Auswahl der wissenschaftlichen Literatur zum Thema „Semi-Heterogeneous Lewis Frustrated Pair“

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Zeitschriftenartikel zum Thema "Semi-Heterogeneous Lewis Frustrated Pair"

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Ma, Yuanyuan, Sai Zhang, Chun-Ran Chang, Zheng-Qing Huang, Johnny C. Ho und Yongquan Qu. „Semi-solid and solid frustrated Lewis pair catalysts“. Chemical Society Reviews 47, Nr. 15 (2018): 5541–53. http://dx.doi.org/10.1039/c7cs00691h.

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Wan, Qiang, Sen Lin und Hua Guo. „Frustrated Lewis Pairs in Heterogeneous Catalysis: Theoretical Insights“. Molecules 27, Nr. 12 (10.06.2022): 3734. http://dx.doi.org/10.3390/molecules27123734.

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Frustrated Lewis pair (FLP) catalysts have attracted much recent interest because of their exceptional ability to activate small molecules in homogeneous catalysis. In the past ten years, this unique catalysis concept has been extended to heterogeneous catalysis, with much success. Herein, we review the recent theoretical advances in understanding FLP-based heterogeneous catalysis in several applications, including metal oxides, functionalized surfaces, and two-dimensional materials. A better understanding of the details of the catalytic mechanism can help in the experimental design of novel heterogeneous FLP catalysts.
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Liu, Lei, Jan Gerit Brandenburg und Stefan Grimme. „On the hydrogen activation by frustrated Lewis pairs in the solid state: benchmark studies and theoretical insights“. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 375, Nr. 2101 (24.07.2017): 20170006. http://dx.doi.org/10.1098/rsta.2017.0006.

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Recently, the concept of small molecule activation by frustrated Lewis pairs (FLPs) has been expanded to the solid state showing a variety of interesting reactivities. Therefore, there is a need to establish a computational protocol to investigate such systems theoretically. In the present study, we selected several FLPs and applied multiple levels of theory, ranging from a semi-empirical tight-binding Hamiltonian to dispersion corrected hybrid density functionals. Their performance is benchmarked for the computation of crystal geometries, thermostatistical contributions, and reaction energies. We show that the computationally efficient HF-3c method gives accurate crystal structures and is numerically stable and sufficiently fast for routine applications. This method also gives reliable values for the thermostatistical contributions to Gibbs free energies. The meta-generalized gradient approximated TPSS-D3 evaluated in a projector augmented plane wave basis set is able to produce sufficiently accurate reaction electronic energies. The established protocol is intended to support experimental studies and to predict new reactions in the emerging field of solid-state FLPs. This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.
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Ghuman, Kulbir Kaur, Laura B. Hoch, Paul Szymanski, Joel Y. Y. Loh, Nazir P. Kherani, Mostafa A. El-Sayed, Geoffrey A. Ozin und Chandra Veer Singh. „Photoexcited Surface Frustrated Lewis Pairs for Heterogeneous Photocatalytic CO2 Reduction“. Journal of the American Chemical Society 138, Nr. 4 (25.01.2016): 1206–14. http://dx.doi.org/10.1021/jacs.5b10179.

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Ghuman, Kulbir Kaur, Laura B. Hoch, Thomas E. Wood, Charles Mims, Chandra Veer Singh und Geoffrey A. Ozin. „Surface Analogues of Molecular Frustrated Lewis Pairs in Heterogeneous CO2 Hydrogenation Catalysis“. ACS Catalysis 6, Nr. 9 (02.08.2016): 5764–70. http://dx.doi.org/10.1021/acscatal.6b01015.

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Trunk, Matthias, Johannes F. Teichert und Arne Thomas. „Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks“. Journal of the American Chemical Society 139, Nr. 10 (03.03.2017): 3615–18. http://dx.doi.org/10.1021/jacs.6b13147.

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Liu, Qiang, Qiaobo Liao, Jinling Hu, Kai Xi, Youting Wu und Xingbang Hu. „Covalent organic frameworks anchored with frustrated Lewis pairs for hydrogenation of alkynes with H2“. Journal of Materials Chemistry A 10, Nr. 13 (2022): 7333–40. http://dx.doi.org/10.1039/d1ta08916a.

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Ghoussoub, Mireille, Shwetank Yadav, Kulbir Kaur Ghuman, Geoffrey A. Ozin und Chandra Veer Singh. „Metadynamics-Biased ab Initio Molecular Dynamics Study of Heterogeneous CO2 Reduction via Surface Frustrated Lewis Pairs“. ACS Catalysis 6, Nr. 10 (23.09.2016): 7109–17. http://dx.doi.org/10.1021/acscatal.6b01545.

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Niu, Zheng, Weijie Zhang, Pui Ching Lan, Briana Aguila und Shengqian Ma. „Promoting Frustrated Lewis Pairs for Heterogeneous Chemoselective Hydrogenation via the Tailored Pore Environment within Metal–Organic Frameworks“. Angewandte Chemie International Edition 58, Nr. 22 (27.05.2019): 7420–24. http://dx.doi.org/10.1002/anie.201903763.

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Niu, Zheng, Weijie Zhang, Pui Ching Lan, Briana Aguila und Shengqian Ma. „Promoting Frustrated Lewis Pairs for Heterogeneous Chemoselective Hydrogenation via the Tailored Pore Environment within Metal–Organic Frameworks“. Angewandte Chemie 131, Nr. 22 (17.04.2019): 7498–502. http://dx.doi.org/10.1002/ange.201903763.

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Buchteile zum Thema "Semi-Heterogeneous Lewis Frustrated Pair"

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Jupp, Andrew R. „Heterogeneous Catalysis by Frustrated Lewis Pairs“. In Frustrated Lewis Pairs, 237–81. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-58888-5_7.

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„Other Directions for FLP Hydrogenations“. In A Primer in Frustrated Lewis Pair Hydrogenation: Concepts to Applications, 129–63. The Royal Society of Chemistry, 2021. http://dx.doi.org/10.1039/9781839162442-00129.

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This chapter described the application of the concept of FLPs in new and unexplored reactivity with dihydrogen beyond organic reductions. The use of this reactivity to generate radicals, effect transfer hydrogenations or dehydrogenation, and the applications of hydrogenation for small-molecule substrates such as CO, CO2 and N2 are considered. In addition, the relevance of FLP reactivity to enzymatic systems, supported FLP catalysts, solid-state reactivity, and heterogeneous catalysts is also considered. These additional directions of growth and applications of FLP–dihydrogen reactivity further affirm the potential of FLP chemistry as a new axiom of chemical reactivity.
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