Relevant bibliographies by topics / Β-acyloxyalkyl

Academic literature on the topic 'Β-acyloxyalkyl'

Author: Grafiati
Published: 4 June 2021
Last updated: 31 January 2023

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Journal articles on the topic "Β-acyloxyalkyl"

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Foubelo, Francisco, Francisco Lloret, and Miguel Yus. "β-Functionalised radicals in organic synthesis: 2-acyloxyalkyl radicals from 2-acyloxyalkyl iodides by the tin route." Tetrahedron 50, no. 17 (April 1994): 5131–38. http://dx.doi.org/10.1016/s0040-4020(01)90423-5.

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2

Beckwith, Athelstan L. J., and Peter J. Duggan. "The mechanism of the β-acyloxyalkyl radical rearrangement. Part 2: β-acyloxytetrahydropyranyl radicals." J. Chem. Soc., Perkin Trans. 2, no. 9 (1993): 1673–79. http://dx.doi.org/10.1039/p29930001673.

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3

FOUBELO, F., F. LLORET, and M. YUS. "ChemInform Abstract: β-Functionalised Radicals in Organic Synthesis: 2-Acyloxyalkyl Radicals from 2-Acyloxyalkyl Iodides by the Tin Route." ChemInform 25, no. 39 (August 18, 2010): no. http://dx.doi.org/10.1002/chin.199439086.

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4

Beckwith, Athelstan L. J., and Peter J. Duggan. "The mechanism of the β-acyloxyalkyl radical rearrangement: kinetic and18O-labelling studies." J. Chem. Soc., Perkin Trans. 2, no. 10 (1992): 1777–83. http://dx.doi.org/10.1039/p29920001777.

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5

Moreira, Rui, Ana Bela Santana, Jim Iley, João Neres, Kenneth T. Douglas, Peter N. Horton, and Michael B. Hursthouse. "Design, Synthesis, and Enzymatic Evaluation ofN1-Acyloxyalkyl- andN1-Oxazolidin-2,4-dion-5-yl-Substituted β-lactams as Novel Inhibitors of Human Leukocyte Elastase." Journal of Medicinal Chemistry 48, no. 15 (July 2005): 4861–70. http://dx.doi.org/10.1021/jm0501331.

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Dissertations / Theses on the topic "Β-acyloxyalkyl"

1

Harman, David Grant, and harmandg@hotmail com. "Mechanisms of the Intriguing Rearrangements of Activated Organic Species." The Australian National University. Faculty of Science, 2003. http://thesis.anu.edu.au./public/adt-ANU20031210.143110.

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Abstract:
The β-acyloxyalkyl radical rearrangement has been known since 1967 but its mechanism is still not fully understood, despite considerable investigation. Since the migration of a β-trifluoroacetoxy group generally proceeds more rapidly and with more varied regiochemistry than its less electronegative counterparts, this reaction was studied in the hope of understanding more about the subtleties of the mechanism of the β- acyloxyalkyl radical rearrangement. The mechanism of the catalysed rearrangement of Nalkoxy- 2(1H)-pyridinethiones was also explored because preliminary studies indicated that the transition state (TS) for this process was isoelectronic with TSs postulated for the β-acyloxyalkyl radical and other novel rearrangements. ¶ A kinetic study of the rearrangement of the 2-methyl-2-trifluoroacetoxy-1-heptyl radical in solvents of different polarity was undertaken using a radical clock method. Arrhenius equations for the rearrangement in each solvent were: hexane, log10[kr (s-1)] = 11.8±0.3 – (48.9±0.7)/ θ; benzene, log10[kr (s-1)] = 12.0±0.2 – (43.7±0.8)/ θ; and propionitrile, log10[kr (s-1)] = 11.9±0.2 – (42.0±0.3)/ θ. Rate constants at 75˚C were: hexane, kr = 2.9 × 104; benzene, kr = 2.8 × 105; and propionitrile, kr = 4.0 × 105 s-1. The equilibrium constant for the reversible rearrangement at 80°C in benzene was 15.1
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2

Duggan, Peter James. "The chemistry of β-acyloxyalkyl radicals." Phd thesis, 1990. http://hdl.handle.net/1885/140072.

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3

Harman, David Grant. "Mechanisms of the Intriguing Rearrangements of Activated Organic Species." Phd thesis, 2003. http://hdl.handle.net/1885/47123.

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Abstract:
The β-acyloxyalkyl radical rearrangement has been known since 1967 but its mechanism is still not fully understood, despite considerable investigation. Since the migration of a β-trifluoroacetoxy group generally proceeds more rapidly and with more varied regiochemistry than its less electronegative counterparts, this reaction was studied in the hope of understanding more about the subtleties of the mechanism of the β- acyloxyalkyl radical rearrangement. The mechanism of the catalysed rearrangement of Nalkoxy- 2(1H)-pyridinethiones was also explored because preliminary studies indicated that the transition state (TS) for this process was isoelectronic with TSs postulated for the β-acyloxyalkyl radical and other novel rearrangements. ¶ ...
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