Auswahl der wissenschaftlichen Literatur zum Thema „Pingding shi fan xue xiao“

Recently, sulfonamides have been shown to be promising electrolyte components due to their high chemical and electrochemical stability in lithium batteries [1, 2]. The electrolyte stability becomes critical when applying high voltage and/or utilizing Ni-rich layered oxides in high energy density lithium-ion batteries. Another approach to successful Ni-rich cathode performance is to develop a stable and effective cathode electrolyte interphase (CEI). Given the success of sultones and sulfates in this regard [3, 4], it is hypothesized that nitrogen analogs, like sulfonamides, could be tailored to provide a similar benefit. Indeed, Yim et al. [5, 6] have shown that N,N,N’,N’-tetraethylsulfamide (TES) forms a CEI on NMC811 that imparts high voltage cycling stability and less cathode corrosion. Our earlier studies of TES with Ni-rich NCA also formed a favorable CEI and these results are the topic of this presentation. Herein, we examine the performance of 0 - 4 wt.% TES in our commercially available, high power INR18650-P28A. These cells contain a composite SiO/graphite anode in addition to a Ni-rich cathode. As shown in Fig 1, TES significantly decreased the impedance of the cathode interface after conditioning compared to the control electrolyte. Thereafter, cells containing up to 2%TES show improved capacity retention during long-term high-rate cycling (+1C/-80W). Part of this success was due to a suppression of resistance growth during cycling by TES. Fast charge cycling (+3C/-2C), however, was moderately impaired with increased TES. Considering the largely reduced impedance of the cathode, fast-charge performance may have suffered due to anode rate limitations. These results will be discussed as well as gas generation, storage performance, and additional rate and cycling tests. [1] Shuting Feng, Mingjun Huang, Jessica R. Lamb, Wenxu Zhang, Ryoichi Tatara, Yirui Zhang, Yun Guang Zhu, Collin F. Perkinson, Jeremiah A. Johnson, Yang Shao-Horn. Chem, 5, 2630-2641 (2019) [2] Weijiang Xue, Mingjun Huang, Yutao Li, Yun Guang Zhu, Rui Gao, Xianghui Xiao, Wenxu Zhang, Sipei Li, Guiyin Xu, Yang Yu, Peng Li, Jeffrey Lopez, Daiwei Yu, Yanhao Dong, Weiwei Fan, Zhe Shi, Rui Xiong, Cheng-Jun Sun, Inhui Hwang, Wah-Keat Lee, Yang Shao-Horn, Jeremiah A. Johnson, Ju Li. Nature Energy, 6, 495-505 (2021) [3] Koji Abe, Manuel Colera, Kei Shimamoto, Masahide Kondo, Kazuhiro Miyoshi. Journal of Electrochemical Society, 161 (6) A863-A870 (2014) [4] Jian Xia, N. N. Sinha, L. P. Chen, J. R. Dahn. Journal of Electrochemical Society, 161 (3) A264-A274 (2014) [5] Kwangeun Jung, Taeeun Yim. Journal of Alloys and Compounds, 834,155155 (2020) [6] Ji Won Kim, Kwangeun Jung, Taeeun Yim. Journal of Mater. Sci & Tech. 86, 70-76 (2021) Figure 1

Lithium-ion batteries (LIBs) have gained increasing importance in energy storage systems, driven by the growing demands of grid storage, automotive, and portable consumer applications. To meet the need for high energy density batteries, one promising approach involves the utilization of high capacity layered transition metal oxide cathodes, such as nickel-rich LiNi0.8Mn0.1Co0.1O2 (NMC811), which can deliver a high reversible specific capacity of over 180 mAh·g-1 [1,2]. However, due to the structural and interfacial instability[3], nickel-rich NMC cathode still faces challenges in long-term galvanostatic cycling. For these reasons, design of novel electrolyte formulations, which enable formation of an effective cathode electrolyte interphase (CEI), is highly desirable. Recent studies have highlighted the cross-talk between the cathode and anode, indicating that the evolution of the solid electrolyte interphase (SEI) can impact the formation of the CEI[4]. Thus, establishing an effective SEI/CEI pair is essential for achieving long-term cycling of nickel-rich NMC cathode-based cells. Electrolyte optimization plays a crucial role in facilitating the formation of a desirable SEI/CEI pair, leading to an improved cell performance and longevity. Lithium (difluoromethanesulfonyl)(trifluoro-methanesulfonyl)imide (LiDFTFSI) has proven to be promising in solid-polymer-electrolyte batteries due to the good SEI/CEI formation ability and suppressed Al-dissolution[5]. Additionally, LiDFTFSI exhibits also good compatibility with Li-metal batteries[6], heralding promising applications in Li-ion batteries. However, there is lack of systematic research investigating the potential impact of LiDFTFSI on the cathode as well as on resulting CEI formation and dynamics. In this work, we demonstrated enhanced galvanostatic cycling performance of NMC811||graphite cells achieved by utilizing LiDFTFSI and lithium hexafluorophosphate (LiPF6) in a blended salt organic carbonate-based electrolyte formulation. Comprehensive electrochemical and post mortem analysis revealed that the LiDFTFSI alone can effectively mitigate the structural changes in the NMC811 electrode by facilitating the formation of modified CEI. However, the continued growth of an inhomogeneous CEI, caused by the cross-talk effect between electrodes, adversely affected long-term cycling stability. To address this, vinylene carbonate (VC) was introduced to the electrolyte. Synergistic effect with LiDFTFSI leads to the formation of effective and uniform SEI and CEI. As a result, 720 charge/discharge cycles were achieved in NMC811||graphite cells with LiDFTFSI and VC containing electrolytes at 1C while maintaining 80% state-of-health (SOH80%). References [1] R. Schmuch, R. Wagner, G. Hörpel, T. Placke, M. Winter, Nature Energy 2018, 3, 267–278. [2] W. Xue, M. Huang, Y. Li, Y. G. Zhu, R. Gao, X. Xiao, W. Zhang, S. Li, G. Xu, Y. Yu, P. Li, J. Lopez, D. Yu, Y. Dong, W. Fan, Z. Shi, R. Xiong, C.-J. Sun, I. Hwang, W.-K. Lee, Y. Shao-Horn, J. A. Johnson, J. Li, Nature Energy 2021, 6, 495–505. [3] K. Guo, S. Qi, H. Wang, J. Huang, M. Wu, Y. Yang, X. Li, Y. Ren, J. Ma, Small Science 2022, 2, 2100107. [4] S. Fang, D. Jackson, M. L. Dreibelbis, T. F. Kuech, R. J. Hamers, Journal of Power Sources 2018, 373, 184–192. [5] H. Zhang, U. Oteo, X. Judez, G. G. Eshetu, M. Martinez-Ibañez, J. Carrasco, C. Li, M. Armand, Joule 2019, 3, 1689–1702. [6] L. Qiao, U. Oteo, M. Martinez-Ibañez, A. Santiago, R. Cid, E. Sanchez-Diez, E. Lobato, L. Meabe, M. Armand, H. Zhang, Nat. Mater. 2022, 21, 455–462.

Thesis (M.Phil.)--Hong Kong University of Science and Technology, 2004.
Includes bibliographical references (leaves 323-342). Also available in electronic version. Access restricted to campus users.