Thematische Bibliographien / Pickering interfacial catalysis / Zeitschriftenartikel

Zeitschriftenartikel zum Thema „Pickering interfacial catalysis“

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Autor: Grafiati
Veröffentlicht am 22. Juni 2024

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1

Zhao, Qiangqiang, Xiao Zhao, Hui Peng, Yang Liu, Lihui Yang, Jie Sun, Lei Yang und Yifeng Shen. „Correction: Static phase transfer catalysis for Williamson reactions: pickering interfacial catalysis“. Catalysis Science & Technology 9, Nr. 15 (2019): 4147. http://dx.doi.org/10.1039/c9cy90061f.

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2

Ma, Shenghua, Wei Zong und Xiaojun Han. „Magnetic-responsive Pickering emulsion and its catalytic application at the water–oil interface“. New Journal of Chemistry 45, Nr. 8 (2021): 3974–80. http://dx.doi.org/10.1039/d0nj05875k.

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3

Qi, Liang, Zhigang Luo und Xuanxuan Lu. „Modulation of starch nanoparticle surface characteristics for the facile construction of recyclable Pickering interfacial enzymatic catalysis“. Green Chemistry 21, Nr. 9 (2019): 2412–27. http://dx.doi.org/10.1039/c9gc00779b.

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4

Zhang, Hong, Minjing Shang, Yuchao Zhao und Yuanhai Su. „Process Intensification of 2,2′-(4-Nitrophenyl) Dipyrromethane Synthesis with a SO3H-Functionalized Ionic Liquid Catalyst in Pickering-Emulsion-Based Packed-Bed Microreactors“. Micromachines 12, Nr. 7 (05.07.2021): 796. http://dx.doi.org/10.3390/mi12070796.

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A stable water-in-oil Pickering emulsion was fabricated with SO3H-functionalized ionic liquid and surface-modified silica nanoparticles and used for 2,2′-(4-nitrophenyl) dipyrromethane synthesis in a packed-bed microreactor, exhibiting high reaction activity and product selectivity. The compartmentalized water droplets of the Pickering emulsion had an excellent ability to confine the ionic liquid against loss under continuous-flow conditions, and the excellent durability of the catalytic system without a significant decrease in the reaction efficiency and selectivity was achieved. Compared with the reaction performance of a liquid–liquid slug-flow microreactor and batch reactor, the Pickering-emulsion-based catalytic system showed a higher specific interfacial area between the catalytic and reactant phases, benefiting the synthesis of 2,2′-(4-nitrophenyl) dipyrromethane and resulting in a higher yield (90%). This work indicated that an increase in the contact of reactants with catalytic aqueous solution in a Pickering-emulsion-based packed-bed microreactor can greatly enhance the synthetic process of dipyrromethane, giving an excellent yield of products and a short reaction time. It was revealed that Pickering-emulsion-based packed-bed microreactors with the use of ionic liquids as catalysts for interfacial catalysis have great application potential in the process of intensification of organic synthesis.
5

Sadgar, Amid L., Tushar S. Deore und Radha V. Jayaram. „Pickering Interfacial Catalysis—Knoevenagel Condensation in Magnesium Oxide-Stabilized Pickering Emulsion“. ACS Omega 5, Nr. 21 (19.05.2020): 12224–35. http://dx.doi.org/10.1021/acsomega.0c00819.

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6

Wang, Meng, Mengjie Wang, Shengmiao Zhang und Jianding Chen. „Pickering gel emulsion stabilized by enzyme immobilized polymeric nanoparticles: a robust and recyclable biocatalyst system for biphasic catalysis“. Reaction Chemistry & Engineering 4, Nr. 8 (2019): 1459–65. http://dx.doi.org/10.1039/c9re00158a.

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7

Zhang, Mingjie, Zhiyang Tang, Wenqin Fu, Weiying Wang, Rong Tan und Donghong Yin. „An ionic liquid-functionalized amphiphilic Janus material as a Pickering interfacial catalyst for asymmetric sulfoxidation in water“. Chemical Communications 55, Nr. 5 (2019): 592–95. http://dx.doi.org/10.1039/c8cc08292h.

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Novel IL-functionalized amphiphilic Janus chiral salen TiIV catalysts behaved as Pickering interfacial catalysts, dramatically accelerating asymmetric sulfoxidation with aq. H2O2 in water through the formation of stable Pickering emulsions.
8

Reeves, Matthew, Kevin Stratford und Job H. J. Thijssen. „Quantitative morphological characterization of bicontinuous Pickering emulsions via interfacial curvatures“. Soft Matter 12, Nr. 18 (2016): 4082–92. http://dx.doi.org/10.1039/c5sm03102h.

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9

Wang, Lei, Ping Wen, Xiaoman Liu, Yuting Zhou, Mei Li, Yudong Huang, Lin Geng, Stephen Mann und Xin Huang. „Single-step fabrication of multi-compartmentalized biphasic proteinosomes“. Chemical Communications 53, Nr. 61 (2017): 8537–40. http://dx.doi.org/10.1039/c7cc04180b.

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Multi-compartmentalized biphasic proteinosomes were self-assembled using a single-step double Pickering emulsion procedure, and exploited for enzyme-mediated interfacial catalysis, polysaccharide shell templating, and hydrogel functionalization.
10

Zhao, Qianqiang, Xiao Zhao, Hui Peng, Yang Liu, Lihui Yang, Jie Sun, Lei Yang und Yifeng Shen. „Static phase transfer catalysis for Williamson reactions: Pickering interfacial catalysis“. Catalysis Science & Technology 9, Nr. 13 (2019): 3445–53. http://dx.doi.org/10.1039/c9cy00620f.

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11

Li, Dan-dan, Jian-zhong Jiang und Chun Cai. „Palladium nanoparticles anchored on amphiphilic Janus-type cellulose nanocrystals for Pickering interfacial catalysis“. Chemical Communications 56, Nr. 65 (2020): 9396–99. http://dx.doi.org/10.1039/d0cc03892j.

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12

Lv, Huihui, Zebo Wang, Jialong An, Zhanfeng Li, Lei Shi und Yuanyuan Shan. „Preparation and Emulsifying Properties of Carbon-Based Pickering Emulsifier“. Processes 11, Nr. 4 (02.04.2023): 1070. http://dx.doi.org/10.3390/pr11041070.

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Water is increasingly being used as a solvent in place of organic solvent in order to meet the demand for green chemical synthesis. Nevertheless, many of the reaction substrates are organic matter, which have low water solubility, resulting in a low reaction interface and limiting the development of organic-water biphasic systems. A surfactant is typically added to the two-phase system to form an emulsion to increase the contact area between the organic phase and the water. Compared to ordinary emulsion stabilized with the surfactant, Pickering emulsion offers better adhesion resistance, biocompatibility, and environmental friendliness. It possesses unrivaled benefits as an emulsifier and catalyst in a two-phase interfacial catalysis system (PIC). In this study, the amine group (NNDB) was employed to alter the surface of graphene oxide (GO). A stable Pickering emulsion was created by adsorbing GO-NNDB on the toluene–water interface. It was determined that the emulsion system had good stability by analyzing digital photographs and microscope images of droplets at various temperatures, and fluorescence microscopy images of emulsion droplets created by both newly added and recovered emulsifiers. This work provided the groundwork for future applications of Pickering emulsion in interfacial catalysis.
13

Xue, Nan, Gaihong Zhang, Xiaoming Zhang und Hengquan Yang. „A reinforced Pickering emulsion for cascade reactions“. Chemical Communications 54, Nr. 92 (2018): 13014–17. http://dx.doi.org/10.1039/c8cc07644h.

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14

Chang, Fuqiang, Carolien M. Vis, Menno Bergmeijer, Stuart C. Howes und Pieter C. A. Bruijnincx. „Bifunctional Janus Silica Spheres for Pickering Interfacial Tandem Catalysis“. ChemSusChem 14, Nr. 23 (28.10.2021): 5328–35. http://dx.doi.org/10.1002/cssc.202101238.

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15

Pei, Xiaoyan, Jiang Liu, Wangyue Song, Dongli Xu, Zhe Wang und Yanping Xie. „CO2-Switchable Hierarchically Porous Zirconium-Based MOF-Stabilized Pickering Emulsions for Recyclable Efficient Interfacial Catalysis“. Materials 16, Nr. 4 (17.02.2023): 1675. http://dx.doi.org/10.3390/ma16041675.

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Stimuli-responsive Pickering emulsions are recently being progressively utilized as advanced catalyzed systems for green and sustainable chemical conversion. Hierarchically porous metal–organic frameworks (H-MOFs) are regarded as promising candidates for the fabrication of Pickering emulsions because of the features of tunable porosity, high specific surface area and structure diversity. However, CO2-switchable Pickering emulsions formed by hierarchically porous zirconium-based MOFs have never been seen. In this work, a novel kind of the amine-functionalized hierarchically porous UiO-66-(OH)2 (H-UiO-66-(OH)2) has been developed using a post-synthetic modification of H-UiO-66-(OH)2 by (3-aminopropyl)trimethoxysilane (APTMS), 3-(2-aminoethylamino)propyltrimethoxysilane (AEAPTMS) and 3-[2-(2-aminoethylamino)ethylamino]propyl-trimethoxysilane (AEAEAPTMS), and employed as emulsifiers for the construction of Pickering emulsions. It was found that the functionalized H-UiO-66-(OH)2 could stabilize a mixture of toluene and water to give an emulsion even at 0.25 wt % content. Interestingly, the formed Pickering emulsions could be reversibly transformed between demulsification and re-emulsification with alternate addition or removal of CO2. Spectral investigation indicated that the mechanism of the switching is attributed to the reaction of CO2 with amino silane on the MOF and the generation of hydrophilic salts, leading to a reduction in MOF wettability. Based on this strategy, a highly efficient and controlled Knoevenagel condensation reaction has been gained by using the emulsion as a mini-reactor and the emulsifier as a catalyst, and the coupling of catalysis reaction, product isolation and MOF recyclability has become accessible for a sustainable chemical process.
16

Yang, Bingyu, Loïc Leclercq, Jean-Marc Clacens und Véronique Nardello-Rataj. „Acidic/amphiphilic silica nanoparticles: new eco-friendly Pickering interfacial catalysis for biodiesel production“. Green Chemistry 19, Nr. 19 (2017): 4552–62. http://dx.doi.org/10.1039/c7gc01910f.

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17

Xie, Haisheng, Wenyu Zhao, Daniel Chikere Ali, Xuehong Zhang und Zhilong Wang. „Interfacial biocatalysis in bacteria-stabilized Pickering emulsions for microbial transformation of hydrophobic chemicals“. Catalysis Science & Technology 11, Nr. 8 (2021): 2816–26. http://dx.doi.org/10.1039/d0cy02243h.

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18

Tang, Jun, Shixiong Cao und Jianli Wang. „CO2-switchable Pickering emulsions: efficient and tunable interfacial catalysis for alcohol oxidation in biphasic systems“. Chemical Communications 55, Nr. 74 (2019): 11079–82. http://dx.doi.org/10.1039/c9cc04947a.

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19

Du, Kuan, Beichen Yu, Yimin Xiong, Long Jiang, Jun Xu, Yi Wang, Sheng Su, Song Hu und Jun Xiang. „Hydrodeoxygenation of Bio-Oil over an Enhanced Interfacial Catalysis of Microemulsions Stabilized by Amphiphilic Solid Particles“. Catalysts 13, Nr. 3 (12.03.2023): 573. http://dx.doi.org/10.3390/catal13030573.

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Bio-oil emulsions were stabilized using coconut shell coke, modified amphiphilic graphene oxide, and hydrophobic nano-fumed silica as solid emulsifiers. The effects of different particles on the stability of bio-oil emulsions were discussed. Over 21 days, the average droplet size of raw bio-oil increased by 64.78%, while that of bio-oil Pickering emulsion stabilized by three particles only changed within 20%. The bio-oil Pickering emulsion stabilized by Ni/SiO2 was then used for catalytic hydrodeoxygenation. It was found that the bio-oil undergoes polymerization during catalytic hydrogenation. For raw bio-oil hydrodeoxygenation, the polymerization reaction was little affected by the temperature below 200 °C, but when the temperature raised to 250 °C, it was greatly accelerated. However, the polymerization of monocyclic aromatic compounds in the reaction process was partially inhibited under the bio-oil Pickering emulsion system. Additionally, a GC-MS analysis was performed on raw bio-oil and hydrodeoxygenated bio-oil to compare the change in GC-MS-detectable components after hydrodeoxygenation at 200 °C. The results showed that the Pickering emulsion catalytic system greatly promoted the hydrodeoxygenation of phenolic compounds in bio-oil, with most monocyclic phenolic compounds detected by GC-MS converting to near 100%.
20

Zhang, Shi, Dmytro Dedovets, Andong Feng, Kang Wang und Marc Pera-Titus. „Pickering Interfacial Catalysis for Aerobic Alcohol Oxidation in Oil Foams“. Journal of the American Chemical Society 144, Nr. 4 (24.01.2022): 1729–38. http://dx.doi.org/10.1021/jacs.1c11207.

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21

Zhao, Guolin, Yao Li, Bing Hong, Xia Han, Shuangliang Zhao, Marc Pera-Titus und Honglai Liu. „Nanomixing Effects in Glycerol/Dodecanol Pickering Emulsions for Interfacial Catalysis“. Langmuir 34, Nr. 50 (25.11.2018): 15587–92. http://dx.doi.org/10.1021/acs.langmuir.8b02892.

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22

Zhang, Shi, Bing Hong, Zhaoyu Fan, Jingya Lu, Yisheng Xu und Marc Pera-Titus. „Aquivion–Carbon Composites with Tunable Amphiphilicity for Pickering Interfacial Catalysis“. ACS Applied Materials & Interfaces 10, Nr. 31 (12.07.2018): 26795–804. http://dx.doi.org/10.1021/acsami.8b08649.

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23

Xu, Chuanbang, Yan Sun, Yuanyuan Sun, Ruiyun Cai und Shengmiao Zhang. „High Internal Phase Pickering Emulsion Stabilized by Lipase-Coated ZIF-8 Nanoparticles towards Recyclable Biphasic Biocatalyst“. Catalysts 13, Nr. 2 (10.02.2023): 383. http://dx.doi.org/10.3390/catal13020383.

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High internal phase Pickering emulsion (Pickering HIPE) stabilized by enzyme-decorated metal-organic frameworks (MOFs) nanoparticles is developed for biphasic biocatalysts to enhance lipase catalysis and recycling. Specifically, enzyme decorated nanoparticles are prepared via ZIF-8 physisorption of a model lipase Candida antarctica Lipase B (CALB), named ZIF-8@CALB, to be both Pickering stabilizer and catalytic sites. An oil-in-water (o/w) Pickering HIPE with oil/water volume ratio of 3 could then be fabricated by homogenizing p-nitrophenyl palmitate (p-NPP) n-heptane solution into the ZIF-8@CALB aqueous dispersion. The biocatalytic hydrolysis of p-NPP is conducted by just standing the biphasic system at room temperature. The Pickering HIPE system achieves a product conversion of up to 48.9% within 0.5 h, whereas the p-NPP n-heptane solution system containing free CALB only achieves a stable product conversion of 6.8% for the same time. Moreover, the ZIF@CALB could be recovered by a simple centrifugation at 800 rpm, and then reused in the next cycle. The hydrolysis equilibrium conversion rate of p-NPP keeps over 40% for all 8 cycles, reflecting the high catalytic efficiency and recyclability of the Pickering HIPE. This study provides a new opportunity in designing Enzyme-MOFs-based Pickering interfacial biocatalyst for practical applications.
24

Zhao, Wenyu, Haisheng Xie, Xuehong Zhang und Zhilong Wang. „Correlation Relationship between Phase Inversion of Pickering Emulsions and Biocatalytic Activity of Microbial Transformation of Phytosterols“. Catalysts 13, Nr. 1 (30.12.2022): 72. http://dx.doi.org/10.3390/catal13010072.

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Microbial transformation of hydrophobic phytosterols into the pharmaceutical steroid precursors AD (androst-4-ene-3, 17-dione) and ADD (androst-4-diene-3, 17-dione) in a water–plant oil two-phase system by Mycolicibacterium neoaurum is a paradigm of interfacial biocatalysis in Pickering emulsions stabilized by bacterial cells. In the present work, phase inversion of Pickering emulsions—i.e., Pickering emulsions turning from water-in-oil (W/O) emulsions into oil-in-water (O/W) ones—was observed during microbial transformation in the presence of high concentrations of crystal phytosterols. It was found that there is a correlation relationship between the phase behaviors of Pickering emulsions and the biocatalytic activity of utilizing M. neoaurum as a whole-cell catalyst. Efficient microbial transformation under the high crystal phytosterol loadings was achieved due to the formation of O/W emulsions where interfacial biocatalysis took place. Under the optimal conditions (volume ratio of soybean oil to water: 15:35 mL, phytosterols concentration in the soybean oil: 80 g/L, glucose as co-substrate in the aqueous culture medium: 10 g/L), the concentrations of AD and ADD reached 4.8 g/L based on the whole broth (16 g/L based on the oil phase) after microbial transformation for 9 days.
25

Luo, Ruidong, Jinfeng Dong und Yunbai Luo. „pH-Responsive Pickering emulsion stabilized by polymer-coated silica nanoaggregates and applied to recyclable interfacial catalysis“. RSC Advances 10, Nr. 69 (2020): 42423–31. http://dx.doi.org/10.1039/d0ra07957j.

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We synthesized a diblock copolymer and grafted it onto fumed silica in the presence of trifluoroacetic acid to obtain a pH-responsive Pickering emulsion system stabilized by polymer-coated nanoaggregates, P-Si.
26

Pera-Titus, Marc, Loïc Leclercq, Jean-Marc Clacens, Floryan De Campo und Véronique Nardello-Rataj. „Pickering Interfacial Catalysis for Biphasic Systems: From Emulsion Design to Green Reactions“. Angewandte Chemie International Edition 54, Nr. 7 (21.01.2015): 2006–21. http://dx.doi.org/10.1002/anie.201402069.

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27

Wang, Chao, Enqi Bu, Ying Chen, Zhengdong Cheng, Jingtao Zhang, Riyang Shu und Qingbin Song. „Enhanced photoreforming hydrogen production: Pickering interfacial catalysis from a bio-derived biphasic system“. Renewable Energy 134 (April 2019): 113–24. http://dx.doi.org/10.1016/j.renene.2018.09.001.

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28

Ding, Yu, Hao Xu, Haihong Wu, Mingyuan He und Peng Wu. „An amphiphilic composite material of titanosilicate@mesosilica/carbon as a Pickering catalyst“. Chemical Communications 54, Nr. 57 (2018): 7932–35. http://dx.doi.org/10.1039/c8cc03267j.

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The amphiphilic TS-1@silica/carbon (TS-1@Si/C) composite nanoparticle material, synthesized by self-assembling method, constructs stable oil-in-water Pickering emulsion, exhibiting attractive interfacial activity and stability for selective epoxidation of 1-hexene.
29

Pera-Titus, Marc, Loic Leclercq, Jean-Marc Clacens, Floryan De Campo und Veronique Nardello-Rataj. „ChemInform Abstract: Pickering Interfacial Catalysis for Biphasic Systems: From Emulsion Design to Green Reactions“. ChemInform 46, Nr. 13 (März 2015): no. http://dx.doi.org/10.1002/chin.201513347.

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30

Shi, Hui, Zhaoyu Fan, Virginie Ponsinet, Remi Sellier, Honglai Liu, Marc Pera-Titus und Jean-Marc Clacens. „Glycerol/Dodecanol Double Pickering Emulsions Stabilized by Polystyrene-Grafted Silica Nanoparticles for Interfacial Catalysis“. ChemCatChem 7, Nr. 20 (05.08.2015): 3229–33. http://dx.doi.org/10.1002/cctc.201500556.

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31

Zhou, Wen-Juan, Lin Fang, Zhaoyu Fan, Belén Albela, Laurent Bonneviot, Floryan De Campo, Marc Pera-Titus und Jean-Marc Clacens. „Tunable Catalysts for Solvent-Free Biphasic Systems: Pickering Interfacial Catalysts over Amphiphilic Silica Nanoparticles“. Journal of the American Chemical Society 136, Nr. 13 (21.03.2014): 4869–72. http://dx.doi.org/10.1021/ja501019n.

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32

Dong, Zhe, Ziheng Cui, Jun Jin, Xinyi Cheng, Gangcheng Wu, Xingguo Wang und Qingzhe Jin. „Enzymatic Synthesis of Structured Lipids Enriched with Medium- and Long-Chain Triacylglycerols via Pickering Emulsion-Assisted Interfacial Catalysis: A Preliminary Exploration“. Molecules 29, Nr. 4 (19.02.2024): 915. http://dx.doi.org/10.3390/molecules29040915.

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Medium- and long-chain triacylglycerol (MLCT), as a novel functional lipid, is valuable due to its special nutritional properties. Its low content in natural resources and inefficient synthesis during preparation have limited its practical applications. In this study, we developed an effective Pickering emulsion interfacial catalysis system (PE system) for the enzymatic synthesis of MLCT by trans-esterification. Lipase NS 40086 served simultaneously as a catalyst and a solid emulsifier to stabilize the Pickering emulsion. Benefitting from the sufficient oil–water interface, the obtained PE system exhibited outstanding catalytic efficiency, achieving 77.5% of MLCT content within 30 min, 26% higher than that of a water-free system. The Km value (0.259 mM) and activation energy (14.45 kJ mol−1) were 6.8-fold and 1.6-fold lower than those of the water-free system, respectively. The kinetic parameters as well as the molecular dynamics simulation and the tunnel analysis implied that the oil–water interface enhanced the binding between substrate and lipase and thus boosted catalytic efficiency. The conformational changes in the lipase were further explored by FT-IR. This method could give a novel strategy for enhancing lipase activity and the design of efficient catalytic systems to produce added-value lipids. This work will open a new methodology for the enzymatic synthesis of structured lipids.
33

Yang, Bingyu, Loïc Leclercq, Véronique Schmitt, Marc Pera-Titus und Véronique Nardello-Rataj. „Colloidal tectonics for tandem synergistic Pickering interfacial catalysis: oxidative cleavage of cyclohexene oxide into adipic acid“. Chemical Science 10, Nr. 2 (2019): 501–7. http://dx.doi.org/10.1039/c8sc03345e.

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34

Chen, Zhaowei, Haiwei Ji, Chuanqi Zhao, Enguo Ju, Jinsong Ren und Xiaogang Qu. „Individual Surface-Engineered Microorganisms as Robust Pickering Interfacial Biocatalysts for Resistance-Minimized Phase-Transfer Bioconversion“. Angewandte Chemie International Edition 54, Nr. 16 (23.02.2015): 4904–8. http://dx.doi.org/10.1002/anie.201412049.

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35

Tang, Jun, Qi Zhang, Kecheng Hu, Peng Zhang und Jianli Wang. „Novel high TEMPO loading magneto-polymeric nanohybrids: An efficient and recyclable Pickering interfacial catalyst“. Journal of Catalysis 353 (September 2017): 192–98. http://dx.doi.org/10.1016/j.jcat.2017.07.020.

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36

Shakeel, Ahmad, Ujala Farooq und Claire Chassagne. „Interfacial and Bulk Stabilization of Oil/Water System: A Novel Synergistic Approach“. Nanomaterials 10, Nr. 2 (18.02.2020): 356. http://dx.doi.org/10.3390/nano10020356.

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Oil/water emulsions are usually stabilized either by interfacial modification using nanoparticles and surfactants (stated as pickering emulsion or bijels) or by bulk stabilization with the help of low-molecular-weight or polymeric gelators (known as bigels) in response to some external stimuli (e.g., pH, temperature). Both these approaches result in different systems that are quite useful for different applications, including catalysis, pharmaceutical and agrochemicals. However, these systems also possess some inherent drawbacks that need to be addressed, like difficulty in fabrication and ensuring the permanent binding of nanoparticles at the oil/water interface, in case of nanoparticles stabilized emulsions (i.e., interfacial stabilization). Similarly, the long-term stability of the oil/water systems produced by using (hydro/organo) gelators (i.e., bulk stabilization) is a major concern. Here, we show that the oil/water system with improved mechanical and structural properties can be prepared with the synergistic effect of interfacial and bulk stabilization. We achieve this by using nanoparticles to stabilize the oil/water interface and polymeric gelators to stabilize the bulk phases (oil and water). Furthermore, the proposed strategy is extremely adaptable, as the properties of the resultant system can be finely tuned by manipulating different parameters such as nanoparticles content and their surface functionalization, solvent type and its volume fraction, and type and amount of polymeric gelators.
37

Sun, Zhiyong, Ulrich Glebe, Himanshu Charan, Alexander Böker und Changzhu Wu. „Enzyme–Polymer Conjugates as Robust Pickering Interfacial Biocatalysts for Efficient Biotransformations and One‐Pot Cascade Reactions“. Angewandte Chemie International Edition 57, Nr. 42 (15.10.2018): 13810–14. http://dx.doi.org/10.1002/anie.201806049.

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38

Zou, Yulin, Yintang Zhang, Xiaoyan Liu und Haixia Zhang. „Solvent-Free Synthetic Fe3O4@ZIF-8 Coated Lipase as a Magnetic-Responsive Pickering Emulsifier for Interfacial Biocatalysis“. Catalysis Letters 150, Nr. 12 (12.05.2020): 3608–16. http://dx.doi.org/10.1007/s10562-020-03240-w.

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39

Dong, Zhe, Zengshe Liu, Jie Shi, Hu Tang, Xia Xiang, Fenghong Huang und Mingming Zheng. „Carbon Nanoparticle-Stabilized Pickering Emulsion as a Sustainable and High-Performance Interfacial Catalysis Platform for Enzymatic Esterification/Transesterification“. ACS Sustainable Chemistry & Engineering 7, Nr. 8 (25.03.2019): 7619–29. http://dx.doi.org/10.1021/acssuschemeng.8b05908.

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40

Cheng, Jie, Ning Wang, Na Li, Xiaonan Zhou, Dianyu Yu und Lianzhou Jiang. „Construction of magnetic switchable Pickering interfacial catalysis system and its application in the hydrolysis of crude rice bran oil“. International Journal of Food Science & Technology 57, Nr. 5 (16.02.2022): 2879–85. http://dx.doi.org/10.1111/ijfs.15587.

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41

Shi, Hui, Zhaoyu Fan, Virginie Ponsinet, Remi Sellier, Honglai Liu, Marc Pera-Titus und Jean-Marc Clacens. „Inside Cover: Glycerol/Dodecanol Double Pickering Emulsions Stabilized by Polystyrene-Grafted Silica Nanoparticles for Interfacial Catalysis (ChemCatChem 20/2015)“. ChemCatChem 7, Nr. 20 (Oktober 2015): 3189. http://dx.doi.org/10.1002/cctc.201501070.

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42

Diaz de Tuesta, Jose L., Bruno F. Machado, Philippe Serp, Adrián M. T. Silva, Joaquim L. Faria und Helder T. Gomes. „Janus amphiphilic carbon nanotubes as Pickering interfacial catalysts for the treatment of oily wastewater by selective oxidation with hydrogen peroxide“. Catalysis Today 356 (Oktober 2020): 205–15. http://dx.doi.org/10.1016/j.cattod.2019.07.012.

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43

Xie, Yi, Mingshuai Sun, Yu Shen, Hang Li, Guojun Lv, Zhe Cai, Chaoqun Yang, Gusai Awadalkrim Ahead Ali, Fumin Wang und Xubin Zhang. „Preparation of rGO–mesoporous silica nanosheets as Pickering interfacial catalysts“. RSC Advances 6, Nr. 104 (2016): 101808–17. http://dx.doi.org/10.1039/c6ra22389c.

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44

Hiebler, Katharina, Georg J. Lichtenegger, Manuel C. Maier, Eun Sung Park, Renie Gonzales-Groom, Bernard P. Binks und Heidrun Gruber-Woelfler. „Heterogeneous Pd catalysts as emulsifiers in Pickering emulsions for integrated multistep synthesis in flow chemistry“. Beilstein Journal of Organic Chemistry 14 (19.03.2018): 648–58. http://dx.doi.org/10.3762/bjoc.14.52.

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Within the “compartmentalised smart factory” approach of the ONE-FLOW project the implementation of different catalysts in “compartments” provided by Pickering emulsions and their application in continuous flow is targeted. We present here the development of heterogeneous Pd catalysts that are ready to be used in combination with biocatalysts for catalytic cascade synthesis of active pharmaceutical ingredients (APIs). In particular, we focus on the application of the catalytic systems for Suzuki–Miyaura cross-coupling reactions, which is the key step in the synthesis of the targeted APIs valsartan and sacubitril. An immobilised enzyme will accomplish the final product formation via hydrolysis. In order to create a large interfacial area for the catalytic reactions and to keep the reagents separated until required, the catalyst particles are used to stabilise Pickering emulsions of oil and water. A set of Ce–Sn–Pd oxides with the molecular formula Ce0.99− x Sn x Pd0.01O2−δ (x = 0–0.99) has been prepared utilising a simple single-step solution combustion method. The high applicability of the catalysts for different functional groups and their minimal leaching behaviour is demonstrated with various Suzuki–Miyaura cross-coupling reactions in batch as well as in continuous flow employing the so-called “plug & play reactor”. Finally, we demonstrate the use of these particles as the sole emulsifier of oil–water emulsions for a range of oils.
45

Yang, Yulin, Wen-Juan Zhou, Armin Liebens, Jean-Marc Clacens, Marc Pera-Titus und Peng Wu. „Amphiphilic Titanosilicates as Pickering Interfacial Catalysts for Liquid-Phase Oxidation Reactions“. Journal of Physical Chemistry C 119, Nr. 45 (28.10.2015): 25377–84. http://dx.doi.org/10.1021/acs.jpcc.5b07175.

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46

Li, Shengnan, Xiaotong Lu, Qi Liu, Limin Wang, Yujing Liu, Zhongqiu Liu und Anguo Ying. „Template-free fabrication of magnetic mesoporous poly(ionic liquid)s: efficient interfacial catalysts for hydrogenation reaction and transesterification of soybean oil“. Journal of Materials Chemistry A 10, Nr. 7 (2022): 3531–42. http://dx.doi.org/10.1039/d1ta09265k.

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47

Lu, Xiaotong, Shengnan Li, Limin Wang, Sujuan Huang, Zhongqiu Liu, Yujing Liu und Anguo Ying. „Novel photic and magnetic double responsive Pickering interfacial solid catalysts for biodiesel production“. Fuel 310 (Februar 2022): 122318. http://dx.doi.org/10.1016/j.fuel.2021.122318.

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48

Fan, Zhaoyu, Astrid Tay, Marc Pera-Titus, Wen-Juan Zhou, Samy Benhabbari, Xiaoshuang Feng, Guillaume Malcouronne et al. „Pickering Interfacial Catalysts for solvent-free biomass transformation: Physicochemical behavior of non-aqueous emulsions“. Journal of Colloid and Interface Science 427 (August 2014): 80–90. http://dx.doi.org/10.1016/j.jcis.2013.11.047.

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49

Shankar, Ravi, Bhawana Jangir und Asmita Sharma. „Palladium nanoparticles anchored on polymer vesicles as Pickering interfacial catalysts for hydrolytic oxidation of organosilanes“. New Journal of Chemistry 41, Nr. 16 (2017): 8289–96. http://dx.doi.org/10.1039/c7nj01314k.

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The self-assembly of functional polymer vesicles embedded with PdNPs at water–chloroform interfaces provides a novel catalytic route for the synthesis of poly(hydrosiloxane)s, H2RSi[OSiRH]nOSiRH2.
50

Tang, Jun, Xue Zhou, Shixiong Cao, Lingyu Zhu, Lingling Xi und Jianli Wang. „Pickering Interfacial Catalysts with CO2 and Magnetic Dual Response for Fast Recovering in Biphasic Reaction“. ACS Applied Materials & Interfaces 11, Nr. 17 (08.04.2019): 16156–63. http://dx.doi.org/10.1021/acsami.9b00821.

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