Auswahl der wissenschaftlichen Literatur zum Thema „Homolysis“
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Zeitschriftenartikel zum Thema "Homolysis"
Zhang, Chen, Junxia Pi, Shu Chen, Ping Liu und Peipei Sun. „Construction of a 4H-pyrido[4,3,2-gh]phenanthridin-5(6H)-one skeleton via a catalyst-free radical cascade addition/cyclization using azo compounds as radical sources“. Organic Chemistry Frontiers 5, Nr. 5 (2018): 793–96. http://dx.doi.org/10.1039/c7qo00926g.
Der volle Inhalt der QuelleShin, Jeongcheol, Jiseon Lee, Jong-Min Suh und Kiyoung Park. „Ligand-field transition-induced C–S bond formation from nickelacycles“. Chemical Science 12, Nr. 48 (2021): 15908–15. http://dx.doi.org/10.1039/d1sc05113j.
Der volle Inhalt der QuelleQianzhu, Haocheng, Wenjuan Ji, Xinjian Ji, Leixia Chu, Chuchu Guo, Wei Lu, Wei Ding, Jiangtao Gao und Qi Zhang. „Reactivity of the nitrogen-centered tryptophanyl radical in the catalysis by the radical SAM enzyme NosL“. Chemical Communications 53, Nr. 2 (2017): 344–47. http://dx.doi.org/10.1039/c6cc08869d.
Der volle Inhalt der QuelleIshihara, Koji, und Thomas Wilson Swaddle. „The pressure dependence of rates of homolytic fission of metal–ligand bonds in aqueous solution“. Canadian Journal of Chemistry 64, Nr. 11 (01.11.1986): 2168–70. http://dx.doi.org/10.1139/v86-356.
Der volle Inhalt der QuelleYorimitsu, Hideki. „Homolytic substitution at phosphorus for C–P bond formation in organic synthesis“. Beilstein Journal of Organic Chemistry 9 (28.06.2013): 1269–77. http://dx.doi.org/10.3762/bjoc.9.143.
Der volle Inhalt der QuelleCameron, Dale R., Alison M. P. Borrajo, Gregory R. J. Thatcher und Brian M. Bennett. „Organic nitrates, thionitrates, peroxynitrites, and nitric oxide: a molecular orbital study of the (X = O, S) rearrangement, a reaction of potential biological significance“. Canadian Journal of Chemistry 73, Nr. 10 (01.10.1995): 1627–38. http://dx.doi.org/10.1139/v95-202.
Der volle Inhalt der QuelleEdeleva, Mariya, Gerard Audran, Sylvain Marque und Elena Bagryanskaya. „Smart Control of Nitroxide-Mediated Polymerization Initiators’ Reactivity by pH, Complexation with Metals, and Chemical Transformations“. Materials 12, Nr. 5 (26.02.2019): 688. http://dx.doi.org/10.3390/ma12050688.
Der volle Inhalt der QuelleShu, Xing-Zhong, und Xiaobo Pang. „Titanium: A Unique Metal for Radical Dehydroxylative Functionalization of Alcohols“. Synlett 32, Nr. 13 (04.03.2021): 1269–74. http://dx.doi.org/10.1055/a-1406-0484.
Der volle Inhalt der QuelleKoppenol, Willem H., und Reinhard Kissner. „Can ONOOH Undergo Homolysis?“ Chemical Research in Toxicology 11, Nr. 2 (Februar 1998): 87–90. http://dx.doi.org/10.1021/tx970200x.
Der volle Inhalt der QuelleTurrà, Natascia, Ulrich Neuenschwander und Ive Hermans. „Molecule-Induced Peroxide Homolysis“. ChemPhysChem 14, Nr. 8 (04.04.2013): 1666–69. http://dx.doi.org/10.1002/cphc.201300130.
Der volle Inhalt der QuelleDissertationen zum Thema "Homolysis"
Marquess, Daniel. „Studies on the insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis“. Thesis, University of Oxford, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.306548.
Der volle Inhalt der QuelleHelling, Christoph [Verfasser], und Stephan [Akademischer Betreuer] Schulz. „Pnictogen–Carbon Bond Homolysis : an approach to the synthesis of group 13 metal-substituted pnictanyl radicals / Christoph Helling ; Betreuer: Stephan Schulz“. Duisburg, 2021. http://d-nb.info/123491123X/34.
Der volle Inhalt der QuelleHavot, Jeffrey. „Synthèse et étude d'alcoxyamines inédites : de la théranostique à l'activation par résonnance plasmonique“. Electronic Thesis or Diss., Aix-Marseille, 2022. http://www.theses.fr/2022AIXM0080.
Der volle Inhalt der QuelleAlkoxyamines are molecules well-known for their abilities to generate radicals from C-ON bond homolysis. This homolysis can be induced by various methods like thermally, by photocatalysis or by enzymatic activation. In addition, it is easy to modulate their chemical properties by modifying their structure. Thus we can imagine many various applications for these compounds. Here we will describe the synthesis of new alkoxyamines and investigations about their properties. These alkoxyamines have ben developed in order to acquire new knowledge about their reactivity, but also to improve their structures with respect to innovative applications like theranostic, or some new homolysis pathways like localized plasmon resonance
Robertson, Jeremy. „Ring expansion reaction via homolytic pathways“. Thesis, University of Oxford, 1990. http://ora.ox.ac.uk/objects/uuid:194ca194-4848-470b-a21f-c16869257b96.
Der volle Inhalt der QuelleSpratley, A. „Some studies of the homolytic reactions of chlorinated benzenes“. Thesis, City University London, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.355587.
Der volle Inhalt der QuelleNorberg, Daniel. „Quantum Chemical Studies of Radical Cation Rearrangement, Radical Carbonylation, and Homolytic Substitution Reactions“. Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-8178.
Der volle Inhalt der QuelleCarré, Christiane. „Étude des réactions photoinduites de l'octahydro-1,2,3,4,6,7,8,9 phénazine en solution ou la voie des diazines vers la photo-homolyse de l'eau“. Paris 11, 1985. http://www.theses.fr/1985PA112084.
Der volle Inhalt der QuelleNi, Liming. „Synthesis and evaluation of new peptidyl phosphonate analogs of benzamidine, lysine and homolysine as irreversible inhibitors for thrombin and other trypsin-like enzymes“. Diss., Georgia Institute of Technology, 1997. http://hdl.handle.net/1853/27080.
Der volle Inhalt der QuelleLingua, Hugo. „SH2 sur les dialkylzincs par les radicaux α-alcoxycarbonyle, carbozincations et additions radicalaires impliquant des ynamides : approches expérimentales et théoriques“. Thesis, Aix-Marseille, 2017. http://www.theses.fr/2017AIXM0564.
Der volle Inhalt der QuelleThe reactivity of ethyl α-bromoacrylate and ethyl benzylidene malonate towards dialkylzincs in aerobic medium was studied in order to evaluate the capacity of tertiary α-alcoxycarbonyl radicals to undergo SH2 at zinc leading to a zinc enolate. The use of ethyl α-bromoacrylate allowed the synthesis of cyclopropanes and keto-esters. With the second substrate, the addition of the alkyl group was shown to be reversible. The inhibitor effect of additives like TMSCl or CuCl suggested that zinc peroxydes formed in situ could play a key role in the process. Theoretical studies highlighted the crucial role of the stabilization of the zinc enolate through the formation of a 5 or 6-membered chelate. Regio- and stereoselective synthesis of tri- and tetra-substituted enamides was achieved through the carbozincation of ynamides in the presence of dialkylzincs and CuI or FeCl2 as catalyst. CuI was shown to be more efficient and less substrate-dependent than FeCl2. Molecular modelings were performed to better understand this phenomen. Finally, intermolecular addition of sulfanyl radicals onto ynamides was revisited. Theoretical calculations and experimental results showed that the regio- and stereo-selectivity of the process depended on the nature of the substituent on the carbon in β position of the nitrogen atom and on experimental conditions. Unprecedented intermolecular addition of a carbon-centered radical has been described and opened new perspectives for the synthesis of original tetrasubstituted enamides
Vallet, Anne-Laure. „Réactivités de NHC-Boranes Soufrés“. Thesis, Paris 11, 2014. http://www.theses.fr/2014PA112261.
Der volle Inhalt der QuelleAlong with the development of green chemistry, it became necessary to avoid toxic metallic complexes in organic reactions and replace them by more sustainable compounds. An hydrogen donors for radical reactions, trialkylstannanes are still widely used. NHC-boranes seem to be good substitutes for deoxygenation reactions. However, dehalogenation reactions are less effective and polar reversal catalysis was used. This work was the starting point of this Ph.D thesis where the synthesis of new NHC-boranes bearing a B-S or B-N bound is developed. The study of the properties of these new complexes was performed and applications in organic chemistry as well as in polymer science were found. Besides, to study polar effects on the formation and on the reactivity of boryl radicals, a new family of carbene-boranes was synthesized
Bücher zum Thema "Homolysis"
Turovsʹkyĭ, A. A. Non-valency interaction in organic peroxides homolysis reactions. Hauppauge, N.Y: Nova Science Publishers, 2011.
Den vollen Inhalt der Quelle finden(Editor), Gennadii Efremovich Zaikov, Yu B. Monakov (Editor), Alfonso Jimenez (Editor) und Iu B. Monakov (Editor), Hrsg. Homolytic and Heterolytic Reactions: Problems and Solutions. Nova Science Publishers, 2004.
Den vollen Inhalt der Quelle findenHomolytic Aromatic Substitution: International Series of Monographs on Organic Chemistry. Elsevier Science & Technology Books, 2014.
Den vollen Inhalt der Quelle findenBuchteile zum Thema "Homolysis"
Cleaves, Henderson James. „Homolysis“. In Encyclopedia of Astrobiology, 1. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-27833-4_733-3.
Der volle Inhalt der QuelleCleaves, Henderson James. „Homolysis“. In Encyclopedia of Astrobiology, 1117. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-44185-5_733.
Der volle Inhalt der QuelleCleaves, Henderson James. „Homolysis“. In Encyclopedia of Astrobiology, 761–62. Berlin, Heidelberg: Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-11274-4_733.
Der volle Inhalt der QuelleCleaves II, Henderson James. „Homolysis“. In Encyclopedia of Astrobiology, 1. Berlin, Heidelberg: Springer Berlin Heidelberg, 2022. http://dx.doi.org/10.1007/978-3-642-27833-4_733-4.
Der volle Inhalt der QuelleCleaves II, Henderson James. „Homolysis“. In Encyclopedia of Astrobiology, 1343–44. Berlin, Heidelberg: Springer Berlin Heidelberg, 2023. http://dx.doi.org/10.1007/978-3-662-65093-6_733.
Der volle Inhalt der QuelleAntal, Michael Jerry, Andrew Brittain, Carlos DeAlmeida, Sundaresh Ramayya und Jiben C. Roy. „Heterolysis and Homolysis in Supercritical Water“. In ACS Symposium Series, 77–86. Was,hington, DC: American Chemical Society, 1987. http://dx.doi.org/10.1021/bk-1987-0329.ch007.
Der volle Inhalt der QuelleStein, Stephen E., und Mahendra M. Suryan. „Homolysis of Substituted Anisoles: Substituent Effects on Phenoxyl Radical Stabilities“. In Oxygen Radicals in Biology and Medicine, 105–14. Boston, MA: Springer US, 1988. http://dx.doi.org/10.1007/978-1-4684-5568-7_15.
Der volle Inhalt der QuelleFink, Richard G. „Coenzyme B12-Based Chemical Precedent for Co-C Bond Homolysis and Other Key Elementary Steps“. In Vitamin B12and B12-Proteins, 383–402. Weinheim, Germany: Wiley-VCH Verlag GmbH, 2007. http://dx.doi.org/10.1002/9783527612192.ch25.
Der volle Inhalt der QuelleRossi, Roberto A., María E. Budén und Javier F. Guastavino. „Homolytic Aromatic Substitution“. In Arene Chemistry, 219–42. Hoboken, NJ: John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch9.
Der volle Inhalt der QuelleHalpern, J. „Homolytic Ligand Dissociation“. In Inorganic Reactions and Methods, 9. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch5.
Der volle Inhalt der QuelleKonferenzberichte zum Thema "Homolysis"
Tumanov, Vladimir Evgen'vich, und Andrei Ivanovich Prokhorov. „Web database on bond dissociation energies of organic compounds“. In 23rd Scientific Conference “Scientific Services & Internet – 2021”. Keldysh Institute of Applied Mathematics, 2021. http://dx.doi.org/10.20948/abrau-2021-21.
Der volle Inhalt der QuelleJeremić, Svetlana R., Jelena R. Đorović Jovanović, Marijana S. Stanojević Pirković und Zoran S. Marković. „THERMODYNAMICALLY INVESTIGATIONS OF FREE RADICAL SCAVENGER POTENCY OF 1,2,4-TRIHYDROXYTHIOXANTHONE“. In 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac, 2021. http://dx.doi.org/10.46793/iccbi21.414j.
Der volle Inhalt der QuelleBerichte der Organisationen zum Thema "Homolysis"
Lee, Shaoyung. Kinetic study of the reaction of ferrocenes and ferrocenium ions with ground and excited states of tris(2,2-bipyridine)chromium ions and the preparation and homolysis of organocobalt complexes. Office of Scientific and Technical Information (OSTI), Januar 1990. http://dx.doi.org/10.2172/6835414.
Der volle Inhalt der QuelleHeinekey, D. M. Homolytic activation of hydrocarbons and hydrogen by persistent metal radicals. Office of Scientific and Technical Information (OSTI), Januar 1992. http://dx.doi.org/10.2172/6716196.
Der volle Inhalt der QuelleHeinekey, D. M. Homolytic activation of hydrocarbons and hydrogen by persistent metal radicals. Progress report, January 1, 1992--November 1, 1992. Office of Scientific and Technical Information (OSTI), Dezember 1992. http://dx.doi.org/10.2172/10136755.
Der volle Inhalt der Quelle[Homolytic activation of hydrocarbons and hydrogen by persistent radicals]. Office of Scientific and Technical Information (OSTI), Januar 1993. http://dx.doi.org/10.2172/6837370.
Der volle Inhalt der Quelle[Homolytic activation of hydrocarbons and hydrogen by persistent radicals]. Final report. Office of Scientific and Technical Information (OSTI), Februar 1993. http://dx.doi.org/10.2172/10122867.
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