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Journal articles on the topic 'Alkaline Earth Metal hydrides'

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Published: 24 August 2024

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1

Yang, Wen-Hua, Wen-Cai Lu, Shan-Dong Li, Xu-Yan Xue, Wei Qin, K. M. Ho, and C. Z. Wang. "Superconductivity in alkaline earth metal doped boron hydrides." Physica B: Condensed Matter 611 (June 2021): 412795. http://dx.doi.org/10.1016/j.physb.2020.412795.

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2

Shi, Xianghui, Zhizhou Liu, and Jianhua Cheng. "Research Progress of Molecular Alkaline-Earth Metal Hydrides." Chinese Journal of Organic Chemistry 39, no. 6 (2019): 1557. http://dx.doi.org/10.6023/cjoc201903043.

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3

Reckeweg, Olaf, Jay C. Molstad, Scott Levy, and Francis J. DiSalvo. "Syntheses and Crystal Structures of the New Ternary Barium Halide Hydrides Ba2H3X (X = Cl or Br)." Zeitschrift für Naturforschung B 62, no. 1 (January 1, 2007): 23–27. http://dx.doi.org/10.1515/znb-2007-0104.

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Single crystals of the isotypic hydrides Ba2H3X (X = Cl or Br) were obtained by solid-state reactions of Ba, NaCl, NaNH2 and metallic Na, or Ba, NH4Br and Na, respectively, in sealed, silicajacketed stainless-steel ampoules. The crystal structures of the new compounds were determined by means of single crystal X-ray diffraction. Ba2H3Cl and Ba2H3Br crystallize in a stuffed anti CdI2 structure and adopt the space group P3̄m1 (No. 164) with the lattice parameters a = 443.00(6), c = 723.00(14) pm and a = 444.92(4), c = 754.48(14) pm, respectively. The hydride positions are derived by crystallographic reasoning and with the help of EUTAX calculations. The results are compared with known data for binary and ternary alkaline earth metal hydrides.

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4

Kunkel, Nathalie, Holger Kohlmann, Adlane Sayede, and Michael Springborg. "Alkaline-Earth Metal Hydrides as Novel Host Lattices for EuIILuminescence." Inorganic Chemistry 50, no. 13 (July 4, 2011): 5873–75. http://dx.doi.org/10.1021/ic200801x.

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5

Yvon, Klaus, and Bernard Bertheville. "Magnesium based ternary metal hydrides containing alkali and alkaline-earth elements." Journal of Alloys and Compounds 425, no. 1-2 (November 2006): 101–8. http://dx.doi.org/10.1016/j.jallcom.2006.01.049.

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6

Zhang, Song, Lu Wang, Yun-Long Tai, Yun-Lei Teng, Juan Zhao, Wei Zhu, and Bao-Xia Dong. "Metal carbonates-induced solution-free dehydrogenation of alkaline earth metal hydrides at room temperature." Journal of Solid State Chemistry 289 (September 2020): 121485. http://dx.doi.org/10.1016/j.jssc.2020.121485.

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7

Gebreyohannes, Muez Gebregiorgis, Chernet Amente Geffe, and Pooran Singh. "Computational study of pressurized tetragonal magnesium hydride (MgH4) as a potential candidate for high-temperature superconducting material." Materials Research Express 9, no. 3 (March 1, 2022): 036001. http://dx.doi.org/10.1088/2053-1591/ac5e22.

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Abstract The dream of realizing room temperature superconductivity is one of the most challenging problems in condensed matter physics. Currently, materials with dense hydrogen contents at high pressures hold great promise for realizing room temperature superconductivity. In particular, pressurized alkaline earth metal hydrides received particular attention following the recently predicted sodalite-like calcium hydride (CaH6) with predicted Tc about 261 K above a pressure of 150 GPa; and magnesium hydride (MgH6) with predicted Tc about 270 K above 300 GPa. In this paper, we studied magnesium hydride (MgH4) with tetragonal (I4/mmm) type symmetry, and we found that this structure shows the highest T c ≅ 313 K at a pressure of 280 GPa which is higher than that of MgH6. Using density-functional perturbation theory (DFPT), the superconducting transition temperature, electron-phonon coupling, Eliashberg spectral function, and the logarithmic average frequency were computed. Our results reveal that, the computed values are reasonably in agreement with previous estimates.

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8

IVANOVIĆ, NENAD, NIKOLA NOVAKOVIĆ, DANIELE COLOGNESI, IVANA RADISAVLJEVIĆ, and STANKO OSTOJIĆ. "ELECTRONIC PRINCIPLES OF SOME TRENDS IN PROPERTIES OF METALLIC HYDRIDES." International Journal of Modern Physics B 24, no. 06n07 (March 20, 2010): 703–10. http://dx.doi.org/10.1142/s0217979210064320.

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Due to their extensive present, important and versatile potential applications, metal hydrides (MH) are among the most investigated solid-state systems. Theoretical, numerical and experimental studies have provided a considerable knowledge about their structure and properties, but in spite of that, the basic electronic principles of various interactions present in MH have not yet been completely resolved. Even in the simplest MH, i.e. alkali hydrides (Alk-H), some trends in physical properties, and especially their deviations, are not well understood. Similar doubts exist for the alkaline-earth hydride (AlkE-H) series, and are even more pronounced for complex systems, like transition metal-doped AlkE-H, alanates and borohydrides. This work is an attempt of explaining some trends in the physical properties of Alk-H and AlkE-H, employing the Bader analysis of the charge distribution topology evaluated by first-principle all-electron calculations. These results are related to some variables commonly used in the explanation of experimental and calculated results, and are also accompanied by simple tight-binding estimations. Such an approach provides a valuable insight in the characteristics of M-H and H-H interactions in these hydrides, and their possible changes along with external parameters, like temperature, pressure, defect or impurity introduction. The knowledge of these basic interactions and processes taking place in simple MH are essential for the design and optimisation of complex MH-systems interesting for practical hydrogen storage applications.

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9

Kunkel, Nathalie, Holger Kohlmann, Adlane Sayede, and Michael Springborg. "ChemInform Abstract: Alkaline-Earth Metal Hydrides as Novel Host Lattices for EuII Luminescence." ChemInform 42, no. 35 (August 4, 2011): no. http://dx.doi.org/10.1002/chin.201135009.

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10

Stavila, Vitalie. "Structural features of metal dodecahydro-closo-dodecaborates." Acta Crystallographica Section A Foundations and Advances 70, a1 (August 5, 2014): C1026. http://dx.doi.org/10.1107/s2053273314089736.

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Metal dodecahydro-closo-dodecaborates have been recently explored as materials for hydrogen storage and as promising ionic conductors. However, their utility as hydrogen storage media is impeded by their high thermal stability, kinetic limitations, and side reactions. The high thermal and chemical stability of these materials makes them interesting for solid battery membrane applications, however more work is needed to understand the complicated phase transitions which occur in many metal dodecahydro-closo-dodecaborates. Recent literature suggests that dodecahydro-closo-dodecaborate species are formed as stable intermediates during the dehydrogenation of metal borohydrides [1]. This hypothesis is especially intriguing in the context of high thermal stability reported for compounds containing icosahedral dodecahydro-closo-dodecaborate anions in the presence of hydrogen gas [2]. Here, a series of multi-component alkali, alkaline-earth and transition metal [B12H12]2- compounds were isolated and characterized by single-crystal and powder X-ray diffraction techniques. Attempts to rehydrogenate M2B12H12 and MB12H12 (where M= alkali or alkaline-earth metal) in the presence of the metal hydrides we made, and several compounds were found to be susceptible to dehydrogenation/rehydrogenation reactions. In addition, selected M2B12H12 compounds were found to display high-temperature phases with increased values of alkali metal ionic conductivity.

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11

Hrenar, Tomica, Hans-Joachim Werner, and Guntram Rauhut. "Towards accurate ab initio calculations on the vibrational modes of the alkaline earth metal hydrides." Physical Chemistry Chemical Physics 7, no. 17 (2005): 3123. http://dx.doi.org/10.1039/b508779a.

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12

Sundqvist, Bertil. "Pressure-Temperature Phase Relations in Complex Hydrides." Solid State Phenomena 150 (January 2009): 175–95. http://dx.doi.org/10.4028/www.scientific.net/ssp.150.175.

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Interest in hydrogen as a future energy carrier in mobile applications has led to a strong increase in research on the structural properties of complex alkali metal and alkaline earth hydrides, with the aim to find structural phases with higher hydrogen densities. This contribution reviews recent work on the structural properties and phase diagrams of these complex hydrides under elevated pressures, an area where rapid progress has been made over the last few years. The materials discussed in greatest detail are LiAlH4, NaAlH4, Li3AlH6, Na3AlH6, LiBH4, NaBH4, and KBH4. All of these have been studied under high pressure by various methods such as X-ray or neutron scattering, Raman spectroscopy, differential thermal analysis or thermal conductivity measurements in order to find information on their structural phase diagrams. Based mainly on experimental studies, preliminary or partial phase diagrams are also given for six of these materials. In addition to this information, data are provided also on experimental results for a number of other complex hydrides, and theoretical predictions of new phases and structures under high pressures are reviewed for several materials not yet studied experimentally under high pressure.

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13

Ali, Sharafat. "Elastic Properties and Hardness of Mixed Alkaline Earth Silicate Oxynitride Glasses." Materials 15, no. 14 (July 19, 2022): 5022. http://dx.doi.org/10.3390/ma15145022.

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The incorporation of nitrogen as a second anion species into oxide glasses offers unique opportunities for modifying glass properties via changes in glass polymerization and structure. In this work, the compositional dependence of elastic properties and the nanoindentation hardness of mixed alkaline-earth silicate oxynitride glasses containing a high amount of nitrogen (>15 at.%, c.a. 35 e/o) were investigated. Three series of silicon oxynitride glass compositions AE–Ca–Si–O–N glasses (where AE = Mg, Sr, and Ba) having varying amounts of modifiers were prepared using a new glass synthesis route, in which a precursor powder of metal hydrides was used. The obtained glasses contained high amounts of N (19 at.%, c.a. 43 e/o) and modifier cations (26 at.%, c.a. 39 e/o). Mg–Ca–Si–O–N glasses had high values of nanohardness (12–16 GPa), along with a reduced elastic modulus (130–153 GPa) and Young’s modulus (127–146 GPa), in comparison with the Sr–Ca- and Ba–Ca-bearing oxynitride glasses. Both the elastic modulus and the nanohardness of AE–Ca–Si–O–N glasses decreased with an increase in the atomic number of the AE element. These property changes followed a linear dependence on the effective cation field strength (ECFS) of the alkaline earth (AE) modifier, according to their valences and ionic radii. No mixed alkaline-earth effect was observed in the current investigation, indicating that the properties were more dictated by the nitrogen content.

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14

Yoshida, M., K. Yvon, and P. Fischer. "LiSr2PdH5, the first mixed alkali-alkaline earth transition metal hydride." Journal of Alloys and Compounds 194, no. 1 (April 1993): L11—L13. http://dx.doi.org/10.1016/0925-8388(93)90635-z.

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15

Pistidda, C., A. Santoru, S. Garroni, N. Bergemann, A. Rzeszutek, C. Horstmann, D. Thomas, T. Klassen, and M. Dornheim. "First Direct Study of the Ammonolysis Reaction in the Most Common Alkaline and Alkaline Earth Metal Hydrides by in Situ SR-PXD." Journal of Physical Chemistry C 119, no. 2 (January 6, 2015): 934–43. http://dx.doi.org/10.1021/jp510720x.

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16

Zhang, Yu, Keiji Shimoda, Hiroki Miyaoka, Takayuki Ichikawa, and Yoshitsugu Kojima. "Thermal decomposition of alkaline-earth metal hydride and ammonia borane composites." International Journal of Hydrogen Energy 35, no. 22 (November 2010): 12405–9. http://dx.doi.org/10.1016/j.ijhydene.2010.08.018.

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17

Zhao, Juan, Yin-Fan Wei, Yue-Ling Cai, Long-Zheng Wang, Ju Xie, Yun-Lei Teng, Wei Zhu, Ming Shen, and Bao-Xia Dong. "Highly Selective and Efficient Reduction of CO2 to Methane by Activated Alkaline Earth Metal Hydrides without a Catalyst." ACS Sustainable Chemistry & Engineering 7, no. 5 (February 13, 2019): 4831–41. http://dx.doi.org/10.1021/acssuschemeng.8b05177.

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18

Shi, Xianghui, Guorui Qin, Yang Wang, Lanxiao Zhao, Zhizhou Liu, and Jianhua Cheng. "Super‐Bulky Penta‐arylcyclopentadienyl Ligands: Isolation of the Full Range of Half‐Sandwich Heavy Alkaline‐Earth Metal Hydrides." Angewandte Chemie 131, no. 13 (February 19, 2019): 4400–4404. http://dx.doi.org/10.1002/ange.201814733.

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19

Shi, Xianghui, Guorui Qin, Yang Wang, Lanxiao Zhao, Zhizhou Liu, and Jianhua Cheng. "Super‐Bulky Penta‐arylcyclopentadienyl Ligands: Isolation of the Full Range of Half‐Sandwich Heavy Alkaline‐Earth Metal Hydrides." Angewandte Chemie International Edition 58, no. 13 (March 22, 2019): 4356–60. http://dx.doi.org/10.1002/anie.201814733.

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20

Colognesi, D., G. Barrera, A. J. Ramirez-Cuesta, and M. Zoppi. "Hydrogen self-dynamics in orthorhombic alkaline earth hydrides through incoherent inelastic neutron scattering." Journal of Alloys and Compounds 427, no. 1-2 (January 2007): 18–24. http://dx.doi.org/10.1016/j.jallcom.2006.03.031.

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21

YOSHIDA, M., K. YVON, and P. FISCHER. "ChemInform Abstract: LiSr2PdH5, the First Mixed Alkali-Alkaline Earth Transition Metal Hydride." ChemInform 24, no. 24 (August 20, 2010): no. http://dx.doi.org/10.1002/chin.199324032.

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22

Xu, Dongdong, Chunhui Shan, Yingzi Li, Xiaotian Qi, Xiaoling Luo, Ruopeng Bai, and Yu Lan. "Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study." Inorganic Chemistry Frontiers 4, no. 11 (2017): 1813–20. http://dx.doi.org/10.1039/c7qi00459a.

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23

Kan, Hong Min, Ning Zhang, Xiao Yang Wang, and Hong Sun. "Recent Advances in Hydrogen Storage Materials." Advanced Materials Research 512-515 (May 2012): 1438–41. http://dx.doi.org/10.4028/www.scientific.net/amr.512-515.1438.

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An overview of recent advances in hydrogen storage is presented in this review. The main focus is on metal hydrides, liquid-phase hydrogen storage material, alkaline earth metal NC/polymer composites and lithium borohydride ammoniate. Boron-nitrogen-based liquid-phase hydrogen storage material is a liquid under ambient conditions, air- and moisture-stable, recyclable and releases H2controllably and cleanly. It is not a solid material. It is easy storage and transport. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based distribution infrastructure. An air-stable composite material that consists of metallic Mg nanocrystals (NCs) in a gas-barrier polymer matrix that enables both the storage of a high density of hydrogen and rapid kinetics (loading in <30 min at 200°C). Moreover, nanostructuring of Mg provides rapid storage kinetics without using expensive heavy-metal catalysts. The Co-catalyzed lithium borohydride ammoniate, Li(NH3)4/3BH4 releases 17.8 wt% of hydrogen in the temperature range of 135 to 250 °C in a closed vessel. This is the maximum amount of dehydrogenation in all reports. These will reduce economy cost of the global transition from fossil fuels to hydrogen energy.

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24

Madern, Nicolas, Véronique Charbonnier, Judith Monnier, Junxian Zhang, Valérie Paul-Boncour, and Michel Latroche. "Investigation of H Sorption and Corrosion Properties of Sm2MnxNi7−x (0 ≤ x < 0.5) Intermetallic Compounds Forming Reversible Hydrides." Energies 13, no. 13 (July 4, 2020): 3470. http://dx.doi.org/10.3390/en13133470.

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Intermetallic compounds are key materials for energy transition as they form reversible hydrides that can be used for solid state hydrogen storage or as anodes in batteries. ABy compounds (A = Rare Earth (RE); B = transition metal; 2 < y < 5) are good candidates to fulfill the required properties for practical applications. They can be described as stacking of [AB5] and [AB2] sub-units along the c crystallographic axis. The latter sub-unit brings a larger capacity, while the former one provides a better cycling stability. However, ABy binaries do not show good enough properties for applications. Upon hydrogenation, they exhibit multiplateau behavior and poor reversibility, attributed to H-induced amorphization. These drawbacks can be overcome by chemical substitutions on the A and/or the B sites leading to stabilized reversible hydrides. The present work focuses on the pseudo-binary Sm2MnxNi7−x system (0 ≤ x < 0.5). The structural, thermodynamic and corrosion properties are analyzed and interpreted by means of X-ray diffraction, chemical analysis, scanning electron microscopy, thermogravimetric analysis and magnetic measurements. Unexpected cell parameter variations are reported and interpreted regarding possible formation of structural defects and uneven Mn distribution within the Ni sublattice. Reversible capacity is improved for x > 0.3 leading to larger and flatter isotherm curves, allowing for reversible capacity >1.4 wt %. Regarding corrosion, the binary compound corrodes in alkaline medium to form rare earth hydroxide and nanoporous nickel. As for the Mn-substituted compounds, a new corrosion product is formed in addition to those above mentioned, as manganese initiates a sacrificial anode mechanism taking place at the early corrosion stage.

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25

Mukherjee, Debabrata, Danny Schuhknecht, and Jun Okuda. "Hydrido Complexes of Calcium: A New Family of Molecular Alkaline-Earth-Metal Compounds." Angewandte Chemie International Edition 57, no. 31 (June 28, 2018): 9590–602. http://dx.doi.org/10.1002/anie.201801869.

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26

Kritikos, M., and D. Nore´us. "Synthesis and characterization of ternary alkaline-earth transition-metal hydrides containing octahedral [Ru(II)H6]4− and [Os(II)H6]4− complexes." Journal of Solid State Chemistry 93, no. 1 (July 1991): 256–62. http://dx.doi.org/10.1016/0022-4596(91)90297-u.

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27

Li, Yongtao, Fang Fang, Yun Song, Yuesheng Li, Dalin Sun, Shiyou Zheng, Leonid A. Bendersky, Qingan Zhang, Liuzhang Ouyang, and Min Zhu. "Hydrogen storage of a novel combined system of LiNH2–NaMgH3: synergistic effects of in situ formed alkali and alkaline-earth metal hydrides." Dalton Trans. 42, no. 5 (2013): 1810–19. http://dx.doi.org/10.1039/c2dt31923c.

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28

Wiesinger, Michael, Brant Maitland, Christian Färber, Gerd Ballmann, Christian Fischer, Holger Elsen, and Sjoerd Harder. "Simple Access to the Heaviest Alkaline Earth Metal Hydride: A Strongly Reducing Hydrocarbon-Soluble Barium Hydride Cluster." Angewandte Chemie 129, no. 52 (November 30, 2017): 16881–86. http://dx.doi.org/10.1002/ange.201709771.

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29

Wiesinger, Michael, Brant Maitland, Christian Färber, Gerd Ballmann, Christian Fischer, Holger Elsen, and Sjoerd Harder. "Simple Access to the Heaviest Alkaline Earth Metal Hydride: A Strongly Reducing Hydrocarbon-Soluble Barium Hydride Cluster." Angewandte Chemie International Edition 56, no. 52 (November 30, 2017): 16654–59. http://dx.doi.org/10.1002/anie.201709771.

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30

Li, Qian, Bing Xu, Tengfei Huang, Wenjie Yu, and Xuefeng Wang. "Activation of CO2 by Alkaline-Earth Metal Hydrides: Matrix Infrared Spectra and DFT Calculations of HM(O2CH) and (MH2)(HCOOH) Complexes (M = Sr, Ba)." Inorganic Chemistry 60, no. 15 (July 22, 2021): 11466–73. http://dx.doi.org/10.1021/acs.inorgchem.1c01477.

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31

Reckeweg, O., and F. J. DiSalvo. "Alkaline Earth Metal-Hydride-Iodide Compounds: Syntheses and Crystal Structures of Sr2H3I and Ba5H2I3.9(2)O2." Zeitschrift für Naturforschung B 66 (2011): 0021. http://dx.doi.org/10.5560/znb.2011.66b0021.

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32

Rudolph, Daniel, Thomas Wylezich, Atul D. Sontakke, Andries Meijerink, Philippe Goldner, Philip Netzsch, Henning A. Höppe, Nathalie Kunkel, and Thomas Schleid. "Synthesis and optical properties of the Eu2+-doped alkaline-earth metal hydride chlorides AE7H12Cl2 (AE = Ca and Sr)." Journal of Luminescence 209 (May 2019): 150–55. http://dx.doi.org/10.1016/j.jlumin.2019.01.033.

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33

Reckeweg, Olaf, and Francis J. DiSalvo. "ChemInform Abstract: Alkaline Earth Metal-Hydride-Iodide Compounds: Syntheses and Crystal Structures of Sr2H3I and Ba5H2I3.9(2)O2." ChemInform 42, no. 14 (March 14, 2011): no. http://dx.doi.org/10.1002/chin.201114015.

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34

Mukherjee, Debabrata, Thomas Höllerhage, Valeri Leich, Thomas P. Spaniol, Ulli Englert, Laurent Maron, and Jun Okuda. "The Nature of the Heavy Alkaline Earth Metal–Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster." Journal of the American Chemical Society 140, no. 9 (February 7, 2018): 3403–11. http://dx.doi.org/10.1021/jacs.7b13796.

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35

Gilson, Denis F. R., and Ralph O. Moyer. "Counterion Influence on the Vibrational Wavenumbers in Ternary and Quaternary Metal Hydride Salts, A2MH6 (A = Alkali Metal, Alkaline Earth, and Lanthanides; M = Ir, Fe, Ru, Os, Pt, Mn)." Inorganic Chemistry 51, no. 3 (January 23, 2012): 1231–32. http://dx.doi.org/10.1021/ic202534p.

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36

Gilson, Denis F. R., and Ralph O. Jr Moyer. "ChemInform Abstract: Counterion Influence on the Vibrational Wavenumbers in Ternary and Quaternary Metal Hydride Salts, A2MH6(A: Alkali Metal, Alkaline Earth, and Lanthanides; M: Ir, Fe, Ru, Os, Pt, Mn)." ChemInform 43, no. 16 (March 22, 2012): no. http://dx.doi.org/10.1002/chin.201216006.

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37

BRESE, N. E. "ChemInform Abstract: Alkaline Earth Nitrides and Hydrides." ChemInform 23, no. 3 (August 22, 2010): no. http://dx.doi.org/10.1002/chin.199203280.

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38

Okuda, Jun. "Cationic rare-earth metal hydrides." Coordination Chemistry Reviews 340 (June 2017): 2–9. http://dx.doi.org/10.1016/j.ccr.2016.09.009.

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39

Gingl, F., A. Hewat, and K. Yvon. "Orthorhombic Ba6Mg7H26: a new fluoride-related ternary alkaline earth hydride." Journal of Alloys and Compounds 253-254 (May 1997): 17–20. http://dx.doi.org/10.1016/s0925-8388(96)03005-8.

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40

Gingl, F., K. Yvon, and P. Fischer. "Strontium magnesium tetrahydride (SrMgH4): a new ternary alkaline earth hydride." Journal of Alloys and Compounds 187, no. 1 (August 1992): 105–11. http://dx.doi.org/10.1016/0925-8388(92)90526-f.

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41

Fuentealba, P., O. Reyes, H. Stoll, and H. Preuss. "Ground state properties of alkali and alkaline–earth hydrides." Journal of Chemical Physics 87, no. 9 (November 1987): 5338–45. http://dx.doi.org/10.1063/1.453653.

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42

Chapple, Peter M., Julien Cartron, Ghanem Hamdoun, Samia Kahlal, Marie Cordier, Hassan Oulyadi, Jean-François Carpentier, Jean-Yves Saillard, and Yann Sarazin. "Metal–metal bonded alkaline-earth distannyls." Chemical Science 12, no. 20 (2021): 7098–114. http://dx.doi.org/10.1039/d1sc00436k.

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The complete series of heterobimetallic alkaline-earth distannyls [Ae{SnR₃}₂·(thf)_x] (Ae = Ca, Sr, Ba) have been prepared for R = Ph and SiMe₃, and their bonding and electronic properties have been comprehensively investigated.

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43

Nafezarefi, F., H. Schreuders, B. Dam, and S. Cornelius. "Photochromism of rare-earth metal-oxy-hydrides." Applied Physics Letters 111, no. 10 (September 4, 2017): 103903. http://dx.doi.org/10.1063/1.4995081.

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44

Pedersen, A. S. "Magnesium (Beryllium) and Alkaline Earth (Calcium, Strontium and Barium) Hydrides." Solid State Phenomena 49-50 (January 1996): 35–70. http://dx.doi.org/10.4028/www.scientific.net/ssp.49-50.35.

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45

Zhang, Chao, Xiao-Jia Chen, Rui-Qin Zhang, and Hai-Qing Lin. "Chemical Trend of Pressure-Induced Metallization in Alkaline Earth Hydrides." Journal of Physical Chemistry C 114, no. 34 (August 5, 2010): 14614–17. http://dx.doi.org/10.1021/jp103968c.

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46

Gupta, M. "Electronic Structure of Hydrides Containing Alkali and Alkaline-earth Elements*." Zeitschrift für Physikalische Chemie 1, no. 1 (January 1992): 543–52. http://dx.doi.org/10.1524/zpch.1992.1.1.543.

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47

Gupta, M. "Electronic Structure of Hydrides Containing Alkali and Alkaline-earth Elements*." Zeitschrift für Physikalische Chemie 181, Part_1_2 (January 1993): 9–18. http://dx.doi.org/10.1524/zpch.1993.181.part_1_2.009.

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48

Zurek, Eva. "Hydrides of the Alkali Metals and Alkaline Earth Metals Under Pressure." Comments on Inorganic Chemistry 37, no. 2 (June 6, 2016): 78–98. http://dx.doi.org/10.1080/02603594.2016.1196679.

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Rowberg, Andrew J. E., Leigh Weston, and Chris G. Van de Walle. "Ion-Transport Engineering of Alkaline-Earth Hydrides for Hydride Electrolyte Applications." Chemistry of Materials 30, no. 17 (August 13, 2018): 5878–85. http://dx.doi.org/10.1021/acs.chemmater.8b01593.

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Blanco, Fernando, David G. Lloyd, Ibon Alkorta, and José Elguero. "Neutral Alkaline-Metal and Alkaline-Earth-Metal Derivatives of Imidazole and Benzimidazole." Journal of Physical Chemistry A 118, no. 23 (June 3, 2014): 4195–204. http://dx.doi.org/10.1021/jp502443h.

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