiansk psykologi." Thesis, University of Gävle, Ämnesavdelningen för kultur- och religionsvetenskap, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:hig:diva-6707.

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This assignment is a venture into the use of the concept alchemy in the texts on analytical psychology written by Carl G. Jung. Originally the idea was to compare the blending of colours in art painting with the Jungian understanding of alchemy. In order to understand the many and it seems differentiated correlations to alchemy in the texts on analytical psychology written by C.G. Jung, I have found it necessary to investigate the history of alchemy in modern Europe and the Egyptian figure of Hermes Trismegistos. This helps shedding light on Jung’s manner of writing in his texts on analytical psychology.

The assignment includes an understanding of colours as understood by Goethe as well as the aspect of alchemy in the Rosicrucian movement and the kabbalah. The Jungian aspects of world religions are in this context emphasized as well as the use of symbols and symbolic speech.

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Szuromi, Endre. "Alkene-oxo and alkene-alkene coupling on Pt(II)." Diss., Columbia, Mo. : University of Missouri-Columbia, 2005. http://hdl.handle.net/10355/4156.

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Thesis (Ph. D.)--University of Missouri-Columbia, 2005.
The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file viewed on (November 14, 2006) Vita. Includes bibliographical references.
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García, Ruiz Víctor M. "Studien zur Anwendung der Olefinmetathese." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=962929832.

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Husain, A. H. "Mechanism of alkene epoxidation." Thesis, University of Cambridge, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.604836.

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Heterogeneous silver catalysed ethene epoxidation is a strategically important selective oxidation giving rise to ethene epoxide a versatile monomer that is largely converted to glycols and used as antifreeze. Several aspects of this commercially important reaction were investigated using electrochemical promotion, a technique which involves electropumping of ions from a solid ion-conducting electrolyte to the surface of a porous catalytically active metal film. The most notable result in this work from ethene epoxidation was the elucidation of the NOx promotion effect. It was shown that adsorbed alkali and parts per million levels of nitric oxide added in the gas feed were minimum and sufficient conditions for the appearance of this phenomenon. Another commercially daunting and scientifically challenging reaction that was studied in this work was the heterogeneous propene epoxidation on silver catalysts. Using electrochemical promotion this work has shown that ethene and propene epoxidation react in a very different and contrasting manner to the addition of cholorine (CI), alkali and nitric oxide (NO) promoters. Basically potassium (K) alone is bad for ethene epoxide (EO), good for propene epoxide (PO), CI is good for EO, indifferent for PO, K+CI is good for EO, bad for PO and K+NO is good for EO, bad for PO. X-ray photoelectron spectroscopic investigation of the silver catalyst revealed that the substantially different state of oxygenation of the silver subsurface region could be the origin of the very different selectivity observed with these two alkenes. The underlying reason for the observed promotion in selectivity with adsorbed chlorine in ethene epoxidation was investigated by studying the effect of all four halogen promoters’ viz., fluorine, chlorine, bromine and iodine on supported silver on alumina catalysts. It was found that chlorine is the best promoter amongst them all. The behaviour of the halogens had a direct bearing to their electron affinity. And it seems that electronic affects are at work and geometric effects due to site blocking can be ruled out.
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Hudson, Richard D. A. "Alkenyl-extended cyclohexadienyl complexes." Thesis, University of East Anglia, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.309965.

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Richardson, Guy Norbury. "#mu#-alkenyl diruthenium chemistry." Thesis, University of Bristol, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.260516.

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Pullin, Robert David Charles. "Amine-promoted alkene aziridination." Thesis, Imperial College London, 2011. http://hdl.handle.net/10044/1/6939.

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Aziridines, the smallest saturated aza-heterocycle, are not only prevalent in several natural products, but also represent a versatile synthetic tool for the chemist via exploitation of the strained ring system. Research described in this thesis concerns the chemistry of N-N ylides (aminimines), which were utilised in a novel tertiary amine-promoted organocatalytic approach to the aziridination of α,β-unsaturated carbonyl compounds. Through the use of modified conditions two important classes of substrates, dienones and alpha-enolizable enones, both of which had previously shown poor reactivity with the system, can now be aziridinated in good yields. Studies have also focused on the development of an asymmetric variant of the methodology using chiral tertiary amine promoters. A variety of novel chiral six-membered 1,4-heterocycles and cinchona alkaloid derivatives have been synthesised and their utility towards asymmetric alkene aziridination has been assessed, aiding the understanding of the proposed transition state model for the reaction.
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Knoke, Stefan. "Video- und elektronenmikroskopische Untersuchungen der Olefinpolymerisation mit trägerfixierten Katalysatorsystemen." [S.l.] : [s.n.], 2003. http://deposit.ddb.de/cgi-bin/dokserv?idn=973585625.

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Books on the topic "Alkemy"

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van, Berge Alexander, and Smyth Judith, eds. Jen Alkema: Architect. Warnsveld, The Netherlands: Terra, 2003.

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Reisinger, Attila. Alkony. Budapest: Littera Nova Kiadó, 2013.

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Coelho, Paulo. Sang Alkemis. Jakarta: Gramedia, 2005.

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Palmgren, Reidar. Lentämisen alkeet. Helsingissä: Otava, 2004.

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Wang, Jianbo, ed. Stereoselective Alkene Synthesis. Berlin, Heidelberg: Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-31824-5.

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Afrikan alkhemy: Spiritual & soul transformation in America. Nashville, TN: One Horn Press, 1995.

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Hanson, Hertha. Alkemi, romantik och rasvetenskap: Om en vetenskaplig tradition. Nora: Nya doxa, 1994.

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Assis, Cecy de. Alkymya de assustos: Poesia. Rio de Janeiro, RJ: Philobiblion, 1987.

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Karlsson, Thomas. Go tisk kabbala och runisk alkemi: Johannes Bureus och den go tiska esoterismen. Stockholm: Institutionen fo r etnologi, religionshistoria och genusstudier, Stockholms universitet, 2010.

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Traube, Klaus. Der Atom-Skandal: Alkem, Nukem und die Konsequenzen. Reinbek bei Hamburg: Rowohlt, 1988.

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Book chapters on the topic "Alkemy"

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Gooch, Jan W. "Alkene." In Encyclopedic Dictionary of Polymers, 27–28. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_437.

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Gondesen, Björn. "Alkene." In Chemie 7, 35–41. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-55094-6_6.

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Wollrab, Adalbert. "Alkene." In Organische Chemie, 84–149. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-00781-1_3.

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Wollrab, Adalbert. "Alkene." In Organische Chemie, 84–155. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-45144-7_3.

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Wollrab, Adalbert. "Alkene." In Organische Chemie, 75–134. Berlin, Heidelberg: Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-09137-1_3.

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Bährle-Rapp, Marina. "Alken." In Springer Lexikon Kosmetik und Körperpflege, 20. Berlin, Heidelberg: Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_327.

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Cinellu, Maria Agostina. "Gold-Alkene Complexes." In Modern Gold Catalyzed Synthesis, 175–99. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527646869.ch7.

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Bianchini, Claudio, and Andrea Meli. "Alkene/CO Copolymerisation." In Mechanisms in Homogeneous Catalysis, 271–309. Weinheim, FRG: Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527605134.ch7.

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"tert.-Alkenyl Oxygen Compounds; Alkoxy-alkenes (I)." In Substance index, edited by Backes, Fröhlich, and Padeken. Stuttgart: Georg Thieme Verlag, 2001. http://dx.doi.org/10.1055/b-0035-113780.

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"tert.-Alkenyl Oxygen Compounds; Alkoxy-alkenes (II)." In Substance index, edited by Backes, Fröhlich, and Padeken. Stuttgart: Georg Thieme Verlag, 2001. http://dx.doi.org/10.1055/b-0035-113781.

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Conference papers on the topic "Alkemy"

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Sze-Ming Yang and Wen-Bin Lee. "The properties of alkoxy substituted polyaniline." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.834713.

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Smit, Biljana, Zoran Simic, Darko Asanin, and Radoslav Pavlovic. "Electrochemical selenium-initiated cyclization of alkenyl hydantoins." In The 19th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2015. http://dx.doi.org/10.3390/ecsoc-19-a059.

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Brigandi, Paul J., Paul J. Caronia, Stephen Cree, Morgan Hughes, and Colin Li Pi Shan. "Ethylene alkene elastomers for cable insulation applications." In 2016 IEEE/PES Transmission and Distribution Conference and Exposition (T&D). IEEE, 2016. http://dx.doi.org/10.1109/tdc.2016.7520063.

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Karjalainen, Jaana, David Sherrington, and Osmo Hormi. "Efficient Polymer-supported Sharpless Alkene Epoxidation Catalyst." In The 1st International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02047.

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Galewski, Zbigniew. "Liquid crystalline properties of 4-alkoxy-4'-bromoazobenzenes." In Liquid Crystals: Materials Science and Applications, edited by Jozef Zmija. SPIE, 1995. http://dx.doi.org/10.1117/12.215544.

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Poth, L., Q. Zhong, J. V. Ford, Z. Shi, and A. W. Castleman. "The Metastable Decay of Alkene Clusters after Photoionization." In Resonance ionization spectroscopy 1996: Eighth international symposium. AIP, 1997. http://dx.doi.org/10.1063/1.52228.

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Reuter, Christopher B., and Timothy Ombrello. "Ozone-Enhanced Flame Propagation of Alkane/Alkene/Air Mixtures." In AIAA Scitech 2020 Forum. Reston, Virginia: American Institute of Aeronautics and Astronautics, 2020. http://dx.doi.org/10.2514/6.2020-0179.

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Galewski, Zbigniew. "Liquid-crystalline properties of 4-halogenobenzylidene-4'-alkoxy-anilines." In Liquid and Solid State Crystals: Physics, Technology, and Applications, edited by Jozef Zmija. SPIE, 1993. http://dx.doi.org/10.1117/12.156968.

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Tretiak, O. Yu, M. V. Balabas, and P. K. Olshin. "Raman spectroscopy investigation of alkene-based anti-relaxation coating." In 2014 International Conference Laser Optics. IEEE, 2014. http://dx.doi.org/10.1109/lo.2014.6886414.

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Kaddami, H., S. Cuney, J. P. Pascault, and J. F. Gérard. "Hybrid organic-inorganic coatings based on alkoxy-terminated macromonomers." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49449.

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Reports on the topic "Alkemy"

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SENUM, G. I., and R. N. DIETZ. QUANTIFICATION OF FUGITIVE REACTIVE ALKENE EMISSIONS FROM PETROCHEMICAL PLANTS WITH PERFLUOROCARBON TRACERS. Office of Scientific and Technical Information (OSTI), June 2004. http://dx.doi.org/10.2172/15008762.

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Dibble, Theodore S. Dynamics of Peroxy and Alkenyl Radicals Undergoing Competing Rearrangements in Biodiesel Combustion. Office of Scientific and Technical Information (OSTI), March 2016. http://dx.doi.org/10.2172/1243092.

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Lopez de Victoria, G. Chemotactic behavior of deep subsurface bacteria toward carbohydrates, amino acids and a chlorinated alkene. Office of Scientific and Technical Information (OSTI), February 1989. http://dx.doi.org/10.2172/6324569.

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Brown, Herbert C., Ashok M. Salunkhe, and Ankush B. Argade. Organoboranes. 55. An Improved Procedure for the Conversion of Representative Achiral and Chiral Monoalkyl-, (E)- and (Z)-Alkenyl-, and Arylboronates into the Corresponding Organldichloroboranes. Fort Belvoir, VA: Defense Technical Information Center, June 1992. http://dx.doi.org/10.21236/ada251643.

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Jensen, Michael Vinter, and Mette Løvschal. Boes Skov prøveudgravningsrapport (trial excavation report): SBM 1531/ FHM5693 Boes Skov, Alken, Dover sogn, Hjelmslev herred, tidl. Skanderborg amt. Sted nr. 16.02.03. Aarhus University Library, 2017. http://dx.doi.org/10.7146/aul.204.147.

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Løvschal, Mette, Louise Søndergaard, and Michael Vinter. Boes Skov I Boes Skov I udgravningsberetning (excavation report): SBM 1531 Boes Skov I, Alken, Dover sogn, Hjemlev herred, Skanderborg amt, 160203-335. Aarhus University Library, 2018. http://dx.doi.org/10.7146/aul.247.177.

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