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1
Kerr, Andrew, George A. Jenner, and Brian J. Fryer. "Sm–Nd isotopic geochemistry of Precambrian to Paleozoic granitoid suites and the deep-crustal structure of the southeast margin of the Newfoundland Appalachians." Canadian Journal of Earth Sciences 32, no. 2 (February 1, 1995): 224–45. http://dx.doi.org/10.1139/e95-019.
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In the Eastern Central Mobile Belt of the Newfoundland Appalachians, late Precambrian basement inliers have εNd from −3 to +2, but Cambro-Ordovician metasedimentary rocks have initial εNd below −7. This region is inferred to have an "inverted" crustal residence structure, which influenced subsequent Appalachian-cycle magmatism. Ordovician and Silurian granitoid suites have εNd of −8 to −2, bracketing both basement and cover, but peraluminous, "S-type" granites have the lowest εNd. Devonian granites have initial εNd values from −5 to +1, and low εNd is associated with peraluminous character. These Paleozoic granites show geographic trends, with lowest εNd values in areas where metasedimentary rocks are abundant. They are suggested to contain anatectic material from both Precambrian basement and metasedimentary cover, but some "I-type" suites probably also include a mantle-derived component. In the adjacent Avalon Zone, Precambrian plutonic suites mostly have εNd from +1 to +6, but there are negative εNd values (−8 to −4) in the westernmost Avalon Zone. Devonian plutonic suites mostly have εNd from +2 to +5. Thus, the Precambrian crust of the Avalon Zone is largely "juvenile," except at its westernmost edge. Contrasts across the Eastern Central Mobile Belt–Avalon Zone boundary, defined by the Dover–Hermitage Bay fault system, indicate a major, crustal-scale structure, and suggest an isotopically distinct "central block" beneath the central Appalachian Orogen, rather than a simple extension of "Avalonian" crust. Similar geographic–isotopic patterns have been reported in Nova Scotia and New Brunswick, suggesting that this pattern represents a first-order deep-crustal subdivision of the northern Appalachian Orogen.
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Arsouze, T., J. C. Dutay, M. Kageyama, F. Lacan, R. Alkama, O. Marti, and C. Jeandel. "A modeling sensitivity study of the influence of the Atlantic meridional overturning circulation on neodymium isotopic composition at the Last Glacial Maximum." Climate of the Past 4, no. 3 (September 4, 2008): 191–203. http://dx.doi.org/10.5194/cp-4-191-2008.
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Abstract. Using a simple parameterisation that resolves the first order global Nd isotopic composition (hereafter expressed as εNd in an Ocean Global Circulation Model, we have tested the impact of different circulation scenarios on the εNd in the Atlantic for the Last Glacial Maximum (LGM), relative to a modern control run. Three different LGM freshwater forcing experiments are performed to test for variability in the εNd oceanic distribution as a function of ocean circulation. Highly distinct representations of the ocean circulation are generated in the three simulations, which drive significant differences in εNd, particularly in deep waters of the western part of the basin. However, at the LGM, the Atlantic is more radiogenic than in the modern control run, particularly in the Labrador basin and in the Southern Ocean. A fourth experiment shows that changes in Nd sources and bathymetry drive a shift in the εNd signature of the basin that is sufficient to explain the changes in the εNd signature of the northern end-member (NADW or GNAIW glacial equivalent) in our LGM simulations. All three of our LGM circulation scenarios show good agreement with the existing intermediate depth εNd paleo-data. This study cannot indicate the likelihood of a given LGM oceanic circulation scenario, even if simulations with a prominent water mass of southern origin provide the most conclusive results. Instead, our modeling results highlight the need for more data from deep and bottom waters from western Atlantic, where the εNd change in the three LGM scenarios is the most important (up to 3 εNd. This would also aid more precise conclusions concerning the evolution of the northern end-member εNd signature, and thus the potential use of εNd as a tracer of past oceanic circulation.
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Mikhailik, P. E., I. A. Vishnevskaya, E. V. Mikhailik, M. G. Blokhin, M. V. Chervyakovskaya, V. A. Rashidov, and X. Ren. "Genesis and Nd Isotope Composition of Ferromanganese Deposits of the Sea of Okhotsk and the Kuril Island Arc." Russian Geology and Geophysics 62, no. 9 (September 1, 2021): 1074–87. http://dx.doi.org/10.2113/rgg20194142.
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Abstract —The Nd isotope composition of ferromanganese deposits (FMD) from the central part of the Sea of Okhotsk and the Kuril island arc has been studied. The results showed that diagenetic samples from the Deryugin Basin have a heterogeneous Nd isotope composition. The positive εNd values here might be both due to the input of a terrigenous impurity and due to diffuse endogenetic element supply. The FMD samples from the Sonne underwater ridge show a εNd value specific to seawater (–3.2). The εNd value of hydrogenetic FMD from Volcano 7.14 is –3.4, which corresponds to the εNd value of the Pacific water. The FMD samples from Volcano 5.5 are characterized by εNd = –2.0. The higher εNd value might be due to a moderate dilution of the hydrothermal fluid by seawater and might also indicate the presence of volcanic fragments in the FMD samples. The highest εNd value (+4.4) has been established for volcaniclastic sandstone saturated with Fe and Mn hydroxides. It points to a mixing of volcanomictic and hydrothermal materials.
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Bock, B., S. M. McLennan, and G. N. Hanson. "The Taconian orogeny in southern New England: Nd-isotope evidence against addition of juvenile components." Canadian Journal of Earth Sciences 33, no. 12 (December 1, 1996): 1612–27. http://dx.doi.org/10.1139/e96-122.
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Nd-isotope data for pre-Taconian (meta)sedimentary and igneous rocks, syn-Taconian (meta)sedimentary rocks, and Late Ordovician–Silurian plutonic rocks indicate that the Ordovician Taconian orogeny did not add significant amounts of juvenile crust to the Laurentian margin in southern New England. Nd-isotope compositions of Grenvillian crust and Late Proterozoic to Early Cambrian rift sediments range from εNd of −3.1 to −6.6 at 450 Ma. Sedimentary rocks deposited during the Cambrian and the early Middle Ordovician, which represent the drift stage of Laurentia, and earliest Taconian sedimentary rocks show more negative εNd(450 Ma), with a range from −11.7 to −13.3. Sedimentary rocks deposited in response to the Taconian orogeny have uniform εNd(450 Ma) values of about −8. Middle to Late Ordovician and Permian plutonic rocks from southwestern Connecticut have εNd(450 Ma) values of −2 to −5, which indicates that these rocks contain older crustal components. Rocks with juvenile Nd characteristics are the early Paleozoic Maltby Lake Volcanics (εNd(450 Ma) +8) from southwestern Connecticut, and Middle Ordovician igneous samples from the Hawley Formation (εNd(450 Ma) +6 to −0.6) in Massachusetts.
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Khim, Boo-Keun, Keiji Horikawa, Yoshihiro Asahara, Ji-Eun Kim, and Minoru Ikehara. "Detrital Sr–Nd isotopes, sediment provenances and depositional processes in the Laxmi Basin of the Arabian Sea during the last 800 ka." Geological Magazine 157, no. 6 (November 23, 2018): 895–907. http://dx.doi.org/10.1017/s0016756818000596.
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Abstract87Sr/86Sr ratios and εNd values of detrital particles at International Ocean Discovery Program (IODP) Site U1456 in the Laxmi Basin of the Arabian Sea were measured to trace changes in sediment provenance over glacial–interglacial cycles. Based on the correlation of planktonic foraminiferal (Globigerinoides ruber) δ18O fluctuations with the LR04 stack of benthic foraminifera δ18O values, combined with shipboard biostratigraphic and palaeomagnetic data, the studied interval spans ∼1.2 Ma. Over the past 800 ka, 87Sr/86Sr values ranged from 0.711 to 0.726 while εNd values ranged between −12.5 and −7.3 in the detrital particles. By comparing 87Sr/86Sr ratios and εNd values of the possible sources of river sediments with our data, we found that sediments in the Laxmi Basin were influenced to various degrees by proportions of at least three sediment sources (i.e. Tapi River, Narmada River and Indus River). The Indus River might be a more important contributor to glacial sediments. Although 87Sr/86Sr ratios and εNd values varied quasi-cyclically, this pattern did not correspond precisely to the glacial–interglacial cycles. In particular, low-magnetic-susceptibility (low-MS) intervals coinciding with pelagic carbonates were characterized by low 87Sr/86Sr ratios and high εNd values, whereas high-MS intervals matching turbidite deposits showed high 87Sr/86Sr ratios and low εNd values. Thus, this study reveals that differences in the depositional processes between glacial and interglacial periods, governed by changes in sea level and monsoon activity, are an important factor in deciding 87Sr/86Sr ratios and εNd values of the detrital fraction in the Indus Fan of the Arabian Sea.
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Dubois-Dauphin, Quentin, Paolo Montagna, Giuseppe Siani, Eric Douville, Claudia Wienberg, Dierk Hebbeln, Zhifei Liu, et al. "Hydrological variations of the intermediate water masses of the western Mediterranean Sea during the past 20 ka inferred from neodymium isotopic composition in foraminifera and cold-water corals." Climate of the Past 13, no. 1 (January 10, 2017): 17–37. http://dx.doi.org/10.5194/cp-13-17-2017.
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Abstract. We present the neodymium isotopic composition (εNd) of mixed planktonic foraminifera species from a sediment core collected at 622 m water depth in the Balearic Sea, as well as εNd of scleractinian cold-water corals (CWC; Madrepora oculata, Lophelia pertusa) retrieved between 280 and 442 m water depth in the Alboran Sea and at 414 m depth in the southern Sardinian continental margin. The aim is to constrain hydrological variations at intermediate depths in the western Mediterranean Sea during the last 20 kyr. Planktonic (Globigerina bulloides) and benthic (Cibicidoides pachyderma) foraminifera from the Balearic Sea were also analyzed for stable oxygen (δ18O) and carbon (δ13C) isotopes. The foraminiferal and coral εNd values from the Balearic and Alboran seas are comparable over the last ∼ 13 kyr, with mean values of −8.94 ± 0.26 (1σ; n = 24) and −8.91 ± 0.18 (1σ; n = 25), respectively. Before 13 ka BP, the foraminiferal εNd values are slightly lower (−9.28 ± 0.15) and tend to reflect higher mixing between intermediate and deep waters, which are characterized by more unradiogenic εNd values. The slight εNd increase after 13 ka BP is associated with a decoupling in the benthic foraminiferal δ13C composition between intermediate and deeper depths, which started at ∼ 16 ka BP. This suggests an earlier stratification of the water masses and a subsequent reduced contribution of unradiogenic εNd from deep waters. The CWC from the Sardinia Channel show a much larger scatter of εNd values, from −8.66 ± 0.30 to −5.99 ± 0.50, and a lower average (−7.31 ± 0.73; n = 19) compared to the CWC and foraminifera from the Alboran and Balearic seas, indicative of intermediate waters sourced from the Levantine basin. At the time of sapropel S1 deposition (10.2 to 6.4 ka), the εNd values of the Sardinian CWC become more unradiogenic (−8.38 ± 0.47; n = 3 at ∼ 8.7 ka BP), suggesting a significant contribution of intermediate waters originated from the western basin. We propose that western Mediterranean intermediate waters replaced the Levantine Intermediate Water (LIW), and thus there was a strong reduction of the LIW during the mid-sapropel ( ∼ 8.7 ka BP). This observation supports a notable change of Mediterranean circulation pattern centered on sapropel S1 that needs further investigation to be confirmed.
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Samson, Scott D., Sandra M. Barr, and Chris E. White. "Nd isotopic characteristics of terranes within the Avalon Zone, southern New Brunswick." Canadian Journal of Earth Sciences 37, no. 7 (July 1, 2000): 1039–52. http://dx.doi.org/10.1139/e00-015.
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Nd isotopic data are presented for rock units in four terranes within the traditional Avalon Zone of southern New Brunswick. Initial εNd values for igneous rocks within the Caledonia terrane range from -1.6 to +4.6, whereas values for sedimentary rocks range from -8.4 to +3.6. A granite within the Kingston terrane has εNd(438 Ma) = +4.0. Nd isotopic compositions for the Kingston and Caledonia terranes are similar to those of the Mira terrane in Cape Breton Island, the Antigonish Highlands of Nova Scotia, and plutonic rocks of eastern Newfoundland. Each of these regions may be a dismembered part of a single terrane, the Avalon terrane sensu stricto. Initial εNd values for rocks from the Brookville terrane range from -1.3 to +2.8. The Coverdale anorthosite within the Brookville terrane has a present day εNd value of -12.1 and a depleted mantle model age of 1.3 Ga, similar to Mesoproterozoic anorthosites in Laurentia. Clastic sedimentary rocks in the Green Head Group have εNd(750 Ma) values of -2.0 and -10.9. Viewed as a whole, the Brookville terrane is isotopically more evolved than the Caledonia terrane. Initial εNd values for rocks in the New River terrane range from -2.9 to 0.0. The Nd isotopic composition of the Brookville and New River terranes are thus similar to one another and have isotopic character similar to that of the Bras d'Or terrane of Cape Breton Island. It is suggested that all three regions belong to a single terrane (Bras d'Oria).
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Garzione, Carmala N., P. Jonathan Patchett, Gerald M. Ross, and JoAnne Nelson. "Provenance of Paleozoic sedimentary rocks in the Canadian Cordilleran miogeocline: a Nd isotopic study." Canadian Journal of Earth Sciences 34, no. 12 (December 1, 1997): 1603–18. http://dx.doi.org/10.1139/e17-129.
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Nd isotopes and trace elements in sedimentary rocks of the Yukon, the Northwest Territories, and northern British Columbia are used to examine the source of sediments in the Canadian Cordilleran miogeocline. Previous Nd isotope studies in southern Alberta demonstrated that strata of Neoproterozoic to Late Ordovician age were derived from Archean and Proterozoic Canadian Shield sources, whereas by the Late Devonian, a shift of 6 εNd units to younger crustal sources (εNd (T) = −6 to −9) had occurred. In this study, we found that the shift to younger crustal Nd isotopic signatures in the Yukon and Northwest Territories occurred much earlier than in southern Alberta. Cambrian and older strata have εNd(T) values of −10.0 to −21.1, consistent with derivation from Canadian Shield sources. Lower Ordovician through Permian strata in the Yukon and Northwest Territories, including the Innuitian-derived Imperial Assemblage, have εNd(T) values of −5 to −11.4. In northern British Columbia, the shift to a younger source reflects a wider range of εNd(T) values, from -−8.7 to −14.6 in Middle Ordovician through Middle Devonian strata, suggesting continued input from Canadian Shield sources. By the Middle Devonian, a complete shift to younger crustal signatures (εNd(T) = −5.9 to −10.5) had occurred in northern British Columbia. Several sources for the more juvenile sediments include (1) a mixture of locally erupted volcanic rocks with Canadian Shield sources, (2) a Grenville source, and (3) an Innuitian source. We propose that Ordovician to Lower Devonian strata were derived from a mixture of locally erupted, juvenile volcanics and pre-Cambrian Canadian Shield sources, and post-Middle Devonian strata were sourced from the Innuitian orogen in the Canadian Arctic.
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Chauvel, C., N. T. Arndt, S. Kielinzcuk, and A. Thom. "Formation of Canadian 1.9 Ga old continental crust. I: Nd isotopic data." Canadian Journal of Earth Sciences 24, no. 3 (March 1, 1987): 396–406. http://dx.doi.org/10.1139/e87-042.
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A Nd isotopic study was carried out on 1.9−1.8 Ga rocks from two parts of the Trans-Hudson Orogen in northern Canada. The first part is the Reindeer Lake Zone in the Churchill Province in Saskatchewan, where a variety of volcanic, granitoid, and sedimentary rocks are preserved in several lithotectonic belts that border a reworked Archean craton to the northwest. The second area comprises the Ottawa and Belcher islands, in Hudson Bay, and the Fox River volcanics, in Manitoba. These form part of the Circum-Superior Belt, a band of basaltic volcanics and sedimentary rocks that overlies the Archean Superior craton.From U–Pb zircon ages, Pb–Pb ages, and Sm–Nd ages, Nd initial isotopic compositions were calculated for all analyzed samples. In the Saskatchewan terrains, we obtained a large range of εNd values, from +5 to −8. The highest values (+4 to +5) come from two volcanic-dominated belts (Flin Flon and Western la Ronge), lower values (~+2) characterize intervening sediment-dominated domains (Eastern La Ronge, Glennie Lake, and Kisseynew), and still lower values (−1 to −4) were found in migmatitic and granitoid belts adjacent to the reworked Archean craton in the northwest. Each lithotectonic belt has its own characteristic, restricted range of εNd values, and, with few exceptions, there is no correlation between εNd and rock type; i.e., in individual belts, volcanics, granites, and sediments have very similar εNd values.In the Circum-Superior Belt, three lava flows from the Ottawa Islands have εNd values ranging from +4.5 to 0, and samples from the Belcher Islands have values ranging from +3.5 to −9.These results are explained by mixing between mantle-derived rocks and variable amounts of Archean continental crustal rocks. Assuming that 1.9 Ga ago the mantle had an εNd value of +5 and Archean crust had an εNd value of −12, we calculate proportions of Archean crustal material in Trans-Hudson rocks ranging from ~2 to 35 %, increasing systematically toward the Archean platform. The mean Archean component is about 8%: this area of Proterozoic continental crust is clearly dominated by material derived directly from the mantle.The similarity between the εNd values of sediments, granites, and volcanics in the Trans-Hudson Orogen suggests that sedimentary processes played a dominant role in transporting Archean detritus from eroding Archean continental areas into basins, where it mixed with mantle-derived volcanic material and melted to form granitoids.
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Fryer, Brian J., John D. Greenough, and J. Victor Owen. "Iapetus Ocean floor stuffed into a suture zone: xenolith Nd isotopic evidence for Dunnage-equivalent basement in central Newfoundland." Canadian Journal of Earth Sciences 34, no. 10 (October 1, 1997): 1392–400. http://dx.doi.org/10.1139/e17-111.
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Granulite-facies xenoliths from Late Jurassic alkaline lamprophyres may represent basement to the Dunnage Zone in north-central Newfoundland (Notre Dame Bay area). At 143 Ma the xenoliths had positive εNd values between 0.9 and 4.7. They give Nd depleted mantle model ages around 700 Ma and have trace element and major element compositions reminiscent of oceanic arc-related intermediate volcanic and sedimentary rocks. Their positive εNd values and associated "young" Nd model ages argue against their representing Grenvillian crust. Similarly, Gander Zone basement to the east produced granitic rocks with strongly negative εNd values unlike those of the xenoliths. Positive εNd values for Avalonian granites indicate that the xenoliths could represent Avalon-type basement; however, there are 100–200 km of Gander and Dunnage zone rocks between the xenoiith locality and the Avalon Zone. Early orogenic volcanic rocks and some late orogenic to postorogenic granitic rocks in the central to northern portion of the Gander Zone have positive εNd values, consistent with extraction from a depleted mantle at the same time as material forming the xenoliths. Similarities between the xenolith chemistry and that of early orogenic (Cambrian) arc-related intermediate volcanic rocks of the Dunnage Zone indicate that the xenoliths and basement in the Notre Dame Bay area are composed of Iapetus Ocean floor relics (volcanic or volcanic-rich sedimentary rocks) stuffed into a collisional suture zone during ocean closure.
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Udoratina, O. V., K. V. Kulikova, A. S. Shuyskiy, A. A. Sobolevа, V. L. Andreichev, I. I. Golubeva, and V. A. Kapitanova. "GRANITOID MAGMATISM IN THE NORTH OF THE URALS: U–Pb AGE, EVOLUTION, SOURCES." Geodynamics & Tectonophysics 12, no. 2 (June 23, 2021): 287–309. http://dx.doi.org/10.5800/gt-2021-12-2-0525.
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This work presents the summarization of U–Pb (SIMS, TIMS) zircon dates and petrogeochemical signatures of granitoids of the north of the Urals (Polar, Subpolar, and Northern Urals) obtained over the last decade. Granitе melts were formed from melting of different substrates, highly heterogeneous in composition and age, at all geodynamic stages distinguished in the studied area. Preuralides include island arc–accretionary (735–720 Ma, 670 Ma), collisional (650–520 Ma), and rift-related (520–480 Ma) granitoids. Uralides includes primitive island-arc granitoids (460–429 Ma), mature island-arc granitoids (412–368 Ma), early collisional (360–316 Ma) and late collisional (277–249 Ma) granitoids. As a result, the general trend of variations of oxygen (δ18OZrn, ‰), neodymium (εNd(t)wr), and hafnium (εHf(t)Zrn) isotope compositions identified in time. Mantle isotope compositions (δ18OZrn (+5.6), εNd(t)wr (+1.7), εHf(t)Zrn (+8.7...+10.6)), common for island arc granitoids (Preuralides) are changed by crustal–mantle ones (δ18OZrn (+7.2...+8.5), εNd(t)wr (–4.8...+1.8), εHf(t)Zrn (+2.1 to +13)), typical of collisional granites. According to this, the crustal matter played a significant role during the formation of the latter. The crustal-mantle isotope compositions are changed by the mantle ones, characteristic of rift-related (δ18OZrn (+4.7...+7), εNd(t)wr (+0.7...+5.6), εHf(t)Zrn (–2.04...+12.5)) and island-arc (Uralides; δ18OZrn (+4.2...+5.7), εNd(t)wr (+4.1...+7.4), εHf(t)Zrn (+12...+15.2)) granitoids.
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Stone, P., and J. A. Evans. "Silurian provenance variation in the Southern Uplands terrane, Scotland, assessed using neodymium isotopes and linked with regional tectonic evolution." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 91, no. 3-4 (2000): 447–55. http://dx.doi.org/10.1017/s0263593300008294.
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ABSTRACTThe progressive changes in the provenance of Silurian greywacke turbidites in the Southern Uplands terrane reflect geotectonic events at the Laurentian continental margin during closure of the Iapetus Ocean. In the northern Gala Group, juvenile andesitic detritus in some beds gives εNd values no lower than −4·2; more commonly, quartzo-feldspathic greywackes have εNd values in the −5·5 to −6·7 range, produced by the mixing of juvenile plutonic and Proterozoic basement detritus during arc unroofing. In the southern (younger) Gala Group, Proterozoic εNd values range down from −7·7 to −11·2 with only sporadic evidence for a juvenile component. An abrupt change is seen between the Gala Group and its tectonostratigraphical successor, the Hawick Group. In the latter, εNd values have a compact range between −4·7 and −6·6, indicating the renewed dominance of a more juvenile, plutonic provenance. Regional variations in the Sr/Rb ratio suggest that this was more evolved than the source of the Gala Group plutonic material. The Wenlock greywackes of the Riccarton Group have εNd values in the range −5·1 to −7·8, overlapping with the Hawick Group and with coeval greywackes from both the Midland Valley and Lakesman terranes. Overall, the data support proposals that the Iapetus Ocean had effectively closed by mid-Silurian times. Conversely, data from greywacke boulders in the basal Old Red Sandstone conglomerate of the Midland Valley terrane militate against its Wenlock juxtaposition with the Southern Uplands.
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Xu, Jianzhong, Guangming Yu, Shichang Kang, Shugui Hou, Qianggong Zhang, Jiawen Ren, and Dahe Qin. "Sr-Nd isotope evidence for modern aeolian dust sources in mountain glaciers of western China." Journal of Glaciology 58, no. 211 (2012): 859–65. http://dx.doi.org/10.3189/2012jog12j006.
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AbstractIn order to apportion the dust sources of mountain glaciers in western China, the Sr-Nd isotopic compositions of insoluble particles were determined in snow samples collected from 13 sites. The combined plot of 87Sr/86Sr and εNd(0) demonstrates a distinctive geographic pattern over western China, which can be classified into three regions from north to south. Samples from the Altai mountains show the lowest 87Sr/86Sr ratio and the highest εNd(0) value, similar to the data of deserts in the north of China such as the Gurbantunggut desert. Samples from the southern Tibetan Plateau (TP) and Himalaya show the highest 87Sr/86Sr and lowest εNd(0) values, resembling the local and regional dust sources found in the southern TP and Himalaya-India region. Samples from the Tien Shan and northern Tibetan Plateau exhibit intermediate 87Sr/86Sr and εNd(0) values, similar to the data reported for the northern margin of the TP (NM_TP). However, three sampling sites, JMYZ (Jiemayangzong) located in the Himalaya and ZD (Zadang) and YL (Yulong) located in the southeast TP, presented distinctive Sr-Nd isotopic signatures typical of the NM_TP, suggesting potential long-range and high-altitude dust transport across the TP.
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Barr, Sandra M., and Ernst Hegner. "Nd isotopic compositions of felsic igneous rocks in Cape Breton Island, Nova Scotia." Canadian Journal of Earth Sciences 29, no. 4 (April 1, 1992): 650–57. http://dx.doi.org/10.1139/e92-056.
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Nd isotopic data from 18 felsic plutonic and volcanic units in Cape Breton Island show variations consistent with other geological and geophysical evidence for at least three distinct terranes. A ca. 1.2 Ga syenite considered to be part of Grenvilleage basement exposed in the northwestern part of the island yields an initial εNd value of +0.4 and a depleted-mantle model age (TDM) of 1.66 Ga, suggesting substantial involvement of older (Archean or Early Proterozoic) crust in its petrogenesis. A TDM of 1.38 Ga indicated by Nd isotopic data for a Devonian granite spatially associated with the syenite is also consistent with the presence of older crust in that part of Cape Breton Island. In contrast, Silurian rhyolite and Devonian granites from the Aspy terrane have TDM ranging from 0.7 to 1.1 Ga and initial εNd between +2.8 and −1.2, and overlap in isotopic characteristics with late Precambrian and Early Ordovician plutons in the Bras d'Or terrane that yield TDM of 0.9–1.1 Ga and initial εNd of +1.4 to −1.8. The relatively small variation in εNd and TDM in these terranes suggests that old crust like that under the Blair River Complex may not be present. Granitic plutons and rhyolite in the Mira terrane of southeastern Cape Breton Island have a range in TDM (0.8–1.2 Ga) similar to that of the Aspy and Bras d'Or terranes, but initial εNd values ranging from +0.8 to +5.0 indicate more juvenile crust. This juvenile crust also appears to be present under southern New Brunswick and eastern Newfoundland and may be characteristic of the Avalon terrane.
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CHEN, BIN, and BOR-MING JAHN. "Geochemical and isotopic studies of the sedimentary and granitic rocks of the Altai orogen of northwest China and their tectonic implications." Geological Magazine 139, no. 1 (January 2002): 1–13. http://dx.doi.org/10.1017/s0016756801006100.
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The Altai orogen (northwest China) represents the southwestern margin of the Central Asian Orogenic Belt. Geochemical and Nd–Sr isotope analyses were carried out on the Palaeozoic sedimentary and granitic rocks in order to trace their sources and to evaluate the pattern of continental growth of the orogen. Nd isotopic data for both the granites and sediments suggest a significant proportion of middle Proterozoic crust beneath the Altai orogen. However, addition of juvenile material (arc/back-arc oceanic crust) during Palaeozoic times is also significant. Trace elements and isotopic data of sediments suggest their sources were immature. They represent mixtures between a Palaeozoic juvenile component and an evolved continental crust. The early Palaeozoic sediments show εNd(T) = −3.4 to −5.0, TDM = 1.5–1.8 Ga, and ISr = 0.710–0.712. They represent a passive margin setting, with a predominance of evolved crustal material in the source. The Devonian sequences, however, might have been deposited in a back-arc basin setting, produced by subduction of the Junggar oceanic crust along the Irtysh fault. A significant addition of arc material into the sedimentary basin is responsible for the highly variable εNd values (−6 to 0) and ISr (0.711–0.706). The Carboniferous rocks were also deposited in a back-arc basin setting but with predominantly arc material in the source as suggested by an abrupt increase in εNd(T) (+6 to +3) and decrease in ISr (0.7045–0.7051). Voluminous syn-orogenic granitoids have εNd(T) = +2.1 to −4.3, ISr = 0.705–0.714 and TDM = 0.7–1.6 Ga. They were not derived by melting of local metasedimentary rocks as suggested by previous workers, but by melting of a more juvenile source at depth. Post-orogenic granites have higher εNd(T) (∼ +4.4) than the syn-orogenic granitoids, indicating their derivation from a deeper crustal level where juvenile crust may predominate.
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Barrie, C. Tucker, and Steven B. Shirey. "Nd- and Sr-isotope systematics for the Kamiskotia–Montcalm area: implications for the formation of late Archean crust in the western Abitibi Subprovince, Canada." Canadian Journal of Earth Sciences 28, no. 1 (January 1, 1991): 58–76. http://dx.doi.org/10.1139/e91-006.
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Geochemistry and Nd isotopic compositions are used to characterize mantle and crustal sources and to provide constraints on petrogenetic models for tholeiitic, calc-alkalic, and lamprophyric suites in the Kamiskotia–Montcalm area. The Kamiskotia gabbroic complex (KGC) and cogenetic, bimodal volcanic rocks have εNd(t) = +2.2 to +2.6, consistent with a direct derivation from a long-term, light rare-earth element (LREE)-depleted mantle. The Montcalm gabbroic complex has decreasing εNd(t) upsection from +2.8 to +1.0, consistent with contamination by long-term, LREE-enriched (with respect to the long-term, LREE-depleted Abitibi mantle) crust during fractionation. Two calc-alkalic lamprophyre samples, characterized by large-ion lithophile element (LILE) and LREE enrichment and high MgO, Ni, and Cr contents, have εNd(t) of +2.5 and +2.8, indicating a derivation from a depleted mantle source that had undergone recent trace-element enrichment. A different lamprophyre suite is extremely LILE and LREE enriched and has an εNd(t) of +1.0, indicating a derivation from a slightly different source that had earlier LREE enrichment. Granitoid rocks internal and external to greenstone belt rocks have εNd(t) = +2.5 to +3.8 and +0.6 to −0.4, respectively. The lower values provide additional evidence for the existence of LREE-enriched crust in this area.Considering these data along with other radiogenic isotope studies, a petrogenetic and tectonic model is suggested for the crustal development of the southern Abitibi Subprovince. From >2740 to 2698 Ma—the major period of volcanic activity—komatiitic and tholeiitic suites and one lamprophyre suite were derived from a uniformly LREE-depleted mantle reservoir with εNd(t) = +2 to +3. Calc-alkalic granitoids were emplaced generally after 2700 Ma. Their long-term, LREE-depleted and LREE-enriched Nd isotopic signatures are similar to signatures in continental-arc settings (e.g., the Coastal Batholith of Peru). Form 2690 to 2670 Ma, when transpressional tectonism prevailed, mantle-derived magmatism was represented by long-term, LREE-enriched (εNd(t) = +1 to +2) lamprophyric and alkalic volcanic suites.The Kamiskotia suite has a seven-point, whole-rock – mineral isochron Sm–Nd age of 2710 ± 30 Ma, identical to U–Pb zircon ages for the suite, indicating closed-system behavior. An Rb–Sr mineral – whole-rock isochron age from one KGC sample is 2450 ± 30 Ma, identical to U–Pb ages for the Hearst–Matachewan dike swarm, a prominent feature in the KGC area. Regression of whole-rock and mineral-isotope data for one granitoid sample with a U–Pb zircon age of 2696 ± 1.5 Ma gives identical ages of 2530 ± 30 Ma in the Sm–Nd and Rb–Sr systems. The latter data add to an increasing body of evidence for cryptic, late thermal events after granitoid–greenstone belt development in the southern Abitibi Subprovince.
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Nicholson, Suzanne W., Klaus J. Schulz, Steven B. Shirey, and John C. Green. "Rift-wide correlation of 1.1 Ga Midcontinent rift system basalts: implications for multiple mantle sources during rift development." Canadian Journal of Earth Sciences 34, no. 4 (April 1, 1997): 504–20. http://dx.doi.org/10.1139/e17-041.
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Magmatism that accompanied the 1.1 Ga Midcontinent rift system (MRS) is attributed to the upwelling and decompression melting of a mantle plume beneath North America. Five distinctive flood-basalt compositions are recognized in the rift-related basalt succession along the south shore of western Lake Superior, based on stratigraphically correlated major element, trace element, and Nd isotopic analyses. These distinctive compositions can be correlated with equivalent basalt types in comparable stratigraphic positions in other MRS localities around western Lake Superior. Four of these compositions are also recognized at Mamainse Point more than 200 km away in eastern Lake Superior. These regionally correlative basalt compositions provide the basis for determining the sequential contribution of various mantle sources to flood-basalt magmatism during rift development, extending a model originally developed for eastern Lake Superior. In this refined model, the earliest basalts were derived from small degrees of partial melting at great depth of an enriched, ocean-island-type plume mantle source (εNd(1100) value of about 0), followed by magmas representing melts from this plume source and interaction with another mantle source, most likely continental lithospheric mantle (εNd(1100) < 0). The relative contribution of this second mantle source diminished with time as larger degree partial melts of the plume became the dominant source for the voluminous younger basalts (εNd(1100) value of about 0). Towards the end of magmatism, mixtures of melts from the plume and a depleted asthenospheric mantle source became dominant (εNd(1100) = 0 to +3).
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Haynes, Shannon J., Kenneth G. MacLeod, Jean-Baptiste Ladant, Andrew Vande Guchte, Masoud A. Rostami, Christopher J. Poulsen, and Ellen E. Martin. "Constraining sources and relative flow rates of bottom waters in the Late Cretaceous Pacific Ocean." Geology 48, no. 5 (February 27, 2020): 509–13. http://dx.doi.org/10.1130/g47197.1.
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Abstract Geochemical data suggest that ocean circulation patterns changed over a period of long-term cooling during the last 10 m.y. of the Cretaceous (late Campanian–Maastrichtian). Proposed changes include enhanced deep-water formation in the South Atlantic and/or Indian sectors of the Southern Ocean, initiation or enhanced deep-water formation in the North Atlantic, and alternating regions of deep convection in the North and South Pacific. Existing geochemical data do not allow simple confirmation or rejection of any of these scenarios. To test Pacific circulation during the Maastrichtian, we measured neodymium isotopic (εNd) values from four Pacific Deep Sea Drilling Project and Ocean Drilling Program sites and compare results both to Earth system model simulations using Maastrichtian paleogeography and to previous studies. Pacific εNd results consistently show a small negative εNd excursion during a well-documented, ∼1–3 m.y. early Maastrichtian cooling pulse (EMCP) but no other consistent trends across the late Campanian–late Maastrichtian interval (∼10 m.y.). Model results show that different CO2 forcings lead to changes in rates, but not patterns, of circulation. These combined results support the existence of a sustained source region for intermediate and deep waters in the southwestern Pacific throughout the late Campanian–Maastrichtian and indicate that changes in εNd values during the EMCP reflect an increased rate of overturning in the Pacific rather than changes in the source area of Pacific bottom waters.
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Ayache, Mohamed, Jean-Claude Dutay, Thomas Arsouze, Sidonie Révillon, Jonathan Beuvier, and Catherine Jeandel. "High-resolution neodymium characterization along the Mediterranean margins and modelling of <i>ε</i><sub>Nd</sub> distribution in the Mediterranean basins." Biogeosciences 13, no. 18 (September 22, 2016): 5259–76. http://dx.doi.org/10.5194/bg-13-5259-2016.
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Abstract. An extensive compilation of published neodymium (Nd) concentrations and isotopic compositions (Nd IC) was realized in order to establish a new database and a map (using a high-resolution geological map of the area) of the distribution of these parameters for all the Mediterranean margins. Data were extracted from different kinds of samples: river solid discharge deposited on the shelf, sedimentary material collected on the margin or geological material outcropping above or close to a margin. Additional analyses of surface sediments were done in order to improve this data set in key areas (e.g. Sicilian strait). The Mediterranean margin Nd isotopic signatures vary from non-radiogenic values around the Gulf of Lion, (εNd values ∼ −11) to radiogenic values around the Aegean and the Levantine sub-basins up to +6. Using a high-resolution regional oceanic model (1/12° of horizontal-resolution), εNd distribution was simulated for the first time in the Mediterranean Sea. The high resolution of the model provides a unique opportunity to represent a realistic thermohaline circulation in the basin and thus apprehend the processes governing the Nd isotope distribution in the marine environment. Results are consistent with the preceding conclusions on boundary exchange (BE) as an important process in the Nd oceanic cycle. Nevertheless this approach simulates a too-radiogenic value in the Mediterranean Sea; this bias will likely be corrected once the dust and river inputs will be included in the model. This work highlights that a significant interannual variability of εNd distribution in seawater could occur. In particular, important hydrological events such as the Eastern Mediterranean Transient (EMT), associated with deep water formed in the Aegean sub-basin, could induce a shift in εNd at deep/intermediate depths that could be noticeable in the eastern part of the basin. This underlines that the temporal and geographical variations of εNd could represent an interesting insight of Nd as tracer of the Mediterranean Sea circulation, in particular in the context of palaeo-oceanographic applications.
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Robinson, Suzanne, Ruza F. Ivanovic, Lauren J. Gregoire, Julia Tindall, Tina van de Flierdt, Yves Plancherel, Frerk Pöppelmeier, Kazuyo Tachikawa, and Paul J. Valdes. "Simulating marine neodymium isotope distributions using Nd v1.0 coupled to the ocean component of the FAMOUS–MOSES1 climate model: sensitivities to reversible scavenging efficiency and benthic source distributions." Geoscientific Model Development 16, no. 4 (February 22, 2023): 1231–64. http://dx.doi.org/10.5194/gmd-16-1231-2023.
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Abstract. The neodymium (Nd) isotopic composition of seawater is a widely used ocean circulation tracer. However, uncertainty in quantifying the global ocean Nd budget, particularly constraining elusive non-conservative processes, remains a major challenge. A substantial increase in modern seawater Nd measurements from the GEOTRACES programme, coupled with recent hypotheses that a seafloor-wide benthic Nd flux to the ocean may govern global Nd isotope distributions (εNd), presents an opportunity to develop a new scheme specifically designed to test these paradigms. Here, we present the implementation of Nd isotopes (143Nd and 144Nd) into the ocean component of the FAMOUS coupled atmosphere–ocean general circulation model (Nd v1.0), a tool which can be widely used for simulating complex feedbacks between different Earth system processes on decadal to multi-millennial timescales. Using an equilibrium pre-industrial simulation tuned to represent the large-scale Atlantic Ocean circulation, we perform a series of sensitivity tests evaluating the new Nd isotope scheme. We investigate how Nd source and sink and cycling parameters govern global marine εNd distributions and provide an updated compilation of 6048 Nd concentrations and 3278 εNd measurements to assess model performance. Our findings support the notions that reversible scavenging is a key process for enhancing the Atlantic–Pacific basinal εNd gradient and is capable of driving the observed increase in Nd concentration along the global circulation pathway. A benthic flux represents a major source of Nd to the deep ocean. However, model–data disparities in the North Pacific highlight that under a uniform benthic flux, the source of εNd from seafloor sediments is too non-radiogenic in our model to be able to accurately represent seawater measurements. Additionally, model–data mismatch in the northern North Atlantic alludes to the possibility of preferential contributions from “reactive” non-radiogenic detrital sediments. The new Nd isotope scheme forms an excellent tool for exploring global marine Nd cycling and the interplay between climatic and oceanographic conditions under both modern and palaeoceanographic contexts.
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Smith, Alan D., Alan D. Brandon, and Richard StJ Lambert. "Nd–Sr isotope systematics of Nicola Group volcanic rocks, Quesnel terrane." Canadian Journal of Earth Sciences 32, no. 4 (April 1, 1995): 437–46. http://dx.doi.org/10.1139/e95-037.
Full textAbstract:
Volcanic rocks of the Nicola Group belong to an arc built on the western margin of the Quesnel terrane in the Late Triassic to Early Jurassic. Low-K – high-K compositional types define a Rb–Sr isochron of 222 ± 15 Ma with initial 87Sr/86Sr = 0.70367 ± 2. The corresponding Nd isotopic compositions of these samples (εNd(222 Ma) = +5.1 to +7.8) fall within the range for early Mesozoic island arcs. A comparable range of εNd(222 Ma) (+5.0 to +7.9) in picrite–shoshonite samples precludes generation of increasingly potassic magmas by progressive metasomatism of the mantle wedge alone. Source-region heterogeneity, possibly imparted by changes in the composition of subducted slab components or interaction with amphibole or phlogopite in the source remnant of an earlier (Permian) arc on the Quesnel terrane, is required to account for geochemical differences between these rock suites. Crustal contamination is severely limited from the high εNd values, such that continental basement now underlying the Quesnel terrane is likely an artifact of later terrane obduction.
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Nosova, А. А., N. М. Lebedeva, А. А. Vozniak, L. V. Sazonova, Yu О. Larionova, and I. А. Kondrashev. "Nd-isotope effects through factional crystallisation-assimilation (AFC) processes in the continental crust, heterogeneous in age: the example of ferrobasalts from the Ladoga Graben (Karelia, Russia)." Doklady Rossijskoj akademii nauk. Nauki o Zemle 515, no. 1 (September 30, 2024): 74–85. http://dx.doi.org/10.31857/s2686739724030106.
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Petrography, geochemistry and isotope geochemistry of the Mesoproterozoic volcanic rocks occurred as lava flows and the Valaam sill in the Ladoga rift, have been studied. The Ladoga rift is located in the area of thrusting of the Palaeoproterozoic Svekofennian orogenic complexes onto the Archean Karelian craton. Ferrobasites of close composition and geological position in lava flows and sill have different Nd isotopic composition, differing by 5 units εNd(t): –4…-5 in ferrobasalts of lava flows and a very low-radiogenic Nd isotopic composition in mafic rocks of the sill (εNd(t) to –11 for ferrogabbro), and identical to the isotopic composition of its acidic rocks (εNd(t) to –11 for granophyres). It is shown that in the crust, heterogeneous in age, the process of fractional crystallisation along the tholeiitic trend combined with assimilation of melt from wall rocks can be an effective mechanism for forming such “paradoxical” features of the Nd isotopic composition. The isotopic composition of sill rocks indicates the probable presence of Mesoarchean blocks in the lower crust of the Ladoga graben region.
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Stevenson, R. K., and A. Turek. "An isotopic study of the Island Lake Greenstone Belt, Manitoba: crustal evolution and progressive cratonization in the late Archean." Canadian Journal of Earth Sciences 29, no. 10 (October 1, 1992): 2200–2210. http://dx.doi.org/10.1139/e92-174.
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Three new U–Pb zircon ages are reported for units within the Island Lake Greenstone Belt in northern Manitoba: the Jubilee Island dacite (2761 ± 12 Ma), the Chapin Bay tonalite (2748 ± 3 Ma), and the Wassagomach tonalité (2778 ± 5 Ma). Rb–Sr data suggest a mild metamorphic event about 2736 ± 67 Ma ago. Basalts within the basal Hayes River Group (2860–2900 Ma) appear to be derived from a time-averaged, Nd-depleted mantle with εNd values between +0.78 and +2.1. Lower εNd values (< +0.31) are found in volcanic and intrusive rocks of the same age, implying contamination by or remelting of preexisting crust to form the more felsic derivatives. εNd values of early tonalitic, trondhjemitic, and granitic plutons (2729–2900 Ma) decrease from +0.31 to −1.8 as the plutons become younger, and are indicative of a period of dominantly intracrustal recycling processes in the Island Lake region. It is suggested that this trend records the evolution of the Island Lake region through extensive intracrustal melting and recycling from a variably contaminated volcanic arc to a small mature craton. Uplift associated with the plutonism resulted in sedimentation of the Island Lake Group (2729–2749 Ma), followed by renewed granitic plutonism of the Late Intrusive Suite (2699–2729 Ma). εNd values of these units range from +3 to −3, suggesting renewed interaction of depleted mantle with the Island Lake crust. This possibly resulted from magmatism associated with the accretion of the Island Lake Terrane to the rest of the Superior Province.
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Turkina, O. M. "Variation in Trace Element and Isotope Composition of Neoarchean Mafic Granulites of the Southwest Siberian Craton: A Consequence of Various Mantle Sources or Crustal Contamination." Петрология 31, no. 2 (March 1, 2023): 182–201. http://dx.doi.org/10.31857/s0869590323020061.
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The paper presents geochemical and isotopic characteristics of Neoarchean (2.7–2.66 Ga) mafic granulites of the Sharyzhalgay uplift in the southwestern Siberian craton. Mafic and predominant felsic granulites compose fragments of the metamorphic complex among the Neoarchean and Paleoproterozoic granitoids. Mafic granulites are characterized by the mineral association Cpx + Pl ± Hbl ± Opx ± Qz and include two types with different major and immobile trace element contents. The dominant rocks of the first type have a wide range of Mg# and concetrations of TiO2 and immobile trace elements (REE, Zr, Nb, and most positive εNd(Т) va-lues. The first type of mafic granulites show elevated (La/Sm)n and enrichment in Th and LREE relative Nb which is typical of basalts of subduction origin or crustal contaminated basalts. The absence of negative correlation between (La/Sm)n and εNd(Т) and a clear positive correlation of TiO2 with Nb testify against the effect of crustal contamination on the composition of the mafic granulites. The magmatic protoliths of first type of mafic granulites are suggested to form by the melting of depleted peridotites of the subcontinental mantle which metasomatized by melts formed from basalts or terrigenous sediments of the subducting plate. Mafic granulites of the second type have a narrower range of Mg#, TiO2 content, positive εNd(Т), flat rare earth patterns and no subduction signatures, which indicates an asthenospheric depleted mantle source. Ma-fic granulites contaminated by the Paleoarchean crust are characterized by increased (La/Sm)n, depletion of Nb relative to Th and LREE, and negative εNd(Т) values. Post magmatic influence of granitoids lead to the enrichment of mafic granulites in biotite and apatite, an increased in concentrations of K2O, P2O5, a signi-ficant enrichment of Zr, Nb, Th, LREE, and negative εNd(Т) values. The difference between mafic granulites of the first and second types is not resulted from crustal contamination, but is due to the melting of two types of sources: asthenospheric and subcontinental lithospheric mantle. The subcontinental lithospheric mantle of the Irkut block was isotopically depleted for the Neoarchean time (∼2.7 Ga), and its enrichment in incompatible trace elements, presumably by felsic melts generated from the rocks of subducting plate, immediately preceded mafic magmatism.
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Goulart, Luís Emanoel Alexandre, and Mauricio Antonio Carneiro. "Evolution of arc magmatism in the Carmópolis de Minas Layered Suite, Minas Gerais, Brazil: Sm-Nd and Rb-Sr isotope geochemistry." Rem: Revista Escola de Minas 66, no. 4 (December 2013): 447–54. http://dx.doi.org/10.1590/s0370-44672013000400007.
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The Carmópolis de Minas Layered Suite (CMLS) is a Neoarchean Unit metamorphosed at amphibolite- to granulite-facies conditions, comprised of metaultramafic rocks, amphibolites and metarhyolites. The CMLS is marked by two distinct phases of tholeiitic and calc-alkaline magmatism. Previous geochemical data and regional constraints suggest that the CMLS is possibly a metamorphosed arc-tholeiitic suite of the type boninite-basalt-andesite-rhyolite, interpreted in this study as a dismembered remnant of the juvenile oceanic arc. The rocks of tholeiitic affinity record a signature of depleted to enriched mantle with positive to weakly negative εNd(t) and predominantly positive εSr(t) values, indicating some degree of crustal assimilation. The rocks of calc-alkaline affinity present a signature of juvenile crust with εNd(t) close to the CHUR and weakly positive εSr(t) values. The Sm-Nd isochron age of 2736 ± 300 Ma obtained with εNd(i) = +0.4, suggests the edification of an intra-oceanic arc during the late phases of the Rio das Velhas Tectonothermal Event. The arc evolution involved tholeiitic magmatism in the early stages in association with calc-alkaline magmatism, of probably anatectic character, in the tardy-orogenic stages.
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Kerr, Andrew, and Richard J. Wardle. "Definition of an Archean – Proterozoic crustal suture by isotopic studies of basement intersections from offshore wells in the southern Labrador Sea." Canadian Journal of Earth Sciences 34, no. 2 (February 1, 1997): 209–14. http://dx.doi.org/10.1139/e17-017.
Full textAbstract:
Eight hydrocarbon exploration wells in the southern Labrador Sea penetrated Precambrian basement rocks, adjacent to the course of a Lithoprobe marine seismic reflection survey. The rock types are mostly Early Proterozoic (1870–1800 Ma) calc-alkaline plutonic rocks or their metamorphic derivatives, but one example is a Middle Proterozoic (1270 Ma) anorogenic intrusion. These samples of buried basement document a transition from juvenile Proterozoic crust in the southeast (shown by εNd from +0.8 to +2.2) to ancient Archean crust in the northwest (shown by εNd from −2.7 to −7.0). However, initial Sr isotope ratios do not show such a clear pattern. The transition in εNd is similar to results of onland studies in Labrador and formerly adjacent south Greenland, and delimits the hidden edge of the North Atlantic Archean craton within the Early Proterozoic Makkovikian–Ketilidian Orogen. These results from close to the seismic profile confirm that regional reflectivity contrasts on either side of the isotopic boundary record fundamental differences between local Archean and Proterozoic crust. Southeast-dipping reflectors that broadly correspond with the boundary zone probably represent a collisional suture zone, along which juvenile terranes were probably placed structurally above the Archean craton.
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Xu, Wentao, Fulai Liu, Wang Xu, Huining Wang, Lei Ji, Fang Wang, and Dan Wang. "Geochemical and Geochronological Constraints of Permian-Triassic Magmatism on Oceanic Subduction and Continental Collision during the Eastern Paleo-Tethyan Evolution." Minerals 12, no. 5 (May 17, 2022): 633. http://dx.doi.org/10.3390/min12050633.
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The Jinshajiang–Ailaoshan–Song Ma orogenic belt (JASB), as a vital segment of the eastern Paleo-Tethyan tectonic zone, is one of the most important zones in which to study the Paleo-Tethyan tectonic evolution. We have undertaken an integrated geochronological, petrological, and geochemical study of mafic rocks from the JASB to reveal the subduction and closure processes of the eastern Paleo-Tethyan Ocean during the Permian to Triassic. In conjunction with previous magmatic and metamorphic records in the JASB, three important tectonic stages are identified: (1) Early Permian to Early Triassic (ca. 288–248 Ma). Most of the Early Permian to Early Triassic mafic rocks have normal mid-ocean ridge basalt (N-MORB)- or enriched MORB (E-MORB)-like rare earth elements (REE) and trace element-normalized patterns with positive εNd(t) and εHf(t) values and negative Nb and Ta anomalies. Their La/Nb ratios and εNd(t) values show that approximately 3%–15% of slab-derived fluid accounts for the generation of these rocks. These characteristics suggest that the mafic rocks formed in an arc/back-arc basin setting at this stage. Additionally, the Early Permian mafic rocks are mainly exposed in the Jomda–Weixi–Yaxuanqiao–Truong Son magmatic rock belt (JYTB) on the western side of the JASB, indicating that the westward subduction of the Jinshajiang–Ailaoshan–Song Ma Paleo-Tethys Ocean (JASO) began in the Early Permian. Middle Permian mafic rocks are exposed in the Ailaoshan-Day Nui Con Voi metamorphic complex belt and the JYTB on both sides of the JASB. We propose that the bipolar subduction of the JASO occurred in the Middle Permian and ended in the Early Triassic. (2) Middle Triassic (ca. 248–237 Ma). The mafic rocks at this stage have LREE- and LILE-enriched patterns, negative Nb and Ta anomalies and negative εNd(t) values. Their variable εHf(t), εNd(t) values and La/Nb ratios show that these mafic rocks were highly affected by crustal material (ca. 16%). Considering the Middle Triassic high-pressure (HP) metamorphism and massive Al-enriched felsic magmatism in the JASB, these rocks may have formed in a collisional setting between the South China Block (SCB) and the North Qiangtang–Simao–Indochina Block (QSIB) during the Middle Triassic. (3) Late Triassic (ca. 235–202 Ma). The mafic rocks at this stage have negative εNd(t) and εHf(t) values and show terrestrial array characteristics. The εNd(t) values and La/Nb ratios show that approximately 30% of crustal components account for the generation of these rocks. Combined with the contemporaneous bimodal magma and metamorphism during the Late Triassic, we suggest that these rocks may have formed in a postcollisional extensional setting associated with magma diapir.
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Kiseleva, Olga, Pavel Serov, Evgenia Airiyants, Aleksey Travin, Dmitriy Belyanin, Brain Nharara, and Sergey Zhmodik. "Nd-Sr Isotopic Study of Magmatic Rocks and 40Ar/39Ar Dating of the Mafic Dike of the Proterozoic Ulan-Sar’dag Ophiolite Mélange (Southern Siberia, East Sayan, Middle Belt, Russia)." Minerals 12, no. 1 (January 14, 2022): 92. http://dx.doi.org/10.3390/min12010092.
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We report the first radiogenic Nd-Sr isotope data in the magmatic rocks island-arc ophiolite assemblage from the middle branch of the East Sayan ophiolite complexes to better constrain geodynamic processes in this segment of the CAOB in southern central Siberia. The magmatic rocks belong to the following geochemical types: (1) Ensimatic island-arc boninites; (2) island-arc assemblage; (3) enriched basalts of mid-ocean ridges; and (4) oceanic island-like basalts. The boninites have a positive value εNd (T), which is generated from a depleted mantle source (N-MORB). The island-arc assemblage has negative or slightly positive εNd (T) and was formed from an enriched mantle source due to the subduction of terrigenous rocks. The source of the terrigenous material was most likely the rocks of the Archean TTG (Trondhjemite Tonalite Granodiorite) complex of the Gargan block. Isotopic ratios for E-MOR and OIB-like basalts are characterized by positive or slightly negative values of εNd (T). The mafic dike, which crosscut ophiolite rocks, corresponds to OIB-like basalts. The values of εNd (T), measured 87Sr/86Sr and I (Sr), in the mafic dike correspond to the EM I mantle source. The E-MOR and OIB-like basalts appear to be formed in late-stage asthenospheric mantle melting via the decompression melting processes. The obtained isotope geochemical data for the E-MOR and OIB-like basalts probably indicate the mixing of island-arc melts with asthenospheric melts. We undertook 40Ar/39Ar dating of the mafic dike, which crosscut the ophiolite unit. The mafic dike has a whole-rock 40Ar/39Ar weighted mean plateau age of 799 ± 11 Ma. The dating constrains the minimum age of the ophiolite and island-arc magmatism in the region.
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Ladant, Jean-Baptiste, Christopher J. Poulsen, Frédéric Fluteau, Clay R. Tabor, Kenneth G. MacLeod, Ellen E. Martin, Shannon J. Haynes, and Masoud A. Rostami. "Paleogeographic controls on the evolution of Late Cretaceous ocean circulation." Climate of the Past 16, no. 3 (June 9, 2020): 973–1006. http://dx.doi.org/10.5194/cp-16-973-2020.
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Abstract. Understanding of the role of ocean circulation on climate during the Late Cretaceous is contingent on the ability to reconstruct its modes and evolution. Geochemical proxies used to infer modes of past circulation provide conflicting interpretations for the reorganization of the ocean circulation through the Late Cretaceous. Here, we present climate model simulations of the Cenomanian (100.5–93.9 Ma) and Maastrichtian (72.1–66.1 Ma) stages of the Cretaceous with the CCSM4 earth system model. We focus on intermediate (500–1500 m) and deep (> 1500 m) ocean circulation and show that while there is continuous deep-water production in the southwestern Pacific, major circulation changes occur between the Cenomanian and Maastrichtian. Opening of the Atlantic and Southern Ocean, in particular, drives a transition from a mostly zonal circulation to enhanced meridional exchange. Using additional experiments to test the effect of deepening of major ocean gateways in the Maastrichtian, we demonstrate that the geometry of these gateways likely had a considerable impact on ocean circulation. We further compare simulated circulation results with compilations of εNd records and show that simulated changes in Late Cretaceous ocean circulation are reasonably consistent with proxy-based inferences. In our simulations, consistency with the geologic history of major ocean gateways and absence of shift in areas of deep-water formation suggest that Late Cretaceous trends in εNd values in the Atlantic and southern Indian oceans were caused by the subsidence of volcanic provinces and opening of the Atlantic and Southern oceans rather than changes in deep-water formation areas and/or reversal of deep-water fluxes. However, the complexity in interpreting Late Cretaceous εNd values underscores the need for new records as well as specific εNd modeling to better discriminate between the various plausible theories of ocean circulation change during this period.
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Pasquier, Benoît, Sophia K. V. Hines, Hengdi Liang, Yingzhe Wu, Steven L. Goldstein, and Seth G. John. "GNOM v1.0: an optimized steady-state model of the modern marine neodymium cycle." Geoscientific Model Development 15, no. 11 (June 16, 2022): 4625–56. http://dx.doi.org/10.5194/gmd-15-4625-2022.
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Abstract. Spatially distant sources of neodymium (Nd) to the ocean that carry different isotopic signatures (εNd) have been shown to trace out major water masses and have thus been extensively used to study large-scale features of the ocean circulation both past and current. While the global marine Nd cycle is qualitatively well understood, a complete quantitative determination of all its components and mechanisms, such as the magnitude of its sources and the paradoxical conservative behavior of εNd, remains elusive. To make sense of the increasing collection of observational Nd and εNd data, in this model description paper we present and describe the Global Neodymium Ocean Model (GNOM) v1.0, the first inverse model of the global marine biogeochemical cycle of Nd. The GNOM is embedded in a data-constrained steady-state circulation that affords spectacular computational efficiency, which we leverage to perform systematic objective optimization, allowing us to make preliminary estimates of biogeochemical parameters. Owing to its matrix representation, the GNOM model is additionally amenable to novel diagnostics that allow us to investigate open questions about the Nd cycle with unprecedented accuracy. This model is open-source and freely accessible, is written in Julia, and its code is easily understandable and modifiable for further community developments, refinements, and experiments.
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Kim, Daeyeong, Sang-Bong Yi, Hyeoncheol Kim, Taehwan Kim, Taehoon Kim, and Jong Ik Lee. "Geochemistry and Geochronology of Early Paleozoic Intrusive Rocks in the Terra Nova Bay Area, Northern Victoria Land, Antarctica." Minerals 11, no. 7 (July 20, 2021): 787. http://dx.doi.org/10.3390/min11070787.
Full textAbstract:
The Terra Nova Intrusive Complex (TNIC) in northern Victoria Land, Antarctica, results from widespread magmatism during the Early Paleozoic Ross Orogeny. According to field relationships, geochemistry, and geochronology data, the northern part of the TNIC comprises the Browning Intrusive Unit (BIU), which is associated with an arc crustal melting including migmatization of the Wilson Metamorphic Complex, and the later Campbell Intrusive Unit (CIU), which is attributed to the mantle and crustal melting processes. Zircon U-Pb ages suggest Late Neoproterozoic to Early Cambrian protolith with Late Cambrian metamorphism (502 ± 15 Ma) in the WMC, Late Cambrian formation (~500 Ma) of the BIU, and Early Ordovician formation (~480–470 Ma) of the CIU. Sr-Nd isotopic characteristics of the BIU indicate predominant crustal component (εNd(t) = −8.7 to −8.9), whereas those of the CIU reflect both mantle (εNd(t) = 1.8 to 1.6) and crustal (εNd(t) = −4.0 to −7.5) compositions. These results suggest that the northern TNIC magmatism occurring at ~500–470 Ma originated from partial melting of the mantle–mafic crust components and mixing with felsic crust components. By integrating the results with previous studies, the TNIC is considered to be formed by a combination of the mantle and mafic crust melting, crustal assimilation, felsic crust melting, and magma mixing during the Ross Orogeny.
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Seifert, Karl E., and James F. Olmsted. "Geochemistry of North Shore Hypabyssal dikes and sills in the Midcontinent Rift of Minnesota: an example the 47th Avenue sill." Canadian Journal of Earth Sciences 41, no. 7 (July 1, 2004): 829–42. http://dx.doi.org/10.1139/e04-038.
Full textAbstract:
This study presents geochemical data for several of the numerous small to large dikes and sills, including the 47th Avenue sill, exposed along the shore of Lake Superior in and north of Duluth, Minnesota. These intrusions are late magmatic features of the Proterozoic Midcontinent Rift System and together form the North Shore Hypabyssal Group. The dikes are geochemically distinct from the sills, and, when the two are exposed together, the younger dike intrudes the older sill. Dikes are primitive with Mg# up to 68, have positive εNd values, and are oriented approximately northsouth with steep westerly or near vertical dips. The older sills are more evolved, usually have εNd values near or below 0, and have the same gentle easterly dip as the thick sequence of North Shore Volcanic Group flows they intrude. Dike compositions correlate best with a mixture of widespread basalt compositions types 4 and 5, with primitive geochemistry and positive εNd values, whereas sill compositions are similar to widespread basalt composition type 4 typical of most North Shore Volcanic Group flows. The 47th Avenue sill in Duluth is an evolved single intrusion North Shore Hypabyssal Group diabase sill with trough banding, sharp lower and upper contacts, and a spectacular fractured and undulating roof zone containing blocks of the overlying ferroandesite flow.
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Whalen, Joseph B., Leslie R. Fyffe, Frederick J. Longstaffe, and George A. Jenner. "The position and nature of the Gander–Avalon boundary, southern New Brunswick, based on geochemical and isotopic data from granitoid rocks." Canadian Journal of Earth Sciences 33, no. 2 (February 1, 1996): 129–39. http://dx.doi.org/10.1139/e96-013.
Full textAbstract:
In southern New Brunswick, the Gander–Avalon boundary is obscured by boundary-parallel faults and various cover sequences. Siluro-Devonian granites, which intrude unequivocal Gander or Avalon rocks, display exclusively negative (−1.9 ± 1.0) and positive (+1.9 ± 0.7) εNd(T) signatures, respectively. Such contrasting Nd isotopic signatures, combined with other geochemical differences between plutons, are potentially valuable tools for terrane analysis. Nine small Devonian plutons intruding the boundary zone fall into contrasting geochemical groups with (La/Lu)N <4 and >4. The former are topaz-bearing granites, while the latter are volcanic-arc-type granites. Except for one pluton, with an εNd(T) signature of –2.0, εNd(T) values range from –0.4 to +0.7, spanning the gap between "type" Avalon and "type" Gander plutons. These results suggest the plutons sampled either (i) stratigraphically overlapping or tectonically interleaved Gander and Avalon basement rocks, or (ii) a distinct basement source beneath the boundary zone. Our results demonstrate that the Gander–Avalon boundary in southern New Brunswick is not a simple throughgoing crustal fault, and that the Gander and Avalon zones are underlain by different continental basement blocks. Comparison with results from Newfoundland and Nova Scotia suggests that these basement blocks are continuous throughout the Canadian Appalachians.
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FELITSYN, SERGEI B., and ALEXANDER P. GUBANOV. "Nd isotope composition of early Cambrian discrete basins." Geological Magazine 139, no. 2 (March 2002): 159–69. http://dx.doi.org/10.1017/s0016756801006252.
Full textAbstract:
A Nd isotope map of early Cambrian epeiric basins has been inferred from the Nd isotopic signature recorded in phosphatic Small Shelly Fossils. The most radiogenic εNd(t) values characterize water reservoirs along the Avalonian and Cadomian belts, while εNd(t) values of −10 to −20 were obtained in Laurentia and East Gondwanan Australia and China. Such a distribution of Nd isotope signatures results from the different provenance of early Cambrian epeiric seas: juvenile magmatic arcs and/or cordilleran for Mongolia, Siberia, Iberia and adjacent terranes, and cratonic sources for Laurentia and East Gondwana. Biogenic apatite of Small Shelly Fossils may be a useful tool for mapping of Nd isotope composition and documenting water mass exchange between discrete basins.
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Nedosekova, Irina, Nikolay Vladykin, Oksana Udoratina, and Boris Belyatsky. "Ore and Geochemical Specialization and Substance Sources of the Ural and Timan Carbonatite Complexes (Russia): Insights from Trace Element, Rb–Sr, and Sm–Nd Isotope Data." Minerals 11, no. 7 (June 30, 2021): 711. http://dx.doi.org/10.3390/min11070711.
Full textAbstract:
The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky complex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.
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Bédard, L. Paul, and John N. Ludden. "Nd-isotope evolution of Archaean plutonic rocks in southeastern Superior Province." Canadian Journal of Earth Sciences 34, no. 3 (March 1, 1997): 286–98. http://dx.doi.org/10.1139/e17-026.
Full textAbstract:
The Opatica plutonic belt, Abitibi greenstone belt, and Pontiac Subprovince represent a major proportion of the southeastern Superior Province, which was formed and accreted rapidly between approximately 2.9 and 2.8 Ga. Plutons in these belts are grouped into four types: (i) trondhjemite–tonalite–granodiorite (TTG) suite (2.82–2.69 Ga), (ii) monzodiorite (MZD) suite (2.697–2.669 Ga), (iii) late alkaline granitoid (ALK) suite (2.68–2.67 Ga), and (iv) anatectic granite and monzonite (ANA) suite (2.69–2.64 Ga). The four suites are represented in all belts and show similar petrography and geochemistry. In terms of Nd-isotope composition, the TTG, MZD, and ALK suites are typical of destructive plate margin magmatism and have + 1.4 < initial εNd < +3.7, values which are very similar to that of the Abitibi mantle (εNd + 2.5). The lower values for the ANA suites (εNd + 0.1 to + 2.4) result from recycling of crustal components. In the Opatica belt the ANA granitoids fall on the Nd-isotope evolution curve defined by the Opatica TTG plutons, and are thus considered to be melt products of this suite. However, Abitibi and Pontiac ANA suites show a larger range of εNd, from + 0.1 to + 2.4, compared with + 1.0 to + 1.3 for the Opatica, suggesting more heterogeneous crustal source rock. Recent geological mapping and geophysical studies associated with the Lithoprobe project have suggested that the Opatica belt represents a plutonic belt against which the Abitibi was accreted by subduction-related collision and that the Pontiac Subprovince is dominated by imbricated metasediments related to the final stages of collision in the Abitibi region. The Nd-isotope data provide support for these arguments. Early plutonic suites are mantle derived and related to arc-accretion processes. As the collision process progresses, a more evolved isotopic component is introduced, possibly in relation to sediment subduction into the mantle. Anatexis of the crust in the central Opatica belt and the core of the Pontiac Subprovince resulted in the formation of granites with a crustal signature for Nd isotopes.
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Ayache, Mohamed, Jean-Claude Dutay, Kazuyo Tachikawa, Thomas Arsouze, and Catherine Jeandel. "Neodymium budget in the Mediterranean Sea: evaluating the role of atmospheric dusts using a high-resolution dynamical-biogeochemical model." Biogeosciences 20, no. 1 (January 16, 2023): 205–27. http://dx.doi.org/10.5194/bg-20-205-2023.
Full textAbstract:
Abstract. The relative importance of river solid discharge, deposited sediment remobilisation, and atmospheric dust as sources of neodymium (Nd) to the ocean is the subject of ongoing debate, the magnitudes of these fluxes being associated with a significant uncertainty. The Mediterranean basin is a specific basin; it receives a vast amount of emissions from different sources and is surrounded by continental margins, with a significant input of dust as compared to the global ocean. Furthermore, it is largely impacted by the Atlantic water inflow via the Strait of Gibraltar. Here, we present the first simulation of dissolved Nd concentration ([Nd]) and Nd isotopic composition (εNd) using a high-resolution regional model (NEMO/MED12/PISCES) with an explicit representation of all Nd inputs, and the internal cycle, i.e. the interactions between the particulate and dissolved phases. The high resolution of the oceanic model (at 1/12∘), essential to the simulation of a realistic Mediterranean circulation in present-day conditions, gives a unique opportunity to better apprehend the processes governing the Nd distribution in the marine environment. The model succeeds in simulating the main features of εNd and produces a realistic distribution of [Nd] in the Mediterranean Sea. We estimated the boundary exchange (BE, which represents the transfer of elements from the margin to the sea and their removal by scavenging) flux at 89.43 × 106 g(Nd) yr−1, representing ∼84.4 % of the total external Nd source to the Mediterranean basin. The river discharge provided 3.66 × 106 g(Nd) yr−1, or 3.5 % of the total Nd flow into the Mediterranean. The flux of Nd from partially dissolved atmospheric dusts was estimated at 5.2 × 106 g(Nd) yr−1, representing 5 % of the total Nd input, and 7.62 × 106 g(Nd) yr−1 comes from the Atlantic across the Strait of Gibraltar, i.e. 7.1 % of the total Nd input. The total quantity of Nd in the Mediterranean Sea was estimated to 7.28 × 109 g(Nd); this leads to a new calculated Nd residence time of ∼68 year. This work highlights that the impact of river discharge on [Nd] is localised near the catchments of the main rivers. In contrast, the atmospheric dust input has a basin-wide influence, correcting for a too-radiogenic εNd when only the BE input is considered and improving the agreement of simulated dissolved Nd concentration with field data. This work also suggests that εNd is sensitive to the spatial distribution of Nd in the atmospheric dust, and that the parameterisation of the vertical cycling (scavenging/remineralisation) considerably constrains the ability of the model to simulate the vertical profile of εNd.
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Villeneuve, M. E., R. J. Thériault, and G. M. Ross. "U–Pb ages and Sm–Nd signature of two subsurface granites from the Fort Simpson magnetic high, northwest Canada." Canadian Journal of Earth Sciences 28, no. 7 (July 1, 1991): 1003–8. http://dx.doi.org/10.1139/e91-091.
Full textAbstract:
Two undeformed biotite granites recovered from exploratory hydrocarbon drill holes that penetrated basement in the Fort Simpson magnetic high were analyzed for U–Pb zircon geochronology and Sm–Nd isotopic composition. Both samples give crystallization ages of 1845 Ma, with errors of less than 5 Ma. This age overlaps with the waning stages of magmatism in the Great Bear magmatic zone of Wopmay Orogen, 200 km to the east. One sample has an initial εNd of +1.3 and a TDM of 2.14 Ga, whereas the other yielded an initial εNd of −2.1 and a TDM of 2.45 Ga. The latter sample indicates that Early Proterozoic light rare-earth element enriched lithosphere with a crustal history dating back to at least 2.45 Ga is present in the subsurface west of Wopmay Orogen.
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Liu, Guichun, Guangyan Chen, M. Santosh, Xin Qian, Zaibo Sun, Jian-Wei Zi, Tianyu Zhao, Qinglai Feng, and Shen Ma. "Tracking Prototethyan assembly felsic magmatic suites in southern Yunnan (SW China): evidence for an Early Ordovician–Early Silurian arc–back-arc system." Journal of the Geological Society 178, no. 4 (March 2, 2021): jgs2020–221. http://dx.doi.org/10.1144/jgs2020-221.
Full textAbstract:
Early Paleozoic trondhjemites, gneissic granites and alkali granites in southern Yunnan preserve important records of the tectonic evolution of the Prototethyan Ocean and regional correlations. Zircon ages suggest that these granitoids were emplaced from 476 to 436 Ma. The trondhjemites are characterized by high Na2O and low K2O contents, with εNd(t) values of −1.9 to −3.5 and εHf(t) values of −2.8 to +3.9. The trondhjemites were derived from an amphibolite source with a juvenile mafic component. The gneissic granites belong to the metaluminous low-K calc-alkaline series with an εNd(t) value of −6.2 and εHf(t) values of −5.0 to −0.4. The alkali granites belong to the high-K calc-alkaline series and yield εNd(t) values of −10.1 to −10.7 and εHf(t) values of −7.9 to −2.3. The gneissic granites were derived from an ‘ancient' lower mafic crust, whereas the alkali granites were derived from a meta-sedimentary source. These granitoids were formed during the subduction of the Prototethyan Ocean beneath the Simao Block and can be compared with similar igneous rocks from the Truong Son and Tam Ky-Phuoc Son zones in southern Laos. Our study, along with Early Paleozoic igneous suites from southern Laos, central Vietnam and the Malay Peninsula, suggests an arc–back-arc system along the northern margin of Gondwana.Supplementary material: Tables of zircon U–Pb and in-situ Hf and geochemical data are available at https://doi.org/10.6084/m9.figshare.c.5322386
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Mezger, Jochen E., Robert A. Creaser, Philippe Erdmer, and Stephen T. Johnston. "A Cretaceous back-arc basin in the Coast Belt of the northern Canadian Cordillera: evidence from geochemical and neodymium isotope characteristics of the Kluane metamorphic assemblage, southwest Yukon." Canadian Journal of Earth Sciences 38, no. 1 (January 1, 2001): 91–103. http://dx.doi.org/10.1139/e00-076.
Full textAbstract:
The Coast Belt of the northern Cordillera in Canada is the locus of the boundary between accreted and ancient North American margin rocks. The largest exposure of metasedimentary rocks in the Coast Belt is the Kluane metamorphic assemblage (KMA), a northwest-striking belt 160 km long of graphitic micaquartz schist and gneiss with minor interfoliated olivine serpentinite. The KMA does not appear to correlate with other sedimentary or metamorphic rock assemblages in the Canadian Cordillera. To determine its tectonic setting and protolith provenance, we analyzed trace element, rare earth elements, and neodymium isotope compositions of the KMA, of the adjacent pericratonic Aishihik metamorphic suite (AMS) of the YukonTanana terrane, and of adjacent slates of the Dezadeash Formation (DF), filling a Late Jurassic Early Cretaceous flysch basin. The εNd(0) values of analyzed KMA samples range from 1.4 to 5.6 and depleted mantle model ages (TDM) range from 1.16 to 1.45 Ga. KMA samples are intermediate between more evolved AMS samples (average εNd(0) 25, TDM = 2.6 Ga) and more juvenile DF samples (εNd(0) = +1.9, TDM = 0.95 Ga). The intermediate characteristics of the KMA samples cannot be linked to a known source region and are interpreted to reflect homogeneous mixing from predominantly juvenile and minor evolved sedimentary sources. A compatible tectonic setting is a back-arc basin within influence of a continental source. Eastward subduction of the KMA beneath ancient North America collapsed the back-arc basin by latest Cretaceous time.
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DeWolfe, Y. M., H. L. Gibson, and S. J. Piercey. "Petrogenesis of the 1.9 Ga mafic hanging wall sequence to the Flin Flon, Callinan, and Triple 7 massive sulphide deposits, Flin Flon, Manitoba, CanadaThis is a companion paper to DeWolfe, Y.M., Gibson, H.L., Lafrance , B., and Bailes, A.H. 2009. Volcanic reconstruction of Paleoproterozoic arc volcanoes: the Hidden and Louis formations, Flin Flon, Manitoba, Canada. Canadian Journal of Earth Sciences, 46: this issue." Canadian Journal of Earth Sciences 46, no. 7 (July 2009): 509–27. http://dx.doi.org/10.1139/e09-033.
Full textAbstract:
A detailed study of the geochemical and isotopic characteristics of the volcanic rocks of the Hidden and Louis formations, which make up the hanging wall to the volcanogenic massive sulphide deposits at Flin Flon, Manitoba, was carried out on a stratigraphically controlled set of samples. The stratigraphy consists of the lowermost, dominantly basaltic, Hidden formation, and the overlying, dominantly basaltic, Louis formation. Of importance petrogenetically, is the 1920 unit a basaltic andesite with Nb/Thmn = 0.54–0.62, εNd(1.9Ga) = +3.6–+5.9, εHf(1.9Ga) = +8.5–+9.6, and 204Pb/206Pb = 23.9. The basaltic flows that dominate the Hidden formation have Nb/Thmn = 0.16–0.29, εNd(1.9Ga) = +1.7–+4.4, εHf(1.9Ga) = +7.0–+11.8 and 204Pb/206Pb = 16.9–18.6). The Carlisle Lake basaltic–andesite (top of Hidden formation) is characterized by Nb/Thmn = 0.16–0.14, and 204Pb/206Pb = 21.4. The rhyodacitic Tower member (bottom of Louis formation) has Nb/Thmn = 0.23, εNd1.9Ga = +4.6, εHf1.9Ga = +9.3, and 204Pb/206Pb = 22.2. The basaltic flows that dominate the Louis formation have Nb/Thmn = 0.18–0.25, εNd(1.9Ga) = +3.6–+4.2, εHf(1.9Ga) = +8.4–+11.3 and 204Pb/206Pb = 17.9. The Hidden and Louis formations show dominantly transitional arc tholeiite signatures, with the 1920 unit having arc tholeiite characteristics. It is interpreted to have formed through extensive fractional crystallization of differentiated magmas at shallow levels in oceanic crust. Given the geological, geochemical, and isotopic characteristics of the Hidden and Louis formations, they are interpreted to represent subducted slab metasomatism with minor contamination from subducted sediments.
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Olive, Valérie, Réjean Hébert, and Michel Loubet. "Isotopic and trace element constraints on the genesis of a boninitic sequence in the Thetford Mines ophiolitic complex, Quebec, Canada." Canadian Journal of Earth Sciences 34, no. 9 (September 1, 1997): 1258–71. http://dx.doi.org/10.1139/e17-100.
Full textAbstract:
The Mont Ham Massif (part of the Thetford Mines ophiolite, south Quebec) represents a magmatic sequence made up of tholeiitic and boninitic derived products. A geochemical study confirms the multicomponent mixing models that have been classically advanced for the source of boninites, with slab-derived components added to the main refractory harzburgitic peridotite. An isochron diagram of the boninitic rocks is interpreted as a mixing trend between two components: (i) a light rare earth element (LREE) enriched component (A), interpreted as slab-derived fluid–melts equilibrated with sedimentary materials (εNd = −3, 147Sm/144Nd = 0.140), and (ii) a LREE-depleted component (B) (0.21 < 147Sm/144Nd < 0.23), interpreted as slab-derived fluid–melt equilibrated with recycled Iapetus oceanic crust and equated to the Nd-isotope characteristics of the Iapetus mantle (εNd = 9). A multicomponent source is also necessary to explain the Nd-isotope and trace element composition of the tholeiites, which are explained by the melting of a more fertile, lherzolitic mantle and (or) mid-ocean ridge basalt source (component C), characterized by a large-ion lithophile element depleted pattern and an Iapetus mantle Nd isotopic composition (εNd = 9), mixed in adequate proportions with the two previously infered slab-derived components (A and B). The genesis of the boninites of Mont Ham is not significantly different from those of boninites located in the Pacific. An intraoceanic subduction zone appears to be an appropriate geodynamic environment for the Mont Ham ophiolitic sequence.
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THOMAS, ROBERT J., JOACHIM JACOBS, and BRUCE M. EGLINGTON. "Geochemistry and isotopic evolution of the Mesoproterozoic Cape Meredith Complex, West Falkland." Geological Magazine 137, no. 5 (September 2000): 537–53. http://dx.doi.org/10.1017/s0016756800004519.
Full textAbstract:
Whole-rock major and trace element geochemical and Rb–Sr/Sm–Nd isotopic data are presented for the Mesoproterozoic (∼1.0 Ga) metamorphic and igneous rocks of the Cape Meredith Complex, West Falkland. The data indicate that the oldest rocks, the ∼1.1 Ga supracrustal gneisses of the Big Cape Formation, which form three petrographic and geochemical groups (mafic amphibolite, quartz–plagioclase–biotite–hornblende intermediate gneiss and acid gneiss), probably represent a juvenile calc-alkaline, basalt–andesite–rhyolite volcanic sequence, with epsilon (εNdT) values and NdTDM ages of ∼+3 to +6 and ∼1100 to 1400 Ma respectively. It is argued on geochemical grounds that these metavolcanics were extruded in an island-arc at around 1120 Ma. The Big Cape Formation was intruded by granitoids during and after a collisional orogenic event at around 1090 Ma. The oldest, foliated, (G1) granodiorite was emplaced as thin sheets at approximately 1090 to 1070 Ma and is characterized by εNd values of ∼+1.5 to 4 (TDM = ∼1200 to 1400 Ma), showing its juvenile nature. The ∼1070 Ma (G2) syntectonic granitoid gneisses and ∼1000 Ma G3 post-tectonic granites also exhibit juvenile characteristics (εNd = ∼0 to +5 and TDM = 2200 to 1200 Ma, respectively). The granitoids show a time-composition evolution from Na-rich (G1) granodiorite to potassic, high-High Field Strength Element granites (G3). The geochemical and isotopic characteristics and geological evolution of the Cape Meredith Complex is comparable with that of the adjacent Gondwana crustal blocks in Natal (SE Africa) and Dronning Maud Land (East Antarctica), supporting models that demonstrate these areas evolved in a contiguous, juvenile arc environment prior to, and during, a major orogenic event at ∼1.1 Ga. These events were associated with the birth of the Rodinian supercontinent. The three areas remained juxtaposed during Rodinia break-up and were subsequently incorporated into Gondwana in the same relative positions.
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Savko, K. A., A. V. Samsonov, and A. N. Larionov. "Mesoarchean silicic volcanics of the Kursk block, Voronezh crystalline massif: composition, age and correlation with the Ukrainian shield." Доклады Академии наук 486, no. 6 (June 28, 2019): 718–22. http://dx.doi.org/10.31857/s0869-56524866718-722.
Full textAbstract:
Rhyolites and basite rocks are present in the Archaean greenstone belts of the Kursk Domain (KD) of the East Sarmatia. The rhyolite age is 3122 ± 9 Ma (zircons, SIMS). A positive εNd (3122) = + 0.9 for rhyolites and their Sm-Nd model age ТNd (DM) = 3300 Ma as well as the age of the inherited zircon (3250 Ma) testifies to the participation of the more ancient crust component in the formation of rhyolite magmas. In geochemistry, rhyolites are very close to the TTG of the KD with an age 2.96-3.03 Ga. In the Middle Dnieper granite - greenstone area there are rhyolites and dacites with an age of 3.12 Ga with εNd (T) = + 0.6 - (+1.2) and very close geochemical characteristics. Thus, the hypothesis of a common geological history of the eastern part of Ukrainian Shield and KD in Mesoarchean is confirmed.
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Clift, Peter D., Peng Zhou, Daniel F. Stockli, and Jerzy Blusztajn. "Regional Pliocene exhumation of the Lesser Himalaya in the Indus drainage." Solid Earth 10, no. 3 (May 16, 2019): 647–61. http://dx.doi.org/10.5194/se-10-647-2019.
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Abstract. New bulk sediment Sr and Nd isotope data, coupled with U–Pb dating of detrital zircon grains from sediment cored by the International Ocean Discovery Program in the Arabian Sea, allow the reconstruction of erosion in the Indus catchment since ∼17 Ma. Increasing εNd values from 17 to 9.5 Ma imply relatively more erosion from the Karakoram and Kohistan, likely linked to slip on the Karakoram Fault and compression in the southern and eastern Karakoram. After a period of relative stability from 9.5 to 5.7 Ma, there is a long-term decrease in εNd values that corresponds with increasing relative abundance of >300 Ma zircon grains that are most common in Himalayan bedrocks. The continuous presence of abundant Himalayan zircons precludes large-scale drainage capture as the cause of decreasing εNd values in the submarine fan. Although the initial increase in Lesser Himalaya-derived 1500–2300 Ma zircons after 8.3 Ma is consistent with earlier records from the foreland basin, the much greater rise after 1.9 Ma has not previously been recognized and suggests that widespread unroofing of the Crystalline Lesser Himalaya and to a lesser extent Nanga Parbat did not occur until after 1.9 Ma. Because regional erosion increased in the Pleistocene compared to the Pliocene, the relative increase in erosion from the Lesser Himalaya does not reflect slowing erosion in the Karakoram and Greater Himalaya. No simple links can be made between erosion and the development of the South Asian Monsoon, implying a largely tectonic control on Lesser Himalayan unroofing.
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Yang, Xiangrong, Detian Yan, Tong Li, Liwei Zhang, Bao Zhang, Jie He, Haoyuan Fan, and Yunfei Shangguan. "Oceanic environment changes caused the Late Ordovician extinction: evidence from geochemical and Nd isotopic composition in the Yangtze area, South China." Geological Magazine 157, no. 4 (November 14, 2019): 651–65. http://dx.doi.org/10.1017/s0016756819001237.
Full textAbstract:
AbstractThe Ordovician–Silurian (O–S) transition was a critical interval in geological history. Multiple geochemical methods are used to explore the changes in oceanic environment. The Nd isotopic compositions in the Yangtze Sea are controlled by two sources: the continental erosion and the Panthalassa Ocean. High εNd(t) values during the Katian, late Hirnantian and Rhuddanian intervals are associated with the high sea level, which resulted in less terrestrial input based on the low Ti/Al and Zr/Al ratios. In contrast, low εNd(t) values during the early Hirnantian interval are related to the sea-level fall; in this case, the exposure of submarine highs and the growth of Yangtze Oldlands could lead to more continental materials being transported into the Yangtze Sea based on high Ti/Al and Zr/Al ratios. In addition, the negative εNd(t) excursion can also be attributed to the weak circulation between the Yangtze Sea and Panthalassa Ocean when sea level was low. Furthermore, the sea-level eustacy plays a significant role in the changes in redox water conditions. The redox indices, mainly UEF, Ce/Ce* and Corg/PT, across the O–S transition show a predominance of anoxic ocean over the Yangtze Sea during the Katian, late Hirnantian and Rhuddanian intervals, and an oxygenated episode was briefly introduced during the early Hirnantian period because of the fall in sea level. The Late Ordovician biotic crisis was marked by two-phase extinction events, and the change in sea level and redox chemistry may be the important kill mechanisms.
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Whalen, Joseph B., George A. Jenner, Frederick J. Longstaffe, and Ernst Hegner. "Nature and evolution of the eastern margin of lapetus: geochemical and isotopic constraints from Siluro-Devonian granitoid plutons in the New Brunswick Appalachians." Canadian Journal of Earth Sciences 33, no. 2 (February 1, 1996): 140–55. http://dx.doi.org/10.1139/e96-014.
Full textAbstract:
In the Gander Zone, Ordovician to Devonian, metaluminous to slightly peraluminous plutons, with within-plate affinities, intrude a lower Paleozoic metasedimentary package. During the Siluro-Devonian, εNd(T) and δ18O values of the metasedimentary rocks would have been about −7 to −8 and +10 to +14[Formula: see text], respectively. Granitoid εNd(T) values range from −0.3 to −4.2, δ18O values lie between +6.6 and +10.4[Formula: see text], and published Pb isotopic compositions are radiogenic (207Pb/204Pb > 15.65). εNd(T) values of associated Silurian gabbros are somewhat positive (+1.2 to +2.3); some plutons exhibit evidence for comingling with this mafic component. Potential source materials include enriched-mantle, supracrustal, and infracrustal sources. Although some constraints can be put on the first two sources, the nature of infracrustal material is difficult to evaluate. Heterogeneous data obtained from Silurian plutons can be explained by crust–mantle mixing. If some plutons contain a significant mantle component, then Mesoproterozoic or older crust is required. However, mixing is potentially complex and significant Neoproterozoic contributions cannot be excluded. The more compositionally homogeneous Devonian plutons probably represent partial melts of hybridized lower crust. The crustal component is interpreted as reflecting the seismically defined Central Crustal Block. The Gander Zone was probably deposited on Avalonian Brookville belt basement when it formed part of the Amazonian craton. Gander Zone clastic sediments, which are characterized by pre-Neoproterozoic isotopic signatures, were derived from this composite Gondwanan craton. We attribute Siluro-Devonian plutonism to collision and lithospheric delamination which accompanied, and followed, accretion of Avalonian belts to Laurentia during its collision with Gondwana.
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Mikhailik, Pavel, Irina Vishnevskaya, Liang Yi, Natalia Soloshenko, and Vadim Pellinen. "Sr and Nd Isotopes in Mineral Fractions of Ferromanganese Crusts from the Northernmost Pacific." Journal of Marine Science and Engineering 11, no. 10 (October 5, 2023): 1920. http://dx.doi.org/10.3390/jmse11101920.
Full textAbstract:
A study of the isotopic compositions of neodymium and strontium in four mineral fractions of the hydrogenous ferromanganese crusts of the northernmost Pacific has been carried out for the first time. The relationship of the 87Sr/86Sr ratio and εNd value of the residual fraction in heterochronous layers of the ferromanganese crusts have shown that the sources of detrital matter are from rock weathering by the Yukon River, the Kuskokwim River, the Anadyr River and the rivers of Kamchatka. The amount of aluminosilicate impurity does not affect the isotopic compositions of the chemogenic (loosely bound, Mn oxides or manganese, hydrous Fe oxides or ferrous) fractions. The decreased εNd value in the ferrous fraction seems to be related to the presence of rare earth element (REE) phosphate complexes in seawater. The increase in those complexes is a consequence of melt waters entering the ocean during warming periods. Our data indicate that the carbonate REE complexes are not the dominant form of the REEs in the northernmost Pacific, which leads to the fact that the neodymium isotopic compositions of the manganese and ferrous fractions of hydrogenous ferromanganese crusts are different. A decrease in εNd value in the ferrous fraction may be a marker of a local increase in the surface water bioproductivity. Our data also show that the increase of the REE in the ferrous fraction relative to the manganese fraction does not reflect the participation of hydrothermal matter in the formation of mixed hydrogenous–hydrothermal crusts but is a consequence of an increase in the REE phosphate complexes.
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Smirnov, Yu V., and S. I. Dril. "SOURCES OF THE PALEOZOIC SEDIMENTARY ROCKS IN THE NORA-SUKHOTINO TERRANE: RESULTS OF Sm-Nd ISOTOPIC-GEOCHEMICAL STUDIES." Geodynamics & Tectonophysics 14, no. 6 (December 14, 2023): 0730. http://dx.doi.org/10.5800/gt-2023-14-6-0730.
Full textAbstract:
The paper presents the first results on Sm-Nd isotopic-geochemical studies of the Paleozoic sedimentary rocks in the Nora-Sukhotino terrane at the northeastern flank of the South Mongolia-Khingan orogenic belt.According to the studies, the sedimentary rocks of the Zeya-Selemdzha and Amur fragments of the Nora-Sukhotino terrane are characterized by the two-stage Mesoproterozoic Nd-model age (TNd(DM2)=1.62–1.08 Ga) at negative εNd(0)=–9.5…–3.0 and εNd(T)=–5.8...–0.2. Based on previous geochemical and isotopic (U-Pb, Lu-Hf) studies of sedimentary rocks of the Nora-Sukhotino terrane, as well as on the available models for the formation of the South Mongolia-Khingan orogenic belt, it can be assumed that most of the Paleozoic sediments of the Nora-Sukhotino terrane were carried from the Mamyn terrane of the Argun superterrane with the participation of the island arc formations.
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Norman, David I., Kent C. Condie, Robert W. Smith, and W. F. Thomann. "Geochemical and Sr and Nd isotopic constraints on the origin of late Proterozoic volcanics and associated tin-bearing granites from the Franklin Mountains, west Texas." Canadian Journal of Earth Sciences 24, no. 4 (April 1, 1987): 830–39. http://dx.doi.org/10.1139/e87-081.
Full textAbstract:
Late Proterozoic volcanic and granitic rocks from the Franklin Mountains in west Texas define a continuous tholeiitic trend from rhyolite (granite) to trachyte with a small compositional gap between trachyte and basalt. Volcanics and granitic rocks have immobile-element geochemical affinities with volcanics from continental-margin-arc systems and associated back-arc basins. Felsic volcanics and granitic rocks appear to have formed by fractional crystallization of basalt during which REE and high-field-strength elements were stabilized as fluoride complexes and concentrated in late or post-magmatic fluids.A Rb–Sr isochron from nonhematized samples (1064 ± 5 Ma, i = 0.7034) falls within the error of reported U–Pb zircon dates and probably dates a period of hydrothermal alteration. εNd values (0.7–2.5 at 1065 Ma) fall below a depleted mantle growth curve and probably reflect contamination of the fractionating magmas with older continental crust. Changes in the isotopic composition of Nd during hydrothermal alteration may also contribute to the spread in εNd values.