Dissertationen zum Thema „Diphosphines synthesis“
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Taylor, Peter Neil. „Synthesis and study of medium-ring diphosphines“. Thesis, University of Bristol, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.319096.
Der volle Inhalt der QuelleLong, James Maurice. „Synthesis of new axially chiral diphosphines and phosphinamines for asymmetric catalysis“. Thesis, University of Oxford, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.337600.
Der volle Inhalt der QuelleWoodworth, Patrick. „Synthesis and Analysis of Gold Nanoclusters“. VCU Scholars Compass, 2018. https://scholarscompass.vcu.edu/etd/5569.
Der volle Inhalt der QuelleLeonard, Thomas Ralph. „New diphosphanes and their application in the synthesis of rigid backboned diphosphines“. Thesis, University of Bristol, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.529843.
Der volle Inhalt der QuelleLam, Tun Chiao Hubert. „Synthesis of chiral amino (amido) diphosphines and applications in palladium catalyzed asymmetric processes“. Thesis, King's College London (University of London), 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.398250.
Der volle Inhalt der QuelleEkanayake, Dewmi A. „Copper Hydride Clusters Stabilized by NH-Centered Diphosphines: Synthesis, Structures, and Implications in Catalysis“. University of Cincinnati / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1626356614867446.
Der volle Inhalt der QuelleMarsh, Paul Samuel. „Synthesis, characterisation and precious metal chemistry of symmetrical and unsymmetrical diphosphines based on 9-phosphabicyclononanes“. Thesis, University of Bristol, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289719.
Der volle Inhalt der QuelleZwart, Guilhem. „Hydrogénolyse de (pseudo-)haloboranes et de chlorophosphines“. Electronic Thesis or Diss., université Paris-Saclay, 2024. http://www.theses.fr/2024UPASF049.
Der volle Inhalt der QuelleThis thesis examines the challenges posed by uncertain access to chemical elements, exacerbated by a linear economic paradigm of their exploitation. The study focuses on boron and phosphorus, whose usage and recycling remain understudied. Boron, crucial in various industries, requires energy-intensive processes to be converted into active hydroboranes, used in fine chemistry. Two methods exist for their synthesis: the industrial method from borate, and the reaction of BCl₃ with a hydride donor. Using H₂ as a reducing agent could improve these processes. This research explores the synthesis of hydroboranes [9-BBN]₂ and [Cy₂BH]₂ from their halogenated and triflate derivatives, with a base and H₂. Base screening showed that trialkylamines, particularly NEt₃, are effective. The reaction relies on a frustrated Lewis pair mechanism to activate H₂. It was also found that dialkylboranes can catalyze the hydrogenolysis of other chloroboranes, particularly BCl₃, yielding HCl₂B· NEt₃ and H₂ClB·NEt₃. Finally, this strategy was extended to phosphorus, optimizing the hydrogenolysis of chlorophosphines into diphosphines. The method, effective for various substrates, proceeds in three steps : catalyst hydrogenolysis, hydride transfer, and base-assisted condensation into diphosphine. These transformations were modeled each time using density functional theory (DFT) and often present long reaction times (up to several days), but usually with good yields (> 70 %) under mild pressure and temperature conditions
Gramage-Doria, Rafael. „Large cavity cyclodextrin-based macrocyclic ligands : synthesis, coordination and catalytic properties“. Phd thesis, Université de Strasbourg, 2012. http://tel.archives-ouvertes.fr/tel-00767168.
Der volle Inhalt der QuelleFiedler, Tobias [Verfasser], und John A. [Akademischer Betreuer] Gladysz. „Syntheses of Gyroscope-like Osmium Complexes and Cage-like Diphosphines = Synthese gyroskopartiger Osmiumkomplexe und käfigartiger Diphosphine / Tobias Fiedler. Betreuer: John A. Gladysz“. Erlangen : Universitätsbibliothek der Universität Erlangen-Nürnberg, 2011. http://d-nb.info/1015475116/34.
Der volle Inhalt der QuelleSalomon, Christine. „Nouvelle synthèse stéréosélective de diphosphines à pont méthano P-stéréogéniques : applications en catalyse asymétrique et pour la préparation de clusters ou de polymères de coordination chiraux“. Thesis, Dijon, 2010. http://www.theses.fr/2010DIJOS010/document.
Der volle Inhalt der QuelleWe were interested in asymmetric synthesis of P-stereogenic methano bridged ligands and in their applications in asymmetric catalysis, coordination chemistry and in the preparation of coordination polymers of transition metals. P-stereogenic diphosphines were obtained highly stereoselectively by creation of a phosphorus-carbon bond on the methano bridge, starting from the anion formed in α position of methylphosphine borane. Several strategies were investigated, with the electrophiles varying from oxazaphospholidine borane complex, phosphinite borane, to chlorophosphine borane. The most stereoselective synthesis was obtained using chlorophosphine borane leading enantiomeric excesses up to 99%. Various methano bridge diphosphine diboranes, dissymmetric or C2-symmetric, bearing alkyl or aryl substituants (Me, OMe, Ph, o-An...), have been synthetised. The first chiral palladium clusters was prepared by reaction of the freshly decomplexed diphosphine with palladium acetate and trifluorocetic acid in water/acetone mixture under CO pressure. The palladium trimetallic center structure of the cluster was confirmed by X-ray analysis. Electrochemical properties and EPR analysis pointed out the formation of the first radical in highly structurated chiral environment. Preliminary studies of the chiral clusters in asymmetric Friedel Craft reaction were carried out, but lead to the product in a non-catalytic way and with no significant optical activity. The prepared chiral ligands were tested in asymmetric catalyzed hydrogenation, hydrosilylation, allylation and Diels Alder reaction using rhodium, palladium and silver derived catalysts and afforded low selectivities from 30 to 38% e.e. Nevertheless, the stereoselective syntheses of the diphosphine ligands elaborated in this work allow to pursue the optimisation of asymmetric catalysis by structural modifications. In the last chapter, P-stereogenic methano bridge diphosphines were used for the preparation of a new class of chiral coordination polymers derived from copper and silver. Photophysical studies and circular dichroism confirmed the 1-D structure and the optical properties of such polymers
Kandala, Srikanth Richmond Michael G. „Synthesis and characterization of diphosphine ligands and diphosphine substituted osmium and ruthenium clusters“. [Denton, Tex.] : University of North Texas, 2007. http://digital.library.unt.edu/permalink/meta-dc-3955.
Der volle Inhalt der QuelleSTEPHAN, MASSOUD. „Synthese enantioselective de mono et diphosphines tertiaires“. Paris 6, 1991. http://www.theses.fr/1991PA066345.
Der volle Inhalt der QuelleCrabtree, Simon Peter. „Synthesis, structure and reaction studies of diphosphine rhodium complexes“. Thesis, Durham University, 1996. http://etheses.dur.ac.uk/5299/.
Der volle Inhalt der QuelleKandala, Srikanth. „Synthesis and characterization of diphosphine ligand substituted osmium and ruthenium clusters“. Thesis, University of North Texas, 2007. https://digital.library.unt.edu/ark:/67531/metadc3955/.
Der volle Inhalt der QuelleLE, GOASTER CELINE. „Synthese asymetrique de nouvelles diphosphines fonctionnalisees et de bis-1,3-oxaphospholanes“. Rennes 1, 1997. http://www.theses.fr/1997REN10163.
Der volle Inhalt der QuelleFraze, Kendra Eileen. „Synthesis, electrochemistry, and thermodynamics of mononuclear and dinuclear nickel(II) diphosphine complexes“. Connect to online resource, 2007. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3273652.
Der volle Inhalt der QuelleNewman, C. R. „A new conformationally flexible diphosphine, NUPHOS, synthesis and applications in asymmetric catalysis“. Thesis, Queen's University Belfast, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.426656.
Der volle Inhalt der QuelleMerdes, Rachid. „Syntheses asymetriques de diphosphines tertiaires chirales et quelques applications a la catalyse homogene“. Paris 6, 1993. http://www.theses.fr/1993PA066428.
Der volle Inhalt der QuellePaavola, Sari. „Synthesis and characterisation of 1,2-diphosphino-o-carborane metal complexes“. Helsinki : University of Helsinki, 2002. http://ethesis.helsinki.fi/julkaisut/mat/kemia/vk/paavola/.
Der volle Inhalt der QuelleMICHAUD, GUILLAUME. „Synthese de nouvelles diphosphines atropoisomeres dissymetriques caracteristiques et evaluation en hydrogenation asymetrique“. Paris 6, 2001. http://www.theses.fr/2001PA066340.
Der volle Inhalt der QuelleLa, PenseÌe Annemarie Agnes. „Homoleptic diarsine and diphosphine complexes of iron(II), ruthenium(II) and rhodium(III) : synthesis and electrochemistry“. Thesis, University of Liverpool, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.250371.
Der volle Inhalt der QuelleSupplee, Carolyn. „Synthesis and characterization of bimetallic palladium and platinum complexes resulting from chelating tertiary/secondary diphosphine ligands /“. The Ohio State University, 1989. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487599963591294.
Der volle Inhalt der QuelleAlmotawa, Ruaa Mohammed. „Silver(I) and Copper(I) Complexes from Homoleptic to Heteroleptic: Synthesis, Structure and Characterization“. Thesis, University of North Texas, 2018. https://digital.library.unt.edu/ark:/67531/metadc1404512/.
Der volle Inhalt der QuelleTang, Pui-ling, und 鄧佩玲. „Synthesis, luminescence and host-guest chemistry of mono- and dinuclear platinum(II) complexes of pyridyl and diphosphine ligands“. Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243654.
Der volle Inhalt der QuelleTang, Pui-ling. „Synthesis, luminescence and host-guest chemistry of mono- and dinuclear platinum(II) complexes of pyridyl and diphosphine ligands /“. Hong Kong : University of Hong Kong, 2002. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155040.
Der volle Inhalt der QuelleCrosman, George Adrian. „Immobilization of Rh-diphosphine complexes on mesostructured materials and their application to asymmetric hydrogenation and hydroboration“. Aachen Shaker, 2009. http://d-nb.info/999464981/04.
Der volle Inhalt der QuelleNyamwihura, Rogers. „Synthesis of Gold Complexes From Diphosphine Ligands and Screening Reactions of Heterocyclic Acetylacetonato (ACAC) Ligands with Transitional Metal Complexes“. Thesis, University of North Texas, 2015. https://digital.library.unt.edu/ark:/67531/metadc804890/.
Der volle Inhalt der QuelleKoner, Abhishek [Verfasser]. „On the imidazole-2-thione-based route to tricyclic 1,4-diphosphinines: synthesis, structures and reactions / Abhishek Koner“. Bonn : Universitäts- und Landesbibliothek Bonn, 2018. http://d-nb.info/1154485862/34.
Der volle Inhalt der QuelleSivakumar, V. „Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes“. Thesis, Indian Institute of Science, 2006. https://etd.iisc.ac.in/handle/2005/293.
Der volle Inhalt der QuelleSivakumar, V. „Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes“. Thesis, Indian Institute of Science, 2006. http://hdl.handle.net/2005/293.
Der volle Inhalt der QuelleJacobsen, George M. „Synthesis, characterization, and reactivity of iron(II) and cobalt(II) complexes containing diphosphine ligands that feature a pendant amine base“. Connect to online resource, 2007. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3256473.
Der volle Inhalt der QuelleWu, Guanmin. „Synthesis, characterization, and kinetics of isomerization, C-H and P-C bond activation for unsaturated diphosphine-coordinated triosmium carbonyl clusters“. Thesis, University of North Texas, 2008. https://digital.library.unt.edu/ark:/67531/metadc6037/.
Der volle Inhalt der QuelleWu, Guanmin Richmond Michael G. „Synthesis characterization, and kinetics of isomerization, C-H and P-C bond activation for unsaturated diphosphine-coordinated triosmium carbonyl clusters“. [Denton, Tex.] : University of North Texas, 2008. http://digital.library.unt.edu/permalink/meta-dc-6037.
Der volle Inhalt der QuelleSamuels, Michiel C. „Solid phase strategies for the preparation of phosphorus ligand libraries“. Thesis, University of St Andrews, 2014. http://hdl.handle.net/10023/6357.
Der volle Inhalt der QuelleFernandez, Cristina Carcedo. „Chiral diphosphine ligands derived from 1, 4:3, 6-dianhydro-d-mannitol : synthesis, co-ordination to transition metals and catalytic applications“. Thesis, Cardiff University, 2005. http://orca.cf.ac.uk/54551/.
Der volle Inhalt der QuelleMayberry, Darrell D. „Synthesis, Characterization, and Reactivity of Prochiral Ruthenium Clusters and Bimetallic Rhenium Complexes with an Unsymmetrical Diphosphine and Hard-Soft Donor Ligands“. Thesis, University of North Texas, 2019. https://digital.library.unt.edu/ark:/67531/metadc1538707/.
Der volle Inhalt der QuellePoola, Bhaskar. „Synthesis and characterization of quinoxaline-functionalized, cage-annulated oxa- and thiacrown ethers and reaction chemistry of the diphosphine ligand 2,3-bis(diphenylphosphino)-N-p-tolylmaleimide (bmi) at triosmium carbonyl clusters“. Thesis, University of North Texas, 2006. https://digital.library.unt.edu/ark:/67531/metadc5608/.
Der volle Inhalt der QuelleLiu, Jie. „Substitution chemistry of the cobalt complexes RCCo3(CO)9 (R = H, CHO) with the diphosphine ligand: 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Syntheses, X-ray structures and reactivity“. Thesis, University of North Texas, 2001. https://digital.library.unt.edu/ark:/67531/metadc3043/.
Der volle Inhalt der QuelleStolze, Karoline. „Synthese und Charakterisierung niedervalenter Actinoidphosphidtelluride und ternärer Selen-Halogenid-Komplexe des Iridiums“. Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-202233.
Der volle Inhalt der QuelleAlberico, Elisabetta [Verfasser]. „Optically active [(η6-arene)Cr(CO)3]-based [(eta6-arene)Cr(CO)3-based] diphosphines : synthesis and application in asymmetric homogeneous hydrogenation / vorgelegt von Elisabetta Alberico“. 2003. http://d-nb.info/970879490/34.
Der volle Inhalt der QuelleBhowmick, Arnab. „Synthesis and characterization of transition metal cluster containing diphosphine ligands“. Thesis, 2012. http://ethesis.nitrkl.ac.in/3085/2/Online_project_on_metal_clusters.pdf.
Der volle Inhalt der QuelleWu, Zih-Shing, und 吳梓翔. „Synthesis and Characterization of Rhenium Isocyanide Complexes and Ruthenium Diphosphine Complexes“. Thesis, 2008. http://ndltd.ncl.edu.tw/handle/17291636285220419350.
Der volle Inhalt der Quelle高雄醫學大學
醫藥暨應用化學研究所碩士班
96
The preparation and characterization of RuCl2(POMe)2 (POMe = diphenyl(2-methoxyphenyl)phosphine) was reported. However, the reactions of RuCl2(POMe)2 with refluxing RCN (R = Me, Et) led to loss of CH3Cl to give Ru(RCN)2(PO)2 (R = Me(1), Et(3)), which are never reported. Adding KPF6 or KBF4 in the reactions will give additional products [Ru(RCN)2(PO)(POMe)]+ (R = Me(2), Et(4)) according to the solvent selection. Complexes 2 and 4 were observed the dealkylating via loss of CH3Cl or [CH3(POMe)]+ pathways. The [CH3(POMe)]+ pathway needs excess POMe which may come from the thermal decomposition of [RuCl(POMe)2(RCN)]+. The NMR and ESI-mass monitoring spectra also help us to understand the Ru complexes dealkylation pathway. The structures of 1, 2, and 3 were confirmed by X-ray analyses.
MacFarlane, Kenneth Shawn. „Synthesis, characterization, and reactivity of ruthenium(II)-diphosphine complexes for catalytic homogeneous hydrogenation“. Thesis, 1995. http://hdl.handle.net/2429/4792.
Der volle Inhalt der QuelleLi, Guo An, und 李國安. „supercritical fluid synthesis of copper diphosphide nanowires for energy storage applications“. Thesis, 2016. http://ndltd.ncl.edu.tw/handle/386cqq.
Der volle Inhalt der Quelle國立清華大學
化學工程學系
105
Phosphorus-rich transition metal phosphide CuP2 nanowires were synthesized with high quality and high yield (∼60%) via the supercritical fluid−liquid−solid (SFLS) growth at 410 °C and 10.2 MPa. The obtained CuP2 nanowires have a high aspect ratio and exhibit a single crystal structure of monoclinic CuP2 without any impurity phase. CuP2 nanowires have progressive improvement for semiconductors and energy storages compared with bulk CuP2. Being utilized for back-gate field effect transistor (FET) measurement, CuP2 nanowires possess a p-type behavior intrinsically with an on/off ratio larger than 104 and its single nanowire electrical transport property exhibits a hole mobility of 147 cm2 V−1 s−1, representing the example of a CuP2 transistor. In addition, CuP2 nanowires can serve as an appealing anode material for a lithium-ion battery electrode. The discharge capacity remained at 945 mA h g−1 after 100 cycles, showing a good capacity retention of 88% based on the first discharge capacity. Even at a high rate of 6 C, the electrode still exhibited an outstanding result with a capacity of ∼600 mA h g−1. Ex-situ transmission electron microscopy and CV tests demonstrate that the stability of capacity retention and remarkable rate capability of the CuP2 nanowires electrode are attributed to the role of the metal phosphide conversion-type lithium storage mechanism. Finally, CuP2 nanowire anodes and LiFePO4 cathodes were assembled into pouch-type lithium batteries offering a capacity over 60 mA h. The full cell shows high capacity and stable capacity retention and can be used as an energy supply to operate electronic devices such as mobile phones and mini 4WD cars. However, due to increasing demand for lithium-ion batteries, lithium metal on earth cannot meet the need so that the price of lithium increases year by year. Future work must be looking for high abundance of alternative materials as ion conduction of battery. Sodium ion battery is currently one of the most feasible option. We applied previously calcined copper phosphide nanowires to sodium ion batteries, and electrochemical results shows that capacity possesses 975 mA h g-1 after 100 charge/discharge cycle, with retention 95%.
Rodríguez-Bárzano, A., Rianne M. Lord, A. M. Basri, Roger M. Phillips, A. J. Blacker und P. C. McGowan. „Synthesis and anticancer activity evaluation of η5-C5(CH3)4R ruthenium complexes bearing chelating diphosphine ligands“. 2014. http://hdl.handle.net/10454/9498.
Der volle Inhalt der QuelleThe complexes [RuCp*(PP)Cl] (Cp* = C5Me5; [1], PP = dppm; [4], PP = Xantphos), [RuCp#(PP)Cl] (Cp# = C5Me4(CH2)5OH; [2], PP = dppm; [5], PP = Xantphos) and [RuCp*(dppm)(CH3CN)][SbF6] [3] were synthesized and evaluated in vitro as anticancer agents. Compounds 1–3 gave nanomolar IC50 values against normoxic A2780 and HT-29 cell lines, and were also tested against hypoxic HT-29 cells, maintaining their high activity. Complex 3 yielded an IC50 value of 0.55 ± 0.03 μM under a 0.1% O2 concentration.
Lin, Chien-Nan, und 林建男. „Dicyanobenzene-, Diphosphine-, and N-Heterocyclic Carbene-Bridged EFe3Cu2 (E = S, Se, Te) Complexes: Synthesis, Transformation, Semiconductivity, and Catalysis“. Thesis, 2015. http://ndltd.ncl.edu.tw/handle/74844266434313295108.
Der volle Inhalt der Quelle國立臺灣師範大學
化學系
103
1. S/Fe/Cu/Dppx System A reversible vapochemical and mechanochemical solid-state transformation between a dppe-linked SFe3Cu2-based cluster [{(m3-S)Fe3(CO)9}Cu2(dppe)] and its 1D polymer [{(m4-S)Fe3(CO)9}Cu2(dppe)(MeCN)2]n, was demonstrated, in which polymer [{(m4-S)Fe3(CO)9}Cu2(dppe)(MeCN)2]n exhibited semi-conducting properties with an energy gap of 1.69 eV. 2. Se, Te/Fe/Cu/p-DCB System When solid reactants [EFe3(CO)9Cu2(MeCN)2] (E = Se, Te) and 1,4-dicyanobenzene (p-DCB) were mixed in 1:1 and 1:1.5 ratios and ground with drops of THF, two EFe3(CO)9Cu2-based THF-encapsulated single/double and single/single p-DCB-linked 1D polymers [SeFe3(CO)9Cu2(p-DCB)1.5•0.5THF]n (1a-THF) and [TeFe3(CO)9Cu2(p-DCB)•THF]n (2b-THF) were obtained, respectively. X-ray analysis showed that the neighboring benzenes of the double p-DCB linkers of 1a-THF displayed a parallel-displaced geometry with an intramolecular pi···pi interaction and the oxygen atom of the lattice THF of 1a-THF or 2b-THF interacted with its adjacent hydrogen atoms of the p-DCB ligands to give weak C─H…O hydrogen bonds. When the grinding solvent changed into CH2Cl2, only TeFe3(CO)9Cu2-based single/double p-DCB-linked polymer [TeFe3(CO)9Cu2(p-DCB)1.5]n (1b) was obtained. Instead, upon heating at 60 oC under vacuum, the lattice THF of 1a-THF could be removed to give [SeFe3(CO)9Cu2(p-DCB)1.5]n (1a). 1a and 1b were isomorphous and exhibited tight crystal-packed structures. Interestingly, when [EFe3(CO)9Cu2(MeCN)2] and p-DCB were mixed in a 1:1.5 ratio and ground with CH2Cl2/toluene (v/v = 1/1), the EFe3(CO)9Cu2-based toluene-encapsulated single/double p-DCB-linked polymers [EFe3(CO)9Cu2(p-DCB)1.5•0.5toluene]n (E = Se, 1a-toluene; Te, 1b-toluene) were obtained, in which the benzene ring of the guest toluene and its adjacent hydrogen atom of the titled benzene of the p-DCB ligand showed significant C─H···pi interaction. In addition, mechanochemically reversible solid-state structural transformations among 1a, 1a-THF, and 1a-toluene, as well as 1b-toluene, 2b-THF, and 1b were achieved by grinding with THF, CH2Cl2, CH2Cl2/toluene, or additional p-DCB ligands, accompanied with the uptake and removal of the lattice solvent, the slippage of the packing layers, and crystal to crystal expansion and contraction. In addition, the measurement of conductivity showed that polymers 1a(1b), 1a(1b)-toluene, and 2b-THF exhibited semiconducting behaviors (dc conductivity, 10−3−10−2 Ω−1cm−1; energy gap, 1.42−1.50 eV) which could be tuned by weak pi···pi interaction and C─H···O hydrogen bonding, elucidated by DFT calculations. 3. Te/Fe/Cu/NHC System A new type of TeFe3(CO)9-incorporated dicopper N-heterocyclic carbene (NHC) complexes was obtained directly from one-pot reactions. By the introduction of the electron-donating and bulky cluster anion [TeFe3(CO)9]2− and NHCs as the ligands, these di-Cu(I)-based complexes exhibited pronounced catalyst activities toward the homocoupling of arylboronic acids with low Cu loadings (0.5 or 1.0 mol%) and high yields (up to 98%).
Elowe, Paul Richard. „The Selective Oligomerization of Ethylene Using Chromium Diphosphine Catalysts and the Synthesis and Reactivity of Group 7 Carbonyl Derivatives Relevant to Synthesis Gas Conversion“. Thesis, 2009. https://thesis.library.caltech.edu/5240/1/1_Title.pdf.
Der volle Inhalt der QuelleThe work presented in this thesis explores two distinct fields of organometallic chemistry with a common goal of selectively transforming cheap and abundant feedstocks to value-added chemicals using homogeneous catalysts.
Chapter 1 presents the synthesis and characterization of a series of bis(diphenylphosphino)amine ligands and their corresponding chromium(III) trichloride complexes. The isolated chromium complexes are precursors to highly active catalysts for the selective oligomerization of ethylene to 1-hexene and 1-octene. The unique feature of the ligands presented herein is the presence of coordinating functionalities tethered to the nitrogen backbone. These act as hemilabile donors, which stabilize the active species and/or transition states during catalysis. This increased stability leads to more productive catalysts. Furthermore, important solvent and additive effects have been investigated. While reactions in non-polar solvents exhibit poor activity at lower ethylene pressures, those in more polar solvents are highly active and generate very little undesired polymer. Varying the solvent has a significant impact on 1-hexene/1-octene selectivity as well. Experiments with potentially coordinating additives result in a higher tendency for 1-octene formation. An investigation of catalyst decomposition is also discussed.
Chapter 2 presents synthetic, structural and reactivity studies on a series of Group 7 carbonyl derivatives relevant to synthesis gas conversion. Reduction of the carbonyl precursors with a hydride source generates the corresponding formyl species. This reaction is facilitated when more electrophilic carbonyl complexes are employed. Neutral and cationic Fischer carbene complexes were prepared by the reaction of the formyl species with boranes and alkyltriflates, respectively. Further reduction of Group 7 methoxycarbenes with a hydride leads to the formation of a reactive methoxymethyl species. Dimethyl ether release is obtained from treatment of a manganese methoxymethyl species with a hydride. Moreover, subjecting manganese methoxymethyl complexes to an atmosphere of CO generates acyl complexes via migratory insertion. Preliminary mechanistic details are presented.
Wang, Chih-Chin, und 王致欽. „Diphosphine-, Dipyridyl-, and N-Heterocyclic Carbene-Bridged EFe3Cu2 (E = S, Se, Te) Complexes: Synthesis, Reactivity, Optical properties, and Catalysis“. Thesis, 2016. http://ndltd.ncl.edu.tw/handle/93291126112830988787.
Der volle Inhalt der QuelleTai-YenLin und 林泰言. „Syntheses and Characterization of Lead(II), Copper(I) and Iron(II) Complexes with tetradentate diphosphine-dithiolate ligand derivatives“. Thesis, 2015. http://ndltd.ncl.edu.tw/handle/17925395142905230744.
Der volle Inhalt der Quelle國立成功大學
化學系
103
Our laboratory has developed a series of phosphine-thiolate ligands in order to understand metal thiolate chemistry. It is anticipated the information provided from this study can bring insights for understanding the metal-sulfur chemistry in biological systems as well as in toxicity. In this thesis, diphosphine-dithiolate ligand (P2S2) was utilized for exploring metal chemistry. 31P, 207Pb NMR in solid and solution state were applied on two lead(II) compelexes, Pb(P2S2”) (1) and [Pb(P2S2”)]2·[Pb2(P2S2”)2] (2). Pb(P2S2”) (1) is a monolead(II) species binding with a P2S2” ligand. [Pb(P2S2”)]2·[Pb2(P2S2”)2] contains two monolead(II) units and a dimeric unit. These compounds were synthesized and characterized in our laboratory before. In addition, a hexacopper(I) complex of P2S2” ligand, [Cu3(P2S2”)(Im)(TMSPhS)]2 , has been isolated and characterized by X-ray crystallography and spectroscopies. Finally, iron carbonyl chemistry with P2S2” ligand was also been explored. The isolated compound was identified as cis-Fe(P2S2”)(CO)2 by comparing the spectroscopies with the other analogue cis-Fe(P2S2*)(CO)2, that is synthesized and well characterized in our laboratory.