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Relevant bibliographies by topics / Alkali metal

Academic literature on the topic 'Alkali metal'

Author: Grafiati

Published: 4 June 2021

Last updated: 18 May 2024

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Journal articles on the topic "Alkali metal"

1

Ogihara, Wataru, Masahiro Yoshizawa, and Hiroyuki Ohno. "Novel Alkali Metal Ionic Liquids:N-Ethylimidazolium Alkali Metal Sulfates." Chemistry Letters 31, no. 9 (September 2002): 880–81. http://dx.doi.org/10.1246/cl.2002.880.

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Kiselev, A. I. "Metal-nonmetal transition in indium-alkali metal and aluminum-alkali metal melts." Russian Metallurgy (Metally) 2012, no. 2 (February 2012): 102–8. http://dx.doi.org/10.1134/s0036029512020103.

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Back, Oliver, Christoph Förster, Thomas Basché, and Katja Heinze. "Alkali Blues: Blue‐Emissive Alkali Metal Pyrrolates." Chemistry – A European Journal 25, no. 26 (March 28, 2019): 6542–52. http://dx.doi.org/10.1002/chem.201806103.

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Kubota, K., and H. Matsumoto. "Electrochemical Deposition of Alkali Metal in Low-Melting Alkali Metal Perfluorosulfonylamides." ECS Transactions 64, no. 4 (August 15, 2014): 319–22. http://dx.doi.org/10.1149/06404.0319ecst.

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Yu, Pei, Yong Shen Chua, Hujun Cao, Zhitao Xiong, Guotao Wu, and Ping Chen. "Hydrogen storage over alkali metal hydride and alkali metal hydroxide composites." Journal of Energy Chemistry 23, no. 4 (July 2014): 414–19. http://dx.doi.org/10.1016/s2095-4956(14)60166-2.

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Yang, Rui Juan, Ying Hui Wang, and Shi Quan Liu. "The Crystallization of Lithium-Iron-Phosphate Glasses Containing Alkali and Alkali-Earth Metal Oxides." Key Engineering Materials 636 (December 2014): 69–72. http://dx.doi.org/10.4028/www.scientific.net/kem.636.69.

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The crystallization activation energies and crystalline phases of lithium-iron-phosphate (LIP) glasses with alkali and alkali-earth metal oxides have been studied and compared. The results indicate that the alkali and alkali-earth metal oxides reduce the glass crystallization. Moreover, the alkali metal oxides result in the changes in the crystalline phase, while the alkali-earth metal oxides make the glass crystallization more sensitive to the thermal treatment conditions.

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Ruschewitz, Uwe. "Ternary Alkali Metal Transition Metal Acetylides." Zeitschrift für anorganische und allgemeine Chemie 632, no. 5 (April 2006): 705–19. http://dx.doi.org/10.1002/zaac.200600017.

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8

Xu, Bo, and Larry Kevan. "Formation of alkali metal particles in alkali metal cation exchanged X zeolite exposed to alkali metal vapor: control of metal particle identity." Journal of Physical Chemistry 96, no. 6 (March 1992): 2642–45. http://dx.doi.org/10.1021/j100185a046.

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9

Wu, Pengfei, Zhen Cui, Xinmei Wang, and Yingchun Ding. "Tunable optical absorption of WS2 monolayer via alkali metal modulation." Modern Physics Letters B 34, no. 10 (January 31, 2020): 2050089. http://dx.doi.org/10.1142/s021798492050089x.

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The electronic and optical absorption behaviors of alkali-metal atoms doped WS2 monolayer were systematically investigated by employing density functional theory based on first-principles calculations. The observed all alkali-metal-doped WS2 monolayer present metal behaviors, whereas the intrinsic WS2 monolayer exhibits semiconductor behavior. Charge density difference demonstrates that the large charge transfer occurs between the alkali metal and WS2 layer. The work function of WS2 can be adjusted from 5.12 eV to 5.52 eV. Importantly, the absorption spectrums of alkali-metal-doped WS2 appear with some absorption peaks at the 405 nm, 512 nm and 575 nm in the visible light range, which demonstrate the alkali-metal-doped WS2 can be used for photovoltaic and visible photocatalytic devices. Furthermore, the absorption spectrum of WS2 is generally redshifted through alkali metal doping. This indicates that alkali metal doping can broaden its application in optoelectronic devices.

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Slobodin, B. V., and L. L. Surat. "Alkali metal zinc vanadates." Russian Journal of Inorganic Chemistry 51, no. 9 (September 2006): 1345–48. http://dx.doi.org/10.1134/s0036023606090026.

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Dissertations / Theses on the topic "Alkali metal"

1

Chen, Jian. "Alkali metal cluster theory." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.305984.

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2

Robinson, Alex Lockwood. "Sonoluminescence for the quantitative analysis of alkali and alkaline earth chlorides /." Thesis, Connect to this title online; UW restricted, 2001. http://hdl.handle.net/1773/8687.

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Jones, Sally Anne. "Alkali and alkaline earth metal fluoride mediated aromoatic halogen exchange reactions." Thesis, University of Liverpool, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367085.

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Allen, Katharine M. "Intercalation chemistry of alkali metal fullerides." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390457.

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Witherow, Rebecca A. "Minor Alkaline Earth Element and Alkali Metal Behavior in Closed-Basin Lakes." The Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=osu1250628213.

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Salter, Tom E. "Infrared spectroscopy of alkali metal-solvent clusters." Thesis, University of Leicester, 2007. http://hdl.handle.net/2381/29997.

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Infrared (IR) photodepletion spectroscopy coupled with mass spectrometry has been applied in the investigation of size-specific alkali metal-solute complexes. IR spectra have been recorded in the N-H stretching region for Li(NH3)n (4 = n = 7) and Na(NH3)n (3 = n = 8) and in the N-H and C-H stretching regions for Li(NH2CH 3)n (3 = n = 5), with supporting ab initio calculations. All clusters display a red-shift of the N-H stretching modes, consistent with partial electron transfer from the nitrogen to the alkali metal atom. For Li(NH3)n, the IR spectra indicate that the first salvation shell is found to be completed with four ammonia molecules, which is in agreement with conclusions drawn from previous photoionisation studies. This finding is given credence from DFT and MP2 ab initio calculations carried out in the present work, where the lowest energy isomer for n = 4 is adopts a tetrahedral structure. The IR spectra for Na(NH3)n clusters are less definitive, but indicate a completed inner salvation shell with six ammonia molecules, a conclusion in disagreement with some previous experimental and theoretical investigations, but which is consistent with high-level ab initio calculations carried out in the present study. Ab initio investigations into the localisation of the alkali metal valence electron in the three systems determined that not only are a critical number of solvent molecule required to permit formation of a solvated electron, but also a specific geometrical configuration is required. For lithium-ammonia and sodium-ammonia clusters, formation of the solvated electron was found to coincide with an ammonia molecule entering the second salvation shell, whereas for lithium-methylamine, electron salvation was not observed for the largest cluster studied, Li(NHCH3)4.

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O'Shaughnessy, Paul. "Alkali metal complexes of phosphorus donor ligands." Thesis, University of Newcastle Upon Tyne, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323668.

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Skipper, N. "The alkali metal ions in aqueous solutions." Thesis, University of Bristol, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.379533.

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Nogueira, F. B. "Electrochemical testing of alkali metal-oxygen batteries." Thesis, University of Liverpool, 2018. http://livrepository.liverpool.ac.uk/3019388/.

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Ramsay, Donna Louise. "Alkali-metal-mediated cleave and capture chemistry." Thesis, University of Strathclyde, 2015. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=25765.

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Whilst metallation, a fundamental reaction in synthetic chemistry, is well established with mono-metallic organolithium reagents, recently a second generation of bimetallic reagents has been gathering momentum, evading some of the limitations associated with organolithium reagents. This study extends the current research in this area of synergic bimetallic chemistry and reports the synthesis and characterisation of new compounds from reactions of bases with different substrates, as well as detailed studies of the starting reagents. A new method for synthesising the utility organoamidolithium reagent LiTMP by way of a transmetallation reaction between tBuLi and Zn(TMP)₂ is described. This realised a new crystalline polymorph of LiTMP in the cyclotrimer (LiTMP)₃ 2.1. Remarkably an interrogation of the two most popular aluminating reagents “LiTMP·Al(iBu)₃” 3.1 and “LiTMP·Al(TMP)(iBu)₂” 3.2 established that 3.1 is not a single species as previously reported but in fact a complex mixture of five distinct species all in equilibria with each other. Additionally it was discovered that the modus operandi of both reagents is a two-step lithiation - trans-metaltrapping protocol, and not by direct alumination. The pharmacologically relevant amine DMPEA was studied with a range of bimetallic base mixtures. Post metallation and subsequent β-elimination the NMe₂ fragment was captured in three different crystalline compounds: [TMEDA·Na(TMP)(NMe₂)Zn(tBu)] 4.2, [PMDETA·Li(NMe₂)Zn(tBu)₂] 4.3 and [THF·Li(TMP)(NMe₂)Al(iBu)₂] 4.4. The first crystal structure where DMPEA is bonded to a metal has also been revealed in [DMPEA·Li(TMP)Zn(Me)₂] 4.5. Probing ferrocene with bimetallic mixtures afforded a range of mono- and dideprotonated products depending on the stoichiometry used. Both zincations in TMEDA·Na(μ-TMP)[μ-(C₅H₄)Fe(C₅H₅)]Zn(tBu) 5.1 and [TMEDA·Na(μ-TMP)Zn(tBu)]₂(C₅H₄)₂Fe 5.2 and aluminations in THF·Li(μ-TMP)[μ- (C5H4)Fe(C5H5)]Al(iBu)2 5.4, [THF·Li(μ-TMP)Al(iBu)2]2(C5H4)2Fe 5.5, [TMP(H)·Li(μ-TMP)Al(iBu)2]2(C5H4)2Fe 5.6 and TMP(H)·Li(TMP)[(C5H4)Fe(C5H5)]Al(iBu)2 5.7 were possible. The zinc system also provided the novel ferrocenophane type structure [{Fe(C₅H₄)₂}₂{Na₂Zn₂(tBu)₂·(THF)₆}] 5.8, as well as hints of a possible polymetallated product.

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Books on the topic "Alkali metal"

1

Jitka, Eysseltová, Dirkse T. P. 1915-, Makovicka Jiři, and Salomon M, eds. Alkali metal orthophosphates. Oxford: Pergamon, 1988.

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Jitka, Eysseltová, Dirkse T. P. 1915-, Makovic̆ka Jiřı́, and Salomon Mark, eds. Alkali metal orthophosphates. Oxford: Pergamon, 1988.

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3

Paolo, Franzosini, and International Union of Pure and Applied Chemistry., eds. Molten alkali metal alkanoates. Oxford: Pergamon, 1988.

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4

P, Bonzel H., Bradshaw A. M, Ertl G, WE-Heraeus Foundation, and Physikzentrum (Bad Honnef Germany), eds. Physics and chemistry of alkali metal adsorption. Amsterdam: Elsevier, 1989.

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5

Georgiev, Mladen. F' centers in alkali halides. Berlin: Springer-Verlag, 1988.

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6

Sigel, Astrid, Helmut Sigel, and Roland K. O. Sigel, eds. The Alkali Metal Ions: Their Role for Life. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-21756-7.

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7

Reinhold, Catherine Janey. Reduced species in alkali metal loaded framework materials. Birmingham: University of Birmingham, 2003.

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8

Gibb, G. C. Alkali metal phophates as corrosion inhibitors for aluminium. Manchester: UMIST, 1993.

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9

Happer, William. Optically pumped atoms: Alkali-metal vapors for application. Weinheim: Wiley-VCH, 2010.

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1917-, Miyamoto Hiroshi, Salomon Mark, and Scrosati Bruno, eds. Alkali metal halates, ammonium iodate and iodic acid. Oxford: Pergamon, 1987.

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Book chapters on the topic "Alkali metal"

1

Gooch, Jan W. "Alkali Metal." In Encyclopedic Dictionary of Polymers, 27. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_425.

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2

Boustani, Ihsan. "Alkali Metal Clusters." In Molecular Modelling and Synthesis of Nanomaterials, 69–111. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-32726-2_3.

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3

Yates, John T. "Alkali Metal Sources." In Experimental Innovations in Surface Science, 694–97. New York, NY: Springer New York, 1997. http://dx.doi.org/10.1007/978-1-4612-2304-7_204.

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4

Rouxel, J. "Alkali-Metal Intercalates." In Inorganic Reactions and Methods, 288–95. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145326.ch165.

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5

Scattergood, Allen, Don R. McAdams, and James P. McReynolds. "Alkali Metal Cyanates." In Inorganic Syntheses, 86–90. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch24.

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6

Ogihara, Wataru, Masahiro Yoshizawa-Fujita, and Hiroyuki Ohno. "Alkali Metal Ionic Liquids." In Electrochemical Aspects of Ionic Liquids, 317–24. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2011. http://dx.doi.org/10.1002/9781118003350.ch22.

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7

Fernandez, Richard E., and Joseph S. Thrasher. "Alkali Metal Polyhydrogen Fluorides." In ACS Symposium Series, 237–50. Washington, DC: American Chemical Society, 1994. http://dx.doi.org/10.1021/bk-1994-0555.ch014.

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Ogihara, Wataru, Masahiro Yoshizawa, and Hiroyuki Ohno. "Alkali Metal Ionic Liquid." In Electrochemical Aspects of Ionic Liquids, 259–65. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/0471762512.ch21.

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9

Shi, Hang, Yuxin Wu, Junfu Lyu, Man Zhang, and Hai Zhang. "Precipitation Characteristics of Alkali/Alkaline Earth Metal in High Alkali Coal." In Clean Coal and Sustainable Energy, 97–106. Singapore: Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-16-1657-0_7.

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Bhattacharya, Pabitra Krishna, and Prakash B. Samnani. "Alkali and Alkaline Earth Metal Ions in Biochemical Systems." In Metal Ions in Biochemistry, 63–81. 2nd edition. | Boca Raton : CRC Press, 2021. | Originally published: Metal ions in biochemistry / P.K. Bhattacharya. 2005.: CRC Press, 2020. http://dx.doi.org/10.1201/9781003108429-3.

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Conference papers on the topic "Alkali metal"

1

TOPINKOVÁ, Michaela, Jozef VLČEK, Miroslava KLÁROVÁ, Hana OVČAČÍKOVÁ, Petra MAIEROVÁ, and Veronika BLAHŮŠKOVÁ. "Modification of the hydration processes of alkali activated blast furnace slag." In METAL 2020. TANGER Ltd., 2020. http://dx.doi.org/10.37904/metal.2020.3455.

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Brown, Justin M., Colin M. Hessel, and Joel M. Hensley. "Alkali-Metal Mixture for Synthetic Alkali Vapor Density Reduction." In 2019 IEEE International Symposium on Inertial Sensors and Systems (INERTIAL). IEEE, 2019. http://dx.doi.org/10.1109/isiss.2019.8739404.

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Tran, Khanh-Quang, M. Kristiina Iisa, Britt-Marie Steenari, Oliver Lindqvist, Magnus Hagstro¨m, and Jan B. C. Pettersson. "Capture of Alkali Metals by Kaolin." In 17th International Conference on Fluidized Bed Combustion. ASMEDC, 2003. http://dx.doi.org/10.1115/fbc2003-083.

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Alkali metals present in biomass fuels may cause increased bed agglomeration during fluidized bed combustion. In worst case this may lead to complete defluidization of the bed. Other problems caused by alkali metals include increased fouling and slagging. One possibility to reduce the impact of alkali metals is to add sorbents, e.g. aluminosilicates, to the bed for the capture of alkali metals. In the current investigation, the capture of vapor phase potassium compounds by kaolin was investigated in a fixed bed reactor. The reactor consisted of an alkali metal source placed at a variable temperature from which gaseous potassium compounds were generated, a fixed bed holding the kaolin, and an on-line detector for the alkali metal concentration. The on-line alkali metal detector was based on ionization of alkali metals on hot surfaces and is capable of detecting alkali metals down to ppb levels. This makes it possible to perform experiments at alkali metal concentrations relevant to fluidized bed combustion of biomass fuels. In the experiments, KCl was used as the alkali metal source with inlet concentrations of 0.5–3.5 ppm. The experiments were performed at reactor temperatures of 800–900°C and a contact time of 0.26 s. The capture efficiencies of KCl were always above 97%. The capture efficiency was somewhat higher in oxidizing than in reducing gas atmospheres. In the oxidizing gas atmosphere, the conversion was slightly higher with H2O addition than without. The capture efficiency decreased slightly as temperature or KCl concentration was increased.

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Tarau, Calin, William G. Anderson, and Derek Beard. "Alkali Metal Heat Pipes for Kilopower." In 14th International Energy Conversion Engineering Conference. Reston, Virginia: American Institute of Aeronautics and Astronautics, 2016. http://dx.doi.org/10.2514/6.2016-4603.

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Béguin, F., L. Duclaux, K. Méténier, E. Frackowiak, J. P. Salvetat, J. Conard, S. Bonnamy, and P. Lauginie. "Alkali-metal intercalation in carbon nanotubes." In ELECTRONIC PROPERTIES OF NOVEL MATERIALS--SCIENCE AND TECHNOLOGY OF MOLECULAR NANOSTRUCTURES. ASCE, 1999. http://dx.doi.org/10.1063/1.59857.

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Reid, Robert S. "SAFE Alkali Metal Heat Pipe Reliability." In SPACE TECHNOLOGY AND APPLICATIONS INT.FORUM-STAIF 2003: Conf.on Thermophysics in Microgravity; Commercial/Civil Next Generation Space Transportation; Human Space Exploration; Symps.on Space Nuclear Power and Propulsion (20th); Space Colonization (1st). AIP, 2003. http://dx.doi.org/10.1063/1.1541285.

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POLK, J., and T. PIVIROTTO. "Alkali metal propellants for MPD thrusters." In Conference on Advanced SEI Technologies. Reston, Virigina: American Institute of Aeronautics and Astronautics, 1991. http://dx.doi.org/10.2514/6.1991-3572.

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Cattaneo, Lorena, Giorgio Longoni, Antonio Bonucci, and Stefano Tominetti. "Alkali metal sources for OLED devices." In Workshop on Building European OLED Infrastructure, edited by Thomas P. Pearsall and Jonathan Halls. SPIE, 2005. http://dx.doi.org/10.1117/12.634736.

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TKACHENKO, Serhii, Adelia KASHIMBETOVA, Pavel GEJDOŠ, Carolina OLIVER-URRUTIA, Mariano CASAS-LUNA, Martin JULIŠ, Edgar B. MONTUFAR, and Ladislav ČELKO. "Effects of the heat treatment temperature on composition, microstructure and in vitro mineralization of alkali treated titanium." In METAL 2021. TANGER Ltd., 2021. http://dx.doi.org/10.37904/metal.2021.4260.

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Salvail, Patrick G. "Alkali Metal Handling Practices at NASA MSFC." In SPACE TECHNOLOGY AND APPLICATIONS INT.FORUM-STAIF 2003: Conf.on Thermophysics in Microgravity; Commercial/Civil Next Generation Space Transportation; Human Space Exploration; Symps.on Space Nuclear Power and Propulsion (20th); Space Colonization (1st). AIP, 2003. http://dx.doi.org/10.1063/1.1541283.

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Reports on the topic "Alkali metal"

1

BREHM, W. F. Removal of Retired Alkali Metal Test Systems. Office of Scientific and Technical Information (OSTI), January 2003. http://dx.doi.org/10.2172/810103.

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Happer, William. Physics of Optically Pumped Alkali-Metal Atoms. Fort Belvoir, VA: Defense Technical Information Center, April 2013. http://dx.doi.org/10.21236/ada590923.

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Antoniak, Z. I. Two-phase alkali-metal experiments in reduced gravity. Office of Scientific and Technical Information (OSTI), June 1986. http://dx.doi.org/10.2172/5409718.

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Henning, Robert. Zintl cluster chemistry in the alkali-metal-gallium systems. Office of Scientific and Technical Information (OSTI), March 1998. http://dx.doi.org/10.2172/350829.

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Tatar, Robert C., and Richard P. Messmer. Valence Bond Cluster Studies of Alkali Metal/Semiconductor Bonding. Fort Belvoir, VA: Defense Technical Information Center, December 1986. http://dx.doi.org/10.21236/ada184276.

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Scoles, G. Spectroscopic Investigation of Alkali Metal Doped Hydrogen Helium Clusters. Fort Belvoir, VA: Defense Technical Information Center, September 2000. http://dx.doi.org/10.21236/ada383557.

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Nelson, E. J. Structural studies of alkali metal adsorption on silicon surfaces. Office of Scientific and Technical Information (OSTI), December 1999. http://dx.doi.org/10.2172/753248.

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Author, Not Given. 3718-F Alkali Metal Treatment and Storage Facility Closure Plan. Office of Scientific and Technical Information (OSTI), December 1991. http://dx.doi.org/10.2172/10191009.

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Daniel T. Schwartz, Bekki Liu, Marlina Lukman, Kavita M. Jeerage, William A. Steen, Haixia Dai, Qiuming Yu, and J. Antonio Medina. Potential Modulated Intercalation of Alkali Cations into Metal Hexacyanoferrate Coated Electrodes. Office of Scientific and Technical Information (OSTI), February 2002. http://dx.doi.org/10.2172/792792.

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Schwartz, Daniel T. Potential Modulated Intercalation Of Alkali Cations Into Metal Hexacyanoferrate Coated Electrodes. Office of Scientific and Technical Information (OSTI), June 2000. http://dx.doi.org/10.2172/828572.

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