Relevant bibliographies by topics / 3-dimethylpentane

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Academic literature on the topic '3-dimethylpentane'

Author: Grafiati
Published: 4 June 2021
Last updated: 6 February 2022

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Journal articles on the topic "3-dimethylpentane"

1

Dokolas, Peter, Steven M. Loer, and David H. Solomon. "Reaction of Acyclic Hydrocarbons Towards t-Butoxy Radicals. A Study of Hydrogen Atom Abstraction by Using the Radical Trapping Technique." Australian Journal of Chemistry 51, no. 12 (1998): 1113. http://dx.doi.org/10.1071/c98055.

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The reaction of 3-methylpentane and 2,4-dimethylpentane toward t-butoxy radicals has been investigated, in neat and benzene solutions, by using the radical trapping technique. Abstraction occurs principally from the tertiary and secondary C-H reaction sites of 3-methylpentane and the tertiary position of 2,4-dimethylpentane. The tertiary and in particular secondary C-H reaction sites of 2,4-dimethylpentane are shown to be considerably less susceptible towards t-butoxy radical facilitated abstraction compared with the equivalent reaction sites of 3-methylpentane. As a result, the latter is three times as reactive as 2,4-dimethylpentane as a neat hydrocarbon solution and seven times as reactive in a diluted mixture of benzene. Diferences in selectivity and rate of hydrogen abstraction, between the substrates, are interpreted in terms of non-bonding interactions retarding t-butoxy radicals from approaching sterically demanding C-H reaction sites. The selectivity from 3-methylpentane is solvent-insensitive whereas abstraction from 2,4-dimethylpentane is modified in benzene. Further, the rate of hydrogen abstraction, from either substrate, to t-butoxy radical β-scission is considerably smaller in benzene. Both observations are interpreted in terms of t-butoxy radical solvation by the aromatic solvent.
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Svoboda, Václav, Vladimı́r Hynek, and Bohumı́r Koutek. "Enthalpies of vaporization, and the cohesive and internal energies of 2,2-dimethylpentane, 2,4-dimethylpentane, 2,2,3-trimethylpentane, 2,3,3-trimethylpentane, and 3-ethylpentane." Journal of Chemical Thermodynamics 30, no. 11 (November 1998): 1411–17. http://dx.doi.org/10.1006/jcht.1998.0414.

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NAGUMO, Shinji, Takayuki ARAI, and Hiroyuki AKITA. "Enzymatic Hydrolysis of meso(syn-syn)-1,3,5-Triacetoxy-2,4-dimethylpentane and Acetylation of meso(syn-syn)-3-Benzyloxy-2,4-dimethylpentane-1,5-diol by Lipase." CHEMICAL & PHARMACEUTICAL BULLETIN 44, no. 7 (1996): 1391–94. http://dx.doi.org/10.1248/cpb.44.1391.

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NAGUMO, S., T. ARAI, and H. AKITA. "ChemInform Abstract: Enzymatic Hydrolysis of meso(syn-syn)-1,3,5-Triacetoxy-2,4- dimethylpentane and Acetylation of meso(syn-syn)-3-Benzyloxy-2,4- dimethylpentane-1,5-diol by Lipase." ChemInform 28, no. 1 (August 4, 2010): no. http://dx.doi.org/10.1002/chin.199701051.

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Solano-Serena, Floriane, Rémy Marchal, Serge Casarégola, Christelle Vasnier, Jean-Michel Lebeault, and Jean-Paul Vandecasteele. "A Mycobacterium Strain with Extended Capacities for Degradation of Gasoline Hydrocarbons." Applied and Environmental Microbiology 66, no. 6 (June 1, 2000): 2392–99. http://dx.doi.org/10.1128/aem.66.6.2392-2399.2000.

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ABSTRACT A bacterial strain (strain IFP 2173) was selected from a gasoline-polluted aquifer on the basis of its capacity to use 2,2,4-trimethylpentane (isooctane) as a sole carbon and energy source. This isolate, the first isolate with this capacity to be characterized, was identified by 16S ribosomal DNA analysis, and 100% sequence identity with a reference strain of Mycobacterium austroafricanum was found. Mycobacterium sp. strain IFP 2173 used an unusually wide spectrum of hydrocarbons as growth substrates, including n-alkanes and multimethyl-substituted isoalkanes with chains ranging from 5 to 16 carbon atoms long, as well as substituted monoaromatic hydrocarbons. It also attacked ethers, such as methyl t-butyl ether. During growth on gasoline, it degraded 86% of the substrate. Our results indicated that strain IFP 2173 was capable of degrading 3-methyl groups, possibly by a carboxylation and deacetylation mechanism. Evidence that it attacked the quaternary carbon atom structure by an as-yet-undefined mechanism during growth on 2,2,4-trimethylpentane and 2,2-dimethylpentane was also obtained.
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Schuler, Robert H., and Laszlo Wojnarovits. "Radical Yields in the Radiolysis of Branched Hydrocarbons: Tertiary C−H Bond Rupture in 2,3-Dimethylbutane, 2,4-Dimethylpentane, and 3-Ethylpentane." Journal of Physical Chemistry A 107, no. 43 (October 2003): 9240–47. http://dx.doi.org/10.1021/jp030658+.

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Bouzas, Alberto, M. Cruz Burguet, Juan B. Montón, and Rosa Muñoz. "Densities, Viscosities, and Refractive Indices of the Binary Systems Methyltert-Butyl Ether + 2-Methylpentane, + 3-Methylpentane, + 2,3-Dimethylpentane, and + 2,2,4-Trimethylpentane at 298.15 K." Journal of Chemical & Engineering Data 45, no. 2 (March 2000): 331–33. http://dx.doi.org/10.1021/je9902793.

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Guerrero-Zárate, David, Gustavo A. Iglesias-Silva, and Alejandro Estrada-Baltazar. "P–ρ–T Data and Derivative Properties of 3-Methylpentane, 2,4-Dimethylpentane, and 2,3,4-Trimethylpentane from 283.15 to 363.15 K at Pressures up to 65 MPa." Journal of Chemical & Engineering Data 64, no. 12 (December 3, 2019): 6020–30. http://dx.doi.org/10.1021/acs.jced.9b00846.

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Akai, Yuto, Laure Konnert, Takeshi Yamamoto, and Michinori Suginome. "Asymmetric Suzuki–Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos." Chemical Communications 51, no. 33 (2015): 7211–14. http://dx.doi.org/10.1039/c5cc01074h.

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Axially chiral 1,1′-biaryl-2-carboxylates were synthesized via Suzuki–Miyaura cross-coupling of 2,4-dimethylpentan-3-yl 1-halo-2-naphthoates with arylboronic acids with single-handed helical polymer ligands PQXphos.
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Collins, DJ, and HA Jacobs. "Steric and Stereoelectronic Effects in the Hydrogenolysis and Birch Reduction of Some Hindered Tertiary-Benzylic Carbinols." Australian Journal of Chemistry 40, no. 12 (1987): 1989. http://dx.doi.org/10.1071/ch9871989.

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3-(4'-Methoxyphenyllpentan-3-ol (3a) and 3-(4'-methoxypheny1)-2,4-dimethylpentan-3-ol (3b) underwent catalytic hydrogenolysis over 10% palladium/charcoal at moderate temperatures and pressures. The more hindered tertiary-benzylic carbinols 3-(4'-methoxypheny1)-2,2,4-trimethylpentan-3-ol (6), 3-(4'-methoxyphenyl)-2,2,4,4-tetramethylpentan-3-ol (3c), 1-(4'- methoxyphenyl )-2,2,6,6-tetramethylcyclohexan-l-ol (8) and 1-(1',1'-dimethylethy1)-6-methoxy- 2,2-dimethyl-l,2,3,4-tetrahydronaphthalen-1-ol (10) were completely resistant to hydrogenolysis, even under vigorous conditions. While the hindered tertiary-benzylic carbinols (6),(8) and (10) readily underwent Birch reduction, the analogous di-t-butyl anisyl carbinol (3c) was unchanged. The failure of (3c) to undergo Birch reduction is probably due to a hitherto unrecognized stereoelectronic effect: the C-OH bond of (3c) is constrained to lie more or less in the plane of the benzene ring, and addition of an electron to the benzene ring of the derived oxyanion (31) is inhibited in this conformation.
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Book chapters on the topic "3-dimethylpentane"

1

Wohlfarth, Ch. "Viscosity of 2,3-dimethylpentane." In Supplement to IV/18, 482. Berlin, Heidelberg: Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75486-2_268.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture Methanol CH4O + C7H14O 2,4-Dimethylpentan-3-one (LB2063, VMSD1111)." In Binary Liquid Systems of Nonelectrolytes, 182–84. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_14.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture Methanol CH4O + C7H14O 2,4-Dimethylpentan-3-one (LB2061, VMSD1212)." In Binary Liquid Systems of Nonelectrolytes, 185–87. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_15.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture Cyclopentane C5H10 + C7H16 2,2-Dimethylpentane (LB1954, VMSD1212)." In Binary Liquid Systems of Nonelectrolytes, 3506–8. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_1033.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture Cyclopentane C5H10 + C7H16 2,3-Dimethylpentane (LB1955, VMSD1212)." In Binary Liquid Systems of Nonelectrolytes, 3509–11. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_1034.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture Cyclopentane C5H10 + C7H16 2,4-Dimethylpentane (LB1956, VMSD1212)." In Binary Liquid Systems of Nonelectrolytes, 3512–14. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_1035.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture Cyclopentane C5H10 + C7H16 3,3-Dimethylpentane (LB1957, VMSD1212)." In Binary Liquid Systems of Nonelectrolytes, 3515–17. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_1036.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture 2,2-Dimethylpentane C7H16 + C16H34 Hexadecane (LB1814, VMSD1111)." In Binary Liquid Systems of Nonelectrolytes, 1691–93. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_478.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture 2,2-Dimethylpentane C7H16 + C16H34 Hexadecane (LB1822, VMSD1212)." In Binary Liquid Systems of Nonelectrolytes, 1694–96. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_479.

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Cibulka, I., L. Hnědkovský, J. C. Fontaine, K. Sosnkowska-Kehiaian, and H. V. Kehiaian. "Volumetric Properties of the Mixture 2,2-Dimethylpentane C7H16 + C16H34 Hexadecane (LB1826, VMSD1412)." In Binary Liquid Systems of Nonelectrolytes, 1697–99. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-73584-7_480.

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