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Relevant bibliographies by topics / Adsorption Separation

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Academic literature on the topic 'Adsorption Separation'

Author: Grafiati

Published: 4 June 2021

Last updated: 12 February 2022

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Journal articles on the topic "Adsorption Separation"

1

Banaszkiewicz, Tomasz. "The Possible Coupling of LNG Regasification Process with the TSA Method of Oxygen Separation from Atmospheric Air." Entropy 23, no. 3 (March 15, 2021): 350. http://dx.doi.org/10.3390/e23030350.

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Liquefied Natural Gas (LNG) must be vaporized before it is used in the combustion process. In most regasification terminals, energy that was previously expended to liquefy natural gas is dissipated in the environment. The paper proposes the use of the thermal effect of LNG regasification for the atmospheric air separation as a possible solution to the LNG exergy recovery problem. The presented idea is based on the coupling of the LNG regasification unit with an oxygen generator based on the Temperature Swing Adsorption (TSA) process. Theoretical analysis has revealed that it is thermodynamically justified to use the LNG enthalpy of vaporization for cooling of the TSA adsorption bed for increasing its adsorptive capacity. It has been shown that 1 kg of LNG carries enough exergy for separating up to approximately 100 g of oxygen using the TSA method. Although the paper suggests using the enthalpy of LNG vaporization for atmospheric air separation, similar processes for other gas mixture separations using the TSA method can be applied.

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Xue, Cai Long, Wen Ping Cheng, Wen Ming Hao, Jing Hong Ma, and Rui Feng Li. "CH4/N2 Adsorptive Separation on Zeolite X/AC Composites." Journal of Chemistry 2019 (January 2, 2019): 1–9. http://dx.doi.org/10.1155/2019/2078360.

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A series of zeolite X/activated carbon (AC) composites were prepared from the same starting materials at various activation time. The corresponding modified samples were obtained by being treated with diluted NH4Cl solution. The relationship between porosity development, surface properties, and CH4/N2 adsorption performance was investigated. The increase of micropore volume is beneficial to the improvement of CH4 and N2 adsorption capacity, but more sensitive for CH4. In addition, the polar functional groups of zeolite X/AC composites may enhance CH4 adsorption capacity. More importantly, both developing micropore structure and surface modification contributed to enhance the adsorption selectivity αCH4/N2. As the optimum sample of these studies, HZAC(24) showed CH4 adsorption capacity of 17.3 cm3/g and the highest adsorption selectivity αCH4/N2 of 3.4. The CH4 and N2 adsorption isotherms of all samples can be well fitted by the Langmuir–Freundlich model. HZAC(24) showed an excellent cyclability of adsorption/desorption of CH4 with a neglectable capacity loss after subsequent cycles. Moreover, HZAC(24) displayed relatively rapid adsorption kinetics. These properties of zeolite X/AC composites are essential for the adsorptive separation of CH4 from N2 in the pressure swing adsorption (PSA) process.

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DeWitt, Stephen J. A., Anshuman Sinha, Jayashree Kalyanaraman, Fengyi Zhang, Matthew J. Realff, and Ryan P. Lively. "Critical Comparison of Structured Contactors for Adsorption-Based Gas Separations." Annual Review of Chemical and Biomolecular Engineering 9, no. 1 (June 7, 2018): 129–52. http://dx.doi.org/10.1146/annurev-chembioeng-060817-084120.

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Recent advances in adsorptive gas separations have focused on the development of porous materials with high operating capacity and selectivity, useful parameters that provide early guidance during the development of new materials. Although this material-focused work is necessary to advance the state of the art in adsorption science and engineering, a substantial problem remains: how to integrate these materials into a fixed bed to efficiently utilize the separation. Structured sorbent contactors can help manage kinetic and engineering factors associated with the separation, including pressure drop, sorption enthalpy effects, and external heat integration (for temperature swing adsorption, or TSA). In this review, we discuss monoliths and fiber sorbents as the two main classes of structured sorbent contactors; recent developments in their manufacture; advantages and disadvantages of each structure relative to each other and to pellet packed beds; recent developments in system modeling; and finally, critical needs in this area of research.

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Kour, Jagjit, Puspa Lal Homagai, Megh Raj Pokhrel, and Kedar Nath Ghimire. "Adsorptive Separation of Metal Ions with Surface Modified Desmostachya bipinnata." Nepal Journal of Science and Technology 13, no. 1 (January 21, 2013): 101–6. http://dx.doi.org/10.3126/njst.v13i1.7448.

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The biomass of Desmostachy bipannata (Kush, a religious plant of Hindus) was modified for the better adsorption of metal ions from aqueous solution. The FTIR and SEM images were used for the characterization of biomass. The adsorptive separation of metal ions from aqueous solution was studied with equilibrium isotherm and kinetic model. Langmuir adsorption isotherm and pseudo second order kinetic model showed better explanation for the adsorption process. The experimental results suggest that biomass from Kush can be used as an effective biosorbent for the removal of metal ions from aqueous solution. Nepal Journal of Science and Technology Vol. 13, No. 1 (2012) 101-106 DOI: http://dx.doi.org/10.3126/njst.v13i1.7448

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Akulinin, E. I., A. A. Ishin, S. A. Skvortsov, D. S. Dvoretsky, and S. I. Dvoretsky. "Optimization of Adsorption Processes with Cyclic Variable Pressure in Gas Mixture Separation." Advanced Materials & Technologies, no. 3 (2017): 051–60. http://dx.doi.org/10.17277/amt.2017.03.pp.051-060.

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6

Helfferich, Friedrich G. "Gas separation by adsorption processes." Reactive Polymers, Ion Exchangers, Sorbents 9, no. 3 (December 1988): 301–2. http://dx.doi.org/10.1016/0167-6989(88)90256-5.

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Yang, RalphT. "Gas Separation by Adsorption Processes." Chemical Engineering Science 43, no. 4 (1988): 985. http://dx.doi.org/10.1016/0009-2509(88)80096-4.

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8

Kirkby, N. "Gas Separation by Adsorption Processes." Gas Separation & Purification 2, no. 1 (March 1988): 41. http://dx.doi.org/10.1016/0950-4214(88)80042-2.

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9

Rees, LovatV C. "Gas Separation International — Adsorption Sessions." Gas Separation & Purification 5, no. 4 (December 1991): 273. http://dx.doi.org/10.1016/0950-4214(91)80037-6.

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Rege, Salil U., Joel Padin, and Ralph T. Yang. "Olefin/paraffin separations by adsorption: π-Complexation vs. kinetic separation." AIChE Journal 44, no. 4 (April 1998): 799–809. http://dx.doi.org/10.1002/aic.690440405.

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Dissertations / Theses on the topic "Adsorption Separation"

1

Battrum, M. J. "Gas separation by adsorption." Thesis, University of Bath, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376289.

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Nassara, Ramiel. "Adsorption separation of ethyleneethane." Thesis, University of Ottawa (Canada), 2008. http://hdl.handle.net/10393/27721.

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To offset rising energy costs, it is becoming a necessity to lower energy usage within industrial processes. Such can be said for the separation of olefin/paraffin mixtures. An example of such a mixture is ethylene/ethane. This highly energy intensive industrial separation employs cryogenic distillation to achieve a high purity product. Subsequently, the energy cost to run such a system is extremely high. Hybrid scenarios have been explored, with adsorption being a potential candidate. This work studied the potential of three adsorbents for the separation of ethylene/ethane: AgNO3/SiO2, CuCl/SiO 2, and CECA 13X. AgNO3/SiO2 and CuCl/SiO 2 were both prepared in the laboratory. Pure component constant volume experiments were conducted, along with binary mixture predictions for all three adsorbents at 3 different temperatures. The expected working capacities were also calculated for the three adsorbents. Finally, an economic analysis, without taking competitive adsorption in to factor, was conducted to give a rough idea of how much a potential PSA system would cost using the three adsorbents individually. CuCl/SiO2 yielded the most favorable results of the three adsorbents, but more studies were determined necessary on the optimization of the preparation of the adsorbent. AgNO3/SiO 2 was not completely ruled out, however. Both the adsorbents showed characteristics for a potential use within industry. CECA 13X was not considered a viable candidate for such a separation.

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Hart, J. "Separation of gases by adsorption." Thesis, University of Bath, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.234617.

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Liow, J.-L. "Air separation by pressure swing adsorption." Thesis, University of Cambridge, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373659.

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Murray, John William. "Air separation by rapid pressure swing adsorption." Thesis, University of Cambridge, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627170.

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Kastrisianki-Guyton, Emma. "Dispersion, adsorption properties and separation of nanoparticles." Thesis, University of Bristol, 2015. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.683906.

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Recent years have seen a surge in interest into the properties of new materials, and their application in electronic devices. This project has used techniques common for colloidal systems in order to gain insight into these systems. The work has mainly focussed on single-walled carbon nanotubes (SWCNTs), however silicon nanowires have also briefly been studied. Pluronic block copolymers are commonly used to stabilise SWCNTs in water, most commonly F127. Such dispersions were studied using small-angle neutron scattering (SANS) experiments performed at a range of solvent contrast systems. The data were successfully fitted to a relatively simple core-shell cylinder model. Data fitting was consistent with SWCNTs present in small bundles in dispersion, with an average radius of 10 A, surrounded by a water-swollen F127 layer of 61 A thickness, with a water content of 94% in the adsorbed layer. Increasing the temperature of F127 /SWCNT /D20 systems so that they were above the critical micellisation temperature (CMT) of the polymer was seen to have only a small impact on the polymer adsorption, with the adsorbed layer thickness increasing from ~55 to 65 A, and the adsorbed amount increasing by between 50 and 100% (from ~ 1 to 1.5 mg m- 2). Dispersions of SWCNTs in surfactant mixtures of SDS and sodium cholate (SC) are often used to separate SWCNTs by electronic type. SWCNTs were dispersed with SDS and studied using small-angle scattering techniques at various contrasts. Data were fitted to a core-shell cylinder model, and the fits were consistent with small SWCNT bundles of an average radius of 10 A, surrounded by an adsorbed layer of thickness 18 A. The adsorbed amount of SDS at the SWCNT surface was calculated to be 2.5 mg m-2 , however the adsorbed amount at the SDS headgroup/water interface was calculated to be 0.85 mg m- 2 , a value closer to previously reported values for the adsorption of SDS on carbon surfaces. Subsequently, SWCNTs dispersed with SC and mixtures of SDS and SC (1:4 and 3:2 volume ratios of SDS:SC) were studied with SANS, and the dimensions of the decorated SWCNTs were not seen to vary greatly between the different surfactants studied. Finally, the separation of nanoparticles has been investigated. The separation of SWCNTs based on their electronic properties using aqueous PEG/dextran twophase polymer systems was studied. Although absorbance spectra suggested that an electronic separation of SWCNTs had occurred, the process was found to be highly irreproducible. Additionally, variations in temperature were found to have little effect on partitioning and no separation by electronic type was seen when F127-dispersed SWCNTs rather than SC-stabilised SWCNTs were used, suggesting that, unlike F127, SC adsorbs differently to SWCNTs depending on their electronic type. Silicon nanowires (SiNWs) have also been briefly studied, and separating the nanowires by length was attempted using glass bead columns, however no significant separation by length was achieved.

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Al-Damkhi, Ali M. "Separation of n-paraffins by selective adsorption." Thesis, Aston University, 1986. http://publications.aston.ac.uk/10192/.

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A study has been undertaken of the vapor-phase adsorptive separation of n-alkanes from Kuwait kerosene (Kuwait National Petroleum Company, heavy kerosene) using zeolite molecular sieves. Due to the shortage of information on the adsorption of multicomponent systems in the open literature, the present investigation was initiated to study the effect of feed flowrate, temperature, and zeolite particle size on the height of mass transfer zone (MTZ) and the dynamic capacity of the adsorbent for multicomponent n-alkanes adsorption on a fixed-bed of zeolite type-5A. The optimum operating conditions for separation of the n-alkanes has been identified so that the effluent would also be of marketable quality. The effect of multicycle adsorption-desorption stages on the dynamic behaviour of zeolite using steam as a desorbing agent has been studied and compared with n-pentane and n-hexane as desorbing agents. The separation process comprised one cycle of adsorption using a fixed-bed of zeolite type-5A. The bed was fed with vaporized kerosene until saturation had been achieved whereby the n-alkanes were adsorbed and the denormalized material eluted. The process of adsorption-desorption was carried out isobarically at one atmosphere. A mathematical model has been developed to predict the breakthrough time using the method of characteristics. The results were in a reasonable agreement with the experimental values. This model has also been utilized to develop the equilibrium isotherm. Optimum operating conditions were achieved at a feed flowrate of 33.33 x 10-9 m3/s, a temperature of 643 K, and a particle size of (1.0 - 2.0) x 10-3 m. This yielded an HMTZ value and a dynamic capacity of 0.206 m and 9.6S3 x 10-2 kg n-alkanes/kg of zeolite respectively. These data will serve as a basis for design of a commercial plant. The purity of liquid-paraffin product desorbed using steam was 83.24 wt%. The dynamic capacity was noticed to decrease sharply with the cycle number, without intermediate reactivation of zeolite, while it was kept unchanged by intermediate reactivation. Normal hexane was found to be the best desorbing agent, the efficiency of which was mounted to 88.2%.

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8

Toreci, Isil. "Adsorption separation of methyl chloride from air." Thesis, University of Ottawa (Canada), 2004. http://hdl.handle.net/10393/26784.

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In this study methyl chloride was selected as the main adsorbate since it is one of the volatile organic compounds produced largely in industry. Nitrogen was the other adsorbate since air is composed of nitrogen by 79%. As adsorbents one in-house adsorbent; SBA-15 and three commercial adsorbents; HiSiv-3000 (ZSM-5 zeolite), activated carbon cloth, mesoporous activated carbon were used. Experiments of constant volume technique were performed in order to obtain adsorption isotherms of methyl chloride and nitrogen with the adsorbents mentioned above up to 1.6 arm in the temperature range of 21.5 and 80°C. Langmuir, Freundlich, Sips and Toth isotherm models were fitted to these isotherms. By using the Toth isotherm parameters adsorption isosteres were obtained. Henry's Law constants and heat of adsorption values were calculated. Expected working capacities for pressure swing adsorption (PSA), vacuum swing adsorption (VSA), temperature swing adsorption (TSA) were obtained and feasibility of these processes was discussed. The binary system behavior was also predicted for HiSiv-3000 and SBA-15 by using Extended Langmuir and Ideal Adsorbed Solution models. Methyl chloride adsorption breakthrough curves with HiSiv-3000 and SBA-15 for vacuum swing adsorption application was produced. The effects of modeling parameters such as temperature, inlet concentration, flow rate and bed length were investigated. It was concluded that mesocarbon is the best adsorbent to separate methyl chloride from air. Carbon cloth has the lowest heat of adsorption for methyl chloride. Prediction of binary system behavior showed that nitrogen adsorption is negligible. Mesocarbon shows the highest expected working capacities for PSA, VSA and TSA. VSA and TSA were found to be two promising processes for separation of methyl chloride from air. (Abstract shortened by UMI.)

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9

Bessho, Naoki. "Advanced pressure swing adsorption system with fiber sorbents for hydrogen recovery." Diss., Georgia Institute of Technology, 2010. http://hdl.handle.net/1853/42822.

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A new concept of a "fiber sorbent" has been investigated. The fiber sorbent is produced as a pseudo-monolithic material comprising polymer (cellulose acetate, CA) and zeolite (NaY) by applying hollow fiber spinning technology. Phase separation of the polymer solution provides an appropriately porous structure throughout the fiber matrix. In addition, the zeolite crystals are homogeneously dispersed in the polymer matrix with high loading. The zeolite is the main contributor to sorption capacity of the fiber sorbent. Mass transfer processes in the fiber sorbent module are analyzed for hydrogen recovery and compared with results for an equivalent size packed bed with identical diameter and length. The model indicates advantageous cases for application of fiber sorbent module over packed bed technology that allows system downsizing and energy saving by changing the outer and bore diameters to maintain or even reduce the pressure drop. The CA-NaY fiber sorbent was spun successfully with highly porous structure and high CO2 sorption capacity. The fiber sorbent enables the shell-side void space for thermal moderation to heat of adsorption, while this cannot be applied to the packed bed. The poly(vinyl alcohol) coated CA-NaY demonstrated the thermal moderation with paraffin wax, which was carefully selected and melt at slightly above operating temperature, in the shell-side in a rapidly cycled pressure swing adsorption. So this new approach is attractive for some hydrogen recovery applications as an alternative to traditional zeolite pellets.

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Armstrong, Jayne. "Gas adsorption and separation properties of porous material." Thesis, University of Newcastle upon Tyne, 2013. http://hdl.handle.net/10443/2119.

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The development of new porous materials for use in applications such as gas storage and separation processes, catalysis, catalysts supports and the removal of environmentally unfriendly species has increased rapidly over the past decade. Research into the development of these new materials has been dominated by metal organic frameworks, covalent organic frameworks, nanoporous polymers and, most recently, porous organic cage molecules. This thesis describes adsorption studies of a metal organic framework, Zn (TBAPy) and a porous tetrahedral organic cage molecule of ~ 1 nm diameter formed by the condensation reaction of 1,3,5- triformylbenzene with 1,2-ethylenediamine. The development of metal organic frameworks has traditionally involved the formation of rigid network structures, analogous to that of zeolites. More recently the focus has shifted to those of dynamic, flexible framework materials, and the response of these materials to adsorption of gases and vapours. The metal organic framework Zn (TBAPy) is based on a zinc metal centre functionalised with benzoate fragments. The initial two-dimensional structure undergoes rearrangement of the paddlewheel units to form a 3D framework, Zn (TBAPy)' upon desolvation. The ability of this 3D network to separate p-xylene and m-xylene was investigated. It was found that these isomers produced different effects on the framework, with p-xylene producing a typical Type I isotherm, whereas m-xylene induced a structural change within the material, with a much slower rate of m-xylene adsorption at higher pressures. This could potentially lead to the equilibrium separation of these two isomers by the metal organic framework Zn (TBAPy)'. The 1 nm diameter tetrahedral cage molecules formed by the condensation reaction of 1,3,5-triformylbenzene with 1,2-ethylenediamine can exist in a number of stable polymorphs, Cage 1α, Cage 1β and Cage 1γ. These polymorphs can be interconverted by exposure to certain organic vapours/solvents. The conversion of Cage 1β to Cage 1α by adsorption of probe molecules ethyl acetate, 2-butanone, diethyl ether, pentane and methanol was studied. Adsorption of ethyl acetate, 2- butanone and diethyl ether produced unusual adsorption isotherms, which included desorption of adsorbed vapour with increasing pressure during the adsorption isotherms. This desorption is attributed to the structural change from Cage 1β to Cage 1α. The unusual desorption step is not observed for methanol or pentane adsorption. The adsorption of methyl acetate was studied over a wide temperature range in order to assess the thermodynamic and kinetic characteristics of the unusual desorption step. The adsorption of dichloromethane showed the reverse transformation of Cage 1α to Cage 1β, showing that the inter conversion produces stable polymorphs. The kinetics of the structural transformation followed an Avrami model and the mechanism is an activated process. Cage 1α has voids between the cages, which are connected by very narrow constrictions that allow the kinetic molecular sieving of oxygen, carbon dioxide and nitrogen. It was found that oxygen adsorbs approximately ten times faster than nitrogen on Cage 1α, with selectivity and rate constants similar to those observed for carbon molecular sieves. The thermodynamics and kinetic results are discussed in terms of structural characteristics and diffusion into molecular cage materials. The kinetic molecular sieving is not present in the polymorph Cage 1β, which has wider pores.

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Books on the topic "Adsorption Separation"

1

Gas separation by adsorption processes. London: Imperial College Press, 1997.

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Yang, R. T. Gas separation by adsorption processes. Singapore: World Scientific, 1997.

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Yang, R. T. Gas separation by adsorption processes. Boston: Butterworths, 1987.

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Al-Damkhi, Ali Mohammed. Separation of n-paraffins by selective adsorption. Birmingham: Aston University. Department of Chemical Engineering, 1986.

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Takeuchi, Yasushi. Kyūchakuzai no kaishitsu to bunri sōsa e no ōyō ni kansuru kenkyū. Kawasaki-shi: Meiji Daigaku Kagaku Gijutsu Kenkyūjo, 1993.

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Valencia, Susana, and Fernando Rey, eds. New Developments in Adsorption/Separation of Small Molecules by Zeolites. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-63853-5.

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Tsai, Huimin. Separation of nickel from aqueous solution by adsorption onto fungal biomass. Manchester: UMIST, 1995.

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Zee, Gerard van. Counter current sorption using fiber sorbents: A novel separation technique for water purification in power and space efficient equipment. Delft, Netherlands: Delft University Press, 1996.

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International Institute of Refrigeration. Commission A3. Comparaison avec la cryogénie des procédés PSA et membranes pour la séparation des gaz industriels: Compte rendu de la réunion de la Commission A3 = Comparison between cryogenics and PSA and membrane processes for industrial gas separation : proceedings of the meeting of Commission A3, October 24-25, 1989. Paris, France: Institut international du froid, 1989.

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Al-Zaid, Khairya Ali. The adsorptive separation of aromatic hydrocarbon mixtures. Birmingham: Aston University. Department of Chemical Engineering, 1987.

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Book chapters on the topic "Adsorption Separation"

1

Venkatesan, Saravanan. "Adsorption." In Separation and Purification Technologies in Biorefineries, 101–48. Chichester, UK: John Wiley & Sons, Ltd, 2013. http://dx.doi.org/10.1002/9781118493441.ch5.

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Mersmann, Alfons, Matthias Kind, and Johann Stichlmair. "Adsorption, Chromatography, Ion Exchange." In Thermal Separation Technology, 483–560. Berlin, Heidelberg: Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-12525-6_9.

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Mollerup, Jørgen M. "Adsorption Isotherms." In Preparative Chromatography for Separation of Proteins, 11–79. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2017. http://dx.doi.org/10.1002/9781119031116.ch2.

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Storti, Giuseppe, Maurizio Masi, and Massimo Morbidelli. "On Countercurrent Adsorption Separation Processes." In Adsorption: Science and Technology, 357–81. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-2263-1_19.

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Grevillot, Georges. "Separation Processes Based on Electrosorption Phenomena." In Adsorption: Science and Technology, 193–221. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-2263-1_11.

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Kommu, Anitha, and Jayant K. Singh. "Graphene Nanopores-Based Separation of Impurities from Aqueous Medium." In Aqueous Phase Adsorption, 43–68. Boca Raton : Taylor & Francis, CRC Press, 2019.: CRC Press, 2018. http://dx.doi.org/10.1201/9781351272520-2.

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Scopes, Robert K. "Separation by Adsorption—Affinity Techniques." In Protein Purification, 187–237. New York, NY: Springer New York, 1994. http://dx.doi.org/10.1007/978-1-4757-2333-5_7.

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Barker, P. E., and G. Ganetsos. "Biochemical Reaction and Separation in Chromatographic Columns." In Adsorption: Science and Technology, 491–504. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-2263-1_25.

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Gupta, Krishna M., and Jianwen Jiang. "Aqueous Separation in Metal-Organic Frameworks: From Experiments to Simulations." In Aqueous Phase Adsorption, 111–34. Boca Raton : Taylor & Francis, CRC Press, 2019.: CRC Press, 2018. http://dx.doi.org/10.1201/9781351272520-4.

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Scopes, Robert K. "Separation by Adsorption I: General Principles." In Protein Purification, 102–45. New York, NY: Springer New York, 1994. http://dx.doi.org/10.1007/978-1-4757-2333-5_5.

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Conference papers on the topic "Adsorption Separation"

1

SIRCAR, SHIVAJI. "ADSORPTION TECHNOLOGY FOR GAS SEPARATION." In Proceedings of the Third Pacific Basin Conference. WORLD SCIENTIFIC, 2003. http://dx.doi.org/10.1142/9789812704320_0009.

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DA SILVA, FRANCISCO A., and ALÍRIO E. RODRIGUES. "PROPYLENE/PROPANE SEPARATION BY PRESSURE SWING ADSORPTION." In Proceedings of the Second Pacific Basin Conference. WORLD SCIENTIFIC, 2000. http://dx.doi.org/10.1142/9789812793331_0107.

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Mimura, Hitoshi, Minoru Matsukura, Fumio Kurosaki, Tomoya Kitagawa, Akira Kirishima, and Nobuaki Sato. "Multi-Nuclide Separation Using Different Types of Zeolites." In 2017 25th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/icone25-66611.

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Development of selective adsorbents is very important subject for the effective multi-nuclide decontamination related to the severe accident of Fukushima Daiichi Nuclear power Station (Fukushima NPS). In this study, the adsorption properties for nine kinds of zeolites (Zeolite A, Zeolite X, Zeolite Y, Zeolite L, Modified Chabazite, Phillipsite, Erionite, Synthetic Mordenite, Natural Mordenite and Clinoptilolite) are evaluated in the presence of sodium salts, boric acid and seawater. The present study deals with (1) selective adsorption properties for single nuclide ions (Cs+, Sr2+, Eu3+, I−, UO22+, Am3+ and NpO2+), and (2) multi-nuclide adsorption properties of 26 elements (typical elements in Advanced Liquid Processing System (ALPS) in Fukushima NPP-1) for the above zeolites. The distribution coefficient (Kd, ml/g) and uptake (R, %) were estimated by batch method using NaI (Tl) scintillation counter, ICP-AES and AAS. Zeolites with different crystal structures have the diversity of the adsorption selectivity for various radioactive nuclides. Chabazite, mordenite and clinoptilolite with lantern or tunnel structure were very effective for the adsorption of monovalent Cs+ ions even in real seawater. Zeolite A and X with three-dimensional cage structures were effective for the adsorption of divalent Sr2+ and Co2+ ions under the practical condition (30% diluted seawater). Zeolite L was effective for the adsorption of Eu3+ ions under the practical condition. As for I− adsorption, Ag-zeolites are found to be effective, and the uptake (%) of I− (NaI in pure water) for Ag-zeolites was estimated to be above 98% in pure water. As for actinoid adsorption, the distribution profile, Kdvs pH, had a maximum depending on the hydrolysis pH. Zeolite A, Zeolite L and Zeolite X showed an excellent adsorption property for UO22+, Am3+ and NpO2+, respectively. Selective adsorption tendencies of different zeolites were evaluated for 26 elements referred to ALPS. Comparing the uptake results for different zeolites, the following tendency of adsorbability was observed. Mordenite had adsorption selectivity for monovalent alkali metal ions of Rb+ and Cs+. Zeolite A and X exhibited relatively high adsorption selectivity for divalent ions of Sr2+ and Co2+. Zeolite L had adsorption selectivity for trivalent lanthanide ions such as Ce3+ and Eu3+. These tendencies were the same as those without boric acid. Thus, the zeolites with diverse adsorption selectivity are effective for the multi-nuclide decontamination of radioactive contaminated water.

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Yusop, Mohamad Firdaus Mohamad, Mohd Azmier Ahmad, Nasehir Khan E. M. Yahaya, Jamilah Karim, Muhammad Azroie Mohamed Yusoff, Noor Haza Fazlin Hashim, and Nor Salmi Abdullah. "Effect Bed Height on Adsorption of Cu(II) by Using Corncob Based Activated Carbon." In Third International Conference on Separation Technology 2020 (ICoST 2020). Paris, France: Atlantis Press, 2020. http://dx.doi.org/10.2991/aer.k.201229.023.

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5

Akulinin, Е. I., D. S. Dvoretsky, О. О. Golubyatnikov, S. I. Dvoretsky, and S. A. Skvortsov. "Optimizing cycles of adsorption separation of gas mixtures." In International Conference "Actual Issues of Mechanical Engineering" (AIME 2018). Paris, France: Atlantis Press, 2018. http://dx.doi.org/10.2991/aime-18.2018.3.

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6

MOTA, J. P. B. "MOLECULAR SIMULATION OF GAS SEPARATION BY ADSORPTION PROCESSES." In Proceedings of the Third Pacific Basin Conference. WORLD SCIENTIFIC, 2003. http://dx.doi.org/10.1142/9789812704320_0051.

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7

Nasarudin, Amir Asyraf, Norzita Ngadi, Noorhalieza Ali, Roshanida A. Rahman, Aziatul Niza Sadikin, and Nor Adha Omar. "Screening Factors Influencing Adsorption of Methylene Blue Aqueous Solution Onto Immobilized Glycerine Pitch/Sodium Alginate Beads." In Third International Conference on Separation Technology 2020 (ICoST 2020). Paris, France: Atlantis Press, 2020. http://dx.doi.org/10.2991/aer.k.201229.016.

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8

Gao, Ting, Wensheng Lin, Anzhong Gu, and Min Gu. "CBM Liquefaction Processes Integrated With Adsorption Separation of Nitrogen." In ASME 2008 2nd International Conference on Energy Sustainability collocated with the Heat Transfer, Fluids Engineering, and 3rd Energy Nanotechnology Conferences. ASMEDC, 2008. http://dx.doi.org/10.1115/es2008-54040.

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Coalbed methane (CBM) is a kind of important energy resources in the world. Liquefaction is a good option for recovery of CBM. Generally, CBM consists of a lot of nitrogen besides methane, which is usually required to be separated by adsorption before liquefaction, or by distillation after liquefaction. For the CBM adsorption-liquefaction processes, two novel processes are proposed, which integrate the two parts of adsorption and liquefaction together by utilizing the residue pressure of the waste nitrogen: the released nitrogen expanded directly to precool CBM, or further compressed and then expanded to liquefy CBM. Taking the unit product liquefaction power consumption as the major index and nitrogen content of CBM feed gas together with residue pressure of waste nitrogen as variables, the system performance of these two integrated processes is studied and compared with that of the nitrogen expansion liquefaction process without integration. By simulation and calculation with HYSYS, it is confirmed that system power consumption can be reduced by both methods to utilize the residue pressure, and for CBM with high nitrogen content, the energy conservation effect is considerable, furthermore, it is better to use waste nitrogen to precool CBM than to liquefy it.

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JIN, XU, and S. FAROOQ. "SEPARATION OF OXYGEN-ARGON MIXTURE BY PRESSURE SWING ADSORPTION." In Proceedings of the Third Pacific Basin Conference. WORLD SCIENTIFIC, 2003. http://dx.doi.org/10.1142/9789812704320_0060.

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XIE, Y. C., J. ZHANG, Y. GENG, W. TANG, and X. Z. Tong. "LARGE SCALE CO SEPARATION BY VPSA USING CUCL/ZEOLITE ADSORBENT." In Selected Reports at the 4th Pacific Basin Conference on Adsorption Science and Technology. WORLD SCIENTIFIC, 2007. http://dx.doi.org/10.1142/9789812770264_0018.

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Reports on the topic "Adsorption Separation"

1

Veronica J. Rutledge. Adsorption Model for Off-Gas Separation. Office of Scientific and Technical Information (OSTI), March 2011. http://dx.doi.org/10.2172/1017866.

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2

Yang, Ralph T. AIR SEPARATION BY PRESSURE SWING ADSORPTION USING SUPERIOR ADSORBENTS. Office of Scientific and Technical Information (OSTI), August 2001. http://dx.doi.org/10.2172/789503.

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3

Allendorf, Mark D., Joseph C. Sanders, and Jeffery A. Greathouse. Computational investigation of noble gas adsorption and separation by nanoporous materials. Office of Scientific and Technical Information (OSTI), October 2008. http://dx.doi.org/10.2172/943323.

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Benjamin, M. M. Adsorption/Membrane Filtration as a Contaminant Concentration and Separation Process for Mixed Wastes and Tank Wastes - Final Report. Office of Scientific and Technical Information (OSTI), October 1999. http://dx.doi.org/10.2172/775428.

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Gu, B., and K. E. Dowlen. An investigation of groundwater organics, soil minerals, and activated carbon on the complexation, adsorption, and separation of technetium-99. Office of Scientific and Technical Information (OSTI), January 1996. http://dx.doi.org/10.2172/219315.

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Benjamin, M. M. Adsorption/membrane filtration as a contaminant concentration and separation process for mixed wastes and tank wastes. Progress report, 1996--1997. Office of Scientific and Technical Information (OSTI), January 1997. http://dx.doi.org/10.2172/13440.

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Benjamin, M. M., and G. Korshin. Adsorption/membrane filtration as a contaminant concentration and separation process for mixed wastes and tank wastes. 1998 annual progress report. Office of Scientific and Technical Information (OSTI), June 1998. http://dx.doi.org/10.2172/13441.

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Ghosh, Tushar, Sudarsha Loyalka, Mark Prelas, and Dabir Viswanath. Adsorptive Separation and Sequestration of Krypton, I and C14 on Diamond Nanoparticles. Office of Scientific and Technical Information (OSTI), March 2015. http://dx.doi.org/10.2172/1178432.

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