Thematische Bibliographien / MIL-100(Fe)

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  2. Dissertationen
  3. Buchteile
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Auswahl der wissenschaftlichen Literatur zum Thema „MIL-100(Fe)“

Autor: Grafiati
Veröffentlicht am 25. Mai 2024

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Zeitschriftenartikel zum Thema "MIL-100(Fe)"

1

Chen, Zhiming, Bo Xu, Xiaomei Wang, Li Zhang, Xiaoqing Yang und Cuncheng Li. „Sandwich-like MIL-100(Fe)@Pt@MIL-100(Fe) nanoparticles for catalytic hydrogenation of 4-nitrophenol“. Catalysis Communications 102 (Dezember 2017): 17–20. http://dx.doi.org/10.1016/j.catcom.2017.08.015.

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2

Pasaribu, Marvin Horale, Karelius Karelius, Eka Putra Ramdhani, Retno Agnestisia, Zimon Pereiz und Erwin Prasetya Toepak. „Synthesis of Mil-100(Fe)@Fe3O4 Composite using Zircon Mining Magnetic Waste as an Adsorbent for Methylene Blue Dye“. BIO Web of Conferences 70 (2023): 02010. http://dx.doi.org/10.1051/bioconf/20237002010.

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The objectives of the present study are to synthesize MIL-100(Fe)@Fe3O4 composite and to clarify its ability as an adsorbent for methylene blue dye. The magnetite (Fe3O4) was synthesized using iron precursor from the zircon mining magnetic waste. The MIL-100(Fe) was composited with magnetite using a room-temperature in situ synthesis method. The MIL-100(Fe)@Fe3O4 composite obtained was then characterized using the Fourier transform infrared spectroscopy and X-ray diffraction. The synthesized MIL-100(Fe) and MIL-100(Fe)@Fe3O4 were then used to adsorb methylene blue dye from aqueous phase. The maximum methylene blue removal from both adsorbents was obtained at pH of 9. The adsorption kinetics showed that the adsorption followed a pseudo second-order kinetics model with the rate constant values for MIL-100(Fe) and MIL-100(Fe)@Fe3O4 were 1.012 x 10-2 and 3.963 x 10-2 g/mg.menit, respectively. The results also showed that the adsorption isotherm of MIL-100(Fe) and MIL-100(Fe)@Fe3O4 follows the Langmuir isotherm for adsorption capacities were 137.70 and 151.47 mg/g, respectively. The results indicate that the iron content in the zircon mining magnetic waste as precursor for synthesis MIL-100(Fe)@Fe3O4 composite can be employed as an excellent adsorbent for removal of methylene blue dye from aqueous phase.
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Mokhtarian, Fatemeh, Banafsheh Rastegari, Sedigheh Zeinali, Maryam Tohidi und Hamid Reza Karbalaei-Heidari. „Theranostic Effect of Folic Acid Functionalized MIL-100(Fe) for Delivery of Prodigiosin and Simultaneous Tracking-Combating Breast Cancer“. Journal of Nanomaterials 2022 (12.01.2022): 1–16. http://dx.doi.org/10.1155/2022/1108865.

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The metal organic framework (MOF) member, MIL-100(Fe), is considered as attractive drug nanocarrier that may be due to the great porosity, colloidal stability, and biocompatibility. In the present study, the new electrochemical synthesis procedure was presented for MIL-100(Fe) building block, and secondly, folic acid (FA) was introduced to the structure for assessing its potential targeted ability to be entrapped by folic acid-positive breast cancer cells, MCF-7. Several techniques such as SEM, XRD, and FT-IR were used to characterize synthesized nanostructures. Both MIL-100(Fe) and MIL-100(Fe)/FA nanoparticles were between 50 to 200 nm with a slightly positive net charge with an area of 1350 and 831.84 m2/g, respectively. The prodigiosin (PG) is selected as a model drug for MIL-100(Fe) and MIL-100(Fe)/FA-targeted delivery owing to its natural fluorescence and cancer cell selectiveness. The loading capacity of both nanocarrier was around 40% with 93-97% loading efficacy. Moreover, the pH-sensitive prodigiosin release rate of MIL-100(Fe)@PG and MIL-100(Fe)/FA@PG showed that 69 to 73% of the drug was released after 24 hours in an acidic environment with around 20% unwanted leakage. The anticancer potential MIL-100(Fe)/FA cells showed the improvement of selective index (SI) from 3.21 to 12.48 which means that folic acid acts as an effective ligand. The study of cells treated with fluorescence microscopy and flow cytometry analysis reveals the dependence of the receptor on the nanoparticle through endocytosis. Considering the effects of nanoparticles on healthy cells, MIL-100(Fe) and MIL-100(Fe)/FA nanoparticles can be introduced as targeted drug delivery systems for smart targeting breast cancer cells with minimal side effects.
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Le Thanh Bac. „Green synthesis of MIL-100(Fe) metal-organic frameworks as a carrier for chloroquine delivery“. Journal of Military Science and Technology, Nr. 76 (12.12.2021): 61–67. http://dx.doi.org/10.54939/1859-1043.j.mst.76.2021.61-67.

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The metal-organic framework MIL-100(Fe) was synthesized by the green process using the ultrasonic method and water. By using this approach, the energy consumption was reduced by 100 times compared to the hydrothermal method. The prepared MIL-100(Fe) was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET surface area measurements. The XRD pattern showed characteristic peaks of MIL-100 (Fe) with the main peaks at 6.3o, 10.3o, 11.1o, and 20.1o. The prepared MIL-100(Fe) was of particle size in a range of from 100 nm to 200 nm, and surface area of 950 m2/g with a pore volume of 0.52 cm3/g. The obtained MIL-100 (Fe) showed a high loading capacity for the chloroquine drug with a maximal capacity of 555 mg/g.
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Pereiz, Zimon, Yunus Pebriyanto, Oktaviani Naulita Turnip, Miranti Maya Sylvani, Karelius Karelius, Eka Putra Ramdhani, Chuchita Chuchita, Retno Agnestisia, Marvin Horale Pasaribu und Erwin Prasetya Toepak. „Synthesis of MIL-100(Fe)@Fe3O4 from Magnetic Zircon Mining Waste Modified by CTAB for Naphthol Dye in Water Removal“. BIO Web of Conferences 79 (2023): 12005. http://dx.doi.org/10.1051/bioconf/20237912005.

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The synthesis of MIL-100(Fe)@Fe3O4 composite modified by CTAB has been reported in this study. This research begins with synthesis of magnetite (Fe3O4), using an iron precursor from zircon mining magnetic waste. The MIL-100(Fe)@Fe3O4 was composited with CTAB using a room-temperature in situ synthesis method. The MIL-100(Fe)@Fe3O4-CTAB composite obtained was then characterized using Fourier Transform Infrared spectroscopy and X-ray diffraction. The synthesized MIL-100(Fe)@Fe3O4-CTAB was then used to adsorb naphthol dye from the aqueous phase. The maximum naphthol removal was obtained at a concentration of CTAB of 0.4 M and pH of 6. The adsorption kinetics showed that the adsorption followed a pseudo second-order kinetics model, with the rate constant values for MIL-100(Fe)@Fe3O4-CTAB being 1,712 x 10-2 g/mg.menit, respectively. The results also showed that the adsorption isotherm of MIL-100(Fe)@Fe3O4-CTAB follows the Langmuir isotherm for adsorption capacities of 63,036 mg/g, respectively. The results indicate that naphthol dye can be effectively removed from the aqueous phase by using the iron content in the magnetic waste from zircon mining, which was used as a precursor for the manufacture of MIL-100(Fe)@Fe3O4-CTAB composite.
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Chen, Gongsen, Xin Leng, Juyuan Luo, Longtai You, Changhai Qu, Xiaoxv Dong, Hongliang Huang, Xingbin Yin und Jian Ni. „In Vitro Toxicity Study of a Porous Iron(III) Metal‒Organic Framework“. Molecules 24, Nr. 7 (28.03.2019): 1211. http://dx.doi.org/10.3390/molecules24071211.

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A MIL series metal‒organic framework (MOF), MIL-100(Fe), was successfully synthesized at the nanoscale and fully characterized by TEM, TGA, XRD, FTIR, DLS, and BET. A toxicological assessment was performed using two different cell lines: human normal liver cells (HL-7702) and hepatocellular carcinoma (HepG2). In vitro cytotoxicity of MIL-100(Fe) was evaluated by the MTT assay, LDH releasing rate assay, DAPI staining, and annexin V/PI double staining assay. The safe dose of MIL-100(Fe) was 80 μg/mL. It exhibited good biocompatibility, low cytotoxicity, and high cell survival rate (HL-7702 cells’ viability >85.97%, HepG2 cells’ viability >91.20%). Therefore, MIL-100(Fe) has a potential application as a drug carrier.
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Elharony, Noura Elsayed, Ibrahim El Tantawy El Sayed, Abdullah G. Al-Sehemi, Ahmed A. Al-Ghamdi und Ahmed S. Abou-Elyazed. „Facile Synthesis of Iron-Based MOFs MIL-100(Fe) as Heterogeneous Catalyst in Kabachnick Reaction“. Catalysts 11, Nr. 12 (29.11.2021): 1451. http://dx.doi.org/10.3390/catal11121451.

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An effective technique was proposed for the synthesis of novel α-aminophosphonates: a three-component one-pot condensation reaction of aniline, aromatic aldehydes, and triphenyl phosphite in the presence of (MIL-100(Fe)) as a heterogeneous catalyst. Initially, MIL-100(Fe) was synthesized using H3BTC and ferric nitrate at low temperature and atmospheric pressure. Further, MIL-100(Fe) was characterized using various techniques such as XRD, BET surface area, scanning electron microscopy (SEM), Fourier-transform infrared (FT-IR), and thermogravimetric analysis (TGA). Herein, MIL-100(Fe) showed exceptional catalytic performance for the synthesis of α-aminophosphonate and its derivatives compared with conventional solid catalysts, and even homogeneous catalysts. The study demonstrated that MIL-100(Fe) is an ecofriendly and easily recyclable heterogeneous catalyst in Kabachnick reactions for α-aminophosphonate synthesis, with high yield (98%) and turnover frequency (TOF ~ 3.60 min−1) at room temperature and a short reaction time (30 min).
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Han, Rui, Yuanling Sun, Yanna Lin, Hao Liu, Yuxue Dai, Xiaodong Zhu, Dandan Gao, Xueying Wang und Chuannan Luo. „A simple chemiluminescent aptasensor for the detection of α-fetoprotein based on iron-based metal organic frameworks“. New Journal of Chemistry 44, Nr. 10 (2020): 4099–107. http://dx.doi.org/10.1039/c9nj05870b.

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9

Matskan, P. A., E. V. Evdokimova und G. V. Mamontov. „MIL-100(Fe)/Diatomite Composites for Photo-Fenton Degradation of Phenol“. Кинетика и катализ 64, Nr. 4 (01.07.2023): 418–27. http://dx.doi.org/10.31857/s045388112304007x.

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Porous materials based on metal-organic framework MIL-100(Fe) and diatomite were synthesized. Composites possess specific surface area of 322 and 441 m2/g and hierarchical porous structure with broad pores of diatomite and narrow pores of MIL-100(Fe) particles. Influence of synthesis strategy on structure of materials and their catalytic properties in photocatalytic degradation of phenol was investigated. Composite obtained with preliminary wet impregnation of iron nitrate solution show predominant formation of MIL-100(Fe) particles inside the pores of diatomite. Materials demonstrate catalytic activity in phenol degradation by photo-Fenton process. Composite synthesized without preliminary wet impregnation displays highest catalytic activity with predominant formation of MIL-100(Fe) particles on external surface of diatomite.
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Chen, Xi, Yanshuang Zhang, Xiangyun Kong, Zanru Guo, Wenyuan Xu, Zhili Fang, Shaohui Wang, Lingzhi Liu, Yongxin Liu und Jiali Zhang. „Controlling crystal growth of MIL-100(Fe) on Ag nanowire surface for optimizing catalytic performance“. RSC Advances 10, Nr. 42 (2020): 25260–65. http://dx.doi.org/10.1039/d0ra04211k.

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Dissertationen zum Thema "MIL-100(Fe)"

1

Mielcarek, Angelika Maria. „Surface engineered hybrid nanocarriers for cancer treatment“. Electronic Thesis or Diss., Université Paris sciences et lettres, 2020. http://www.theses.fr/2020UPSLE033.

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Les nanoparticules métallo-organiques (nanoMOFs) sont des matériaux cristallins poreux à fort potentiel en biomédecine. Les nanoparticules (NP) de carboxylate de fer MIL-100(Fe) sont particulièrement intéressantes. Cependant, malgré de nombreux avantages, ces NP ont tendance à s'agréger dans les milieux physiologiques et à s'accumuler dans les organes après administration intraveineuse. Dans ce travail, nous avons étudié l'impact de différentes voies de modification de surface (covalente et non covalente) sur la stabilité des NP de MIL-100(Fe) dans les milieux physiologiques et la capacité des revêtements à ajuster la biodistribution in vivo et la pharmacocinétique des NP. Nous avons également entrepris de développer une voie de synthèse pour diminuer la taille des NP afin de réduire la capture par les macrophages. Enfin, nous avons étudié l'encapsulation et la libération du méthotrexate (MTX), un médicament anticancéreux dans des NP de MIL-100(Fe) dans deux types d'applications : NP cœur-coquille nanoMOF-oxyde de fer et l’évaluation de la toxicité de molécules par des vers C. elegans
Metal-Organic Frameworks nanoparticles (nanoMOFs) are porous crystalline materials of interest for biomedicine applications. Particularly attractive ones are MIL-100(Fe) iron carboxylate nanoparticles (NPs). Despite many advantages, these NPs tend to aggregate in physiological media and accumulate in organs after intravenous administration. In this work, we investigated the impact of different surface modifications route (covalent and non-covalent) on the colloidal stability of MIL-100(Fe) NPs in physiological media and the ability of the coatings to tune the in vivo biodistribution and pharmacokinetics of NPs. We also investigated different synthesis route to decrease the size of the NPs, in a view of reducing the macrophage recognition. Finally, we studied the encapsulation and release of anticancer drug, Methotrexate (MTX), into magnetic core-shell nanoMOFs-iron oxide NPs and the toxicity evaluation of molecules based on C. elegans worms
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Buchteile zum Thema "MIL-100(Fe)"

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Deshpande, Bhavna D., Pratibha S. Agrawal, M. K. N. Yenkie und S. J. Dhoble. „Wastewater Purification Using Nano-Scale Techniques“. In Water Pollution Sources and Purification: Challenges and Scope, 132–95. BENTHAM SCIENCE PUBLISHERS, 2022. http://dx.doi.org/10.2174/9789815050684122010009.

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This paper presents an exhaustive study of modern methods used to purify water with the support of nanomaterials. For deriving maximum benefits from nanotechnology, the environmental sustainability of the nano-particles must be assessed. Nanoparticles possess useful characteristics contributing to water treatment and the removal of numerous pollutants. Materials such as zeolites, chitosan, MWCNT, nano-composites (Fe3O4 /TiO2 , GO/FeO·Fe2O3 , etc.), nano-oxides (ZnO, TiO2 , Al2O3 , Fe2O3 , Fe3O4 , etc.) and MOF (MOF-808, Cu-terephthalate, CoFe2O4 /MIL-100(Fe), UiO-66-NHC(S) NHMe, etc.) have been included in the study including their apparent functionality in treating contaminated water streams. Additionally, known methods to synthesize these nano particles from diverse sources have been studied. The review highlights the removal of pollutants (non-biodegradable, heavy metals, inorganics, and organics) by adsorption using photo nano adsorbents. Devoid of any recognized standards, the performance of the nanomaterials in wastewater treatment needs further research. With the further advancement of nano technology, ideological guidelines along with general cons and future challenges affecting humans and the ecosystem have been reported to provide further scope for research in this domain.
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Konferenzberichte zum Thema "MIL-100(Fe)"

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Vyshegorodtseva, E. V., P. A. Matskan und G. V. Mamontov. „Formation of hierarchical MIL-100(Fe)diatomite composite“. In INTERNATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF COMBUSTION AND PROCESSES IN EXTREME ENVIRONMENTS (COMPHYSCHEM’20-21) and VI INTERNATIONAL SUMMER SCHOOL “MODERN QUANTUM CHEMISTRY METHODS IN APPLICATIONS”. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0032906.

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Lee, Halim, Soyeon Ahn und Jooyoun Kim. „Water Filtration Efficiency of Mil-100(FE) Metal Organic Framework Immobilized on Nanofibrous Membrane“. In Breaking Boundaries. Iowa State University Digital Press, 2022. http://dx.doi.org/10.31274/itaa.13721.

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3

Razavi, Navid Reza Darban, Nahid Hassanzadeh Nemati und Soroush Sardari. „Fabrication of MIL-100 (Fe) metal-organic framework nanocarrier for the controlled release of Paclitaxel against MCF-7 breast cancer cells“. In 2022 29th National and 7th International Iranian Conference on Biomedical Engineering (ICBME). IEEE, 2022. http://dx.doi.org/10.1109/icbme57741.2022.10053070.

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