Auswahl der wissenschaftlichen Literatur zum Thema „Shift nitroxides“
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Zeitschriftenartikel zum Thema "Shift nitroxides"
Sweger, Sarah R., Vasyl P. Denysenkov, Lutz Maibaum, Thomas F. Prisner und Stefan Stoll. „The effect of spin polarization on double electron–electron resonance (DEER) spectroscopy“. Magnetic Resonance 3, Nr. 1 (01.07.2022): 101–10. http://dx.doi.org/10.5194/mr-3-101-2022.
Der volle Inhalt der QuelleMaryunina, Kseniya Yu, Xiao Zhang, Sadafumi Nishihara, Katsuya Inoue, Vitaly A. Morozov, Galina V. Romanenko und Victor I. Ovcharenko. „A heterospin pressure sensor“. Journal of Materials Chemistry C 3, Nr. 30 (2015): 7788–91. http://dx.doi.org/10.1039/c5tc01005e.
Der volle Inhalt der QuelleBonesteel, Jo-Anne K., Babul Borah und Richard D. Bates. „Effects of nitroxide free radicals on proton donor chemical shifts“. Journal of Magnetic Resonance (1969) 98, Nr. 3 (Juli 1992): 475–82. http://dx.doi.org/10.1016/0022-2364(92)90002-o.
Der volle Inhalt der QuelleKirste, B. „EPR and ENDOR Investigations of a Cholestane Spin Probe in Liquid Crystals“. Zeitschrift für Naturforschung A 42, Nr. 11 (01.11.1987): 1296–304. http://dx.doi.org/10.1515/zna-1987-1112.
Der volle Inhalt der QuelleMaupu, Alexandre, Yara Kanawati, Adrien Métafiot und Milan Maric. „Ethylene Glycol Dicyclopentenyl (Meth)Acrylate Homo and Block Copolymers via Nitroxide Mediated Polymerization“. Materials 12, Nr. 9 (11.05.2019): 1547. http://dx.doi.org/10.3390/ma12091547.
Der volle Inhalt der QuelleBales, Barney L., Francis L. Harris, Mirna Peric und Miroslav Peric. „Electron Paramagnetic Resonance Line Shifts and Line Shape Changes Due to Spin Exchange of Nitroxide Free Radicals in Liquids. 7. Singly Charged Surfactant Nitroxide“. Journal of Physical Chemistry A 113, Nr. 33 (20.08.2009): 9295–303. http://dx.doi.org/10.1021/jp905335r.
Der volle Inhalt der QuelleRomanenko, G. V., S. E. Tolstikov, E. V. Tretyakov, S. V. Fokin, V. N. Ikorskii und V. I. Ovcharenko. „Shift of stereochemical nonrigidity from coordination units to polymethylene fragments in heterospin copper(II) hexafluoroacetylacetonate complexes with nitronyl nitroxide biradicals“. Russian Chemical Bulletin 56, Nr. 9 (September 2007): 1795–804. http://dx.doi.org/10.1007/s11172-007-0279-6.
Der volle Inhalt der QuelleBales, Barney L., und Miroslav Peric. „EPR Line Shifts and Line Shape Changes Due to Spin Exchange of Nitroxide Free Radicals in Liquids“. Journal of Physical Chemistry B 101, Nr. 43 (Oktober 1997): 8707–16. http://dx.doi.org/10.1021/jp970995g.
Der volle Inhalt der QuelleHwang, Jimmy S., und Ghassan A. Oweimreen. „Relating static shifts in the ESR spectra of a nitroxide radical in solution to second order perturbation theory“. Concepts in Magnetic Resonance Part A 30A, Nr. 6 (2007): 349–57. http://dx.doi.org/10.1002/cmr.a.20096.
Der volle Inhalt der QuelleMancini, Giordano, Marco Fusè, Filippo Lipparini, Michele Nottoli, Giovanni Scalmani und Vincenzo Barone. „Molecular Dynamics Simulations Enforcing Nonperiodic Boundary Conditions: New Developments and Application to the Solvent Shifts of Nitroxide Magnetic Parameters“. Journal of Chemical Theory and Computation 18, Nr. 4 (08.03.2022): 2479–93. http://dx.doi.org/10.1021/acs.jctc.2c00046.
Der volle Inhalt der QuelleDissertationen zum Thema "Shift nitroxides"
Vaiedelich, Enzo. „Les agents de contraste radicalaires pour l'IRM de demain“. Electronic Thesis or Diss., Aix-Marseille, 2023. http://www.theses.fr/2023AIXM0049.
Der volle Inhalt der QuelleThis work presents the synthesis of new radical probes sensitive to enzyme activity. These shift nitroxides are synthesized for new methods of detecting enzyme activity by RPE. In addition, these probes allow application in MRI-PDN as new contrast agents for MRI and thus in-vivo measurement of enzyme activity. As a result, they could one day replace the current contrast agents, mostly made from gadolinium. The first part is devoted to the state of the art in the field of contrast agents and MRI-PDN. The second part is devoted to the establishment of the synthesis paths of the proposed targets in 17 and 18 steps, and to the improvement of the first 6 steps already achieved within the CRAB team of the ICR. The third and final part is devoted to the cybotactic study of certain synthetic intermediates possessing characteristics. Thus, it will be detailed of the expected or not interactions between solvent and synthesis intermediates
Jacoutot, Samuel. „Synthèse de sondes nitroxydes pour la détection de l’activité enzymatique : application à la spectroscopie par RPE et à l'IRM rehaussée par effet Overhauser“. Electronic Thesis or Diss., Aix-Marseille, 2020. http://www.theses.fr/2020AIXM0489.
Der volle Inhalt der QuelleThis work presents the synthesis of new radical probes to investigate enzymatic activity. Those probes, named “shifting nitroxides”, are synthesized to develop new methods for the detection of enzymatic activity using EPR, but also for an application in diagnosis by OMRI. The shifing nitroxides could then be an efficient alternative to the gadolinium based contrast agents. The first part focused on the optimization of the synthesis of the free shifting nitroxyde, a key synthetic intermediate. The yield has been improved from 2 to 13 % over ten synthetic steps. The second part is devoted to the synthesis of several nitroxides based probes from the free shifting nitroxide. Thus, this manuscript describes the synthesis of nitroxydes suitable for the detection of lipases by EPR spectroscopy. Other probes have been synthesized for the early detection of pulmonary inflammations: one is currently used for the development of earth’s magnetic field MRI, and the other has been used to develop the first example of in vivo detection of a disease by OMRI. Finally, the synthesis of the first family of shifting nitroxydes recognized by UPA is also described. These probes are then promising for the early diagnosis of cancers using OMRI