Thematische Bibliographien / Aluminosilicates de calcium

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Auswahl der wissenschaftlichen Literatur zum Thema „Aluminosilicates de calcium“

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Veröffentlicht am 25. Mai 2024

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Zeitschriftenartikel zum Thema "Aluminosilicates de calcium"

Loganina, Valentina Ivanovna, Ludmila V. Makarova, Roman V. Tarasov und Anton D. Ryzhov. „The Limy Composite Binder with the Use of the Synthesized Aluminosilicates“. Applied Mechanics and Materials 662 (Oktober 2014): 11–14. http://dx.doi.org/10.4028/www.scientific.net/amm.662.11.

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The information about the structure and properties of the synthesized nanodisperse additive based on the aluminosilicates of calcium, intended for the production of limy dry construction mixes are provided. It is shown that the mineral composition of an additive is presented by crystal types of hydroxides of aluminum (bayerite and boyhmite) and the nanostructured amorphous aluminosilicate of calcium. It is established that the additive based on the aluminosilicates accelerates the process of hardening of limy compositions.

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Abdulvaliyev, Rinat, Nazym Akhmadiyeva, Sergey Gladyshev, Nazira Samenova, Olga Kolesnikova und Olimpiada Mankesheva. „Behavior of Calcium Compounds under Hydrothermal Conditions during Alkaline Leaching of Aluminosilicates with the Synthesis of Fillers for Composites“. Journal of Composites Science 7, Nr. 12 (05.12.2023): 508. http://dx.doi.org/10.3390/jcs7120508.

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Calcium oxide plays an important role in alumina production by binding SiO2 from aluminosilicate raw materials (bauxite, nepheline, kaolinite, etc.) in aluminum-free compounds. The efficiency of the hydrochemical technology depends on the activities of calcium oxide or its compounds introduced into the alkaline aluminosilicate slurry. In this paper, we considered the effects of different calcium compounds (calcium carbonate CaCO3, gypsum CaSO4·H2O, calcium oxide CaO and calcium hydroxide Ca(OH)2), introduced during the hydrothermal stripping of aluminosilicates with alkaline solutions, on the degree of aluminum oxide extraction, with the subsequent production of fillers for composites. Ca(OH)2 was obtained by the CaO quenching method. Extraction of Al2O3 in an alkaline solution was only possible with Ca(OH)2, and the degree of extraction depended on the conditions used for CaO quenching. The effects of temperature and of the duration of CaO quenching on particle size were investigated. In potassium solution, the best results for Al2O3 extraction were obtained using CaSO4·H2O gypsum. The obtained solutions were processed using the crystallization method.

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Jiang, Fengrui, Laifei Cheng, Yiguang Wang und Xuanxuan Huang. „Calcium–magnesium aluminosilicate corrosion of barium–strontium aluminosilicates with different strontium content“. Ceramics International 43, Nr. 1 (Januar 2017): 212–21. http://dx.doi.org/10.1016/j.ceramint.2016.09.138.

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Morozova, Alla G., Tatiana M. Lonzinger, Vadim A. Skotnikov, Gennady G. Mikhailov, Yury Kapelyushin, Mayeen Uddin Khandaker, Amal Alqahtani et al. „Insights into Sorption–Mineralization Mechanism for Sustainable Granular Composite of MgO-CaO-Al2O3-SiO2-CO2 Based on Nanosized Adsorption Centers and Its Effect on Aqueous Cu(II) Removal“. Nanomaterials 12, Nr. 1 (30.12.2021): 116. http://dx.doi.org/10.3390/nano12010116.

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Although copper is needed for living organisms at low concentrations, it is one of the pollutants that should be monitored along with other heavy metals. A novel and sustainable composite mineralizing sorbent based on MgO-CaO-Al2O3-SiO2-CO2 with nanosized adsorption centers was synthesized using natural calcium–magnesium carbonates and clay aluminosilicates for copper sorption. An organometallic modifier was added as a temporary binder and a source of inovalent ions participating in the reactions of defect formation and activated sintering. The sorbent-mineralizer samples of specified composition and properties showed irreversible sorption of Cu2+ ions by the ion exchange reactions Ca2+ ↔ Cu2+ and Mg2+ ↔ Cu2+. The topochemical reactions of the ion exchange 2OH− → CO32−, 2OH− → SO42− and CO32− → SO42− occurred at the surface with formation of the mixed calcium–copper carbonates and sulfates structurally connected with aluminosilicate matrix. The reverse migration of ions to the environment is blocked by the subsequent mineralization of the newly formed interconnected aluminosilicate and carbonate structures.

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Hoyle, Susan L., und Michael W. Grutzeck. „Incorporation of Cesium by Hydrating Calcium Aluminosilicates“. Journal of the American Ceramic Society 72, Nr. 10 (Oktober 1989): 1938–47. http://dx.doi.org/10.1111/j.1151-2916.1989.tb06004.x.

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Loganina, Valentina Ivanovna, Kristina Vladimirovna Zhegera und Maria Anatolyevna Svetalkina. „Additive Based on Synthetic Aluminosilicates for Dry Lime Construction Mixtures“. Physchem 3, Nr. 1 (15.03.2023): 198–209. http://dx.doi.org/10.3390/physchem3010013.

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The possibility of increasing the durability of coatings based on lime dry construction mix by introducing an additive containing synthetic aluminosilicates is substantiated. The regularities of the structure formation of the lime composite in the presence of an additive containing synthetic aluminosilicates, which additionally consists of a formation of calcium–sodium hydrosilicates and minerals of the zeolite group, an increase in the amount of chemically bound lime by 8.74%, are revealed. X-ray diffraction analysis and thermodynamic calculations have established that the mineralogical composition of the crystalline phase of the additive based on synthetic aluminosilicates is represented by thenardite, gibbsite, and the minerals of the zeolite group. It is shown that the content of the amorphous phase is 77.5%. It was found that the additive based on synthetic aluminosilicates is characterized by high activity, which is more than 350 mg/g. It was also found that the introduction of an additive based on synthetic aluminosilicates into the formulation of a lime dry mixture accelerates the curing of coatings and increases the compressive strength after 28 days of air-dry hardening by 1.9 times.

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Gordienko, P. S., I. A. Shabalin, S. B. Yarusova, A. P. Suponina und I. G. Zhevtun. „Sorption of cesium ions by nanostructured calcium aluminosilicates“. Russian Journal of Physical Chemistry A 90, Nr. 10 (18.09.2016): 2022–28. http://dx.doi.org/10.1134/s0036024416100125.

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Daniil, Andreana, George P. Dimitrakopulos, Savvas Varitis, George Vourlias, George Kaimakamis, Erasmia Pantazopoulou, Eleni Pavlidou, Anastasios I. Zouboulis, Theodoros Karakostas und Philomela Komninou. „Stabilization of Cr-rich tannery waste in fly ash matrices“. Waste Management & Research: The Journal for a Sustainable Circular Economy 36, Nr. 9 (31.05.2018): 818–26. http://dx.doi.org/10.1177/0734242x18775488.

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In the present work, the stabilization/solidification of a Cr-rich ash obtained from the anoxic incineration of tannery hazardous wastes was studied. Chromium in the starting waste was exclusively in amorphous form and in trivalent state. The waste was embedded in fly ash-based cementitious material matrices. Calcium and sodium hydroxides, as well as sodium silicate, were used as activators. The proposed process combines mechanical activation with hydrothermal curing. Successful immobilization of chromium was achieved, as attested by standard leaching tests. Backscattered electron images revealed the existence of the C-S-H gel, and elemental mapping by energy dispersive X-ray spectroscopy showed a good interdispersion of chromate and aluminosilicate species, verifying that chromium was well distributed in the final amorphous cementitious matrix. X-ray diffraction confirmed the absence of Cr-rich crystalline phases of calcium aluminosilicates, where chromium can enter in hexavalent state. The stiffness of the stabilized samples was reduced with increasing the amount of added Cr-rich ash, as attested by measurements of the dynamic Young’s modulus.

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Kozhuhova, N. I., I. V. Zhernovsky, M. I. Kozhukhova und E. V. Voitovich. „Correlation of Quality Assessment Methods of Class F Fly as for Synthesis of Geopolymers“. Materials Science Forum 974 (Dezember 2019): 61–66. http://dx.doi.org/10.4028/www.scientific.net/msf.974.61.

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The demand of highly effective aluminosilicates such as class F fly ash for use in geopolymer synthesis initiated a strong scientific interest for a design of the quality assessment methods. At the same time, the existing assessment methods apparently differ in key parameters which determine the quality of aluminosilicate. This research was focused on determination of relationship between the key parameters of different assessment methods for different types of low-calcium fly ash with high portion of vitreous phase. The insoluble aluminosilicate portion in fly ash that remained after treatment in aggressive acidic media followed by high-temperature treatment at 1000 °C (or the parameter α) was measured in this study. The experimental data showed a very low correlation (R2=0.34) between parameter α and compressive strength of the fly-ash based geopolymer paste. The correlation factors between such genetic parameters of fly ash as portion of vitreous phase (C), SiO2-bonding degree in vitreous phase (fSi) and parameter α demonstrated dramatically different values: R2 (С-α)=0.01; R2(fSi-α)=0.71; R2 (С-fSi)=0.0, respectively.

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Śnieżek, Edyta, Maciej Ludwig und Jacek Szczerba. „Formation Mechanism of Gehlenite-Anorthite Materials Containing ZrO₂ from Andalusite, CaCO₃ and ZrO₂“. Key Engineering Materials 788 (November 2018): 120–25. http://dx.doi.org/10.4028/www.scientific.net/kem.788.120.

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This paper reports the results of using natural andalusite (Al2SiO5) in combination with CaCO3 and ZrO2 in order to obtain aluminosilicate product. This work was devoted to the study of the mechanism of new phases creation in the Al2SiO5-CaO-ZrO2 phase system during heating at different temperatures (1000, 1100, 1200, 1300 and 1400°C). Al2SiO5, CaCO3, and ZrO2 were used in a weight ratio of 45:50:5, respectively. According to the phase composition and chemical analysis in microareas, it was found, that andalusite reacted with CaO giving two calcium aluminosilicates: gehlenite and anorthite at 1400°C. ZrO2 was presented as the separated phase at this temperature. Other occurring transition phases were: CaZrO3 at 1000 and 1200°C, Ca2SiO4 at 1000, 1100 and 1200°C, Ca3ZrSi2O9 at 1300°C. The synthesis mostly depended on the diffusion of Ca2+ ions.

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Dissertationen zum Thema "Aluminosilicates de calcium"

Kozaily, Jad. „Structure et dynamique d'aluminosilicates de calcium fondus“. Phd thesis, Université d'Orléans, 2012. http://tel.archives-ouvertes.fr/tel-00717373.

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L'étude des silicates fondus présente un intérêt dans divers domaines de recherche comme la géologie ou la fabrication des verres avec des applications technologiques importantes telles que par exemple, le confinement des déchets nucléaires. Ces recherches demandent des informations fondamentales sur la structure et la dynamique de ces liquides au niveau microscopique mais l'acquisition des données est très souvent limitée par les températures de fusion élevées des composés étudiés. Notre travail s'est donc basé sur l'utilisation de techniques sans contact afin de s'affranchir de cette difficulté. Dans le cadre de cette thèse, nous nous sommes intéressés à l'étude des propriétés structurales et dynamiques de divers aluminosilicates de calcium (CAS) fondus. Pour cela, nous avons développé un dispositif utilisant la lévitation aérodynamique afin d'effectuer des expériences de diffusion quasi-élastique des neutrons. En combinant ces mesures avec la diffusion inélastique des rayons X, nous avons pu obtenir des résultats sur la dynamique microscopique des CAS à l'état liquide ainsi que dans le régime de surfusion. En particulier, nous avons pu déterminer l'évolution de la viscosité avec la température et les coefficients de diffusion cohérents. Nous avons pu aussi étudier l'évolution de la dynamique de ces verres en fonction de l'augmentation de la quantité de silice dans la composition. En parallèle de nos travaux sur la dynamique, nous avons aussi réalisé des expériences de diffraction de neutrons et de rayons X sur les mêmes compositions et températures afin d'examiner l'ordre atomique local et essayer de le corréler aux propriétés dynamiques observées.

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SABER, DRISS. „Une nouvelle famille de materiaux laser potentiels : les aluminosilicates de calcium type gehlenite activee aux lanthanides (nd#3#+, ho#3#+, er#3#+)“. Paris 6, 1991. http://www.theses.fr/1991PA066318.

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Ce travail concerne la recherche des nouveaux materiaux laser solide repondant aux exigences suivantes: 1) rendement eleve grace au pompage par diodes laser (gaalas); 2) emission a des longueurs d'onde variees, principalement autour de 1,5-2 m (tres recherchees actuellement). La gehlenite (ca#2al#2sio#7) a ete choisie comme matrice hote d'ions activateurs terres rares (nd#3#+, ho#3#+, er#3#+, ce#3#+). Cette etude comporte trois parties: 1) evaluation de la capacite d'accueil de cette matrice pour les ions lanthanides et elaboration par la methode czochralski de gros cristaux de ca#2al#2sio#7 dopes; 2) etude approfondie des proprietes optiques de l'ion nd#3#+ dans la gehlenite conduisant a la mise en evidence d'un materiau laser potentiel ca#2al#2sio#7:nd#3#+ susceptible d'etre pompe par diode et de presenter une large accordabilite entre 1,06 et 1,10 m. Les avantages de ce composes par rapport au y#3al#5o#1#2:nd#3#+ (yag) laser solide commercial le plus connu sont presentes et commentes; 3) etude approfondie des proprietes optiques des ions er#3#+, ho#3#+ et ce#3#+ dans la gehlenite conduisant a la mise en evidence de materiaux laser potentiels emettant a des longueurs d'onde variees. En particulier, l'emission de ho#3#+ et er#3#+ respectivement a 1,95 m et 1,54 m permettrait d'envisager, pour ca#2al#2sio#7:ho et ca#2al#2sio#7:er, diverses applications dans le domaine des telecommunications, medical, militaire, etc.

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Le, Cornec Domitille. „Étude de la structure des laitiers vitrifiés de hauts-fourneaux et de leur réactivité à l'eau en milieu basique“. Electronic Thesis or Diss., Sorbonne université, 2019. http://www.theses.fr/2019SORUS556.

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Le laitier de hauts-fourneaux est un sous-produit de l’industrie sidérurgique utilisé comme ajout cimentaire. Ce verre aluminosilicaté riche en calcium (Ca) possède des propriétés hydrauliques latentes. Il permet la fabrication de ciments au laitier ayant une faible empreinte carbone et une bonne résistance aux milieux agressifs. L’objectif de cette thèse est, tout d’abord, d’étudier la structure vitreuse des laitiers et son impact sur les propriétés du matériau. Nous couplons des techniques chimiquement sélectives (XANES et EXAFS) à des techniques permettant une analyse moyenne du matériau (MEB, RPE, PDF) et complétons ces résultats expérimentaux par une modélisation. L’hydratation du laitier se fait par un mécanisme de dissolution-reprécipitation dans lequel le Ca joue un rôle prépondérant. Cet élément se trouve dans des environnements complexes et n’est pas réparti de façon aléatoire dans la structure vitreuse. Les sites du Ca forment un sous-réseau d’éléments modificateurs du réseau vitreux qui pourrait faciliter la dissolution du laitier. Suite à cela, nous étudions la spéciation du titane (Ti) dans les laitiers. Cet élément, présent de façon mineure dans la composition, a été rapporté industriellement comme ayant un impact néfaste sur la résistance mécanique des mortiers contenant des ciments au laitier. Le Ti se trouve majoritairement en coordinance 5 dans les laitiers et il stabilise leur structure vitreuse. Ceci pourrait conduire à une perte de réactivité du matériau et être à l’origine des baisses de performances observées industriellement. Des tests de résistance à la compression sont réalisés sur micro-mortiers
Blast-furnace slag is a by-product of steel industry used as a supplementary cementitious material. This calcium (Ca)-rich aluminosilicate glass has latent hydraulic properties. It can be used to make slag cements with low-carbon footprints and high resistances to aggressive environments.The objective of this thesis is, first, to study the glassy structure of slags and its impact on the properties of the material. We use chemically selective techniques (XANES and EXAFS), medium-range analysis (SEM, EPR, PDF) and complete these results with a simulation. The hydration of slag is based on a dissolution-reprecipitation mechanism in which Ca plays a significant role. This element is in complex environments and is not randomly distributed in the glassy structure. The Ca sites form a modifier sublattice which could make the dissolution of the slag easier.We, then, study the speciation of titanium (Ti) in the slags. This element is minimally present in the composition but according to industrial reports, it lowers the mechanical resistance of mortars containing slag cements. Ti is mainly five-fold coordinated and stabilizes the glassy structure. This could lead to a loss of reactivity of the material and cause the industrially observed performance deterioration. Compressive strength tests are performed on micro-mortars

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Zhang, Siqi. „The effect of boron substitution on the structure of calcium-aluminosilicate calcium-fluoro-aluminosilicate glasses and glass-ceramics“. Thesis, University of Birmingham, 2017. http://etheses.bham.ac.uk//id/eprint/7173/.

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This work focuses on the effect of boron substitution for aluminium on the structure o£ a series of fluorine-free (4.5Si02-3A12O3-1.5P205-5Ca0) and fluorine-containing (4.5Si02-3A1203-1.5P205-3Ca0-2CaF2) glasses and the resultant glass ceramics has been studied by using a combination of analytical tools like helium pycnometer, FTIR, Raman, XRD, multinuclear MAS-NMR spectroscopy and thermal analysis by DSC and TGA. The morphology of the crystal phases was observed by ESEM, and the identification of the composition observed was achieved by EDX. The density of both boron-substituted aluminium glasses and glass ceramics decreased with increasing boron content. The glass transition temperature decreased generally with an increase of boron substitution in fluorine-free glasses. When the sintering temperature was raised to 1100°C, the calcium phosphate (C'4P20 9) phase transferred to the tricalcium phosphate [Ca3(P04)2] phase, and anorthite and aluminium phosphorus phases were crystallised. The fluorapatite phase was the first phase to be formed in the fluorine-containing glass ceramics, and with the sintering temperature raised to 1100°C, the mullite and aluminium phosphorus phases were crystallised. All the NMR results investigate the structure of boron-substituted glasses and glass-ceramics which are agree with XRD results. ESEM and EDX analysis showed changes in the composition of glass ceramics with boron substitution.

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Boissonnet, Germain. „Factors influencing the thermal insulation potential of different thermal barrier coating systems“. Thesis, La Rochelle, 2019. http://www.theses.fr/2019LAROS007.

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Dans les turbines à gaz aéronautiques, les matériaux employés dans les parties les plus chaudes sont soumis à des environnements chimiques extrêmes, sous fortes pressions et températures. Ainsi, des systèmes de revêtement « barrière thermique, BT » sont appliqués sur les substrats en superalliage à base nickel. Ces systèmes multicouches (zircone stabilisée à l’yttrine (YSZ) /couche de liaison en MCrAl ou NiPtAl/substrat refroidi) permettent d’abaisser la température à la surface des pièces, conduisant à un comportement thermomécanique adéquat et à une diminution des vitesses d’oxydation/corrosion. Cependant, l’augmentation nécessaire de la température des gaz d’entrée de turbine (augmentation du rendement moteur) entraîne de nouveaux phénomènes de dégradation (CMAS) et une perte d’efficacité des revêtements BT actuels. Par ailleurs, l’évaluation de la durée de vie des revêtements BT s’avère cruciale pour déterminer celle des moteurs. Comprendre l’évolution du pouvoir isolant des revêtements BT en environnement agressif constitue donc un enjeu essentiel du point de vue scientifique et technologique. A partir des revêtements couramment employés (YSZ) déposés par projection plasma (PS) ou en phase vapeur (EB-PVD), la présente étude a visé à mieux comprendre l’effet de l’évolution des propriétés microstructurales et chimiques des revêtements sur leur pouvoir isolant, dans le but de développer des outils nécessaires à la mise au point des revêtements du futur. De plus, une partie des travaux menés a porté sur une solution alternative plus économique et écologique d’élaboration de revêtements BT, fondée sur un procédé par voie barbotine, permettant in fine d’obtenir une barrière constituée de microsphères creuses d’alumine. Ce travail a permis de montrer que l’évolution par frittage des phases céramiques en YSZ, les changements de phase cristalline, les réactions avec les CMAS et la croissance d’oxydes thermiques modifient la diffusivité thermique. En revanche, celle-ci évolue moins avec la température puisque les revêtements en alumine issus de barbotines se sont avérés plus stables et ce, notamment, lorsque leur élaboration a été réalisée sous atmosphères hybrides (mélanges Ar/air)
In aeronautical gas turbine engines, the metallic materials employed in the hottest sections are subject to very harsh chemical environments at high pressures and temperatures. Therefore, thermal barrier coating systems (TBCs) are applied onto nickel-based superalloy substrates. These multi-layered systems (ceramic yttria-stabilized zirconia (YSZ) / MCrAl or NiPtAl bond coats / cooled substrate) lower the temperature at the components surface, which ensures an adequate thermomechanical behaviour and reduces the oxidation/corrosion rates. However, the increase of the turbine inlet temperature (increased engine performance) brings about new degradation phenomena (e.g. CMAS) and loss of efficiency of the current TBCs. Therefore, understanding the evolution of the insulation ability of TBCs in such harsh environments is key from both the scientific and technological perspectives to estimate the lifetime of these coatings, hence that of the engines. Based on current plasma-sprayed (PS) and electron-beam physical vapour deposited (EB-PVD) YSZ coatings, this thesis seeks to provide a better comprehension on the relationships between the intrinsic properties of the current TBCs and their thermal insulation capacity as a basis for the development of future coatings. Also, this work studies an alternative solution to create a TBC made of hollow alumina microspheres by the slurry route. We will show that the sintering of the YSZ, the evolution of crystal phases, the reactions between YSZ and CMAS and the growth of thermal oxides alter the thermal diffusivity to different extents. In contrast, the evolution of the thermal diffusivity with temperature is less marked with the slurry alumina coatings, which appear more stable when hybrid Ar/air annealing atmospheres are employed upon their synthesis

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Oppici, Maria A. „Sodium sulfate hot corrosion of silicon carbide fiber-reinforced calcium aluminosilicate“. Thesis, Monterey, Calif. : Springfield, Va. : Naval Postgraduate School ; Available from National Technical Information Service, 1995. http://handle.dtic.mil/100.2/ADA297663.

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Bouchouicha, Hamed. „Élaboration, caractérisation structurale et étude des propriétés de luminescence des verres et des vitrocéramiques alumino-silicatés de calcium dopés à l'europium“. Thesis, Lyon, 2016. http://www.theses.fr/2016LYSE1035/document.

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Ce travail de thèse porte sur l'étude des verres alumino-silicatés de calcium dopés à l'europium et le processus de leur cristallisation sous forme des vitrocéramiques dans le cadre de la recherche de nouveaux phosphores pour application LED à émission blanche. Nous avons étudié trois échantillons vitreux avec différentes teneurs en silice et avons élaboré des vitrocéramiques cristallisées. La caractérisation des verres et des vitrocéramiques a été réalisée par différentes techniques expérimentales : l'analyse thermique, la diffraction des rayons X et la spectroscopie de diffusion Raman. Les propriétés spectroscopiques de l'ion europium dans les verres et les vitrocéramiques synthétisés ont été étudiées. Le contrôle de la cristallisation des vitrocéramiques GC34 et GC50 par la diffraction des rayons X a permis d'identifier deux phases la mélilite et l'anorthite. Dans le cas de la vitrocéramique GC7, une seule phase alumino-calcique qui est la mayenite est cristallisée majoritairement. L'étude par la spectroscopie de diffusion Raman a permis d'une part, de suivre l'évolution de la cristallisation pendant les traitements thermiques en surface et en profondeur dans l'ensemble des vitrocéramiques. Nous avons montré que le processus de cristallisation a eu lieu en surface des échantillons et correspond typiquement à une nucléation hétérogène. D'autre part, une étude comparative avec des échantillons naturels analogues prise de la base de données RRUFF nous a permis de valider l'ensemble des résultats trouvés. Dans le cas des vitrocéramiques GC34 et GC50, les mesures des spectres d'émission et les durées de vie de l'ion Eu3+ montrent bien son incorporation dans les phases cristallines formées. L'ion Eu3+ tend à occuper seulement les sites Ca2+ (CN= 8) de la mélilite majoritaire dans la vitrocéramique GC34 alors, qu'il tend à s'incorporer dans les sites Ca2+ (CN= 6 et 7) et Ca2+ (CN=8) respectivement, des phases anorthite et mélilite formées dans la vitrocéramique GC50. Ces résultats ont été confirmés par les mesures d'affinement de raies. L'étude des spectres d'émission de l'ion Eu2+ a permis de mettre en évidence une modification de son environnement durant la cristallisation traduite par son incorporation dans les sites Ca2+ après réduction de l'ion Eu3+ pendant les recuits. Dans le cas de la vitrocéramique GC7, les spectres d'émissions et les mesures du déclin de luminescence de l'ion Eu3+ montrent bien que l'ion Eu3+ est incorporé dans la phase mayenite formée. En terme d'application, les mesures des coordonnées trichromatiques suggèrent que la dévitrification des verres semble être une technique efficace permettant d'obtenir de nouveaux matériaux luminophores (LED blanches) à émission intensifiée (cas des vitrocéramiques GC34 et G50) et accordable en modifiant leur composition et l'excitation
This work concerns the study of calcium aluminosilicate glass doped with europium and their process of crystallization as glass-ceramics as part of the search for new phosphors for white LED application. We studied three glass samples with different silica contents and have elaborated crystallized glass-ceramics. Characterization of glasses and glass-ceramics was performed by different experimental techniques: thermal analysis, X-ray diffraction and Raman spectroscopy. The spectroscopic properties of the europium ion in the glass and glass-ceramic synthesized were studied.Control of crystallization of GC34 and GC50 glass-ceramics by X-ray diffraction have been identified two phases, melilite and anorthite. In the case of the GC7 glass-ceramic, a single aluminum calcium phase, mayenite which crystallized predominantly. The study by Raman spectroscopy allowed to follow the evolution of the crystallization during heat treatment in the surface and of glass-ceramics. We have shown that the crystallization process initiate at the surface of the samples and corresponds typically to a heterogeneous nucleation. On the other hand, a comparison with similar natural samples allowed us to validate all the identifications.In the case of GC34 and GC50 glass-ceramics, emission spectra and lifetimes of Eu3+ ion clearly show its incorporation into the new-formed crystalline phases. The Eu3+ ion occupy the Ca2+ sites (CN = 8) in the major mélilite phase of the the GC34 glass-ceramic while, it incorporates the Ca2+ sites (CN = 6 and 7) and Ca2+ (CN = 8) of anorthite and mélilite phases formed in the GC50 glass-ceramic, respectively. These results were confirmed by Fluorescence Line Narrowing (FLN) measurements. The study of emission spectra of the Eu2+ ion allowed highlighting changes during crystallization associated with the reduction of the Eu3+ ions during annealing. In the case of the low silicate GC7 glass-ceramic, emission spectra and lifetimes measurements of the Eu3+ ion show that the Eu3+ ions are incorporated into the mayenite phase. In terms of application, the analyses of the trichromatic coordinates suggest that the glass devitrification appears to be an efficient technique to achieve new white LED phosphor materials with intensified (mainly for GC34 and G50 glass-ceramics) and tunable emission by varying composition and/or excitation

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Newton, Peter J. „Sodium sulfate corrosion of silicon carbide fiber-reinforced calcium aluminosilicate glass-ceramic matrix composites“. Thesis, Monterey, Calif. : Springfield, Va. : Naval Postgraduate School ; Available from National Technical Information Service, 1994. http://handle.dtic.mil/100.2/ADA283703.

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Bouhadja, Mohammed. „Modélisation des verres d 'aluminosilmicates de calcium par dynamique moléculaire : Structure et dynamique“. Phd thesis, Université de Grenoble, 2013. http://tel.archives-ouvertes.fr/tel-00961955.

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Ce travail a pour but d'étudier les propriétés structurales et dynamiques des verres aluminosilicate de calcium CaO-Al2O3-SiO2 (CAS) par dynamique moléculaire classique, à partir d'un potentiel empirique de type Born-Mayer-Huggins, construit sur la base de résultats de dynamique moléculaire ab initio (AIMD) et expérimentaux. Il montre de bonnes propriétés de transférabilité sur toutes les concentrations pour les propriétés structurales et dynamiques étudiées. L'évolution des propriétés structurales a été étudiée en fonction de la température et de la concentration en silice pour trois rapports de concentrations R = [CaO]/[Al2O3]= 1, 1.57 et 3. Les résultats révèlent la présence d'oxygènes non-pontants et tricoordonnés et d'aluminium penta-coordonnés pour toutes les concentrations dont le nombre diminue avec l'augmentation avec la concentration en silice. L'étude de la viscosité et du temps de relaxation structural avec la température a permis de montrer que la fragilité diminue avec l'augmentation de la concentration en silice pour les trois valeurs de R. Une corrélation avec l'évolution des oxygènes non pontant indique que ces derniers jouent un rôle prépondérant pour la fragilité. Il est montré que la théorie des couplages de modes s'applique à la dynamique des CAS et qu'une violation de la relation de Stokes-Einstein se produit au-dessus du point de fusion expérimental indiquant une hétérogénéité dynamique.

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Selmani, Samira. „Formulation de liants aluminosilicates à partir de différentes argiles tunisiennes“. Thesis, Limoges, 2015. http://www.theses.fr/2015LIMO0041.

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Ce travail est basé sur la synthèse d’un liant aluminosilicaté de type géopolymère à partir de différentes argiles tunisiennes. Afin de comprendre les mécanismes de géopolymérisation, une première étape a concerné la caractérisation des matières premières argileuses par différentes méthodes d’analyses ainsi que leur comportement vis-à-vis du traitement thermique. La faisabilité des matériaux consolidés a été étudiée afin de comprendre le rôle des minéraux associés et la granulométrie de l’argile, en présence d’une solution de référence et de sources aluminosilicatées connues, sur les produits synthétisés. Afin d’identifier le rôle de la solution alcaline, de nouvelles formulations ont été élaborées et comparées aux précédentes en présence des argiles tunisiennes. Plusieurs techniques ont été réalisées pour évaluer les matériaux au cours de leur formation par spectroscopie infrarouge et après consolidation par diffraction des rayons X, microscopie électronique à balayage et analyse thermique. Leurs propriétés mécaniques ont été testées par compression
This work is based on the synthesis of geopolymers from different Tunisian clays. In order to understand the geoplymerization mechanisms two steps are established. The first is relate to the characterization of the raw clays materials through different analyzes and their behavior with thermal treatment. The second involve around the study of geopolymers feasibility in order to understand the role of associated minerals and particle size, in the presence of a reference solution and aluminosilicate sources, on the synthesized products. To identify the role of the alkaline solution, new formulations have been developed and compared with previous one in the presence of Tunisian clays. Several techniques are used to characterize the materials during their formation: Infrared Spectroscopy, X ray diffraction, Scanning Electron Microscopy analysis and Thermal analysis. Their mechanical properties were tested by compression

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Bücher zum Thema "Aluminosilicates de calcium"

Newton, Peter J. Sodium sulfate corrosion of silicon carbide fiber-reinforced calcium aluminosilicate glass-ceramic matrix composites. Monterey, Calif: Naval Postgraduate School, 1994.

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Buchteile zum Thema "Aluminosilicates de calcium"

Goulding, Keith W. T. „Potassium—Calcium Exchange Equilibria in Aluminosilicate Minerals and Soils“. In ACS Symposium Series, 327–40. Washington D.C.: American Chemical Society, 1987. http://dx.doi.org/10.1021/bk-1987-0323.ch015.

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Zhang, Lin, Hiroshi Yamada, Yusuke Imai und Chao Nan Xu. „Development of A Novel Elasticoluminescent Material with Calcium Aluminosilicate“. In High-Performance Ceramics V, 352–54. Stafa: Trans Tech Publications Ltd., 2008. http://dx.doi.org/10.4028/0-87849-473-1.352.

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Schofield, J. M., P. A. Bingham und R. J. Hand. „The Immobilisation of a Chloride Containing Actinide Waste Surrogate in Calcium Aluminosilicate Glasses“. In Ceramic Transactions Series, 69–80. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2009. http://dx.doi.org/10.1002/9780470538371.ch8.

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Law, D. W., C. Gunasekara und S. Setunge. „Use of Brown Coal Ash as a Replacement of Cement in Concrete Masonry Bricks“. In Lecture Notes in Civil Engineering, 23–25. Singapore: Springer Nature Singapore, 2023. http://dx.doi.org/10.1007/978-981-99-3330-3_4.

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AbstractPortland cement production is not regarded as environmentally friendly, because of its associated high carbon emissions, which are responsible for 5% of global emissions. An alternative is to substitute fly ash for Portland cement. Australia has an abundance of brown coal fly ash, as it is the main source of primary energy in the State of Victoria. Currently, the majority of this material is stored in landfills and currently there is no commercial use for it in the cement industry because brown coal fly ash cannot be used as a direct replacement material for Portland cement due to the high sulfur and calcium content and low aluminosilicate content. However, the potential exists to use brown coal fly ash as a geopolymeric material, but there remains a significant amount of research needed to be conducted. One possible application is the production of geopolymer concrete bricks. A research project was undertaken to investigate the use of brown coal fly ash from Latrobe Valley power stations in the manufacture of geopolymer masonry bricks. The research developed a detailed understanding of the fundamental chemistry behind the activation of the brown coal fly ash and the reaction mechanisms involved to enable the development of brown coal fly ash geopolymer concrete bricks. The research identified suitable manufacturing techniques to investigate relationships between compressive strength and processing parameters and to understand the reaction kinetics and microstructural developments. The first phase of the research determined the physical, chemical, and mineralogical properties of the Loy Yang and Yallourn fly ash samples to produce a 100% fly ash-based geopolymer mortar. Optimization of the Loy Yang and Yallourn geopolymer mortars was conducted to identify the chemical properties that were influential in the production of satisfactory geopolymer strength. The Loy Yang mortars were able to produce characteristic compressive strengths acceptable in load-bearing bricks (15 MPa), whereas the Yallourn mortars produced characteristic compressive strengths only acceptable as non-load-bearing bricks (5 MPa). The second phase of the research transposed the optimal geopolymer mortar mix designs into optimal geopolymer concrete mix designs while merging the mix design with the optimal Adbri Masonry (commercial partner) concrete brick mix design. The reference mix designs allowed for optimization of both the Loy Yang and Yallourn geopolymer concrete mix designs, with the Loy Yang mix requiring increased water content because the original mix design was deemed to be too dry. The key factors that influenced the compressive strength of the geopolymer mortars and concrete were identified. The amorphous content was considered a vital aspect during the initial reaction process of the fly ash geopolymers. The amount of unburnt carbon content contained in the fly ash can hinder the reactive process, and ultimately, the compressive strength because unburnt carbon can absorb the activating solution, thus reducing the particle to liquid interaction ratio in conjunction with lowering workability. Also, fly ash with a higher surface area showed lower flowability than fly ash with a smaller surface area. It was identified that higher quantity of fly ash particles <45 microns increased reactivity whereas primarily angular-shaped fly ash suffered from reduced workability. The optimal range of workability lay between the 110–150 mm slump, which corresponded with higher strength displayed for each respective precursor fly ash. Higher quantities of aluminum incorporated into the silicate matrix during the reaction process led to improved compressive strengths, illustrated by the formation of reactive aluminosilicate bonds in the range of 800–1000 cm–1 after geopolymerization, which is evidence of a high degree of reaction. In addition, a more negative fly ash zeta potential of the ash was identified as improving the initial deprotonation and overall reactivity of the geopolymer, whereas a less negative zeta potential of the mortar led to increased agglomeration and improved gel development. Following geopolymerization, increases in the quantity of quartz and decreases in moganite correlated with improved compressive strength of the geopolymers. Overall, Loy Yang geopolymers performed better, primarily due to the higher aluminosilicate content than its Yallourn counterpart. The final step was to transition the optimal geopolymer concrete mix designs to producing commercially acceptable bricks. The results showed that the structural integrity of the specimens was reduced in larger batches, indicating that reactivity was reduced, as was compressive strength. It was identified that there was a relationship between heat transfer, curing regimen and structural integrity in a large-volume geopolymer brick application. Geopolymer bricks were successfully produced from the Loy Yang fly ash, which achieved 15 MPa, suitable for application as a structural brick. Further research is required to understand the relationship between the properties of the fly ash, mixing parameters, curing procedures and the overall process of brown coal geopolymer concrete brick application. In particular, optimizing the production process with regard to reducing the curing temperature to ≤80 °C from the current 120 °C and the use of a one-part solid activator to replace the current liquid activator combination of sodium hydroxide and sodium silicate.

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Shah, Naresh, Gerald P. Huffman, Frank E. Huggins und Anup Shah. „REACTION OF CALCIUM AND ALKALI ELEMENTS WITH ALUMINOSILICATES AND QUARTZ DURING COAL COMBUSTION“. In 1991 International Conference on Coal Science Proceedings, 404–7. Elsevier, 1991. http://dx.doi.org/10.1016/b978-0-7506-0387-4.50103-0.

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Gharzouni, Ameni, Clément Alizé und Sylvie Rossignol. „Fire Resistant Geopolymers Based on Several Clays Mixtures“. In Clay and Clay Minerals [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.98566.

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This chapter aims to highlight the effect of clay mixture mineral composition and alkali concentration of potassium alkaline solutions on the thermal behavior of geopolymer materials. For this, three mixtures composed of kaolin (pure, impure kaolin or mixture of both), calcium carbonate, sand and potassium feldspar and three potassium alkaline silicate solutions with different concentrations were used (5, 6 and 7 mol.L−1). At first, the effect of rotary calcination parameters at 750°C such as the dwell time (30, 60, 120 and 180 min) and weight powder (100, 400 and 500 g) was investigated. It was demonstrated that the kaolin dehydroxylation is quasi complete (> 90%) and do not significantly depend on the dwell time and powder weight. Whereas the carbonate decomposition degree increases with the increase of dwell time and the decrease of powder weight but still not complete (<80%). These differences influence the feasibility of consolidated materials. Indeed, a flash setting occurs for samples based mixtures with high calcium carbonate decomposition degree (> 50%) and low wettability values (500 μL/g) for the three used alkaline solutions. The thermal behavior at 1000°C depends on the chemical composition of the aluminosilicate source and the concentration of alkaline solution. A conservation of the compressive strength at 43 MPa after thermal treatment at 1000°C of geopolymers based on mixture of pure and impure kaolin and a low potassium concentration solution (5 mol.L−1) was evidenced.

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Sato, K., J. Iritani, R. Miyamoto, S. Fujita, K. Suzuki, M. Ohkawa und T. Mori. „Reactivity of superoxide ions (O2−) occluded in micropores of calcium aluminosilicate varied via substitution with transition metal ions“. In Molecular Sieves: From Basic Research to Industrial Applications, Proceedings of the 3rd International Zeolite Symposium (3rd FEZA), 2001–8. Elsevier, 2005. http://dx.doi.org/10.1016/s0167-2991(05)80566-x.

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Konferenzberichte zum Thema "Aluminosilicates de calcium"

Kuleshova, L. A., A. S. Kasakova und I. S. Tatyanchenko. „INFLUENCE OF PRECURSORS ON THE CONTENT OF MINERAL PHOSPHORUS FRACTIONS IN THE SOILS OF RICE FIELDS IN THE ROSTOV REGION.“ In STATE AND DEVELOPMENT PROSPECTS OF AGRIBUSINESS Volume 2. DSTU-Print, 2020. http://dx.doi.org/10.23947/interagro.2020.2.704-708.

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The article is devoted to the problem of phosphoric nutrition of rice on chestnut soils of the northernmost zone of rice cultivation in Russia. The paper reveals the role of water-soluble fractions of phosphorus, aluminosilicates, iron phosphates and calcium phosphates in the nutrition of rice plants during the growing season. The influence of the previous culture on the content and consumption of these fractions was established.

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Stokes, Jamesa L., Michael J. Presby, Rebekah I. Webster, John Setlock und Bryan J. Harder. „Thermochemical/Thermomechanical Synergies in High-Temperature Solid Particle Erosion of CMAS-Exposed EBCs“. In ASME Turbo Expo 2023: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2023. http://dx.doi.org/10.1115/gt2023-101212.

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Abstract Environmental barrier coatings (EBCs) are an enabling technology for the use of SiC-based ceramic matrix composites in next generation gas turbine engines. In the extreme engine environment, EBCs must be able to withstand a variety of individual damage mechanisms and their interactions with each other. Ingested particulates/debris can cause both thermochemical and thermomechanical degradation of EBCs. Siliceous debris primarily based on calcium magnesium aluminosilicates (CMAS) can melt and infiltrate and/or react with EBCs above 1200°C. Similarly, ingested debris can lead to mechanical damage and recession of coatings due to particulate erosion. Both modes of degradation can occur simultaneously during engine operation, and it is crucial to comprehensively understand the mechanisms of coating failure due to high-temperature particulate interactions. This study assesses the erosion durability of Yb2Si2O7-based EBCs exposed to CMAS of various loads in NASA Glenn’s Erosion Burner Rig Facility. CMAS exposures and erosion testing were carried out at 1316°C. The effects of CMAS loading and exposure time on EBC erosion durability were evaluated using Al2O3 as an erodent material.

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Zhang, Y. Y., Y. H. Qi und Z. S. Zou. „Early stage hydration properties of calcium aluminosilicate slag“. In 2016 6th International Conference on Advanced Design and Manufacturing Engineering (ICADME 2016). Paris, France: Atlantis Press, 2016. http://dx.doi.org/10.2991/icadme-16.2016.6.

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dos Santos, J. F. M., L. A. O. Nunes, N. G. C. Astrath, M. L. Baesso, R. Moncorgé und T. Catunda. „High-order nonlinearities in Tb3+ doped calcium aluminosilicate glasses“. In Advanced Solid State Lasers. Washington, D.C.: OSA, 2015. http://dx.doi.org/10.1364/assl.2015.atu2a.11.

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Li, L., N. Hitchman und J. Knapp. „Failure of Thermal Barrier Coatings Subjected to CMAS Attack“. In ITSC2009, herausgegeben von B. R. Marple, M. M. Hyland, Y. C. Lau, C. J. Li, R. S. Lima und G. Montavon. ASM International, 2009. http://dx.doi.org/10.31399/asm.cp.itsc2009p0077.

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Abstract This work investigates the effect of calcium-magnesium aluminosilicate (CMAS) deposits on thermal barrier coatings. CMAS infiltration was achieved by means of a cement tape containing synthetic glass powder. The tape was placed on coating surfaces and melted in a tube furnace or with a flame burner. The resulting coating failures were investigated by examining thermomechanical and thermochemical interactions between the coatings and aluminosilicate deposits. It was found that the porous nature of thermal spray TBCs makes them vulnerable to CMAS attack even before discernible chemical reactions start. Possible mitigation approaches are proposed for improving coating life under such conditions.

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Majidi, Azar P., und Tsu-Wei Chou. „Elevated Temperature Studies of Continuous and Discontinuous Fiber Reinforced Ceramic Matrix Composites“. In ASME 1989 International Gas Turbine and Aeroengine Congress and Exposition. American Society of Mechanical Engineers, 1989. http://dx.doi.org/10.1115/89-gt-124.

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This paper reviews the analytical and experimental investigations at the Center for Composite Materials of the University of Delaware on ceramic matrix composites with continuous and discontinuous reinforcements. The focus is on the strength, fracture and creep behaviors of these composites. The experimental studies have been conducted on hot-pressed SiC whisker reinforced alumina and Nicalon SiC fiber reinforced calcium aluminosilicate (CAS) composites.

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Borrero-González, L. J., I. A. A. Terra, L. A. O. Nunes, A. N. Medina und M. L. Baesso. „Spectroscopic Properties and Laser Performance in Yb3+, Er3+ Co-Doped Calcium Aluminosilicate Glasses“. In Laser Science. Washington, D.C.: OSA, 2012. http://dx.doi.org/10.1364/ls.2012.lw5i.4.

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Sohn, Y. H., P. Mohan, P. Schelling und D. Nguyen. „Degradation of Thermal Barrier Coatings by Fuel Impurities and CMAS“. In ITSC2009, herausgegeben von B. R. Marple, M. M. Hyland, Y. C. Lau, C. J. Li, R. S. Lima und G. Montavon. ASM International, 2009. http://dx.doi.org/10.31399/asm.cp.itsc2009p0089.

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Abstract This study investigates the degradation of YSZ-CoNiCrAlY thermal barrier coatings (TBCs) due to vanadium and phosphorus pentoxides and calcium-magnesium aluminosilicate (CMAS) sand at temperatures up to 1400 °C. The pentoxides are shown to degrade bond coat and topcoat layers through acidic dissolution, while CMAS sand is shown to degrade YSZ layers through ingress and the precipitation of ZrO2 grains. Density functional theory simulations provide insights on reactions at the surface of fluorite-structured oxides and the role of oxygen vacancy clustering. A method to mitigate melt-infiltration attack through electrophoretic deposition is introduced.

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Wei, Liu, Wang Qing, Xu Changfeng, Zhang Mengchuan, Kong Xinmin, Yao Erdong und Que Junren. „A Green and Environmentally Friendly Chelated Retarding Acid for Acidification of Sandstone Reservoirs“. In ASME 2022 41st International Conference on Ocean, Offshore and Arctic Engineering. American Society of Mechanical Engineers, 2022. http://dx.doi.org/10.1115/omae2022-79271.

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Abstract Matrix acidizing is the main method to relieve formation damage in sandstone reservoirs. However, many problems in conventional mud acid acidification need to be carefully considered, such as fast acid-rock reaction, short effective action time, excessive dissolution near the well zone, and the secondary sedimentations from fluorosilicic acid, aluminosilicate, calcium fluoride and other pollution of the reservoir. In this paper, a green and degradable amino acid chelating agent is investigated. This new type of sandstone chelating retarded acid system have features of chelating metal ions and slow proton release. The chelating ability of new retarder acid to calcium and iron metal ions was determined by complexometric titration. The retarding performance of chelating retarder acid were studied by core flow instrument and microscopic scanning electron microscopy. The results show that the new acid system is manifested by strong chelating ability to iron and calcium ions, low corrosion rate, good retarding performance. The permeability is increased by 225% after acidification. The results of electron microscopy scanning of the core surface before and after acidification show that the new acid solution acidification can effectively enlarge the pore-throat without generating secondary precipitations, which is a good choice for sandstone acidification practice.

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Le Losq, Charles, Bjorn O. Mysen und George D. Cody. „In situ Raman Spectroscopy of Water-Bearing Calcium Aluminosilicate Melts during High Temperature and High Pressure Diamond Cell Experiments“. In Goldschmidt2020. Geochemical Society, 2020. http://dx.doi.org/10.46427/gold2020.1453.

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