Dissertationen zum Thema „UV index“

En les últimes dècades, l'increment dels nivells de radiació solar ultraviolada (UVR) que arriba a la Terra (principalment degut a la disminució d'ozó estratosfèric) juntament amb l'augment detectat en malalties relacionades amb l'exposició a la UVR, ha portat a un gran volum d'investigacions sobre la radiació solar en aquesta banda i els seus efectes en els humans.
L'índex ultraviolat (UVI), que ha estat adoptat internacionalment, va ser definit amb el propòsit d'informar al públic general sobre els riscos d'exposar el cos nu a la UVR i per tal d'enviar missatges preventius. L'UVI es va definir inicialment com el valor màxim diari. No obstant, el seu ús actual s'ha ampliat i té sentit referir-se a un valor instantani o a una evolució diària del valor d'UVI mesurat, modelitzat o predit. El valor concret d'UVI està afectat per la geometria Sol-Terra, els núvols, l'ozó, els aerosols, l'altitud i l'albedo superficial.
Les mesures d'UVI d'alta qualitat són essencials com a referència i per estudiar tendències a llarg termini; es necessiten també tècniques acurades de modelització per tal d'entendre els factors que afecten la UVR, per predir l'UVI i com a control de qualitat de les mesures. És d'esperar que les mesures més acurades d'UVI s'obtinguin amb espectroradiòmetres. No obstant, com que els costs d'aquests dispositius són elevats, és més habitual trobar dades d'UVI de radiòmetres eritemàtics (de fet, la majoria de les xarxes d'UVI estan equipades amb aquest tipus de sensors).
Els millors resultats en modelització s'obtenen amb models de transferència radiativa de dispersió múltiple quan es coneix bé la informació d'entrada. No obstant, habitualment no es coneix informació d'entrada, com per exemple les propietats òptiques dels aerosols, la qual cosa pot portar a importants incerteses en la modelització. Sovint, s'utilitzen models més simples per aplicacions com ara la predicció d'UVI o l'elaboració de mapes d'UVI, ja que aquests són més ràpids i requereixen menys paràmetres d'entrada.
Tenint en compte aquest marc de treball, l'objectiu general d'aquest estudi és analitzar l'acord al qual es pot arribar entre la mesura i la modelització d'UVI per condicions de cel sense núvols.
D'aquesta manera, en aquest estudi es presenten comparacions model-mesura per diferents tècniques de modelització, diferents opcions d'entrada i per mesures d'UVI tant de radiòmetres eritemàtics com d'espectroradiòmeters. Com a conclusió general, es pot afirmar que la comparació model-mesura és molt útil per detectar limitacions i estimar incerteses tant en les modelitzacions com en les mesures.
Pel que fa a la modelització, les principals limitacions que s'han trobat és la falta de coneixement de la informació d'aerosols considerada com a entrada dels models. També, s'han trobat importants diferències entre l'ozó mesurat des de satèl·lit i des de la superfície terrestre, la qual cosa pot portar a diferències importants en l'UVI modelitzat.
PTUV, una nova i simple parametrització pel càlcul ràpid d'UVI per condicions de cel serens, ha estat desenvolupada en base a càlculs de transferència radiativa. La parametrització mostra una bona execució tant respecte el model base com en comparació amb diverses mesures d'UVI. PTUV ha demostrat la seva utilitat per aplicacions particulars com ara l'estudi de l'evolució anual de l'UVI per un cert lloc (Girona) i la composició de mapes d'alta resolució de valors d'UVI típics per un territori concret (Catalunya).
En relació a les mesures, es constata que és molt important saber la resposta espectral dels radiòmetres eritemàtics per tal d'evitar grans incerteses a la mesura d'UVI. Aquest instruments, si estan ben caracteritzats, mostren una bona comparació amb els espectroradiòmetres d'alta qualitat en la mesura d'UVI. Les qüestions més importants respecte les mesures són la calibració i estabilitat a llarg termini. També, s'ha observat un efecte de temperatura en el PTFE, un material utilitzat en els difusors en alguns instruments, cosa que potencialment podria tenir implicacions importants en el camp experimental.
Finalment, i pel que fa a les comparacions model-mesura, el millor acord s'ha trobat quan es consideren mesures d'UVI d'espectroradiòmetres d'alta qualitat i s'usen models de transferència radiativa que consideren les millors dades disponibles pel que fa als paràmetres òptics d'ozó i aerosols i els seus canvis en el temps. D'aquesta manera, l'acord pot ser tan alt dins un 0.1º% en UVI, i típicament entre menys d'un 3%. Aquest acord es veu altament deteriorat si s'ignora la informació d'aerosols i depèn de manera important del valor d'albedo de dispersió simple dels aerosols. Altres dades d'entrada del model, com ara l'albedo superficial i els perfils d'ozó i temperatura introdueixen una incertesa menor en els resultats de modelització.
The increase in solar ultraviolet radiation (UVR) levels reaching the Earth surface during the last decades (mostly induced by the stratospheric ozone depletion), together with a detected increase in UVR-related diseases, has lead to a high volume of investigations about this band of the solar radiation and its effects on human beings.
The ultraviolet Index (UVI), which is currently internationally adopted, was defined in order to disseminate information to the public about the risks of exposing the naked body to UVR and to send preventive messages. UVI was initially defined as the maximum daily value. However, the current use of this index has been widened and nowadays it makes sense to refer to an instantaneous value or to the evolution of the measured, modelled, or predicted UVI during the day. The actual value of UVI is affected by the Sun-Earth geometry, clouds, ozone, aerosols, altitude and ground albedo.
High quality UVI measurements are essential as a reference and to study long-term trends; accurate modelling techniques are needed to understand the way factors affect UVR, to predict UVI, and as a quality control of the measurements. For the UVI measurement, best accuracy is expected with data from spectroradiometers. However, since the costs of these devices are expensive, data from erythemal radiometers are more commonly available (most UVI networks are equipped with this latter type of sensors). Best UVI modelling performance is found with multi-scattering radiative transfer models when the input information is well known. However, some relevant input information, such as the aerosol optical properties, is usually not available which can lead to large modelling uncertainties. More simple models are often used for applications such as UVI prediction or elaboration of UVI maps, as they are much faster and require less input parameters.
Considering this framework, the general objective of this work is to analyse the agreement that can be reached between modelled and measured UVI for cloudless conditions.
For this, model-measurement comparisons are presented for different modelling techniques, for several input options, and for UVI measured by both erythemal radiometers and spectroradiometers. As a general conclusion, it can be stated that the comparison of modelled vs. measured UVI is very useful to detect limitations and estimate uncertainties in both the modelling and measurements.
As far as modelling is concerned, the main limitations found are the lack of knowledge in the aerosol information considered as input. Also, important differences are found between the ozone column from satellite and from ground based measurements, which lead to important differences in the modelled UVI.
PTUV, a new simple parameterisation for fast UVI calculations for cloudless conditions, has been developed based on radiative transfer calculations. The parameterisation shows a good performance both with respect to the base model and to diverse UVI measurements. PTUV has demonstrated to be useful for particular applications such as to study the annual UVI variation at a particular site (Girona) and to build high resolution maps of typical UVI for a territory (Catalonia).
Regarding the measurements, it is found that the use of the actual spectral response of the erythemal radiometers is very important to avoid large uncertainties in the measured UVI. If well characterised, the erythemal radiometers compare reasonably well with high quality spectroradiometers when measuring UVI. Major issues with respect to the measurements are long term calibration accuracy and stability. Also, a temperature effect in PTFE, a material used as diffuser in some instruments, has been observed, which could have potentially important implications in the experimental field.
Finally, and concerning the model-measurement comparisons, the best agreement has been found when high quality spectroradiometric UVI measurements are considered and radiative transfer models are applied taking into account the best data available regarding aerosol and ozone optical parameters and their changes in time. In this case, the agreement can be as high as 0.1% in UVI, and typically less than 3%. This agreement deteriorates greatly if aerosols are ignored, and depends importantly on the aerosol single scattering albedo. Other data, such as ground albedo or the actual atmospheric temperature and ozone profiles, introduce lower uncertainty in the modelling results.

The extinction of solar radiation by atmospheric aerosols influences the Ultraviolet (UV) flux at the surface, which in turn has implications on both human and environmental health. In this study we present measurements of aerosol optical depth ( and #964;a) in the UV at Boulder, Colorado and Atlanta, Georgia using direct measurements of solar UV radiation. The wavelength dependence of and #964;a and the single scattering albedo ( and #969;o) are determined from the measured values of and #964;a. Daily averages of and #964;a range between 0.09 and 0.52 at Boulder and between 0.23 and 2.09 for Atlanta between the wavelengths of 332 and 340 nm. The average ngstrm exponent ( and #945;) is 0.83 at Boulder and 1.43 in Atlanta. Results clearly show that aerosols have a significant effect on the UV Index. Day-to-day changes in the UV index during the one month measurement period in Atlanta range between 2-3 UV Index units at solar noon. It is estimated that when changes in and #964;a and and #969;o occur simultaneously, the UV Index can change up to 6 units from one day to the next at solar noon in the Atlanta area. The single scattering albedo ( and #969;o) was estimated to range between 0.8 and 0.99 for Atlanta. The results suggest an increasing trend in and #969;o with increases in and #964;a. In addition, a new synthetic current UV Index is developed which expands to nearly 10,000 cities the number of current UV Index reports that can be distributed to the public in the United States. Right now, current UV Index values are limited to specific UV measuring sites, constrained by the difficulties of maintaining accurate calibration within the network of UV instruments. The distribution of UV Index values to more cities will increase the publics awareness of the harmful effects of the sun. This new UV Index can be accessed through The Weather Channel website.

Mestrado Vinifera EuroMaster - Instituto Superior de Agronomia
Wines are an important source of phenolic compounds. Red wines have a polyphenol content (especially tannins but also anthocyanins, flavonols, resveratrol and phenolic acids) considerably higher and different than whites. The phenolic content of wines is often described by two values that are called IPT and is representative of the total phenolic profile and anthocyanin index that is representative of the anthocyanins of a wine. The goal of this study is to try understanding how the different phenolic families contribute to the total polyphenolic index of the wine. For this reason representative compounds of some major phenolic families have been studied. The molecular absorbance was measured by a UV spectrophotometer at wavelength of 280 nm. From the result we calculated the polyphenolic index per milligram and the polyphenolic index of each compound used. This gave us an idea of the ‘’weight’’ that the different molecules have. Continuously combinations in pairs were made in order to try simulate better the wine environment. From the result obtained, we understood that total polyphenolic index per milligram for wine is a very complicated variable based both, in the ‘’weight’’ that the phenolic compounds have but also in the proportion that can be found in wine

Predmet istraživanja ove disertacije je monitoring i analiza ultraljubičastog zračenja, toplotnih indeksa i zagađujućih materija u vazduhu većih naselja na teritoriji Vojvodine. Cilj istraživanja je da se prostornom i vremenskom analizom posmatranih parametara dođe do što optimalnijih saznanja o stanju kvaliteta životne sredine na području Vojvodine kao i stvaranje jedinstvene baze podataka koja će služiti za buduća istraživanja. U radu je ispitan odnos između sunčevog globalnog i UV zračenja, izvedena i verifikovana empirijska jednačina za procenu dnevnih suma UV-B zračenja u osam naselja za period 1981-2008, analizirane koncentracije pet zagađujućih materija u sedam naselja za period 2001-2008. godina i analizirani toplotni indeksi u sedam naselja u periodu od 1992. do 2008. Analiza pokazuje da rekonstruisane vrednosti dnevnih suma UV-B zračenja i srednji godišnji toplotni indeksi u svim naseljima pokazuju tendenciju rasta i da dominantan uticaj na kvalitet vazduha u naseljima Vojvodine imaju čestice. Napravljena je jedinstvena baze podataka sa vrednostima koncentracija zagađivača vazduha, toplotnih indeksa, UV i globalnog zračenja.
This study analyzes UV radiation, heat indexes and air pollution in town in Vojvodina region. Objective of the thesis is to provide scientific facts about environmental quality in Vojvodina, as well as, to generate unique data base for the future research. The relationship between UV-B and global radiation has been studied and correlation equation for estimating UV-B from global radiation has been deduced. Equation was used for UV-B radiation calculation in eight towns in Vojvodina region during the period 1981-2008. This study also analyzes concentrations of five air pollutant in during the period 2001-2008, and heat index during the period 1992-2008. in seven towns in Vojvodina. The results from this study show growth UV-B radiation and heat index in all towns, and denote particulate maters as main air pollutants in Vojvodina towns.

Preliminary results of research focused on the applications of DC diaphragm discharge in water solutions containing humic substances are presented in this diploma thesis. Electrical discharges in water produce various reactive species such as radicals (•OH, •O, •H), ions and molecules (H2O2, O3). These species have high oxidation potential and thus they easily react with order species and molecules. Such reactions could lead, for example, to destruction of organic pollutants dissolved in water. This work studies this effect on humic matters that can be contained in water coming from floods. Diaphragm discharge investigated by this work was created in the reactor using konstant DC high voltage up to 2 kV that gave the total input power from 100 to 200 W. Breakdown and discharge ignition started in the pin-hole in the dielectric barrier separating two electrode spaces (anode and cathode space). Presented work investigates decomposition of humic substances by the electric discharge in the dependence of solution properties and discharge conditions. Parameters such as initial solution conductivity, electrolyte kind or input power have been investigated. Moreover, substantial effect of pH on humic acid decomposition has been observed. Refraktometry and absorption spectroscopy in UV-VIS region together with fluorescence spectroscopy has been used for the detection of changes in humic solutions.

Various carbon content hydrogenated amorphous silicon carbide (a-Si1¡
xCx:H) and hydrogenated amorphous silicon (a-Si:H) thin films have been deposited on various substrates by using plasma enhanced chemical vapour deposition (PECVD) technique. Transmission spectra of these films have been determined within UV-Visible region and the obtained data were analysed to find related physical constants such as
refractive indices, thicknesses, etc. Fourier transform infrared (FT-IR) spectrometry technique has been used to determine transmission &
reflection type spectra of these films. Obtained data were analysed to determine bond structures of the films. E®
ects of relative concentration of ethylene (C2H4) gas on thin film bond structure and on optical constants have been questioned.

Abstract Integrated optical (IO) sensor allowing sensitive, label-free, real-time and multi-parameter monitoring of bio-molecular interactions are conventionally fabricated with inorganic dielectrics inherited from CMOS manufacturing technology. Polymers as complement materials to inorganic dielectrics are becoming to have an increasing market share for IO circuits in optical communications networks owing to its good optical properties, versatile processibility and low cost. This work aims at developing disposable low-cost biosensors based mainly on polymeric materials, with a performance comparable to inorganic-dielectric based IO biosensors. This thesis describes the development of polymer IO biosensors based on the Young interferometer (YI) transducer platform for ambient noise compensation and a complete periodic intensity fringe pattern. Three different waveguide configurations were utilized, taking into consideration operational simplicity, fabrication simplicity and enhanced sensitivity. Among the developed polymer biosensors, an unconventional interferometer structure: a vertically placed dual-slab waveguide interferometer and an inverted rib waveguide configuration were employed. To enhance the sensitivity of the waveguides, deposition of Ta2O5 high index coating was performed on the rib waveguide configuration. Along with the development of polymer biosensors based on the inverted-rib waveguide configuration, a fabrication process was also developed featuring UV-imprinting and spin coating. The simple two-step fabrication process demonstrated using a polymer mold is potentially transferable to the roll-to-roll manufacture process. Calibration of the developed sensors was performed by homogeneous refractive index (RI) sensing with glucose de-ionized water solutions. By investigating an antibody – antigen binding interaction involving C-reactive protein and its conjugates, this thesis confirmed the applicability of the developed sensors to specific molecule detection. Moreover, to establish the influence of water molecular absorption on measurement stability, an evaluation was carried out on the polymeric waveguide. Finally, the thesis presented a comparison between the developed sensors, exploring their sensitivities, stabilities, limits of detection (LODs) and other aspects related to operation and fabrication. The results indicated that the Ta2O5-coated polymer waveguide sensor had a high sensing capability. In homogeneous RI sensing, the achieved detection limits were 9×10-7 RIU (refractive index unit), i.e., three times the noise level, and 270 fg/mm2 for surface mass density
Tiivistelmä Integroidulla optiikalla toteutetut anturit mahdollistavat biomolekulaarisen vuorovaikutuksen tutkimisen käyttäen herkkiä moniparametrisia ja merkkiaineettomia menetelmiä. Näiden bioantureiden valmistukseen käytetään tavallisesti CMOS-teknologian piiristä tuttuja epäorgaanisia puolijohteita ja eristemateriaaleja. Viime aikoina on kuitenkin polymeeristen materiaalien käyttöä integroidussa optiikassa tutkittu merkittävästi johtuen polymeerien hyvistä optisista ominaisuuksista, monipuolisesta työstettävyydestä ja edullisista kustannuksista. Tämän työn tarkoituksena on kehittää edullisia, kertakäyttöisiä, pääasiallisesti polymeerisistä materiaaleista valmistettuja bioantureita, jotka vastaavat suorituskyvyltään epäorgaanisista materiaaleista valmistettuja integroidun optiikan antureita. Tässä työssä kehitetyt polymeeriset integroidun optiikan bioanturit perustuvat Youngin interferometriin mahdollistaen ympäristökohinan kompensoinnin ja ne tuottavat pintavuorovaikutusten tutkimiseen jaksoittaisen interferenssikuvion. Työssä hyödynnettiin kolmea erilaista valokanavarakennetta huomioiden niiden käytön helppous, valmistuksen yksinkertaisuus ja mittausherkkyys. Yksi kehitetyistä polymeerisistä bioantureista koostui päällekkäisistä kerrostetuista polymeerikerroksista. Toisen tutkitun rakenteen toiminta puolestaan perustui käänteiseen harjannevalokanavaan. Mittausherkkyyttä parannettiin pinnoittamalla polymeerirakenne Ta2O5-pinnoitteella. Näin muodostui kerrostettu komposiittivalokanava, joka oli tässä työssä tutkittu kolmas sensorirakenne. Itse bioanturien lisäksi kehitettiin myös valmistusprosessi, jossa hyödynnettiin UV-painatusta ja nestefaasipinnoitusta. Tässä työssä havaittiin lisäksi, että kehitetty yksinkertainen valmistusmenetelmä on paitsi toimiva, myös mahdollisesti siirrettävissä rullalta rullalle valmistus- ja tuotantoteknologiaan. Kehitettyjen anturien kalibrointi suoritettiin homogeenisella taitekerroinmittauksella käyttäen liuoksia, jotka valmistettiin glukoosista ja deionisoidusta vedestä. Kehitettyjen anturien soveltuvuus spesifien molekyylien tunnistamista varten todennettiin tutkimalla vasta-aineiden ja antigeenien sitoutumisreaktioita ja vuorovaikutusta C-reaktiivisella proteiinilla ja sen konjugaateilla. Lisäksi työssä tutkittiin veden absorption vaikutusta mittauksen stabiilisuuteen. Tutkimuksessa suoritettiin vertailu kehitettyjen anturien ja niiden ominaisuuksien välillä kiinnittäen huomiota mittausherkkyyteen, stabiilisuuteen, määritys- ja toteamisrajoihin ja muihin anturien valmistukseen sekä käyttöön liittyviin keskeisiin piirteisiin. Tulokset osoittavat, että Ta2O5-pinnoitetun polymeerivalokanavan mittausherkkyys oli suurin vertailluista rakenteista. Homogeenisessä taitekerroinmittauksessa saavutettu määritys- ja toteamisraja oli 9×10-7 taitekerroinyksikköä (RIU). Pintamassatiheysmittauksessa saavuttu tulos oli 270 fg/mm2

Jusqu’à récemment, la plupart des applications des arcs électriques mettaient en oeuvre les propriétés du coeur de la colonne, un effort particulier a donc été effectué pour développer des méthodes de caractérisation de ces zones dont la température moyenne est de l’ordre de 10000 K. Avec le développement de la plasma-chimie, le diagnostic des zones périphériques d’arcs et des décharges hors équilibre est devenu un enjeu primordial. Les méthodes de mesure classiques sont mal adaptées pour cette tâche ; le but du travail présenté dans cette thèse se résume donc au développement et à la validation de techniques de diagnostic adaptées à ces zones, dont la température cinétique n’excède pas 8000 K. Deux méthodes innovantes basées sur l’indice de réfraction, l’ombroscopie quantitative et la déflectométrie moirée, ont été étudiées en détails. Les résultats théoriques ainsi que le traitement des données obtenues ont été validés sur un jet de plasma laminaire d’argon, un modèle parfait de zone périphérique. Pour sonder les décharges hors équilibre, l’utilisation du spectre UV de OH a été aussi envisagée. À cette occasion, un programme de simulation de spectre moléculaire a été développé. L’étude des spectres synthétiques obtenus a permis de mettre au point des méthodes de mesure simples de la température rotationnelle et vibrationnelle pour une large gamme de résolution. Une des méthodes développées a été mise en œuvre sur une décharge à faible intensité de courant. On montre que les résultats obtenus par spectroscopie moléculaire sur le radical OH sont très proches de ceux obtenus à l’aide d’une simulation
Until recently, most of electrical arcs applications were dealing with the properties of the centre of the plasma column, a large number of works was then done to develop diagnostic techniques dedicated to those area where the mean temperature is about 10000 K. With the emergence of plasma chemistery, the diagnostic of arc’s peripheral areas and un-equilibrium discharges become a goal of prime importance. Classical diagnostic techniques are not adapted to those objects where the maximum temperature is around 8000 K; the principal aim of this work was to develop and check diagnostic techniques. Two inovating techniques based on refractive index, the quantitative shadowgraphy and the moiré deflectometry were studied extensively and checked on a laminar plasma jet, a perfect model of arc’s peripheral area. To probe unequilibrium discharge, the use of UV OH spectrum was considered. At this occasion, a spectrum simulation software was written. The study of synthetic spectra lead to the creation of simple measurement methods of rotationnal and vibrationnal OH temperature for a large range of resolution. Those methods was checked on a low power electric discharge. It can be shown that result from molecular spectroscopy are close to those obtained by simulation

This diploma thesis deals with determination of carbohydrates in wine. Theoretical part attends to production of wine from grape to treatment and training of wine. It refers saccharides in wine, especially glucose and fructose. The study provides an overview of the available sources concerning the possibilities of determination of carbohydrates in wine by chromatographic methods and Skalar automated chemistry analyser. The study shortly refers simple analytical methods for determination of wine saccharides. The experimental part based on this search deals with analysis of saccharides by high performance liquid chromatography with refractive index detector and UV detector on aminoalkyl column and determination of reducting sugars by Skalar automated chemistry analyser. Finally, the results of these methods were compared.

CoordenaÃÃo de AperfeÃoamento de Pessoal de NÃvel Superior
FundaÃÃo de Amparo a Pesquisa do Estado do PiauÃ
Objetivo: Investigar o potencial biotecnolÃgico do bagaÃo de uva, variedade Benitaka, cultivada no municÃpio de SÃo JoÃo do PiauÃ, PiauÃ, por meio de metodologias analÃticas cientificamente reconhecidas, buscando reconhecer os principais grupos de metabÃlitos responsÃveis por atividade antioxidante. Metodologia: As uvas (Vitis vinifera L.), variedade Benitaka, foram resultantes da safra 2011/2012 e coletadas no Polo de Viticultura do Assentamento Marrecas, no MunicÃpio de SÃo JoÃo do PiauÃ/PI e posteriormente higienizadas, prensadas em despolpadeira para separaÃÃo do bagaÃo, o qual foi submetido à desidrataÃÃo, trituraÃÃo, peneiramento e formaÃÃo do bagaÃo de uva em pÃ. A partir do bagaÃo de uva em pà foram realizadas anÃlises da composiÃÃo centesimal, conteÃdo de minerais, fibra dietÃtica total, solÃvel e insolÃvel, determinaÃÃo de Vitamina C, conteÃdo de antocianinas, perfil de Ãcidos graxos e investigaÃÃo de sua qualidade microbiolÃgica. Foram tambÃm elaborados extratos a partir de diferentes solventes, os quais foram analisados quanto à toxicidade frente à Artemia salina sp., conteÃdo de fenÃlicos totais, flavonÃides totais e taninos totais; atividade antioxidante in vitro pelos mÃtodos de DPPHâ e autooxidaÃÃo do sistema β-caroteno/Ãcido linoleico; estabilidade oxidativa em Ãleo de soja e identificaÃÃo e quantificaÃÃo de polifenÃis por HPLC-UV. Os resultados foram expressos como mÃdia e desvio padrÃo (n=3) e utilizou-se o programa estatÃstico SAS para AnÃlise de VariÃncia e Teste de Tukey. Adotou-se o nÃvel de significÃncia de 5% (p<0,05). Resultados: Os resultados mostraram que no bagaÃo de uva em pà a quantidade de fibra dietÃtica total (46,17g/100g) se destacou quantitativamente em relaÃÃo aos carboidratos (29,2g/100g), proteÃnas (8,49g/100g) e lipÃdeos (8,16g/100g). O valor energÃtico total encontrado foi de 224Kcal/100g. A fraÃÃo fibra insolÃvel (79%) foi superior à fraÃÃo solÃvel (21%). O conteÃdo de Vitamina C foi de 26,25mg de Ãcido ascÃrbico/100g e de antocianinas, 131mg/100g. Os minerais ferro (18,08mg/100g), potÃssio (1,40mg/100g), zinco (0,98mg/100g), manganÃs (0,82mg/100g) e cÃlcio (0,44mg/100g) estavam presentes em maiores concentraÃÃes. A fraÃÃo lipÃdica foi composta principalmente por Ãcido linoleico (89,61%) e o teor de PUFA (89,61%) >MUFA (21,37%) >SFA (18,46%). O rendimento dos extratos variou de 6,85% a 45,5%, dependendo do solvente de extraÃÃo, sendo que o menor rendimento foi observado no extrato acetÃnico e o maior no extrato metanÃlico. O conteÃdo de fenÃlicos totais, flavonoides totais e taninos totais variaram em funÃÃo do solvente de extraÃÃo. Os extratos etanÃlico e acetÃnico conseguiram estabilizar o radical DPPHâ de forma eficiente, com valores de EC50 de 0,31 Âg/mL e 0,39 Âg/mL, os quais nÃo diferiram estatisticamente dos padrÃes quercetina (0,22 Âg/mL) e BHT (0,11 Âg/mL). Em relaÃÃo à avaliaÃÃo da atividade antioxidante pelo mÃtodo de autooxidaÃÃo do sistema β-caroteno/Ãcido linolÃico, os extratos agiram de forma similar ao antioxidante sintÃtico BHT, com mÃdias de EC50 de 0.34 Âg/mL a 0.36 Âg/mL. O extrato etanÃlico aumentou a vida de prateleira do Ãleo de soja de forma similar ao BHT. O composto fenÃlico presente em maior concentraÃÃo foi isoquercitrina (12,94 mg/100g), seguido de rutina (7,54 mg/100g), quercetina (5,4 mg/100g) e resveratrol (2,5 mg/100g). ConclusÃo: Os resultados mostraram que o bagaÃo de uva representa uma fonte potencialmente importante de nutrientes e compostos fenÃlicos; alÃm de elevado potencial antioxidante, o que contribui para o seu elevado valor como um subproduto de frutos, com possibilidades de comercializaÃÃo como antioxidante natural.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
O processo de humificação, conversão de resíduos orgânicos em húmus, é um fator importante na compreensão da dinâmica da matéria orgânica. A sua quantificação, é fundamental para o estudo da evolução química dessa substância. O objetivo deste trabalho foi caracterizar as amostras de ácidos húmicos (AHs) e quantificar o grau de humificação do solo e das frações físicas (por tamanho de partículas). As análises de Espectroscopias de Fluorescência de Raios X por Dispersão de Comprimento de Onda, Fluorescência na região do Visível, Espectroscopia Vibracional na região de Infravermelho e de Absorção na região do Ultravioleta e Vísivel, Espectrocospia Raman, acompanhadas das técnicas de Análise Térmica, Microscopia Eletrônica de Varredura com Canhão Eletrônico por Efeito de Campo e Espalhamento Dinâmico da Luz foram utilizadas. A quantificação do grau de humificação mostrou que AHs extraídos da profundidade (10- 20 cm) possuem estruturas aromáticas mais condensadas. A fração de AH que apresentou maior grau de humificação foi a extraída do solo com a adição de calagem, o que demonstra uma influência do calcário na aceleração do processo de humificação. O estudo das frações granulométricas do solo, determinou, com espectroscopia de infravermelho, os atributos orgânicos que estão associados as frações do solo e, que a maioria dos minerais presentes nas frações granulométricas, foram identificados como sendo caulinita, haloisita, quartzo e gibbsita. Já para o estudo da humificação dos AHs extraídos das frações granulométricas, a quantificação do grau de humificação, do maior para o menor, é procedente da fração silte, seguidos da fração argila e, por fim, a fração areia.
The humification process, conversion of organic waste into humus, is an important factor to understand the organic matter dynamics. Its quantification is vital for the study of this substance chemical evolution. This study aimed at characterizing humic acid (HA) samples and quantify the degree of soil humification and physical fractions (particle size). The analysis of Spectroscopies of wavelenght dispersive X-ray fluorescence, visible fluorescence, vibrational infrared region, ultraviolet and visible light absorption and Raman along with the techniques of Thermal Analysis, scanning electron microscopy with field effect gun and dynamic light scattering were employed. The humification degree quantification revealed that the HA extracted from the 10-20cm depth presented more polycondensed structures. The HA fraction that presented the highest humification degree was extracted from the soil with the addition of liming, which demonstrates the limestone influence in the acceleration of the humification process. The study of the soil granulometric fractions determined, with infrared spectroscopy, the organic properties that are associated to soil fractions and that most of the minerals present in the granulometric fractions, were identified as kaolinite, halloysite, quartz and gibbsite.The study of the humification in the HA extracted from the granulometric fractions quantified the humification degree and revealed the highest values in the silt fraction followed by the clay fraction and, finally, the lowest values were found in the sand fraction.

The thesis deals with the design and creation of a weather station suitable for gardeners. The created device is able to measure temperature, pressure, humidity, amount of precipitation, wind speed and direction, UV index and also temperature and soil moisture at several depths. The weather station is powered by a battery with auxiliary charging from a photovoltaic panel. The thesis is divided into several parts. The theoretical part describes the individual physical principles of measurement of the considered physical quantities. Subsequently, a comparison of available sensors is made and then a final selection is made. The third part deals with the design and implementation of the hardware circuitry including the creation of the PCB. In this section, the holders of each sensor are also designed for printing on a 3D printer, which are then printed. The fourth section deals with software design issues, which is described in more detail. Finally, the whole weather station is assembled, wired and the functionality of all components is verified by sending the measured data to Thingspeak.

碩士
大仁科技大學
環境管理研究所
104
The purpose of this study was to investigate the Temporal and Spatial characteristics of ultraviolet (UV) index in north, central, south, east regions, and offshore islands of Taiwan and further compare Taiwan’s UV readings with Australia. Results showed that Taiwan's UV readings are higher in summer and lower in winter. In summer, UV readings concentrate at the very high radiation level, and readings above the high level account more than 50%. In winter, UV readings concentrate at the moderate or low level, but readings at the extreme level may also occur in high mountain areas. Besides, regional distributions and variations of UV radiation levels are similar across Taiwan, where moderate readings account for the majority, followed by very high readings and high readings in similar ratios. The ratio of high readings is highest in central and south Taiwan and lowest in north Taiwan; the ratio of very high readings is higher in central, south, and east Taiwan and lower in north and offshore islands of Taiwan; in terms of extreme readings, east Taiwan has the highest ratio, followed by central and south Taiwan, while north Taiwan has the lowest. As to distribution of radiation levels in areas of high concern, the monitoring station in Pingtung shows high level > moderate > very high > extreme > low level in the area. The high level readings take 67% annually and 86.2%~97.4% from May to August. The monitoring station in Kenting showed very high > moderate > high > extreme = low level in the area. Readings above the high level account for 65.4% annually and 73.3%~96.7% from April to October. In high mountain areas, Tataka and Mt. Jade stations have respectively detected a UV index of 11 or higher in 84 and 118 days, even during winter times. The highest UV index ever recorded in Mt Ali is 8 and that in Sun Moon Lake is 12. Finally, comparison of UV index in Taiwan and Australia in the same time periods showed that Alice Springs has higher monthly average and annual average than Taiwan. In terms of annual average, the index in Australia is 1.45 times of the index in Taiwan.

碩士
淡江大學
機械與機電工程學系碩士班
97
A UV curing acrylic resin /nano scaled meter zinc oxide hybrid films with tunable optical properties were prepared by means of the sol-gel synthesis method. The ZnO precursor solution which includes different weight ratios(30wt%、40wt%及50wt%) mixed with the UV curing acrylic resin through the way of sol-gel，and then this synthesis generates transparent hybrid films via the process of make a wet thin film by deposition on spotless glass substrate，ultraviolet curing and desorption treatment at different drying temperatures (250℃、275℃and 300℃). The approximately 40nm-80nm zinc oxide uniformly distributes over a matrix and FTIR analysis show no existence of chemical bodings between zinc oxide and UV curing acrylic resin。The refractive indices of these molecular hybrid films are much higher than that of UV curing acrylic resin e.g., at a ZnO loading of 30 wt % under at 300℃desorption treatment, the resulting molecular hybrid film exhibits a measured refractive index of 1.72 compared to that of 1.63.Additional, the cut-off wavelength of transmittance at ultraviolet wavelength range in the hybrid films shifted to the long wavelength side.

Relationship between the UV index and selected parameters Abstract Ultraviolet radiation (UV radiation) is a shortwave radiation with wavelengths from 100 to 400 nm. This radiation has both positive and negative effects on living organisms and human health. Therefor the so-called UV index (UVI), characterizing the biological effect of UV radiation on human health was defined in 1994. This thesis aims to evaluate the link between selected factors (total ozone column, solar elevation angel, cloudiness and altitude) and the UVI values. Observed data at four stations in Czechia (Hradec Králové, Košetice, Kuchařovice, Labská bouda) and SYNOP reports from the four nearest stations during the period 2010−2017 were used. The Sun elevation (angle of Sun ray) has the strongest effect on the UVI values. The highest UVI values are generally reached at high angels when the Sun rays go the shortest path through the atmosphere. The increase of the UVI is exponential, from an angle of 30ř the increase is approximately linear. The UVI values increase on average by 0.8 at the Hradec Králové station and by 0.9 at the Labská bouda station for angle increasing by 5ř. The effect of clouds is significant and depends on the height and the clouds amount. High level clouds reduce UVI negligible, overcast sky by only 15 %. Medium and...

Numerous techniques have been used to characterize ultraviolet polarization sensitivity (PS) in teleost fishes. To date PS in the rainbow trout (Oncorhynchus mykiss) has been characterized using compound action potential (CAP) recordings from the optic nerve. CAP recordings have also been used in conjunction with chromatic adaptation to isolate the individual cone photoreceptor mechanisms responsible for PS detection. The primary goal of this thesis was to discover the ancestry of PS within the Salmoninae clade containing Salmo, Salvelinus and Oncorhynchus, by characterizing and mapping the cone photoreceptor mechanisms mediating PS onto the phylogeny. I developed a research paradigm that used electroretinogram (ERG) recordings to characterize PS in rainbow trout. Substantial differences were found between CAP and ERG recordings. When identical stimuli were used, ERG recordings produced two additional peaks of maximal sensitivity at 45° and 135°. Chromatic adaptation was used to explore differences in bipolar cell and optic nerve generated PS curves. Under chromatic adaptation, with the use of ERG recordings, the additional peaks shifted consistently with the adaptation of either the horizontal or vertical polarization detector mechanism. These findings have contributed to the understanding of how ultraviolet polarized light is processed within the visual system I then used CAP and ERG recordings to characterize PS in Atlantic salmon (Salmo salar), because of its basal relationship within the Salmo, Salvelinus and Oncorhynchus clade. PS results obtained from CAP and ERG recordings were similar for Atlantic salmon and rainbow trout. CAP recordings generated a `W'-shaped PS curve maximally sensitive at 0°, 90°, and 180°, while ERG recordings generated a tuning curve with the additional peaks of maximal sensitivity at 0°, 45°, 90°, 135° and 180°. Therefore, it was concluded that both PS and the mechanisms of retinal processing underlying it are ancestral within the clade making up Salmo, Salvelinus and Oncorhychus. This has implications for the sensory abilities available when diadromous life histories evolved in Salmonidae.

碩士
國立臺北科技大學
有機高分子研究所
98
This work, we use dendrimer which has high branch and is a three-dimentional space structure, it has nighteen acrylate group. It reacts with different amount of Thiophenol, 4-Methylthiophenol, 2-Mercaptothiazoline, 2-Mercaptobenzothiazole to proceed the addition reaction for synthesizing the Sulfur-containg high refractive index UV curing oilgomer. To explore the effects of the structure on the refractive index,and then we can test the structure identification by FT-IR, HPLC and the physical properties by Refraction index, Rheometer, Pencil Hardness, Thermal Gravimetric Analysis (TGA), Doublebean Photocalorimeric Accessory(DPA). In the experimental results, the more moles of thiols branch of the dendrimer the higher RI index ,viscosity, and thermal cracking temperature of that. In these thiols,2-Mercaptobenzothiazole structure which enhance the refraction index is the largest. In UV curing Kinetic analysis, 4-Methylthiophenol system has the highest conversion and reaction rate.In the hardness test, 2-Mercaptothiazoline system has the highest hardness.

碩士
逢甲大學
資訊電機工程碩士在職專班
100
Abstract: This paper reports an evaluation method of the refractive index of ultraviolet (UV) exposed resin by monitoring the diffraction pattern of a roll-to-roll imprinted blazed grating. The relationship among the diffraction efficiency, refractive index and shape of the grating is calculated using the commercial rigorous coupling wave analysis (RCWA) modeling software. The objective is to determine the refractive index to a precision of the order of 10-3 to insure the accuracy of the ray tracing simulation in the design of UV embossed structured films. Keyword : GSOLVER、Roll-to-Roll

碩士
淡江大學
化學工程與材料工程學系碩士班
99
In this study, UV-cured hybrid optical thin films were successfully prepared on PMMA substrates using TiO2 sols and acrylic monomers. TiO2 nanoparticles were synthesized via a sol-gel route at room temperature. Through the heat reflux process, the TiO2 nanoparticles became partial crystalline. The prepared TiO2 sols can provide operating control for the preparation of hybrid thin films by spin coating. Transparent high-refractive-index thin films were obtained with high TiO2 content. Photocatalytic ability of synthesized TiO2 nanoparticles was poor while some crystal structure existed. This may resulted from limited crystallinity of TiO2, and avoided a distinct degradation of organic moieties in the hybrids. TiO2 sols were characterized by DLS, TEM, XRD, and UV-Vis absorption, while TiO2 hybrid thin films were analyzed by UV-Vis absorption, FTIR, N&K, TGA, SEM, AFM, and contact angle. All hybrid thin films showed good adhesion to the PMMA substrate with refractive index falling over the range 1.66-1.82. These results suggested the potential application of present TiO2 hybrid films in optical devices, such as anti-reflective coatings.

Raman spectroscopy is a form of vibrational spectroscopy that is capable of probing biological samples at a molecular level. In this work it was used in the analysis of ionizing radiation-induced damage in DNA. Spectra of both simple, short-stranded DNA oligomers (SS-DNA) and the more complicated calf-thymus DNA (CT-DNA) were acquired before and after irradiation to a variety of doses from 0 to ~2000 Gy. In a technique known as ultraviolet resonance Raman spectroscopy (UVRRS), three UV wavelengths of 248, 257 and 264 nm were utilized in order to selectively enhance contributions from different molecular groups within the samples. Assignment of the spectral peaks was aided by the literature, as well as through analysis of UVRR spectra of short strands of the individual DNA bases obtained at each of the three incident UV wavelengths. Difference spectra between the irradiated and unirradiated samples were calculated and the samples exposed to ~2000 Gy showed significant radiation-induced features. Intensity increases of spectral peaks, observed primarily in the CT-DNA, indicated unstacking of the DNA bases and disruption of Watson-Crick hydrogen bonds, while intensity decreases of spectral peaks, observed only in the SS-DNA, indicated both base damage and the loss of structural integrity of the DNA molecule. The high molecular specificity of UVRRS allowed for precise identification of the specific bonds affected by the radiation, and the use of the varying incident wavelengths allowed for the observation of damage to moieties that would otherwise have been excluded. The use of UVRRS shows promise in the study of radiation-induced damage to DNA and would be well suited for extension to the study of more complicated biological systems.

碩士
建國科技大學
機電光系統研究所
94
In this thesis, the main purpose is how to analyze and make acing，gradient index and UV-curable fiber lens, and elucidates differences and restrictions of usages between these three kinds of fiber lenses. Lens will discharge due to the tilting arc during to make a arcing fiber lens. So now, this situation can be controlled by having the curvature radius range between 70 ~ 125μm ±2μm. This can be completed by cutting the gradient index fiber lens with precise measurements. The range of cutting length is 100 m ~ 10 mm. As the result of the 10m of distributing points limit, the margin of error will be ±12 m. The surface of UV-curable fiber lens can be handled through O2 plasma. So now, the radius curvature can be controlled within the range of 65 ~ 92μm and margin of error will be ±2μm. The arcing fiber lens will cause the optic axis to tilt at approximately 4.3 degrees, while the optic axis of the gradient index fiber lens tilt at approximately 0.5 degrees. The tilt of optic axis of the UV-curable fiber lens is much smaller than both the arcing fiber lens and the gradient index fiber lens. Therefore, the UV-curable fiber lens has higher product developing value with whole and simple design.