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1

Lu, Gui-Fen, Min Zhu, Wei-Hua Zhu, and Zhong-Ping Ou. "2-Ethyl 4-methyl 5-ethyl-3-methyl-1H-pyrrole-2,4-dicarboxylate." Acta Crystallographica Section E Structure Reports Online 68, no. 2 (January 21, 2012): o483. http://dx.doi.org/10.1107/s1600536812001729.

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2

Choi, Hong Dae, Pil Ja Seo, Byeng Wha Son, and Uk Lee. "5-Ethyl-3-(3-fluorophenylsulfonyl)-2-methyl-1-benzofuran." Acta Crystallographica Section E Structure Reports Online 67, no. 5 (April 29, 2011): o1278. http://dx.doi.org/10.1107/s1600536811015443.

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3

Choi, Hong Dae, Pil Ja Seo, and Uk Lee. "5-Ethyl-3-(2-fluorophenylsulfonyl)-2-methyl-1-benzofuran." Acta Crystallographica Section E Structure Reports Online 68, no. 10 (September 5, 2012): o2838. http://dx.doi.org/10.1107/s1600536812036872.

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4

Stoermer, Martin, and John Pinhey. "Ethyl (E)-3-methyl-5-phenyl-2-pentenoate." Molecules 3, no. 8 (March 6, 1998): M51. http://dx.doi.org/10.3390/m51.

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5

Stoermer, Martin, and John Pinhey. "Ethyl (Z)-3-Methyl-5-phenyl-2-pentenoate." Molecules 3, no. 8 (March 6, 1998): M52. http://dx.doi.org/10.3390/m52.

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6

Choi, Hong Dae, Pil Ja Seo, Byeng Wha Son, and Uk Lee. "5-Ethyl-2-methyl-3-methylsulfinyl-1-benzofuran." Acta Crystallographica Section E Structure Reports Online 63, no. 7 (June 13, 2007): o3166. http://dx.doi.org/10.1107/s160053680702716x.

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7

Coles, Simon J., Holger Guthmann, Michael B. Hursthouse, and Patrick J. Murphy. "2-Ethyl 5-methyl 3-hydroxythiophene-2,5-dicarboxylate." Acta Crystallographica Section E Structure Reports Online 57, no. 10 (September 29, 2001): o976—o977. http://dx.doi.org/10.1107/s1600536801015379.

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8

Choi, Hong Dae, Pil Ja Seo, Byeng Wha Son, and Uk Lee. "5-Ethyl-2-methyl-3-phenylsulfonyl-1-benzofuran." Acta Crystallographica Section E Structure Reports Online 64, no. 6 (May 7, 2008): o1016. http://dx.doi.org/10.1107/s1600536808012877.

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9

Swamy, G. Y. S. K., K. Ravikumar, P. Narender, and V. Jayathirtha Rao. "Ethyl 3-(2-chloro-5-methyl-3-pyridyl)-3-hydroxy-2-methylenepropanoate." Acta Crystallographica Section E Structure Reports Online 63, no. 5 (April 6, 2007): o2188—o2189. http://dx.doi.org/10.1107/s1600536807014535.

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10

Swamy, G. Y. S. K., K. Ravikumar, P. Narender, and V. Jayathirtha Rao. "Methyl 3-(2-chloro-5-ethyl-3-pyridyl)-3-hydroxy-2-methylenepropanoate." Acta Crystallographica Section E Structure Reports Online 62, no. 4 (March 29, 2006): o1612—o1614. http://dx.doi.org/10.1107/s1600536806010646.

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The molecule of title compound, C12H14ClNO3, has an L-shaped conformation, with the methyl propanoate unit at the base. The molecules are linked via O—H...N hydrogen bonds into infinite chains of graph-set motif C(6) running along the b axis. In addition, the structure is further stabilized by C—H...O, C—H...Cl and C—H...π interactions.
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11

Elerman, Y., A. Elmali, E. Kendi, S. Özbey, and V. Ertüzün. "4-Ethyl-2-(2-hydroxynaphthylmethylidene)amino-5-methyl-3-thiophenecarbonitrile." Acta Crystallographica Section C Crystal Structure Communications 53, no. 8 (August 15, 1997): 1158–60. http://dx.doi.org/10.1107/s0108270196014515.

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12

Swamy, G. Y. S. K., K. Ravikumar, P. Narender, and V. Jayathirtha Rao. "2-[(2-Chloro-5-ethyl-3-pyridinyl)(hydroxy)methyl]acrylonitrile." Acta Crystallographica Section E Structure Reports Online 61, no. 3 (February 19, 2005): o708—o709. http://dx.doi.org/10.1107/s1600536805004563.

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13

Choi, Hong Dae, Pil Ja Seo, and Uk Lee. "3-(4-Bromophenylsulfonyl)-5-ethyl-2-methyl-1-benzofuran." Acta Crystallographica Section E Structure Reports Online 68, no. 12 (November 30, 2012): o3487. http://dx.doi.org/10.1107/s1600536812048313.

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14

Chandrakantha, T. N., Puttaraja Puttaraja, M. K. Kokila, and N. C. Shivaprakash. "Ethyl 5-Ethoxy-3-methyl-1H-indole-2-carboxylate." Acta Crystallographica Section C Crystal Structure Communications 54, no. 11 (November 15, 1998): 1685–87. http://dx.doi.org/10.1107/s010827019800568x.

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15

Wu, Hai-Qiang, Lin-Kun An, Zhi-Shu Huang, Lian-Quan Gu, Sharifuddin M. Zain, and Seik Weng Ng. "Ethyl 3-methyl-5-nitro-1H-imidazole-2-carboxylate." Acta Crystallographica Section E Structure Reports Online 60, no. 6 (May 15, 2004): o994—o995. http://dx.doi.org/10.1107/s1600536804011080.

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16

Choi, Hong Dae, Pil Ja Seo, Byeng Wha Son, and Uk Lee. "5-Ethyl-3-(4-Fluorophenylsulfonyl)-2-methyl-1-benzofuran." Acta Crystallographica Section E Structure Reports Online 66, no. 10 (September 18, 2010): o2575. http://dx.doi.org/10.1107/s1600536810036391.

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17

Choi, Hong Dae, Pil Ja Seo, Byeng Wha Son, and Uk Lee. "Ethyl 2-(5-methyl-3-methylsulfinyl-1-benzofuran-2-yl)acetate." Acta Crystallographica Section E Structure Reports Online 63, no. 9 (August 17, 2007): o3839. http://dx.doi.org/10.1107/s1600536807040263.

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18

Mohamed, Shaaban K., Joel T. Mague, Mehmet Akkurt, Alaa A. Hassan, and Mustafa R. Albayati. "Ethyl 2-(5-methoxy-2-methyl-1H-indol-3-yl)acetate." Acta Crystallographica Section E Structure Reports Online 69, no. 8 (July 13, 2013): o1242. http://dx.doi.org/10.1107/s1600536813018618.

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19

Choi, Hong Dae, Pil Ja Seo, Byeng Wha Son, and Uk Lee. "Ethyl 2-(3-ethylsulfinyl-5-methyl-1-benzofuran-2-yl)acetate." Acta Crystallographica Section E Structure Reports Online 65, no. 4 (March 14, 2009): o763. http://dx.doi.org/10.1107/s1600536809008460.

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20

Shi, Qiu-Zhong, Yong-Nan Cao, Shi-Bing Ma, Guo-Xi Wang, Guang-Fan Han, and Zheng Xing. "Synthesis of Novel Ethyl 1-aryl-3-methyl-8-oxo-1,8-dihydropyrano[2′,3′:4,5] Pyrimido[6,1-b]Quinazoline-2-carboxylate Derivatives." Journal of Chemical Research 40, no. 12 (December 2016): 767–71. http://dx.doi.org/10.3184/174751916x14798109099372.

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In this paper, a new series of ethyl 1-aryl-3-methyl-8-oxo-1,8-dihydropyrano[2′,3′:4,5]pyrimido[6,1-b]quinazoline-2-carboxylate derivatives was synthesised by the cyclisation of methyl anthranilate with ethyl 5-cyano-6-[(ethoxymethylene)amino]-2-methyl-4-aryl-4H-pyran-3-carboxylate derivatives, which were obtained from reaction of triethyl orthoformate with 6-amino-5-cyano-2-methyl-4-aryl-4H- pyran-3-carboxylate derivatives. The title compounds possessed good fluorescence properties. In addition, ethyl 5-cyano-6-[(ethoxymethylene) amino]-2-methyl-4-(p-tolyl)-4H-pyran-3-carboxylate and ethyl 3-methyl-8-oxo-1-(p-tolyl)-1,8-dihydropyrano[2′,3′:4,5]pyrimido[6,1-b] quinazoline-2-carboxylate were further determined by single crystal X-ray diffraction analysis.
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21

Senge, Mathias O. "Benzyl 4-ethyl-3-methyl-5-(phthalimidomethyl)pyrrole-2-carboxylate." Acta Crystallographica Section E Structure Reports Online 63, no. 8 (July 5, 2007): o3363. http://dx.doi.org/10.1107/s1600536807031820.

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22

Rathore, R. S., T. Narasimhamurthy, R. Venkat Ragavan, V. Vijayakumar, and S. Sarveswari. "3-Ethyl-4-methyl-1H-pyrazol-2-ium-5-olate." Acta Crystallographica Section E Structure Reports Online 67, no. 8 (July 23, 2011): o2129. http://dx.doi.org/10.1107/s160053681102808x.

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23

Radi, Smaail, and Hassan Lazrek. "1-[(2-Acetoxyethoxy)methyl]-3-ethyl-5-bromo-6-azauracil." Molecules 5, no. 12 (April 28, 2000): M154. http://dx.doi.org/10.3390/m154.

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24

Asiri, Abdullah Mohamed. "2-Ethyl 4-methyl 5-amino-3-methylthiophene-2,4-dicarboxylate." Molbank 2003, no. 3 (June 21, 2003): M340. http://dx.doi.org/10.3390/m340.

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25

Kim, D. G., K. Yu Petrova, T. V. Frolova, V. V. Sharutin, I. G. Ovchinnikova, M. A. Ezhikova, and M. I. Kodess. "Halocyclization of 3-Allyl-5-ethyl-6-methyl-2-thiouracil." Russian Journal of Organic Chemistry 55, no. 9 (September 2019): 1333–37. http://dx.doi.org/10.1134/s1070428019090112.

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26

Herrag, Leila, Rachid Touzani, Abdelkrim Ramdani, and Belkheir Hammouti. "1-{[Benzyl-(2-cyano-ethyl)-amino]-methyl}-5-methyl-1H-pyrazole-3-carboxylic acid ethyl ester." Molbank 2006, no. 5 (September 1, 2006): M494. http://dx.doi.org/10.3390/m494.

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27

Bardi, R., A. M. Piazzesi, and A. Del Pra. "Structure of ethyl 2-(3-methyl-1,2,4-oxadiazol-5-yl)-2-phenylhydrazonoethanoate." Acta Crystallographica Section C Crystal Structure Communications 49, no. 4 (April 15, 1993): 768–70. http://dx.doi.org/10.1107/s0108270192009806.

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28

Attayibat, Ahmed, Smaail Radi, Yahya Lekchiri, Abdelkrim Ramdani, and Maryse Bacquet. "1-(2-ethoxy-2-oxoethyl)-5-methyl-1H-pyrazole-3-ethyl carboxylate." Molbank 2007, no. 2 (May 31, 2007): M527. http://dx.doi.org/10.3390/m527.

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29

Bahadur, Sher, Itrat Anis, Muhammad Raza Shah, and Kuldip Singh. "2-(2-Methyl-5-nitro-1H-imidazol-1-yl)ethyl 3-bromobenzoate." Acta Crystallographica Section E Structure Reports Online 65, no. 5 (April 30, 2009): o1176. http://dx.doi.org/10.1107/s1600536809015499.

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30

Tan, Cheng-Xia, Jian-Ming Gu, De-Long Shen, Jian-Quan Weng, and De-Fang Fan. "3-(5-Ethyl-2-methyl-4-nitro-2H-pyrazole-3-carbonyl)oxazolidin-2-one." Acta Crystallographica Section E Structure Reports Online 60, no. 6 (May 29, 2004): o1084—o1085. http://dx.doi.org/10.1107/s1600536804012280.

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31

Meng, Ge, Mei Wang, Ya-Nan Cheng, Kai Chen, Jing Tong, and Jie-He Zhang. "3-Ethyl-2-(ethylimino)-4-methyl-2,3-dihydro-1,3-thiazole-5-carboxylate Ethyl Ester." Molbank 2016, no. 4 (November 29, 2016): M919. http://dx.doi.org/10.3390/m919.

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32

Sonar, Vijayakumar N., Sean Parkin, and Peter A. Crooks. "3-Ethyl-2-methyl-5-methylene-6,7-dihydroindol-4(5H)-one." Acta Crystallographica Section E Structure Reports Online 64, no. 1 (December 6, 2007): o158. http://dx.doi.org/10.1107/s1600536807063076.

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33

Yamamoto, N., K. Machida, T. Taga, and H. Ogoshi. "Structure of ethyl 4-acetyl-5-methyl-3-trifluoromethylpyrrole-2-carboxylate." Acta Crystallographica Section C Crystal Structure Communications 42, no. 11 (November 15, 1986): 1573–76. http://dx.doi.org/10.1107/s0108270186091436.

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34

Gainsford, Graeme J., and Jennifer M. Mason. "Ethyl 1-benzyl-4-hydroxy-2-methyl-5-oxopyrrolidine-3-carboxylate." Acta Crystallographica Section E Structure Reports Online 66, no. 4 (March 27, 2010): o957. http://dx.doi.org/10.1107/s1600536810010834.

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35

Pan, Yu-Zhen, You-Gui Wang, Jian-Hui Liu, and Li-Cheng Sun. "10-Ethyl-3-(5-methyl-1,3,4-oxadiazol-2-yl)-10H-phenothiazine." Acta Crystallographica Section E Structure Reports Online 68, no. 3 (February 10, 2012): o649. http://dx.doi.org/10.1107/s160053681200462x.

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36

Meng, Qing-Yang, Jiong Jia, Ling Yin, Fu-Xu Zhan, and Jian-Wu Wang. "Ethyl 3-{5-[(diethylamino)methyl]isoxazol-3-yl}-2-phenylpyrazolo[1,5-a]pyridine-5-carboxylate." Acta Crystallographica Section E Structure Reports Online 66, no. 4 (March 3, 2010): o723. http://dx.doi.org/10.1107/s1600536810004174.

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37

Yang, Guiqiu, Jiakuang Liang, Haibo Yu, and Bin Li. "2-(2-Chloropyridin-3-yl)-N-ethyl-4-methyl-1,3-oxazole-5-carboxamide." Acta Crystallographica Section E Structure Reports Online 66, no. 12 (November 13, 2010): o3154. http://dx.doi.org/10.1107/s1600536810045885.

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38

Seferoğlu, Zeynel, Tuncer Hökelek, Ertan Şahin, and Nermin Ertan. "3-(5-Ethyl-1,3,4-thiadiazol-2-yldiazenyl)-1-methyl-2-phenyl-1H-indole." Acta Crystallographica Section E Structure Reports Online 63, no. 2 (January 10, 2007): o568—o570. http://dx.doi.org/10.1107/s1600536807000165.

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39

Herrag, Leila, Rachid Touzani, Abdelkrim Ramdani, and Belkheir Hammouti. "1-{[Benzyl-(2-cyano-ethyl)-amino]-methyl}-5-methyl-1H-pyrazole-3-carboxylic acid methyl ester." Molbank 2006, no. 5 (September 1, 2006): M493. http://dx.doi.org/10.3390/m493.

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40

Liu, He-Chao, and Ya-Qing Feng. "3-Ethyl 5-methyl 4-(2-chlorophenyl)-6-methyl-2-[(2-phthalimidoethoxy)methyl]-1,4-dihydropyridine-3,5-dicarboxylate diethyl ether hemisolvate." Acta Crystallographica Section E Structure Reports Online 61, no. 9 (August 20, 2005): o3006—o3007. http://dx.doi.org/10.1107/s1600536805023950.

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41

Zhang, Dehua, Xiaoyan Zhang, and Yang Liu. "(Z)-Ethyl 3-(4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxamido)-2-cyano-3-(4-fluorophenyl)acrylate." Acta Crystallographica Section E Structure Reports Online 63, no. 10 (September 15, 2007): o4051. http://dx.doi.org/10.1107/s1600536807042699.

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42

Collins, DJ, TC Hughes, and WM Johnson. "Regiospecific Syntheses of the Monomethylated 3-Phenyldihydro-1,2,4-triazin-6(1H)-ones." Australian Journal of Chemistry 49, no. 4 (1996): 463. http://dx.doi.org/10.1071/ch9960463.

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Unambiguous syntheses of four unreported monomethylated derivatives of 3-phenyldihydro-1,2,4-triazin-6(1H)-ones, namely, the 1-methyl (2), 2-methyl (3), 4-methyl (4) and the imidic O-methyl derivative (5), are described. Regioselectivity was achieved for the synthesis of (2) by addition of ethyl glycinate to the 1,3-dipolar nitrile imine derived from N- methylbenzohydrazonoyl bromide hydrobromide (8). The key step for the synthesis of (3) was addition of benzyl 3-methylcarbazate (14) to ethyl N-[ chloro (phenyl) methylene ] glycinate (15b). The 4-methyl compound (4) was prepared by cycloaddition of ethyl N-( thiobenzoyl ) sarcosinate (21) with hydrazine hydrate, and the O-methyl compound (5) was prepared by reaction of sodium methoxide with 6-chloro-3-phenyl-4,5-dihydro-1,2,4-triazine (23).
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43

Kochikyan, T. V., M. A. Samvelyan, V. S. Arutyunyan, and A. A. Avetisyan. "Synthesis and Some Transformations of Ethyl 5-Alkoxymethyl-3-(2-methyl-3-oxobutyl)-2-oxotetrahydrofuran-3-carboxylates." Russian Journal of Organic Chemistry 39, no. 9 (September 2003): 1329–33. http://dx.doi.org/10.1023/b:rujo.0000010223.97769.33.

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44

He, Xiaoran, Bei Chen, Jianbo Wang, and Meiyu He. "Mass spectrometric study on methyl 5-methyl-2-oxo-3-[2-(4-R-phenyl)-1-ethyl]cyclopentanecarboxylates and methyl 2-oxo-5-(4-R-phenyl)-3-propylcyclopentanecarboxylates." Rapid Communications in Mass Spectrometry 11, no. 16 (October 30, 1997): 1818–22. http://dx.doi.org/10.1002/(sici)1097-0231(19971030)11:16<1818::aid-rcm992>3.0.co;2-q.

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45

Yuvaraj, Haldorai, S. Sundaramoorthy, D. Velmurugan, and Rajesh G. Kalkhambkar. "Ethyl 4-(3-bromophenyl)-6-methyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate." Acta Crystallographica Section E Structure Reports Online 66, no. 12 (November 27, 2010): o3325. http://dx.doi.org/10.1107/s1600536810049019.

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46

Wang, Ke, Weike Wang, Yifeng Wang, and Danqian Xu. "Ethyl 4-(4-chlorophenyl)-2-methyl-5-oxo-5,6,7,8-tetrahydroquinoline-3-carboxylate." Acta Crystallographica Section E Structure Reports Online 69, no. 7 (June 19, 2013): o1127. http://dx.doi.org/10.1107/s1600536813016541.

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47

Wang, Yu-Cheng, Xiang-Shan Wang, Zhao-Sen Zeng, and Da-Qing Shi. "Ethyl 5-cyano-4-(2,3-dimethoxyphenyl)-2-methyl-6-oxopyridine-3-carboxylate." Acta Crystallographica Section E Structure Reports Online 61, no. 10 (September 17, 2005): o3261—o3263. http://dx.doi.org/10.1107/s1600536805028679.

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48

Begum, Noor Shahina, and D. E. Vasundhara. "Ethyl 6-methyl-4-(3-nitrophenyl)-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate." Acta Crystallographica Section E Structure Reports Online 62, no. 12 (November 24, 2006): o5796—o5798. http://dx.doi.org/10.1107/s1600536806049270.

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49

Natarajan, S., P. Indumathi, B. Palakshi Reddy, V. Vijayakumar, and P. L. Nilantha Lakshman. "Ethyl 2-methyl-5-oxo-4-(3,4,5-trimethoxyphenyl)-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate." Acta Crystallographica Section E Structure Reports Online 66, no. 9 (August 11, 2010): o2240. http://dx.doi.org/10.1107/s1600536810030333.

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50

Youssif, Shaker, and Fatmah Agili. "One-pot Synthesis of Fused 2-Thiouracils: Pyrimidopyrimidines, Pyridopyrimidines and Imidazolopyrimidines." Zeitschrift für Naturforschung B 63, no. 7 (July 1, 2008): 860–64. http://dx.doi.org/10.1515/znb-2008-0709.

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Several 6-substitued-1-methyl-2,5,7,8-tetrahydro-2-thiopyrimido[4,5-d]pyrimidine-4-ones and ethyl 7-amino-5-aryl-1-methyl-4-oxo-1,2,3,4-tetrahydro-2-thiopyrido[2,3-d]pyrimidines-6-carboxylates were synthesized by treatment of 6-amino-1-methyl-2-thiouracil with primary amines and formalin (40%), and with ethyl 3-aryl-2-cyanoacrylate respectively. 8-Substituted-7-hydroxy-3- methyl-2-thioxanthines were synthesized by the treatment of 6-amino-1-methyl-5-nitroso-2-thiouracil with benzylidene-anilines. Elemental and spectral analyses were performed for the new compounds.
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