Dissertations / Theses on the topic '2D morphology'

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1

Hayes, Susan. "Seeing and measuring the 2D face." University of Western Australia. School of Anatomy and Human Biology, 2009. http://theses.library.uwa.edu.au/adt-WU2010.0067.

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This is a study of the factors that affect face shapes, and the techniques that can be used to measure variations in two dimensional representations of faces. The materials included thirty photographs of people in natural poses and thirty portraits that were based on the pose photographs. Visual assessors were asked to score the photographs and portraits in terms of pose (cant, turn and pitch) and also to compare the portraits to the photographs and score them in terms of likeness in the depiction of the face and its component features. Anthropometric indices were derived and used to score the images for the pose variables as well as for aspects of individual variation in external face shape and the spatial arrangement of the features. Geometric morphometric analysis was also used to determine the shape variation occurring in the photographs, the variation within the portraits, and to specifically discern where the portraits differ from the photographs in the depiction of head pose and individual differences in facial morphology. For the analysis of pose it was found that visual assessors were best at discerning the extent of head turning and poorest at discerning head pitch. These tendencies occurred in the visual assessments of both the photographs and the portrait drawings. For the analysis of the individual variation in face shapes it was found that external face shape varies according to upper face dimensions and the shape of the chin, and that vertical featural configurations are strongly linked to external face shape. When the portrait and photograph data were placed in the same geometric morphometric analysis the inaccuracies in the portrait drawings became evident. When these findings were compared to the visual assessments it transpired that, on average, visual assessment was generally congruent with the geometric morphometric analysis, but were possibly confounded by patterns of dysmorphology in the portraits that were contrary to what this study suggests are normal patterns of face shape variation. Overall this study has demonstrated that while anthropometric and visual assessments of facial differences are quite good, both were comparatively poor at assessing head pitch and tended to be confounded by the dysmorphologies arising in the portrait drawings. Geometric morphometric analysis was found to be very powerful in discerning complex shape variations associated with head pose and individual differences in facial morphology, both within and between the photographs and portraits.
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2

Kozarek, Jessica Lindberg. "Channel Morphology and Riparian Vegetation Influences on Fluvial Aquatic Habitat." Diss., Virginia Tech, 2011. http://hdl.handle.net/10919/77172.

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As public awareness of river degradation has grown in recent years, the number of stream restoration activities has increased dramatically. Anthropogenic influences at a range of spatial scales from watershed landuse to riparian vegetation management to local channel morphology can have hierarchical relationships to local (meso- and macro-) in-stream habitat characteristics. This research examined these influences first by examining the influence of complex channel morphology on meso-scale brook trout (Salvelinus fontinalis) habitat in Shenandoah National Park, VA, and then by examining the combined influence of watershed urbanization and riparian vegetation (100-200 m reaches) on stream temperature. Moving beyond one-dimensional (1D) averaged representations of fish habitat, this research explored the distribution of two-dimensional (2D) flow complexity metrics at the meso-habitat scale as explanatory variables for brook trout habitat preferences and as potential metrics to evaluate habitat restoration design. Spatial hydraulic complexity metrics, including area-weighted circulation and kinetic energy gradients, were calculated based on 2D depth averaged modeled velocity distributions in two 100-m reaches on the Staunton River. While there were no statistically significant correlations between kinetic energy gradients or area-weighted circulation and fish density, fish density was positively correlated to the percent of the channel dominated by protruding boulders. The structural complexity of areas with protruding boulders create complex flow patterns suggesting that flow complexity plays an important role in available brook trout habitat preferences at the local scale, although the 2D depth averaged model may not have adequately represented this complexity. The 2D distribution of flow characteristics was then investigated further to quantify areas of flow refugia (low velocity shelters) and the relationship between these areas, traditional measures of habitat quality, and fish biomass. Flow complexity in the vicinity of flow obstructions (in this case, boulders) was investigated further using patch classification and landscape ecology metrics. The relative influence of riparian vegetation on stream temperature (another important habitat characteristic) in urban and nonurban watersheds was investigated in 27 paired forested and nonforested reaches in PA, MD, and DE. Riparian vegetation and watershed-scale urbanization both influence stream temperature, which can have profound impacts on in-stream ecosystems. Generally, increased urbanization and removal of riparian forest influenced maximum stream temperatures resulting in higher maximum summer stream temperatures (up to 1.8°C); however, the influence of riparian forests (at at 100-200 m reach scale) decreased with increasing urbanization. Extreme maximum summer temperatures, which are a concern for aquatic biota, increased in both frequency and duration in urban nonforested reaches relative to forested reaches indicating that the addition of a forested 100-200 m long buffer partially mitigated these temperature extremes even in urban watersheds. Overall, changes to channel morphology and riparian vegetation had measurable local effects on stream habitat (temperature and hydraulic complexity) yet the implications of restoration efforts at the local scale on ecosystem services at a larger (km +) scale requires further study.
Ph. D.
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3

Devotta, Ashwin Moris. "Characterization & modeling of chip flow angle & morphology in 2D & 3D turning process." Licentiate thesis, Högskolan Väst, Forskningsmiljön produktionsteknik(PTW), 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:hv:diva-8671.

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Within manufacturing of metallic components, machining plays an important role and is of vital significance to ensure process reliability. From a cutting tool design perspective,  tool macro geometry  design  based on physics based  numerical modelling  is highly needed  that can predict chip morphology.  The chip morphology describes the chip shape geometry and the chip curl geometry. The prediction of chip flow and chip shape is vital in predicting chip breakage, ensuring good chip evacuation and lower surface roughness.  To this end, a platform where such a  numerical model’s chip morphology prediction  can be compared with experimental investigation is needed and is the focus of this work. The studied cutting processes are orthogonal cutting process and nose turning process. Numerical models that simulate the chip formation process are employed to predict the chip morphology and are accompanied by machining experiments. Computed tomography is used  to scan the chips obtained from machining experiments and its ability to capture the variation in  chip morphology  is evaluated.  For nose turning process,  chip  curl parameters during the cutting process are to be calculated. Kharkevich model is utilized in this regard to calculate the  ‘chip in process’ chip curl parameters. High speed videography is used to measure the chip side flow angle during the cutting process experiments and are directly compared to physics based model predictions. The results show that the methodology developed provides  the framework where advances in numerical models can be evaluated reliably from a chip morphology prediction capability view point for nose turning process. The numerical modeling results show that the chip morphology variation for varying cutting conditions is predicted qualitatively. The results of quantitative evaluation of chip morphology prediction shows that the error in prediction is too large to be used for predictive modelling purposes.
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4

Ding, Huaxiong. "Combining 2D facial texture and 3D face morphology for estimating people's soft biometrics and recognizing facial expressions." Thesis, Lyon, 2016. http://www.theses.fr/2016LYSEC061/document.

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Puisque les traits de biométrie douce peuvent fournir des preuves supplémentaires pour aider à déterminer précisément l’identité de l’homme, il y a eu une attention croissante sur la reconnaissance faciale basée sur les biométrie douce ces dernières années. Parmi tous les biométries douces, le sexe et l’ethnicité sont les deux caractéristiques démographiques importantes pour les êtres humains et ils jouent un rôle très fondamental dans l’analyse de visage automatique. En attendant, la reconnaissance des expressions faciales est un autre challenge dans le domaine de l’analyse de visage en raison de la diversité et de l’hybridité des expressions humaines dans différentes cultures, genres et contextes. Ce thèse est dédié à combiner la texture du visage 2D et la morphologie du visage 3D pour estimer les biométries douces: le sexe, l’ethnicité, etc., et reconnaître les expressions faciales. Pour la reconnaissance du sexe et de l’ethnicité, nous présentons une approche efficace en combinant à la fois des textures locales et des caractéristiques de forme extraites à partir des modèles de visage 3D, contrairement aux méthodes existantes qui ne dépendent que des textures ou des caractéristiques de forme. Afin de souligne exhaustivement la différence entre les groupes sexuels et ethniques, nous proposons un nouveau descripteur, à savoir local circular patterns (LCP). Ce descripteur améliore Les motifs binaires locaux (LBP) et ses variantes en remplaçant la quantification binaire par une quantification basée sur le regroupement, entraînant d’une puissance plus discriminative et une meilleure résistance au bruit. En même temps, l’algorithme Adaboost est engagé à sélectionner les caractéristiques discriminatives fortement liés au sexe et à l’ethnicité. Les résultats expérimentaux obtenus sur les bases de données FRGC v2.0 et BU-3DFE démontrent clairement les avantages de la méthode proposée. Pour la reconnaissance des expressions faciales, nous présentons une méthode automatique basée sur les multi-modalité 2D + 3D et démontrons sa performance sur la base des données BU-3DFE. Notre méthode combine des textures locales et des descripteurs de formes pour atteindre l’efficacité et la robustesse. Tout d’abord, un grand ensemble des points des caractéristiques d’images 2D et de modèles 3D sont localisés à l’aide d’un nouvel algorithme, à savoir la cascade parallèle incrémentielle de régression linéaire (iPar-CLR). Ensuite, on utilise un nouveau descripteur basé sur les histogrammes des gradients d’ordre secondaire (HSOG) en conjonction avec le descripteur SIFT pour décrire la texture locale autour de chaque point de caractéristique 2D. De même, la géométrie locale autour de chaque point de caractéristique 3D est décrite par deux nouveaux descripteurs de forme construits à l’aide des quantités différentielle de géométries de la surface au premier ordre et au second ordre, à savoir meshHOG et meshHOS. Enfin, les résultats de reconnaissance des descripteurs 2D et 3D fournis par le classifier SVM sont fusionnés à la fois au niveau de fonctionnalité et de score pour améliorer la précision. Les expérimentaux résultats démontrent clairement qu’il existe des caractéristiques complémentaires entre les descripteurs 2D et 3D. Notre approche basée sur les multi-modalités surpasse les autres méthodes de l’état de l’art en obtenant une précision de reconnaissance 86,32%. De plus, une bonne capacité de généralisation est aussi présentée sur la base de données Bosphorus
Since soft biometrics traits can provide sufficient evidence to precisely determine the identity of human, there has been increasing attention for face based soft biometrics identification in recent years. Among those face based soft biometrics, gender and ethnicity are both key demographic attributes of human beings and they play a very fundamental and important role in automatic machine based face analysis. Meanwhile, facial expression recognition is another challenge problem in face analysis because of the diversity and hybridity of human expressions among different subjects in different cultures, genders and contexts. This Ph.D thesis work is dedicated to combine 2D facial Texture and 3D face morphology for estimating people’s soft biometrics: gender, ethnicity, etc., and recognizing facial expression. For the gender and ethnicity recognition, we present an effective and efficient approach on this issue by combining both boosted local texture and shape features extracted from 3D face models, in contrast to the existing ones that only depend on either 2D texture or 3D shape of faces. In order to comprehensively represent the difference between different genders or ethnics groups, we propose a novel local descriptor, namely local circular patterns (LCP). LCP improves the widely utilized local binary patterns (LBP) and its variants by replacing the binary quantization with a clustering based one, resulting in higher discriminative power as well as better robustness to noise. Meanwhile, the following Adaboost based feature selection finds the most discriminative gender- and ethnic-related features and assigns them with different weights to highlight their importance in classification, which not only further raises the performance but reduces the time and memory cost as well. Experimental results achieved on the FRGC v2.0 and BU-3DFE data sets clearly demonstrate the advantages of the proposed method. For facial expression recognition, we present a fully automatic multi-modal 2D + 3D feature-based facial expression recognition approach and demonstrate its performance on the BU–3DFE database. Our approach combines multi-order gradientbased local texture and shape descriptors in order to achieve efficiency a nd robustness. First, a large set of fiducial facial landmarks of 2D face images along with their 3D face scans are localized using a novel algorithm namely incremental Parallel Cascade of Linear Regression (iPar–CLR). Then, a novel Histogram of Second Order Gradients (HSOG) based local image descriptor in conjunction with the widely used first-order gradient based SIFT descriptor are employed to describe the local texture around each 2D landmark. Similarly, the local geometry around each 3D landmark is described by two novel local shape descriptors constructed using the first-order and the second-order surface differential geometry quantities, i.e., Histogram of mesh Gradients (meshHOG) and Histogram of mesh Shape index (curvature quantization, meshHOS). Finally, the Support Vector Machine (SVM) based recognition results of all 2D and 3D descriptors are fused at both featurelevel and score-level to further improve the accuracy. Comprehensive experimental results demonstrate that there exist impressive complementary characteristics between the 2D and 3D descriptors. We use the BU–3DFE benchmark to compare our approach to the state-of-the-art ones. Our multi-modal feature-based approach outperforms the others by achieving an average recognition accuracy of 86,32%. Moreover, a good generalization ability is shown on the Bosphorus database
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5

Wijenayaka, A. K. Lahiru Anuradha. "Improved theoretical prediction of nanoparticle stability and the synthesis, characterization, and application of gold nanopartticles of various morphology in surface-enhanced infrared spectroscopy." Diss., University of Iowa, 2015. https://ir.uiowa.edu/etd/1931.

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The overarching objective of the investigations discussed herein is the development of a model experimental system for surface-enhanced infrared absorption (SEIRA) spectroscopy, with potential applicability in higher order infrared spectroscopic techniques, specifically, surface-enhanced two-dimensional infrared (SE-2D IR) spectroscopy. Theoretical predictions that accurately predict the stability of functionalized nanoparticles enable guided design of their properties but are often limited by the accuracy of the parameters used as model inputs. Hence, first, such parameterization limitations for the extended DLVO (xDLVO) theory are overcome using a size-dependent Hamaker constant for gold, interfacial surface potentials, and tilt angles of self-assembled monolayers (SAMs), which collectively improves the predictive power of xDLVO theory for modeling nanoparticle stability. Measurements of electrical properties of functionalized gold nanoparticles validate the predictions of xDLVO theory using these new parameterizations illustrating the potential for this approach to improve the design and control of the properties of functionalized gold nanoparticles in various applications. Next, a series of experiments were conducted to elucidate the behavior of various infrared active molecules in the presence of spherical gold nanoparticles of average diameter ∼20 nm. Here, the spectroscopic anomalies, specifically the shifted vibrational frequency and the dispersive lineshape observed in the infrared spectra for SCN- in the presence of gold nanoparticles provide direct evidence of SIERA. Nevertheless, it was evidenced that nanomaterial with plasmonic properties that extends into the infrared wavelengths are imperative in observing efficient infrared enhancements. Hence, nanomaterial indicating plasmonic properties extending into the infrared wavelengths were synthesized via a straightforward, seedless, one-pot synthesis. The gold nanostars prepared here indicated plasmonic behavior clearly extending into the near infrared, with simple plasmonic tunability via changing the buffer concentration used during synthesis. The systematic understanding achieved here in terms of theoretical prediction of nanoparticle stability, origin of infrared spectral anomalies in the presence of nanomaterials, and the preparation of infrared plasmonic material, collectively provides a resilient framework for the further investigation of surface-enhanced infrared spectroscopic techniques including SEIRA and SE-2D IR spectroscopies.
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6

Feng, Xinliang, Xiaodong Zhuang, Wuxue Zhao, Fan Zhang, Yu Cao, Feng Liu, and Shuai Bia. "A two-dimensional conjugated polymer framework with fully sp2-bonded carbon skeleton." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-224298.

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The synthesis of crystalline two-dimensional (2D) covalent organic frameworks (COFs) with fully unsaturated carbon–carbon backbones via a solution approach remains a great challenge. In this work, we report the first example of an olefin-linked 2D conjugated COF using a Knoevenagel polycondensation reaction of 1,4-phenylene diacetonitrile and three armed aromatic aldehyde. The resulting 2D poly(phenelyenevinylene) framework (2DPPV) possesses a sheet morphology, and a crystalline layered structure featuring a fully sp2-bonded carbon skeleton with pendant cyanide groups. Its unique alternating structure with a serrated configuration has been essentially evaluated using HR-TEM TEM analysis, nitrogen physisorption measurements, PXRD studies and theoretical simulations. Upon thermal and activation treatments, the as-prepared 2DPPV can be facilely converted into porous carbon nanosheets with large specific surface areas of up to 880 m2 g−1 which exhibit an excellent electrochemical performance as supercapacitor electrodes and electrocatalysts for the oxygen reduction reaction. This represents an economic non-template approach to 2D porous carbon materials for energy-related applications.
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7

Baubet, Bertrand. "Influence de la morphologie 2D de la phase active sur la sélectivité des catalyseurs sulfures en HDS des essences." Thesis, Lyon 1, 2013. http://www.theses.fr/2013LYO10067.

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Ce travail de thèse étudie l’influence de la morphologie des feuillets de sulfure de molybdène sur la sélectivité des catalyseurs d’hydrotraitement. Les feuillets de phase active présentent en effet deux types de bords appelés « M-edge » et « S-edge » susceptibles de conduire à des réactivités différentes. Le changement de la morphologie 2D des feuillets pourrait modifier les proportions de bords M et S exposés et ainsi les propriétés catalytiques des catalyseurs sulfures. Pour cela, des catalyseurs non promus (Mo) et promus (CoMo), supportés sur alumine ont été préparés par imprégnation à sec puis sulfurés dans des conditions variées (gaz et température). Des tests catalytiques en hydrodésulfuration (HDS) sélective des essences de FCC (sélectivité HDS/HYD) ont ensuite permis d’évaluer l’impact de la morphologie en s’appuyant sur des modèles géométriques construits à partir de calculs DFT et de caractérisations expérimentales (TEM, IR (CO), TPR, XPS). Les résultats obtenus pour les catalyseurs de type Mo semblent ainsi confirmer l’influence de la morphologie 2D sur la sélectivité HDS/HYD, le bord M paraissant être le plus sélectif pour les catalyseurs non promus. Ils mettent également en évidence l’importance de la réductibilité plus ou moins marquée des bords sur les propriétés catalytiques, notamment sur le bord M. Le changement des conditions de sulfuration semble donc affecter la morphologie des particules mais également les propriétés chimiques propres à chaque bord. En ce qui concerne les catalyseurs promus, la variation des conditions de sulfuration semble agir essentiellement au niveau de la répartition du promoteur entre les bords M et S. Cependant, les interactions avec le support paraissent constituer un frein aux effets de promotion. Dans ce contexte, les sulfurations à haute température sous H2S pur permettent d’obtenir des gains significatifs en activité et sélectivité. Ces résultats semblent dus à de faibles interactions avec le support et une décoration privilégiée du bord S qui pourrait favoriser la réaction d’HDS et limiter la réaction d’HYD. Au final, les interprétations effectuées en terme de morphologie 2D tendent à confirmer que ce paramètre peut constituer un axe de développement intéressant pour les catalyseurs d’hydrotraitement. L'optimisation des conditions de sulfuration permettraient bien de faire varier la morphologie et le taux de décoration du promoteur des catalyseurs, améliorant ainsi significativement l'activité et la sélectivité
This thesis examines the influence of the morphology of particles of molybdenum sulfide on selectivity of hydrotreating catalysts. Nanoparticles of active phase present two types of edges called “M-edge” and “S-edge” which may lead to different reactivities. The change in morphology of the 2D sheets could change the proportions of M and S edges exposed and thus the catalytic properties of sulfide catalysts. For this, non-promoted (Mo) and promoted (CoMo) catalysts, supported on alumina were prepared by dry impregnation and sulfide in various conditions (gas and temperature). Catalytic tests in selective hydrodesulfurization (HDS) of FCC gasoline (selectivity HDS /HYD) were then used to assess the impact of the morphology based on geometrical models which were constructed with DFT calculations and experimental characterizations (TEM, IR (CO), TPR, XPS). The results for Mo catalysts seem to confirm the influence of the 2D morphology selectivity HDS / HYD, M-edge appearing to be the most selective for non-promoted catalysts. They also highlight the importance of the reducibility more or less pronounced of the edges on the catalytic properties, especially on the M-edge. The different conditions of sulfidation seem to affect the morphology of the particles but also the specific chemical properties at each edge. Regarding to the promoted catalysts, the different conditions of sulfidation appear to act primarily at the distribution of the promoter between the M and S edges. However, interactions with the carrier appear to constitute an obstacle to promoting effects. In this context, sulfidations at high temperature in pure H2S lead to obtain significant gains in activity and selectivity. These results appear to be due to weak interactions with the carrier and to the presence of the promoter on the S-edge which could promote the HDS reaction and limit the HYD reaction. Finally, the interpretations made in terms of 2D morphology tend to confirm that this parameter can be an interesting line of development for hydrotreating catalysts. Optimization of the sulfidation conditions could effectively allow to vary the morphology and the rate of decoration of promoted catalysts which significantly improve the activity and selectivity
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8

Lottin, Delphine. "Dimensions fractales, morphologie et caractéristiques dimensionnelles 2D et 3D d'agrégats de nanoparticules de suie aéronautique : Etude par microscopie électronique en transmission et tomographie électronique." Thesis, Aix-Marseille, 2013. http://www.theses.fr/2013AIXM4012/document.

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Les agrégats de suie émis par les processus de combustion dans les turbines aéronautiques contribuent à modifier le bilan radiatif de l'atmosphère et la qualité de l'air. La connaissance de leurs caractéristiques physiques et chimiques est indispensable pour évaluer leur rôle dans les processus physico-chimiques atmosphériques et leur impact sur l'environnement et la santé publique. Dans ce contexte, notre étude vise à déterminer la taille et la morphologie d'agrégats de suie aéronautique à partir de mesures expérimentales menées en microscopie électronique en transmission (MET) et en tomographie électronique.Nous avons réalisé des clichés MET d'agrégats de suie émis par des turboréacteurs aéronautiques. Nous avons établi une méthode pour caractériser la morphologie des agrégats en déterminant leur allongement, leur compacité et la tortuosité de leur contour en analysant leur projection. Nous avons également développé un logiciel de traitement et d'analyse des images MET qui permet de reconstruire en 3D un agrégat à partir de ses projections et l'analyse de ses caractéristiques dimensionnelles et morphologiques à partir de sa reconstruction. Les résultats obtenus nous ont permis d'étudier la validité des relations liant les caractéristiques microphysiques 2D et 3D proposées dans la littérature et d'en proposer de nouvelles pour les agrégats étudiés.Ces résultats constituent la première caractérisation morphologique 3D d'agrégats de suie aéronautique à partir d'analyses par MET et tomographie électronique. Ils montrent que les propriétés morphologiques de ces agrégats ne permettent pas d'utiliser la méthode d'ensemble pour déterminer la dimension fractale massique
Soot aggregates emitted by aircraft engines' combustion processes are involved in the modification of the global radiative budget and the air quality. The knowledge of their physical and chemical characteristics is a prerequisite to any evaluation of the way they may act in the atmospheric physical and chemical processes and their impact on the environment and public health. In this context, our study aims at determining the size and morphological characteristics of aircraft soot aggregates on the basis of experimental measurements by transmission electron microscopy (TEM) and electron tomography.We have acquired TEM pictures of soot aggregates emitted by aircraft engines. We have established a method to characterize the morphology of these aggregates by determining their elongation, their compacity and the tortuosity of their edge. This method is based on the analysis of their TEM projection. Besides, we have developed a software to process and analyse TEM pictures. It allows to reconstruct aggregates from their projections and to determine their size and morphological characteristics. Our results have lead us to study the validity of the relationships linking the 2D and 3D microphysical characteristics presented in the literature and to suggest new ones for the studied aggregates.These results constitute the first 3D morphological and size characterizations of aircraft soot aggregates using TEM and electron tomography. They highlight the fact that the morphological properties of these aggregates do not fulfil the hypotheses required for the use of the collective method to determine the mass fractal dimension
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9

Feng, Xinliang, Xiaodong Zhuang, Wuxue Zhao, Fan Zhang, Yu Cao, Feng Liu, and Shuai Bia. "A two-dimensional conjugated polymer framework with fully sp2-bonded carbon skeleton." Royal Society of Chemistry, 2016. https://tud.qucosa.de/id/qucosa%3A30310.

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The synthesis of crystalline two-dimensional (2D) covalent organic frameworks (COFs) with fully unsaturated carbon–carbon backbones via a solution approach remains a great challenge. In this work, we report the first example of an olefin-linked 2D conjugated COF using a Knoevenagel polycondensation reaction of 1,4-phenylene diacetonitrile and three armed aromatic aldehyde. The resulting 2D poly(phenelyenevinylene) framework (2DPPV) possesses a sheet morphology, and a crystalline layered structure featuring a fully sp2-bonded carbon skeleton with pendant cyanide groups. Its unique alternating structure with a serrated configuration has been essentially evaluated using HR-TEM TEM analysis, nitrogen physisorption measurements, PXRD studies and theoretical simulations. Upon thermal and activation treatments, the as-prepared 2DPPV can be facilely converted into porous carbon nanosheets with large specific surface areas of up to 880 m2 g−1 which exhibit an excellent electrochemical performance as supercapacitor electrodes and electrocatalysts for the oxygen reduction reaction. This represents an economic non-template approach to 2D porous carbon materials for energy-related applications.
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10

Bouhnaida, Zaïnaba. "Étude comparative de trois systèmes de préparation canalaire en endodontie : Étude in vitro en micro-CT." Thesis, Reims, 2018. http://www.theses.fr/2018REIMO201/document.

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Le but de cette étude est de comparer le respect de la morphologie canalaire après instrumentation à l’aide de trois systèmes de mise en forme canalaire différents : le One Shape NEW Generation®, le Wave One® et le Revo-S® grâce à une étude en Micro-tomographie assistée par ordinateur ou micro-CT (Computed Tomography). La mise en place d’une chaîne méthodologique totalement tridimensionnelle (3D) comprenant la reconstruction, le recalage et la segmentation a permis de traiter les images acquises et d’extraire les images recalées des canaux dentaires avant et après instrumentation. Les artéfacts de segmentation dus aux calcifications et aux débris dentinaires ont été traités. Une méthode d’estimation des zones non instrumentées a également été décrite.Le transport canalaire a été calculé pour chaque coupe de chaque tiers radiculaire, en comparant la position du centroïde avant et après instrumentation. La comparaison des moyennes de transport canalaire ne montre pas de différence significative entre les 3 systèmes d’instrumentation.Cette approche méthodologique en 4 parties a permis de valider un protocole d’imagerie 3D reproductible, qui pourra être appliqué in vitro en recherche endodontique dans l’analyse des effets instrumentaux
The aim of this study is to compare the respect of the root canal morphology after instrumentation with different shaping systems (One Shape NEW Generation®, Wave One® and Revo-S®), by using Micro-Computed Tomography.We used a fully three-dimensional (3D) methodological process which involved the reconstruction, registration and segmentation. By this methodological process, images have been acquired and processed in order to extract registered canals images before and after the instrumentation. The segmentation artifacts like calcifications and debris have been taken into account. A method to estimate the non-instrumented zones is also described.The canal transportation was calculated for each slice of each root-third by comparing the position of the centroids before and after instrumentation. No significant difference was found between the three instrumentation systems when canal transport means were done.This 4-part methodological approach has enabled the validation of a reproducible 3D imaging protocol. This can be applied in vitro in endodontic research for analysis of the instrumental effects
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11

Acharya, Rajendra. "Synthesis, Characterization and Photophysical Studies of Porphyrin and N-Confused Porphyrin Derivatives and Self-assembled Nano-Morphologies." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1376061548.

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12

Ahonen, Jani. "Can morphologic restoration of hydropower outlet channels create hydraulically suitable spawning and larvae habitats for grayling? : Modelling the effects of environmental measures with HEC-RAS." Thesis, Umeå universitet, Institutionen för ekologi, miljö och geovetenskap, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-144188.

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The aim of this study was to model if hydraulically suitable habitats for juvenile and spawning grayling could be created by morphological restoration alone in the Bjurfors Övre hydropower outlet channel in the Ume River Basin. The study was done by 2D modelling with HEC-RAS using hourly water flow and level data collected during the period 20160521-20161029. Suitable water depth and velocity values for larvae and spawning grayling were collected from literature. Environmental measures for the Bjurfors Övre outlet channel were designed based on the morphology in outlet channels with documented reproducing grayling populations and large habitat diversities. The outlet channel at present morphology and after morphological modifications were modelled at different flow scenarios (0-369m3/s) and areas of suitable water velocities and depths before and after proposed measures were compared. Results show that suitable velocity areas would increase with a factor of between 1,03-1,81 and the suitable depth areas with a factor of 2,34-19,09 and that suitable depths may be the major limiting factor in current conditions. Results also show that zero-flow events at Bjurfors Övre hydropower plant create unsuitable velocities for larvae and spawning grayling and that the frequency and duration of such events could be more limiting than the mere occurrence of such events. The study indicates that the morphological restoration in hydropeaking outlet channels could improve the availability of habitats with suitability water depth and velocity not only for larvae and spawning grayling, but for other lotic organisms. The study also showed that HEC-RAS modelling is a potential resource effective way to assess to what extent certain proposed environmental measures may create suitable water depths and velocities in hydropeaking outlet channels.
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13

Moreau, Éric. "Etude de la morphologie et de la topologie 2D et 3D d'un sol argileux par analyse d'images - application à la décontamination des sols par champs électriques." Poitiers, 1997. http://www.theses.fr/1997POIT2261.

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Les comportements hydrauliques et electriques d'un sol dependent fortement de sa structure. Une reconstruction 3d basee sur l'acquisition d'images de coupes successives d'un echantillon de sol argileux impregne d'une resine dopee est realisee. Deux techniques sont utilisees: la tomographie scanner a rayons x et l'acquisition de coupes seriees distantes de 100 m. La reconstruction en trame cubique permet de decrire l'organisation 3d du reseau de fractures, et de comparer les representations bi- et tridimensionnelles a partir de criteres morphologiques. L'objectif est de determiner si les proprietes electriques et hydrauliques du sol issues d'une analyse 2d correspondent aux phenomenes tridimensionnels. Ces parametres caracterisent la geometrie des fractures, la topologie du reseau d'ecoulement et la texture des images 2d et 3d (porosite, distribution des largeurs, seuil de percolation, dimension fractale, etc. ). Bien qu'elles donnent une idee globale de la structure, les informations issues du scanner a rayons x ne permettent pas une comparaison precise. Par contre, l'analyse du volume obtenu a partir des 250 coupes seriees montre que les representations 2d et 3d presentent d'importantes similitudes morphologiques mais que les caracteristiques topologiques different fortement. En outre, l'etude theorique et experimentale montre que la migration des fluides par electro-osmose au sein des milieux poreux est d'autant plus intense que la taille des pores est faible et que la surface d'echange solide-liquide est grande. Par consequent, il semble que l'intensite de la decontamination des sols par champs electriques peut etre estimee par analyse d'images bidimensionnelles. Les logiciels d'acquisition, de traitement, d'analyse et de visualisation d'images 2d et 3d ont ete developpes sous x window
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14

Sahel, Ai͏̈cha. "Mise au point de logiciels de traitement d'images pour l'étude de la morphologie et du comportement hydraulique d'un réseau 2D de fractures dans des roches granitiques." Poitiers, 1996. http://www.theses.fr/1996POIT2271.

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Cette etude consiste a mettre au point des logiciels de traitement d'images consacres a la caracterisation d'un reseau 2d de fractures du point de vue morphologie et comportement hydraulique. L'etude de la connectivite et la quantification des differentes caracteristiques geometriques du reseau dans le plan sont faites a l'aide d'algorithmes issus de la morphologie mathematique, notamment la squelettisation. En effet, la plus grande partie de notre traitement repose sur le squelette des fractures. La reconstruction du graphe, decrit par le reseau de fractures, effectuee a l'aide d'une recherche arborescente automatique orientee suivant le sens d'ecoulement, a permis de dresser une carte de chemins de la circulation du fluide sous forme d'un fichier numerique. Ce fichier peut etre exploite pour une etude statistique (histogramme des longueurs, des largeurs, des orientations) ou pour le calcul de certains parametres geologiques (porosite, densite de fracturation, degre d'interconnectivite,). L'estimation de la valeur de la permeabilite a partir de l'image du reseau de fractures repose sur les dimensions des differentes fractures formant le reseau percolant. Celui-ci est extrait de facon automatique en fonction des conditions limites requises. La resistance hydraulique de chaque fracture etant calculee a l'aide de la loi de poiseuille, relative a un ecoulement laminaire, la permeabilite est evaluee donc a partir de la resistance hydraulique equivalente du reseau. Une etude comparative par analyse fractale du reseau de fractures a ete faite pour chercher une eventuelle correlation entre la permeabilite et la dimension fractale en fonction de la direction d'observation
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15

Mishra, Maneesh Kumar. "Development of orthopedic insoles and shoes 3D design process for atypical foot morphologies." Thesis, Lille 1, 2019. http://www.theses.fr/2019LIL1I091.

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Les besoins dans le secteur des semelles orthopédiques sont de plus en plus importants. Le but médical de ces prothèses plantaires est souvent de corriger la posture ou le déséquilibre biomécanique qui tend à causer de la douleur dans diverses zones du corps en fonction de la pathologie du patient. Les besoins en matière de personnalisation des chaussures orthopédiques augmentent également. Cela est dû à la progression des personnes de plus en plus obèses ou ayant des problèmes de diabète, voire d'autres maladies. Mais, le coût de ses produits peut varier de un à deux voire plus en fonction de la qualité du produit qui nécessite de l'adapter par un processus manuel à la morphologie du pied. Quel que soit le produit thérapeutique envisagé, le modèle économique n'est plus adapté aux besoins des patients et aux impératifs budgétaires de la sécurité sociale. Un nouveau processus de création est nécessaire et doit intégrer des outils numériques pour réduire ces coûts de fabrication, tout en améliorant la qualité des produits. Notre étude a été de faire le point sur les moyens de mesure utilisés et d'analyser la profession de podologue en mettant en évidence les aspects médicaux et économiques permettant de détecter la barrière technologique. La mise en œuvre du nouveau processus de conception de ces produits thérapeutiques pour les pieds a nécessité d'acquérir les connaissances morphologiques, anthropométriques et biomécanique du pied. Afin de caractériser dimensionnellement et morphologiquement le pied, un processus de détection de points anthropométriques et de création de courbes morphologiques a été mise en place. A ce stade de l'étude, il nous a été possible d'analyser une population d'individus mâle et femelle afin d'extraire les morphologies les plus représentatives d'une population cible. C'est à partir de méthodes de classification non supervisé que nous avons classé la population et détecté les centroïdes. Les techniques qui ont ensuite été utilisées pour détecter les points anthropométriques du pied ont été intégrées dans le processus de création de semelles customisées. En combinant cette technique qui extrait le contour englobant l'empreinte du pied, une méthode qui utilise ce contour pour créer la forme 2D de la semelle et la forme 3D de la ‘forme’ standard, nous avons créé la forme 3D de la semelle ajustée au pied et à la ‘forme’. Ce processus a montré le besoin de créer la ‘forme’ customisée de la personne. Après une analyse technique détaillée de la ‘forme’, nous avons mis en place un processus de création 3D de la ‘forme’ customisée. Ce processus prend directement en compte la forme du pied du patient sur laquelle nous détectons les points anthropométriques et créons les contours morphologiques de celui-ci. Ces contours servent d’appui à un espace d’aisance 3D sur lequel est accroché un réseau de courbes définissant le modèle filaire de la surface de la ‘forme’. Cette aisance spatiale est paramétrable afin de définir un confort spécifique au patient ou de contrôler ses besoins thérapeutiques. Ces deux processus à vocation customisation peuvent être connectés l'un à l'autre pour améliorer le confort au porté des chaussures pour un patient ou pour l'ensemble de la population en l'appliquant sur chaque centroïde de la classification
The needs in the sector of orthopedic insoles are becoming more important. The medical purpose of these plantar prostheses is often to correct the posture or biomechanical imbalance that tends to cause pain in various areas of the body depending on the pathology of the patient. The need for personalization of orthopedic shoes is also increasing. This is due to the progression of people who are increasingly obese or have problems with diabetes or other diseases. But, the cost of its products can vary from one to two or more depending on the quality of the product that requires adaptation by a manual process to the morpology of the foot. Whatever the therapeutic product envisaged, the economic model is no longer adapted to the needs of patients and the budgetary imperatives of social security. A new creative process is needed and must incorporate digital tools to reduce these manufacturing costs, while improving the quality of products. Our study was to take stock of the means of measurement used and analyze the profession of podiatrist by highlighting the medical and economic aspects to detect the technological barrier. The implementation of the new design process for these therapeutic foot products required the acquisition of morphological, anthropometric and biomechanical knowledge of the foot. In order to characterize the foot dimenally and morphologically, a process of detection of anthropometric points and creation of morphological curves has been implemented. At this stage of the study, we were able to analyze a population of male and female individuals to extract the most representative morphologies of a target population. It was from unsupervised classification methods that we classified the population and detected centroids. The techniques that were then used to detect the anthropometric points of the foot were incorporated into the process of creating customized insoles. By combining this technique that extracts the outline encompassing the footprint, a method that uses this outline to create the 2D shape of the insole and the 3D shape of the standard shoe-last, we have created the 3D shape of the insole adjusted to foot and the standard shoe-last. This process showed the need to create the custom shoe-last of the person. After a detailed technical analysis of the shoe-last, we set up a customized shoe-last 3D creation process. This process directly takes into account the shape of the patient's foot on which we detect the anthropometric points and create the morphological contours of it. These contours serve to support a 3D space of ease on which is hung a network of curves defining the wire model of the surface of the shoe-last. This spatial ease is parametrizable in order to define a specific comfort to the patient or control his therapeutic needs. These two customization processes can be connected to each other to improve the wearing comfort of shoes for a patient or for the entire population by applying it to each centroid of the classification
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16

Young, Sue Mea, and 楊淑媚. "Monte Carlo Simulations on the Evolution of 2D Surface Morphology." Thesis, 1993. http://ndltd.ncl.edu.tw/handle/33552203434942930895.

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17

Cheng, Hao-Yuan, and 鄭皓元. "The River Morphology Behavior Simulation after Dam Removal Using SRH-2D Numerical Model." Thesis, 2019. http://ndltd.ncl.edu.tw/cgi-bin/gs32/gsweb.cgi/login?o=dnclcdr&s=id=%22107NCHU5080049%22.&searchmode=basic.

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碩士
國立中興大學
水土保持學系所
107
Barrages are common hydraulic structures in Taiwan, such as the check dam, reservoir and weir. The aim of building the reservoir and weir are used to store water for people''s livelihood. Check dam is utilized to block sediment and effectively mitigate disasters to the downstream. However, as time passed by, barrages gradually lose its function of sediment storing gradually due to the serious deposition at upstream of the barrages. In addition, the shortage of sediment supply also induces significant scour downstream. The present study tries to adjust the barrages in order to effectively manage the sediment supply in downstream of the river . Ultimate targets are to let the river gradually return to the state of natural balance. In the research works, the SRH-2D numerical model is used to simulate Comb check dam located in Landao creek and Shigang Dam located in Daija river. The goals of research work are to assess the effects of fluvial change on adjusting the barrages in different ways, including the change of erosion and deposition, the degree of sediment transport, and influence area. The further work is to look for the proper and effective ways of adjusting the barrages to reduce the negative effects after adjusting the barrages. The numerical results show that more deposition appears in the downstream to cause the reduction of elevation between the upstream and downstream and gentler slope in the river, as more vertical bars of barrages are removed. The various types of adjusting the dam including four different ways. After 60 hours of flooding, the change of fluvial bed and degree of headward erosion are similar except Case five. Due to the steep slope and high concentration of sediment in Taiwan rivers. It is necessary to operate and manage the barrages normally. According to different demand conditions to adjust the barrages appropriately in order to achieve the balance and stability of the sediment supply. Finally, nature is the best way to make the river recover its original situation.
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18

Sochorová, Zuzana. "Sledování tvorby plovoucího biofilmu Mycobacterium smegmatis - morfologická a proteomová analýza." Master's thesis, 2012. http://www.nusl.cz/ntk/nusl-306649.

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Microorganisms grow in planktonic form, but more often they adhere to a number of surfaces and create three-dimensional structures called biofilms. Floating biofilms, which are formed at the water-air interface, are one of the life strategies, which the bacteria can take. Non-pathogenic Mycobacterium smegmatis was used as a laboratory model for the study of this kind of biofilm. The understanding of mechanisms of their formation of this species may be applicable to the pathogenic species of the genus Mycobacterium, study of which in the laboratory brings a number of disadvantages. This diploma thesis focuses on the morphological and proteome analysis of the M. smegmatis floating biofilm. Using a stereo microscope and scanning electron microscopy was observed that bacteria clump and create the "nucleation centres" at the beginning of the biofilm development. This centers grow to the surroundings and connect afterwards. In the later stages of the development the centers fuse in compact layer, which then grows into the compact and multilayer biofilm. The key method in this study was two-dimensional electrophoresis of proteins. The proteome analysis of floating biofilm was performed with this method. The preparation of protein samples and the method for protein concentration measurement was optimized....
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