Um die anderen Arten von Veröffentlichungen zu diesem Thema anzuzeigen, folgen Sie diesem Link: Hexahydropyrimidines.

Zeitschriftenartikel zum Thema „Hexahydropyrimidines“

Geben Sie eine Quelle nach APA, MLA, Chicago, Harvard und anderen Zitierweisen an

Wählen Sie eine Art der Quelle aus:

Machen Sie sich mit Top-50 Zeitschriftenartikel für die Forschung zum Thema "Hexahydropyrimidines" bekannt.

Neben jedem Werk im Literaturverzeichnis ist die Option "Zur Bibliographie hinzufügen" verfügbar. Nutzen Sie sie, wird Ihre bibliographische Angabe des gewählten Werkes nach der nötigen Zitierweise (APA, MLA, Harvard, Chicago, Vancouver usw.) automatisch gestaltet.

Sie können auch den vollen Text der wissenschaftlichen Publikation im PDF-Format herunterladen und eine Online-Annotation der Arbeit lesen, wenn die relevanten Parameter in den Metadaten verfügbar sind.

Sehen Sie die Zeitschriftenartikel für verschiedene Spezialgebieten durch und erstellen Sie Ihre Bibliographie auf korrekte Weise.

1

Moser, Shasta, Ryan Church, M. Brad Peori und Keith Vaughan. „Triazene derivatives of (1,x)-diazacycloalkanes. Part IV.1 Synthesis and characterization of 1-[2-aryl-1-diazenyl]-3-(3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinylmethyl)hexahydropyrimidines and 1-(5,5-dimethyl-3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinylmethyl)-5,5-dimethyl-3-[2-aryl-1-diazenyl]hexahydropyrimidines from the reaction of diazonium salts with mixtures of formaldehyde and 1,3-diaminopropanes“. Canadian Journal of Chemistry 83, Nr. 8 (01.08.2005): 1071–83. http://dx.doi.org/10.1139/v05-131.

Der volle Inhalt der Quelle
Annotation:
Two new series of bistriazenes have been synthesized from a general reaction of diazonium salts with a mixture of a propanediamine and formaldehyde. Such reaction with 1,3-diaminopropane itself affords the 1-[2-aryl-1-diazenyl]-3-(3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinylmethyl)hexahydropyrimidines (6). 2,2-Dimethyl-1,3-diamino propane reacts in an analogous manner to give the 1-(5,5-dimethyl-3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinylmethyl)- 5,5-dimethyl-3-[2-aryl-1-diazenyl]hexahydropyrimidines (7). All new compounds have been characterized by IR and NMR spectroscopy, with elemental analysis or high resolution mass spectrometry of most of the new compounds. NMR assignments have been analyzed by a series of DEPT, COSY, and HSQC experiments. One example of each series has been unequivocally characterized by X-ray crystallography. The general conclusion of this study is that alkanediamines with three carbon atoms in the spacer link between the nitrogen atoms give rise to the linear bicyclic molecules of type 18, in contrast to the case of ethylenediamine (spacer link has two carbon atoms), which affords cage-like molecules of type 17.Key words: bistriazene, hexahydropyrimidine, diazonium coupling, formaldehyde, diaminopropane, nuclear magnetic resonance.
APA, Harvard, Vancouver, ISO und andere Zitierweisen
2

Badamshin, A. G., D. R. Latypova und V. A. Dokichev. „Synthesis of Polyfunctionalized Hexahydropyrimidines“. Russian Journal of Organic Chemistry 55, Nr. 2 (Februar 2019): 168–73. http://dx.doi.org/10.1134/s1070428019020076.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
3

Zelenin, Kirill N., Valeriy V. Alekseyev, Ilya V. Ukraintsev und Igor V. Tselinsky. „2-SUBSTITUTED HEXAHYDROPYRIMIDINES AND THEIR TAUTOMERISM“. Organic Preparations and Procedures International 30, Nr. 1 (Februar 1998): 53–61. http://dx.doi.org/10.1080/00304949809355259.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
4

Katritzky, Alan R., Sandeep K. Singh und Hai-Ying He. „Novel Syntheses of Hexahydropyrimidines and Tetrahydroquinazolines“. Journal of Organic Chemistry 67, Nr. 9 (Mai 2002): 3115–17. http://dx.doi.org/10.1021/jo010927x.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
5

Luk'yanov, O. A., G. V. Pokhvisneva und T. V. Ternikova. „N,N?-Diacylated imidazolidines and hexahydropyrimidines“. Russian Chemical Bulletin 43, Nr. 8 (August 1994): 1376–80. http://dx.doi.org/10.1007/bf00703698.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
6

Farrell, Joshua R., Jonathan Niconchuk, Christine S. Higham und Brittany W. Bergeron. „Phenol derivatized hexahydropyrimidines prepared from Mannich condensations“. Tetrahedron Letters 48, Nr. 45 (November 2007): 8034–36. http://dx.doi.org/10.1016/j.tetlet.2007.09.038.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
7

Shafikova, E. A., D. V. Petrov, T. A. Sapozhnikova, N. J. Baschenko und V. A. Dokichev. „Synthesis of norbornane series tetra- and hexahydropyrimidines“. Chemistry of Heterocyclic Compounds 45, Nr. 6 (Juni 2009): 685–90. http://dx.doi.org/10.1007/s10593-009-0328-1.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
8

Tingley, Reid, M. Brad Peori, Ryan Church und Keith Vaughan. „Triazene derivatives of (1,x)-diazacycloalkanes. Part V.1 Synthesis and characterization of 4-ethyl-3-({6-ethyl-3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinyl}methyl)-1-[2-aryl-1-diazenyl)hexa- hydropyrimidines from the reaction of diazonium salts with mixtures of formaldehyde and 1,3-diaminopentane“. Canadian Journal of Chemistry 83, Nr. 10 (01.10.2005): 1799–807. http://dx.doi.org/10.1139/v05-192.

Der volle Inhalt der Quelle
Annotation:
A new series of bistriazenes has been synthesized from a general reaction of diazonium salts with a mixture of 1,3-diaminopentane (DYTEK® EP diamine) and formaldehyde, which affords the 4-ethyl-3-({6-ethyl-3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinyl}methyl)-1-[2-aryl-1-diazenyl]hexahydropyrimidines (1). Each of the molecules of type 1 is built up of two equivalent 3-(aryldiazenyl)-6-ethylhexahydro-1-pyrimidinyl groups attached to a central methylene group. The importance of this study is in part due to the fact that the formaldehyde–1,3-diaminopentane system has not previously been investigated. All new compounds have been characterized by IR and NMR spectroscopy, with elemental analysis for selected compounds; one example from the series has been unequivocally characterized by X-ray crystallography. Although analysis of the NMR spectra is made somewhat difficult because of broadness and coalescence of signals due to the rotational dynamics of the N—N single bonds, it is possible to fully assign the proton spectra of all compounds and to detect 94% of all carbon signals. The fine structure within the proton spectra illustrate the diastereotopic nature of the methylene group protons because of the presence of a stereocenter in each hexahydropyrimidine ring. The general conclusion of this study is that alkanediamines with three carbon atoms in the spacer link between the nitrogen atoms give rise to the linear bicyclic molecules of type 1, 2, and 3, in contrast to the case of ethylenediamine (spacer link has two carbon atoms), which affords molecules of type 7 that exemplify the bridged bicyclic bistriazene structure. The new compounds of series 1 represent an extension of a broad ranging study of the synthesis of new bistriazene derivatives of (1,x)-diazacycloalkanes.Key words: triazene, diazonium coupling, hexahydropyrimidine, diaminopentane, diazacycloalkanes, stereocenter, diastereotopic protons.
APA, Harvard, Vancouver, ISO und andere Zitierweisen
9

Bergeron, Raymond J., und Howard W. Seligsohn. „Hexahydropyrimidines as masked spermidine vectors in drug delivery“. Bioorganic Chemistry 14, Nr. 4 (Dezember 1986): 345–55. http://dx.doi.org/10.1016/0045-2068(86)90001-5.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
10

LUK'YANOV, O. A., G. V. POKHVISNEVA und T. V. TERNIKOVA. „ChemInform Abstract: N,N′-Diacylated Imidazolidines and Hexahydropyrimidines.“ ChemInform 26, Nr. 12 (18.08.2010): no. http://dx.doi.org/10.1002/chin.199512067.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
11

ZELENIN, K. N., V. V. ALEKSEYEV, I. V. UKRAINTSEV und I. V. TSELINSKY. „ChemInform Abstract: 2-Substituted Hexahydropyrimidines and Their Tautomerism.“ ChemInform 29, Nr. 24 (22.06.2010): no. http://dx.doi.org/10.1002/chin.199824134.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
12

Katritzky, Alan R., Sandeep K. Singh und Hai-Ying He. „ChemInform Abstract: Novel Syntheses of Hexahydropyrimidines and Tetrahydroquinazolines.“ ChemInform 33, Nr. 52 (18.05.2010): no. http://dx.doi.org/10.1002/chin.200252148.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
13

Janati, Fatemeh, Majid M. Heravi und Ahmad Mirshokraie. „Superparamagnetic Iron Oxide as an Efficient Catalyst for the One-Pot, Solvent-Free Synthesis of 5,5-Disubstituted Hexahydropyrimidines and Their Spiro Analogues“. Journal of Chemistry 2013 (2013): 1–5. http://dx.doi.org/10.1155/2013/214617.

Der volle Inhalt der Quelle
Annotation:
Superparamagnetic Fe3O4is shown to act as a very efficient catalyst for the one-pot, three-component synthesis of 5,5-disubstituted hexahydropyrimidines and their spiropiperidines. The catalyst is easily recovered by the use of an external magnet and reused in several reactions without any noticeable loss of activity. The products are obtained in short time and good purity upon separation of the catalyst and evaporation of the volatiles of the reaction mixture.
APA, Harvard, Vancouver, ISO und andere Zitierweisen
14

KNABE, J., und J. BIWERSI. „ChemInform Abstract: Racemates and Enantiomers of 5,5-Disubstituted Hexahydropyrimidines.“ ChemInform 25, Nr. 16 (19.08.2010): no. http://dx.doi.org/10.1002/chin.199416191.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
15

Göblyös, Anikó, László Lázár und Ferenc Fülöp. „Ring-chain tautomerism of 2-aryl-substituted-hexahydropyrimidines and tetrahydroquinazolines“. Tetrahedron 58, Nr. 5 (Januar 2002): 1011–16. http://dx.doi.org/10.1016/s0040-4020(01)01196-6.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
16

Ahmed, Nayeem, Saima Tarannum und Zeba N. Siddiqui. „Dy/chitosan: a highly efficient and recyclable heterogeneous nano catalyst for the synthesis of hexahydropyrimidines in aqueous media“. RSC Advances 5, Nr. 63 (2015): 50691–700. http://dx.doi.org/10.1039/c5ra08160b.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
17

Tolpygin, I. E. „Chemosensor activity of 2-(anthracen-9-yl)-substituted imidazolidines and hexahydropyrimidines“. Russian Journal of Organic Chemistry 48, Nr. 1 (Januar 2012): 104–8. http://dx.doi.org/10.1134/s1070428012010162.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
18

Garratt, Peter J., Simon N. Thorn und Roger Wrigglesworth. „Regioselective and enantiospecific synthesis of 6-substituted and 5,6-disubstituted hexahydropyrimidines“. Tetrahedron Letters 32, Nr. 5 (Januar 1991): 691–94. http://dx.doi.org/10.1016/s0040-4039(00)74861-1.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
19

Sosnovskikh, V. Ya, und V. A. Kutsenko. „Synthesis of 2-(2-hydroxyaroylmethylene)hexahydropyrimidines from 2-trichloromethylchromones and trimethylenediamine“. Russian Chemical Bulletin 48, Nr. 11 (November 1999): 2117–20. http://dx.doi.org/10.1007/bf02494859.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
20

Korbonits, Dezsö, Erzsébet Tóbiás-Héja und Pαl Kolonits. „Ring – Chain Tautomerism of 4-Hydroximino-hexahydropyrimidines Substituted in Position 2“. Chemische Berichte 124, Nr. 5 (Mai 1991): 1199–202. http://dx.doi.org/10.1002/cber.19911240536.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
21

Zhou, Hui, Hetti Handi Chaminda Lakmal, Jonathan M. Baine, Henry U. Valle, Xue Xu und Xin Cui. „Catalytic [2 + 2 + 2] cycloaddition with indium(iii)-activated formaldimines: a practical and selective access to hexahydropyrimidines and 1,3-diamines from alkenes“. Chemical Science 8, Nr. 9 (2017): 6520–24. http://dx.doi.org/10.1039/c7sc02576a.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
22

Latypova, D. R. „Mannich-Type Reaction for Synthesis of Hexahydropyrimidines and 3,7-Diazabicyclo[3.3.1]Nonanes“. Bashkir chemistry journal 25, Nr. 2 (August 2018): 10. http://dx.doi.org/10.17122/bcj-2018-2-10-23.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
23

Lorente, Antonio, José L. Garacia Navio, José C. Lopez Perez und José L. Soto. „A Simple Synthesis of 4-Amino-6-aryl-2-thioxotetra-and -hexahydropyrimidines“. Synthesis 1985, Nr. 01 (1985): 89–92. http://dx.doi.org/10.1055/s-1985-31121.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
24

Shakirov, R. R., T. V. Dokichev, R. Z. Biglova, N. M. Vlasova, N. Z. Baibulatova und R. F. Talipov. „Methyl nitroacetate and 3-nitropropionate in the synthesis of hexahydropyrimidines and piperidines“. Chemistry of Heterocyclic Compounds 44, Nr. 1 (Januar 2008): 43–49. http://dx.doi.org/10.1007/s10593-008-0011-y.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
25

Pokhvisneva, G. V., und O. A. Luk’yanov. „Synthesis of 2-substituted 1-tosyl-3-(1-tosyliminoalkyl)imidazolidines and-hexahydropyrimidines“. Russian Chemical Bulletin 55, Nr. 5 (Mai 2006): 903–6. http://dx.doi.org/10.1007/s11172-006-0350-8.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
26

KALYANAM, N., P. C. PARTHASARATHY, L. ANANTHAN, S. G. MANJUNATHA und M. A. LIKHATE. „ChemInform Abstract: Studies on Antiamoebic Compounds. Part 4. Synthesis of Hexahydropyrimidines and Tetrahydroimidazoles.“ ChemInform 23, Nr. 28 (21.08.2010): no. http://dx.doi.org/10.1002/chin.199228071.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
27

Zohdi, Hussein F., Nora M. Rateb und Sherif M. Elnagdy. „Green synthesis and antimicrobial evaluation of some new trifluoromethyl-substituted hexahydropyrimidines by grinding“. European Journal of Medicinal Chemistry 46, Nr. 11 (November 2011): 5636–40. http://dx.doi.org/10.1016/j.ejmech.2011.09.036.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
28

Hwang, Jong Yeon, Hee-Young Kim, Suyeon Jo, Eunjung Park, Jihyun Choi, Sunju Kong, Dong-Sik Park et al. „Synthesis and evaluation of hexahydropyrimidines and diamines as novel hepatitis C virus inhibitors“. European Journal of Medicinal Chemistry 70 (Dezember 2013): 315–25. http://dx.doi.org/10.1016/j.ejmech.2013.09.055.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
29

Sosnovskikh, V. Ya, und V. A. Kutsenko. „ChemInform Abstract: Synthesis of 2-(2-Hydroxyaroylmethylene)hexahydropyrimidines from 2-Trichloromethylchromones and Trimethylenediamine.“ ChemInform 31, Nr. 14 (09.06.2010): no. http://dx.doi.org/10.1002/chin.200014136.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
30

GARRATT, P. J., S. N. THORN und R. WRIGGLESWORTH. „ChemInform Abstract: Regioselective and Enantiospecific Synthesis of 6-Substituted and 5,6- Disubstituted Hexahydropyrimidines.“ ChemInform 22, Nr. 50 (22.08.2010): no. http://dx.doi.org/10.1002/chin.199150159.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
31

Tolpygin, I. E. „ChemInform Abstract: Chemosensor Activity of 2-(Anthracen-9-yl)-Substituted Imidazolidines and Hexahydropyrimidines.“ ChemInform 43, Nr. 29 (21.06.2012): no. http://dx.doi.org/10.1002/chin.201229176.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
32

KORBONITS, D., E. TOBIAS-HEJA und P. KOLONITS. „ChemInform Abstract: Ring-Chain Tautomerism of 4-Hydroximino-hexahydropyrimidines Substituted in Position 2.“ ChemInform 22, Nr. 31 (22.08.2010): no. http://dx.doi.org/10.1002/chin.199131084.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
33

KORBONITS, D., E. TOBIAS-HEJA, K. SIMON und P. KOLONITS. „ChemInform Abstract: Solvent-Dependent Reversible Rearrangement of 4-(Hydroxyimino) hexahydropyrimidines to 4-Aminotetrahydropyrimidine 3-Oxides.“ ChemInform 25, Nr. 20 (19.08.2010): no. http://dx.doi.org/10.1002/chin.199420072.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
34

Orelli, Liliana R., María B. García, Isabel A. Perillo, Loris Tonidandel und Pietro Traldi. „A comparison of the electron ionization and electrospray behaviour of some N,N′-disubstituted hexahydropyrimidines“. Rapid Communications in Mass Spectrometry 20, Nr. 5 (07.02.2006): 823–28. http://dx.doi.org/10.1002/rcm.2375.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
35

Subramaniyan, Vasudevan, Ashok Kumar, Anbarasu Govindaraj und Ganesan Mani. „Crystal structure and DFT analyses of a pentacoordinated PCP pincer nickel(II) complex“. Acta Crystallographica Section C Structural Chemistry 75, Nr. 6 (21.05.2019): 734–39. http://dx.doi.org/10.1107/s2053229619006211.

Der volle Inhalt der Quelle
Annotation:
The reaction of NiCl2 with 1,3-bis[(diphenylphosphanyl)methyl]hexahydropyrimidine in the presence of 2,6-dimethylphenyl isocyanide and KPF6 afforded a new pentacoordinated PCP pincer NiII complex, namely {1,3-bis[(diphenylphosphanyl)methyl]hexahydropyrimidin-2-yl-κN 2}(2,6-dimethylphenyl isocyanide-κC)nickel(II) hexafluoridophosphate 0.70-hydrate, [Ni(C9H9N)(C30H30ClN2P2)]PF6·0.7H2O or [NiCl{C(NCH2PPh2)2(CH2)3-κ3 P,C,P′}(Xylyl-NC)]PF6·0.7H2O, in very good yield. Its X-ray structure showed a distorted square-pyramidal geometry and the compound does not undergo dissociation in solution, as shown by variable-temperature NMR and UV–Vis studies. Density functional theory (DFT) calculations provided an insight into the bonding; the nickel dsp 2-hybridized orbitals form the basal plane and the nearly pure p orbital forms the axial bond. This is consistent with the NBO (natural bond orbital) analysis of analogous nickel(II) complexes.
APA, Harvard, Vancouver, ISO und andere Zitierweisen
36

Kireeva, D. R., und A. I. Kamalova. „Synthesis of Hexahydropyrimidines and 1,2,3,4-Tetrahydropyridines by Reaction of Ethyl Benzoylacetate with Formaldehyde and Primary Amines“. Russian Journal of Organic Chemistry 56, Nr. 10 (Oktober 2020): 1733–37. http://dx.doi.org/10.1134/s1070428020100103.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
37

Berges, David A., Jianmei Fan, Sylvie Devinck und Kendall Mower. „Preference for AxialN-Alkylation of Tetrahydro-1,3-oxazines and Hexahydropyrimidines: Manifestation of a Kinetic Anomeric Effect“. Journal of Organic Chemistry 65, Nr. 3 (Februar 2000): 889–94. http://dx.doi.org/10.1021/jo991752i.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
38

Dandia, Anshu, Anuj K. Jain und Sonam Sharma. „Indium triflate catalyzed one-pot multicomponent synthesis of spiro-hexahydropyrimidines explained by multiple covalent bond formation“. Tetrahedron Letters 53, Nr. 39 (September 2012): 5270–74. http://dx.doi.org/10.1016/j.tetlet.2012.07.079.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
39

Maloshitskaya, Olga, Jari Sinkkonen, Vladimir V. Ovcharenko, Kirill N. Zelenin und Kalevi Pihlaja. „Chain-ring-chain tautomerism in 2-aryl-substituted hexahydropyrimidines and 1H-2,3-dihydroperimidines. Does it appear?“ Tetrahedron 60, Nr. 32 (August 2004): 6913–21. http://dx.doi.org/10.1016/j.tet.2004.05.092.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
40

Shephard, MJ, und MN Paddonrow. „A Caveat Concerning the Use of the AM1 and PM3 Semiempirical Methods in Calculating Conformational Preferences in Acyclic Amines and Saturated Azaheterocycles“. Australian Journal of Chemistry 46, Nr. 4 (1993): 547. http://dx.doi.org/10.1071/ch9930547.

Der volle Inhalt der Quelle
Annotation:
A theoretical investigation of the conformational analysis of several acyclic amines, N- alkylated saturated azaheterocycles and alkylcyclohexanes (alkyl = Me, Et, isopropyl, t-butyl) has been carried out by using the MNDO, AM1 and PM3 semiempirical methods. It is found that all three methods correctly predict, qualitatively, the conformational preferences in alkylcyclohexanes, although the PM3 method underestimates the conformational energy for the t-butyl group by as much as 13 kJ/mol. Both AM1 and PM3 overestimate the conformational energy of the nitrogen lone pair to the extent that it exceeds that of the isopropyl group and (in the case of PM3) the t-butyl group, thereby leading to erroneous predictions of favoured conformations in amines and azaheterocycles . Thus, axial N-alkylpiperidines are predicted to be more stable than the equatorial conformers. Thus, application of the AM1 and PM3 methods to the conformational analysis of molecules containing amine functionalities is not recommended. Although the MNDO method gives a qualitative account of the conformational analysis of such molecules, with the exception of hexahydropyridazines and hexahydropyrimidines, the resulting conformational energies and molecular geometries are in poor agreement with experimental data.
APA, Harvard, Vancouver, ISO und andere Zitierweisen
41

Besse, Richard, Peter J. Garratt, Christopher J. Hobbs, Helen M. Rogers, A. Mannan Sueleiman, Christopher S.J. Walpole und Roger Wrigglesworth. „Ring size preference in the intramolecular cyclisation of amines with esters. Synthesis of aminoacid derived hexahydropyrimidines and tetrahydroimidazoles“. Tetrahedron 46, Nr. 23 (Januar 1990): 7803–12. http://dx.doi.org/10.1016/s0040-4020(01)90077-8.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
42

Kar, Purabi, Aparajita Nayak, Y. P. Bhoi und B. G. Mishra. „Preparation and catalytic application of sulfonated PVA-Zr-pillared clay nanocomposite materials towards one pot synthesis of hexahydropyrimidines“. Microporous and Mesoporous Materials 223 (März 2016): 176–86. http://dx.doi.org/10.1016/j.micromeso.2015.11.006.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
43

Dandia, Anshu, Anuj K. Jain und Sonam Sharma. „ChemInform Abstract: Indium Triflate Catalyzed One-Pot Multicomponent Synthesis of Spiro-Hexahydropyrimidines Explained by Multiple Covalent Bond Formation.“ ChemInform 44, Nr. 2 (08.01.2013): no. http://dx.doi.org/10.1002/chin.201302147.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
44

Huang, Zhi-Tang, Wei-Xing Gan und Xiao-Jun Wang. „Synthesis and X-ray structure analysis of 2-[cyano(aryl)-methylene]-imidazolidines, -hexahydropyrimidines, and -hexahydro-1H-1,3-diazepines“. Journal f�r Praktische Chemie 330, Nr. 5 (1988): 724–34. http://dx.doi.org/10.1002/prac.19883300507.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
45

Ahmed, Nayeem, Saima Tarannum und Zeba N. Siddiqui. „ChemInform Abstract: Dy/Chitosan: A Highly Efficient and Recyclable Heterogeneous Nano Catalyst for the Synthesis of Hexahydropyrimidines in Aqueous Media.“ ChemInform 46, Nr. 44 (15.10.2015): no. http://dx.doi.org/10.1002/chin.201544187.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
46

Saraswathi, K., M. Suresh und A. Pandurangan. „Synthesis, Hirshfeld surface analysis, spectral investigations, DFT calculations, ADME studies and molecular docking of Hexahydropyrimidines derivative against dimeric Apolipoprotein A-IV“. Journal of Molecular Structure 1255 (Mai 2022): 132447. http://dx.doi.org/10.1016/j.molstruc.2022.132447.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
47

BESSE, R., P. J. GARRATT, C. J. HOBBS, H. M. ROGERS, A. M. SUELEIMAN, C. S. J. WALPOLE und R. WRIGGLESWORTH. „ChemInform Abstract: Ring Size Preference in the Intramolecular Cyclisation of Amines with Esters. Synthesis of Amino Acid Derived Hexahydropyrimidines and Tetrahydroimidazoles.“ ChemInform 22, Nr. 9 (23.08.2010): no. http://dx.doi.org/10.1002/chin.199109085.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
48

Palermo, Valeria, Ángel Sathicq, Thierry Constantieux, Jean Rodríguez, Patricia Vázquez und Gustavo Romanelli. „New Vanadium Keggin Heteropolyacids Encapsulated in a Silica Framework: Recyclable Catalysts for the Synthesis of Highly Substituted Hexahydropyrimidines Under Suitable Conditions“. Catalysis Letters 145, Nr. 4 (19.02.2015): 1022–32. http://dx.doi.org/10.1007/s10562-015-1498-3.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
49

Huang, Zhi-tang, und Zhi-rong Liu. „Synthesis of 2-(Benzoylmethylene)imidazolidines and -hexahydropyrimidines by Condensation of Ethyl Benzoylacetimidates With 1,2-Ethanediamine or 1,3-Propandiamine, and Some Addition Reactions“. Synthesis 1987, Nr. 04 (1987): 357–62. http://dx.doi.org/10.1055/s-1987-27942.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
50

Ishar, M. P., Gurmit Singh und Gurpinder Singh. „An Efficient Route to Novel 2-(Salicylmethylidine)imidazolidines and (Salicylmethylidene)hexahydropyrimidines through Reactions of 2-(N-Methylanilino)-3-formylchromone with Aliphatic Diamines“. Synlett, Nr. 2 (2003): 0256–58. http://dx.doi.org/10.1055/s-2003-36780.

Der volle Inhalt der Quelle
APA, Harvard, Vancouver, ISO und andere Zitierweisen
Wir bieten Rabatte auf alle Premium-Pläne für Autoren, deren Werke in thematische Literatursammlungen aufgenommen wurden. Kontaktieren Sie uns, um einen einzigartigen Promo-Code zu erhalten!

Zur Bibliographie