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Journal articles on the topic 'Activity /osmotic coefficients'

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Author: Grafiati

Published: 10 December 2022

Last updated: 28 January 2023

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1

Castellanos, Miguel A., Mercedes Caceres, and Javier Nunez. "Osmotic and activity coefficients of some cobaltammine salts." Journal of Chemical & Engineering Data 30, no. 3 (July 1985): 344–49. http://dx.doi.org/10.1021/je00041a033.

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2

Ding-Quan, Wu, Xu Zheng-Liang, and Qu Song-Sheng. "The Activity Coefficients and Osmotic Coefficients of Sodium Tungstate in Aqueous Solution." Acta Physico-Chimica Sinica 6, no. 05 (1990): 633–37. http://dx.doi.org/10.3866/pku.whxb19900523.

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3

Passamonti, Francisco J., María R. Gennero de Chialvo, and Abel C. Chialvo. "Evaluation of the activity coefficients of ternary molecular solutions from osmotic coefficient data." Fluid Phase Equilibria 559 (August 2022): 113464. http://dx.doi.org/10.1016/j.fluid.2022.113464.

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4

Duignan, Timothy T., and X. S. Zhao. "Prediction of the Osmotic/Activity Coefficients of Alkali Hydroxide Electrolytes." Industrial & Engineering Chemistry Research 60, no. 41 (October 6, 2021): 14948–54. http://dx.doi.org/10.1021/acs.iecr.1c02950.

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5

Lyubartsev, Alexander P., and Aatto Laaksonen. "Osmotic and activity coefficients from effective potentials for hydrated ions." Physical Review E 55, no. 5 (May 1, 1997): 5689–96. http://dx.doi.org/10.1103/physreve.55.5689.

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6

Attwood, D., N. A. Dickinson, V. Mosquera, and V. Perez Villar. "Osmotic and activity coefficients of amphiphilic drugs in aqueous solution." Journal of Physical Chemistry 91, no. 15 (July 1987): 4203–6. http://dx.doi.org/10.1021/j100299a050.

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7

Apelblat, Alexander. "Activity and osmotic coefficients in electrolyte solutions at elevated temperatures." AIChE Journal 39, no. 5 (May 1993): 918–23. http://dx.doi.org/10.1002/aic.690390523.

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8

Tsurko, Elena N., Roland Neueder, Rainer Müller, and Werner Kunz. "Osmotic Coefficients and Activity Coefficients in Aqueous Aminoethanoic Acid–NaCl Mixtures at 298.15 K." Journal of Chemical & Engineering Data 59, no. 9 (August 19, 2014): 2741–49. http://dx.doi.org/10.1021/je500271z.

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9

Sergievskii, V. V., and A. M. Rudakov. "Dependence of the osmotic coefficients and average ionic activity coefficients on hydrophobic hydration in solutions." Russian Journal of Physical Chemistry A 90, no. 8 (July 21, 2016): 1567–73. http://dx.doi.org/10.1134/s003602441607027x.

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10

Wu, Dingquan, Songsheng Qu, and Zhengliang Xu. "Isopiestic activity coefficients and osmotic coefficients of sodium molybdate and sodium tungstate in aqueous solution." Journal of Chemical Thermodynamics 22, no. 1 (January 1990): 35–39. http://dx.doi.org/10.1016/0021-9614(90)90028-o.

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11

Zavitsas, Andreas A. "Properties of aqueous solutions. A treatise against osmotic and activity coefficients." Journal of Molecular Liquids 348 (February 2022): 118410. http://dx.doi.org/10.1016/j.molliq.2021.118410.

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12

Baes, C. F., and Bruce A. Moyer. "ESTIMATING ACTIVITY AND OSMOTIC COEFFICIENTS IN UO2(NO3)2- HNO3- NaNO3MIXTURES." Solvent Extraction and Ion Exchange 6, no. 4 (January 1988): 675–97. http://dx.doi.org/10.1080/07366298808917960.

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13

Manohar, S., and J. Ananthaswamy. "Activity coefficients of NaCl in NaCl–NaOAc–H2O at 25, 35, and 45 °C." Canadian Journal of Chemistry 69, no. 1 (January 1, 1991): 111–15. http://dx.doi.org/10.1139/v91-018.

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The activity coefficients of NaCl were estimated by measuring the EMFs of the cell[Formula: see text]at four ionic strengths, i.e., 0.5, 1.0, 2.0, and 3.0 mol/kg and at temperatures 25, 35, and 45 °C. The results were analyzed in terms of Harned's rule, the Pitzer and Rush–Johnson–Scatchard treatments. Osmotic coefficients and excess free energies of mixing were calculated at all ionic strengths and temperatures studied. Key words: activity coefficients, sodium chloride, sodium acetate, Pitzer formalism, Scatchard equation.

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14

Partanen, Jaakko Ilmari, Pentti Olavi Minkkinen, Julius Glaser, Imre Tóth, Susan Jagner, Daniel R. Carcanague, Ito Chao, and K. N. Houk. "Activity and Osmotic Coefficients of Dilute Potassium Chloride Solutions at 273 K." Acta Chemica Scandinavica 46 (1992): 116–21. http://dx.doi.org/10.3891/acta.chem.scand.46-0116.

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15

Baabor, J., M. A. Gilchrist, and E. J. Delgado. "Osmotic and activity coefficients of aqueous lithium sulfate solutions at 40�C." Journal of Solution Chemistry 25, no. 11 (November 1996): 1105–11. http://dx.doi.org/10.1007/bf00972925.

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16

Partanen, Jaakko I., and Pentti O. Minkkinen. "Activity and osmotic coefficients of dilute sodium chloride solutions at 273 K." Journal of Chemical & Engineering Data 36, no. 4 (October 1991): 432–35. http://dx.doi.org/10.1021/je00004a026.

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17

Passamonti, Francisco J., María R. Gennero de Chialvo, and Abel C. Chialvo. "Alternative formalism for the evaluation of the activity coefficients on ternary electrolyte solutions from osmotic coefficient data." Fluid Phase Equilibria 547 (November 2021): 113169. http://dx.doi.org/10.1016/j.fluid.2021.113169.

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18

Venkateswarlu, Ch, and J. Ananthaswamy. "Thermodynamics of electrolyte solutions: activity coefficients of NaCl in the NaCl–NiCl2–H2O system at 25, 35, and 45 °C." Canadian Journal of Chemistry 68, no. 2 (February 1, 1990): 294–97. http://dx.doi.org/10.1139/v90-040.

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The activity coefficients of NaCl in the NaCl–NiCl2–H2O system were estimated at 25, 35, and 45 °C and total ionic strengths of 0.5, 1.0, 2.0, and 3.0 m by an EMF method using a Na-ion selective electrode and a silver–silver chloride reference electrode. The Harned coefficients were calculated at all the temperatures studied. At 25 °C the data were analysed using the Pitzer formalism. The osmotic coefficients and the excess free energies of mixing were also calculated at 25 °C. Keywords: activity coefficients, sodium chloride, nickel chloride, Pitzer equations, thermodynamics.

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19

Miladinović, Jelena, Rozalija Ninković, Milica Todorović, and Joseph A. Rard. "Isopiestic Investigation of the Osmotic and Activity Coefficients of {yMgCl2+(1−y)MgSO4}(aq) and the Osmotic Coefficients of Na2SO4⋅MgSO4(aq) at 298.15 K." Journal of Solution Chemistry 37, no. 3 (January 18, 2008): 307–29. http://dx.doi.org/10.1007/s10953-007-9238-y.

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20

Mukherjee, Lal M., and Roger G. Bates. "Osmotic and activity coefficients at 25°C for tetraalkylammonium bromides in deuterium oxide." Journal of Solution Chemistry 14, no. 4 (April 1985): 255–62. http://dx.doi.org/10.1007/bf00644457.

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21

Xin, Nan, Yanjun Sun, Clayton J. Radke, and John M. Prausnitz. "Osmotic and activity coefficients for five lithium salts in three non–aqueous solvents." Journal of Chemical Thermodynamics 132 (May 2019): 83–92. http://dx.doi.org/10.1016/j.jct.2018.12.016.

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22

Macaskill, J. B., and Roger G. Bates. "Osmotic and activity coefficients of monomethyl-, dimethyl-, and trimethylammonium chlorides at 25�C." Journal of Solution Chemistry 15, no. 4 (April 1986): 323–30. http://dx.doi.org/10.1007/bf00648886.

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23

Messnaoui, Brahim, Abdelfetah Mounir, Abderrahim Dinane, Abderrahim Samaouali, and Bahija Mounir. "Determination of water activity, osmotic coefficients, activity coefficients, solubility and excess Gibbs free energies of NaCl-sucrose-H2O mixture at 298.15 K." Journal of Molecular Liquids 284 (June 2019): 492–501. http://dx.doi.org/10.1016/j.molliq.2019.03.156.

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24

Bates, Roger G., and J. B. Macaskill. "Activity and osmotic coefficients oft-butylammonium chloride; Activity coefficients of HCl in mixtures with tris hydrochloride ort-butylammonium chloride at 25�C." Journal of Solution Chemistry 14, no. 10 (October 1985): 723–34. http://dx.doi.org/10.1007/bf00647688.

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25

Filipovic, Vladimir, Ljubinko Levic, Biljana Curcic, Milica Nicetin, Lato Pezo, and Nevena Misljenovic. "Optimisation of mass transfer kinetics during osmotic dehydration of pork meat cubes in complex osmotic solution." Chemical Industry and Chemical Engineering Quarterly 20, no. 3 (2014): 305–14. http://dx.doi.org/10.2298/ciceq120511012f.

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This paper presents the effects of different process temperature (20, 35 and 50 ?C), immersion time (1, 3 and 5 hours) and the concentration of sugar beet molasses + NaCl + sucrose water solution on osmotic dehydration of pork meat (M. triceps brachii) cubes, shaped 1 x 1 x 1 cm, at atmospheric pressure. The main objective was to examine the influence of different parameters on the mass transfer kinetics during osmotic treatment. The observed system?s responses were: water loss, solid gain, and water activity. The optimum osmotic conditions (temperature of 40 ?C, treatment time of 4.1 h and concentration 67 %), were determined using response surface method, by superimposing the contour plots of each process variable, and the responses were: water loss=0.46, solid gain=0.15, and water activity=0.79. Transport coefficients, for both solids and water transfer and energy of activation for all samples were also determined.

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26

Ninkovic, Rozalija, Milica Todorovic, and Jelena Miladinovic. "Mathematical model for exergy in the system NaCl-H2O." Chemical Industry 58, no. 1 (2004): 1–5. http://dx.doi.org/10.2298/hemind0401001n.

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In this work mathematical models for the exergy and relative enthalpy of the water solution of sodium-chloride and the pure crystalline sodium-chloride where derived. The environment was defined with the temperature 20 ?C, pressure 101,325 kPa and with liquid water and crystalline sodium-chloride, both having at the defined environmental conditions the value of exergy equal zero. The obtained mathematical model is valid in the temperature interval from 0 to 170?C and for the all compositions of solution, until to saturation. The derived mathematical model for the exergy is based on the Pitzer's ion interaction equation which satisfactory represents the dependence of the osmotic coefficient and the mean ionic activity coefficient on the composition of solution. The calculated values of exergy using the mathematical model were compared with the appropriate diagram for the exergy constructed using the table values of activity coefficients, osmotic coefficients and partial molar enthalpies.

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27

Donchev, Stanislav, Tsvetan V. Tsenov, and Christomir Christov. "Chemical and geochemical modeling. Thermodynamic models for binary fluoride systems from low to very high concentration (> 35 m) at 298.15 K." Acta Scientifica Naturalis 8, no. 2 (July 1, 2021): 1–15. http://dx.doi.org/10.2478/asn-2021-0014.

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Abstract In this study we developed well validated thermodynamic models for solution behavior and solid-liquid equilibrium for all fluoride binary systems, for which activity data are available. The subject of modeling study are 5 fluoride systems of the type 1-1 (HF-H2O, NaF-H2O, KF-H2O, RbF-H2O, and CsF-H2O) and one of 1-2 type (H2SiF6-H2O) from low to very high concentration at 298.15 K. Models are developed on the basis of Pitzer ion interactions approach. The recommendations on mean activity coefficients (γ±) have been used to construct the model for HF-H2O system. To parameterize models for all other 5 binary systems we used all available raw experimental osmotic coefficients data (φ) for whole concentration range of solutions, and up to saturation point. The predictions of new developed here models are in excellent agreement with experimental osmotic coefficients data, and with recommendations on activity coefficients in binary solutions from low to very high concentration: up to 20 mol. kg−1 in HF-H2O, and up to 35.6 mol.kg−1 in CsF-H2O. The Deliquescence Relative Humidity (DRH (%)) and thermodynamic solubility products (as ln Ko sp) of 4 solid phases [NaF(s), KF.2H2O(s), RbF(s), and CsF(s)] have been determined on the basis of evaluated model parameters and using experimental m(sat) solubility data.

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28

Rard, Joseph A., and Donald G. Miller. "Isopiestic determination of the osmotic and activity coefficients of ZnCl2(aq) at 298.15 K." Journal of Chemical Thermodynamics 21, no. 5 (May 1989): 463–82. http://dx.doi.org/10.1016/0021-9614(89)90164-x.

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29

Miladinović, Jelena, Rozalija Ninković, and Milica Todorović. "Osmotic and Activity Coefficients of {yKCl+(1−y)MgCl2}(aq) at T=298.15 K." Journal of Solution Chemistry 36, no. 11-12 (September 29, 2007): 1401–19. http://dx.doi.org/10.1007/s10953-007-9197-3.

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30

Wagle, Vikrant B., and Vilas G. Gaikar. "Osmotic and Activity Coefficients of Short-Chain Alkyl Benzene Sulfonates by Vapor Pressure Osmometry." Journal of Chemical & Engineering Data 51, no. 3 (May 2006): 886–91. http://dx.doi.org/10.1021/je050348f.

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31

Bonner, O. D. "Osmotic and activity coefficients of the sodium salts of formic, acetic and propionic acids." Journal of Solution Chemistry 17, no. 10 (October 1988): 999–1002. http://dx.doi.org/10.1007/bf00649743.

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32

Apelblat, Alexander, John L. Oscarson, James J. Christensen, and Reed M. Izatt. "Estimation of activity and osmotic coefficients of strong electrolytes in water at elevated temperatures." Journal of Solution Chemistry 17, no. 2 (February 1988): 95–108. http://dx.doi.org/10.1007/bf00646429.

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33

Cadena, J. C., and C. M. Romero. "Osmotic and activity coefficients of α,ω-amino acids in aqueous solutions at 298.15K." Fluid Phase Equilibria 370 (May 2014): 8–11. http://dx.doi.org/10.1016/j.fluid.2014.02.004.

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34

Marjanović, V., R. Ninković, J. Miladinović, M. Todorović, and V. Pavićević. "Osmotic and activity coefficients of {yNa2SO4+(1−y)ZnSO4}(aq) at T=298.15 K." Journal of Chemical Thermodynamics 37, no. 2 (February 2005): 111–16. http://dx.doi.org/10.1016/j.jct.2004.07.032.

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35

Ciurzyńska, Agnieszka, Joanna Cichowska, Hanna Kowalska, Kinga Czajkowska, and Andrzej Lenart. "Osmotic dehydration of Braeburn variety apples in the production of sustainable food products." International Agrophysics 32, no. 1 (January 1, 2018): 141–46. http://dx.doi.org/10.1515/intag-2016-0099.

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AbstractThe aim of this work was to investigate the effects of osmotic dehydration conditions on the properties of osmotically pre-treated dried apples. The scope of research included analysing the most important mass exchange coefficients,i.e.water loss, solid gain, reduced water content and water activity, as well as colour changes of the obtained dried product. In the study, apples were osmotically dehydrated in one of two 60% solutions: sucrose or sucrose with an addition of chokeberry juice concentrate, for 30 and 120 min, in temperatures of 40 and 60°C. Ultrasound was also used during the first 30 min of the dehydration process. After osmotic pre-treatment, apples were subjected to innovative convective drying with the puffing effect, and to freeze-drying. Temperature and dehydration time increased the effectiveness of mass exchange during osmotic dehydration. The addition of chokeberry juice concentrate to standard sucrose solution and the use of ultrasound did not change the value of solid gain and reduced water content. Water activity of the dried apple tissue was not significantly changed after osmotic dehydration, while changes in colour were significant.

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36

Salamat-Ahangari, Rahman, Laya Saemi Pestebaglu, and Zohreh Karimzadeh. "Determination of Activity Coefficients, Osmotic Coefficients, and Excess Gibbs Free Energies of KCl and KBr Aqueous Mixtures at 298.15 K." Journal of Chemical & Engineering Data 63, no. 2 (January 5, 2018): 290–97. http://dx.doi.org/10.1021/acs.jced.7b00460.

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37

Partanen, Jaakko I. "Mean Activity Coefficients and Osmotic Coefficients in Aqueous Solutions of Salts of Ammonium Ions with Univalent Anions at 25 °C." Journal of Chemical & Engineering Data 57, no. 10 (September 18, 2012): 2654–66. http://dx.doi.org/10.1021/je300474k.

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38

Pavićević, V., R. Ninković, M. Todorović, and J. Miladinović. "Osmotic and activity coefficients of {yNaH2PO4+(1−y)Na2SO4}(aq) at the temperature 298.15 K." Fluid Phase Equilibria 164, no. 2 (October 1999): 275–84. http://dx.doi.org/10.1016/s0378-3812(99)00256-3.

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39

Bley, Michael, Magali Duvail, Philippe Guilbaud, and Jean-François Dufrêche. "Simulating Osmotic Equilibria: A New Tool for Calculating Activity Coefficients in Concentrated Aqueous Salt Solutions." Journal of Physical Chemistry B 121, no. 41 (October 10, 2017): 9647–58. http://dx.doi.org/10.1021/acs.jpcb.7b04011.

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40

Calvar, Noelia, Ángeles Domínguez, and Eugénia A. Macedo. "Activity and Osmotic Coefficients of Binary Mixtures of NTf2– Ionic Liquids with a Primary Alcohol." Journal of Chemical & Engineering Data 61, no. 12 (November 4, 2016): 4123–30. http://dx.doi.org/10.1021/acs.jced.6b00556.

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41

Yi, Xin, Jiugang Hu, Weili Zhang, Xueying Zhang, Min Sun, and Shijun Liu. "Isopiestic Measurements of Osmotic and Activity Coefficients of NiCl2–NH4Cl–H2O Systems at 308.15 K." Journal of Chemical & Engineering Data 63, no. 8 (July 31, 2018): 3136–44. http://dx.doi.org/10.1021/acs.jced.8b00400.

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42

Gampe, Teresa, and Zofia Libuś. "Osmotic and activity coefficients of C2H5SO4Na(aq) and C2H5SO4K(aq) at the temperature 298.15 K." Journal of Chemical Thermodynamics 26, no. 3 (March 1994): 261–69. http://dx.doi.org/10.1016/0021-9614(94)90004-3.

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43

Ninković, Rozalija, Jelena Miladinović, Milica Todorović, Snežana Grujić, and Joseph A. Rard. "Osmotic and Activity Coefficients of the {xZnCl2+(1−x)ZnSO4}(aq) System at 298.15 K." Journal of Solution Chemistry 36, no. 4 (April 17, 2007): 405–35. http://dx.doi.org/10.1007/s10953-007-9128-3.

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44

Tsurko, Elena N., Roland Neueder, and Werner Kunz. "Activity of Water and Osmotic Coefficients of Histidine Derivatives in Aqueous Solutions at 310.15 K." Journal of Solution Chemistry 37, no. 3 (January 12, 2008): 421–31. http://dx.doi.org/10.1007/s10953-007-9237-z.

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45

Romero, Carmen M., and Manuel S. Páez. "Isopiestic determination of osmotic and activity coefficients of aqueous solutions of aliphatic polyols at 298.15K." Fluid Phase Equilibria 240, no. 2 (February 2006): 140–43. http://dx.doi.org/10.1016/j.fluid.2005.12.016.

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46

Bley, Michael, Magali Duvail, Philippe Guilbaud, and Jean-François Dufrêche. "Activity Coefficients of Aqueous Sodium, Calcium, and Europium Nitrate Solutions from Osmotic Equilibrium MD Simulations." Journal of Physical Chemistry B 122, no. 31 (July 15, 2018): 7726–36. http://dx.doi.org/10.1021/acs.jpcb.8b04950.

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47

Amado-Gonzalez, Eliseo, and Luis H. Blanco. "Osmotic and Activity Coefficients of Dilute Aqueous Solutions of Unsymmetrical Tetraalkylammonium Iodides at 298.15 K." Journal of Chemical & Engineering Data 57, no. 4 (March 2012): 1044–49. http://dx.doi.org/10.1021/je2009413.

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48

Tsurko, Elena N., Roland Neueder, and Werner Kunz. "Activity of Water and Osmotic Coefficients for Two- and Three-Basic Amino Acid Ternary Solutions." Journal of Chemical & Engineering Data 57, no. 11 (October 26, 2012): 3123–27. http://dx.doi.org/10.1021/je300701m.

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49

Macaskill, J. B., and Roger G. Bates. "Osmotic and activity coefficients of tris sulfate from isopiestic vapor pressure measurements at 25.degree.C." Journal of Chemical & Engineering Data 31, no. 4 (October 1986): 416–18. http://dx.doi.org/10.1021/je00046a013.

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50

Thurmond, Valerie L., and Garrett W. Brass. "Activity and osmotic coefficients of sodium chloride in concentrated solutions from 0 to -40.degree.C." Journal of Chemical & Engineering Data 33, no. 4 (October 1988): 411–14. http://dx.doi.org/10.1021/je00054a007.

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