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Thematische Bibliographien / Relay catalysis / Zeitschriftenartikel

Zeitschriftenartikel zum Thema „Relay catalysis“

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Autor: Grafiati

Veröffentlicht am 7. Juli 2024

Zuletzt aktualisiert am 7. Juli 2024

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1

Lee, Sang-gi, Kyu Ree Lee, Yu Lim Lee und Kyu In Choi. „Cooperative Rh(II)/Pd(0) Dual Catalysis for the Synthesis of Carbo- and Heterocyclic Compounds“. Synthesis 54, Nr. 03 (29.09.2021): 555–64. http://dx.doi.org/10.1055/a-1657-2068.

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AbstractDual transition-metal catalysis has been introduced as a robust tool to synthesize a diverse range of organic compounds that cannot to be accessed by traditional single-metal catalysis. In this context, we have recently developed cooperative Rh(II)/Pd(0) dual catalytic systems that have been utilized for the preparation of heterocyclic compounds through the reaction between Rh(II)-carbenoid and π-allyl Pd(II)-complex intermediates in either synergistic or tandem relay catalysis. In synergistic Rh(II)/Pd(0) dual catalysis, the two reactive intermediates are generated simultaneously, which then undergo formal [6+3] dipolar cycloaddition to afford medium-sized heterocyclic compounds. On the other hand, tandem relay dual catalysis can be enabled through judicious choice of reaction parameters, which proceed through the insertion of Rh(II)-carbenoid into O–H or C–H bonds, followed by Pd(0)-catalyzed allylation to provide allylated benzo-fused cyclic compounds or chiral β-lactam derivatives.1 Introduction2 Synergistic Dual Rh(II)/Pd(0)-Catalyzed Dipolar [6+3]-Cycloaddition for the Synthesis of 1,4-Oxazonines3 Tandem Relay Dual Rh(II)/Pd(0) Catalysis for the Synthesis of 2-Aminoindanones4 Asymmetric Tandem Relay Dual Rh(II)/Pd(0) Catalysis for the Synthesis of α-Quaternary Chiral β-Lactams5 Tandem Relay Dual Rh(II)/Pd(0) Catalysis for the Synthesis of α-Quaternary Indolinones and Benzofuranones6 Conclusion

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2

Jeso, Valer, und Glenn C. Micalizio. „Relay catalysis at a boron centre“. Nature 494, Nr. 7436 (Februar 2013): 179–81. http://dx.doi.org/10.1038/494179a.

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3

Zhang, Yu, Xiao-Ling Feng, Jia-Ye Ni, Bo Fu, Hai-Min Shen und Yuan-Bin She. „Efficient Inhibition of Deep Conversion of Partial Oxidation Products in C-H Bonds’ Functionalization Utilizing O2 via Relay Catalysis of Dual Metalloporphyrins on Surface of Hybrid Silica Possessing Capacity for Product Exclusion“. Biomimetics 9, Nr. 5 (29.04.2024): 272. http://dx.doi.org/10.3390/biomimetics9050272.

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To inhibit the deep conversion of partial oxidation products (POX-products) in C-H bonds’ functionalization utilizing O2, 5-(4-(chloromethyl)phenyl)-10,15,20-tris(perfluorophenyl)porphyrin cobalt(II) and 5-(4-(chloromethyl)phenyl)-10,15,20-tris(perfluorophenyl)porphyrin copper(II) were immobilized on the surface of hybrid silica to conduct relay catalysis on the surface. Fluorocarbons with low polarity and heterogeneous catalysis were devised to decrease the convenient accessibility of polar POX-products to catalytic centers on the lower polar surface. Relay catalysis between Co and Cu was designed to utilize the oxidation intermediates alkyl hydroperoxides to transform more C-H bonds. Systematic characterizations were conducted to investigate the structure of catalytic materials and confirm their successful syntheses. Applied to C-H bond oxidation, not only deep conversion of POX-products was inhibited but also substrate conversion and POX-product selectivity were improved simultaneously. For cyclohexane oxidation, conversion was improved from 3.87% to 5.27% with selectivity from 84.8% to 92.3%, which was mainly attributed to the relay catalysis on the surface excluding products. The effects of the catalytic materials, product exclusion, relay catalysis, kinetic study, substrate scope, and reaction mechanism were also investigated. To our knowledge, a practical and novel strategy was presented to inhibit the deep conversion of POX-products and to achieve efficient and accurate oxidative functionalization of hydrocarbons. Also, a valuable protocol was provided to avoid over-reaction in other chemical transformations requiring high selectivity.

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4

He, Yan-Hong, Yang Xiang, Da-Cheng Yang und Zhi Guan. „Combining enzyme and photoredox catalysis for aminoalkylation of indoles via a relay catalysis strategy in one pot“. Green Chemistry 18, Nr. 19 (2016): 5325–30. http://dx.doi.org/10.1039/c6gc00550k.

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5

Zhou, Wei, Kang Cheng, Qinghong Zhang und Ye Wang. „Relay catalysis in the conversion of syngas“. Chinese Science Bulletin 66, Nr. 10 (25.11.2020): 1157–69. http://dx.doi.org/10.1360/tb-2020-1309.

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6

Cheng, Xing, Yinghua Yu, Zhifeng Mao, Jianxin Chen und Xueliang Huang. „Facile synthesis of substituted 3-aminofurans through a tandem reaction of N-sulfonyl-1,2,3-triazoles with propargyl alcohols“. Organic & Biomolecular Chemistry 14, Nr. 16 (2016): 3878–82. http://dx.doi.org/10.1039/c6ob00377j.

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7

Viertl, Wolfgang, Johann Pann, Richard Pehn, Helena Roithmeyer, Marvin Bendig, Alba Rodríguez-Villalón, Raphael Bereiter et al. „Performance of enhanced DuBois type water reduction catalysts (WRC) in artificial photosynthesis – effects of various proton relays during catalysis“. Faraday Discussions 215 (2019): 141–61. http://dx.doi.org/10.1039/c8fd00162f.

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8

Song, Chuanling, Jianwu Wang und Zhenghu Xu. „Tandem metal relay catalysis: from cyclopropene to polysubstituted furan“. Org. Biomol. Chem. 12, Nr. 31 (2014): 5802–6. http://dx.doi.org/10.1039/c4ob00987h.

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Transmetalation is a key step in traditional coupling reactions. An efficient synthetic methodology of tetrasubstituted furans from cyclopropenes with Cu–Pd transmetalation relay catalysis was presented.

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9

Tripathi, Ravi, Rachel Glaves und Dominik Marx. „The GTPase hGBP1 converts GTP to GMP in two steps via proton shuttle mechanisms“. Chemical Science 8, Nr. 1 (2017): 371–80. http://dx.doi.org/10.1039/c6sc02045c.

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10

Tang, Xinxin, Lan Gan, Xin Zhang und Zheng Huang. „n-Alkanes to n-alcohols: Formal primary C─H bond hydroxymethylation via quadruple relay catalysis“. Science Advances 6, Nr. 47 (November 2020): eabc6688. http://dx.doi.org/10.1126/sciadv.abc6688.

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Nature is able to synergistically combine multiple enzymes to conduct well-ordered biosynthetic transformations. Mimicking nature’s multicatalysis in vitro may give rise to new chemical transformations via interplay of numerous molecular catalysts in one pot. The direct and selective conversion of abundant n-alkanes to valuable n-alcohols is a reaction with enormous potential applicability but has remained an unreached goal. Here, we show that a quadruple relay catalysis system involving three discrete transition metal catalysts enables selective synthesis of n-alcohols via n-alkane primary C─H bond hydroxymethylation. This one-pot multicatalysis system is composed of Ir-catalyzed alkane dehydrogenation, Rh-catalyzed olefin isomerization and hydroformylation, and Ru-catalyzed aldehyde hydrogenation. This system is further applied to synthesis of α,ω-diols from simple α-olefins through terminal-selective hydroxymethylation of silyl alkanes.

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11

Luo, Yanlong, Huaming Sun, Weiqiang Zhang, Xiu Wang, Shan Xu, Guofang Zhang, Yajun Jian und Ziwei Gao. „Triple zirconocene/brønsted acid/CuO cooperative and relay catalysis system for tandem Mannich addition/C–C formative cyclization/oxidation“. RSC Advances 7, Nr. 46 (2017): 28616–25. http://dx.doi.org/10.1039/c7ra00870h.

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12

Wang, Kaixuan, Chaoran Xu, Xinyue Hu, Yuqiao Zhou, Lili Lin und Xiaoming Feng. „Catalytic asymmetric [3+2] cycloaddition of isomünchnones with methyleneindolinones“. Chemical Communications 57, Nr. 71 (2021): 8917–20. http://dx.doi.org/10.1039/d1cc03685h.

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13

Wu, Huaimo, Song Liu, Youyi Wang, Man Yuan, Hong Zhang, Hua Zhou, Lianbo Xiao, Changwu Zheng und Hongxi Xu. „An efficient approach for the synthesis of 1,2-dihydroxanthones enabled by one-pot Claisen condensation/cyclization reactions“. Organic & Biomolecular Chemistry 19, Nr. 18 (2021): 4126–31. http://dx.doi.org/10.1039/d1ob00470k.

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14

Galenko, Ekaterina E., Alexey V. Galenko, Alexander F. Khlebnikov und Mikhail S. Novikov. „Domino transformation of isoxazoles to 2,4-dicarbonylpyrroles under Fe/Ni relay catalysis“. RSC Advances 5, Nr. 24 (2015): 18172–76. http://dx.doi.org/10.1039/c5ra01889g.

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15

Sawant, Devesh M., Shivani Sharma, Ramdas S. Pathare, Gaurav Joshi, Sourav Kalra, Sukanya Sukanya, Antim K. Maurya et al. „Relay tricyclic Pd(ii)/Ag(i) catalysis: design of a four-component reaction driven by nitrene-transfer on isocyanide yields inhibitors of EGFR“. Chemical Communications 54, Nr. 82 (2018): 11530–33. http://dx.doi.org/10.1039/c8cc05845h.

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16

Manisha, Manisha, Seema Dhiman, Jopaul Mathew und S. S. V. Ramasastry. „One-pot relay catalysis: divergent synthesis of furo[3,4-b]indoles and cyclopenta[b]indoles from 3-(2-aminophenyl)-1,4-enynols“. Organic & Biomolecular Chemistry 14, Nr. 24 (2016): 5563–68. http://dx.doi.org/10.1039/c6ob00319b.

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Described herein a divergent strategy for the synthesis of furo[3,4-b]indoles via a sequential Ag(i)/Bi(iii)/Pd(ii) catalysis and cyclopenta[b]indoles via a one-pot Ag(i)/Brønsted acid relay catalysis, starting from the easily accessible 3-(2 aminophenyl)-4-pentenyn-3-ols.

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17

Das, Manajit, Pooja Sharma und Raghavan B. Sunoj. „Machine learning studies on asymmetric relay Heck reaction—Potential avenues for reaction development“. Journal of Chemical Physics 156, Nr. 11 (21.03.2022): 114303. http://dx.doi.org/10.1063/5.0084432.

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The integration of machine learning (ML) methods into chemical catalysis is evolving as a new paradigm for cost and time economic reaction development in recent times. Although there have been several successful applications of ML in catalysis, the prediction of enantioselectivity ( ee) remains challenging. Herein, we describe a ML workflow to predict ee of an important class of catalytic asymmetric transformation, namely, the relay Heck (RH) reaction. A random forest ML model, built using quantum chemically derived mechanistically relevant physical organic descriptors as features, is found to predict the ee remarkably well with a low root mean square error of 8.0 ± 1.3. Importantly, the model is effective in predicting the unseen variants of an asymmetric RH reaction. Furthermore, we predicted the ee for thousands of unexplored complementary reactions, including those leading to a good number of bioactive frameworks, by engaging different combinations of catalysts and substrates drawn from the original dataset. Our ML model developed on the available examples would be able to assist in exploiting the fuller potential of asymmetric RH reactions through a priori predictions before the actual experimentation, which would thus help surpass the trial and error loop to a larger degree.

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18

Ji, Wei-Wei, E. Lin, Qingjiang Li und Honggen Wang. „Heteroannulation enabled by a bimetallic Rh(iii)/Ag(i) relay catalysis: application in the total synthesis of aristolactam BII“. Chemical Communications 53, Nr. 41 (2017): 5665–68. http://dx.doi.org/10.1039/c7cc02105d.

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19

Wang, Leilei, Leiyang Lv und Zhiping Li. „Concomitant functionalization of two different ketones by merging Brønsted acid catalysis and radical relay coupling“. Organic Chemistry Frontiers 9, Nr. 6 (2022): 1561–66. http://dx.doi.org/10.1039/d1qo01787j.

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A novel protocol for the concomitant functionalization of two different ketones integrated with unactivated olefins and tert-butyl hydroperoxide by merging Brønsted acid catalysis and radical relay coupling was reported.

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20

Xiao, Jun-An, Hai Peng, Jin-Shao Liang, Ru-Fang Meng, Wei Su, Qi Xiao und Hua Yang. „Gold/scandium bimetallic relay catalysis of formal [5+2]- and [4+2]-annulations: access to tetracyclic indole scaffolds“. Chemical Communications 57, Nr. 98 (2021): 13369–72. http://dx.doi.org/10.1039/d1cc05658a.

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21

Li, Zhimei, Zhiyin Xiao, Fenfen Xu, Xianghua Zeng und Xiaoming Liu. „Enhancement in catalytic proton reduction by an internal base in a diiron pentacarbonyl complex: its synthesis, characterisation, inter-conversion and electrochemical investigation“. Dalton Transactions 46, Nr. 6 (2017): 1864–71. http://dx.doi.org/10.1039/c6dt04409c.

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22

Ni, Qijian, Xiaoxiao Song, Chin Wen Png, Yongliang Zhang und Yu Zhao. „Access to substituted cyclobutenes by tandem [3,3]-sigmatropic rearrangement/[2 + 2] cycloaddition of dipropargylphosphonates under Ag/Co relay catalysis“. Chemical Science 11, Nr. 45 (2020): 12329–35. http://dx.doi.org/10.1039/d0sc02972f.

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In situ generation of allenes through [3,3]-sigmatropic rearrangement of propargylphosphonates. Divergent allene–allene or allene–alkyne cycloaddition by Ag/Co relay catalysis. Products as promising suppressors of cellular proliferation.

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23

Jia, Yanyan, Tuanjie Li, Chenxia Yu, Bo Jiang und Changsheng Yao. „A facile one-pot synthesis of 2,3-diarylated benzo[b]furans via relay NHC and palladium catalysis“. Organic & Biomolecular Chemistry 14, Nr. 6 (2016): 1982–87. http://dx.doi.org/10.1039/c5ob02336j.

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An efficient one-pot synthesis of 2,3-diarylated benzo[b]furans was realized through the relay catalysis of N-Heterocyclic Carbene (NHC) and palladium from substituted 2′-bromodiphenylbromomethanes and aryl aldehydes.

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24

Kundu, Sohom, Isa Valiyev, Debabrata Mondal, Vishnu Verman Rajasekaran, Abir Goswami und Michael Schmittel. „Proton transfer network with luminescence display controls OFF/ON catalysis that generates a high-speed slider-on-deck“. RSC Advances 13, Nr. 8 (2023): 5168–71. http://dx.doi.org/10.1039/d3ra00062a.

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Upon addition/removal of silver(i) ions and due to efficient inter-component communication, a supramolecular multicomponent network acts as an OFF/ON proton relay with luminescence display enabling switchable catalysis.

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25

Meng, Fan-Tao, Jing-Long Chen, Xiao-Yan Qin, Tian-Shu Zhang, Shu-Jiang Tu, Bo Jiang und Wen-Juan Hao. „Gold self-relay catalysis for accessing functionalized cyclopentenones bearing an all-carbon quaternary stereocenter“. Organic Chemistry Frontiers 9, Nr. 1 (2022): 140–46. http://dx.doi.org/10.1039/d1qo01313k.

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A new gold(i) self-relay catalysis consisting of a 3,3-rearrangement, Nazarov cyclization and Michael addition cascade of 1,3-enyne acetates with aurones and their derived azadienes is reported, producing functionalized cyclopentenones.

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26

Tel-Vered, Ran, Omer Yehezkeli, Huseyin Bekir Yildiz, Ofer I Wilner und Itamar Willner. „Photoelectrochemistry with Ordered CdS Nanoparticle/Relay or Photosensitizer/Relay Dyads on DNA Scaffolds“. Angewandte Chemie International Edition 47, Nr. 43 (13.10.2008): 8272–76. http://dx.doi.org/10.1002/anie.200802590.

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27

Wang, Xianghua, Shuli Dong, Zhili Yao, Lei Feng, Philias Daka, Hong Wang und Zhenghu Xu. „Synthesis of Spiroaminals and Spiroketals with Bimetallic Relay Catalysis“. Organic Letters 16, Nr. 1 (09.12.2013): 22–25. http://dx.doi.org/10.1021/ol4033286.

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28

Escolano, Marcos, Javier Torres Fernández, Fernando Rabasa-Alcañiz, María Sánchez-Roselló und Carlos del Pozo. „Enantioselective Synthesis of Pyrrolizidinone Scaffolds through Multiple-Relay Catalysis“. Organic Letters 22, Nr. 24 (30.11.2020): 9433–38. http://dx.doi.org/10.1021/acs.orglett.0c03344.

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29

Jiao, Dongxia, Jinghua An, Huixiang Li, Zhipeng Huang, Yehong Wang und Feng Wang. „Relay catalysis for conversion of secondary amine to formamide“. Chinese Journal of Catalysis 53 (Oktober 2023): 161–70. http://dx.doi.org/10.1016/s1872-2067(23)64518-8.

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30

Gao, Qian, Peng Zhou, Feng Liu, Wen-Juan Hao, Changsheng Yao, Bo Jiang und Shu-Jiang Tu. „Cobalt(ii)/silver relay catalytic isocyanide insertion/cycloaddition cascades: a new access to pyrrolo[2,3-b]indoles“. Chemical Communications 51, Nr. 46 (2015): 9519–22. http://dx.doi.org/10.1039/c5cc02754c.

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The combination of Co(acac)₂ and AgOTf enables the bimetallic relay catalysis reaction of 2-ethynylanilines and isocyanides, allowing an easy and low-cost access to new densely functionalized pyrrolo[2,3-b]indoles.

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31

Jung, Jihye, Jan Braun, Tibor Czabany und Bernd Nidetzky. „Interplay of nucleophilic catalysis with proton transfer in the nitrile reductase QueF from Escherichia coli“. Catalysis Science & Technology 9, Nr. 3 (2019): 842–53. http://dx.doi.org/10.1039/c8cy02331j.

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32

Guo, Changyan, Yonghong Zhang, Yi Zhang und Jide Wang. „An efficient approach for enhancing the catalytic activity of Ni-MOF-74 via a relay catalyst system for the selective oxidation of benzylic C–H bonds under mild conditions“. Chemical Communications 54, Nr. 30 (2018): 3701–4. http://dx.doi.org/10.1039/c7cc09602j.

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A facile and efficient approach for enhancing the catalytic activity of Ni-MOF-74 via a relay catalysis strategy with [bmim]Br was developed, which is excellent for the selective oxidation of benzylic C–H bond under mild conditions.

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33

Galenko, Ekaterina E., Olesya A. Tomashenko, Alexander F. Khlebnikov und Mikhail S. Novikov. „Metal/organo relay catalysis in a one-pot synthesis of methyl 4-aminopyrrole-2-carboxylates from 5-methoxyisoxazoles and pyridinium ylides“. Organic & Biomolecular Chemistry 13, Nr. 38 (2015): 9825–33. http://dx.doi.org/10.1039/c5ob01537e.

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Methyl 4-aminopyrrole-2-carboxylates were easily synthesized by the reaction of 5-methoxyisoxazoles with phenacylpyridinium salts under hybrid relay catalysis leading to 1-(5-methoxycarbonyl-1H-pyrrol-3-yl)pyridinium salts followed by a one pot Zincke cleavage.

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34

Yang, Dongfeng, Chengyi Wang, Yu Wang, Guohua Liu, Tanyu Cheng und Rui Liu. „One-pot enantioselective construction of 3,4-dihydro-2H-1,4-oxazines over Ru/Au relay catalysis and its mechanistic serendipity“. Organic Chemistry Frontiers 9, Nr. 1 (2022): 102–8. http://dx.doi.org/10.1039/d1qo01482j.

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35

Chen, Ying, Zi-Hao Li, Jing-Jing Hu, Si-Yuan Peng, Lei Rong, Yunxia Sun und Xian-Zheng Zhang. „Remote-controlled multi-enzyme system for enhanced tumor therapy via dark/light relay catalysis“. Nanoscale Horizons 5, Nr. 2 (2020): 283–93. http://dx.doi.org/10.1039/c9nh00583h.

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36

Wang, Bin, Ying Chen, Ling Zhou, Jianwu Wang und Zhenghu Xu. „Zn/Sc bimetallic relay catalysis: one pot cycloisomerization/carbonyl–ene reaction toward oxazole derivatives“. Organic & Biomolecular Chemistry 14, Nr. 3 (2016): 826–29. http://dx.doi.org/10.1039/c5ob02158h.

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37

Kusakabe, Mayu, Kazunori Nagao und Hirohisa Ohmiya. „Radical Relay Trichloromethylacylation of Alkenes through N-Heterocyclic Carbene Catalysis“. Organic Letters 23, Nr. 18 (31.08.2021): 7242–47. http://dx.doi.org/10.1021/acs.orglett.1c02639.

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38

Lu, Liang-Qiu, Yuehui Li, Kathrin Junge und Matthias Beller. „Relay Iron/Chiral Brønsted Acid Catalysis: Enantioselective Hydrogenation of Benzoxazinones“. Journal of the American Chemical Society 137, Nr. 7 (13.02.2015): 2763–68. http://dx.doi.org/10.1021/jacs.5b00085.

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39

Song, Chuanling, Di Sun, Xianglong Peng, Jing Bai, Rongyi Zhang, Shengzhen Hou, Jianwu Wang und Zhenghu Xu. „Dimerization of cyclopropenes to bifurans using tandem metal relay catalysis“. Chemical Communications 49, Nr. 80 (2013): 9167. http://dx.doi.org/10.1039/c3cc44762f.

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40

Liu, Xufang, Bingxue Liu und Qiang Liu. „Migratory Hydrogenation of Terminal Alkynes by Base/Cobalt Relay Catalysis“. Angewandte Chemie 132, Nr. 17 (20.04.2020): 6816–21. http://dx.doi.org/10.1002/ange.201916014.

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41

Liu, Xufang, Bingxue Liu und Qiang Liu. „Migratory Hydrogenation of Terminal Alkynes by Base/Cobalt Relay Catalysis“. Angewandte Chemie International Edition 59, Nr. 17 (02.03.2020): 6750–55. http://dx.doi.org/10.1002/anie.201916014.

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42

Dhiman, Seema, und S. S. V. Ramasastry. „Synthesis of polysubstituted cyclopenta[b]indoles via relay gold(i)/Brønsted acid catalysis“. Chemical Communications 51, Nr. 3 (2015): 557–60. http://dx.doi.org/10.1039/c4cc08174a.

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43

Cheng, Jian, Jin Xie und Chengjian Zhu. „Relay photocatalytic cascade reactions: synthesis of indolo[2,1-a]isoquinoline derivatives via double C(sp3)–H bond functionalization“. Chemical Communications 54, Nr. 13 (2018): 1655–58. http://dx.doi.org/10.1039/c7cc09820k.

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A relay photoredox catalysis strategy concomitant with [1,5] hydrogen atom transfer has been applied in the construction of a biologically important indolo[2,1-a]isoquinoline framework via a cascade reaction. This reaction enables double C(sp³)–H bond functionalization and formation of two carbon–carbon double bonds.

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44

Rao, Qian, Yan Zhang, Xin-Yu Gu, Yin-Ping Liu, Bo Jiang und Wen-Juan Hao. „A Cascade Synthesis of Unsymmetrical Furanized Triarylmethanes via Gold Self-Relay Catalysis“. Catalysts 13, Nr. 7 (29.06.2023): 1051. http://dx.doi.org/10.3390/catal13071051.

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In this paper, A new gold self-relay catalysis enabling intramolecular annulation and intermolecular Michael addition of 3-yne-1,2-diols with aurone-derived azadienes (or para-quinone methides) is reported, efficiently furnishing a range of unsymmetrical furanized triarylmethanes with substituent diversity in good yields. The overall process was governed by the π- and σ-Lewis acid capability of gold complexes, providing a catalytic strategy for constructing triarylmethane skeletons.

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45

Li, Sifeng, Zihao Wang, Haitao Xiao, Zhaoxiang Bian und Jun (Joelle) Wang. „Enantioselective synthesis of indole derivatives by Rh/Pd relay catalysis and their anti-inflammatory evaluation“. Chemical Communications 56, Nr. 55 (2020): 7573–76. http://dx.doi.org/10.1039/d0cc03158e.

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An efficient Rh/Pd relay catalyzed intermolecular and cascade intramolecular hydroamination for the synthesis of exclusive trans 1-indolyl dihydronaphthalenols (up to 88% yield, 99% ee) is described under mild conditions.

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Carceller, Jose Miguel, Maria Mifsud, Maria J. Climent, Sara Iborra und Avelino Corma. „Production of chiral alcohols from racemic mixtures by integrated heterogeneous chemoenzymatic catalysis in fixed bed continuous operation“. Green Chemistry 22, Nr. 9 (2020): 2767–77. http://dx.doi.org/10.1039/c9gc04127c.

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47

Xiao, Xiong, Jing Zeng, Jing Fang, Jiuchang Sun, Ting Li, Zejin Song, Lei Cai und Qian Wan. „One-Pot Relay Glycosylation“. Journal of the American Chemical Society 142, Nr. 12 (09.03.2020): 5498–503. http://dx.doi.org/10.1021/jacs.0c00447.

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48

Song, Chuanling, Yihua Sun, Jianwu Wang, Hui Chen, Jiannian Yao, Chen-Ho Tung und Zhenghu Xu. „Successive Cu/Pd transmetalation relay catalysis in stereoselective synthesis of tetraarylethenes“. Organic Chemistry Frontiers 2, Nr. 10 (2015): 1366–73. http://dx.doi.org/10.1039/c5qo00205b.

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A new and efficient strategy for the synthesis of tetraaryl-substituted olefins with two cis furans based on a Cu/Pd catalyzed oxidative coupling reaction of cyclopropene with internal alkyne was developed. These novel tetraarylethenes were fully characterized and proved to be good AIE luminogens.

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49

Motika, Stephen E., Qiaoyi Wang, Xiaohan Ye und Xiaodong Shi. „Ambient Synthesis of Dienals via Triazole–Gold and Amine Catalysis Relay“. Organic Letters 17, Nr. 2 (07.01.2015): 290–93. http://dx.doi.org/10.1021/ol503393a.

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50

Meng, Jing, Xing-Han Li und Zhi-Yong Han. „Enantioselective Hydroaminomethylation of Olefins Enabled by Rh/Brønsted Acid Relay Catalysis“. Organic Letters 19, Nr. 5 (23.02.2017): 1076–79. http://dx.doi.org/10.1021/acs.orglett.7b00100.

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