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1

Smit, Christelle. „Exploring the use and relevance of narrative approaches to psycho-social interventions in the south African context : a mixed methods content analysis“. Thesis, University of Fort Hare, 2016. http://hdl.handle.net/10353/6432.

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This study aims to explore the use and relevance of Narrative approaches to psycho-social interventions in the South African context. The profession of psychology in South Africa has been in a state of discontentment since the country’s turn to democracy in 1994 which has been voiced from both those within the profession and those it aims to assist. The loudest call is for a psychology that is relevant to the South African context – culturally, socially, and politically. Narrative approaches to psychotherapy and psycho-social intervention are grounded in post-modern and social-constructionist thought and offer an alternative to mainstream psychological theory. Narrative practice aims to promote social justice and views therapy as a political act. It is also an approach that values local knowledges and sees all therapeutic engagements as cross-cultural encounters which are approached with curiosity and a not-knowing stance, rather than an interpretive, analytical lens. This study has investigated what the existing literature has produced regarding the use and relevance of Narrative approaches in South Africa context. The research process was implemented using a mixed methods research methodology whereby a sample of 58 journal articles (n=58) were analysed using both quantitative and qualitative content analysis. The common themes that emerged from the articles were ‘viewing people in context’, ‘listening to the telling of stories’, ‘theoretical constructs of a narrative approach’, and ‘social phenomena’.
2

Mncunzwa, Gcobisa. „Exploring employees' need for the development of an employee assistance programme at a welfare organisation“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5554.

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The study was conducted in order to determine the employee needs for an employee assistance programme in a welfare organisation in East London, Eastern Cape. This study was born out of a need from the management of this welfare organisation in East London who identified a need for an employee assistance Programme (EAP) within their organisation. According to management, there was a decline in productivity, and high stress levels due to high caseloads and societal demands (Leeuw, May 15, 2015). The theoretical framework that guided this research was systems theory. The rationale for using systems theory is that this study deals with individuals within an organisation who must coexist on a daily basis. There is a general belief that people and their physical-social-cultural environment interact in processes of mutual reciprocity and complementary exchanges (Merton, 2009). A qualitative approach was used in this study. Eight (8) employees from various levels in a welfare organisation were purposively selected to participate in the study. Semi-structured interviews were conducted with the participants and the interviews took more than forty-five (45) minutes each and this enabled the acquisition of rich information which is described in the findings and is used as a basis for the recommendations in the study. After the examination of the needs of employees for an EAP from the observations of both the employer and the employee it was clear that there is a need for employee assistance programmes in welfare organisations. Employees in this organisation are experiencing stress, burnout and were highly concerned about high caseloads that makes them feel incompetent to render adequate and quality services to their employees. The study also revealed that both employees and management of this organisation have different needs, experience different types of problems and view the EAP in different contexts. Despite the differences in their outlook on the situation, the evidence indicates that both employer and employee perceive that there is a need for an EAP, especially clinical services. At the same time, the issue of funding such a programme is also a concern. Recommendations were made for the organisation to develop an EAP to address the needs identified by employees, and for a clear communication strategy be developed to make all levels of employees within the organisation aware of the existence of such a programme. Another recommendation was made for the organisation to identify specific days on which they will conduct preventative awareness and debriefing sessions for the employees. It was also recommended that the South African Council for Social Services Professionals must standardise, regulate and monitor caseloads for the social work profession.
3

Ntozakhe, Luyolo. „Synthesis of modified zinc oxide nanoparticles using pneumatic spray pyrolysis for solar cell application“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5862.

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In this work, the pneumatic spray pyrolysis was used to synthesize un-doped and carbon doped zinc oxide (ZnO) nanoparticles. The zinc acetate, tetrabutylammonium bromide and ethanol were used as starting materials for the desired ZnO nanoparticles and the prepared samples were annealed at 400 oC in the furnace. The as synthesized un-doped and carbon doped ZnO NPs were evaluated using X-ray diffraction (XRD), Scanning electron microscope (SEM), Energy dispersive x-ray spectroscopy (EDX), High-resolution transmission electron microscopy (HRTEM), Raman spectroscopy (RS) and Ultraviolet-visible spectroscopy (UV-Vis). XRD analysis of the synthesized NPs revealed peaks at 31.90°, 34.50°, 36.34°, 47.73°, 56.88°, 63.04°, 68.20°, and 77.33° belonging to the hexagonal Wurtzite ZnO crystal structure. The incorporation of C species into ZnO lattice was cross examined by monitoring the peak positions of the (100), (002) and (001) planes. These three main peaks of C-ZnO NPs show a peak shift to higher 2θ values which indicates substitutional carbon doping in ZnO NPs. SEM analysis has revealed that the as synthesized NPs have spherical shape and the morphology of the NPs change as the concentration of carbon increases. The EDX spectra of both un-doped and doped ZnO nanoparticles have revealed prominent peaks at 0.51 keV, 1.01 keV, 1.49 keV, 8.87 keV and 9.86 keV. Peaks at, X-ray energies of 0.51 keV and 1.01 keV respectively represent the emissions from the K-shell of oxygen and L-shell of zinc. The L-shell emission at 1.01 keV is considered as convolution of Zn 2p3/2 and Zn 2p1/2 photoelectron energies. The occurrence of these peaks in the EDX endorses the existence of Zn and O atoms in the PSP prepared samples. HRTEM analysis has revealed NPs size modal range from 6.65-14.21 nm for the PSP synthesized samples which is in mutual agreement with the XRD data calculated values. More over the selected area diffraction images displaying the fact that only the diffraction planes of (101), (002) and (100) are responsible for the diffraction pattern belonging to Wurtzite ZnO. RS analysis has revealed that the un-doped ZnO and doped ZnO samples have characteristic Raman vibration modes at 325 cm-1, and 434 cm-1 belonging to Wurtzite ZnO structure. Moreover, the prominent peak at 434 cm-1 which is the characteristic peak of E2(2) (high) mode of the Wurtzite ZnO and the E2(2) (high) has been red shifted by 4 cm-1, as compared to that found in the bulk ZnO. Additionally, the effect of carbon doping through Raman spectroscopy peak shifts of the E2(2) (high) mode, A1(LO) mode and multi-phonon has also been considered and discussed in detail. UV-Vis diffuse reflectance spectroscopy has revealed a red shift of the absorption edge with increase in C doping. Finally, the effect of nano-crystallite size and gradual prominence of C into ZnO lattice due to increase in C doping concentration in the PSP prepared nanoparticles was meticulously elaborated through Raman Spectroscopy analysis.
4

Stofile, P. Z. „Prevalence of Group B streptococcus and staphylococcus aureus colonization in the anogenital tract of pregnant women in the Eastern Cape Province, South Africa“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5983.

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Neonatal sickness and death is increasingly becoming a public health problem worldwide. The colonization of Group B Streptococcus and Staphylococcus in the rectovaginal area is among the sources of infections in neonates which can result in illness and mortality. The over exposure of humans to antibiotics is the possible cause of resistance in bacteria. These resistant strains can be passed onto offspring, leading to resistant infections and increasing the morbidity of neonates because of treatment failures. Many people, including healthcare personnel are not aware of the effect of these bacteria, and informing clinics and hospitals can help create awareness and monitoring the levels of resistance among bacteria can assist in preventing the transference of the bacteria. In this study we investigated the prevalence of group B Streptococcus (GBS) and Staphylococcus aureus in the anogenital tract of pregnant women in the Eastern Cape Province, South Africa. A total of 49 isolates from 25 (30.5 percent) pregnant women colonized with GBS were isolated from vaginal and rectal swabs of 82 pregnant women at 25-37 gestation who participated in this study. These isolates were obtained using standard microbiological methods and confirmed by polymerase chain reaction (PCR) technique aimed at the ScpB gene. The isolates were further screened for the presence of 9 serogroups (Ia, Ib, II, III, IV, V, VI, VII, VII) and serogroups Ib 2 (4.8 percent), II 20 (40.8 percent) and IV 5 (10.2 percent) and 22 non-typable (44.9 percent) were identified. Susceptibility profiling of the isolates to 12 antibiotics (tetracycline, clindamycin, erythromycin, gentamycin, naladixic acid, norfloxacin, chloramphenicol, cefuroxime, cefotaxime, imipenem, penicillin and vancomycin) was tested in vitro by the standardized disc diffusion method. All the confirmed GBS isolates (49) were resistant to erythromycin, tetracycline and clindamycin. A higher percentage of the isolates were resistant to gentamycin 44 (90 percent), nalidixic acid 41 (84 percent), penicillin 41 (84 percent), chloramphenicol 38 (78 percent), cefuroxime 36 (74 percent), imipenem 36 (74 percent), cefotaxime 35 (71 percent), norfloxacin 32 (65 percent) and vancomycin 31 (78 percent). Multiple antimicrobial resistance patterns ranged from 9‒11 and indices ranged from 0.7‒0.9, respectively. Among the antimicrobial resistance determinants examined, genes encoding for resistance to erythromycin ermB 25 (51 percent), tetracycline tetM 32 (65 percent) and penicillin bla-Z 4 (8 percent) only were identified. On the other hand, screening for S. aureus yielded a total of 7 isolates from 4 study participants as confirmed by PCR based on staphylococcal, nuc gene. The isolates were further screened for the presence of six virulence genes (Hla, Hlb, LUKM, LUKED, PVL, Eta and Etb) and antibiotic susceptibility pattern by the disc diffusion method using 12 (penicillin, vancomycin, tetracycline, rifampicin, imipenem, gentamycin, chloramphenicol, norfloxacin, oxacillin, erythromycin and sulfamethoxazole-trimethoprim) antibiotics that are adopted in the treatment of infections caused by the organism. PVL 6 (85.7 percent) and eta 1 (14.3 percent) were the two virulence genes detected. The following percentages of antibiotics resistance among the isolates were observed; penicillin G 7 (100 percent), clindamycin 7 (100 percent), vancomycin 5 (100 percent), rifampicin 5 (71 percent), oxacillin 5 (71 percent), erythromycin 5 (71 percent) gentamycin 3 (43 percent), norfloxacin 3 (43 percent), sulfamethoxazole-trimethoprim 3 (43 percent), chloramphenicol 2 (29 percent), imipenem 1 (14 percent). Multiple antimicrobial resistance patterns ranged from 7‒8 and indices ranged from 0.6‒0.7, respectively. Genetic profiling of the resistance genes identified erythromycin ermB 5(71.4 percent), tetracycline tetM 5(71.4 percent) and penicillin bla-Z 1(14.3 percent) only. The findings from the study have revealed GBS and S. aureus colonization of pregnant women in the Eastern Cape Province, and these have great public health implications especially for the neonates who are mostly likely to be infected during birth. The unidentifiable multidrug resistant serogroups of GBS as well as resistant S. aureus limit the choice of drugs in the management of infections caused by these pathogens more so if transmitted to infants. Therefore asymptomatic pregnant women needed to be properly educated about the bacteria as well as the precautions that need to be taken.
5

Mditshwa, Sithembele. „Estimating maize grain yield from crop growth stages using remote sensing and GIS in the Free State Province, South Africa“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/6016.

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Early yield prediction of a maize crop is important for planning and policy decisions. Many countries, including South Africa use the conventional techniques of data collection for maize crop monitoring and yield estimation which are based on ground-based visits and reports. These methods are subjective, very costly and time consuming. Empirical models have been developed using weather data. These are also associated with a number of problems due to the limited spatial distribution of weather stations. Efforts are being made to improve the accuracy and timeliness of yield prediction methods. With the launching of satellites, satellite data are being used for maize crop monitoring and yield prediction. Many studies have revealed that there is a correlation between remotely sensed data (vegetation indices) and crop yields. The satellite based approaches are less expensive, save time, data acquisition covers large areas and can be used to estimate maize grain yields before harvest. This study applied Landsat 8 satellite based vegetation indices, Normalized Difference Vegetation Index (NDVI), Soil Adjusted Vegetation Index (SAVI) and Moisture Stress Index (MSI) to predict maize crop yield. These vegetation indices were derived at different growth stages. The investigation was carried out in the Kopanong Local Municipality of the Free State Province, South Africa. Ground-based data (actual harvested maize yields) was collected from Department of Agriculture, Forestry and Fisheries (DAFF). Satellite images were acquired from Geoterra Image (Pty) Ltd and weather data was from the South African Weather Service (SAWS). Multilinear regression approaches were used to relate yields to the remotely sensed indices and meteorological data was used during the development of yield estimation models. The results showed that there are significant correlations between remotely sensed vegetation indices and maize grain yield; up to 63 percent maize yield was predicted from vegetation indices. The study also revealed that NDVI and SAVI are better yield predictors at reproductive growth stages of maize and MSI is a better index to estimate maize yield at both vegetative and reproductive growth stages. The results obtained in this study indicated that maize grain yields can be estimated using satellite indices at different maize growth stages.
6

Mahachi, Leo Nyikadzino. „Physiochemical, fatty acids, lipid oxidation, sensory characteristics and consumer acceptance of warthog cabanossi produced with pork backfat and fat-tailed sheep backfat“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/6259.

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The objective of this study was to determine the effect of different fat inclusion levels and fat types on the physical and chemical attributes, lipid oxidation, fatty acid composition and sensory characteristics of warthog cabanossi. To achieve this, three types of cabanossi with different pork backfat levels (10 percent, 20 percent and 30 percent) were produced for the first experiment. The results from the study showed that different inclusion levels of pork backfat had an influence (P ≤ 0.05) on the physicochemical and fatty acid composition of warthog cabanossi but did not influence lipid oxidation (P > 0.05). The highest (P ≤0.05) pH, weight and moisture decline was observed in the 10 percent pork backfat cabanossi compared to the 20 percent and 30 percent treatments. However, no differences (P > 0.05) in the water activity of the product were observed. As expected total fat was lower in the 10 percent fat treatment and increased concomitantly. Similarly, protein, ash and salt were higher in the 10 percent fat cabanossi and decreased concomitantly. Differences in the fatty acid composition were observed between treatments. Furthermore, backfat level affected the sensory attributes and consumer acceptance of the cabanossi. Ten percent backfat cabanossi was scored higher (P ≤0.05) for most sensory attributes. Consequently, it was observed that the consumer panel preferred and scored the 10 percent fat cabanossi higher with regards to appearance and taste. In the second experiment, two cabanossi treatments of different fat types (pork backfat and fat-tailed sheep backfat) were produced. The weight loss, moisture content, pH, water activity and salt content did not differ (P > 0.05) between the two cabanossi products. However, there were differences (P ≤0.05) in the protein, fat and ash contents; where protein and ash were higher in the pork backfat cabanossi whilst fat was higher in the sheep backfat cabanossi. Thiobarbituric reactive substances (TBARS) were similar (P > 0.05) between the two fat types cabanossi which could be explained by similar fatty acid profiles being reported for the two cabanossi although the n-6:n-3 ratio was higher (P ≤0.05) in sheep backfat cabanossi. Results from the descriptive sensory analysis showed two distinct products (P ≤0.01) where pork backfat cabanossi scored higher for most attributes. However, the lower scores for sheep backfat cabanossi were within an acceptable range. Sheep backfat cabanossi were also scored for unique attributes that were not detected in the pork backfat cabanossi. This study concluded that fat-tailed sheep backfat can be used to produce an unique cabanossi product of acceptable quality.
7

Walton, Karen Lynn. „The relationship between religion/spirituality and the general psychological well-being of the institutionalized elderly population in the Eastern Cape, South Africa“. Thesis, University of Fort Hare, 2015. http://hdl.handle.net/10353/5708.

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Psychological well-being has a number of known benefits and is important for the quality of life of the elderly in particular. South Africa can be considered a religious country with the majority of citizens identifying with some religious orientation. The elderly are considered to be a more religious segment of the population, leading to a quantitative exploratory study being undertaken in order to ascertain whether a correlation exists between psychological well-being and religiosity/spirituality in the elderly institutionalised population of South Africa. The General Psychological Well-Being Scale and ASPIRES was administered to a convenience sample of 336 participants in the Eastern Cape Province. A significant but weak positive correlation was found between the variables of psychological well-being and religiosity. A difference was also found between White and African participants’ level of psychological well-being. An ANOVA was performed on the demographic information collected from participants. It was found that higher levels of education and access to private medical care were associated with higher levels of psychological well-being. A regression analysis was also performed on the data. It was found that although religiosity/spirituality does account for some of the variance, there were still a large number of other factors that influence psychological well-being in the elderly that were not captured in this study. Limitations of the study are that the results can’t be generalised to elderly residing at home. All of the participants also lived in urban areas and so differences may be found with rural elderly. Some further directions for research are discussed.
8

Magomani, Matimba Israel. „The effect of fire management on chemical and physical properties of rangelands“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/6191.

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The use of fire in rangeland has become standard practice for decades; however, there is no shared understanding of how fire affects soil properties. The exact relationship between fire and soil properties is still yet to be understood. The differences in fire frequency, fire intensity, fire severity, the period between fire and sampling resulted in contradictory results amongst studies. A long-term trial at the University of Fort Hare provides a valuable experimental layout for fire research. The trial was established in 1980 with the aim of investigating the effect of burning frequency on vegetation species composition and biomass production. The objective of this study was however to determine the effect of fire management on soil chemical and physical properties under the long-term burning experiment. The treatments of the study site were: no burn (K), annual (B1), biennial (B2), triennial (B3), quadrennial (B4) and sexennial (B6) burns. A line intercept sampling technique was used to collect the soil samples from the surface (0 to 75 mm) for both chemical and physical analysis. All Burning treatments significantly (p < 0.05) increased the bulk density (Db), soil pH, total cations, Magnesium (Mg) and Calcium (Ca), but reduced the soil porosity and exchangeable acidity when compared to the control. Hydraulic conductivity (Ks), water conducting macroporosity (WCM) and total nitrogen were reduced under more frequent burning treatments (B1, B2), as compared to less frequent burning treatments (B3, B4, B6). The aggregate stability showed an opposite trend. Total organic carbon (TOC) was reduced only under annual burning treatment. Burning frequencies did not impact the extractable Phosphorus (p), Potassium (K), Sodium, soil water repellency and water content significantly (P > 0.05). The risk associated with annual burning showed in this study might facilitate processes such as overflow that lead to soil degradation. Triennial burning in rangeland ecosystem supports soil conservation practices. Further studies that measure the quality of rangeland in triennial burning is necessary.
9

Noruka, Asanda. „An appraisal of the role of the National Rural Youth Service Corps in youth development in peri-urban Buffalo City Metropolitan Municipality, South Africa“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5795.

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Youth unemployment is a global problem, but more-so in Southern globally positioned countries such as South Africa. The government of South Africa has implemented different interventions that attempt to alleviate national youth unemployment. Some of these programmes, such as the National Rural Youth Service Corps (NARYSEC), specifically target youth in rural and peri-urban areas. NARYSEC aims to develop skills of the youth in rural and peri-urban areas as well as assist in rural development. Despite the introduction of NARYSEC, unemployment among the youth continues to be a problem. Against this background, this study sought to examine rural youth and development interventions implemented by NARYSEC in peri-urban Buffalo City Metropolitan Municipality. Furthermore, the study assessed the extent to which NARYSEC interventions are contributing to rural youth and development in peri-urban Buffalo City Metropolitan Municipality. Lastly, the study examined the limitations of NARYSEC interventions in peri-urban youth development. To achieve the above objectives, the study used a qualitative research approach. The sampling procedure was purposive as the research required specific participants who have gone through NARYSEC training. A total of 24 respondents were eventually selected. In-depth, semi-structured interviews and key informant interviews were the primary data collection tools. Some of the main findings are that NARYSEC provides various skills training programmes which prepare young people for the labour market. NARYSEC interventions are also helping communities to reduce crime through providing youth employment opportunities. Furthermore, some youth actively participate in rural development projects such as rehabilitation of local clinics and construction projects. However, the study also found that there are a number of limitations and challenges that are experienced in the implementation of the NARYSEC programme. These challenges include lack of strategic planning in the programme, irregular stipend payments, strained professional relationships between NARYSEC programme facilitators and youth participants, limited passion and commitment to the programme by both youth participants and facilitators.
10

Mkono, Yonela Pelokazi. „Evaluation of some pseudomonas species isolated from Hogsback forest reserve for the production of antibacterial compounds“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5961.

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Pseudomonas species are Gram-negative bacteria most abundant in soil and water bodies, with the capacity to thrive in varied environments. They are largely associated with resistant pathogenic bacteria linked to human and plant diseases. Species such as Pseudomonas aeruginosa have been particularly targeted as case studies due to the extremity to which they pose a threat to human health. With more focus directed at using these species for biocontrol and bioremediation purposes, their role in bioactive compound production may be equally important. As the crisis on antimicrobial resistance still persists, the need for effective antimicrobial compounds is ever more urgent and solutions may possibly still be dormant in bacterial species whose potential has not been fully investigated. On a bid to source out potential antimicrobial compound producers, soil samples were collected from Hogback forest reserve in the province of the Eastern Cape, South Africa. For bacterial screening, M1 and R2A agar were used and the cultures grown at 37˚C for a period of seven days. After the presumed Pseudomonas species were identified, antimicrobial production was determined by submerged fermentation method using nutrient broth as media of choice. Active isolates were further studied to determine the optimum conditions which best facilitate for antimicrobial compound production, with parameters such as temperature (25˚C – 40˚C) and pH (4 – 9) considered. The role plasmids play in antimicrobial compound production was also investigated. Each isolate was grown in fermentation media containing Sodium dodecyl sulphate and Ethedium Bromide, at varying concentrations, to facilitate for plasmid curing. With each sample, distinct colonies were identified with varying pigmentations most dominant being a cream colour. The identity of the isolated strains was achieved through sequencing of 16S rDNA. Phylogenetic analysis showed that isolate A16 had 80 percent homology with Pseudomonas plecoglossicida strain P4 and share a close ancestor with isolates Y52 and Y81, also isolate Y89 showed a 90 percent homology with Pseudomonas sp. Co-11a. With the exception of isolate A16, the isolates which were active against Gram-negative bacteria lost activity as the screening processes continued. When looking at temperature variations, isolates Y81 and A16 were highly active with maximum activity observed at 35˚C while Y89 performed best at 25˚C and Y52 showed constant activity across all studied temperatures. The plasmids in all isolates were found to be 48.5 kb in size with the exception of isolate Y89 which was 20 kb. The plasmids were cured at concentrations of (1 mg/ml; 5 mg/ml; 7 mg/ml; 10 mg/ml; 11 mg/ml) SDS and (125 μg/ml; 6.5 μg/ml; 5μg/ml) EtBr. The curing process also showed changes in both the antimicrobial activity of the isolates as well as their physical characteristics. The isolates are the first reported Pseudomonas species from Hogsback forest reserve with the ability to produce antimicrobial compounds which are active against Gram-positive and Gram-negative bacteria. These mesophilic bacteria also show that plasmids do not pay any role in the production of antimicrobial compounds and that the biosynthesis genes are highly likely to be chromosomal borne meaning that the production cannot be linked to horizontal transfer of genes. Therefore, these isolated Pseudomonas species provide a potential reservoir of antimicrobial compounds which may play an important role in the antimicrobial resistance phenomenon.
11

Masikisiki, Baphumelele. „The investigation of the role and the efficacy of learning technologies towards community skill development“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5972.

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Research has revealed that during systems design and development of e-learning technologies there is a tendency of neglecting the needs of end users and focus on the design process and the technology factors, and this has traditionally been the reason for poor usability of otherwise well conceptualized systems, as a result a number of IT-based learning tools ended up not being usable and not being utilized effectively. This study aims to investigate the impact of e-learning technologies, how people perceive the usage of e-learning technologies towards community skill development. An evaluation of four different e-learning technologies was conducted to investigate the role and efficacy of e-learning technologies within the surrounding communities. Data was analyzed as nominal data using IBM Statistical Package for Social Sciences (SPSS) software 24. Descriptive analysis, frequency, reliability and correctional analysis and also measures of central tendency were computed. Reliability was evaluated for assessing the internal consistency of the items using Cronbach’s alpha. To analyze the relationship between variables matrices of Pearson’s correlation was used. Pearson’s correlation can only be accepted when the significant effect (P>.05), this indicates that there is a positive or a negative relationship between two variables, if these conditions are not met then the proposed correlation or hypothesis can be rejected. Results indicate a poor perception and poor acceptance of e-learning technologies due to a number of factors, these factors include lack of computer-self efficacy which leads to computer anxiety, affordability of internet connectivity which leads to inaccessible of e-learning technologies. The findings also indicated that LAMS was found to be less useable and less useful by a number of students. However, students who enjoy working in groups found LAMS to be useable because it was supporting their preferred learning style, whereas individualistic students preferred Moodle and Dokeos because it was supporting their personal preferences and assessment styles. Having understood all the characteristics of learning tools, relevant learning technologies that are suitable for students can then be recommended.
12

Van, Rooyen Yolande. „An exploration of offenders' experiences and social workers' perceptions of standardised anger management programme:|ba case study at St Albans Correctional Centre“. Thesis, University of Fort Hare, 2016. http://hdl.handle.net/10353/6391.

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The purpose of this research is to explore offenders’ experiences and social workers’ perceptions of the Standardised Anger Management Programme as facilitated by social workers at the Department of Correctional Services. The offender population in South Africa is diverse in terms of culture, language, religion, education and socio economic status. The Department of Correctional Services is committed to providing needs-based programmes for offenders to address their offending behaviour in ways that are appropriate for each. The research design was based on a case study. Thirteen offenders from St Albans Correctional Centre who had completed the Standardised Anger Management Programme, together with three social workers at the centre, participated in the evaluation of the effectiveness of the programme. Evaluations were conducted by means of questionnaires and semi-structured interviews with the thirteen offenders, and a focus group discussion with the three social workers facilitating the programme. Together, these three methods yielded useful and insightful ideas on the areas where the programme’s challenges lie, and led to the formulation of several general and specific recommendations, which are presented in chapter five of this thesis. The thesis bases its critique of the programme on insights gained from the literature; expanding on all aspects of the ecological approach to the individual. A detailed presentation of the ecological approach is given in chapter three. The various individual, micro-, exo- and macrosystems that make up the totality of influences on a person’s life are reviewed, and are referred to again in chapter four, which presents the finding of the study. The findings and discussion thereof are, of course, presented in the context of the Department of Correctional Service’s legislative and legal framework, which takes its direction from the 2005 White Paper on Corrections. This White Paper firmly set the Department of Correctional Services on a path towards rehabilitative, rather than purely punitive, treatment of offenders. Its publication was followed soon after by the introduction of the Standardised Anger Management Programme which, as the name suggests, was an attempt to standardise all the hitherto piecemeal rehabilitative efforts of various centres around the country. The study found that facilitators and the participants of the Standardised Anger Management Programme had areas of commonality regarding their views on the programme. The findings suggest that while participants in the programme gained anger management skills, much needs to be done to revise and improve the programme, so that it better addresses the needs of the unique offender population of South Africa. Among many recommendations made in chapter five, the researcher recommends that social workers are adequately trained and equipped to present the programme. In addition, the issues of course content and cultural assumptions, offender motivation and centre officials’ attitudes also need to be addressed.
13

Ramkhalawon, Shabeerah. „Antibiotic stewardship: the role of clinical pharmacist“. Thesis, Nelson Mandela Metropolitan University, 2015. http://hdl.handle.net/10948/10858.

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South Africa has a high prevalence of infectious diseases; the major ones being the Human Immunodeficiency Virus/Acquired Immune Deficiency Syndrome epidemic, and tuberculosis. South Africa’s burden of resistant bacteria is also increasing. Antibiotic resistance in hospitalised patients leads to an increase in morbidity and mortality, resulting in longer hospital stays, and an increase in hospital costs. In order to counteract the problem of antibiotic resistance in hospitals and other healthcare facilities and preserve the efficacy of currently available antibiotics, there is a need for serious antibiotic management. Antibiotic stewardship initiatives have thus been put in place to guide healthcare professionals on the correct use of antibiotics. Clinical pharmacists can intervene and contribute to antibiotic stewardship owing to comprehensive knowledge of antibiotics, including the properties, uses, safety and efficacy of individual agents. There is a paucity of research to support the role of the clinical pharmacist in antibiotic stewardship in public sector hospitals. The current pharmacist staffing system within public sector hospitals does not adequately support pharmacists, in particular clinical pharmacists, to participate actively in antibiotic stewardship. The primary aim of the study was to evaluate the role of the clinical pharmacist in antibiotic stewardship in a public hospital setting. A secondary aim was to contribute towards more rational inpatient use of antibiotics in the general medical ward. The hypothesis for the study was that clinical pharmacists can make a positive contribution to the correct use of antibiotics in a public hospital setting. The study showed that the introduction of a pharmacist-driven antibiotic stewardship in the ward, using a prospective audit and feedback strategy, had a positive effect on overall appropriateness of antibiotic prescribing (Chi2=7.89; df=3; p=0.04815, Cramer’s V=0.13). However, this finding did not show any reduction in the volume of antibiotic use. Positive patient outcomes were achieved and shown through a reduction in the length of hospital stay (p=0.00487; one-way ANOVA). Although patients were not followed up on discharge to assess re-admission rates, the results are relevant in order to inform the hospital staff about the implementation of antibiotic stewardship at the public hospital setting with the aims of reducing inappropriate antibiotic prescribing and improving patient outcomes. From the results of the study, it can be concluded that the hypothesis was achieved and that the clinical pharmacist did play an integral role in antibiotic prescribing at the public hospital setting. Thus, it can be concluded that the study, though limited in its scope, achieved its aims and objectives, and showed that the clinical pharmacist does play an integral role in the rational use of antibiotics in a public hospital setting.
14

Mqingwana, Phelo Zolisa. „An assessment of the implementation of employment equity: Department of Transport in the province of the Eastern Cape“. Thesis, Nelson Mandela Metropolitan University, 2015. http://hdl.handle.net/10948/11335.

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During the apartheid era black people were systematically excluded from all positions of influence in the state and civil society. The majority of senior posts in government were held by whites, in particular, white males. Women and people with disabilities were similarly disadvantaged and marginalised, particularly those from black communities. With the new post-apartheid dispensation, the democratic government took a conscious decision to change that situation. It is against this background that that the Employment Equity Act (EEA) was introduced in 1998. The two main aims of the Act are: to achieve employment equity by promoting equal opportunity and fair treatment in employment through the elimination of unfair discrimination; and to implement the affirmative action measures, to redress the disadvantages in employment experienced by designated groups in order to ensure their equitable representation in all occupational categories and levels in the workforce. The implement of EEA in the Eastern Cape Department of Transport (ECDOT) has so far not been very successful as the Department still has not managed to meet the set targets. According to their Employment Equity Plan (EEP), the senior management level (SMS) is still dominated by males. Although the situation is slightly better at the middle management level, it is still far from being ideal. The lower ranks are dominated by females. With regard to people with disabilities (PWDs) the Department is still far from meeting their 2% target. The purpose of this research was to determine if the ECDOT has been able to implement the dictates of the EEA. It aims to look at ways in which the EEA can best be implemented in order to ensure that the desired results are achieved. This study was prompted by the fact that the ECDOT has not managed to reach the EEA targets in hiring people with disabilities (PDWs) and elevating women to senior positions. The study explored the views of the employees of the Department regarding the implementation of EE. It was conducted using the quantitative approach. 90 employees were asked to respond to a structured questionnaire designed by the researcher. The findings of the study indicate that although in some areas the Department has been able to successfully implement EE, issues of racial equity, diversity, infrastructure conducive for people with disabilities, recruitment practices, and management commitment still need to be improved on. The study recommends, amongst others, that managers should provide leadership in the implementation process, more recruitment sources should be explored, suitable infrastructure must be provided, diversity issues must be addressed through workshops and training sessions, employee participation needs to be ensured, and that feedback must always be provided to EE beneficiaries in order to keep make sure they remain within the organisation and continue to improve.
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Fudo, Zintle. „Synthesis, characterization and photophysical studies of RU(II)bipyridyl-dithiocarbamate complexes as sensitizers for dye sensitized solar cells“. Thesis, University of Fort Hare, 2018. http://hdl.handle.net/10353/6168.

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The depletion of fossil fuels and the increasing energy demand for energy has led to the search for better and improved technologies with special focus renewable energy, especially solar cells. The first generation solar cells based on silicon are expensive, hence dye sensitized solar cells come in as a better alternative as these solar cells are environmental friendly, they have moderately good conversion efficiency and they are relatively cheap to produce. Dithiocarbamate ligands have been widely used in many research fields, as these are versatile ligands. Coordination of dithiocarbamates with metals such as ruthenium has produced high conversion efficiency and have the ability to extend the MLCT absorptions, and this can further extend their wavelength. In this study five dithiocarbamate sodium salt ligands were prepared and were coded as FL1= Aniline, FL2= p- toluidine, FL3= p- anisidine, FL4=dibenzyl, FL5=diphenyl. These ligands were used to synthesize Ru(II) metal complexes which were formulated as [Ru(FLx)(dcbpy)(NCS)] and [Ru(FLx)2(dcbpy)] where FLx is the dithiocarbamate ligand and dcbpy is 2,2-bipyridine-4,4’-dicarboxylic acid and the complexes were coded as FCx. The synthesized compounds were characterized using techniques such as the melting point, molar conductivity, FT-IR and NMR spectroscopy. For spectroelectrochemical studies of the metal complexes, techniques such as UV-Vis and photoluminescence spectroscopy were carried out. Furthermore, redox properties of the complexes were analyzed using cyclic and square wave voltammetry. The FT-IR displayed all the expected peaks of interest both in the dithiocarbamate ligands and in the metal complexes. The electronic spectra confirmed the successful coordination of ligand to the metal centre, the electronic spectra of the complexes also confirmed the six coordinate octahedral geometry of the complexes. The complexes exhibited some photoluminescence properties that are suitable for dye sensitization. The cyclic voltammogram of the complexes displayed more reduction potentials that could be attributed to the π-conjugation in the ligands incorporated during synthesis. The square wave voltammogram of the complexes is in agreement with the results obtained in cyclic voltammetry.
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Kagoro, Kisemiire Christine. „Evaluation of the development and use of the institutional repository by staff and students at the University of Fort Hare in Eastern Cape, South Africa“. Thesis, University of Fort Hare, 2018. http://hdl.handle.net/10353/6292.

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This study sought to evaluate the development and use of Institutional Repository by staff and students at the University of Fort Hare (UFH) in Eastern Cape, South Africa. In this study, staff comprised of academic staff (lecturers) and library staff. The aim of this study was to investigate the development and use of Institutional Repository at UFH. To achieve the objectives, both qualitative and quantitative research methodologies were employed. Data was collected through questionnaires and face-to-face interviews. Purposive sampling technique was used to select the participants of the study. Qualitative data was analysed thematically while, quantitative data was analysed statically by help of SPSS software. The results showed that: library staff and management are aware and provide support for the development and use of the Institutional Repository at the UFH; awareness level of IR among lecturers and students is still low; the infrastructure available for the use of IR is not well developed; and lastly, library users which consist of students and academic staff face various barriers in the use and support of IR development. The study recommended for dynamic training, and marketing of IR through seminars and workshops should be started by expert affiliations and universities administration to advance the idea of IR among the University community. Low levels of awareness of the university repository, funding and shortage of library staff remains an issue and could be addressed by further investigating the effectiveness of different communication channels. It is pertinent that the findings of this study would be useful in various tertiary’s institutions of higher learning across the globe in order to embark on IR.
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Reid, Lindsay Frederick. „The use of radio frequency identification technology for inventory control in academic libraries in South Africa : a study of the University of South Africa and the University of Fort Hare Library Systems“. Thesis, University of Fort Hare, 2018. http://hdl.handle.net/10353/6314.

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The study sought to investigate the use of RFID technology as inventory control in academic libraries in South Africa, with a focus on the University of South Africa and the University of Fort Hare libraries. The objectives of the study were to describe the current inventory control practices at the libraries of the University of South Africa and the University of Fort Hare in order to determine the infrastructure required for the use of RFID for inventory control for the University of Fort Hare’s libraries; to evaluate the benefits of RFID technologies, in order to gain a competitive advantage for the University of South Africa’s and the University of Fort Hare’s libraries; to identify the challenges associated with adopting RFID technology, as experienced by the libraries of the University of South Africa and the University of Fort Hare. The study adopted both the quantitative and qualitative research approaches. The researcher followed a rigorous methodological path that began with a thorough literature review coupled with the careful and thoughtful posing of research questions and objectives. A purposive sample of forty (40) respondents was selected from the library staff from both the University of South Africa and University of Fort Harelibraries. The collected data were analysed using the Statistical Package for Social Sciences 23 (SPSS 23) and Microsoft Excel 2010. The findings of the study revealed reasons for both academic libraries to invest in RFID technology; these reasons include RFID’s ability to deliver self-service options, inventory control, improved reader access and improved security. The challenges related to the implementation of RFID technology are also related to staff not being rewarded by library management for being innovative; the difficulty of staff learning new technology; the staff’s inability to generate new ideas for the library; and the staff not being able to share knowledge with each other. Further research needs to be conducted by library RFID vendors in order to meet the need, of academic libraries, for RFID inventory control. RFID hardware and software (API software) should be subjected to further investigation for the purposes of research and development. Libraries should work closer with RFID vendors so as to trial and test hardware and software.
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Palmer, Hanli. „Normative indicators for grade 3 and grade 7 isiXhosa-speaking children on the Bender Visual-Motor Gestalt Test (Second Edition)“. Thesis, University of Fort Hare, 2016. http://hdl.handle.net/10353/6346.

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Selecting appropriate normative data for the purpose of evaluating psychometric test scores forms an integral part of the interpretative psychological assessment process. This highlights the well-known problem of utilising measures developed in the United Kingdom (UK), or the United States (US) and accepting their norms unreservedly for the practice on local populations, which questions the tests’ validity and reliability. The current study, which aimed to collect normative indicators on the Bender Gestalt Test (Second Edition), forms part of the continuing effort to develop norms for psychological tests in South Africa, and to focus on the valid and reliable use of measures within the context of South Africa’s multicultural and multilingual population groups. The participants of the research were Black isiXhosa-speaking Grade 3 and Grade 7 learners aged 8 to 9 years (N = 38 ), and 12 to 13 years (N = 23), obtaining their school education in the disadvantaged educational setting of the former Department of Education and Training (ex-DET) schools. The tests were scored according to the Bender Gestalt Test (Second Edition) manual, using the Global Scoring System. Thereafter, the raw scores were converted to Standard Scores, T-scores and Percentile Ranks using the US normative tables, according to chronological age categories. When the two groups were compared to the US norms, the results equated favourably for the present study sample. There were no significant findings in relation to the classroom size or any difference in performance between the schools who participated. The only significant difference revealed between male and female participants was with the Grade 7 sample group, where the males scored significantly lower than females on the Recall phase. These results support the prospect of the continuous revision of norms, and it is suggesting that the cognitive processes measured by this test are likely to derive from robust neurological substrates that are relatively stable across cultural groups.
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Chipendo, Claudio. „Towards a changing context and performance practice of mbira dzavadzimu music in Zimbabwe“. Thesis, University of Fort Hare, 2015. http://hdl.handle.net/10353/6357.

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Mbira dzavadzimu music and performance practice has been in existence since the pre-colonial era. It played a crucial role in ritual and non-ritual activities of the Shona people of Zimbabwe. However, political, social and global influences as well as technological advancement have resulted in change of context and performance practice. Unfortunately, these have not been recorded for future generations. The major aim of the study is therefore to examine the change of context and performance practice of mbira dzavadzimu in Zimbabwe. This was achieved by reviewing mbira dzavadzimu music and performance practice within the modern setting of dandaro. I looked at change from a theoretical lens of the theory of diffusion, syncretism and mediatisation. The study was in the qualitative form superimposed on some case studies. Unstructured interviews, participant and non-participant observations were the main instruments used to collect data from both traditional and modern mbira performances. Data was also collected from museums, archives, radio and television stations. The study established that the changes in context and performance practice of mbira dzavadzimu in Zimbabwe were to a larger extent due to foreign influences such as colonialism, the coming of missionaries, modernisation, urbanisation, commercialisation, mediatisation, the use of modern technology and institutionalisation. Due to the aforementioned influences, the environmental settings, the change of context from sacred to secular, the relationship with ancestral spirits, musical practices, performance situations and quality of sound, have been modified and adjusted in response to the influences of the globalised world’s ever changing audience and performance space. In short, this has resulted in a shift of mbira performances from its traditional to modern settings, from the village to the city and onto the international scene with a new performer-audience setting. Various innovations were carried out on the instrument and its music as a result of the advent of modern technology. The use of microphones, modern amplification systems, recording studios, radio and television broadcast, audio and video cassettes, CDs, DVD, teaching of the instrument using audio and video instructional models and the use of internet sites in learning how to play mbira dzavadzimu and other instruments have become a reality. It has been evident from the study that urban and rural areas take up change in different ways and that in the former change is more pronounced than in the latter. Urban area communities are more “developed” than their rural counterparts because the former are more exposed to technological influences and the commercialisation of music. The study has also established that Zimbabwean mbira music is a good example of modern transculturality. The instrument and its music have played a major role in breaking down cultural boundaries and bringing the people of the world together for purposes of performing on the instrument. From the findings of this study, I attribute most of the changes to technologisation, for most of the changes that have taken place on mbira dzavadzimu were a result of the highly technologised way of life Zimbabweans now lead.
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Morahanye, Mokhantso Lilian. „Investigating adaptation strategies to climate change by smallholder farmers : evidence from, Lesotho“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5807.

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In Lesotho, agriculture is the dominant activity and involves crop and livestock production, range management and forestry activities. The current climatic variability in the country has caused decline in food production as result of increased dry spells, frequency of droughts and erratic rainfall. These climatic events are expected to have a significant impact on the livelihoods of the smallholder farmers. In combatting the harmful effects of climate change, smallholder farmers in Lesotho have employed various adaptation strategies based on their local knowledge and limited means. While these strategies may not be optimal they obviously constitute the basis for potentially effective improved technologies which can be developed and communicated through an efficient extension system, hence the need to precisely identify them and understand the factors that affect their choice. The main objective of this study was therefore, to identify the adaptation strategies and investigate the factors influencing smallholder farmers’ choice of those adaptation strategies. The study made use of multi-stage stratified sampling technique to select 160 respondents across four agro-ecological zones (lowlands, highlands, foothills and Senqu River Valley) in Leribe and Mohales’Hoek districts of Lesotho. Primary data for the study were collected using semi - structured questionnaire assisted with interview schedules administered on the respondents. Data collected were analysed using descriptive statistics and the multinomial logistics regression model. The results show that there are more males than females, majority of the respondents’ attained primary education, and older people dominate the smallholder farming system. The adaptation strategies used in MNL model were soil and water management, crop management and livestock management. The results further revealed that soil and water management strategies were the most adopted climate change strategies amongst smallholder farmers. It is understood that marital status, age and gender, income, land tenure, crop grown, extension services, and agro-ecological zones are the determinant factors influencing the choice of the adaptation strategies. This study concludes by recommending that smallholder farmers should be sensitised about climate change and both government and non-government organisations working on climate change related issues should direct their attention to rural communities to ensure effective response to climate change.
21

Yahaya, Abdulrazaq. „Spatial and seasonal distribution of selected persistent organic pollutants and phenolic derivatives along the course of the Buffalo River in the Eastern Cape Province of South Africa“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5939.

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Persistent organic pollutants (POPs) fall under a group of synthetic chemicals known for their persistence in environmental matrices such as soil and water, and are used in industrial, domestic and agricultural applications. Because of their volatility and lipophilicity, POPs can be transported far away from their point sources and bio-accumulate in food and in fatty tissues of humans and animals. In view of their toxicity and carcinogenicity some organic pollutants such as polychlorinated biphenyl (PCBs), organochlorine pesticides (OCPs) and phenolic derivatives (chlorophenol and nitrophenol) have been classified by United State Environmental Protection Agency (USEPA) and World Health Organization (WHO) as priority pollutants. The present work evaluated the distribution patterns of 19 polychlorinated biphenyls congeners, 17 organochlorine pesticides and selected phenolic derivatives (USEPA 11-priority pollutants) in the Buffalo River, in the Eastern Cape Province, South Africa between December 2015 and May 2016. The Liquid-liquid extraction technique was used for PCBs, OCPs and phenolic derivatives in the river water samples. Silica gel and florisil clean up were carried out for PCBs and OCPs samples respectively and analyzed with gas chromatography electron capture detector (GC/ECD). Phenolic compounds were derivatized and analyzed by gas chromatography mass spectrometer (GC/MS). Limits of detection (LOD), limit of quantitation (LOQ) and relative standard deviation (RSD) for the PCBs were 10 to 330 ng/L, 20 to 1,060 ng/L and 1.18 to 14.1 percent respectively. The LOD, LOQ and RSD for the OCPs were from 20 - 60 ng/L, 110 - 530 ng/L and 0.02 - 0.06 percent, while the corresponding values for the phenolic derivatives were 10 to 70 ng/L, 33 to 222 ng/L and 1.99 - 10.86 percent. In summer, the concentrations of PCBs, OCPs and phenolic derivatives ranged from
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Besman, Shirley. „English first additional language writing competency among grade 12 learners : the case of two Eastern Cape rural public schools“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/6403.

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Contextualized in the South African Language in Education Policy (LiEP) and the Curriculum and Assessment Policy Statement (CAPS), the study aimed at investigating the writing competency of EFAL Grade 12 learners in the two rural public schools. It was the researchers‘ hunch that the learners‘ socio-cultural conditions at which they learn EFAL are not taken into consideration by teachers and that hampers or impedes the development of language and writing. Further, the research sought to unearth the strategies and techniques used by teachers to teach writing in EFAL, and whether these facilitate the development of writing competency, that enhances better performance in other Grade 12 subjects taught through English as a Language of Learning and Teaching (LoLT). The study is informed by the socio-cultural theory, language acquisition theories, and the language learning theories. The study also drew from the writing strategies, writing in the curriculum, and second language learning discourses Framed in the interpretive paradigm and the qualitative approach, the research adopted a case study design. The sample of the study comprised of seven teachers of which two were EFAL teachers and five of these teach content subjects. Twenty four Grade 12 learners constituted the four Focus Groups. The data collection tools comprised of interviews, Focus Group Discussions (FGDs), observation and document analysis. Learners wrote essays and free writing exercises which formed transcripts for document analysis. The purposively selected teachers and the Grade 12 learners were granted interview questions in advance. The collected data was analysed and put under themes as determined by the study‘s research questions. Such themes included; challenges faced by learners when writing in EFAL, strategies used by teachers in teaching writing , perceptions of teachers and learners on learners‘ writing competency and the connection or linkage between learners‘ writing competency in EFAL and content subjects. Learners‘essays and free writing revealed that the learners have limited vocabulary in their FAL. Furthermore, the study made known that learners experience anxiety when they have to answer questions in English and that results in them being incompetent in writing in the target language. Other hindrances to EFAL writing that were revealed by the study included the detrimental effect of social media on the writing competency and lack of motivation to read for writing in English. In addition, the study established that there were teaching approaches that were employed by teachers when teaching writing which included the process writing and integration. Content subject teachers made known to the study that they were not teaching writing to the learners but assess them in essay writing and summaries as required by the school-based assessments in their respective subjects. It was also disclosed in the study that writing encompasses other language skills especially reading. The study also revealed that writing is a skill that is obligatory to be taught because it becomes beneficial to other subjects and that it enhances learners‘ writing for a variety of reasons. Overall, the study made known that there are complex circumstances that Grade 12 learners in rural public schools encounter when engaging in writing in the EFAL. The study concluded that although English could be perceived as a dominant language, it is embedded with multiplicity of challenges in the rural secondary schools where it is used as a LoLT. Such hindrances mostly find expression when learners have to engage in writing activities and encompass; lack of motivation, anxiety, limited vocabulary and the influence of social networks. The study recommended that the EFAL policy makers should not use a blanket approach on how EFAL should be taught but consider the demographic situations of the various sections of South Africa. The study also recommended that code switching which is practiced in bilingual classrooms appears inevitable and therefore should be formalized.
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Soya, Nongesiba. „Perceptions of school stakeholders towards the use of English as a language of learning and teaching (LoLT) in grade 9 Social Sciences“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/6447.

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The dawn of democracy in South Africa led to the development of Language in Education Policy (LiEP) as one of the pieces of legislations that promote languages in schools where parents, learners, who have come of age may choose a language for instruction. LiEP, together with the Constitution of South Africa, promote equal value of all eleven official languages spoken in this country. The promotion of language policies clearly shows that language is the bedrock of the academic development of every child. Unfortunately, Spaull, Van der Berg, Wills, Gustafsson and Kotzè (2016) found that South African Foundation Phase learners lack the most basic skill needed for academic achievement, reading for meaning. Spaull et.al (2016) findings show that language problems start during the early years of schooling. This study aimed at finding out the perceptions of school stakeholders about the use of English as LoLT in Grade 9 Social Sciences, and it is located in the Interpretivist Paradigm. In this study, stakeholders are learners because they are central to learning, parents, as they have the responsibility of choosing LoLT for their children and assist them in their schooling career. Lastly, teachers are stakeholders because of their critical role of imparting knowledge and skills during classroom interaction. The researcher uses a Qualitative approach to identify data-collecting tools suitable for this research, and chooses semi-structured interviews and observations. Semi-structured interviews are flexible and allow deeper probing during the interview. The sample consists of nine Grade 9 learners, three teachers of Grade 9 Social Sciences and six parents from the School Governing Body (SGB). The aim of conducting observations was to find out the language used by learners and teachers during classroom interaction. This study found out that most participants prefer learning Social Sciences in English than in isiXhosa. They are aware of the challenges experienced in the classroom when learning in English but they still choose it. From the sample used, participants clearly indicate that learning in English causes some barriers in the learning and teaching process. However, it also became clear that the benefits associated with learning in English make it difficult to put it at the same level as other languages and participants do not link mother tongue to career opportunities. It is also evident that English will enjoy its hegemony until such time that all stakeholders in Education view the mother tongue as a foundation for learning other languages and as a resource as well so that they can use it in the classroom to understand the content. Policy developers must look deeply into the question of LoLT so that learners receive instruction in a language that will assist them in improved academic performance. Teachers must be equipped with adequate skills to assist learners in developing reading and comprehension skills in the classroom. There is a dire need to develop the culture of reading in rural school learners; and teachers must expose learners to a variety of English reading material.
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Lamana, Andile Robert. „An evaluation of the implementation of the South African Police Service Sector policing in the Eastern Cape“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5271.

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This study focussed on the evaluation of the implementation of the South African Police Service sector policing in the Eastern Cape province of South Africa. A mixed methods approach was used to gather, collect and analyse data for this study. The data were collected through semi-structured in-depth interviews, focus groups discussions and a survey. The quantitative approach dominated in data collection, whilst the qualitative approach was used to corroborate the quantitative findings. For the quantitative approach, 265 questionnaires were administered to 121 volunteer participants targeting the station commanders, cluster commanders and sector commanders. A hundred and forty questionnaires were also administered to the Sector Crime Forum chairpersons who were selected using simple random sampling from 32 police stations. The sector commanders were used for in depth interviews. The rationale behind was that the sector commanders are playing a key role in the implementation of sector policing. Simple random sampling was used to select the participants. The study area was in the Eastern Cape, where the research sample and participants were drawn. The findings of the study indicated that although sector policing minimum standards have been achieved by many stations, the study found out that there are some stations that have not yet attained the policy goals in terms of optimal implementation of sector policing in the Eastern Cape Province. The study established that the farm and rural and remote police stations were not complying with the minimum standards laid down in the National Instruction 3/2009. The problem of non-compliance emanates from the shortages of resources. Further findings on this study were based on the experiences and challenges of the implementers of sector policing. The study found that there were challenges confronted by them in the implementation process. Although some of the participants were indicating their enjoying working closely with their communities, there were some major challenges that they experienced in the process of executing their duties. The results of the study indicate that resources were not adequate to ensure that this new policing strategy is properly executed. Another important finding which was identified by the study was the fact that sector policing, as a new policing strategy, was not adequately communicated and marketed for it to be accepted and to for it to achieve the necessary buy in from stakeholders. The study further established that training, development and capacity building were lacking to capacitate the implementers of the new policing strategy. Further, sector to sector collaboration was identified as another challenge by the study. Team work was very much limited. The study further revealed that command and control was not enhanced by the sector commanders in their sectors. The sector patrol reports were not available in the files and AVL reports were also not retrieved and monitored. The factors highlighted above have a negative bearing on the reduction of crime. Poor police visibility and stakeholder participation in crime prevention programmes are not reducing crime.
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Mamera, Matthew. „Pollution potential of on-site dry sanitation systems associated with the Mzimvubu Water Project, Eastern Cape, South Africa“. Thesis, University of Fort Hare, 2018. http://hdl.handle.net/10353/6038.

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Protecting the environment requires tools that can be used to monitor environmental conditions for proper sustainable management of water resources. The Mzimvubu River is the largest undeveloped river, in the poorest region of South Africa. The South African government announced plans to construct two large storage dams (Ntabelanga and Laleni) in the Tsitsa River, one of the largest tributaries to the Mzimvubu River. The dams and associated infrastructure is termed the Mzimvubu Water Project (MWP). In developing countries like South Africa, several households use pit latrines. Moreover, many people also rely upon untreated groundwater supplies for their drinking water. The shared utilization of both pit latrines and groundwater resources, can lead to human and ecological health risks from microbial and chemical pollutants. These threats can be accelerated due to a permanent rise in the water table associated with dam constructions. Four hillslope sites with pit latrines (MT1, MT2, MT3 and MT4) above 1st order tributaries to the Tsitsa River, in the vicinity of the proposed MWP were chosen for this study. The soils were described and classified at selected locations below the pit latrine and above the tributary. Undisturbed core samples were from representative soil horizons on which hydraulic properties were determined in the laboratory. Samples were also collected to determine the feacal coliform and other bacterial concentrations during a winter and summer period. Mechanistic modelling with Hydrus 2D for a 121 day period was conducted to determine the risk of pollution to surface and groundwater from the various sites. Apedal soils of the Clovelly form dominated upper slopes of MT1 and the lower slopes of MT2. A Clovelly form is hydropedologically termed a recharge soil, as morphological indicators of saturation are absent. Hydromorphic soil properties were observed in the sub-surface B horizons of a Tukulu form in MT1-3 and MT4. High clay contents and strong structure soils of the Sepane form were dominant in MT3. The soils of MT1 and MT2 are relatively sandy with slightly higher hydraulic conductivities compared to MT3 and MT4. In general higher measured faecal coliform concentrations were higher in winter as compared to summer seasons but in most sites both winter and summer seasons had counts < 1 CFU/g. The highest concentrations of total bacteria (9 x 106 CFU/ g soil) was observed in MT3-1. Other sites with potential pollution include MT3-3, with a count above 4 x 104 CFU /g soil in winter and MT1-1 with a count above 2.2 X 104 CFU /g soil in summer. In most of the sites, the E. coli bacteria detections were low (< 1 CFU/g) during both seasons. The highest value in summer of 1.8 x 102 CFU/g was observed in MT3-3 which increased from 1.2 x102 CFU/g in winter. As the soil water flow rate increase the mobility of bacteria increase as well. Hydrus simulations showed that surface water resources are threatened by pollution from MT3 and MT4 due to the prominence of lateral flow. Groundwater pollution is more likely to occur on MT1 and MT2 as the soils are freely drained. Future work should focus on the more direct measurements and modelling of the migration of bacterial pollutants from pit latrines to various water resources.
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Ngozwana, Baselwa. „Leisure time and holiday aspirations of black upper middle class in East London“. Thesis, University of Fort Hare, 2016. http://hdl.handle.net/10353/6380.

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This study examined the holiday and leisure aspirations of the new upper black middle class in East London using qualitative approach. The study investigated aspirations of the black middle class on international travels through the lens of Veblen’s (2002) conspicuous consumption theory which entails that black middle class citizens spend in order to assert their status and belongingness to the middle class. The aim of the study was to understand their holiday and leisure aspirations, what the idea is behind or what motivates their international travels, their travel experiences and class affirmations. This exploration included the challenges and frustrations such as Ebola scare, racism, issues with foreign exchange and variations from these international visits. Data was collected through interviews with upper black middle class who are based in the Buffalo City Metro Municipality in East London, Eastern Cape. Findings from this study revealed that consumption patterns of the emerging black middle class to diverge substantially from the other groups, in terms of greater signalling of social status via visible consumption and preoccupation with reducing an historical asset deficit. Various themes emerged as meanings attached to international travelling and leisure by those black middle class international travellers. These are sense of wealth, status, religion, self-esteem, sense of reward, bonding with friends and conspicuous/visible consumption.
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Busayo, Emmanuel Tolulope. „Township spatial planning and climate change adaptation : a case of Mdantsane in Buffalo City Metropolitan Municipality“. Thesis, University of Fort Hare, 2018. http://hdl.handle.net/10353/6005.

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Spatial planning plays a significant role in enhancing climate change adaptation especially within an urban area. The alignment of spatial planning with climate change adaptation opens an opportunity to improve resilience in areas of high vulnerability and manage the unavoidable. This mini-dissertation examines township spatial planning and climate change adaptation in identifying potentialities for an integrated approach. Therefore, Mdantsane case study as one of the largest townships in South Africa was explored as a unique landscape with reminiscent of apartheid to improve the people’s climate change adaptation under urban poverty, lack of basic facilities and other environmental challenges. In keeping with a case study design, mixed methods were adopted in data collection and analysis making use of GIS and remote sensing techniques alongside pretested open and close-ended questionnaires. The study reveals that townships are extremely susceptible to the impacts of climate change due to their built-up and natural environment set up as well as the existing interrelations. Based on this study major findings, Mdantsane built up cover in year 1996 was 269.496 km2 followed by vegetation area of about 142.272 km2; the area covered by water body was 31.554 km2 while other land surface features cover about 317.277 km2. It was revealed that there was a drastic change in vegetation cover between 1996 and 2016, where built up cover area increased to 375.552 km2 and vegetation cover is 119.277 km2 while water body and other land features cover was about 29.889 and 235.881 km2 respectively. Furthermore, 66 percent of the respondents agreed that agriculture is the predominant land use activity been carried out in the study area, respondents at 74.4 percent affirmed that solid waste and sanitation problems are environmental issues which can lead to climate change over time as a result of the burning of garbage. It is worthy to note that 70 percent of the entire respondents have not participated in any spatial planning process in the past. Thus, comprehensive integration of spatial planning is essential for townships proofing, health, wellbeing and resilience. To this end, the five P’s model (Policy, Public participation, Programme implementation, Political will and Programme monitoring) integration was proposed to seek strategic intervention in sustaining adaptation of local residents to climate change in the future with specific focus to reduce climate and environmental risks in Mdantsane Township.
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Chingosho, Vimbai. „The use of conceptual costume design to express the emotional trajectory of the play sounds of South End“. Thesis, Nelson Mandela Metropolitan University, 2016. http://hdl.handle.net/10948/11449.

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The aim of this study is to illustrate how, in the design of costumes, adopting design elements used to produce conceptual fashion can create conceptual costumes that have the ability to express emotions. The play Sounds of South End (2013) contains such qualities; therefore it has been selected to illustrate how the mood and emotional trajectory of a play can be interpreted through symbolism. The play illustrates the life before and after the forced removals during the apartheid (1960s and 1970s), of a fictional family, the Dietrichs, who live in South End, a suburb in Port Elizabeth, South Africa. A focus on the nature of emotional changes experienced by the family has been used to determine the overall mood of the play, leading to a translation of the shifting mood through a collection of conceptual costumes. The final collection was exhibited as an installation artwork that is an interpretation of the altering moods and emotions that occur in the life of the Dietrich family as the play unfolds. The conceptual costumes have been constructed to imbue the narrative of the play with deep meaning by using symbolic elements, such as colour, texture and weight, to suggest the emotional trajectory within the play. The eight costumes portray the interrelated gradual decline and resultant deterioration of human relations experienced by the Dietrichs, from a contented state of harmonious living to a wounded state of despair.
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Makapela, Lubabalo. „Experience and realities of unemployed youth in Kieskammahoek, Eastern Cape“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5336.

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This study examines the experiences and realities of unemployed youths in Keiskammahoek, in the Eastern Cape Province, South Africa. It looks at the challenges are that experienced by unemployed youths in Keiskammahoek, an area which already has high volume of unemployment. It also explores the factors that account for unemployment amongst the youths in this area. The study adopted a qualitative research approach and the data was collected through semi-structured interviews and observations. Purposive sampling was utilised to collect data from 22 participants who included the rural youths, professionals and decision-makers. The findings of this study reveal that the majority of youths are unskilled and are not easily absorbed in different sectors of the economy. This study recommends that the government needs to target and maximize programmes that are supported by social and economic policies for young people’s benefit in order to alleviate the youth unemployment challenges.
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Peter, Bantu Desmond. „The impact of post-apartheid agricultural changes on citrus farmers in the Peddie area“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5380.

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This study explores the impact of post-apartheid agricultural changes on citrus farmers in the Peddie area. The case study focused on the Craighead Citrus Farm at Kwatho as well as the Naudeshoek Citrus Farm, Ripplemead Citrus Farm and Siyamila Citrus Farm in the Balteni area. The study considered the effect of agricultural changes on citrus production, productivity of the farms in question, as well as the impact on poverty alleviation in Peddie District. In the study, the challenges encountered by both farmers and communities due to the agricultural changes in the new democratic dispensation were also considered. The study further considered the role played by the Department of Agriculture and Ngqushwa Local Municipality in assisting these farmers to increase citrus production in order to create employment opportunities. To achieve these objectives, a review of literature and collection of evidence in the form of interviews, and observations were conducted in the research areas. The research findings indicated that the Craighead Citrus Farms is state owned land, which belonged to Ulimocor, a parastatal under the former homeland government (Ciskei). This farm is no longer operational and is abandoned. During the period of this study the Naudeshoek Citrus Farm, Ripplemead Citrus Farm and Siyamila Citrus Farm were operational and progressing. Citrus farming in this area has potential to boost the economy, which would only be possible with the establishment of partnerships between the emerging farmers, government, commercial farmers and Ngqushwa Local Municipality.
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Adams, Luvo. „A discourse analysis of the construction of gendered relationships in grade 10-12 Life Orientation textbooks in the Eastern Cape“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5532.

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School-based sexuality education has been the subject of research in the social sciences and pedagogical spheres globally. In South Africa, growing interest among social scientists in the topic, were ignited by the introduction of sexuality education as a compulsory part of Life Orientation (LO) by the late 1990s. However, the implementation of LO has been problematic. Reviewed literature in the current study, reveals how the dominance of the heterosex discourse is foregrounded in LO content on gender and sexuality. The current study was aimed at examining the construction of gendered relationships in LO textbooks. The study sampled LO textbooks for Grades 10-12, learners in these grades are between the mean ages 16-18 years. This group is the target group, because they are legally afforded the right to consent to sexual activity with peers, within the same age bracket. Conducted from a social constructionist perspective, the current study employed qualitative methods of inquiry (textual analysis). Against the backdrop of heterosexuality as norm, it was the aim of the current study to understand the subject positions made available for female learners to construct themselves, within the discursive spaces in LO content. Findings suggest that two discourses namely: the heterosex discourse and the discourse of danger and disease, dominate in LO content on gender and sexuality. This leads to the construction of gendered relationships a s inherently heterosexual, leading to the marginalisation of relationships that fall outside of the norm. The female learner is positioned as a passive-victim, incapable of exercising sexual agency, while young men are positioned as inherently more powerful members of the intimate relationships or dangerous sexual predators. In the discourse of danger and disease, she is also positioned as a potential victim but the focus is on equipping her with skills, in a way which positioned her as an active-resistor in refusing sexual activity; and being in control of decision-making on issues of safety in relationships. The implications of these contradictions, is that they focus on the individual and disallow her taking up of sexual agency, and disregard the context in which she has to do so.
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Mgidi, Siphelele. „Relevance of the family assessment for least developed countries (FALDC) assessment tool rendering child protection services in the Eastern Cape, South Africa“. Thesis, University of Fort Hare, 2016. http://hdl.handle.net/10353/6335.

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Assessment tools have been used for various purposes, including for protecting children from maltreatment. The main aim of this study was to to evaluate and determine the relevance of the Family Assessment for Leased Developed Countries (FALDC) assessment tool for child protection services in the Eastern Cape Province. The research was conducted using the social developmental welfare approach (Patel, 2005) and ecological systems theory (Healy, 2005). The study made use of the qualitative research method; in doing so the study made use of the case study design. In using the qualitative research method, focus group discussions were conducted with 29 social workers involved in child protection services. The findings of the study indicated that the FALDC assessment tool provides information useful for child protection services even though it contains sections that are regarded as less relevant to child protection. The study also founded that the FALDC assessment tool is relevant to child protection in the South African context, yet it needs to be aligned so that it provides much of the information desired by those involved in child protection. A conclusion drawn from this study is that the FALDC assessment tool appears to be relevant for child protection services. The FALDC assessment tool needs to be adjusted taking into consideration other aspects important to child protection in the South African child protection context.
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Ntozini, Anathi. „Psychological well-being of institutionalised and non-institutionalised isiXhosa and English ethnic speaking elderly south African residing within the Buffalo City area“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/6368.

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Background: International research has clearly indicated that the world’s population is ageing: almost all countries in the world are experiencing a significant growth in the proportion of older persons in their population. This is also true for developing countries such as South Africa that are beginning to show signs and symptoms of an ageing population. Among Southern African Development Communities (SADC), South Africa has the highest number of ‘senior citizens’. Population reports indicate that the population of old people rose from paltry 2.8 million in 1996 to more than 4 million in 2011 and this is expected to skyrocket to seven million by 2030. In spite of the increasing number of senior citizens in socio-structural landscapes in South Africa, there is still lack of adequate, workable and effective policy frameworks for the wellbeing of the elderly. There is also paucity of psychological data of the elderly, especially along racial divides to determine whether the after-effects of apartheid still hold sway or not in post-apartheid South Africa. This study was conceived to investigate the psychological well-being of the elderly in Buffalo City, Eastern Cape, South Africa between two racial-ethnic elderly groups. The specific objectives of the study were to explore the relationship between the socio-demographic characteristics and psychological well-being of the black (Xhosa) and white (English) elderly in Buffalo City, South Africa and second, to validate the relationship between psychological well-being and physical activity, loneliness, spirituality/religiosity as well as ageism among the sampled population. The set-point theory, selective optimisation compensation theory (SOCT) as well as the continuity theory were employed to guide the conduct of the study. Method: Psychological measuring instruments were deployed to collect data for the study from a total of 301 elderly respondents in retirement and private individual homes (191 isiXhosa and 110 English speaking elderly). Both simple random sampling (SRS) and purposive sampling procedures were used to select the respondents. The measuring instruments included the Ryff Scales of Psychological Well-being (RSPWB), Physical Activity Scale for the Elderly (PASE), Assessment of Spiritual and Religious Sentiments Scale (ASPIRES), University of California at Los Angeles (UCLA) Loneliness Scale, the Palmore Ageism Survey scale and a biographical questionnaire. Data was analysed using MANOVA, One-way variance analysis and regression coefficient. The racial differences logically influenced the selection of the respondents for the study. Results: The study revealed a significant statistical relationship between physical activity (PA) and psychological well-being of the elderly, regardless of the sociodemographic variables. PA showed a significant relationship with psychological wellbeing of the elderly. The study also discovered that loneliness correlates significantly with all four of the psychological well-being scales. It shows that the higher the levels of loneliness experienced by the elderly, socio-demographic variables controlled, the lower the levels of psychological well-being in terms of autonomy, environmental mastery, purpose in life, and self-acceptance. However, with the exception of the relationship between loneliness and purpose in life, ethnic affiliation moderates autonomy, environmental mastery and self-acceptance. English elderly constantly experienced higher levels of autonomy than the isiXhosa elderly do with an increase in loneliness. The study also found a positive relationship between ageism and psychological well- being. However, with low levels of ageism, the English elderly, in comparison with the isiXhosa elderly, is likely to show higher levels of autonomy. In addition, a significant statistical relationship between ageism and environmental mastery and purpose in life was found among the isiXhosa elderly. Although, with an increase in ageism, there is a slight increase in autonomy in both groups, the English elderly throughout showed higher levels of autonomy than the isiXhosa elderly showed. The study found a positive relationship between religiosity/spirituality and psychological well-being of the elderly. However, race could moderate the relationship between prayer fulfillment and psychological well-being at all four levels (autonomy, environmental mastery, purpose in life, and self-acceptance). With an increase in prayer fulfillment, the autonomy of the English elderly increases fairly quickly, while the autonomy of the isiXhosa elderly decreases slightly. Comparatively, the study found that isiXhosa elderly reported lower levels of psychological well-being than the English elderly. Conclusion/Recommendation: The study concludes that there is the need to develop a solid national data bases on needs and use of services, and process of ageing in order to access research data to assist planning, dissemination, delivery and evaluation of effective service delivery for the elderly population in South Africa, especially along racial divides.
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Rumsha, Siphamandla. „Agricultural urbanism and urban agriculture : exploring the possible role of University of Fort Hare and Buffalo City Municipality in supporting small-scale urban farming in East London, South Africa“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5072.

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This study investigates the impact of urban agriculture in the city of East London as well as the possibility of adopting agricultural urbanism as an urban farming model to bolster food security. The study goes further to understand the role that could be played by University of Fort Hare and Buffalo City Metropolitan Municipality in capacitating small scale urban farmers in the city of East London. Unemployment and food insecurity are the key challenges that are affecting many families in South Africa, including urban dwellers. The main objective of this study therefore is to investigate the contributions of urban farming in securing food security and livelihoods in East London. This study adopted a mixed methods research approach, where both quantitative and qualitative methods were used to harvest data. Statistical analysis (descriptive) was then used to analyse quantitative data. Thematic approach used to analyse qualitative data. The study shows that urban farming plays an important role in the livelihoods of urban dwellers. However, the sector still faces various challenges such as lack of recognition by authorities. The study also revealed that the city of East London has potential to establish agricultural urbanism as it has most of the essential aspects that are necessary to establish it. The study recommends strengthening of the partnership between University of Fort Hare, Buffalo City Metropolitan Municipality and small scale urban farmers in East London.
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Pikirai, Kelvin Tinashe. „Eco-tourism and sustainable rural livelihoods in Hogsback, Eastern Cape, South Africa“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5510.

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This study investigates the livelihoods impacts of eco-tourism in Hogsback, the extent to which local community members are effectively participating in eco-tourism activities as well as the negative implications of ecotourism in Hogsback. A qualitative research methodology was employed in order to have a deeper understanding of the issues under study. Simple random sampling and purposive sampling techniques were used to select respondents. In-depth semi structured interviews were used to collect data from 40 respondents and 6 key informants. The study established that eco-tourism activities help mainly individuals rather than the whole community at large and those who benefit; it improves their lives as well as benefiting the economy of the country. This study also found out that the government plays a role to promote development of ecotourism in the community, this is through infrastructure development and providing services for tourism. Lastly the study found out that there are conflicts over ownership of eco-tourism activities, limited funds in promotion of eco-tourism activities and that there is no eco-tourism development strategy. The study recommends that the government of South Africa should design and implement a comprehensive eco-tourism development strategy that puts people at the core.
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Mawokomayi, Betina. „Assessing the role of the community radio stations in facilitating development : a case study of Forte FM in the Eastern Cape Province“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5462.

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Community radio stations play an important role in the development of their communities. Forte FM is a community radio station located at University of Fort Hare Alice campus and was established to facilitate development in communities within the Amathole district municipality. Alice, a small rural town under Raymond Mhlaba Municipality, is one of the communities under the coverage of Forte FM. This study assessed the role that Forte FM plays in facilitating the development of Alice community. The study adopted a mixed method design in which questionnaires and interviews were used to collect primary data. The study findings show that although Forte FM is faced with serious financial challenges, it contributes to the development of Alice in various ways which includes providing the community with agricultural information, health information, promoting local culture, equipping the community with skills, promote local artists and sports personnel and educational programmes. The findings also revealed that the community is involved in the management of some aspects of the station’s operations through a board which is elected annually by the community itself. The results indicate that the radio station involve some community members in programming as experts on some topics or as people who have experienced an ordeal so they could share their experiences and advice other people how to manage similar situations. However, there is need to involve the community in the whole production process. The respondents’ attributed poor levels of community participation in programming to insufficient funds. The study recommends that Forte FM should lobby members of the community to fund the production of programmes since the station belongs to the community. This will enhance the sense of community ownership towards the radio station.
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Baker, William. „Controlled Vocabularies in the Digital Age: Are They Still Relevant?“ Thesis, University of North Texas, 2017. https://digital.library.unt.edu/ark:/67531/metadc1011802/.

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Keyword searching and controlled vocabularies such as Library of Congress subject headings (LCSH) proved to work well together in automated technologies and the two systems have been considered complimentary. When the Internet burst onto the information landscape, users embraced the simplicity of keyword searching of this resource while researchers and scholars seemed unable to agree on how best to make use of controlled vocabularies in this huge database. This research looked at a controlled vocabulary, LCSH, in the context of keyword searching of a full text database. The Internet and probably its most used search engine, Google, seemed to have set a standard that users have embraced: a keyword-searchable single search box on an uncluttered web page. Libraries have even introduced federated single search boxes to their web pages, another testimony to the influence of Google. UNT's Thesis and Dissertation digital database was used to compile quantitative data with the results input into an EXCEL spreadsheet. Both Library of Congress subject headings (LCSH) and author-assigned keywords were analyzed within selected dissertations and both systems were compared. When the LCSH terms from the dissertations were quantified, the results showed that from a total of 788 words contained in the 207 LCSH terms assigned to 70 dissertations, 246 of 31% did not appear in the title or abstract while only 8, or about 1% from the total of 788, did not appear in the full text. When the author-assigned keywords were quantified, the results showed that from a total of 552 words from304 author-assigned keywords in 86 dissertations, 50 or 9% did not appear in the title or abstract while only one word from the total of 552 or .18% did not appear in the full text. Qualitatively, the LCSH terms showed a hierarchical construction that was clearly designed for a print card catalog, seemingly unnecessary in a random access digital environment. While author-assigned keywords were important words and phrases, these words and phrases often appeared in the title, metadata, and full text of the dissertation, making them seemingly unnecessary in a keyword search environment as they added no additional access points. Authors cited in this research have tended to agree that controlled vocabularies such as LCSH are complicated to develop and implement and expensive to maintain. Most researchers have also tended to agree that LCSH needs to be simplified for large, full text databases such as the Internet. Some of the researchers have also called for some form of automation that seamlessly links LCSH to subject terms in a keyword search. This research tends to confirm that LCSH could benefit from simplification as well as automation and offers some suggestions for improvements in both areas.
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Sibanda, Phaxenda Maxwell. „Informal urbanism : an appraisal of socio-legal and economic dynamics in East London, South Africa“. Thesis, University of Fort Hare, 2017. http://hdl.handle.net/10353/5763.

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Many cities and towns in the Global South continue to experience the growth of the informal sector. There are a number of reasons which explain the growth of the informal sector. These include formal sector retrenchments, shortage of jobs in the formal sector and lack of skills. Street vendors are the most visible traders in the informal sector as compared to other kind of traders. In many cities, the spaces in which vendors conduct their trading is not allocated to them legally as they are seen as a nuisance or obstruction to commerce and the free flow of traffic. Against this background, this study examines the contestation for vending in the East London Central Business District (CBD) Eastern Cape, South Africa. It specifically explores social processes and vendor decision making when it comes to choosing (or claiming) a particular vending space, the legal instruments (by-laws) that either promote or constrain informal trading activities. Furthermore, it investigates the extent to which street vending contributes to the traders‟ income generation and sustainable livelihoods. This study uses a qualitative research design. Purposive sampling was used to select thirty informal traders. In-depth semi structured interviews were conducted with all thirty respondents In addition to the thirty respondents, five key informants were interviewed. The study found that street vending plays a major role in providing BCMM people with livelihood opportunities. Trading space in the CBD is strictly competitive and the spaces they acquire are too small for their businesses to expand to another level. Vendors face a lot of challenges but at the epitome of their challenges is the vending by- laws which the vendors view as a major constraint when it comes to operating smoothly in the streets. The study suggested that vending polices and by- laws be reviewed in order to derive a better socio- economic and functional environment for vendors.
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Oza, Tejas. „LCS Capable GSM Network“. Thesis, Uppsala universitet, Institutionen för informationsteknologi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-256061.

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This thesis is about Location Based Services which intends to acquire the location of the mobile phone. The goal of our thesis project is to extend the Mobile Switching Centre and Base Station Controller with location based support which is a part of the Global System for Mobile Communications that follows the 3rd Generation Partnership Project standards and integrate with the Mobile Arts Home Location Register, Gateway Mobile Location Centre and Serving Mobile Location Centre. To achieve this goal the prototype of LCS capable GSM network will be implemented using the functional programming language Erlang/OTP and C programming language. Further for testing and verification, tests will be performed until in the final result the location of mobile phone is obtained.
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Dahlberg, Erik, und Weronica Fohlén. „Hållbarhetsutvärdering - LCSA Analys : av trucksystem inom intern materialhantering“. Thesis, Högskolan i Skövde, Institutionen för handel och företagande, 2018. http://urn.kb.se/resolve?urn=urn:nbn:se:his:diva-15175.

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Allt fler organisationer väljer att jobba med hållbar utveckling, på grund av att det kan ses som en konkurrenskraft. Att arbeta med hållbar utveckling kan innefatta att utföra hållbarhetsutvärderingar, vilket kan göras genom metoden LCSA analys. Syftet med det här arbetet är att utvärdera och analysera ett producerande företags nuvarande klimatpåverkan sett till koldioxidekvivalentutsläpp från intern materialhantering som sker med dieseltruckar. Vidare syftar även arbetet till att visa hur en hållbarhetsutvärdering kan utföras för att påvisa ekologisk, ekonomisk samt social påverkan. I arbetet utförs en hållbarhetsutvärdering av trucksystem, för att identifiera det teoretiskt bästa alternativet, i jämförelse med ett fallföretags nuläge. Den metod som används för hållbarhetsutvärderingen är LCSA analys. Utöver resultatet från hållbarhetsutvärderingen tas även hänsyn till gränssnittet mellan teoretiskt och praktiskt bästa trucksystemalternativ.  Fallföretaget Volvo GTO i Skövde, har i dagsläget 18 dieseldrivna motviktstruckar, vilka har olika kapacitet och varierande arbetsuppgifter. Det nuvarande drivmedlet för samtliga truckar är Diesel Mk1. Fallföretagets flöden i dagsläget ställer generellt höga krav på truckarnas tekniska kapacitet gällande exempelvis åkhastighet, körning i uppförslutning, dragkraft samt lyft- och sänkhastighet. De 18 dieseltruckarna bidrog under år 2017 med ett klimatpåverkande utsläpp om cirka 237 ton koldioxidekvivalenter, sett till hela livscykeln för Diesel Mk1 samt truckflottans totala drifttider.  Gällande hållbarhetsutvärderingen LCSA analys, utförs den på trucksystem drivna av Diesel Mk1, HVO-Diesel, blybatterier samt litiumjonbatterier inom kapaciteterna 3,5, 5 och 8 ton. Analysen tar hänsyn till de tre pelarna inom hållbar utveckling.  Vidare tas hänsyn till trucksystemens tekniska specifikationer, vilket jämförs mot den nuvarande dieseltruckflottan. Generellt kan en lägre teknisk prestanda ses hos de eldrivna trucksystemen, vilket kan påverka möjligheten att implementera de hos fallföretaget. Teoretiskt lägst ekologisk och social påverkan kan ses hos de litiumjonbatteridrivna trucksystemen, lägst påverkan inom den ekonomiska pelaren har blybatteridrift. Ställt mot fallföretagets nuvarande flöden och behov, rekommenderar författarna HVO-Dieseldrivna trucksystem, då de har samma tekniska kapacitet samt lägre ekologisk och social påverkan. Avgränsningar har gjorts för analyserna i rapporten, gällande processgränser och påverkande faktorer. För framtida hållbarhetsutvärderingar rekommenderar författarna att större processgränser och fler påverkande faktorer tas hänsyn till, för att identifiera samtlig påverkan inom pelarna. I rapporten återfinns exempel på påverkan utanför valda processgränser, såsom utsläpp som påverkar över tid och exploatering. Under arbetets gång har informationsgap uppmärksammats inom olika områden. När det gäller forskning kring hållbarhetsutvärderingar saknas beprövade metoder. Därför efterfrågas enklare analysmetoder inom hållbar utveckling. Gap i forskning angående truckteori är något som också uppmärksammats.
The amount of organizations that choose to work with sustainability is increasing due to the potential competitiveness it causes. Working with sustainability may include sustainability evaluations, which can be done through the LCSA analysis method. The purpose of this report is to evaluate and analyze a manufacturing company's current climate impact due to carbon dioxide equivalent emissions from diesel-powered forklifts within internal material handling. Further, the report aims to illustrate how a sustainability evaluation can be conducted to identify ecological, economic and social impact. In the report, a sustainability evaluation of forklift systems is performed to identify the theoretically best alternative, compared to a case company's current situation. The method used for the sustainability evaluation is LCSA analysis. In addition to the results of the sustainability evaluation, the interface between theoretically and practically best forklift system alternatives is considered.  The case company Volvo GTO in Skövde, currently have 18 diesel-powered forklifts, which have different capacities and functions. The current fuel for all forklifts is Diesel Mk1. The flows today generally set high demands on the forklifts technical capacity, for example on, travel speed, climbing ability, traction force and lifting and lowering speed. In the year 2017, the 18 diesel-powered forklifts contributed with a climate impact of approximately 237 tonnes of carbon dioxide equivalents, considering the entire life cycle of Diesel Mk1 and the forklift fleets total run time.  Regarding the sustainability evaluation LCSA analysis, it is performed on forklift systems powered by Diesel Mk1, HVO-Diesel, lead acid batteries and lithium-ion batteries within the capacities 3.5, 5 and 8-tonne. The analysis considers the three pillars of sustainability. Further, the technical specifications of the forklift systems are considered and compared with the current diesel-powered fleet. Generally, a lower technical capacity can be seen in the electric forklift systems, which may affect the ability to implement those at the case company. Theoretically lowest ecological and social impact can be seen within the lithium-ion battery-powered forklift systems, the lowest impact on the economic pillar is seen in the lead acid battery systems. Based on the case company's current flows and demands, the authors recommend HVO-Diesel-powered forklift systems, as they have the same technical capabilities as well as lower ecological and social impacts. Limitations has been set for the reports analyzes, regarding process boundaries and impact indicators. For future sustainability evaluations, the authors recommend that wider process boundaries and more impact indicators are applied to identify the total impact within the pillars of sustainability. The report comprehends examples of impact beyond selected process boundaries, such as emissions affecting over time or exploitation. During the progress of this report, information gaps have been discovered in different areas. Regarding research of sustainability evaluations, proven methods are lacking. Therefore, established methods for evaluation are desired. A gap in research of forklift theory has also been noted.
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Douangaphaivong, Thaveephone NMN. „Littoral Combat Ship (LCS) manpower requirements analysis“. Thesis, Monterey California. Naval Postgraduate School, 2004. http://hdl.handle.net/10945/1272.

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The Littoral Combat Ship's (LCS) minimally manned core crew goal is 15 to 50 manpower requirements and the threshold, for both core and mission-package crews, is 75 to 110. This dramatically smaller crew size will require more than current technologies and past lessons learned from reduced manning initiatives. Its feasibility depends upon changes in policy and operations, leveraging of future technologies and increased Workload Transfer from sea to shore along with an increased acceptance of risk. A manpower requirements analysis yielded a large baseline (200) requirement to support a notional LCS configuration. Combining the common systems from the General Dynamics and Lockheed Martin designs with other assumed equipments (i.e. the combined diesel and gas turbine (CODAG) engineering plant) produce the notional LCS configuration used as the manpower requirements basis. The baseline requirement was reduced through the compounded effect of manpower savings from Smart Ship and OME and suggested paradigm shifts. A Battle Bill was then created to support the notional LCS during Conditions of Readiness I and III. An efficient force deployment regime was adopted to reduce the overall LCS class manpower requirement. The efficiency gained enables the LCS force to "flex" and satisfy deployment requirements with 25% to 30% fewer manpower requirements over the "one-forone" crewing concept. costs $60K.
Lieutenant, United States Navy
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Douangaphaivong, Thaveephone. „Littoral Combat Ship (LCS) manpower requirements analysis /“. Monterey, Calif. : Springfield, Va. : Naval Postgraduate School ; Available from National Technical Information Service, 2004. http://library.nps.navy.mil/uhtbin/hyperion/04Dec%5FDouangaphaivong.pdf.

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Thesis (M.S. in Operations Research)--Naval Postgraduate School, Dec. 2004.
Thesis Advisor(s): Gregory V. Cox, William D. Hatch II. Includes bibliographical references (p. 187-189). Also available online.
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Robin, Clément. „Structure et rhéologie du poly(acide méthacrylique) en régime semi-dilué : organisation sous cisaillement et en température“. Thesis, Paris Est, 2016. http://www.theses.fr/2016PESC1152/document.

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Le poly(acide méthacrylique) (PMAA) est un polyélectrolyte relativement peu étudié qui présente cependant des caractéristiques physico-chimiques variées et très intéressantes. La présence d'un groupement méthyle en alpha du groupement acide carboxylique lui confère un comportement très différent de son homologue beaucoup plus étudié : le poly(acide acrylique). En solvant aqueux et à faible taux d'ionisation, la synergie entre les interactions hydrophobes provenant des groupements méthyle et les liaisons hydrogène intramoléculaires entre les groupements acides carboxyliques sont à l'origine de la conformation très compacte adoptée par la chaîne polymère. Néanmoins, au-delà d'un taux d'ionisation critique, la chaîne de PMAA adopte une conformation très étendue semblable à celle adoptée par un polyélectrolyte classique à taux de charges élevé. L'objectif principal de ce travail est de relier les propriétés rhéologiques à la structure de solutions semi-diluées de PMAA.Le comportement rhéologique des solutions de PMAA a été étudié en fonction du régime de concentration et du taux d'ionisation. Les solutions semi-diluées suffisamment concentrées de PMAA présentent un comportement antithixotrope lorsque les macromolécules sont dans leur état globulaire. Le cisaillement entraîne la formation de liaisons intermoléculaires à l'origine de la formation d'un gel physique. Cette évolution a été reliée à une valeur de contrainte critique de cisaillement indépendante de la concentration pour laquelle le gel se forme. Ce phénomène présente des caractéristiques analogues à celles observées pour des suspensions colloïdales nanométriques.En solution aqueuse, les chaînes de PMAA non ionisées présentent une température critique inférieure de solubilité (LCST) située autour 67 $^{circ}$C. Une étude de ce phénomène par RMN a permis de sonder la mobilité des molécules d'eau au cours de la transition et de mettre en évidence un phénomène de déshydratation des macromolécules. Des mesures de diffusion de neutrons aux petits angles en température ont également montré la formation d'interfaces entre domaines riches et pauvres en polymère. L'emploi de ces différentes approches expérimentales a permis d'identifier un mécanisme de transition de phase très semblable à celui du poly(N-isopropylacrylamide) (PNIPAM). La température de point de trouble coïncide également avec une température de gel pour laquelle un gel viscoélastique se forme.La compréhension du comportement rhéologique et en température du PMAA est une étude nécessaire préalablement à l'élaboration de nanocomposites à base de PMAA et de nanoparticules de silice. Les nanocomposites sont préparés en solution et la fonctionnalisation des particules de silice permet d'augmenter les interactions polymère/silice. Le choix des groupements fonctionnels greffés à la surface des particules de silice a permis de rendre ces interactions variables par le pH de la solution. Une perspective à ce travail sera de corréler les propriétés structurales du nanocomposite à ses propriétés rhéologiques au cours du séchage
Poly(methacrylic acid) (PMAA) is a polyelectrolyte which has been rather scarcely investigated in the literature, despite its various and very interesting physical properties. The behavior of PMAA solutions is drastically different from the one displayed by the extensively studied poly(acrylic acid), due to the methyl group located in the alpha position of the carboxylic acid function. At low ionization degrees in aqueous solvent, synergetic effects resulting from both hydrophobic interactions (methyl groups) and intramolecular hydrogen bonds between acidic groups are responsible for the hypercoiled conformation of the PMAA chains. Nevertheless, above a critical ionization degree, the PMAA macromolecule behaves as an extended chain similar to a usual highly charged polyelectrolyte. The main purpose of this work is to correlate the rheological properties to the structure of the chains for semi-dilute solutions of PMAA.In the semi-dilute regime, above a critical concentration, PMAA solutions display a sharp increase in their viscosity over time under shear. This phenomenon known as antithixotropy occurs only when the macromolecules adopt a hypercoiled conformation. The influence of both concentration and ionization degree on the rheological behavior of PMAA solutions was studied. Shear induces the formation of intermolecular bonds which are responsible for the formation of a physical gel. We have demonstrated that the critical shear stress at which the gel is formed does not depend on the concentration. Interestingly, the results obtained remind some features observed in the case of the shear thickening of charged colloids.Neutral PMAA chains in water also display a Lower Critical Solution Temperature (LCST) around 67 $^{circ}$C. The reorientational dynamics of water molecules above the LCST was studied by means of NMR experiments, which evidenced the dehydration of the polymer coils during phase separation. The formation of interfaces between polymer-rich and polymer-poor domains was investigated by small-angle neutron scattering experiments. A possible mechanism describing the transition at the molecular level was derived from the results obtained throughout the use of complementary experimental approaches. This mechanism is very similar to the one proposed for the LCST transition of poly(N-isopropylacrylamide) (PNIPAM). The cloud point temperature of PMAA solutions is the same as the gel temperature at which a viscoelastic gel is formed.The understanding of the behavior of PMAA solutions under shear as well as under temperature is an essential prerequisite to the design of PMAA/silica nanocomposites. These nanocomposites were are prepared in the solution state. The interactions between PMAA chains and silica were clearly increased by the functionalization of the silica particles. Such interactions between PMAA and filler particles were found to be related to the pH of the solutions, due to the nature of the chemical groups at the surface of the functionalized silica. A possible perspective to this work would be the correlation between the structural features of the nanocomposites and their rheological properties during the drying process
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Lang, Xiaolong. „Structural and Chemical Contributions to Poly (N-alkyl acrylamide) Responsiveness“. Case Western Reserve University School of Graduate Studies / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=case1548428317696918.

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45

Landry, Patrice. „Informationslandschaft Europa / European Information Subject Access Panorama“. Universitätsbibliothek Chemnitz, 2005. http://nbn-resolving.de/urn:nbn:de:swb:ch1-200500625.

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Patrice Landry von der Schweizerischen Landesbibliothek, Bern, berichtete über „The recent history of European cooperation: from the ‚need‘ to cooperate to the ‚will‘ to cooperate“. Er zeichnete kurz die letzten 25 Jahre verbaler Sacherschließung in den USA und den europäischen Ländern nach, die im 21. Jahrhundert in das Projekt MACS mündete. MACS wird es beispielsweise einem englischsprachigen Benutzer gestatten, seine Suchanfrage englisch einzugeben und Erträge über international verlinkte vielsprachige Suchformulierungen zu bekommen.
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Landry, Patrice. „Informationslandschaft Europa / European Information Subject Access Panorama“. Universitätsbibliothek Chemnitz, 2007. http://nbn-resolving.de/urn:nbn:de:swb:ch1-200701289.

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Das Original-Dokument wurde in das Format pdf umgewandelt. Patrice Landry von der Schweizerischen Landesbibliothek, Bern, berichtete über „The recent history of European cooperation: from the ‚need‘ to cooperate to the ‚will‘ to cooperate“. Er zeichnete kurz die letzten 25 Jahre verbaler Sacherschließung in den USA und den europäischen Ländern nach, die im 21. Jahrhundert in das Projekt MACS mündete. MACS wird es beispielsweise einem englischsprachigen Benutzer gestatten, seine Suchanfrage englisch einzugeben und Erträge über international verlinkte vielsprachige Suchformulierungen zu bekommen.
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Martwong, Ekkachai. „Design of surface-attached hydrogel thin films with LCST/UCST temperature-responsive properties“. Thesis, Sorbonne université, 2018. http://www.theses.fr/2018SORUS120/document.

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Les films minces d'hydrogels thermosensibles à propriétés LCST/UCST (Lower/Upper Critical Solution Temperature) avec des températures de transition variables ont été mis au point pour des applications spécifiques. Les réseaux chimiques de polymères fixés de manière covalente sur des substrats solides plans ont été synthétisés par une approche polyvalente et facile à mettre en œuvre en utilisant la chimie click thiol-ène. Elle consiste à déposer des polymères préformés et réactifs en présence des réticulants dithiol sur des substrats modifiés thiol, la réaction de thiol-ène permettant la réticulation simultanée entre chaînes et le greffage en surface. La stratégie CLAG (Cross-Linking And Grafting) donne des films d'hydrogel chimiquement stables et reproductibles avec une large gamme d'épaisseur et avec les propriétés thermostimulables désirées. Les polymères hydrophiles fonctionnalisés par des groupes fonctionnels alcène peuvent être synthétisés en utilisant une copolymérisation radicalaire du monomère souhaité avec du méthacrylate d'allyle dans un solvant organique ou un co-solvant avec de l'eau. Une autre voie est la synthèse dans l'eau en deux étapes: le monomère désiré est copolymérisé avec l'acide acrylique puis le copolymère est modifié par l’allylamine. Trois familles de polymères ont été étudiées: poly(PEGMA), poly(acrylamide) et poly(zwitterion). La température de transition des films d'hydrogel est déterminée en mesurant l'épaisseur dans des solutions aqueuses par ellipsométrie. Les films d'hydrogel de poly(PEGMA) montrent des propriétés de LCST avec la température de transition augmentant avec le nombre d'unités de PEG. La LCST varie de 15°C à 60°C avec deux à cinq unités de PEG dans les chaînes pendantes. La LCST peut également être ajustée en utilisant des copolymères avec différents ratios. Les films d'hydrogel acrylamide ont à la fois des propriétés LCST et UCST. Les films d'hydrogel de poly(sulfobetaïne) montrent un comportement UCST très intéressant en plus d’être « anti-fouling », ce qui est très prometteur pour les applications en biologie
Temperature-responsive surface-attached hydrogel thin films with various LCST/UCST (Lower/Upper Critical Solution Temperature) were designed for specific applications. The chemical polymer networks covalently attached on plane solid substrates were synthesized by a versatile and straightforward approach using thiol-ene click chemistry. It consists in coating ene-reactive polymers and dithiol crosslinkers on thiol-modified substrates, the thiol-ene click reaction allowing simultaneous cross-linking between chains and grafting on the surface. The CLAG (Cross-Linking And Grafting) strategy provides chemically stable and reproducible hydrogel films with a wide range of thickness and with the desired temperature-responsive properties. Ene-functionalized hydrophilic polymers can be synthesized using free radical copolymerization of the desired monomer with allyl methacrylate in organic solvent or co-solvent with water. Another way is the synthesis in water in two steps: the desired monomer is copolymerized with acrylic acid and then the copolymer is post-modified by amidification. Three polymer families were investigated: poly(PEGMA), poly(acrylamide) derivatives and poly(zwitterions). The transition temperature of the hydrogel films is determined by measuring the thickness in aqueous solutions at different temperatures with ellipsometry. Poly(PEGMA) hydrogel films show LCST properties with the transition temperature increasing with the number of PEG units. The LCST ranges from 15 °C to 60 °C with two to five PEG units in the pendant chains. The LCST can also be adjusted using mixed copolymers hydrogel. Poly(acrylamide) derivatives hydrogel films have both LCST and UCST properties. Poly(sulfobetaine) hydrogel films show very interesting UCST behavior in addition to be anti-fouling, which is very promising for biology applications
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GONZALEZ, GONZALEZ GABRIEL 753781, und GONZALEZ GABRIEL GONZALEZ. „Lcs laboratorios en la enseñanza de la psicología“. Tesis de maestría, Universidad Autónoma del Estado de México, 2012. http://hdl.handle.net/20.500.11799/41216.

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Esto motivó la realización de un estudio de campo que permitiera entender elestado actual del empleo de los laboratorios y su papel en la enseñanza de lapsicología en el país. Se estudiaron a los laboratorios que pertenecían a las diezinstituciones de educación superior mejor calificadas en la lista de la Guía Universitaria2010, del Selecciones Reader´s Digest de México, que impartían lacarrera de psicología. Se analizó su equipamiento, su orientación disciplinaria,sus funciones en docencia e investigación, y a partir de los resultados, se analizóuna propuesta de laboratorio.
El propósito de este trabajo consistió en conocer el papel que los laboratorios juegan actualmente en la enseñanza de la psicología en México. Se estudiaron los laboratorios que pertenecían a las diez instituciones de educación superior más prestigiadas del país, que impartían la carrera de psicología. Mediante entrevista de campo, se investigó el equipamiento de los laboratorios, su orientación disciplinaria y sus funciones en la docencia y en la investigación.
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Gastinger, Kay. „Low coherence speckle interferometry (LCSI) for the characterisation of adhesive bonded joints“. [S.l.] : [s.n.], 2007. http://deposit.ddb.de/cgi-bin/dokserv?idn=983586187.

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50

M'Barki, Oualid. „Etude des mécanismes de formation de "membranes vertes" à partir d'un système PVA/eau par une méthode d'inversion de phase originale : LCST-TIPS“. Thesis, Montpellier 2, 2014. http://www.theses.fr/2014MON20031/document.

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Les membranes polymères sont actuellement élaborées par des procédés de séparation de phase impliquant l'utilisation de solvants organiques en grande quantité. Dans cette étude, un nouveau procédé d'élaboration de membrane a été développé en substituant les solvants organiques par l'eau, donc en utilisant un polymère hydrosoluble. Ce procédé, appelé LCST-TIPS, consiste à induire une séparation de phase par augmentation de la température au-delà de la température critique du système polymère/eau, la LCST. Afin de figer la structure de la membrane et la rendre insoluble en milieu aqueux, une réticulation des chaines de polymère doit être réalisée. Dans cette thèse, le système alcool polyvinylique (PVA)/eau a été utilisé et une réticulation chimique a été mise en œuvre en utilisant le glutaraldéhyde. La séparation de phase a été étudiée par analyse UV, turbidimétrie et diffusion de lumière et l'étude de la réticulation a été étudiée en mesurant les temps de prise en gel par rhéologie. Des membranes ont été élaborées en couplant la séparation de phase, la réticulation et l'évaporation du solvant ; les propriétés morphologiques des membranes ont été corrélées aux conditions opératoires choisies. Les chemins de composition ont été simulés en modélisant les transferts de matière et ont été reliés aux cinétiques de réticulation afin de mieux comprendre les morphologies membranaires obtenues. Les propriétés fonctionnelles des membranes PVA ont été évaluées par filtration d'eau après ajout d'un agent porogène (le dextrane) dans le collodion
Polymeric membranes are mostly prepared by phase separation processes requiring high quantities of organic solvents. A new process of membrane preparation is developed in this work and aims at replacing the organic solvents by water, using water soluble polymer. This process, called LCST-TIPS process, consists in coupling a phase separation by increasing temperature until a critical temperature (Lower Critical Solution Temperature – LCST). The cross-linking of the polymer chains has to be performed to obtain insoluble membrane. The polyvinyl alcohol (PVA)/water system was used in this work and a chemical cross-linking using glutaraldehyde in acid medium was performed to fix the membrane structure. First, phase separation and cross-linking were studied separately by UV analysis, turbidimetry and light scattering and by monitoring the gelation during cross-linking using rheological measurements. Membranes were then prepared by coupling the whole phenomena, i.e. phase inversion, cross-linking, solvent evaporation and the effect of formulation and process parameters was studied on PVA membrane morphologies. Composition paths were simulated by modeling mass transfer phenomena during elaboration and were linked to the cross-linking kinetics in order to investigate the link between membrane morphologies and operating conditions. Membranes functional properties were then determined by water filtration tests after addition of a porogenic reagent (dextran) in the collodion